+55

Chemistxj, l02B Exam 1 Chap 13-15 *u,,u,@I !1 h .h,U t islzz

Vlultiple Choiee - Select the best answer choice for the questions below" aird rr. ark the answer in THE
SPACIE PROVIDED, Then answer tlie two free resporrse cluestions that lbllow (3 pts each)
n (
t:l. Consider the following reaction: I{OBr(g) -+ i-{O(S) + %Brz(g)
A plot of [NOBTJ-I vs time gives a straight iine rvith u s1op. of 2.AA M-rs-r. l'he order of the
reaction and the rate constant, respectively, are:
1
A. second-orcler and 0.500 M-rs-l. -
B. first-order and 2.00 s-r.
q. second-orcler and 2.00 M-ls-1.
D. first-order and 0.241 s-I.
E. second-order and 16.6 M-ls-I.
,\
IAt'2.
I Which of the lbllowing types of reactions will NOT result in any change in its reaciion-ratg.when
is lncreaseo'
thr.on."rtration of reactant molecules ls increased? .- ^$ r-> -:
('61'Q jI
A. zero-order ='"
B. flrst-older ,,i(- - I'
C. second-order
D. third-order
E. one-half order

Lr. A catalyst facilitates

a reaction by:
A. increasing the activation energy for the reverse reaction.
B. lowering the activation energy of the reaction.
C. shifting the position of the equilibrium of the reaction.
D. decreasing the temperature at which the reaotion will proceed spontaneously.
E. making the reaction more exothermic.
D
o14. Acertain reactioll has a rate constant of 8.8 s-r at 298I( and 140 s-l at323 K. What is the
activalion energy for this reaction?
A. 38 kJ mol-r \/,= 6 .8s-' c1 2"tQ1V
B. 89 kJ rnol-l
C. 120 kJ mol-l \t; lL+L) :-' n\ '*'2i\/ /\ J-\
D. 23 kJ mol-r
11. 1.2 kJ rnol-r Lc,,1 rn (-,rt) -*,,, ( znt, iz1 f
V. S. As the ternperature of a reaction is increased, the rate of the reaction increases because:
A. reactant molecules collide less frequently.
B. reactant molecules collide with greater energy per collision.
C. activation energy is lowered.
D. reactant molecules collide less fiequently and with greater energy per collision.
E. reactant molecules collide more frequently with less energy per collision.
r
|*_6. 1-he concept of an acid that is NOT lirnited to I{+-or species containir,g one or more protons is
inheient in:
A. only the Arrhenius theory
B. both the Arhenius and the Bronsted-Lorvry theories
C. only the Bronsted-Lowry theory
D. both the Bronsted-Lowry and the Leivis theories
E. only the Lewis thcory
 r
L_1. Which inclication of rela.tiveacid strength shbwn belorljeN[L[ conect?
A. HCI>HFr'
B. HzS > FHr@
C. HzSOr > HSOI- 'z
D. CFTCOzH > CH:COzH
E. HCIO > HCIO,,

For Questions 8 - 12, consider the diagram shown below:

>-
trt)
o)
C
LU
E
(l)
o
o_
eactron
\\
Ug Which letter represents the enthalpy change of the forward direction?

B r. Which letter represents the t{elsrqg! ilgle of thefor wardreaction?

A ,0. Which letter represents the activation-energ y of the-forward reaction?

Dr r. Which letter represents the enthalpy change of the reverse reaction?

ooA"
ND MARK for TITUE or "B" for FALSE : Theforu,ard. reactionis an example of an enclothermic
reaction.

L-, -t:, The rate of formation of oxygen in the reaction 2NzOs(g) + 4NO2(g) + Oz(g) is2.2-B (mol 02) L-
's-'. What is the rate of decomposition of NzOs?
A. 0.57 (mol N2O5) L-rs-r
B. 9.12 (mol NzOs) L-rs'r
C. 2.28 (mo1N2O5) L-rs-l
D. 1.14 (molNzOs) L-rs-
E. 4.56 (molNzOs) L'rs-r

L) 14. For the reaction Hz(g) + Iz(g) + :

2Hl(g)ht 700 K, K, 56.6. If an equilibrium mixture
u17tiO K was found to contain 0.55 M HI and 0.21 M H2, the 12 collcentration must be:
A. o.o46M \ ,-..---.-.--.- (
Jetv ^*\7
c. 22M ("Zt)(r)
D. 2sou, :E.tiv ?: .55t.n;
E. None of the above ' ) = -2,5, l0 =
D
D 15. A certain first-order reaction with an initial reactant concentration of 0.200 M possesses a half-
fif. 1.3 x 10a s. Determine the concentration of this reactant after 2.6 x 104 shas elapsed.
"f
A, 11.025 M M B. c. 0.100Iv1 Il. 0.150 M
0.050 E. 0.200 M
r I l'"/z-\ i \'-x\Oqs >L'-?'b^\0qt--
t'rr=\
T r. r r..
,,rsl orouu
-,-i,-\
'i^\rr\ ' )nr$.A
ZooM L')a= \,'5
.t(x)-;L= 'J
' ,1oo i 2 =
 Ara Determine the rate law for the reaction SzOa2- + 3tr- -, 2SO.r2- * Ir-"

