Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Desalination
journal homepage: www.elsevier.com/locate/desal
Desalination and energy consumption. What can we expect in the near MARK
future?
Domingo Zarzoa,⁎, Daniel Pratsb
a
Valoriza Agua, Paseo de la Castellana, 83-85, 28046 Madrid, Spain
b
University Institute of the Water and the Environmental Sciences, University of Alicante, San Vicente del Raspeig s/n, Alicante, Spain
A R T I C L E I N F O A B S T R A C T
Keywords: Desalination technologies have become necessary tools for hydrological planning, along with conventional water
Desalination resources.
Reverse osmosis One of the main barriers to extend desalination is higher water costs, which are seriously influenced by
Energy energy consumption (represents > 50–60% of total costs).
Renewable
This paper takes into account relevant energy and desalination aspects and different available technologies.
Membranes
This work focuses mainly on reverse osmosis, which is the most widely used technology. It also considers
aspects like major consumers and their contribution to overall. The configuration of HP pumps, membranes and
ERDs is explored, as is what we can expect in the future, while we bear in mind that we are currently very close
to reaching the thermodynamic limits for energy consumption.
Special dedication will be taken to renewable energies and how they can be combined with desalination to
produce more efficient systems, though not necessarily directly coupled to desalination plants.
How to choose the most adequate energy rates and the production plus storage combination is another im-
portant consideration to optimize energy costs. An adequate production management strategy can significantly
reduce the cost of water.
To conclude, emerging technologies are analyzed, by looking at all the possible improvements and potential
generated uses.
⁎
Corresponding author.
E-mail address: dzarzo@sacyr.com (D. Zarzo).
http://dx.doi.org/10.1016/j.desal.2017.10.046
Received 31 August 2017; Received in revised form 25 October 2017; Accepted 25 October 2017
0011-9164/ © 2017 Elsevier B.V. All rights reserved.
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
Table 1 Table 3
Specific energy consumption in different large desalination plants (design). The EC breakdown at the Southern Seawater Desalination Plant (SSDP), Binningup,
Source: Valoriza Agua. Western Australia (SWRO, 306,000 m3/day).
Source: Valoriza Agua.
Plant Capacity Contract year SEC (kW-h/m3)
(m3/day) Process SEC (kW-h/m3) Percentage (%)
2
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
Table 4
Comparison of different pretreatment alternatives.
(Adapted from Buendia et al. [7]).
Gravity filtration + pressurized filtration. Filter backwash made with filtered water Pretreatment recovery (92%) 0.620
Gravity filtration + pressurized filtration. Filter backwash made with brine Pretreatment recovery (96%) 0.613
Double stage filtration (pressurized). Filter backwash made with brine Pretreatment recovery (98%) 0.680
1 stage pressurized filtration. Filter backwash with brine Pretreatment recovery (98%) 0.585
1 stage pressurized filtration. With no low pressure pumps. Filter backwash with brine Pretreatment recovery (98%) 0.576
Double stage filtration (gravity). Filter backwash made with brine Pretreatment recovery (96%) 0.543
3
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
3.5.1. Seawater
Fig. 2. A HP pump with a VFD (represented in orange). (For interpretation of the re-
The use of ERDs for seawater RO was established entirely many
ferences to color in this figure legend, the reader is referred to the web version of this years ago. Due to the high pressure supplied to membrane remains in
article.) brine, with the reduction caused by pressure losses in membranes,
pipes, valves, etc., this pressure can be used to reduce the plant's energy
use. For this purpose, a number of different devices has been histori-
cally used, such as turbines (Pelton, Francis) or current pressure ex-
changers (aka isobaric, hyperbaric), with different designs (displace-
ment, rotating), which are widespread in all modern seawater plants.
Logically, these systems are very efficient with seawater given
higher pressures and higher brine flows, while their use and effective-
ness are lower and less frequent with brackish water plants (they work
with lower pressures and brine flows).
In the study previously mentioned in Section 3.2. (Buendia et al.
