Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
( Reaffirmed 1996 )
Indian Standard
SPECIFICATION FOR COPPER
(i%ird Revision)
Fourth Reprint JUNE 1996
UDC 669.3.001.3
0 Copyright 1980
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
lSr191(PartsftoX)-1980
chairam w-%
DB L. R. VAI~PANATH hadian Copper Information Centre, Calcutta
JWlnks
Suar Da-v Kuran AQOAlZWAG Bralco Metal Industries Pvt Ltd,. Bombay
SEE1 v. a. GaDBE ( A&smats)
Saax S. N. BAEIU Chvtituy Metals Rajasthan Pvt Ltd, Jodhpur
Suns N. M. BAF~A ( Al&n&)
Smtr J. NAWWE BEATT Indiau Telephone Industries Ltd, Bangalore
Sasr A. DWAEKADTATH( Akaufs )
Suar V. N. BE~DE Directorate General of Ordnance Factorie:
( Ministry of Defence ), Calcutta
SEBI S. K. MOHAXTY 1 dl&raufc)
Saar S. N. CHAXDA Bengal Ingot Co Ltd, Calcutta
CDB S. K, DAS Directorate of Production & Inspection (Naval ),
Ministry of Defence ( DGI }
SEPI S. C. PAUL ( Alteraaf~~)
SHBI P. Gxtoan Indian Cable Co, Jamshedpur
Suur Tssnosc Smon ( Alhm~+ )
Saax A. K. (;UtrA’ Dire~~t;e~~neraI of Supplies t Disposals,
2
IS : 191( Parts I to X ) - 1980
Indian Standard
SPECIFICATION FOR COPPER
( Third Revision
0. FOREWORD
0.1 This Indian Standard ( Third Revision) was adopted by the Indian
Standards Jnstitution on 23 April 1980, after the draft finalized by the
Copper and Copper Alloys Sectional Committee had been approved by
the Structural and Metals Division Council.
0.2 The second revision of this standard was published in 1967. The
committee responsible for the preparation of this standard felt that differ-
ent types of coppers included in the earlier version of the standard should
be reviewed and classified. While revising IS : 191, it was decided to exclude
grades OF and DHPz because of their limited use, and cover the require-
ments of other types of copper in series of parts to be published as third
revision of IS : 191. Method of sampling of copper refinery shapes for
chemical analysis has also been incorporated in this revised standard, as
Part III. The method is based on ISO/R 1811-1971 ‘Chemical analysis of
copper and copper alloys - Sampling of copper refinery shapes’, published
by the International Organization for Standardization.
0.2.1 This standard is being issued in 10 parts as follows:
Part I Classification of copper
Part II Dimensions and masses of copper refinery shapes
Part III Methods of sampling of copper refinery shapes for chemi-
cal analysis
Part IV Cathode copper
Part V Electrolytic tough pitch copper ( ETP )
Part VI Fire refined high conductivity copper ( FRHC )
Part VII Fire refined tough pitch copper - wrought products and
alloys ( FRTP-1 and PRTP-2 )
Part VIII Phosphorized copper ( DHP)
Part IX Arsenical tough pitch copper ( ATP)
Part X Phosphorus deoxidized arsenical copper ( DPA ).
3
ISr191(PortsItoX)-1980
4
lbrl9i (Pa&)-1980
Indian Standard
SPECIFICATION FOR COPPER
PART I CLASSIFICATION OF’ COPPER
( Third Revision )
1. SCOPB
1.1 This standard ( Part I ) defines various types of coppers and currently
available cast refinery shapes. It includes a table which classifies these
grades of copper indicating the shapes in which these coppers are available.
2 TERlwIuOLoGY
2.0 For the purpose of this standard, the following definitions shall apply.
&l cop*
2.1.1 Copper- For the purpose of this classification, copper containing
not more than 8.5 percent of alloying elements is included in the term
Qopper’.
2.1.2 Tough Pitch CoppGr- Copper, either electrolytically or fire refined,
cast in the form of refinery shapes, containing a controlled amount of
oxygen for the purpose of obtaining a level set in the casting. By extension,
the term is applicable to fabricators’ products made therefrom.
