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Article history: The timber manufacturing and power generation industry is gradually shifting towards the use of biomass
Received 7 September 2010 such as timber processing waste for fuel and energy production and to help supplement the electri-
Received in revised form 3 February 2011 cal energy demand of national electric gridlines. Though timber processing waste is a sustainable and
Accepted 10 February 2011
renewable source of fuel for energy production, the thermal process of converting the aforementioned
biomass into heat energy produces significant amounts of fine wood waste ash as a by-product material
Keywords:
which, if not managed properly, may result in serious environmental and health problems. Several cur-
Cement replacement material
rent researches had been carried out to incorporate wood waste ash as a cement replacement material in
Wood waste ash
Blended cement
the production of greener concrete material and also as a sustainable means of disposal for wood waste
Hazardous waste management ash. Results of the researches have indicated that wood waste ash can be effectively used as a cement
Green concrete material replacement material for the production of structural grade concrete of acceptable strength and durabil-
Reuse and recycling ity performances. This paper presents an overview of the work carried out by the use of wood waste ash
as a partial replacement of cement in mortar and concrete mixes. Several aspects such as the physical
and chemical properties of wood waste ash, properties of wood waste ash/OPC blended cement pastes,
rheological, mechanical and the durability properties of wood waste ash/OPC concrete mix are detailed
in this paper.
© 2011 Elsevier B.V. All rights reserved.
Contents
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670
1.1. Factors influencing the quantity and quality of wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670
1.2. Uses of wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
2. Physical properties of wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 671
3. Chemical properties and leachate of wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672
3.1. Chemical composition and phases of wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672
3.2. Chemical properties of leachate from wood waste ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 674
4. Properties of wood waste ash blended cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 674
4.1. Standard consistency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 674
4.2. Initial and final setting time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 675
4.3. Soundness . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 675
4.4. Calorimetric and heat evolution characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 675
4.5. Microstructure of cement paste matrix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 675
5. Rheological properties of wood waste ash/OPC concrete and mortar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 676
6. Bulk density and mechanical strength of hardened wood waste ash/OPC concrete and mortar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 678
6.1. Bulk density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 678
6.2. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 678
6.3. Split tensile strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 680
6.4. Flexural strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 680
0921-3449/$ – see front matter © 2011 Elsevier B.V. All rights reserved.
doi:10.1016/j.resconrec.2011.02.002
670 C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685
Table 1
Chemical composition of wood ash from several species of timber (Vassilev et al., 2010).
Biomass group, sub-group and variety SiO2 CaO K2 O P2 O5 Al2 O3 MgO Fe2 O3 SO3 Na2 O TiO2
Mean 22.22 43.03 10.75 3.48 5.09 6.07 3.44 2.78 2.85 0.29
ash produced. The reduction of carbonates and bicarbonates chem- of soil for agriculture applications. Wood waste ash is also used as
ical species which contribute to alkalinity of wood ash at higher a filler material in the construction of flexible pavements for roads
combustion temperatures resulted in a corresponding decrease in and highways (Etiegni and Campbell, 1991). Recent research find-
alkalinity of ash. Moreover, there was a decline in composition light ings confirm the suitability of wood waste ash as a partial cement
metallic elements such as potassium, sodium and zinc in wood replacement material in the production of structural grade concrete
waste ash with increasing temperature of combustion (Etiegni and and self compacting concrete for applications in building construc-
Campbell, 1991). tion (Elinwa and Mahmood, 2002; Elinwa et al., 2008; Abdullahi,
Types of combustion technology used in thermal the conver- 2006).
sion of wood waste into ash has had a significant influence on the
physical and chemical properties of ash produced. Different types
of furnaces and incinerators may have varied thermal conversion 2. Physical properties of wood waste ash
temperatures which have resulted in corresponding variations in
chemical and ash yield properties as discussed earlier. Additionally, Wood ash is reported to consist of a heterogeneous mixture of
different types of combustion technology have significant effects on variable size particles which are generally angular in nature. These
the physical properties of ash produced. Typically, in a grate fired particles were unburned or partially burned wood or bark. In terms
furnace, the wood ash produced is coarser in nature and tend to of fineness, average amount of wood fly ash passing sieve #200
settle inside the combustion chamber as bottom ash. On the con- (75 m) and retained on sieve #325 (45 m) were 50% and 31%
trary, for more advanced and efficient fluidised bed furnaces, the respectively. The bulk density of wood fly ash was determined to
ash produced is predominantly fine fly ash with a finer particle size be relatively low at 490 kg/m3 with a specific gravity value of 2.48.
grading with only a small fraction of coarse ash retained within the Wood fly ash was found to have low average autoclaved expansion
combustion chamber. value of 0.2% (Naik, 1999).
Some species of trees from which the wood wastes were derived Naik et al. (2003) evaluated the physical properties of wood
has shown to be a dominant factor governing the chemical prop- ashes from five different sources which concluded that wood
erties of wood waste ash produced. The chemical composition of ash samples have varying values of unit weight that range from
essential oxide compounds which governs the suitability of wood 162 kg/m3 to a maximum of 1376 kg/m3 . The specific gravity of
ash as a cement replacement material such as silica (SiO2 ), alumina wood waste ash samples investigated ranged between 2.26 and
(Al2 O3 ), iron oxide (Fe2 O3 ) and quicklime (CaO) varies significantly 2.60. The low unit weight and specific gravity of wood ashes rel-
with various species of trees. Variations in the chemical composi- ative to neat cement indicate a possibility of the reduction in the
tion of ash produced from different species of trees can be seen in unit weight of concrete material produced by the partial substitu-
Table 1. tion of cement using wood ash. A higher degree in the variation of
wood ash fineness was observed whereby the percentage of wood
ash retained on a 45 m sieve varied between 23% and 90%.
