Narayana IIT Academy

INDIA
SEC: SR-IIT-IZ(L25) RPTA-5 DATE: 23-09-18
TIME: 09.00 AM TO 12.00 PM MAX. MARKS:180

Name of the Student: ___________________ H.T. NO:

2014_PAPER-II

PHYSICS - KEY
1 2 3 4 5 6 7 8 9 10
C D A A D D A D A A
11 12 13 14 15 16 17 18 19 20
B D B A C B A C B C
CHEMISTRY- KEY
21 22 23 24 25 26 27 28 29 30
C D C A D B A C D C
31 32 33 34 35 36 37 38 39 40
B C B A B A A A A A

MATHS - KEY
41 42 43 44 45 46 47 48 49 50
B C B B A D A D C C
51 52 53 54 55 56 57 58 59 60
A C A D B B A C D B

PHYSICS SOLUTIONS :

1. Let u → vel. Of shell relative to gun

 → recoil vel. Of gun
V → achial vel. Of shell
V cos = u cos  -  ------------ 1
V sin  = u sin  -------------2
Tan  = u sin  -------------3
u cos   
From LCLM mV cos  =M 
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M [ u cos  -  ] = M 
 = m u cos  ------------ 4
M m
m
From the above eqns we get tan  = (1  ) tan 
M
2. Let L1 & L 2 natural lengths of lower and upper springs.
2mg
Elong atran in upper spring =
k
mg
Elong atran in lower spring =
k
2mg mg mg
 L1   L2   L2  L1 
k k k
L2  L1 mg
When the string is cut from mass ‘2’ distance of C.M = = .
3 3k
3. m  10 dx
0  1 xdm
hcm  1
0  dm

P.E = mghcm
4 v0
4. For left ball horizontal vel = v 0 cos  
5
4 v0 4v
For right ball horizontal vel = cos  2  0
3 5
4 v0 4v
From LCLM m( )  m ( 0 )  2 mV H
5 5
 VH  O

5. Distance of null point from ‘M’

M 8R
r=  2R
M  9M
from energy conservation
mv 2 GM 9GM GM 9GM
 m[  ]  o  m[  ]
2 R 7R 2R 6R
4GM
On solving we get V 
7R
6. x  ( so  op )  sp  2m
2 2
 x  2   /2
N 8

Result ant intensity I  I 0  I 0  2 I 0COS  2 I 0
2
7. Let T is time of flight
T
Time to reach the wall =
4
3T
 remaining time =
4
Horizontal distance from the wall after collision
3T 3eR
 eV0 cos  ( ) (V0 cos  T  R )
4 4
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R 3eR
Distance from A = (  )
4 4
8. distance = Vcm .t
4 K .2 K 4 K
9. Equivalent K ef  
6K 3
ket
Arrangemt w 
m
10. for 2nd min A  3
For 3rd max A  6
 phase difference should be in between these two hence  / 3
11. When Z   D    for o1 y  
2d 2 4
1 2
2
 I  2 I 0 cos ( )  2 I 0
2
12. intensity at ‘O’ os zero if  

2 2
2 2 ND
=    z   
 2 d
n 1 T
13. n T   100   100
n 2 T
1 h  l
14. n   100   100
l n l
17. P) 60(1   )  100    3 m / s
8
1
Q) 80(1   )  80    m / s
2
R)  60(1   )  80(1   )  20 v  0
1
  m/s
8
S) 80(1  v1 )  20v1  150
4
1 17
  m/s
40
18. V  2gh

R = v  2 H  2 gh 2 H  2 h ( H )
g g
20. In the 1 orbit K.E. = G M m
st
2R
GM m
P.E. =
R
GMm
T.E. = 
2R
nd GMm
In the 2 orbit K.E. =
4R
GM m
T.E. =
4R
GM m
P.E. =
2R
CHEMISTRY SOLUTIONS
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21. no of GEW of CaCO3  no of GEW.s of MgNO3  no of H 2 SO4
x 2 x 2
 
50 4 49

x  1.78
22. let ‘A’ be the area of cross section of cylinder then
P1  Pgas  PHg  76  76  152cmHg
V1  76  Acm3 P2  Pgas  PHg 76 38 114
T1  300k V2  114  Acm 3
T2 
PV PV
1 1
 2 2  T2  337.5k  64.5o C
T1 T2
1 x
23. for second order t 
k a a  x
t1 a2 x1  a2  x2 
 
t2 a1 x2  a1  x1 
t1  10 min a1  0.08, a1  x1  0.08  0.04  0.04
t2  a2  0.04 a2  x2  0.04  0.01  0.03
K forward
24. 
 NH 4  OH 
NH 3  H 2O 
 K backword

K forward
Here K base  NH 3  
K backward
Kw 10 14 K
kw  ka  kb  kb   4
 forward10
K a 5.6 10 3.4 10

 K forwoard  6.07 105 L mol 1 sec 1

25. a,b) 1st law of thermodynamics

c) dQ  du  pdv
dQ  TdS
 Tds  du  pdv
d) H  U  PV , G  H  Ts
 G  U  PV  TS
dG  dU  PdV  VDP  Tds  sdT
but dU  Tds  pdv
 dG  Tds  pdv
 dG  Tds  pdv  pdv  vdp  Tds  sdT
dG  VdP  sdT
rNa 
26.  0.55  rNa   0.55Cl 1
rCl 1
rNa  rNa   rCl 
 1  0.55  1   1.55
rCl  rCl 1