[7]), a comparison was also made of the different options for the con-
figuration of high pressure pumps and ERDs, as shown in Table 7.
Further to the premises described in Section 3.2., the following data
were assumed:
First pass RO inlet pressure: constant 67 bar
Second pass RO inlet pressure: constant 12.5 bar
Fig. 3. A HP pump with a previous booster pump with a VFD (VFD in orange). (For
Efficiency of ERDs (hyperbaric type): 94%.
interpretation of the references to color in this figure legend, the reader is referred to the
web version of this article.)
For the comparative calculations, the same temperatures, mem-
branes and membrane agings were used.
Despite the simulation dating back to 2011, not many advances
have been developed in recent years for it to be rendered obsolete.
Table 7
Comparison of different HP pumps, ERDs and RO trains.
(Adapted from Buendia et al. [7]).
1 High pressure pump 1st pass with Pelton wheel as an ERD, 3.31
high pressure pump 2nd pass with a VFD
2 High pressure pump 1st pass with a booster pump with a 2.960
VFD. Hyperbaric ERD system with a booster pump with a
VFD, high pressure pump 2nd pass with a VFD
3 Case 2 + interstage turbocharger in 2nd pass 2.923
Fig. 5. Pressure center concept. 4 Pumps in pressure center 2.835
5 Case 2 + Split-hybrid concept in membranes 2.713
6 Case 6 + SWRO membranes in 2nd pass 2.667
7 Case 2 without 2nd pass 2.248
4
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
5
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
Table 9
Historical development of the energy consumption at SWRO Las Palmas III (Spain).
Adapted from Lemes et al. [9].
Design Year SEC (kW-h/ Reduction in SEC from Plant capacity (m3/ Permeate conductivity (μS/ Plant recovery (%)
m3) origin (%) day) cm)
Original design: Francis turbines, 315 ft2 1996 6.67 – 36,000 2600 45.00
membranes
New Pelton wheels (six trains) and 315 ft2 1998 5.85 12.3 36,000 1000 47.90
membranes
Intermediate booster pumps in HP pumps. Brine 2001 5.11 23.4 50,000 1234 48.60
concentrator concept
7th train (new) and increase in PV and membranes 2001 5.11 23.4 57,800 1234 48.60
in all racks
8th train (new) 2003 4.76 28.6 66,000 1498 51.16
10th and 11th trains (new) 2006 4.63 30.6 80,000 1100 52.80
Installing new ERDs (ERI-PX) in trains 5 & 6 2007 4.5 32.5 80,000 1212 53.30
together
Installing new ERDs (ERI-PX) in trains 4 & 7 2009 4.33 35.1 85,000 518 50.75
(individually)
New ERDs in all racks 2011 4.1 38.5 86,500 404 50.08
Table 10
Example of calculations for the supply of a large SWRO plant by solar energy [18].
Case Description Installed power (MWp) Generation Capex (millions of €) Amortization (years) Footprint (Mm2)
1 The whole plant fed by solar energy (SE) 350 100% 700 26 9
2 SE to compensate the peak consumption 255 100% 217 12 5
3 Legal auto-consumption 51.2 20% 46 11 1
desalination plants. In most countries, electrical tariffs depend on dif- and experiences of how to use renewable energies in desalination. Fig. 7
ferent periods (peak, off-peak, shoulder, etc.), which can be used to is a scheme of how to feed different technologies by distinct renewable
adapt the plant's production to the best tariffs. energy sources.