Exneriment Initial [Szos'-l (M) Initial tl-l (M) Initial R.ate(M/s)

1 0.018. 0.036 2.6 x l0-"
2 0.027 0.036 3.9 x 10
3 0.036 0.054 A 7.8 x 10-" *
4 0.050 0.072 \; 1.4 x 10-'

@ rate =,t[SzOs'-] trt

2-'L:lc" trll ot8\t.r rY\- \
B.
C.
--aate= t[SzOs2-]
rate: ft[I-]
D. rur":risror'-l'tl-l
,n:)
i,4" l()a ffi
E rate:ris,o,2.l[t']2 ,@*Ea,!Y*i *Y7A"ai t'o5t{Y
Cmf - x = SdLl
x\
For Questions 17
t,1^tfi
refer to the reaction mechanism shown below: '
-19,
( I uro(l) + . efuOq> + oH-(aq)
(jlo-6q1 FASTEQUTLTBRTUM

t"-'
\ , ,"0, t H:etdGq) -b* -y$dq) + cl-(aq) FASr
lo,on-frc1 + rlpkre) --5* H2o(l) + Io-(aq) slow
\
L,' Which of the lollowing expresses the rate law for the given mechanism?
rate: ft[OH-][HIO]
B. rate : flOH-lllllHClOl
C. :
rate rtoHl tll tHClOl{Cll
D. rate : f[I'][I{2O][ClO:],
E. rate : rU-ltHClOl [Clol [oHl'z
\--
LrrN Which of the following represents an intermediate in the rnechanism?
\-A.I clo-
B. oH-
C. CI'
D. I'izO
E. None of the above

V
7'/^
(ts,\ Which of the following represents a catalyst in the mechanism?
f\. clo-
B. HIO
C. cl-
D. HzO
E. There is no catalyst in the mechanism.
(-
L- ZO. Consider the Haber Process for the synthesis of ammonia gas, an exothermic reaction. Which
factor will)Olinerease the concentration of ammonia?
A. increasing the concentration of Nz
B. increasing the concentration of I{z
C. decreasing the temperature
D. increasing the pressure of the system
E. increasing the volume of the system
 For Qtrestions 21 - 24, trse the follor,ving answer choices:
A. r\oidic becarrse it is strong acid.
a_

B. Basic because it is a strong base.

_Q, -_ -Neutral beeause there is no hydrolysis.
D, Basic because it is the salt of a weak acid.
E. Acidic because it is the salt of a weak base.

Qtr. Predict whether NaI is acidic, basic, or neutral and why.

Dl, Predict whether llzCzO+is acidic, basic, or neutral and rvhy.

C ,J., Predict whether SICO: is aeidic, basic, or neutral and why.

E-rO. Predict whether NHaBr is acidic, basic, or neutral and why.

of the-following substances is NOT a conjugate acid-base pair?

-D-r,A.WhichOH'rc-2
B. HzPO+-/kIPOq'2
x
C. HzOzlITOz' >\00 = q1,frZ
D. HCI/H* \,25
E. IIzSO+/HSO+- \00 - ct

e :e . A 1.25 M solution of the weak acid HA is 9.2Yo dissociated. What is the pH of the solution?
A. 0.64 B. 0,94 c. 1.13 ' D. 2.16 E. 3.39

D-rr.For the reaction 99g) + 3Hz,G) -- gzOig) + Cff+(e), K. :0_03! : 189 at 1000 K. If a vessel is filled
with these gases zuch thafthe-initial concentrations afe 1CO1 M, [Hz] :9.045 M, [HzO] :
i0.020\( and [CH+] :0 010 M,. in which direction will the reacfion occur and wh]?-

u- -ine reaction oror."o, to the left because Q.:0.12. n ( O'tp;-( O:qJ*.

- =
3: Ti:;:::lrli:::::3:fii:;l:lli::il::3:,li',1 {oaq:F (c,oaa)
=

3
E. lll:3:H:iJ::::*Ii,1l,"J',f*,1,::";I:t:u',
L. rre reasrron
The at equurD,ur,
is ar
reaction rs equilibrium because K.: Q.. ffi ,,:u-
i* i:U
u""ourr::::_-_****:.*;
G,= * k.=
e < v _>,1:ior{t,d.li
r8c'1

n
e_ze,DeterminethepHofa0.253MsoIutiono@H4CD?Ku:l'2x10..Vml.|l
A. 2l ri. +.e \c e.n @- y-= v..,.
Wa.5 o Y- b
E, ], Consider thc dimerization reaction: 2A -+ Az
rate = k[Al'
When the initial concentration of A is 2.0 M, it requires 30 min for 60Yo of A to react. Calculate
the rate constant.
A. l.1x lo-3M'ls-l J- r re (Eo)
7,0
B. 3.2 x l}-a M-rs-r
C. 5.0 x M-ls-l
10-a U * Pf,r-r)
D. 4.2 x l}'a M-ls-l
E. None of the above ,O7= v-V Q]= = \t =
\qipri
t4
L 30. A first-order reaction has a half-life of 231 S. The time required for 600/o reaction is:
A. 153 s. B. 73.9 s. C. 170 s. D. 133 s. E. 305 s.
 , For Questions 31 -33, consider a solution of 0.10 M arsenic acid (I{3AsOa), where I(u1 :6.0 x 10-3, Kur:
' 1.0 * l0-7, and K* : 3.0 x i0-12.
'z ,{L
ft-O Determine the plI of this solution.
A. t.7 B. 4.0 c. 6.3 D. 1.0 8.3.2
r-\ z._

