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International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

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International Journal of Heat and Mass Transfer


journal homepage: www.elsevier.com/locate/ijhmt

Evaluation of a human skin surface temperature for the protective


clothing – Skin system based on the protective clothing–skin imitating
material results
Piotr Furmański ⇑, Piotr Łapka
Institute of Heat Engineering, Warsaw University of Technology, Nowowiejska St. 21/25, 00-665 Warsaw, Poland

a r t i c l e i n f o a b s t r a c t

Article history: Experimental studies used for evaluation of quality of the fire-fighters protective clothing are based on
Received 14 December 2016 irradiation of the clothing sample by an external pulse of a given duration. The other side of the clothing
Received in revised form 6 May 2017 sample is in contact with a material imitating the human skin, which has properties different than these
Accepted 9 June 2017
of the skin. Therefore the problem considered in this paper was: what conditions should be satisfied to
convert the experimental results, carried out on the stand with a skin-imitating material, to the case
of the real human skin with different properties for which the experiments are not made? This will allow
Keywords:
for better evaluation of the clothing protecting properties and estimation of the possible burns. Due to
Heat transfer
Protective clothing
multilayer structure of the protective clothing and skin as well as complex phenomena involved in
Skin temperature energy transfer through them the problem is very complicated. Therefore at the first attempt to solve
Temperature conversion method the problem a simplified two-layer, clothing-skin system irradiated from external heat source was con-
sidered in the present paper. Temperature variation in the system was initially determined using the in-
house 1D numerical code accounting for heat conduction in the skin and clothing, non-grey thermal radi-
ation absorption, scattering and emission together with the water vapour diffusion and phase transfor-
mations of bound water to the gaseous phase in the protective clothing. Then the analytical model for
temperature variation in the considered system was proposed and solved using the Laplace transform
approach. In the latter model water vapour diffusion with its phase transformations were excluded
and radiation emission was neglected. The analytical model allowed for deriving a formula which can
be applied for converting the skin surface temperature obtained from the experiments carried out using
the skin-imitating material to the material having skin properties. In order to verify the range of validity
of the formula the analytical predictions were compared to the results of numerical simulations of tem-
perature in the protective clothing-skin system considering cases in which different phenomena were
included. For the majority of the cases studied good matching between analytical and numerical results
was obtained for time corresponding to the heating and cooling processes of the protective clothing-skin
system.
Ó 2017 Elsevier Ltd. All rights reserved.

1. Introduction and convective but of lower intensity. Contact with these hazards
may lead to a risk of serious thermal skin burns. Therefore, to pre-
In many professions, e.g., firefighters, soldiers, petro-chemical vent thermal injuries the firefighters wear the special protective
workers hazards caused by gas ignition, gas and steam explosions, clothing allowing them to safety escape to a secure location in case
electric arc, etc. can occur. Thermal exposure related to these phe- of emergency situation. The typical protective clothing is made of
nomena have usually high intensity, of an order of 80 kW/m2, and several layers of fabric material, e.g., outer shell, moisture barrier,
is characterized by short time of duration of an order of seconds. thermal insulation and inner layer separated by thin air gaps –
During extinguishing of fires (including forest fires) the firefighters see Fig. 1. Performance of these clothing is directly related to com-
are exposed to longer thermal loads, which may be both radiative plex ways of heat and moisture transfer through such multilayer
garments as well as to heat transfer in the human skin.
Quality of the protective clothing is evaluated both by numeri-
⇑ Corresponding author.
cal simulations and experimental investigations. The simulations
E-mail addresses: pfurm@itc.pw.edu.pl (P. Furmański), Piotr.Lapka@itc.pw.edu.pl
(P. Łapka). are based on complex models accounting for different ways of heat

http://dx.doi.org/10.1016/j.ijheatmasstransfer.2017.06.033
0017-9310/Ó 2017 Elsevier Ltd. All rights reserved.
1332 P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

Fig. 1. Schematic of the multilayer structure of the protective clothing and skin.

