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Predict Distillation

Tray Efficiency

Markus Duss

Sulzer Chemtech Ltd

Ross Taylor

Clarkson Univ.

used to estimate the efficiency of cross-flow trays.

This article proposes a modification and clarifies the relationship

between the empirical and theoretical approaches.

D

istillation — the most important unit operation

for separating liquid mixtures — is carried out in

columns equipped with either packing or trays.

In a conventional tray column, vapor rises vertically up O’Connell published a graph showing section efficien-

through the column while the liquid flows downward cies for bubble cap trays, which can be represented by (1):

and across the trays in alternate directions on succes-

sive trays (Figure 1). Column simulation and design

software calculates the number of theoretical stages where μL is the liquid viscosity in mPa-s and α is the rela-

and the section efficiency is used as an efficiency factor tive volatility.

to translate theoretical stages to actual trays. The effi- The relative volatility and the liquid viscosity serve as

ciency of a particular section of a column (ηsection) is the the only input variables in calculating conventional distilla-

number of theoretical stages (nth) found in a section of tion tray efficiencies with the empirical correlation devel-

a column divided by the number of actual trays (ntrays): oped by O’Connell (1). This simple method has survived all

24 www.aiche.org/cep July 2018 CEP Copyright © 2018 American Institute of Chemical Engineers (AIChE)

attempts at being replaced by more rigorous models, despite depends on the flow pattern of the vapor and liquid phases.

lacking a sound theoretical explanation for its success. This Most models for cross-flow trays assume that the vapor

article presents a simple, but fundamentally sound, theoreti- flows vertically in plug flow and the liquid is vertically

cal approach that achieves results equivalent to O’Connell’s well-mixed. With these assumptions, the Murphree point

correlation using the same number of variables — revealing efficiency on a tray is defined as (3):

the hitherto unrecognized relationship between O’Connell’s

empirical correlation and other theoretical models. In addi-

tion, the article introduces a modification to O’Connell’s The Murphree vapor-phase tray efficiency (ηtray) defines

correlation that produces a close-to-perfect match between the fractional approach to equilibrium for a single cross-

the updated correlation and the derived theoretical model. flow tray based on the vapor concentrations on the oper-

ating and equilibrium lines. The following assumptions sim-

The traditional Murphree efficiency plify the mathematics: the liquid travels in plug flow across

approach to tray design the tray, the point efficiency in Eq. 4 is constant across the

The section efficiency is calculated based on fundamen- tray, and the vapor concentration below the tray is uniform.

tal mass-transfer considerations, including the approach to Based on these assumptions, the Murphree tray effi-

equilibrium both locally on the tray (point efficiency) and ciency is (2):

on the tray as a whole (tray efficiency). The conventional

method of designing trays (2) employs Murphree’s defini-

tion of efficiency to quantify the approach to equilibrium.

The overall number of transfer units for the gas phase The section efficiency in a distillation column is related

(NOG) is (3): to the tray efficiency by (2):

where NG and NL represent the number of transfer units in When the equilibrium line is steeper than the operat-

the gas and liquid phases (a measure to quantify mass trans- ing line, as is typically the case for the stripping section of

fer), respectively, and λ is the stripping factor calculated as a column, the stripping factor is greater than one and the

λ = mG/L, where m is the slope of the equilibrium line and section efficiency is less than the tray efficiency. When the

G and L are the gas and liquid flowrates per cross-sectional stripping factor is less than one, the section efficiency is

bubbling area in kmol/m2-s. higher than the tray efficiency, which typically occurs in the

The approach to equilibrium that can be achieved with a rectifying section. When the stripping factor is exactly one

given number of transfer units depends on the concentration the section and tray efficiencies are equal.

profile — the driving force for mass transfer, which, in turn, The more rigorous efficiency model in Eqs. 3–6 requires

a large amount of input data: detailed tray geometry, trans-

Vapor to port properties of the liquid and vapor phases (diffusivities,

Condenser

viscosities, and densities), operating conditions (pressure,

temperature, liquid and gas flowrates), and thermodynamic

Rectifying

Reflux

Section

Liquid Overflows

information (the slope of equilibrium line). This infor-

the Weir mation is necessary for the correlation of mass-transfer

Feed Stage n–1 coefficients, interfacial area, froth height, bubble regimes,

horizontal backmixing, entrainment, and weeping, all of

which are required to calculate the numbers of transfer units

Stripping

Section

Stage n

(and therefore the Murphree point and tray efficiencies) that

Vapor from Stage n+1 are needed for column design.

