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SECTION
STRAIGHT OBJECTIVE TYPE
4.1 In which reaction will an increase in the volume of the container favor the formation of products?
(A) C (s) H 2O( g ) CO( g ) H 2 ( g )
NH 4 HS (s) NH3 ( g ) H 2 S ( g ) is 0.16. The maximum pressure developed in the vessel will be :
(A) 0.8 atm (B) 0.40 atm (C) 0.5 atm (D) None of these
4.16 A vessel contains x mole of A, y mole of B, z mole of C & n moles of an inert gas. The total pressure
due to reacting substances is P0 & vessel pressure is P. then K p for A( g ) B( g ) C ( g ) is
(A) P0 yz ( x2 xy xz ) (B) Pyz ( x2 xy zx hx)
(C) (A) & (B) both (D) None of these
4.17 For the reaction N2 ( g ) 3H 2 ( g ) 2 NH3 ( g ), H 93.6 kJ mol 1. The concentration of H 2 at
equilibrium will increase if
(A) The temperature is lowered (B) The volume of the system is decreased
(C) N 2 is added at constant volume (D) NH 3 is added
4.18 In the preparation of lime stone from the reaction CaCO3 ( s) CaO( s) CO2 ( g ) between a
8500
temperature range of 950 C.K P values follow the following relation log K P 7.27 . In order
T
to decompose all limestone what minimum temperature would be predicted if reaction is carried
out in quiet air & atmospheric pressure is 1 atm.
(A) 896 C (B) 850 C (C) 950 C (D) 800 C
4.19 For the reaction 2 NH3 ( g ) N2 ( g ) 3H 2 ( g ) x kcal, which is correct?
(A) Degree of dissociation will increase on decreasing temperature.
(B) On decreasing the volume of container degree of dissociation will increase.
(C) K C will decrease on increasing temperature.
(D) On adding inert gas at constant pressure the amount of ammonia will increase.
4.20 For a reversible reaction KC K P & H 100 kJ the reverse reaction is favoured if :
(A) Both P & T are reduced (B) P increased & T decreased
(C) Both P & T are increased (D) P decreased & T increased
4.21 In a two step exothermic reaction
A2 ( g ) B2 ( g ) 3C ( g ) D( g ) ; H ve, steps 1 & 2 are favoured
respectively by :
(A) High pressure, high temperature & low pressure, low temperature.
(B) Low pressure, low temperature & low pressure, low temperature.
(C) High pressure, low temperature & low pressure, low temperature.
(D) Low pressure, high temperature & high pressure, high temperature.
4.22 For the reaction CaCO3 ( s) CaO( s) CO2 ( g ) the equilibrium amount of CO2 can be
increased by :
(A) Adding a suitable catalyst (B) Adding more limestone
(C) Increasing volume (D) Adding inert gas at constant volume
4.23 Which one of the following changes would result in a darkening of the colour?
N2O4 ( g ) 2 NO2 ( g ) H ve
(A) Increasing pressure (B) Increases in temperature
(C) Adding inert gas at constant pressure (D) Addition of charcoal
4.24 Solid ammonium cynide decompose in to NH 3 ( g ) & HCN(g) reversibly. The two gases are in
equimolar ratio at all moments. If K p for NH 4CN ( s) NH3 ( g ) HCN ( g ) is 4 atm. The increase
in moles of ammonia due to decomposition is 33.3% then maximum amount of solid decomposed
is:
(A) V/RT moles (B) 2V/RT moles (C) V/3RT moles (D) 3V/RT moles
4.25 For the following equilibrium, 2SO2 ( g ) O2 ( g ) 2SO3 ( g ) the total equilibrium pressure is P1. If
volume of the system is reduced to 1/2 of this initial volume then equilibrium is reestablished. The
new equilibrium total pressure will be :
(A) 2P1 (B) 3 P1 (C) 3.5 P1 (D) Less than 2 P1
4.26 For the reaction: 2A B 3C at 298 K, Kc 49
A 3L vessel contains 2, 1 and 2 moles of A, B and C respectively.
The reaction at the same temperature:
(A) Must proceed in forward direction (B) Must proceed in backward direction
(C) Must be in equilibrium (D) Cannot be predicted
4.27 In a reaction mixture containing H 2 , N 2 and NH 3 at partial pressure of 2 atm, 1 atm and 3 atm
respectively, the value of K p at 725 K is 4.28 105 atm2 . In which direction the net reaction will
go?
N2 ( g ) 3H 2 ( g ) 2 NH 3 ( g )
(A) Forward (B) Backward (C) No net reaction (D) Direction cannot be predicted
4.28 In the following reaction :
2SO2 ( g ) O2 ( g ) 2SO3 ( g )
the equilibrium is not attained. The rate of forward reaction is greater than that of backward
reaction. Thus, which of the following is the correct relation between K p and Qp ?
(A) K p Qp (B) Qp K p (C) Qp K p (D) K p Qp 1
4.29 The equilibrium constant K c for the reaction P4 ( g ) 2 P2 ( g ) is 1.4 at 400 C. Suppose that 3
moles of P4 ( g ) and 2 moles of P2 ( g ) are mixed in 2 litre container at 400 C. What is the value of
reaction quotient (Q)?
3 2
(A) (B) (C) 1 (D) None of these
2 3
4.30 For the reaction A( g ) 3B( g ) 2C ( g ) at 27 C , 2 moles of A, 4 moles of B and 6 moles of C are
present in 2 litre vessel. If K c for the reaction is 1.2, the reaction will proceed in :
(A) Forward direction (B) Backward direction
(C) Neither direction (D) None of these
4.31 When sulphur (in the form of S8 ) is heated at temperature T , at equilibrium, the pressure of S8
falls by 30% from 1.0 atm, because S8 ( g ) is partially converted into S2 ( g ).
Find the value of K p for this reaction.
(A) 2.96 (B) 6.14 (C) 204.8 (D) None of these
4.32 In the presence of excess of anhydrous SrCl2 , the amount of water taken up is governed by
K p 1012 atm4 for the following reaction at 273 K
ANSWERS
4.1 (A) 4.2 (B) 4.3 (C) 4.4 (A) 4.5 (A)
4.6 (C) 4.7 (A) 4.8 (C) 4.9 (A) 4.10 (A)
4.11 (D) 4.12 (B) 4.13 (C) 4.14 (B) 4.15 (C)
4.16 (C) 4.17 (D) 4.18 (A) 4.19 (D) 4.20 (C)
4.21 (B) 4.22 (C) 4.23 (B) 4.24 (A) 4.25 (D)
4.26 (A) 4.27 (B) 4.28 (C) 4.29 (B) 4.30 (A)
4.31 (A) 4.32 (C) 4.33 (A) 4.34 (A) 4.35 (C)
4.36 (C) 4.37 (D) 4.38 (B) 4.39 (B) 4.40 (D)
4.41 (A) 4.42 (A) 4.43 (A) 4.44 (C) 4.45 (C)