1.2. Uses of wood waste ash A sieve analysis results showed that the mean diameter, d50 ,
of sawdust waste incineration fly ash (SWIFA) obtained from an
Currently, ash by-products from the combustion of wood wastes open incineration of sawdust in a drum to be 150 m. The corre-
are commonly used as a soil supplement to improve the alkalinity sponding surface area of SWIFA was determined to be relatively
672 C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685
high (150 m2 /g) which, is possibly due to the increased ash surface
porosity. Other physical properties of SWIFA namely specific grav-
ity, loose bulk density and moisture content were found to be 2.29,
830 kg/m3 and 0.37% respectively (Elinwa and Mahmood, 2002;
Elinwa and Ejeh, 2004). Abdullahi (2006) reported similar results
whereby the specific gravity and the bulk density of wood ash were
found to be 2.13 and 760 kg/m3 respectively.
A micrograph obtained from a scanning electron microscopy
(SEM) analysis on residual ash produced from the incineration of
wood waste ash at a temperature of 1000 ◦ C indicated that wood
waste ash consists of two dominating phases, namely a fibre-like
continuous layer and particle like aggregates. The fibre like con-
tinuous layer is highly carbonaceous in nature with high carbon
content. On the contrary, carbon content in the particle like aggre-
gates’ phase is low and the consists mainly of silica and alumina
compounds as per energy dispersive X-ray (EDX) results illustrated
in Fig. 1 (Udoeyo et al., 2006).
A common finding whereby wood waste fly ash consists of parti-
cles which are highly irregular in shape with a highly porous surface
was reported by Wang et al. (2008a). In addition, crystal like spikes
were also observed to be present on the surface of wood waste fly
ash particles, as can be seen in Fig. 2, which may contribute sig-
nificantly to the high surface area of the ash particles. A specific
gravity of wood waste fly ash was determined to be 2.40 and par-
ticle size grading analysis results indicated that most of the ash
particles have diameter within 30–130 m.
The specific gravity of wood fly ash collected from a forestry
biomass fired power plant was found to be 2.54. Wood fly ash from
the same source consisted of fine ash particles with an average
diameter below 50 m. SEM images of wood fly ash reveals that
wood fly ash consists mainly of highly angular particles with a high
extent of surface porosity. Specific surface areas of wood fly ash col-
lected from two different sources had reported values of 40.29 m2 /g
and 7.92 m2 /g respectively. A higher specific surface area of the for-
mer is due to higher degree of irregularity in particle shape and
porosity of its surface as shown in Fig. 3 (Rajamma et al., 2009).
As physical properties of wood waste ash have significant effect
on pozzolanic and hydraulic reactivity, high degree in variation of
physical properties of wood ash obtained from different sources
mandate proper characterisation of wood ash prior to being incor-
porated as cement replacement material in production of concrete
material for construction.
100
90
Fig. 4. Extent of reactions for various fly ash samples (Wang and Baxter, 2007).
Table 3
Summary of chemical composition of wood waste ash.
Chemical compound SiO2 Al2 O3 Fe2 O3 CaO MgO TiO2 K2 O Na2 O SO3 C P2 O5 LOI (%)
Elinwa and Mahmood (2002) 67.20 4.09 2.26 9.98 5.80 – – 0.08 0.45 – 0.48 4.67
Udoeyo and Dashibil (2002) 78.92 0.89 0.85 0.58 0.96 – – 0.43 – 17.93 – 8.40
Elinwa and Ejeh (2004) 67.20 4.09 2.26 9.98 5.80 – – 0.08 0.45 – 0.48 4.67
Abdullahi (2006) 31.80 28.00 2.34 10.53 9.32 – 10.38 6.50 – – – 27.00
Naik et al. (2003)
W1 32.40 17.10 9.80 3.50 0.70 0.70 1.10 0.90 2.20 – – 31.60
W2 13.00 7.80 2.60 13.70 2.60 0.50 0.40 0.60 0.90 – – 58.10
W3 50.70 8.20 2.10 19.60 6.50 1.20 2.80 2.10 0.10 – – 6.70
W4 30.00 12.30 14.20 2.20 0.70 0.90 2.00 0.50 2.10 – – 35.30
W5 8.10 7.50 3.00 25.30 4.50 0.30 2.70 3.30 12.50 – – 32.80
far below the saturation curve indicate strong pozzolanicity while ing of wood waste ash. De-ionized water acidified using nitric acid
concentrations of OH− ion and corresponding CaO concentrations to adjust the pH to 4 and 5 for leaching of metals from pure wood
of wood waste fly ash F2 plot slightly above the saturation curve waste ash to produce a leachate then analysed using an atomic
implying negative pozzolanicity. Hence, there exists a strong cor- absorption spectrophotometer. Analysis of the leachate from wood
relation between pozzolanicity of wood waste fly ash with its total waste ash indicated the presence of heavy metal ions such as
chemical content of SiO2 , Al2 O3 and Fe2 O3 . Generally, pozzolanic- chromium, iron, zinc and arsenic when using an acidified solution of
ity of wood waste fly ash varies proportionately with sum of SiO2 , both pH 4 and 5. It was observed that arsenic exhibited the highest
Al2 O3 and Fe2 O3 chemical content of the ash. leachability due to its high concentration in the leachate exam-
Quantitative elemental analysis of the wood waste fly ash sam- ined while iron had the least leachability as it was only detected in
ples showed that quantities of Ca, Si, Al and Mg elements present trace amounts. The leachability of chromium, iron, copper and zinc
on the surface of the wood waste fly ash particles are comparable were observed to have significant dependence on the pH value of
to those present on the surface of cement particles and the find- the leaching agent. The aforementioned metal exhibited a higher
ing further supports the analysis results of energy dispersion X-ray degree of leachability with a higher acidity of leaching agent used.