2.1.3 Etectrolytic Co~~sr ( ETP ) -Copper, of any origin, refined by
electrolytic deposition. Usually when this term is used alone, it refers to
electrolytic tough pitch copper. This designation applies to the following.
2.1.3.1 Cathodes, that are the direct products of refining operation.
2.1.3.2 Electrodeposited copper, cast from melted cathodes into
refinery shape, suitable for hot or cold working or both, and by extension,
fabticators’ products made therefrom.
2.1.3.3 Electrodeposited copper, cast into ingot or ingot bar, suitable
for remelting.
2.1.4 Fire-ReJinsd High ConductiviQ Copper ( FRHC) - Copper which, in
the annealed condition, has a minimum electrical conductivity of 100 per-
cent of International Annealed Copper Standard.
5
L-_ ~.~._~~-~_~..-^_~~~. ..^
IS:191 (PartI)-
a) Copper cast in the form of refinery shapes suitable for hot or cold
working or both, and by extension, fabricators’ products made
therefrom ( FRTP-1 ).
b) Ingot or ingot bar suitable for remelting ( FRTP-2 ),
2.2.1 Wire Bar - Refinery shapes for rolling into rod ( and subsequent
drawing into wire ), strip or shape.
6
IS:191 (PartI)-
2.2.3 Cake - Refinery shape for rolling into plate, sheet, strip or shape.
Rectangular in cross section of various sizes. Cast either horizontally or
vertically, from 65 to 1 800 kg or more.
2.2.4 Ingot and Ingot Bar - Refinery shape employed for alloy produc-
tion ( not fabrication ). Both used for remelting. Ingots usually weigh
from 6 to 17 kg and ingot bars from 22 to 36 kg. Both usually notched to
facilitate breaking into smaller pieces.
2.2.5 Cathode - Unmelted flat plate produced by electrolytic refining.
The customary size is about 1 000 mm square and about 13 to 22 mm
thick, weighing up to 130 kg.
3. BASIS OF CLASSIFICATION
3.1 The different refinery shapes currently produced are shown in
Table 1. In each type, the specific coppers are not necessarily available
in a complete range of sizes in the forms shown, nor from any ,one
supplier in all forms.
1. SCOPE
2.1.2 One size of mould shall be used for casting 91 to 105 kg wire
bars. The bottom width of this bar shall be 89 mm, nominal masses being
91 and 102 kg ( set Fig. 1 ).
2.1.2 One size of mould shall be used for casting 109 to 136 kg wire
bars. The bottom width of this bar shall be 102 mm, the nominal masses
being 113, 125 and 136 kg ( see Fig. 2).
2.1.3 All bars shall be 1 372 mm in length. The side draft or taper shall
be 9-5 in 102 mm, that is, 4.8 in 102 mm on each side of the bar. ? he
radius of the corners at the bottom of the bars shall be 16 mm. The end
taper at the bottom shall be 152 mm in overall length and approximately
51 in 305 mm. The end taper of the side shail be approximately 57 in 303
mm and the end of the bar shall be approximately 86 mm in depth at
the point.
9
IS: 191 (PartII)-1990
2.1.4.2 V&idly cast wire bars - The mass and dimensions, and the
permissible tolerances shall be as follows:
Narrow end 92 f 5 mm
Wide end 106 f 5 mm
Length 1 230 mm to 1 375 mm
( taper from end to end )
Mass, Max 113 kg
NOTE - For rod ro!ling purposes, the height of the wire bar should not exceed
108 mm when measured at the high&t point.
2.2.2 Closer tolerances may be agreed to between the supplier and the
purchaser.
2.4 Ingots - Unless otherwise agreed to between the supplier. and the
purchaser, the ingots shall be of the size shown in Fig. 3 and shall have a
nominal mass of 17 kg. If so required by the purchaser, the ingots may be
supplied weighing 6 kg and nbtched in the centre. The ingot bars may
also be supplied with 3 notches and weighing 36 kg. The permissible
variation from the nominal mass of ingots shall be 10 percent.