U
^ (8)What is the concentration of [HzAsO,{-]?
H2I\sOu a------- f++ H2 A='Ou
c.. v. x\
+
r,y)r
-A. 1.0 x 10-7 M
B. 6.0 x 10-3 M \ . \0tv\
+x
c '/-
+y
c. 0.022M C -/ kq't ('o'(\0+
D. 0.077 M t
E. 6.0 x i0-ro M /= jldql,ottL
t93t 97F l?,\= I'Ll
n {ll)O"termine
U i^\ the concentration of .?H =
[AsO4-3].
A. x 10-7
- 1-
10-'M
1.0 H,-A sOu =-- H. + HAdO;'-
-v/ B.
C.
1.4 x 10-17 M
3.0 x 10-12 M
\ . o? tL18 .o7h1e
-l-\
o
+y
D. 3.0 x 10-re M C -/
kr= 1.0 x\(r'1
E. 6.0 x 10-ro M E ,021179'Y , ozlb=ttl) )
(h
!/ 34. lf
increasing the concentration of A in a chemical reaction causes no increase in the rate of the
,.u"tior, then we can say that:
A. Aisacatalyst.
B. the reaction rate is zero-order in [A].
C. the reaction rate is first-order in ln [A].
D. the reaction rate is second-order in 1/[A].
E. A is not involved in the reaction.

FREE RESPONSE: Show all work for credit.

35. (10 points) Cations of transition metals do not exist as isolated species in aqueous solution. Instead they are "complexed"
by anions or neutral molecules which covalently bond to the metal cation. One such complex ion equilibrium is
--]
[Co(H2O)6]2*(aq)+ 4 Cl-(aq) [CoC!]2-(aq) + 6 HrO(D
(pinksolution) il-i - -, (bluesolution)
In other words, a solution of [Co(Urb)u]2'(aq; lives a pink solution, while a solution of tcoclal'z,(afl gives a blue solution. An
equilibriurn mixture of both complex ions gives a violet solution.
(a) A few drops of 1 M aqueous sodium chloride solution is added to a sample of the qarne equilibrium mixture at room
ternperature? There is a color change observed. Does the color become more pink ol'more bluE?-Explain

Cl {era clro ps CT IMNA( \ r.r) ri\ Cort\C {\-c \ ( n r \ ra, i Fo fufn bliUg-
'.}o '\[,no i
becour,, crddi,'3 Yan ( tr rtr\ !ie\o t.rr \\ 5\ r\( { l'3-
€qltit\rDr\ttv\r tO b\ure tr\6\ Q- o( { I'rt pr odUct.

(b) A few drops of I M aqueous silver nitrate are added to the equilibrium mixture. A white precipitate of silver chloride is
forrned. Does the solution become more pink or more blue? Explain.

?rnk? f[0sr\vQ[,nr\ru\Q, ,ur'\\ reaC\ tur\lr\r,"c Cf crp6\rrr4lzg,r\vctch\orid'0

rolridr ul\\ c(.luq i\^a- i€r\C\\Dn
to' \0\t \u \\^.0 \f{t, so \\^.arf il c\n r\oes\abh*i
eft tti [rb r i\,tr r r
 36. An engineer examining the oxidation of SOz in the manufacture of sulfuric acid determines that
K".= 1.7 x 108 at 600 K: 2SOz(S) + Oz(g) <+ 2 SO3(g)
,35b
A) pts) Calculate the equilibrium concentrations if the initial concentrations are SOI :5.00 M, SOz:
ri9
7.00 M & lozl: 3.00 M

oC.
B) (3 pts) If Kc: 5.6 x !02 at 1000 what are the equilibrium concentrations at this temperature?

C) rB pts) Use the van't Hoff equation to find AHoor.

\_" _
tzrfx)
2 SQ rql tC t')) + 25Qr'9 5:.e6- ( z,o -zx) *
ll t
o
3PoM o
c{ +7x tX -2x
SOz= \,LZ Vc = 3,55
!- 2/ X 3,,0* Oz=,6cb

(exf (x) 3q= 1,,18

\
-=7,- X=,5\b

S%= 2) ,o -2 ('5q5 1 - l9,l

0, = "*#
b-
= l,OQ
3,55 _ = #I tr\
{J-.
\00 o
., \\
\]-11
5,6C ,3 )

= 4mo ,qB J
,,(,

il
1
= -
*L"
-l -
"
,- I
I in no particular order:

l/[A]t - 1/[A]o: kt ln[A]o - ln[Alt: kt Alo --

IA [A]t: kt

\n== lAfo I 2k t1p: llk [A]o 1t2-

LLt2 -I lln2lk