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Suggestion solutions
(b) (i) coal-fired power stations; fuel in cars; car exhausts/gas emissions; other named use of a
fossil fuel; contact process; cement manufacture; brick manufacture; roasting of sulphide
ores; burning tyres (any 2) [1]
(NOT volcanoes etc; NOT burning of natural gas)
(no marks for only 1 correct source)
(Reject ionic bond for SnO2 as it repeats the words ionic structure).
(iii) HCO3¯ + H+ → H2CO3 or H2O + CO2 (or equation with H3O+) [1]
HCO3¯ + OH¯ → CO32- + H2O [1]
• (Reject H2CO3 + OH- because question said how HCO3- maintains pH. This implies
that HCO3- reacts with H+ and OH- in an irreversible manner to get rid of them
hence without causing pH to decrease or increase (respectively).)
• (Note: Question is a buffer question)
(Reject “extensive hydrogen bonding”. This implies the substance should be soluble and
extensive or less extensive makes it more or less soluble. The question provided the context
that it ether and water are insoluble, hence the two layers are observed.)
(ii) H H
O
H2N C C NH C CO2H
CH2 CH2OH
CH
H3C CH3
(d) (i) H
-
H2N C COO
CH2
COO-
H3C
(ii) H
-
H2N C COO
(CH2)2
H2N
pH changes will interfere with the hydrogen bonding that is going to happen for B and D. In B,
removes –COOH ability to form H-bonding and in D, removes –NH2 ability to use it lone pair to
attract a H. (Reject: If the –NH2 and the –COOH on the α-carbon is reacted.)
Show by drawing a diagram how the electrostatic attraction between –COO- and –NH3+ will be
disrupted because of their interaction with the heavy metal ion.
(accept: students saying only the –COO- affected. The –NH3+ is indirectly affected because once
the –COO- is bonded with the heavy metal ion, it can’t exhibit electrostatic attraction with the –
NH3+)
(Reject: Heavy metal, M, Na. Using Ca2+, Cd2+, Pb2+ are used)
It facilitates the re-charging process. Re-generates the reactants for the battery to work.
[1]
(b) (i) two from C, CO, hydrocarbon, SO2, H2S, NO2/NOx [1+1]
not CO2, H2, H2O, SO3, NO
(Note: It is important to remember that when Cl2 is dissolved in NaOH, Cl- and ClO- are formed. When
both are added in the presence of acid, they will create Cl2.)
(c) Delocalised ring of electrons (in benzene) is stable, (so is re-formed in second step in
benzene.)
or electrons in the ethene π bond are localised/more available for reaction with electrophiles [1]
(Note: Need to talk about the delocalized electron ring because that arises due to the stability
because of aromaticity. It is insufficient to just state “lose stability due to aromaticity”.)
(d) For a given rate equation: rate = k[A]n
n is the order of reaction. It is given with respect to a given reactant and it is defined as the
power to which the concentration of that reactant raised to in the experimentally determined
rate equation.
1st order w.r.t to ketone [1] 1st order w.r.t to CN- [1] zero order w.r.t to H+ [1]
SN1 mechanism with the formation of the carbocation (draw structure) which enables the
propanol and hydroxide ion to attack it. [1]
2-chloro methylbenzene cannot undergo nucleophilic substitution because the C-Cl bond has
partial double character due to overlapping of p orbital between Cl and the π electron cloud. [1]
A mall coin of mass 3.40g was dissolved in nitric acid and an excess of DMG was added. The
precipitated Ni-DMG was filtered off, washed and dried. Its mas was 4.00g.