and moisture transfer in the clothing [1–11]. Moreover, they resemble properties of the human skin [15]. The skin-simulant
require detailed knowledge of a variety of clothing properties as was attached to a water-cooled plate, whose temperature was kept
well as the model of human skin in order to predict skin burns. at 37 °C with a thermocouple mounted on the surface of skin sim-
The experimental studies use either a mannequin placed in a ulant [16]. Temperature reading from the thermocouple was used
chamber with a flash fire generated or the specially designed lab- together with a semi-infinite body model to evaluate heat flux
oratory stands with samples of the protective clothing reaching the skin-simulant [15–17]. Extension of the proposed test
investigated. method, originally based on the plate geometry, to the cylindrical
In the first case fire test system uses the life-sized mannequin one allowed to study influence of the protective clothing on human
made from a flame-resistant polyester resin reinforced with fibre- limbs (e.g., human arm) [18,19]. The test apparatus used the quartz
glass. The mannequin is instrumented with a large number of heat tubes distributed circularly around the adiabatic sheath. The cloth-
flux sensors distributed over the surface of its body. The measure- ing sample together with skin-simulant (glass ceramic) were
ments are carried out on a mannequin dressed with the test gar- attached to the inner water-cooled cylindrical column maintained
ment or protective clothing [12]. The heat coming from the flash at 37 °C by a constant temperature bath [18,19].
fire generated in the chamber is transferred through the protective As already mentioned in the lab-scale tests one side of the sam-
clothing and the air gap, located between the clothing and man- ple is often irradiated by an external heat pulse of a given duration.
nequin and finally to the heat flux sensors located on its surface. The other side of the sample is in contact with a material imitating
Data from the sensors are collected by a computer and translated the human skin or the copper calorimeter which generally has dif-
into the surface heat flux history, then into the skin temperature ferent properties than the skin. Moreover, neither generation of
distribution history and finally are used for the skin burn damage metabolic heat nor heat transfer by the blood perfusion are
prediction [12]. accounted for in the skin-simulant. The question is then raised if
In the case when the specially designed laboratory stands are and how temperature measurements carried out on the skin-
applied one side of the clothing sample is often irradiated by an imitating material can be converted to the time-variation in the
external heat pulse of a given duration. The opposite side of the human skin surface temperature. The same question is valid for
sample is in contact with a material imitating the human skin the case when the life-size mannequin are used built from materi-
(skin-simulant). Temperatures of the front and back sides of the als with different properties than the human body. The correct
clothing sample are usually measured with thermocouples. Keltner answer will allow to evaluate the clothing protecting properties
[13] measured clothing samples placed between a film heater and and estimate of the possible burns. Therefore the main objective
a skin-simulant sensor. The other side of the sensor was exposed to of the paper was to find a formula which will allow for conver-
the ambient air. Temperature elevation of the skin-simulant sensor sion of the results obtained on the experimental stands using
was recorded, and then this information was input into a skin skin-imitating material to these corresponding to the real skin
model to predict the time to II degree burns [13,14]. Temperature properties. The problem is complex due multilayer structure of
recorded at the back side of the sample clothing (opposite to the the human skin and the protective clothing, different heat transfer
irradiated one) was also used for prediction of the fabric behaviour modes involved (heat conduction and thermal radiation accompa-
[2] in the case when the back side of the clothing was thermally nied by moisture transport) and presence of the heat generation,
insulated with a calcium silicate board. Torvi and Todd [11] used absorption and phase change phenomena (metabolic heat, thermal
the lab-scale test, in which a copper calorimeter with a thermocou- radiation absorption and moisture phase transformations) in the
ple mounted was placed on the other side of thermally irradiated protective clothing-skin system. Moreover, the thermal radiation
sample of the protective clothing. The calorimeter was mounted can be spectrally emitted, scattered and absorbed [20]. Thus in
in an insulating block and recording of its temperature allowed general it seems extremely complicated and even not possible to
to find heat flux leaving the sample and to estimate time required accurately predict the human skin surface temperature variation
to II degree burns [11]. In the further development of the test Tbs(t) basing on temperature measurements carried out on the
methods the skin-simulant was chosen to be a 12.8 mm thickness skin-imitating material Tbsi(t) as heat transfer phenomena and
glass ceramic block with the thermal conductivity of ksi = 1.46 W/ properties of both media are different and lead to different thermal
(m K) and thermal diffusivity of asi = 7.3  107 m2/s, which interaction with the protective clothing.
P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340 1333

Therefore at the first attempt to solve the problem a simplified exerts influence on the metabolic heat generated. The arterial
two-layer, clothing-skin system irradiated from external heat and venous blood temperatures are usually different with the
source was considered in the present paper. The effective proper- venous blood approaching temperature of ambient tissues, while
ties of the protective clothing and skin layers were found by aver- the arterial blood contributes to the body heating. Moreover, the
aging the respective properties of the clothing and skin layers. abrupt heating leads to thermal reaction of the human body which
Temperature variation in the two-layer system was initially deter- manifests itself by intense perspiration, dehydration, vaso-
mined using the in-house 1D numerical code accounting for heat dilatation of the blood vessels, etc. All these coupled and non-
conduction in the skin and clothing, thermal radiation absorption, linear transport phenomena occurring both in the protective cloth-
scattering and emission together with the water vapour diffusion ing and skin make the mathematical modelling and numerical sim-
and phase transformations of bound water to the gaseous phase ulations very difficult [3–8,21,22].
in the protective clothing. The main purpose of numerical simula- Therefore to reach the main goal of the study presented in the
tions was to find which phenomena, accompanying heat transfer introduction a simplified two layer system was considered – see
through the protective clothing, are the most influential on the Fig. 2. The protective clothing layer has the thickness dc while
variation in the skin surface temperature Then the analytical solu- the skin layer the thickness ds. The assumed thermophysical prop-
tion for temperature variation in the considered system based on erties of the skin layers are given in Table 1, while Tables 2 and 3
the Laplace transform approach was proposed. In the latter solu- contain the thermophysical and optical properties of the protective
tion only some phenomena were considered with the water vapour clothing, respectively. The properties have been averaged account-
diffusion and its phase transformations excluded and radiation ing for thickness of the respective layers.
emission neglected. The analytical solution, together with the The thickness averaged properties of the skin and protective
order of magnitude evaluation of different terms, allowed for layer were calculated according to the following formulae:
deriving a simple formula which can be applied for converting
the skin surface temperature Tbsi(t) obtained from the experiments d X
carried out using the skin-imitating material to temperature Tbs(t) k¼P ; ðqcÞ ¼ di ðqcÞi =d;
i i =ki
d i
matching the material having skin properties. Finally, in order to !, ,
Y X
verify the range of validity of the conversion method the analytical K e ¼ ln e K e;i di
d and n ¼ di ni d ð1Þ
predictions were subsequently compared to the results of numer- i i
ical simulations of the skin surface temperature in the protective
clothing-skin system. where the thickness of the air gaps between fabric layers were
assumed to be 0.1 mm, while between the third layer and the skin
6.35 mm. Other properties (d, D, R, e and s) were assumed the same
2. Numerical model as for the first fabric layer (Table 2). The effective thermo-physical
and optical properties were presented in Tables 4 and 5, respec-
The protective clothing is usually made of several layers of fab- tively. Moreover, in Table 4 the properties of the skin imitating
rics which may be separated by thin air gaps. Three or four layers material (PET), which approached to the greatest extent the respec-
are often used, i.e., the outer shell, moisture barrier, thermal insu- tive skin properties, were also inserted.
lation and lining – see Fig. 1. Each of these textile layers has differ- The right side of the considered protective clothing is irradiated
ent thermophysical and optical properties and performs different by the external heat flux qe(t) of the known variation in time, while
role. These layers are porous materials and made of hygroscopic the left side of the skin is kept at constant temperature correspond-
fibres. Therefore many complex transfer phenomena are involved ing to this existing in depth of the human body Tcr = const – see
in energy transfer through the clothing such as heat conduction Fig. 2. The model assumed one dimensional heat and moisture
by fibres and air in the pores, forced convection induced by body transfer due to the small thickness of the considered system in
motion or blast of the external air and thermal radiation coming comparison to its lateral dimensions along the protective clothing
from external heat source and penetrating the semi-transparent and assumed no variation of external thermal conditions in this
clothing with non-grey properties. Additionally, these processes direction. All properties were treated as temperature independent.
are accompanied by diffusion and convection of water vapour in
the garment as well as sorption and desorption phenomena in fab-
2.1. Heat and moisture transfer in the protective clothing and skin
ric fibres. The surroundings and human body (perspiration) are
two main sources of the moisture in garments. Moreover, the
Convection in the hygroscopic porous fabric as well as presence of
water content in the different layers of the protective clothing
free liquid water (only liquid water bounded by textile fibres
affects energy transfer processes as well optical and thermo-
present) were neglected. Additionally, the clothes were assumed
physical properties of the clothing. The clothing during emergency
semi-transparent and containing humid air with the dry air being sta-
situations is exposed to either high temperature or radiative heat
tionary and the water vapour diffusing. Noting the assumption made
flux coming from hot objects. Besides, depending on the fuel burnt,
the energy equation for the protective clothing can be written as:
the fire may have different spectrum of radiation. The visible and
 