These strategies need some storage capacity to adapt production to The nature of the required energy depends on the desalination
requirements, and are more easily implemented in BWRO plants be- process, which can require different forms of energy (thermal, elec-
cause the frequent shutdowns of SWRO plants are not recommendable trical, etc.). The options for applying renewable energies in desalination
for membranes. are: 1) as a source of energy; 2) directly in the internal operation of
It is also possible to take advantage of this strategy if a plant has desalination systems.
seasonal production, but this can sometimes go against our interests; Although industry clearly intends to improve and implement re-
e.g., where energy costs are higher during peak water demands. newable energies in desalination, there are some difficulties for it to
As a relevant example, the BWRO plant Cuevas de Almanzora in spread:
Almeria (Spain) produces water for agriculture irrigation (30,000 m3/
day) with production automatically coupled to the electrical tariff - Production capacity: the energy demand from desalination plants is
timetable, and with automatic shutdown during peak periods and re- very high and the production capacity by renewables is generally
starts during lower price periods. Thanks to this measure, the average low
production cost is 0.34 €/m3 with an energy consumption of 2 kW-h/ - Location: the site selected for a desalination plant in not necessarily
m3 (0.9 in RO + 1.1 in product water pumping) for an average raw the best place to install a renewable energy system. This can be
water salinity of 15,000 μS/cm [18]. solved by locating the renewable energy far away from the desali-
nation plant and by supplying the electrical network which was the
6. Using renewable energies case of the SSDP plant in Australia, fed by the Mumbida wind farm
near Geraldton (400 km north of Perth, 22 turbines, 55 kW) and the
A complete book would be required to describe all the alternatives Greenough River 10 MW Solar farm (80 ha, 150,000 PV panels) [19]
6
D. Zarzo, D. Prats
Table 11
Comparison of the main emerging technologies.
(Adapted from [22]).
Technology FO PV MD CDI
Fundamentals A draw solution with high osmotic pressure is used Membrane separation process with nonporous Pre-heated saline water and permeate are on two An electrochemically induced alternative approach to
to extract the product water from seawater or high membranes applied to miscible liquids. Separation sides of a hydrophobic membrane, which maintains remove ions from concentrated aqueous solutions by
salinity water passing through a membrane. is produced by applying a vacuum on the the liquid streams out of the membrane. Due to ΔT forcing charged ions onto the electrical double layer at
Furthermore, water is separated from the draw membrane side where the permeate is collected as and the vapor pressure driving force, water is an electrode-solution interface when the electrode is
solution by means of thermal or membrane vapor, which is finally condensed as a product. vaporized from the feed side, diffused through the connected to an external power supply.
processes. membrane and finally condensed into the cold
permeate side, to leave salts on the feed side.
Strengths High rejections, low membrane fouling and Latent heat lower than evaporation techniques, Large membrane contact area, high salt rejection, Low operating cost. It is readily amenable to solar
potentially less operation energy useful for temperature- sensitive compounds small footprint and mild operation conditions, power for the photovoltaic production of the necessary
7
capable of integrating renewable energies from electrical power. It requires less pre-treatment of the
different sources feed water, up to 80% energy recovery, charge reversal
drives off any foulants adsorbed on the electrode
surface.
Challenges Reduced fluxes – increased membrane area. Lack of Low permeate flow rate, water flux and membrane Low permeate flow rate and water flux, membrane The most critical component is carbon electrode
effective draw solutions. Separation techniques. stability fouling and membrane pore wetting, long-term materials; electrosorptive capacity strongly depends on
performance, and uncertain economics and energy physical properties, such as surface area and
costs conductivity of the electrode.
Processes -Pressure- enhanced osmosis (PEO) -Vacuum PV -Direct contact MD –
-PRO -PV with carrier gas -Air gap MD
-Integrated FO-RO systems -Vacuum MD
Possible uses Desalination, osmotic power generation and others Desalination, dehydration of organic solvents, Desalination, in general, membrane contactors for Desalination
(osmotic MBR, landfill leachate treatment) separation of azeotropic solutions (ethanol/water) providing gas/liquid or liquid/liquid mass transfer
areas (separation of the aqueous solutions of
organics), water degasification
Current situation Pilot and small plants, some manufacturers produce Commercially used for the dehydration of ethanol Laboratory, pilot and small plants Pilot and small plants
membranes. and isopropanol. For desalination, pilot and small
plants
Desalination 427 (2018) 1–9
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
Table 12
(Relatively) new trends in desalination plants (own making).