spectrometry performed on the wood waste fly ash samples. Apparently, the mineralogical phase of the metal oxides present
in the ash had a significant influence on their susceptibility to the
3.2. Chemical properties of leachate from wood waste ash reaction of H+ ions present in the leaching agent. More H+ ions were
available in a higher acidity leaching agent to react with the min-
For non conventional material such as wood waste ash there eral phases containing metal ions within wood waste ash hence
have been no adequate environmental specifications developed for resulted in a higher leachability of the metals.
its use as a construction material. In the absence of proper specifi- A similar trend of higher metal leachability with an increas-
cation, regulatory evaluators tend to use contaminant leachability ing acidity of leaching agents has been observed by several other
levels of pure wood waste ash in their judgement on the suitability researchers (Fytianos and Tsaniklidi, 1998; Karuppiah and Gupta,
of wood waste ash as construction material. 1997). They also found that a leaching agent of pH 5 did not have
Udoeyo et al. (2006) studied the chemical content especially an adequate quantity of H+ ions to react with iron oxide phases
heavy metal content of leachate produced from the batch leach- produced from the combustion of wood waste.
The concentration of the metallic ions namely arsenic,
chromium, iron and zinc in the leachate of wood waste ash were
found to be higher than the EPA fresh water acute criteria. In the
consideration that wood ash from fresh wood would not normally
have a high chemical composition of these metals, the recorded
high concentration of these metallic ions in the leachate produced
from wood waste ash are attributable to wood preservatives used
during processing of timber. Hence, it is important to screen wood
waste as a part of their selection process for use in concrete (Udoeyo
et al., 2006).
The presence of wood waste ash as a partial cement replacement 4.5. Microstructure of cement paste matrix
material in blended cement paste generally resulted in a higher
magnitude of cement paste soundness. Varying levels of cement Elinwa et al. (2008) performed a microstructural analysis on
replacement using wood waste ash from 0 to 30% causes a corre- concrete mixes containing 0% (PC-01N) and 10% (PC-03N) of wood
sponding increase in the soundness of blended cement paste. At a waste ash by total binder weight and observed a significant reduc-
replacement level of 30%, the most sound blended cement paste tion in porosity of hardened mortar for the latter concrete mix.
reported was 1.45 mm which was still in good compliance with the Additionally, the incorporation of 10% of wood waste ash as sub-
maximum allowable soundness of 10 mm specified by BS 4550-Part stitution of ordinary Portland cement (OPC) in the formulation
3 (Elinwa and Mahmood, 2002; Udoeyo and Dashibil, 2002; Elinwa of concrete mix was found to significantly reduce the percentage
and Ejeh, 2004). of non-hydrated cement and portlandite amount while increasing
the quantity of CSH gel present within the concrete mix produced
4.4. Calorimetric and heat evolution characteristics after a given curing age as summarized in Table 4. These obser-
vations imply a strong pozzolanic reaction between the reactive
The evaluation of heat development characteristics was per- silica present in wood waste ash with the portlandite compound
formed by Rajamma et al. (2009) on samples of wood waste fly generated from the hydration of cement.
ash (WWFA)/OPC blended cement containing 0–30% of WWFA as Pozzolanic reactions, which produced additional CSH gels in the
a partial substitution of OPC. All blended cement paste samples concrete mix with 10% wood waste ash of total binder weight,
tested were observed to reach a steady state temperature of 24 ◦ C were observed to continue beyond the hydration age of 28 days
within 3 days upon mixing. In addition, the time taken to reach up to 90 days. It can be noted in Table 4 that the production of CSH
their peak hydration temperature was observed to be shorter for gel within an equivalent concrete mix containing neat OPC with-
cement pastes containing WWFA. out wood waste ash content (PC-01N) had virtually stopped at the
In the absence of WWFA, neat OPC paste tested was found to age of 28 days and beyond as indicated by the stagnant amount of
reach peak hydration temperature at 40 ◦ C. Peak hydration tem- CSH gel after curing age of 28 days. Continuous production of CSH
peratures attainable by WWFA/OPC blended cement pastes were gel within a concrete mix with 10% wood waste ash content con-
recorded to be lower with increasing levels of cement replace- tributed towards the microstructure densification of the cement
676 C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685
Table 4
Result of micrograph analysis (Elinwa et al., 2008).
3 7 28 60 90
paste matrix, lowered degree of mix porosity, improved the quality A drastic reduction in the slump of concrete mix, from 62 mm
of the cement-aggregate interfacial transition zone and increased for a control concrete to merely 8 mm for a concrete mix with only
the uniformity of pore distribution within the cement paste matrix. 5% wood waste ash, was reported by Udoeyo et al. (2006). Zero
These enhancements of the microstructural properties of cement slump mixes were produced when wood waste ash was used at
paste matrices were beneficial for mechanical strength and dura- a cement substitution level of 20–30%. Such a significant impair-
bility of hardened concrete mix produced. ment of mix workability was probably due to high organic content
The XRD analysis performed on hardened wood waste fly ash of wood waste ash used in the production of the mixes. Wood waste
(WWFA) blended cement paste indicated that calcium silicates ash used in the study was reported to have high value for ignition
peaks in blended cement paste with 10% WWFA of total binder loss (LOI 10.46%), which may implicate the presence of significant
weight was more intense than those with 30% WWFA while the combustible organic content within the ash that renders, in nature,
intensity of the calcium silicate peak of neat OPC paste is the highest a high water absorption of ash. The nature of high water absorp-
at 28 days of curing. The observation implicates that the production tion of wood waste ash is further justified by the research findings
rate of calcium silicate hydrate (CSH) gel which is also the hydra- of Abdullahi (2006) that show the inclusion of wood waste ash col-
tion rate of cement paste was retarded by the inclusion of wood lected from a local bakery as a partial cement replacement material
waste fly ash as a partial cement substitution material in blended at replacement levels of 10%, 20%, 30% and 40% resulted in increase
cement paste (Rajamma et al., 2009). water requirements by 10%, 11.7%, 13.3% and 15% respectively in
Micrographs of hardened cement paste after 24 h of curing indi- order to achieve similar values of slump as the control concrete
cated extensive growth of CSH gel in neat OPC and 10% WWFA (both mixes without wood waste ash content.