near infrared radiation in the wavelength range from about 0.6 @T c @ @T c @q @q
to 1.4 lm is usually not transmitted through the optically thick ðqcÞc ¼ kc þDv a;c v cv T c þ m
_ v bw ðDhv ap þ Dhads Þ r
@t @x @x @x @x
clothing materials. Furthermore, high temperature which may be
ð2Þ
observed in the protective clothing leads to thermochemical reac-
tions and changes in the fabric structure as well as in optical and The first term on the right hand side accounted for heat conduc-
thermo-physical properties. tion in the fabrics or air gaps, the second one for heat transfer asso-
Surface layers of the human body has also the complex struc- ciated with the water vapour diffusion in the fabric, the third one
ture (epidermis, dermis, subcutaneous, muscles). The heat is not for heat absorbed (released) during transition of the water vapour
only conducted or exchanged by blood perfusion with the ambient into liquid water bounded in fibres in fabrics, while the fourth one
tissue but also generated due to metabolism. The perfusion and for thermal radiation in the protective clothing.
metabolic heat generation are generally dependent on the tissue The continuity equation for bounded water in fibres (describing
temperature. Shivering of the tissue and performed work also sorption and desorption phenomenon) was expressed as:
1334 P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

Fig. 2. Schematic of the corresponding, simplified two-layer model of the protective clothing-skin system.

Table 1
Thermo-physical properties and thickness of skin layers [3] (k – thermal conductivity, Heat transfer in the skin may be using different models
q – density, cp – specific heat and d – thickness). [6–8,21,22] but in the present study model the most simple form
of the energy equation for the skin layer was assumed, which fol-
Symbol [unit] Epidermis Dermis Subcutaneous
lowed the Pennes model and which can be presented in the form
ki [W/(m K)] 0.255 0.523 0.167
[8]:
qi [kg/m3] 1200 1200 1000
cpi [kJ/(kg K)] 3.6 3.4 3.06  
@T s @ @T s
di [mm] 0.08 2 10 ðqcÞs ¼ ks þ ðqcÞb xb ðT cr  T s Þ þ qm ð5Þ
@t @x @x
The respective symbols in Eqs. (2)–(5) denote: (qc) – volumetric
specific heat at constant pressure, Dv-a – water vapour diffusion
@
_ v bw
ðq ebw Þ ¼ m ð3Þ coefficient, k – thermal conductivity, m _ v bw – mass rate of transi-
@t w
tion of moisture from bounded to gaseous state, qr – radiative heat
Diffusion of the water vapour through pores of the protective flux, T – temperature, Dhabs – latent heat of desorption, Dhvap –
clothing and its phase transition to or from bounded state was latent heat of vaporization, xb – blood perfusion rate, e – volume
modelled by following equation: fraction, q – density. The sum of volume fractions satisfied the fol-
  lowing constraint: ebw + ef + eg = 1 in the fabric. In the equations
@ @ @q
ðqv eg Þ ¼ Dv a;c v  m_ v bw ð4Þ above the subscripts: a, b, bw, c, cr, f, g, s and v correspond to:
@t @x @x
dry air, blood, bound water, clothing, body interior, dry fabric,

Table 2
Thermo-physical properties and thickness of protective clothing layers [4] (d – average fibre diameter, D – effective diffusivity of bound water in the solid phase (fibres), R – fibre
regain, e – volume fraction of fibre, s – the tortuosity factor).