Trends Remarks
Use of pressure exchange energy recovery systems Absolutely extended in SWRO plants. Less extended in brackish water systems.
Hybrid/split membrane systems Implemented in many large facilities. Reduced energy consumption.
UF as a pretreatment Increasingly extended in large plants. Unfortunately it is not valid for any plant (depends on water quality, fouling,
etc.), and some problems have arisen in large plants. Relatively little impact on energy consumption.
New UF membranes Continuously being developed. Comes close to the commercialization of new UF membranes close to NF. Relatively
little impact on energy consumption.
Use of larger membranes (16–18″) Installed in some large facilities to save the Capex, but not very extensive given membrane weight and management
difficulties. Relatively little impact on energy consumption.
New membranes with a modified surface (nanotubes, Being developed. Slowly commercialized until the appearance of new membrane companies with some large contracts.
nanoparticles) Apparently new developments are reducing energy consumption although in less extent that it was expected.
Large installations versus small installations Economy of scale versus localized energy consumption and brine discharge, proximity to end users and production
management. From the energy consumption point of view large installations are more efficient.
Reduced chemical dosing – zero chemicals A rising trend; reduction in production costs and fouling. Little impact on energy consumption.
Modularity, train sizes, pressure centers Energy optimization versus flexibility in operation.
Another problem of renewable energies is that they can be affected Evidently, the main potential use of these technologies is to produce
by climate change, having impact over wind, solar radiation, rain, energy using the osmotic potential, which has been previously de-
surface water flow, etc. scribed.
In a recent study [21], three hydroelectrical power stations were In a study which analyzed most of these technologies, along with
analyzed in Spain by modeling the energy production during the their advantages and disadvantages, Morillo et al. [23] concluded that
1930–2098 period by considering the predictable effect of climate membrane distillation, FO, electro-separation processes and metal re-
change. covery were the most promising technologies to treat brines from de-
According to this study, energy production is expected to lower, salination plants.
with values ranging from 33% to 73% depending on the power plant, Finally, Table 12 summarizes the state of current trends in RO
water flow, etc. This was studied in different scenarios by presenting plants.
lack of economical feasibility for the three power plants in the future.
By emerging technologies we mean those that are still in the re- Desalination has grown extraordinarily in recent years due to im-
search phase, or have not passed pilot plant stages or have not devel- proved technologies and cost reductions, but limits in energy use op-
oped prototypes. In the desalination field, the best-known are: timization still seem to exist.
Different processes and stages can be optimized when designing
- Forward osmosis (in its various forms: FO, PRO, etc.) desalination plants to accomplish a more efficient plant, besides new
- Pervaporation (PV) developments in membrane manufacturing and new ERDs.
A consensus has been reached in the industry about the need to use
8
D. Zarzo, D. Prats Desalination 427 (2018) 1–9
renewable energies in desalination. However some difficulties, such as [9] R. Lemes, J.L. Perez, L. Lorenzo, D. Zarzo, R. Falcon, R. Arocha, et al., Evolution of
production and energy savings in SWRO plant of Las Palmas III, IDA World
capacity, intermittent production or legal framework, limit this appli- Congress on Desalination and Water Reuse 2011. Perth (Australia), 2011.
cation. [10] T. Chung, L. Luo, F.W. Wan, Y. Cui, G. Amy, What is next for forward osmosis (FO)
Although this is not strictly reduction in energy consumption, the and pressure retarded osmosis (PRO), Sep. Purif. Technol. 156 (2) (2015) 856–860.
[11] A. Ordonez, B. Gutierrez, El aprovechamiento energético de la salmuera mediante
flexibility and management of production and shutdown periods can, osmosis directa (in Spanish), AEDyR (Spanish Desalination and Reuse Association),
besides offering adequate electrical tariffs, reduce energy-related costs. Madrid (Spain), 2012.