10
c .__,_.I
__..___._.._.-.--. - ~-
MASS DIXENSIONS,mm
r------------ -e- -7
kg r rl h h, hp h3 b b1 b2 1 1, lr
91 16 38 92 25 305 102 98 89 4.8 1 372 57 152
102 16 38 102 25 305 102 98 89 4.8 1 372 57 152
11
L- .~
--...-._
----.-.___
__
I I
MASS DIXENBIONB,
mm
r---- ------L-- --
kg I rl rg h h, h2 hs b bl b, 1 4 Ia
113 25 16 38 102 25 305 102 111 102 4.8 1 372 57 152
125 25 16 38 111 25 305 102 111 102 4.8 1 372 57 152
136 25 16 38 121 25 305 102 111 102 4.8 1 372 57 152
FIG. 2 COPPER WIRE BARS OF 113, 125 AND 136 kg .F
. -
12 ,;
+ “!
E,
As in the Original Standard, this Page is Intentionally Left Blank
it__. ____.___
__.__- ..-
Indian Standard
SPECIFICATION FOR COPPER
PART III METHODS OF SAMPLING OF COPPER REFINERY
SHAPES FOR CHEMICAL ANALYSIS
( Third Revision)
1. SCOPE
1.1 This standard ( Part III ) covers methods for preparation of sample of
copper refinery shapes for chemical analysis. The shapes covered are wire
bars, billets, cakes, slabs, ingots and ingot bars, and cathodes.
2. CONSIGNMENTS OF LOTS
2.1 For the determination of the copper content, consignments up to a
total mass of about 300 tonnes should be considered as a single lot, provi-
ded that the whole of the consignment is of the same charge and consists
of uniform shapes. Consignments exceeding 300 tonnes in total mass
should be divided into lots of approximately equal size.
2.2 If a consignment conFists of several charges and/or different shapes,
the consignment should be divided into lots according to charges and
shapes. The size ofthe lots depends on the charges and shapes forming
the consignmint concerned and/or on the arrangements made between
the interested parties.
3. PROCEDURE
3.1 Conventional Procedure
3.1.1 For sampling, take three pieces as gross samples from each of the
lots ( charges, shapes ) dccording to 2 unless otherwise agreed to between
the interested parties;
3.1.2 Remove surface contamination, if any, from the three pieces, and
also remove any surface oxide layer from those areas where samples are
to be taken. Drill holes completely through each piece, or, if the pieces
are too thick, drill holes from two opposite sides to the centre. Do not use
lubricants or similar substances. The Fill should be of cemented carbide
or other suitable hard metal*, and should not contain substantial quantities
l For example, bonded tungsten carbide drill or carbide tipped drill.
IS : 191 (Part III ) - I999
3.2.1 Each party should select a sample of three pieces from the consign-
ment or lot to be investigated. Carry out the sampling in the presence of
both parties by drilling five holes approximately 12 mm in diameter, at
points equally distributed between the ends of the pieces. With wire bars,
billets, ingots and ingot bars, these holes should be along a middle line, and
with slabs and cakes, on a diagonal line drawn between opposite corners.
Drill completely through each piece from top to bottom. Remove
skin and any surface dirt. Do not use lubricant and do not force the drill
to such an extent as to cause oxidation of the chips. If oxidized chips are
obtained, reject all the chips from that hole and drill another hole adja-
cent to the original to provide an unoxidized sample. In the case of
sections more than 125 mm in thickness, drill from both top and bottom
for a depth of not less than 50 mm in each direction instead of drilling
completely through each piece, but in all other respects conduct the drilling
as previously described. Cut up the resulting sample, mix and separate
into four equal portions, and plate each in a sealed package, one for the
manufacturer, one for the purchaser, one for a referee, if necessary, and
one as reserve.
16
Is t 191( Part IV ) - 1980
Indian Standard
SPECIFICATION FOR COPPER
PART IV CATHODE COPPER
( Third Revision )
1. SCOPE
1.1 This standard ( Part IV ) covers requirements of cathode copper.
2. SUPPLY OF ,MATERIAL
1 2.1 General requirements for supply of material shall conform to IS : 1387-
1967*.