Symbol [unit] First layer (Kombat 7.5 oz/yd2) Second layer (ComfortZoneTM) Third layer (AraliteTM)
ki [W/(m K)] 0.179 0.144 0.130
qi [kg/m3] 1384 1295 1380
cpi [kJ/(kg K)] 1.42 1.325 1.2
di [mm] 0.56 0.73 1.66
ei [–] 0.334 0.186 0.115
Ri,/=0.65 [–] 0.084 0.038 0.045
si [–] 1.5 1.25 1.0
Di [m2/s] 6.0  1014 6.0  1014 6.0  1014
di [m] 1.6  105 1.6  105 1.6  105

Table 3
Optical properties of the fabrics [4] (Ke – extinction coefficient, n – refractive index, k – wavelength, x – albedo).

k [lm] First layer Second layer Third layer


Ke,i [1/m] ni [–] xi [–] Ke,i [1/m] ni [–] xi [–] Ke,i [1/m] ni [–] xi [–]
0 0.4 Opaque 1.1937 0.5 Opaque 1.1079 0.5 Opaque 1.0667 0.5
0.4 0.7 396.2 178.1 138.3
0.7 2.5 933.7 590.4 319.7
2.5 5.0 2719.4 1960.3 922.1
5.0 1 Opaque Opaque Opaque
P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340 1335

Table 4
The layers-averaged properties of skin, skin imitation protective clothing as well as some selected blood properties (a – thermal diffusivity, b – thermal effusivity, Fo – Fourier
number, xb – blood perfusion rate, (qc) – volumetric specific heat).

Layer/property Skin Skin simulant Protective clothing Blood


k [W/(m K)] 0.1887 0.2 0.0346 –
(qc) [kg/m3] 323.72  104 154.0  104 53.79  104 399.62  104
d [mm] 12.08 18 9.5 –
pffiffiffiffiffiffiffiffiffiffi
b ¼ kðqcÞ [Ws1/2/(m2 K)] 781.58 554.98 136.42 –
a [m2/s] 5.829  108 12.99  108 6.432  108 –
Fo = as/d 4.993  103 11.28  103 8.724  103 –
xb [m3/(s m3)] – – – 1.25  103
e [–] – – 0.334 –
R/=0.65 [–] – – 0.084 –
s [–] – – 1.5 –
D [m2/s] – – 6.0  1014 –
d [m] – – 1.6  105 –

Table 5
The layers-averaged radiative properties of non-grey fabric.
r;k;e ¼ eh;k Eb;k ðT h Þ ¼ qe;k ðtÞ
qin ð11Þ
k [lm] Ke [1/m] n [–] x [–]
0 0.4 Opaque 1.031 0.5 where the subscripts amb, ce, e, f, h, in and k denote the ambient,
0.4 0.7 61.2 clothing surface, external, fabric layer, hot, incident and wave-
0.7 2.5 156.3 length, respectively. The symbol Eb,k is the spectral blackbody emis-
2.5 5.0 472.1
sive power [23], hamb and hm – convective heat and mass transfer
5.0 1 Opaque _
coefficients, respectively, r – surface hemispherical reflectivity
[23,25], Tamb and Th – temperatures of the ambient air and hot gases,
moist air, skin and water vapour, respectively. For more details respectively. Finally the symbols eh,k is the hot gases monochro-
regarding mathematical modeling of the protective clothing-skin matic emissivity while qe,k is the external radiative heat flux that
system see Łapka et al. [3–8]. is varied in time.
The density of water vapour at the external surface of the pro-
2.2. Radiative heat transfer tective clothing satisfies the equation:

The clothing was assumed semi-transparent and non-grey. @ qv 
Dv a;c ¼ hm;amb ðqv ;amb  qv ;ce Þ ð12Þ
Therefore, distribution of spectral radiative intensity was given @x ce
by the following Radiative Transfer Equation [4,23–26]:
Z At the interface between the protective clothing and skin (sur-
dIk K s;k 0 0 face of the protective clothing – see Fig. 1) the temperature obeys
¼ ðK a;k þ K s;k ÞIk þ K a;k Ib;k þ Uk Ik ðs ÞdX ð6Þ
ds 4p 4p the equations:
where I is radiation intensity, Ib – the blackbody intensity [23], Ka Z 
@T c @T s 1 
kc  ks þ fqin 
r;k;f  es;k Eb;k ðT bs Þ  ð1  es;k Þqr;k;f gdk ¼ 0
in
and Ks – linear absorption and scattering coefficients, respectively
(they are calculated from known Ke = Ka + Ks and x = Ks/Ke), s –
@x @x 0 bs

direction vector, k – wavelength, U – scattering phase function ð13Þ


and X – solid angle. The isotropic scattering in the clothing was

assumed, i.e., Uk = 1. @ qv 
Dv a;c ¼0 ð14Þ
The radiative heat flux was calculated from the formula: @x bs
Z 1 Z
qr ¼ Ik s dX dk ð7Þ where at this interface the radiation intensity emitted by the skin is
0 4p
given by the formula:

2.3. Boundary and initial conditions Eb;k ðT bs Þ qin


r;k;f
Ik jbs ¼ es;k þ ð1  es;k Þ ð15Þ
p p
The right, external surface of the clothing was considered trans-
parent, e.g., diffusively reflecting and transmitting the incident On the left hand side of the system (see Fig. 1) temperature of
thermal radiation. On the right hand side (surface of the protective the skin is assumed to be equal to inner body temperature, i.e.:
clothing) (see Fig. 2) the temperature obeys the equation:

T s j0 ¼ T cr ¼ const ð16Þ
kc @T Dv a;c @@x
qv
cp;v T c þqamb þ 
@x
c

n
R 1 in o  ¼0 In the above equations qin
r;k;f is the radiative heat flux incident on
_ _ _ _ 
þ 0 qr;k;f  r k;f qin ð1 r Þqin
þq in
 r q in
ð1 r Þq in
dk 
r;k;f k;f r;k;e r;k;e k;f r;k;e k;f r;k;f
ce the skin surface and es;k the skin emissivity. The subscript bs
ð8Þ denotes the skin surface which was assumed opaque to radiation.
The unknown clothing surface Tce and skin Tbs temperatures as well
where the radiation intensity, the external heat and incident radia-
as water vapour densities qv,ce and qv,bs were calculated from Eqs.
tive heat fluxes were given by the following expressions:
(8), (13), (12) and (14), respectively. Eq. (9) assumed diffusive
_ qin  _
 qin reflection and transmission of incident radiation intensity, while
r;k;f r;k;e
Ik jce ¼ r k;f þ 1  r k;f ð9Þ Eq. (15) emission and diffusive reflection of incident radiation
p p
intensity on the skin surface. For more details see [23–26]. Initial
qamb ¼ hamb ðT amb  T ce Þ þ hm;amb ðqv ;e  qv ;ce Þcp;v T ce ð10Þ conditions for Eqs. (2)–(5) corresponded to the steady state distri-
butions of temperature, volume fraction of bound water and water
1336 P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

vapour density in the whole system which was in contact only present, uniform initial temperature distribution corresponding
with surroundings at Tamb and relative humidity /amb. For details to the inner body temperature Tcr;
see Łapka et al. [4]. Case 5: Heat conduction in both layers of the system but with
All equations describing heat and moisture transfer were cou- no convective cooling, no blood perfusion and metabolic heat
pled and highly non-linear, therefore for the solution of the system present in the skin, the external radiation being absorbed and
of equations the special in-house iterative algorithm was devel- scattered in the protective clothing with emission of radiation
oped and implemented in C. All the governing equations with accounted for, uniform initial temperature distribution corre-
boundary conditions were discretized applying the Finite Volume sponding to the inner body temperature Tcr;
Method (FVM). The Newton-Raphson method was used to find Case 6: Complex heat and moisture transfer in the system
unknown temperatures from non-linear balance conditions at the including heat conduction in both layers and with convective
internal or external interfaces. The outline of this algorithm was cooling, absorption, scattering and emission of radiation inside
presented in [3–5]. the protective clothing, water vapour diffusion, phase transfor-
mations of bound water to the gaseous phase, no blood perfu-
2.4. Influence of different phenomena on the skin surface temperature sion and metabolic heat present in the skin, uniform initial
temperature distribution corresponding to the inner body tem-
As it was mentioned in the introduction that many phenomena perature Tcr;
affect temperature distribution in the protective clothing-skin sys- Case 7: Heat conduction in both layers of the system but with
tem but due the goal of the present study the skin surface temper- no convective cooling, blood perfusion and metabolic heat pre-
ature is the most important as it determines the possible degree of sent in the skin and the external radiation being absorbed and
burns [3–5]. Therefore it was interesting to find which from the scattered inside the protective clothing with no emission of
phenomena modelled in the previous subsections exert the radiation present, non-uniform initial temperature correspond-
greatest influence on the skin surface temperature. For that reason ing to the stationary state with the inner body temperature Tcr
the following cases were considered during the numerical and ambient air temperature Tamb;
simulations:
In the calculations the skin surface was treated as having black-
Case 1: Heat conduction in both layers of the system with no body properties (ek,s = 1) while fabric as non-grey with the wavelength
convective cooling on the external surface of the protective dependence of the absorption and scattering coefficients presented in
clothing, no blood perfusion and metabolic heat present in the Table 4. The ambient air was assumed at Tamb = 32 °C while the exter-
skin and no radiation in the clothing, uniform initial tempera- nal convective heat and mass transfer coefficients had the values
ture distribution corresponding to the inner body temperature hamb = 10 W/(m2 K) and hm,amb = 0.021 m/s, respectively. The relative
Tcr; humidity of the ambient air was chosen to be /amb = 68%. The inner
Case 2: Heat conduction in both layers of the system but with body temperature was kept at Tcr = 37 °C while the metabolic heat
convective cooling on the external surface of the protective at qm = 384.11 W/m3. The thermophysical properties of the skin, skin
clothing, no blood perfusion and metabolic heat present in the imitation (simulant), protective clothing and blood were taken from
skin and no radiation in the clothing, uniform initial tempera- Table 4. The radiative heat flux incident on the external surface of
ture distribution corresponding to the inner body temperature the protective clothing, see Eq. (11), was assumed wavelength inde-
Tcr; pendent and in a form of a rectangular pulse:
Case 3: Heat conduction in both layers of the system but with
qe;k ðtÞ ¼ qe;max ½HðtÞ  Hðt þ sÞ ð17Þ
convective cooling on the external surface of the protective
clothing, no blood perfusion and metabolic heat present in the where H is the Heaviside step function. The duration of the pulse
skin and no radiation in the clothing, non-uniform initial tem- and its maximum value were assumed as se = 12.5 s and
perature corresponding to the stationary state with the inner qe,max = 20 kW/m2, respectively. The other parameters not
body temperature Tcr and ambient air temperature Tamb; mentioned were assumed the same as in [4].
Case 4: Heat conduction in both layers of the system but with Temperature distribution in the two-layer system for t = se (just
no convective cooling, no blood perfusion and metabolic heat after the exposition ends) was presented in Fig. 3. High tempera-
present in the skin, the external radiation being absorbed and ture drop was observed in the protective clothing with only a
scattered inside the protective clothing with no emission reasonable increase of the skin temperature.