Reboiler Vapor Rises and

Passes through

Combining Eqs. 3–6 yields:

Holes or Valves

Liquid to in Trays

Sump

which liquid flows in alternate directions on successive trays. The topmost

tray has the highest concentration of the more-volatile species and the This simplified, theoretical model follows fundamental

lowest tray has the highest concentration of the less-volatile species. mass transfer principles.

Copyright © 2018 American Institute of Chemical Engineers (AIChE) CEP July 2018 www.aiche.org/cep 25

Reactions and Separations

If there are any hidden ties between the O’Connell less than the α = 4 used in Figure 2, and in such cases the

and traditional methods for calculating tray efficiency, the difference between α and λ is less. For α < 1.3, no signifi-

approaches should produce similar results and the following cant difference exists at any concentration.

approximation must hold:

Revealing the ties

To establish the conditions under which the results of

O’Connell’s correlation and the traditional model can agree,

the stripping factor (λ), must be used instead of the relative

volatility (α), and NG and NL must be expressed in terms

of a single variable, namely the liquid viscosity. And, as in

O’Connell’s approach, only one constant of proportionality

It is not obvious why O’Connell used α in his correla- and one fixed exponent will be used to correlate the number

tion; based on the theoretical model (Eqs. 3–6), it would of transfer units. These simplifications avoid the cumber-

appear that either the slope of the equilibrium line or the some theoretical approach to calculate NG and NL.

stripping factor is more likely to be relevant. In addition, The correlations between NG and NL can be expressed

O’Connell’s method also appears to ignore explicit inclu- with the same parameters in the form:

sion of any mass-transfer performance parameters distin-

guishing the vapor and liquid phases, such as the numbers

of transfer units. And yet, the method has been successfully where c1 and x1 are constants determined by regression.

applied in many cases. Regressing c1 and x1 to minimize the difference between the

The relative volatility (α) might remain nearly constant outcome of the theoretical model (the first line of Eq. 8) and

and is always greater than one over the entire concentra- O’Connell’s correlation (the second line of Eq. 8) yields the

tion range for nonazeotropic systems. On the other hand, proportionality constant c1 = 0.936 and the exponent x1 =

the stripping factor can vary considerably with concentra- –0.25. Thus, Eq. 9 becomes:

tion. Figure 2 is the McCabe-Thiele diagram for a binary

system for which α = 4. The slope of the equilibrium line at

low concentrations of the lower-boiling compound (x 0)

becomes α, whereas the slope becomes 1/α at the opposite Figure 3 reveals the close agreement between the

end of the concentration range (x 1). The diagonal line theoretical model and O’Connell’s empirical approach

in Figure 2 is the operating line (assuming total reflux, i.e., to estimating section efficiencies. The deviation over the

L/G = 1), and, under these circumstances, the stripping fac-

tor is α at one end of the vapor-liquid equilibrium line and 100 +10%

α =1; μL = 0.08 – 5 cP

80 α =1.5; μL = 0.08 – 5 cP

1

mx = 1/α α = 2; μL = 0.08 – 5 cP

1 70

0.9 λx α = 3; μL = 0.08 – 5 cP

Theoretical Model ηsection

1

= 1/α

60 α = 5; μL = 0.08 – 5 cP

0.8

Typical Range

=α m 50

0.7 mx riu in Rectifying

ilib

Liquid Mole Fraction

o

λx =α u Section

0.6

o

Eq =1 40

L /G

0.5 lope 30

e,S

0.4 Lin 20 ηsection (λ) ≈ ηsection (1/λ)

t ing α= 4

ra L/G = 1 10

0.3

O pe

0.2 0

Typical Range 0 10 20 30 40 50 60 70 80 90 100

0.1 in Stripping

Section O’Connell ηsection

0

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 p Figure 3. A parity plot shows that section efficiencies determined by

Vapor Mole Fraction O’Connell’s correlation agree well with the results of the theoretical model.

The range studied, with the relative volatility varying between 1 and 5 and

p Figure 2. This McCabe-Thiele diagram depicts a binary system with a the liquid viscosity varying between 0.08 and 5 mPa-s, covers the majority

relative volatility of α = 4. of commercial distillation applications

26 www.aiche.org/cep July 2018 CEP Copyright © 2018 American Institute of Chemical Engineers (AIChE)

range investigated is less than 10%. The section efficiencies basis only when such symmetry exists.