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I )-1980t shall apply
4. CHEMlCAL COMPOITSION
4.1 The cathode copper shall conform to the requirements of Table 1
when analyzed in accordance with IS : 44U-19642.
TAB= 1 CHEMICAL COMPOSITION
ELEM~ PERCENT
Copper + Silver, Afin 99 90
Bismuth, MUX 0.001
Lead, Max o-005
Total of metallic impurities excluding O-03
silver, Max
NOTE - For special requirements, the limitation of other individual impurities
may be subject to agreement between the purchaser and the supplier.
5. PHYSICAL CONDITION
5.1 Cathodes shall be tough, dense, and free from loose or brittle lumps,
modules and other undue outgrowth. The surface shall be free from slime
and copper sulphate.
*General requirements for the supply of metallurgical materials (Jrrt rctiri~on).
*Specification for copper: Part I Classification of copper ( krd retSon. )
#Methods of chemical analysis of copper (rtiti ).
17
L_.__.~-_-..__l- --... .
II)r191(PartIv)-1999
5.2 Fuli-size or cut to size may be supplied as agreed to between the sup
plier and the purchaser.
8. MARKING
8.1 All cathodes shall be stamped with the manufacturer’s trade mark and
furnace charge or other identifying number.
8.1.1 The material may also be marked with the IS1 Certificatioc Mark.
NOTE -The use of the ISI Certification Mark is governed by the provisions of
the Indian Standards Institution ( Certification Marks) Act and the Rules and
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveys the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testing and
quality control which is devised and supervised by IS1 and operated by the
producer. IS1 marked products are also continuously checked by IS1 for conformity
to that standard as a further safeguard. Details of conditions under which a licence
for the use of the IS1 Certification Mark may be granted to manufacturers or
processors, may be obtained from the Indian Standards Institution.
*Specification for copper: Part III Methods of sampling of copper refinery shapes
for chemical analysis ( t&d feoision ).
18
A.- -.. ____,__ .._-I ..-....- _.
.-I- __-
IS:191 (PartV)-1980
Indian Standard
SPECIFICATION FOR COPPER
PART V ELECTROLYTIC TOUGH PITCH COPPER (ETP)
( Third Revision )
1. SCOPE
1.1 This standard ( part V) covers requirements of electrolytic tough
pitch copper ( ETP) in the form of wire bars, cakes, slabs, billets, ingots
and ingot bars.
2. SUPPLY OF MATERIAL
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS: 191
( Part I )-1980t shall apply.
4. CHEMICAL COMPOSITION
4.1 The copper in all shapes shall conform to the requirements of Table 1
when analyzed in accordance with IS : &O-1964$. The method for
determination of oxygen shall be as agreed to between the supplier and
the purchaser,
ELEMENT PERCENT
19
IS : 191 ( Part V ) - 1986
5. PHYSICAL DEFECTS
5.1 Shapes intended for fabrication shall be substantially free from shrink
holes, cold sets, pits, sloping edges, concave tops, and similar defects in set
or casting. This requirement shall not apply to ingots or ingot bars, in
which physical defects are of no consequence.
7. RESISTiVITY
*Specification for copper: Part II Dimensions and ma5331of copper refinery shaper
( third revision ).
tMethods of test for resistance of metallic electrical resistance material.
20
IS : 191 ( Part v ) - 1980
*Specification for copper: Part III Methods of sampling of copper refinery shapes
for chemical analysis (third r&ion ).
21
As in the Original Standard, this Page is Intentionally Left Blank
IS:191 (PartVI)-1980
Indian Standard
SPECIFICATION FOR COPPER
PART VI FIRE REFINED HIGH CONDUCTIVITY
COPPER (FRHC)
( Third Revision)
1. SCOPE
2. SUPPLY OF MATERIAL
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I )-1980t shall apply.
4. CHEMICAL COMPOSITION
4.1 The copper in all shapes shall conform to the requirements of Table 1
when analyzed in accordance with IS : 440-1964:.