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rNa  rk 1 1 rk  1
 0.74    1

rk 1 rNa 1 0.24 0.55rCl 0.74

rk  0.55
1

rCl 0.74
rK  0.55 r   rCl 1 0.55
1   k  1
rCl 1 0.74 rCl 1 0.74

rk   rCl 1 1.29

rCl  0.74

rk   rCl  1.29
  1.125
rNa   rCl 1 0.74  1.55

98%  1.8 10 49% 1.2  10

28. V   360
98 98
49 12  360
V  120ml
98 18
1
29. N 2 g   O2 g   N 2  O  g  H emf  8  KJ / M
2

H theoritical  BER  BEP  170 KJ / mol

Resonance energy = H exp  H thew  82  170  88KJ / mol

2
30. X  s   A g   2 B g  ; K P 1  x  2 x  2 y 

xdissociates x 2x  2 y

2
Y s   C g   2 B g  K p2  y  2 x  2 y 

Ydissociates Y 2 x  2 y
2
k p1 x  2x  2 y  9 103 x
 2
 3
  2  x  2y
k p2 y 2x  2y  4.5 10 y

x
y
2

2 2
kp1  x  2 x  2 y   x  2 x  x   9 x3  9 10 3

 x  0.1 y  0.05
Ptotal  PA  PB  PC  x  2 x  2 y  y  3  x  y   3  0.15   0.45atm
W
31. PV  RT
M

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MPV 18  31.824 10
vapourW    0.303g vapour
RT 0.0821 760  303
0.303
% of water vapourised  100  15  1%
2
WRT 2  0.0821  303  760
32. V   65.92
MP 18  31.824
33&34. For isothermal process & 34
P1
S1  nRpn
P2
1
 2  8.314  2.303log  11.52 J / K
2
isobasic process
T2  5R 
S 2  nCPln CP  2 
T1
5 400
 2   8.314  2.303log
2 300

 11.96 J / K
for cyclic process S  S1  S2  S3  0

 11.52  11.96  S 3  0
 S3  0.44 J / K
35&36.
Zn 2  2 H 2 O  Zn  OH  2  2 H 
1 O O
1   2
2
 zn  OH 2   H  
kh 
 Zn 2 
2
ch   2ch 
kh   4c 2 h 3 1  h  1
c 1  h 

 zn 2   0H 
kb 
ZN  OH  2
2
 2n  OH 2   H    Zn   OH 2 
consider kb  kb   
 Zn 2   Zn  OH  2 

2 2
  H   OH  

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kl  kb  k w2

kw2
kh 
kb
kw 2
 4c 2 h3 
kb
kw2
h3   10 11
4 c 2 kb

h 3  10 11

h 3  10  1012

1/3
h  10 10 12   2.15  10 4

 H    2ch  2 103  2  5 104  4.3 10 7

p H   log 4.3 107  7  log 4.3  7  0.63  6.37

37. DG = vdp-sdT

MATHEMATICS SOLUTIONS
41. 1,2,3,4,5……….n and erased number is x
n (n  1)
n
2 7
 35
n 1 17
1  n  n   n   n  1
n (n  1) n(n  1) n (n  1)
n n 1
 2  2  2
n 1 n 1 n 1
n 7 2
  35 
2 17 n  1
n 7 n
  35    1
2 17 2
 n=69 w 70 , n=69 , x=7
42.
(4 cos 2 x  1)(cos x)  0
1
cos x   ix  cos x 21
2
 2 , 4 , 6 ......100 (100 L3 L101 )
50 51
Am = ( )  51
50
43.
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3 2
44. x  sn  px  2  1 p1 , r1
x 3  sn 2  px  r  0, 1 p1 , r2
2 x 2  r   0, 1  e1 20
r1  5, r2  7
r1  r2  12
45. Formula

1   1 
46. 4 2a  2 a 6 2  648
9 3   4 9
8 3  648
 2  81,   9
47.
ppT  I , 5  A
q 2.x  pA20 x pT    A20 x  A

2R
48. sin B sin c  2 R cos B cos C
3
1
 atBate
3
49. Let the be ln+ny+n=0
3 3
l( )  m( )n 0
 1 t 1
lt 3  mt 2  nt  3(m  n)  0
m n 3m  n
a bc  , ab  bc  ca  , cos 
e l l
2 a 2  cos 11
50. Tan  m  
as 2
a 2  b 2  al  a  b  1  0
( a  b ) 2  ( a  1) 2  (b  1) 2  0
a=b=1
5a+6b=11=2m
1
ABC  DER
51. 4
52. Find S and R
53. Draw the diagram check the values
54.

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a  b  c  25
2c  2  b, c 2  186
c  12, 24
b8
a5
55. ab  bc  ca  196
56. abc=480
57.
A    , c  B   0, b  , a 2  b 2  12
a b 2
A) x  , y  , x2  y 2 
2 2 4
2 2
B)0   0, c  , n  y  0
ab ab
C) x  ,y ,x  y
abl abl
 b l2
D) x  , y  , x 2  y 2 
3 3 9
58.
r
A) cos A  cos B  cos C  1  , a  b  2 r  R
R
1 n M
B)sin C  ,sin B  ,sin A 
a a c
substitute we get a  b  c
C ) R  b 2  sin C cos  c 2 B cis is 
b 2 cos  c 2 sec s
abc
bc  csc c css  
A  B  900
2 R  sin A  SinB   ab
59.
A) 4 s   2881  c  c1 , k  4
B) 2 r 2  d 2  5
C ) a1a2  b1b2 , k  8
R1  R2  R3
D) is area it is an equillataral triangle
R
9
R1  R2  R3 ,
12
 n  2  n  1 18.17
60) A) A    153
2 2
B) equation P and , we set four terms
C) Rational
 A  100 
C ) tan    4
 LCM of p , q   24 
irrational terms  101  4  9
12
 1 2
x  y  1, 1     212
 3 3

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