Unfortunately, the development of emerging technologies re- [12] R.E. Pattle, Production of electric power by mixing fresh and salt water in the hy-
droelectric pile, Nature 174 (1954) 660.
presents small slow steps for industry, but has promising applications, [13] S. Loeb, Osmotic power plants, Science 189 (1974).
such as energy production using salinity gradients. [14] R.A. Tufa, E. Curcio, W.V. Baak, J. Veerman, S. Grasman, E. Fontananova,
A radical change in technology is not expected in the next few years G.D. Profio, Potential of brackish water and brine for energy generation by salinity
gradient power-reverse electrodialysis (SGP-RE), RSC Adv. 4 (2014) 42617–42623.
and, in any case, coming close to a thermodynamic limit makes a sig-
[15] R.D. Cusick, Y. Kim, B.E. Logan, Energy capture from thermolytic solutions in mi-
nificant reduction in energy use a difficult task. crobial reverse-electrodialysis cells, Science 335 (2012) 1474–1477.
[16] F. Helfer, O. Sahin, C.J. Lemckert, Y.G. Anissimov, Salinity gradient energy: a new
References source of renewable energy in Australia, Water Util. J. 5 (2013) 3–13.
[17] W. Akram, M.H. Sharqawy, J.H. Leinhard, Energy utilization of brine from an MSF
desalination plant by pressure retarded osmosis, Proceedings of the International
[1] IDA, GWI, IDA Desalination Yearbook 2017–2018, Ed. Media Analytics Ltd, UK, Desalination Association World Congress on Desalination and Water Reuse. Tianjin
2017. (China), 2013.
[2] IDA, GWI, IDA Desalination Yearbook 2014–2015, Ed. Media Analytics Ltd, UK, [18] F. Molina, E. Campos, D. Zarzo, Energy recovery and optimization in a brackish
2015. water desalination plant with variable salinity, IDA World Congress on Desalination
[3] F. Lopez, Acuamed, the Spanish approach – the public corporation model, Regional and Water Reuse 2015. San Diego (USA), 2015.
Mediterraean Workshop on Desalination, Non Revenue Water Reduction and [19] M.A. Sanz, D. Zarzo, Australian Desalination plants. PPP models and solutions for
Public-Private-Partnership under Water Scarcity 2016, World Bank, Marseille, the environment, 2 case studies, World Bank Workshop 2016. Marseille, France,
France, 2016. 2016.
[4] AEDyR, Spanish Desalination and Reuse Association, (2009). [20] D. Lopez, Is it possible to obtain desalinated water from the sun? Water and Energy
[5] E. Crespo, Recuperacion de energia mediante turbinado de salmuera en plantas Workshop, University of Alicante, Spain, 2014.
desaladoras, Jornada Tecnica Servicios energéticos y las ventajas de la desalacion y [21] K. Solaun, E. Cerda, The impact of climate change in hydroelectrical generation.
reutilizacion del agua. Las Palmas de Gran Canaria (Spain) October 2017, 2017. Pilot study of 3 power plants, Aquaenergy Conference 2017, Madrid, Spain, 2017.
[6] J. Arrieta, Global partnerships for SWRO & energy recovery devices, Texas Desal [22] D. Zarzo, Problematica Y Soluciones para la Gestion Y Tratamiento de Salmueras
2017. Austin (Texas, USA) September 2017, 2017. Procedentes De Desaladoras (Problem and Solutions for the Management and
[7] R. Buendia, A. Diaz, C. Garcia, D. Zarzo, SWRO design; evolution of energy and Treatment of Brines from Desalination Plants) (PhD Thesis, 2017), University of
chemical consumption and future trends, IDA World Congress on Desalination and Alicante, Spain, 2017.
Water Reuse 2011. Perth (Australia), 2011. [23] J. Morillo, J. Usero, D. Rosado, H. El Bakouri, A. Riaza, F.J. Bernaola, Comparative
[8] C. Garcia, F. Molina, D. Zarzo, 7 year operation of a BWRO plant with raw water study of brine management technologies for desalination plants, Desalination 336
from a coastal aquifer for agricultural irrigation, Desalin. Water Treat. 31 (2011) (2014) 32–49.
331–338.