23
I,,
-_. .-
5. PHYSICAL DEFECTS
5.1 Shapes intended for fabrication shall be substantially free from shrink
holes, cold sets, pits, sloppy edges, concave tops, and similar defects in set
or casting. This requirement shall not apply to ingots or ingot bars, in
which physical defects are of no consequence.
6. SIZE, MASS AND DIMENSION
6.1 Size, mass and dimensions of different copper refinery shapes shall be
in accordance with IS : 191 (Part II)-1980*.
7. RESISTIVITY
7.1 Copper shall have resistivity at a temperature of 20°C ( annealed) not
exceeding the values given in Table 2.
24
IS I 191 ( Part VI ) - 1980
9.1.1 The material may also be marked with the IS1 Certification Mark,
NOTE -The use of the IS1 Certification Mark is governed by the provisions of
the Indian Standards Institution ( Certification Marks ) Act and the Rules and
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveya the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testiug and
uality control which is devised and supervised by IS1 and operated by the pro-
zl cer. IS1 marked products are also continuously checked by IS1 for conformity to
that standard as a further safeguard. Detaib of conditions under which a licence
for the use of the IS1 Certification Mark may be granted to manufacturers or
processors, may be obtained from the Irullan Star&s& Institution,
*Specification for copper: Part III Methods of sampling of copper refinery shapes
for chemical analysis ( &rd reri&~).
25
As in the Original Standard, this Page is Intentionally Left Blank
L.___..__ .I. ----_- _
Indian Standard
SPECIFICATION FOR COPPER
PART VII FIRE REFINED TOUGH PITCH COPPER -
WROUGHT PRODUCTS AND ALLOYS
(FRTP-1 AND FRTP-2)
( Third Revision)
1. SCOPE
1.1 This standard ( Part VII ) covers requirements of fire refined tough
pitch copper for fabricating into wrought products excluding those inten-
ded for electrical purposes. This copper could be used for alloying in cast
and wrought alloys.
2. SUPPLY OF MATERIAL
2.1 General requirements for supply of material shall conform to IS :
1387-1967*.
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I )-1980t shall apply.
4. CHEMICAL COMPOSITION
4.1 The copper in all shapes shall conform to the requirements of Table 1
when analyzed in accordance with IS : 440-1964$. l’he method for deter-
mination of oxygen shall be as agreed to between the supplier and
purchaser.
5. PHYSICAL DEFECTS
5.1 Shapes intended for fabrication shall be substantially free from shrink
holes, cold sets, pits, sloppy edges, concave tops, and similar defects in
set or casting. This requirement shall not apply to ingots or ingot bars, in
which physical defects are of no consequence.
27
4S.r: 191; (4Part VIE) -i 1980
8. MARKING
8.1 All shapes intended for fabrication shall be stamped with the manufac-
turer’s trade-mark and furnace charge or other identifying number. Ingots
and ingot bars shall have a brand stamped or cast in.
8.1.1 Each piece may also be marked with the ISI Certification Mark.
NOTE The use of the IS1 Certification
- Mark is governed by the provisions of
the Indian Standards Institution ( Certification Marks ) Act and the Rules and
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveys the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testing and
quality control which is devised and supervised by IS1 and operated by the
producer. IS1 marked products are also continuously checked by ISI for conformity
to that standard as a further safeguard. Details of conditions under which a licence
for the use of the IS1 Certification Mark may be granted to manufacturers or
processors, may be obtained from the Indian Standards Institution.
28
lS:191(PutwH)-isro
Indian Standard
SPECIFICATION FOR COPPER
PART WI PHOSPHORIZED COPPER ( DHP)
( Third Revision )
1. SCOPE.
1.1 This standard ( Part VIII ) covers requirements of high conductivity
fire refined copper de-oxidized with phosphorus in the form of wire bars,
billets and cakes.
2. SUPPLY OF MATERIAL
2.1 General requirements for supply of material shall conform to
IS : 1387-1967*.
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I )-19807 shall apply.
4. CHEMICAL COMPOSITION
4.1 The copped in all shapes shall conform to the requirements of
Table 1 when analyzed in accordance with IS : 440 - 19641.