type F1 and F2 WWFA) substituted cement paste as can be seen in Elinwa et al. (2008) investigated the effects of partial substi-
Fig. 7a–c. For blended cement paste specimens with type WWFA tution of cement by wood waste ash in the formulation of self
content of 30%, an active formation of ettringite needles within the compacting concrete (SCC) and mortar (SCM) mixes. At a constant
cement paste matrix was noted for the same duration of curing as mix proportion of cement, sand, water binder ratio and dosage of
in Fig. 7d and e. After 30 days of hydration of neat OPC paste and the superplasticizer, the mortar spreads of SCM mixes containing wood
blended cement pastes containing 10% and 30%, WWFA was almost waste ash (from open burning of sawdust) at a cement replace-
completed whereby silicate hardening phases could be observed in ment level ranging from 0% to 20% of binder weight were observed
the micrographs of their respective hardened cement paste matri- to undergo consistent reduction from 270 mm to 200 mm. In addi-
ces as in Fig. 8. In Fig. 8d and e, it can be noted that ettringite needles tion, the fresh SCM mix flow times were found to increase from
observed at earlier age of hydration in the blended cement paste 4 s to 18 s. This occurred when the level of cement replacement
containing 30% of WWFA remained in the paste even after 30 days of wood waste ash in the mix was increased from 0% to 20% by
(Rajamma et al., 2009). total binder weight as summarized in Table 5. SCC mixes con-
taining 20 mm coarse aggregates, wood waste ash as a partial
cement replacement material at 10% binder weight were tested
5. Rheological properties of wood waste ash/OPC concrete using a slump flow, V-funnel, T-5 minutes, U-Box and L-Box pro-
and mortar cedures. They each exhibited good compliance with specifications
in EFNARC (EFNARC, 2002) as summarized in Table 6. The SCC mix
Elinwa and Mahmood (2002) reported that utilization of wood with 10% wood waste ash content was in EFNARC compliance with
waste ash obtained from open burning for sawdust as cement their specified flow and V-Funnel values. This implies adequate mix
replacement material in the production grade 20 concrete has had stability and self-deaeration properties. Moreover, compliance of
adverse effects on the workability of freshly produced concrete mix. the actual T5 minutes test time, within EFNARC specifications, also
While the water binder ratio of the concrete mix were maintained showed that the mix had no segregation. The mix therefore satis-
at a constant at 0.565, increment level of cement replacement by fied the EFNARC requirement because of the good compactibility
wood waste ash from 5% to 30% of the total binder weight at 5% achieved as shown by the U-Box and L-Box values.
intervals resulted in a corresponding gradual decrease in the slump Rajamma et al. (2009) investigated the effects of incorporation
value of the concrete mix by 5–40 mm with reference to the con- of wood waste fly ash from a biomass power plant in mortar mixes
trol concrete mix without wood waste ash content. Similar trends on fresh and hardened properties in the produced mixes. The addi-
in the reduction of concrete workability in terms of slump were tion of wood waste fly ash as a partial substitution of OPC (10%)
reported by Udoeyo and Dashibil (2002) who attempted to pro- by total binder’s weight in mortar mixes had no adverse effect on
duce grade 25 concrete mixes containing a similar range of cement the water demand of wood waste fly ash mortar mixes. This was
replacement (5–30%) of cement using wood waste ash also pro- compared to the control mortar mix in order to achieve a similar
duced from open burning for sawdust. Corresponding decrease in level of workability using solely OPC as binder material. It had also
value of compacting factor of concrete mix with increasing level of been observed that mortar mixes with wood waste fly ash as a par-
cement replacement with wood waste ash was also observed. tial replacement material, using 10% binder weight, had prolonged
C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685 677
Fig. 7. Microstructure of cement paste after 24 h of hydration: (a) neat OPC paste; (b) 10% type F1 WWFA blended cement paste; (c) 10% type F2 WWFA blended cement
paste; (d) 30% type F1 blended cement paste; (e) 30% type F2 blended cement paste (Rajamma et al., 2009).
setting times in comparison to an equivalent control mortar mix. wood waste ash in the mix. An unexpected retardation occurred
Shortened mix setting times recorded when wood waste fly ash was within the mix setting rate. By incorporating the wood waste ash
used at a higher cement replacement level at 20% and 30% binder’s at a cement 10% replacement level, as mentioned earlier, proba-
weight. Higher setting rates were observed when there was a high bly caused a dominating effect over the relatively lower fineness of
rate of absorption when mixing water by organic content of the wood waste ash in comparison to OPC over its organic content.
Table 5
Mix proportion and workability of SCM mixes (Elinwa et al., 2008).
Mix no. Cement (kg/m3 ) SDA, % (kg/m3 ) Sand (kg/m3 ) Water (kg/m3 ) SP dosage (%) w/c Mortar spread (cm) Flow time (s)
Fig. 8. Microstructure of cement paste after 30 days of hydration: (a) neat OPC paste; (b) 10% type F1 WWFA blended cement paste; (c) 10% type F2 WWFA blended cement
paste; (d) 30% type F1 blended cement paste; (e) 30% type F2 blended cement paste (Rajamma et al., 2009).