obtained from the traditional model were calculated using The terms NG and NL quantify mass-transfer behavior

the stripping factor for x = 0 and x = 1. Astonishingly, sub- in the vapor and liquid phases, respectively. Since the slope

stituting Eq. 10 into Eq. 7 produces nearly identical results of the equilibrium line influences the distribution of the

whether λ or 1/ λ is used. The reciprocal of the stripping resistances to mass transfer across the two phases, assuming

factor often is referred to as the absorption factor. that NG = NL does not imply that the liquid-side and vapor-

It is important to understand this outcome since this pro- side resistances to mass transfer are equal. The fundamental

vides the justification for using the relative volatility instead relationship of the gas-side and liquid-side mass transfer

of the stripping factor to represent relevant behavior. While coefficients is (3):

the relative volatility is always greater than one, the strip-

ping factor is smaller than one when the mixture contains

high concentrations of the higher-boiling-point compound.

Using the stripping factor based on α for x = 0 and x = 1 where KOG is the overall gas-phase mass-transfer coefficient

can, in many cases, reflect the approximate slope at total in kmol/m2-s and kG and kL are the gas-side and liquid-side

reflux in the striping and rectifying sections, respectively. mass-transfer coefficients, respectively, in kmol/m2-s.

The dependency of the correlation on the liquid viscos- The relative liquid-phase resistance (LPR) in a column

ity is very similar for the two correlations. However, the is defined as (4):

dependency on α or λ shows that O’Connell overestimates

the impact of α on the section efficiency when compared to

the model based on the traditional approach.

Figure 5 shows the dependency of LPR on the stripping

Understanding the relationship factor. The liquid-phase resistance increases with increas-

Combining Eq. 10 with Eq. 7 yields almost identical ing stripping factor. For small values of λ, the liquid-phase

section efficiencies for a given value of the stripping factor

and its reciprocal. Figure 4 plots the calculated section effi-

ciencies for three different ratios of NG:NL. To allow a com- Nomenclature

parison, the stripping factor was varied and NG was adjusted c1 = proportionality constant

in order to achieve the same maximum section efficiency to G = gas throughput per cross-sectional bubbling area,

kmol/m2-s

reveal apparent symmetries. kG = gas-side mass-transfer coefficient, kmol/m2-s

In the case of NG = NL (Figure 4), there is an apparent kL = liquid-side mass-transfer coefficient, kmol/m2-s

symmetry about λ = 1. Such symmetry is not present in the KOG = overall gas-side mass-transfer coefficient,

other two cases. However, the NG = NL curve is not strictly kmol/m2-s

symmetrical about λ = 1, as the efficiencies for values of λ L = liquid throughput per cross-sectional bubbling

and 1/ λ other than one are slightly different. The use of the area, kmol/m2-s

relative volatility in O’Connell’s method has a theoretical LPR = liquid-phase resistance

m = slope of the equilibrium line

0.8 NG = number of transfer units in gas phase

N L = number of transfer units in liquid phase

0.7 NG= 0.785 NOG = overall number of transfer units in gas phase

0.6

nth = number of theoretical stages

ntrays = number of actual trays

0.5 x1 = exponent to be applied to the liquid viscosity

NG=1.5

Greek Letters

ηsection

0.3 ηpoint = Murphree vapor point efficiency

NG= 2.43

ηtray = Murphree vapor tray efficiency

0.2 ηsection = section efficiency or overall efficiency

NG:NL = 1:1

μ = viscosity, mPa-s or cP

0.1 NG:NL = 1:3

NG:NL = 3:1 λ = stripping factor = mG/L

0 σ = either stripping or absorption factor used

0.01 0.1 1 10 100

in Eq. 15

Stripping Factor, λ Subscripts

G = gas or vapor

p Figure 4. The section efficiency calculated by the theoretical L = liquid

approach depends on the stripping factor.

Copyright © 2018 American Institute of Chemical Engineers (AIChE) CEP July 2018 www.aiche.org/cep 27

Reactions and Separations

λNOG NG:NL = 1:1 LPR will become dominant, i.e., is more than 50% of

90 LPR = 100%

NL

80

the overall resistance.

Liquid Side For increasing values of λ above one, the LPR

70 Resistance

is Dominant increases and section efficiencies decrease. Thus, it

60 would be reasonable to expect that with decreasing

LPR %

40 tion efficiency should increase, but this is not the case.

30

Vapor Side

Resistance

To understand this behavior, it is important to quantify

is Dominant the impact of the stripping factor when converting

20

the Murphree tray efficiency to the section efficiency.