5. SIZE, MASS AND DIMENSION
5.1 Size, mass and dimensions of different copper refinery shapes shall
be in accordance with IS : 191 ( Part II )-19805.
6. EMBRITTLEMENT TEST
6.1 The edges of the test pieces may be carefully rounded and smoo&e-
ned longitudinally. After being exposed to an atmosphere of hydrogen
for 30 minutes at 800 to 875°C and subsequently cooled in the container
itself (out of contact with air ), the test pieces shall be subjected to a
close bend test as described in 6.1.1 to 6.1.3.
*General requirements for the supply of metallurgical materials (i;rst rcuision).
tspecification for copper: Part I Classification of copper ( fhird revision).
Methods of chemical analysis of copper ( revised).
t S ecification for copper: Part II Dimensions and masses of copper refinery shaw
( t&r&vision ).
29
ISr191 (PartVIII)-1986
ELEMENT PERCENT
Copper + Silver, Min 99.80
Phosphorus 0’015-0~10
Antimony, Max 0.005
Arsenic, Max O-05
Bismuth, Max o-003
Iron, Max 0.03
Lead, Max o-01
Nickel, Max 0.10
Selenium + Tellurium, Mow 0’02
Tellurium, Mar o-01
Tin, Max 0.01
Total of impurities excluding silver, 0.06
nickel, arsenic and phosphorus, Max
6.1.2 The convex surface of the bend portion shall not reveal any
cracks, openings or porosity.
6.1.3 For the purpose of this test, one piece of copper shall be
selected from each hundred, or part thereof in the consignment or order,
and the test piece taken from the pieces so selected.
7. PHYSICAL DEFECTS
7.1 All shapes shall be substantially free of shrink holes, cold sets, pits,
sloppy’ edges, and similar defects.
30
1s : 191 ( Part VIII ) - 1984
9. ,MARKING
9.1 Each piece shall be marked with the manufacturer’s trade-mark and
lot number for identification.
9.1.1 The material may also be marked with the IS1 Certification
Mark.
NOTE - ‘The use of the IS1 Certification Mark is governed by the provisions of
the Indian Standards Institution ( Certification Marks) Act and the Rules and
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveys the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testing and
quality control which is devised and supervised by IS1 and operated by the
producer. IS1 marked products are also continuously checked by IS1 for conformity
to that standard as a further safeguard. Details of conditions under which a licence
for the use of the IS1 Certification Mark may be granted to manufacturers or
processors, may be obtained from the Indian Standards Institution.
*Specification for copper : III Method of sampling of copper refinery shapes for
chemical apalysis ( third revision ).
31
As in the Original Standard, this Page is Intentionally Left Blank
its:191 (Part=)-1980
Indian Standard
SPECIFICATION FOR COPPER
PART IX ARSENICAL TOUGH PITCH COPPER (ATP)
( Third Revision )
1. SCOPE
1.1 This standard (Part IX) covers r+ments of arsenical tough #oh
copper in the form of billets and ca&es.
2 SUPPLY OF MATERIAL
21 General requirements for supply of material shall conform to IS :
1387-K&7*.
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I ) - 198Ot shall apply.
4. CHEMICAL COMPOSITION
4.1 The material shall conform to the requirements of Table 1 when
analyzed in accordance with IS : 440-1964:. The method for the
determination of oxygen shall be as agreed to between the supplier and
the purchaser.
TABLE 1 CHEMECAL eOMPOSITION
ELEWDIT hRCENT
33
5. SIZE, MASS AND DIMENSION
5.1 Size, mass and dimensions of different copper refinery shapes shall be
in accordance with IS : 191 ( Part II )-1980*.
7. MARRING
7.1 The shapes intended for fabrication shall be stamped or cast in
with the manufacturer’s trade-mark and furnace charge or other identify-
ing number.
7.1.1 The material may also be marked with the IS1 Certification
Mark.