Fig. 3. Temperature distribution across the skin-protective clothing system for (A) case 1–3 and (B) case 4–7 for t = se (just after the exposition ends).
P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340 1337

heat conduction cause the greatest increase in the skin surface


temperature, i.e., evaluation of the protective clothing quality
should be based on these heat transfer modes. Therefore influence
of moisture transport and accumulation of energy associated with
phase transition of the moisture in the protective clothing were
excluded in the analytical treatment.
In the analytical model it is assumed that radiation transmitted
through the clothing is partly absorbed and scattered in the spec-
tral way. Due to low temperature of the clothing close to the skin-
protective clothing interface in comparison to high temperature of
the external heat source and outer part of the clothing (see Fig. 3
for distribution of temperature) no emission of radiation was
assumed in the fabric layer. The skin surface was treated as opa-
que, diffusively emitting and reflecting (with the absorption coeffi-
cient ak,s = 1–ek,s). It was also assumed that the external surface of
the clothing is convectively cooled by the ambient air at tempera-
ture Tamb with the convective heat transfer coefficient hamb. In the
skin layer heat, besides conduction, can be transferred by the blood
Fig. 4. Temperature of the skin surface versus time for different heat transfer
perfusion and generated due to metabolism.
modes – cases 1–3.
Similarly to the numerical model all properties are constant
within each layer, while the radiative properties are wavelength
dependent. The initial temperature in the system corresponded
to a steady state for which the inner body temperature is Tcr, the
ambient air is at Tamb and no external heat load is applied to the
system and therefore no the radiation in the clothing layer appears.
The Radiative Transfer Equation in the protective clothing Eq.
(6) was solved using the two-flux method [23,27] and allowed to
express the radiation energy absorbed in the clothing, Eq. (2), by
the formula:
Z 1
@qr ðtÞ
 ¼ F k ðxÞqe;k ðtÞdk ð18Þ
@x 0

where
ð2K a;k  r k Þr k expðr k xÞ  G2;k ð2K a;k þ r k Þr k expðrk xÞ
F k ðxÞ ¼
G1;k
ð19Þ
and

Fig. 5. Temperature of the skin surface versus time for different heat transfer G1;k ¼ ð2K a;k þ K s;k  r k Þ expðr k dc Þ  G2;k ð2K a;k þ K s;k þ r k Þ
modes – cases 4–7.  expðr k dc Þ ð20Þ

Figs. 4 and 5 show variation of the skin and its imitation (sim- K s;k  ð1  es;k Þð2K a;k þ K s;k  r k Þ
ulant) surface temperatures with time for each of the cases listed G2;k ¼  ð21Þ
K s;k  ð1  es;k Þð2K a;k þ K s;k þ r k Þ
above. The horizontal dash line corresponds to the minimum value
of temperature taken for evaluation of the burn degree [4]. qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
Numerical analysis of the heat transfer across the protective rk ¼ 2 K a;k ðK a;k þ K s;k Þ ð22Þ
clothing-skin system indicates that variation of the surface tem-
After introducing a definition of the excess temperature:
perature of the skin or skin-simulant with time are similar in shape
for the same case of heat transfer conditions studied. The surface #ðx; tÞ ¼ Tðx; tÞ  T cr ð23Þ
temperature of the skin-simulant, with its properties presented
where
in Table 4, always leads to higher values of temperature than for
the human skin. Intensive cooling of the external surface of the qm
T cr ¼ T cr þ ð24Þ
protective clothing (the cases 2, 3 and 6) causes a shift of the max- ðqcÞb xb
imum skin temperature to shorter times. The highest values of the
and basing on the assumption made the energy Eqs. (2) and (5), for
skin temperature are obtained for only two modes of heat transfer,
the skin and protective clothing, can be cast in the form:
i.e., heat conduction an thermal radiation present in the protective
clothing with no convective cooling of the external surface of the @ 2 #s @#s
as  G#s ¼ ð25Þ
protective clothing (the cases 1, 4 and 5). The blood perfusion even @x2 @t
when the metabolic heat is accounted for decreases the skin sur-
Z 1
face temperature. @ 2 #c Fk @#c
ac þ q ðtÞdk ¼ ð26Þ
@x2 0 ðqcÞc e;k @t
3. Analytical model where
ðqcÞb
Results of the numerical simulation presented above as well as G¼ xb ð27Þ
ðqcÞs
in previous literature [1,3–8,10] suggest that thermal radiation and
1338 P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

while ac = kc/(qc)c and as = ks/(qc)s denote the thermal diffusivity of kc m  hamb 2mdc
D10  e D20
the clothing and skin, respectively.The energy equations were com- kc m þ hamb

Z 1 
pleted with the following boundary conditions: 1 1 dF k ðx ¼ dc Þ
¼ kc
#s ðx ¼ ds ; tÞ ¼ #sm ð28Þ kc m þ hamb 0 s  a r
c k
2 dx