10

Figure 6 illustrates the behavior of Eqs. 3–6, which are

0 the basis for the derived model. The section efficiency

0.01 0.1 1

Stripping Factor, λ

10 100 calculated by Eq. 6 decreases with decreasing λ,

explaining the drop in the section efficiency when the

p Figure 5. The liquid-phase resistance (LPR) depends on the stripping factor and stripping factor becomes small, despite the fact that

the ratio of NG: NL, which is assumed to be one.

the Murphree tray efficiency increases. This explains

1 why O’Connell’s correlation can use α instead of λ

1 = 1 + λ

0.9 NOG NG NL while still achieving meaningful results, provided the

NG = NL = 1

ηpoint = 1—e —NOG assumption NG = NL holds true.

0.8

ηtray = e —1

ληpoint In summary, for increasing values of λ, the liquid-

0.7 λ

In(1+ ηtray (λ—1) phase resistance becomes dominant and reduces the

0.6 ηsection =

section efficiency, whereas for decreasing values of

η or NOG

In(λ)

0.5 λ, the driving force for mass transfer increases. The

0.4 translation of the tray efficiency to section efficiency is

0.3 the reason for the decrease of the section efficiency.

0.2

0.1

Modifying the O’Connell correlation

0

The derived simplified theoretical model is

0.01 0.1 1 10 100 expected to more accurately predict section efficien-

Stripping Factor, λ cies, albeit with increasing complexity. Therefore, a

p Figure 6. This graph shows the relationship between the stripping factor, various simple modification to O’Connell’s correlation better

efficiencies, and the number of transfer units, assuming NG = NL = 1. Reducing reflects theoretical outcomes.

liquid resistance reduces section efficiencies, the opposite of what is expected, as The relative volatility affects the section efficiency

Murphree tray efficiency increases under the same conditions.

in the O’Connell correlation more than it does in

0.8 the theoretical model. Therefore, the exponent on α

ηsection = 0.503 μL-0.226 α-0.08

should be adjusted independently from the exponent

0.7

on the liquid viscosity to better match the theoretical

0.6 prediction.

0.5 Figure 7 shows the relevant range for adjusting

the exponent on α in the O’Connell correlation. The

ηsection

0.4

liquid viscosity was assumed to be 0.2 mPa-s while α

0.3 was varied between 1 and 5. The exponent on α was

regressed and the best-match curve revealed the value

0.2

α = 1/ λ α= λ to be –0.08. The black line represents the theoretical

0.1 dependency of the section efficiency on the stripping

0

factor. The red line is the outcome using an exponent

0.1 0.2 1 5 10 of –0.08 on α for the modified O’Connell method.

Stripping Factor, λ The modified O’Connell correlation (Eq. 2) there-

p Figure 7. The modified O’Connell correlation (red) achieves a good agreement

fore becomes:

with the traditional model (black) for α < 5 when the exponent for α is –0.08. The

liquid viscosity was assumed to be 0.2 mPa-s while α was varied between 1 and 5.

28 www.aiche.org/cep July 2018 CEP Copyright © 2018 American Institute of Chemical Engineers (AIChE)

The new exponent for α is now used to regress the pro- proposed modification. Data points for capacities of more

portionality constant (c1). Equation 10 is thus rewritten: than 98% or less than 25% were excluded from the analy-

sis because the majority of those data points were associ-

ated with reduced efficiency due to jet flood or weeping,

As the parity plot in Figure 8 demonstrates, the modified respectively.

O’Connell correlation (Eq. 13) achieves an almost-perfect Figure 9 indicates that using the exponent of –0.08 for

fit with the combined Eqs. 7 and 14. the relative volatility improves the prediction of section

Based on theoretical considerations, the stripping factor efficiency. Using the stripping factor improves the accuracy

(λ) or its reciprocal (1/ λ) is preferred over the relative vola- further, but, more importantly, it allows Eq. 15 to be used

tility (α). This is because when α is used, it is not possible for absorption and stripping applications as well as for

to distinguish between total and partial reflux conditions; distillation.

the stripping factor helps to account for this. Therefore, the

modified O’Connell correlation can be written as: Eq. 2 Eq.13 Eq. 15

Average Relative Deviation = –17% –6% –2%

Average Absolute Deviation = 21% 16% 15%

where σ = λ if λ > 1 and σ = 1/λ if λ < 1. 140

x O’Connell, Eq.2 +20%

Modified O’Connell, Eq.13

Validation 120 Modified O’Connell, Eq.15

When the O’Connell correlation was modified, the –20%

proportionality constant was retained at 0.503. Since this 100

Predicted Section Efficiency

was not to alter the outcome for small values of α. Chan 80

cyclohexane/n-heptane, iso-butane/n-butane, ethyl‑ 60

ammonia/water. He reported the section efficiency, the rela- 40

capacity (5). Chan’s data were used in order to compare 20 Absorption Data

the outcome of the original O’Connell correlation with the

0

0 20 40 60 80 100 120 140

α =1; μL = 0.08 – 5 cP +10%

90 α =1.5; μL = 0.08 – 5 cP

p Figure 9. Parity plots of measured experimental section efficiencies

α = 2; μL = 0.08 – 5 cP and efficiencies calculated by the original O’Connell correlation (Eq. 2),