NOTE- The use of the IS1 Certification Mark is governed by the provisions of
the Indian Standards Institution ( Certification Mark ) Act and the Ruler and *
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveys the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testing and
quality control which is devised and supervised by IS1 and operated by the
producer. IS1 marked products are also continuously checked by IS1 for conformity
to that standard as a further safeguard. Details of conditions under 1 hich a licence
for the use of the IS1 Certification Marks may be granted to manufacturer or
processors, may be obtained from the Indian Standards Institution.
*Specification for copper: Part II Dimensions and masses of copper refinery shapes
( lird revision) .
tSpecification for copper: Part III Methods of sampling of copper refinery shapes
for chemical analysis ( thud r&&m).
34
L.__._.._._.;_--._.._. ~~_~~~~_~.___
Indian Standard
SPECIFICATION FOR COPPER
PART X PHOSPHORUS DEOXIDIZED ARSENICAL
COPPER (DPA )
( Third Revision )
1. SCOPE
1.1 This standard ( Part X ) covers requirements of phosphorus deoxidized
arsenical copper in the form of billet.
2. SUPPLY OF MATERIAL
2.1 General requirements for supply of material shall conform to IS :
1387-1967*
3. TERMINOLOGY
3.1 For the purpose of this standard, the definitions given in IS : 191
( Part I ) - 1980t shall apply.
4. CHEMICAL COMPOSITION
4.1 The material shall conform to the requirements of Table 1 when
analyzed in accordance with IS : 440-1964$.
5. SIZF, MASS AND DIMENSION
3.1 Size, mass and dimensions of different copper refinery shapes shall be
in accordance with IS : 191 (Part II )-19803.
6. EMBRITTLEMENT TEST
6.1 The edges of the test pieces may be carefully founded and smoothened
longitudinally. After being exposed to an atmosphere of hydrogen for 30
minutes at 800 to 875°C and subsequently cooled in the container itself
( out of contact with air ), the test pieces shall be subjected to a close bend
test as described in 6.1-l to 6.1.3.
35
TABLE 1 CHEMICAL COMposiTION
( c1auss 4.1 )
ELEMENT PEBCENT
Copper + Silver, Min 99-20
Phosphorus ~015-0~10
Arsenic 0.20-O-50
Antimony, Max O-01
Bismuth, A& O*OOS
ISQQ, Mnr o-03
-,- O-010
Ni&d, dfsx o-15
?khaium ad Tdhwium, Max O-02
Tellurium, Afuz PO1
T-r, Mu O-01
T&al of all impurities excluding silver, nickel, O-07
arsenic and phorphorus, MS
,__+S,
A--------C B
FIG. 1 CLOSE BEND TEST
6.1.2 The convex surface of the bend portion shall not reveal any
cracks, openings or porosity.
6.1.3 For the purpose of this test, one piece of copper shall be selected
from each hundred, or part thereof in the consignment or order, and the
test piece taken from the pieces so selected,
7. PHYSICAL DEFECTS
7.1Billet shall be substantially free of shrink holes, cold sets, pits, sloppy
edges, and similar defects.
8. SAMPLING FOR CHEMICAL ANALYSIS
8.1 Sampling shall be done in accordance with IS : 191 ( Part )-19808.
36
L.___._____ _ __.___
_-._,_---.-.._
9. MARKING
9.1 Each billet shall be marked with the manufacturer’s trade-mark and
lot number for identification.
9.1.1 The material may also be marked with the IS1 Certification
Mark.
NOTE - The use of the IS1 Certification Mark is governed by the provisions of
the Indian Standards Institution ( Certification Marks ) Act and the Rules and
Regulations made thereunder. The IS1 Mark on products covered by an Indian
Standard conveys the assurance that they have been produced to comply with the
requirements of that standard under a well-defined system of inspection, testing and
quality control which is devised and supervised by IS1 and operated by the
producer. IS1 marked products are also conti.nuously checked by IS1 for conformity 1
to that standard as a further safeguard. Details of conditions under which a licence
for the use of the IS1 Certification Mark may be granted to manufacturera or
processors, may be obtained from the Indian Standards Institution.