þhamb F k ðx ¼ dc Þqe;k ðsc Þdk
#s ðx ¼ 0; tÞ ¼ #c ðx ¼ 0; tÞ ð29Þ
1 d#cs ðx ¼ dc Þ
þ kc þ hamb ½#cs ðx ¼ dc Þ  #amb  emdc ð43Þ
Z 1 s dx
@#s ðx ¼ 0; tÞ @#c ðx ¼ 0; tÞ
ks ¼ kc þ es;k qinr;k ðx ¼ 0; tÞdk ð30Þ pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
@x @x 0 where the properties bs ¼ ks ðqcÞs and bc ¼ kc ðqcÞc are known as
thermal effusivities of the skin and protective clothing, respectively.
@#c ðx ¼ dc ; tÞ In order to estimate possible burns temperature of the skin sur-
kc ¼ hamb ½#c ðx ¼ dc ; tÞ  #amb  ð31Þ
@x face is required. The Laplace transform for the excess temperature
where corresponding to this surface follows from the Eq. (36):
#ss ðx ¼ 0Þ
r;k ðx ¼ 0Þ ¼ G3;k qe;k ðtÞ
qin ð32Þ #bs ðsÞ ¼ #s ðx ¼ 0; sÞ ¼ þ C 10 þ C 20 ð44Þ
s
and
where the constants C10 and C20 should be found from the set of Eqs.
½ð2K a;k þ K s;k  rk Þ  G2;k ð2K a;k þ K s;k þ r k Þ (40)–(43). Inspection of these equations leads to the conclusion that
G3;k ¼ ð33Þ
G1;k the temperature above depends on the following factors:
 a;k ; K
#bs ¼ #bs ðss;#sm ;#amb ;G;qe;max ;Rc ;bs ;bc ;Rs ;Rc ; es;k ; K  s;k ;Fos ;Foc ;Bic Þ
qm
#sm ¼ ð34Þ ð45Þ
ðqcÞb xb
where the respective Fourier and Biot similarity numbers, thermal
#amb ¼ T amb  T cr ð35Þ resistances for the skin and protective clothing and dimensionless
In order to solve the problem described by the formulae (25)– linear absorption and scattering coefficients are defined by the
(31), the Laplace transform was applied. The solution of Eqs. (26) formulae:
and (26) in the transform domain took in the form: as s ac s hamb dc ds
Fos ¼ ; Foc ¼ ; Bic ¼ ; Rs ¼ ;
#ss ðxÞ d2s d2c kc ks
#s ðx; sÞ ¼ þ C 10 elx þ C 20 elx ð36Þ
s dc  a;k ¼ K a;k dc  s;k ¼ K s;k dc
Rc ¼ ; K and K ð46Þ
Z 1 kc
#cs ðxÞ F k ðxÞ
#c ðx; sÞ ¼ þ e;k ðsÞdk þ D10 emx þ D20 emx
q ð37Þ The thermal properties of the skin, skin imitation and the pro-
s 0 s  ac K 2ak
tective clothing together with, the respective Fourier numbers
where evaluated using the thickness of each layer are shown in Table 4.
sffiffiffiffiffiffiffiffiffiffiffi rffiffiffiffiffi Analysis of the Fourier similarity numbers present in this table
Gþs s leads to the conclusion that their values are of a very small order of
l¼ and m ¼ ð38Þ
as ac magnitude for the given duration of the heat pulse and therefore
the products lds and mdc appearing in Eqs. (40) and (43) assume
and according to Eq. (17) the Laplace transform of radiative flux
high values. This allows for some simplifications in these equations
incident on the external surface of the protective clothing is
which allow the Laplace transform for temperature of the skin sur-
expressed as:
face, Eq. (44) to be cast it in the final form:
qe;max Z
e;k ðsÞ ¼
q ½1  expðsÞ ð39Þ #ss ðx ¼ 0Þ 1
qe;max
s #bs ðsÞ ¼ þ Y c;k ðssÞdk ½1  expðsÞ ð47Þ
s 0 sAðssÞ
After substituting of expressions for the predicted solution, Eqs.
(36) and (37), to the boundary conditions the following set of the where
algebraic equations for the unknown constants C10 and C20 as well pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
bs Gs þ ss
as D10 and D20 were obtained: AðssÞ ¼ 1 þ pffiffiffiffiffi ð48Þ
bc ss
½#sm þ #ss ðx ¼ ds Þ lds  c;k ðssÞ depends, besides time, only on the selected
e2lds C 10 þ C 20 ¼  e ð40Þ and the function Y
s
properties of protective clothing, thermal pulse duration and ambi-
Z 1 ent interaction:
F k ðx ¼ 0Þ
C 10 þ C 20 ¼ D10 þ D20 þ e;k ðsÞdk
q   pffiffiffiffiffi 
s  ac r 2k 2Fo dF k ðx ¼ dc Þ ss
Y c;k ðssÞ ¼
0
hqffiffiffiffiffi c i þ Bic F k ðx ¼ dc Þ exp  pffiffiffiffiffiffiffi
#cs ðx ¼ 0Þ  #ss ðx ¼ 0Þ Rc B Foc þ Bic
ss dx Fo
þ ð41Þ c
s 
pffiffiffiffiffiffiffiffiffiffiffi Rc Foc F k ðx ¼ 0Þ 1 Foc F k ðx ¼ 0c Þ
þ þ pffiffiffiffiffi þ G3
bs G þ s 1 B b c ss B
pffiffi ½C 10  C 20  ¼ D10  D20 þ pffiffi
bc s bc s ð49Þ
Z 1
kc dF k ðx ¼ 0Þ
 þ G 3;k qe;k ðsÞdk where Bk ¼ ss  Foc r 2k .
0 s  ac r 2k dx
The respective expression for the Laplace transform for the skin
ðx¼0Þ ðx¼0Þ
kc d#csdx  ks d#ssdx simulant can be written as:
þ pffiffi Z
bc s s #ss;i ðx ¼ 0Þ 1
qe;max
ð42Þ #bsi ðsÞ ¼ þ Y c;k ðssÞdk ½1  expðsÞ ð50Þ
s 0 sAi
P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340 1339

where from Eq. (48):

bsi
Ai ¼ 1 þ ð51Þ
bc
as no blood perfusion is present in the skin simulant (imitation), i.e.,
G = 0.
R1
The function 0 Y  c;k ðssÞdk qe;max ½1  expðsÞ can be eliminated
s
between Eqs. (47) and (50) to give the following formula relating
surface temperatures of the skin and skin simulant:

T bs ðsÞ  T bs ð0Þ=s Ai
 ¼ ð52Þ
T bsi ðsÞ  T bsi ð0Þ=s AðssÞ

where T bs ðsÞ and T bsi ðsÞ are temperatures of the human skin and
skin-simulant surface while the symbols T bs ð0Þ and T bsi ð0Þ corre-
spond to their initial values.
Validity of the relation Eq. (52), due to earlier assumptions
made, should be checked against numerical solution accounting
for phenomena which are not considered in the simplified analyt-
ical solution. This is carried out in the next section. Fig. 7. Ratio of temperature of skin surface for the skin and skin simulant for
different heat transfer modes – cases 4–6.

4. Checking the validity of the skin-skin simulant relation


ratio of the surface temperatures of the skin and skin-simulant var-
The formula Eq. (52) can be inverted to give: ies only to a small extent with time and within the 1–2% accuracy
 is practically constant as required by Eq. (54) for a period embrac-
L1 T bsi ðsÞT bsi ð0Þ=s
pffiffiffiffiffiffiffiffiffiffiffi ing the maximum temperatures attained by the skin surface for the
T bs ðtÞ  T bs ð0Þ bc þ bsi bc þbs ðGþsÞ=s
¼  ð53Þ cases 1–5. The greatest difference is observed for the case when
T bsi ðtÞ  T bsi ð0Þ bc þ bs
L1 T bsi ðsÞT bsi ð0Þ=s
bc þbs
processes including the heat and moisture transfer are accounted
for – case 6. However as mentioned in Section 2.4 in this case
where the symbol L1 denotes the inverse Laplace transform. More- the skin temperature is decreased in comparison to the most sev-
over, if no perfusion in the skin is also assumed, i.e., G = 0, then the ere case when only heat conduction and thermal radiation occur in
expression above can be further simplified to: the protective clothing. For the case 7, when both generation of
metabolic heat and blood perfusion is assumed and which is not
T bs ðtÞ  T bs ð0Þ bc þ bsi shown in Fig. 6, the left-hand side of Eq. (54) cannot be treated
¼ ð54Þ
T bsi ðtÞ  T bsi ð0Þ bc þ bs as constant even in the limited period of time and requires formula
of Eq. (53) to be used.
The left hand side of the formula above was numerically deter-
mined and compared with the right-hand side using values of ther-
mal effusivity shown in Table 4. 5. Conclusions
Figs. 6 and 7 present variation of the left-hand side of Eq. (54)
with the dimensionless time t/se for different phenomena and The problem of converting temperature measurements carried
external conditions corresponding to different cases listed in Sec- out on the skin-imitating material to the time-variation in the
tion 2 and obtained from the numerical simulations. The horizontal human skin surface temperature was considered in the paper.
dash line here corresponds to the right-hand side of Eq. (54). The The answer to this problem is necessary for evaluation of the pro-
tective clothing quality and estimation of the possible burns for
persons which in their profession activities are exposed to high
thermal loads of short duration.
This complex problem was simplified by considering two-layer
system instead of multilayer structure of the human skin and pro-
tective clothing. At first the numerical simulation were performed
using a model, which accounted for the majority of phenomena
occurring in the skin and clothing. Variation of the skin surface
temperature in time depends on many factors including many
physical properties of the protective clothing, skin or the skin-
imitating material, metabolic heat generation rate, intensity of
heat transfer by the blood perfusion and the magnitude and dura-
tion of the heat load applied to the external surface of the clothing.
Some similarities were observed for variation in the skin surface
temperature with time irrespective whether it is the human skin
or the skin-simulant. Moreover, influence of different phenomena
on the skin surface temperature were investigated. It was found
that accounting only for heat conduction and thermal radiation
in the protective clothing with no convective cooling leads to the
greatest increase in the skin temperature. So this case was consid-
Fig. 6. Ratio of temperature of skin surface for the skin and skin simulant for ered as the most important for evaluation of the protective cloth-
different heat transfer modes – cases 1–3. ing quality. Noting the complex phenomena involved in heat and
1340 P. Furmański, P. Łapka / International Journal of Heat and Mass Transfer 114 (2017) 1331–1340

moisture transfer across the protective clothing-skin system and [2] Y.Y. Jiang, E. Yanai, K. Nishimura, H. Zhang, N. Abe, M. Shinohara, K. Wakatsuki,
An integrated numerical simulator for thermal performance assessments of
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Conflict of interest
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solidification process of semi-transparent materials I: Modelling and
verification, J. Heat Tran. 132 (2010) 023504.
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solidification process of semi-transparent materials I: Modelling and
This work is supported by the National Centre for Research and verification, Int. J. Heat Mass Tranf. 55 (2012) 4941–4952.
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