6. Bulk density and mechanical strength of hardened wood 6.2. Compressive strength
waste ash/OPC concrete and mortar
Several researchers (Elinwa and Mahmood, 2002; Udoeyo and
6.1. Bulk density Dashibil, 2002; Elinwa and Ejeh, 2004; Abdullahi, 2006) had com-
mon findings that show the use of wood waste ash as a partial
Generally, the utilization of wood waste ash as a partial cement cement replacement material in concrete at all level of cement
replacement material in concrete mix reduces bulk density of hard- replacement ranged between 5% and 30% it reduces the compres-
ened concrete. Reduction in bulk density becomes more significant sive strength of the concrete mix produced relative to neat OPC
at higher levels of cement replacement using wood waste ash. Bulk concrete for all curing times. Udoeyo et al. (2006) justified that
density of grade 20 concrete mixes was observed to be reduced the trend observed is most probably due to the mechanism that
from 2482 kg/m3 at 0% wood ash content to 2281 kg/m3 when wood wood waste ash particles act more like filler material within the
ash content was increased up to 40%. The bulk density reduction cement paste matrix than as binder material. Thus, increasing ash
effect is attributed to a lower specific gravity wood waste ash in content as replacement of cement resulted in an increased surface
comparison to OPC (Elinwa et al., 2005). area of filler material to be bonded by decreasing the amount of
C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685 679
Table 6
Fresh property of SCC mixes with 10% wood waste ash (Elinwa et al., 2008).
FC-01M FC-01N
Experimental value Experimental value
cement which caused a decline in strength. However, Elinwa and and 20% and 3% metakaolin as additive reached target strength of
Mahmood (2002) observed a marginal difference of compressive 20 MPa after 28 days of curing period.
strength between wood waste ash concrete and neat OPC control Further evidence of pozzolanic characteristic of wood waste ash
concrete mix. This tends to decrease with prolonged curing dura- was reported by Elinwa et al. (2008) that incorporation of wood
tions, especially beyond 28 days. In addition, Udoeyo and Dashibil waste ash as partial cement replacement material by 10% of total
(2002) observed a higher rate of compressive strength gain for binder weight in self a compacting mortar mix resulted in improve-
concrete mix with wood waste ash content ranging between 15% ment in compressive strength of mix relative to control the mortar
and 25% total binder weight. This was true for increments of 5% mix containing neat OPC as binder. Self compacting mortar mixes
at later curing ages of 56 and 90 days. Both observations are evi- with wood waste ash beyond 10% total binder weight was observed
dence of increased CSH gel formation within cement paste matrix to have lower compressive strength than neat OPC mortar for curing
microstructure of wood waste ash concrete by pozzolanic activity. ages up to 28 days. At a prolonged curing age up to 90 days, mortar
This was done between an amorphous silica content of wood waste mixes with wood waste ash content of 15% exhibited compressive
ash and portlandite from the hydration of cement. strength similar to neat OPC mortar. Similar trends of a higher rate
Elinwa and Ejeh (2004) studied the compressive strength devel- of compressive strength development at later curing ages beyond
opment of mortar mixes containing wood waste ash as a cement 28 days up to 90 days relative to neat OPC mortar were exhibited
replacement between 5 and 30% at stepped increments of 5% by all mortar mixes which had wood waste ash content of 5, 10, 15
observed that mortar mix with 10% wood waste ash content exhib- and 20% of total binder weight.
ited highest compressive strength at all ages of curing up to 60 days. Rajamma et al. (2009) investigated the compressive strength
At a 60 day curing age the mortar mix with 10% of wood waste ash as of cement mortar mixes containing wood waste fly ash obtained
partial cement replacement material exhibited similar compressive from a wood biomass fired power plant. Wood waste fly ash was
strength as equivalent mortar mix with only OPC as binder. used as cement replacement material at replacement level of 10, 20
Naik et al. (2002) investigated the compressive strength devel- and 30% of total binder weight. It was observed that mortar mixes
opment behaviour of a concrete mixture made with wood fly ash with a wood waste fly ash content of 10% exhibited higher 28-day
used as a partial cement substitution material for curing age up to compressive strength but lower flexural strength in comparison
365 days. Wood fly ash was included in the mix at binder substitu- with equivalent neat OPC mortar. The use of wood waste fly ash as
tion levels of 5, 8 and 12% by total binder weight while a quantity of a partial cement replacement material at higher replacement level
binder, aggregate and water/binder ratios remained constant for all of 20 and 30% of total binder weight was observed to reduce 28 day
mixes produced. From the compressive strength results acquired, compressive strength relative to equivalent neat OPC mortar mix.
they concluded that (i) control concrete mixture (without wood Utilization of very finely ground ash from the co-combustion of
waste ash content) achieved a strength of 34 MPa at 28 days and wood waste, sugarcane bagasse and rice husks (BRWA) as partial
44 MPa at 365 days. The strength of (ii) concrete mixtures contain- cement replacement material in concrete was found to significantly
ing wood fly ash ranged from 33 MPa at 28 days and between 42 improve the compressive strength of the concrete mix produced.