80 -10%

α = 3; μL = 0.08 – 5 cP the modified correlation using α (Eq. 13), and the modified correlation

α = 5; μL = 0.08 – 5 cP using λ (Eq. 15) show that the modifications improve the accuracy of the

70

correlation.

Theoretical ηsection

60

50

Literature Cited

40 1. O’Connell, H. E., “Plate Efficiency of Fractionating Columns

and Absorbers,” Transactions of the American Institute of Chemi-

30

cal Engineers, 42, pp. 741–775 (1946).

20 2. Lewis, W. K., “Rectification of Binary Mixtures,” Industrial and

Engineering Chemistry, 28 (4), pp. 399–402 (1936).

10 3. Lockett, M. J., “Distillation Tray Fundamentals,” Cambridge

Univ. Press, New York, NY (1986).

0

4. Chen, G. X., and K. T. Chuang, “Liquid-Phase Resistance to

0 10 20 30 40 50 60 70 80 90 100 Mass Transfer on Distillation Trays,” Industrial and Engineering

Modified O’Connell ηsection Chemistry Research, 34 (9), pp. 3078–3082 (1995).

5. Chan, H., “Tray Efficiencies for Multicomponent Distillation

p Figure 8. A parity plot of section efficiencies calculated by the modified Columns,” PhD Dissertation, the Univ. of Texas at Austin

O’Connell correlation and the theoretical model shows almost-perfect (May 1983).

agreement.

Article continues on next page

Copyright © 2018 American Institute of Chemical Engineers (AIChE) CEP July 2018 www.aiche.org/cep 29

Reactions and Separations

O’Connell’s empirical correlation is similar to the improves gas dispersion and can therefore increase the

traditional theoretical tray efficiency model approach when interfacial area.

the number of transfer units for the liquid phase and the Finding the reason for the success of O’Connell’s

vapor phase can be assumed to be equal. O’Connell’s use correlation and its connections to traditional theoreti-

of the relative volatility approximates the stripping factor in cal efficiencies justifies its use in distillation applications

the stripping section or its reciprocal in the rectifying sec- while also revealing its limitations without the appropriate

tion. Overall, the outcome of the O’Connell method agrees modifications. CEP

well with a theoretical model using the same number of

parameters, namely a constant of proportionality, c1, and an MARKUS DUSS is a senior technical expert in mass transfer and hydraulics

exponent, x1, associated with the liquid viscosity. of structured and random packing at Sulzer Chemtech, Ltd. (Winterthur,

Switzerland; Email: Markus.Duss@sulzer.com). He has worked with

The impact of liquid viscosity on the section efficiency Sulzer Chemtech as a process engineer for more than 30 years and is

should not be interpreted as representing only the liquid- a co-author of Distillation: Equipment and Processes (Elsevier, 2014).

Duss graduated from the Zürich Univ. of Applied Sciences in Winterthur

side properties. Most distillation systems are gas-side in 1983.

controlled and are well represented by the approach shown

ROSS TAYLOR is the Kodak Distinguished Professor of Chemical Engineering

here. Indeed, the liquid viscosity correlates well with other at Clarkson Univ. (Potsdam, NY; Email: rtaylor@clarkson.edu), where

relevant properties, such as the effective interfacial area he teaches equipment and process design courses. He has held a joint

appointment at the Univ. of Twente in The Netherlands and visiting

appointments at Delft Univ. of Technology, BP Engineering in the U.K.,

Acknowledgments and Shell Global Solutions in Amsterdam. Taylor is an author of Mul-

ticomponent Mass Transfer (Wiley, 1993) and of ChemSep, a software

The authors thank Sulzer Chemtech and Clarkson Univ. for making Markus package for rate-based column modeling. He is one of four authors of

Duss’s sabbatical possible in 2016. This paper is based in part on work car- the distillation chapter in the 8th and 9th editions of Perry’s Chemical

ried out during this sabbatical at Clarkson Univ. Engineers’ Handbook.

30 www.aiche.org/cep July 2018 CEP Copyright © 2018 American Institute of Chemical Engineers (AIChE)

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