37
INDIAN STANDARDS
ON
IS :
28-1975 Phosphor bronze ingots and castings ( third rcoision )
191 ( Parts I to X)-1980 Specification for copper ( third r&ion )
288-1960 Copper rods for boiler stay bolts and rivets ( rsuiscd )
613-1964 Copper rods for electrical purposes ( revised)
1264-1965 Brass ingots for gravity die castings and brass gravity die castings ( includ
ing naval brass ) ( revised)
1545-1969 Solid-drawn copper alloy tubes (first r&ion )
1550-1967 Copper sheet and strip for utensils and for general purposes (Jirst revision)
1897-1971 Copper -strip for electrical purposes (Jirst revision )
1972-1977 Copper plate, sheet and strip for industrial purposes (jirst revision )
2501-1972 Copper tubes for general engineering purposes {first revision )
2826-1980 Dimensions for wrought copper and copper alloy rods and bars ( second
reuision )
3051-1965 Dimensions for wrought copper and copper alloys plate
3052-1974 Dimensions for wrought copper and copper alloys, sheet, strip and foil (for
general engineering purposes ) (firs; reuision )
3057-1965 Copper sheets for photo process engravings
3167-1965 Cap copper alloy strip
3288 ( Part I )-1973 Glossary of terms for copper and copper alloys: Part I Cast form
and wrought form ( main types ) (jirsf rssision )
3331-1977 Copper and brass strips/foils for radiator cores (first revision)
3487-1966 Copper strip for foil for manufacture of copper gaskets and copper washers
and eyelets
4171-1967 Copper rods for general engineering purposes
4412-1967 Copper wires for general engineering purposes
4519-1977 Dimensions for copper commutator bars (Jirs: rrsirion )
5053-1969 Dimensions for wrought copper and copper alloy rods for fasteners
5493-l 969 Dimensions for wrought copper and copper alloy tubes
5743-1970 Copper master alloys
5744-1970 Copper alloy screwed ferrules for condenser, evaporator, heater and cooler
tubes
5885-1977 Copper commutator bar (first revision)
6912-1973 Copper and copper alloy forgings
8328-1977 Free cutting copper bars, rods and sections
8362-1977 Copper and copper alloy rolled plates for condensers and heat exchangers
8365-1977 Cadmium-copper and chromium-coppqr electrodes
8631-1977 Copper base alloys for marine propellers
8859-1978 Cast copper tuyere
BUREAU OF INDIAN STANDARDS
Headquarters :
Manak Bhavan, 9 Bahadur Shah Zafar Marg, NEW DELHI 110002
Telephones : 331 01 31
331 13 75
371 94 02
Telegrams : Manaksanstha
(Common to all Offices)
Branch Offices :
‘Pushpak’, Nurmohamed Shaikh Marg, Khanpur, AHMADABAD 380001 301348
SPeenya Industrial Area, 1st Stage, Bangalore-Tumkur Road, 839 49 55
BANGALORE 560058
Gangotri Complex, 5th Floor, Bhadbhada Road, T.T. Nagar, BHOPAL 462003 554021
Plot No. 21 Satyanagar, BHUBANESHWAR 751007 40 36 27
Kalaikathir Building, 6/48 Avanashi Road, COIMBATORE 641037 21 01 41
Plot No. 43, Sector 16 A, Mathura Road, FARIDABAD 121001 8-28 88 01
Savitn Complex, 116 G.T. Road, GHAZIABAD 201001 8-71 19 96
53/5 Ward N9.29, R.G. Barua Road, 5th By-lane, GUWAHATI 781003 541137
5-8-56C L.N. Gupta Marg, Nampally Station Road, HYDERABAD 500001 201083
R 14, Yudhister Marg, C Scheme, JAIPUR 302005 381374
1171418 B Sarvodaya Nagar, KANPUR 206005 21 68 76
Seth Bhawan, 2nd Floor, Behind Leela Cinema, Naval Kishore Road, 238923
LUCKNOW 226001
Patliputra Industrial Estate, PATNA 800013 262305
T.C. No. 14/1421, University P.O., Palayam, THIRUVANANTHAPURAM 695034 621 17