and 46 MPa at 365 days. (iii) The inclusion of wood fly ash in a par- Horsakulthai et al. (2011) investigated the strength development
tial substitution of cement in concrete up to a replacement level of characteristic of concrete mixes produced by incorporation of
12% had a significant contribution to the strength development of BRWA as cement replacement material. BRWA used were obtained
concrete mixtures produced. Continuous strength was gained from from a biomass power plant which used the mixture of wood waste,
the wood fly ash concrete mixes upon prolonged curing durations. sugarcane bagasse and rice husk as fuel and ground to a very fine
This indicated a presence of pozzolanic reactions between wood dust (2% of total mass of ash retained on 45 m sieve). Concrete
waste ash and the cement hydration product. mixes produced had BRWA content of 0%, 10%, 20% and 40% total
Elinwa et al. (2005) attempted to improve compressive strength binder weight as a partial cement replacement material. After 28
of wood waste ash/OPC concrete by the including trace amounts days curing, the concrete mixes with BRWA contents of 10% and
of metakaolin as an additive in the concrete mixes. The concrete 20% total binder weight were determined to have a higher compres-
mixes produced had 20 MPa target strength. This mix included sive strength of 103% and 108% normalized against the compressive
wood waste ash as a cement replacement using a 5% step incre- strength of the control concrete mix. Concrete mixes with 40%
ments between 0 and 40%. Metakaolin was used as an additive BRWA content total binder weight, though exhibited lower com-
material at a constant dosage of 3% by total binder weight. It was pressive strength as early as 7 and 28 days relative to control
observed that the inclusion of metakaolin though at small dosage, concrete mix, had a similar compressive strength as the control
contributed towards the enhancement of an early rate of com- concrete at prolonged curing period of 91 days. Concrete mixes
pressive strength gain of wood waste ash/OPC concrete. SDA/OPC with 10%, 20% and 40% of concrete mixes exhibited higher rates of
concrete with 10% wood waste ash total binder weight exhibited a strength beyond 28 days relative to control concrete mix with only
compressive strength and modulus of rupture which was respec- OPC as binder. Compressive strengths with a given curing time for
tively 37% and 7% higher in comparison to the neat OPC concrete all the mixes examined are summarized in Table 7. Enhancements
though both mixes had same content of metakaolin. Concrete mixes in the compressive strength of concrete with BRWA content as early
with wood waste ash at cement replacement levels of 5%, 10%, 15% as 7 and 28 days were attributed to the micro filler effect of the ultra
680 C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685
1
Naik et al. (2002) investigated the effects of the incorporation
0.8 of wood ash in partial replacement of cement in concrete mix
on flexural strength of hardened concrete. In this study, wood fly
0.6
7 Days ash was incorporated in a concrete mix at a cement replacement
0.4 28 Days level of 0 (control concrete), 5, 8 and 12%. The flexural strength
0.2 results obtained indicated that (i) control mixture achieved flex-
ural strength of 4.1 MPa at 28 days and 4.4 MPa at 365 days; (ii)
0 the strength of concrete mixtures with wood fly ash content varied
0 10 15 20 25 30 between 3.9 and 4.4 MPa at 28 days and between 4.3 and 5.3 MPa
Sawdust ash content (%) at 365 days (iii) and at 7 days, all mixes with wood fly ash content
exhibited superior flexural strength relative to the control concrete
Fig. 9. Split tensile strength ratio versus sawdust ash content (Udoeyo and Dashibil,
2002).
mix. The mix which had 5% wood fly ash exhibited the highest flex-
ural strength. (iv) At 28–365 days, the concrete mix containing 8%
of wood fly ash exhibited optimal flexural strength among all mixes
fine particles of ash which contributed to the denser packing of examined.
the cement paste matrix. A higher compressive strength of BRWA Udoeyo et al. (2006) studied the flexural strength development
mixes at later age of curing (91 and 180 days) were largely due behaviour of concrete mixes produced with the use of wood waste
to continuous formation of CSH gels within cement paste matrix ash as a partial cement replacement material at varying levels of
by pozzolanic reaction between amorphous silica composition of cement replacement; (0 (control concrete), 5, 10, 15, 20, 25 and
BRWA with portlandite from hydration of cement. High rates of 30% binder weight. Flexural strengths of concrete specimens pro-
the pozzolanic reaction which was initiated on the 28 days of curing duced were recorded at 3, 7, 14, 21 and 28 days. Analysis of the
period were largely due to very fine particle size of the ash. results indicated that at all ages the concrete there was an increased
level of cement replacement with wood waste ash that resulted
6.3. Split tensile strength in a decreased magnitude of flexural strength. For instance, at 28
days, the flexural strength of the concrete mix with 5% wood waste
Udoeyo and Dashibil (2002) reported a reduction in both the ash content was recorded at 5.20 MPa as compared to 5.57 MPa of
compression and split tensile strength of concrete produced by control concrete specimens. A gradual reduction occurred in the
partial replacement of cement with wood waste ash. Split tensile flexural strength over 28 days. Results revealed a decrease from
strength of concrete mixes at 7 and 28 days was observed to decline 5.20 MPa with 5% wood waste ash concrete to 3.74 MPa with 30%
with increasing level of cement replacement with wood waste ash. total binder mass with wood waste ash content in the mix was
The effects of reduction in split tensile strength of concrete by the observed. By performing a regression analysis of flexural strength
use of wood waste ash as partial cement replacement material and compressive strength data acquired, they also found a strong
was less pronounced in comparison with reduction in compres- direct linear proportional correlation between flexural strength and
sive strength. It was observed that the marginal difference in split the compressive strength of wood waste ash concrete mixes pro-
tensile strength of SDA/OPC concrete mixes with reference to neat duced for up to 28 days as presented in the following equation.
OPC concrete were more significant at 7 days. However, at 28 days
ff = 0.234fcu − 0.908 (R2 = 0.94) (1)
the SDA/OPC concrete mixes with a cement replacement level up
to 25% total binder weight exhibited a split tensile strength values Rajamma et al. (2009) evaluated the 28 days flexural strength
of over 90% of split tensile strength of neat OPC concrete as seen in of mortar mixes produced by partial replacement of cement binder
Table 8. The graphical correlation between a split tensile strength using fly ash from two distinct wood biomass power plants. Mor-
ratio (split tensile strength of SDA concrete to neat OPC concrete) tar bars specimens fabricated for flexure testing were produced
and sawdust ash content in Fig. 9 illustrates a further reduction with the use of wood fly ash at 0 (control mortar), 10, 20 and 30%
C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685 681
120 120
100 100
Weight (g)
80
Weight (g)
80
60 60
Control Control
40 10% SWIFA 40 10% SWIFA
20 20
0 0
0 1 2 3 4 5 6 0 1 2 3 4 5 6
Age (weeks) Age (weeks)
Fig. 10. Variation of mass of concrete with the duration of immersion in nitric acid Fig. 11. Variation of mass of concrete with the duration of immersion in sulphuric
20% (Elinwa and Ejeh, 2004). acid 20% (Elinwa and Ejeh, 2004).
Udoeyo and Dashibil (2002) investigated the resistance of con- concrete as can be seen in Fig. 10. However, a 10% wood waste
crete containing wood waste ash against acid attack. Two batches ash concrete mix was observed to have a lower resistance against
of concrete specimens having the same mix proportions (1 binder: the corrosive action of sulphuric acid in comparison to the con-
2 sand: 4 gravel and w/c ratio of 0.65) were produced. One of trol concrete containing only neat OPC as binder. This is due to
the batches contained neat OPC as a binder while the other batch higher loss in mass of 10% wood waste ash concrete as compared
had 15% total binder weight of wood waste ash used in partial to OPC concrete when immersed in 20% sulphuric acid as indicated
replacement of cement and 85% total binder weight of cement. in Fig. 11.
The hardened concrete cubes produced were immersed in a 20%
concentrated nitric acid solution. The cubes were immersed and 7.2. Water absorption
their loss of mass was noted at 7, 14, 21, 28, 35, 42, 49, 56, 63
and 70 days. There was a continuous marginal increase in mass Elinwa and Ejeh (2004) studied the effects of the incorporation
for both sets of concrete specimens upon immersion in the con- of wood waste ash as a partial cement replacement material in mor-
centrated nitric acid solution up to 9 weeks of immersion due to tar mixes on its water absorption property. Two batches of mortar
the absorption of water. At the tenth week of immersion, there mixes with the same mix proportions (1 binder: 3 sand: 0.6 w/b
was observable mass decrease in both batches of specimens and ratio) were cast whereby one batch contained 15% wood waste
it could be noted that mass decrease of the concrete specimens ash as a partial replacement material while the other had no wood
with 15% total binder weight of wood ash were less pronounced waste ash content. It was observed that inclusion of wood waste
in comparison to control concrete specimens with neat OPC as ash as a cement replacement material at 15% total binder weight
binder. contributed towards the reduction in water absorption of the mor-
Elinwa and Ejeh (2004) studied the effects of incorporating tar mix produced. Average water absorptions of mortar mixes with
wood waste ash in concrete for resistance against corrosive action. 15% of wood waste ash and without wood waste ash content were
Two types of corrosion tested were concentrated nitric acid and recorded to be 0.8% and 1.25% respectively whereby both are still
sulphuric acid both having a 20% concentration. A batch of con- far below maximum of 10%.
crete with wood waste ash used as a partial cement replacement Udoeyo et al. (2006) investigated the water absorption prop-
level of 10% total binder weight and a corresponding batch of con- erties of concrete with wood waste ash as a partial cement
trol concrete a having similar mix proportion as the former but replacement material. Concrete mixes with wood waste ash con-
without wood waste ash content. Both specimens were immersed tent ranging between 5% and 30% at increments of 5% were
in both types of acid solution mentioned earlier. Their loss in mass produced for water absorption tests. The water absorption of
was noted every week for total immersion up to 5 weeks. The resis- concrete with wood waste ash as a partial cement replacement
tance of concrete containing 10% of wood waste ash by total binder material was observed to increase gradually from 0.14 to 1.05%
weight against corrosive action of nitric acid was observed to be with the increase in level of cement replacement from 5% to 30% as
higher than control concrete mix because loss in mass of wood shown in Fig. 12. At levels of cement replacement by wood waste
waste ash concrete was less pronounced relative to the control ash up to 30%, concrete mix produced still has satisfactory values
682 C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685
entrained air (Neville, 1995). Wang et al. (2008c) observed that the
40 use of wood waste fly ash in partial substitution of cement raised
30 the demand of air entraining agents of the mix to achieve a given
20 range of entrained air content within the concrete mix. This was
probably attributed to the absorption of air entraining agent by
10
active carbon available in the organic content of wood waste fly
0 ash. Similar behaviour was observed for other types of fly ashes
10BRWA1
20BRWA1
40BRWA1
10BRWA2
PC1
PC2
10. Reuse and recycling of wood waste ash significant increase in heavy metal concentration was found due to
addition of wood ash.
10.1. Use of wood waste ash in the production of controlled low Nguyen and Pascal (1997) measured tree growth response by
strength material (CLSM) the use of wood ash from two different sources as a forest soil
amendment. Four different application rates (0, 2, 4 and 8%) were
Naik (1999) investigated physical, chemical and morphological used. They observed that the addition of wood ash to forest soil
properties of wood ash and found that it could be potentially used as affected all the measured growth parameters within the wood ash
a pozzolanic mineral admixture and chemical activator in cement application zone. However, a 2% application rate was found to be
based material. Furthermore, he indicated that wood ash has sig- optimum.
nificant potential to be used in the production of controlled low Meyers and Kopecky (1998) evaluated the effects of land spread-
strength material (CLSM) and other construction material such as ing wood ash on forage crop yield and the elemental composition
masonry product, roller compacted concrete pavement and (RCCP) of soil nutrient levels. The use of wood ash as soil supplementary
and blended cements. material resulted in higher crop yield in comparison to the use
As an extension from his previous work, Naik (2000) proceeded of lime and fertilizer. No adverse effects were noted at wood ash
further to study the use of wood waste ash as a main component application rate of up to 20 tonnes per acre.
in the production of CLSM. In the study, a total of 31 CLSM mix- The use of wood ash as a liming agent to control the alkalinity of
tures were formulated using three distinct sources of wood fly soil has been in practice in the agricultural sector for many years.
ash to obtain a range of compressive strengths between 0.34 MPa Wood ash for land application involves several considerations. Prior
and 1.0 MPa at the age of 28 days. CLSM mixtures produced con- to planting any crops on agricultural land, the existing nutrient and
sisted only of three constituent materials namely cement, water pH level must be determined by appropriate soil testing methods. In
and wood waste fly ash. Each batch of CLSM mixture produced order to minimize potential air and ground water pollution, wood
was evaluated for its rheological and hardened state properties. ash applications on agricultural land should be limited to a level
Rheological properties of the mix examined included fresh unit that maintains the soil pH for the intended crop growth. Moreover,
weight, amount of bleed water, settlement, setting and harden- excessive applications of wood ash may result in higher soil alkalin-
ing characteristics. Aspects of hardened CLSM properties evaluated ity which may render the land unsuitable for planting certain crops.
were compressive strength, density and permeability of hardened Generally, the liming ability of wood ash is estimated using a mea-
mix. surable parameter called the calcium carbonate equivalent (CCE).
Several CLSM mixtures with high volumes of wood waste fly ash However, CCE content may vary significantly for wood ash from
were found to be appropriate for backfill and excavation work and different sources but the variations are normally within the range
for making low to medium strength concrete (Naik, 1999, 2000). of 25–60%. In the presence of proper soil tests and laboratory data
Further evidence was reported by Fehrs (1996) who studied the on lime equivalency of wood ash used, application rates for wood
mechanical and rheological properties of low strength concrete ash are calculated as the ratio of recommended lime application
and CLSM by the incorporation of wood waste ash as constituent rate to the lime equivalency of wood ash (Siddique, 2008).
material. He concluded that wood ash can be suitably used as a
constituent material in the manufacture of low strength and CLSM
material. 10.3. Use of wood ash as a pollution control agent
10.2. Use of wood ash for improvement of soil alkalinity and as Wood ash has been used as a replacement for lime or cement
fertilizer kiln dust in the solidification of hazardous wastes. In addition, wood
ash is an effective liming agent and has been widely used for pH and
Naylor and Schmidt (1986) evaluated wood ash for use as a fer- odour control of hazardous and non hazardous wastes. Wood ash
tilizer and liming agent for agricultural soil. In this study, wood has been added to compost as a colour and odour control agent.
ash was mixed with acidic soil at application rates of 0, 0.4, 1.8 Wood ash has been found to be able to capture several water borne
and 2.4 tonnes/acre to assess any changes in extractable nutri- contaminants (NCASI, 1993).
ents and soil pH. They observed that increasing the rate of wood
ash application resulted in a higher soil pH and concentrations
of extractable phosphate, potassium and calcium ions. The ash 11. Conclusions and summary
neutralizing capability was found to be half of that achieved by
agricultural limestone. 1. Quantity and quality of wood ash are dependent on several
Etiegni and Campbell (1991) investigated the suitability of wood factors namely, combustion temperatures of wood biomass,
ash as an agricultural soil supplement and liming agent. In this species of wood from which wood biomass fuels were derived
study, two types of plants, namely winter wheat and poplar, were and types of combustion technology used. Hence, proper char-
grown in a green house on six different soil samples amended with acterisation of wood ash is mandatory prior to its application as
varying amounts of wood ash. The results obtained indicated a sub- a constituent material in the production of concrete mixtures.
stantial increase in the biomass of wheat and in the diameter and 2. Particle distribution of wood ash is generally coarser in com-
height of the poplar at ash in soil concentration up to 2% (equiv- parison to ordinary Portland cement (OPC). However, specific
alent to application rate of 16 tonne/acre). Furthermore, from an surface of wood ash is comparatively higher than OPC due to
analysis of their results, the authors indicated that wood ash can be high irregularity in the shape of wood ash particles and its
suitably applied as a low grade fertilizer with significant potassium porous nature.
and liming agent content. 3. Wood ash has a chemical composition which varies signifi-
Bramryd and Frashman (1995) reported a decrease in acid- cantly within species of trees from which the wood biomass
ity and aluminium concentration when wood ash was applied to was derived but is generally rich in lime and silica compounds.
soil bearing 35 year old pine trees in Sweden. In addition, con- 4. Blended cement with wood ash as a partial OPC replacement
centrations of extractable Manganese ions were found to increase material has a higher standard consistency, initial and final set-
following wood ash applications. Copper ion content in the soil was ting time. It tends to have more soundness but a lower rate of
also found to increase with the presence of wood ash. However, no heat development relative to neat OPC paste.
C.B. Cheah, M. Ramli / Resources, Conservation and Recycling 55 (2011) 669–685 685
5. Significant amounts of ettringite crystals are formed within a AUPE001] and Research University Postgraduate Research Grant
cement paste matrix upon hydration of wood ash-OPC blended Scheme (USM-RUPRGS) [Grant No. 1001/PPBGN/843086].
cement especially at high level of OPC substitution by wood
ash. References
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The review work is jointly supported by Universiti Sains
Malaysia Fellowship Programme [RU: 1001/441/29301/CIPS/