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1 AITS-FT-X (Paper-2)-PCM-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – X
PAPER-2

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. B 24. C 47. B
ALL INDIA TEST SERIES

2. C 25. C 48. C

3. C 26. C 49. A

4. A, C 27. A, B, D 50. A, C, D

5. A, C, D 28. A, B, C 51. B, C

6. A, C, D 29. A, B, C, D 52. A, C, D

7. A, C 30. A, B, D 53. A, D

8. B, C 31. B, D 54. A, B, C

9. A 32. A 55. D

10. C 33. B 56. A

11. 5 34. 2 57. 4

12. 6 35. 4 58. 9

13. 6 36. 1 59. 4

14. 2 37. 3 60. 3

15. 4 38. 4 61. 5

16. 6 39. 2 62. 1

17. 8 40. 0 63. 1

18. 4 41. 5 64. 4

19. 4 42. 7 65. 6

20. 4 43. 2 66. 5

21. 00001.50 44. 45123.00 67. 00000.70

22. 00011.15 45. 31536.20 68. 00016.40

23. 00000.25 46. 00000.55 69. 00000.50

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A

1. gequator   0.9  gpoles


 gpole  2R   0.9  gpole
g
 2R 
10
g 2gR v
Peripheral velocity on equator v  R  R   e
10R 20 2 5

2. The current distribution is equivalent to three current


carrying loops as shown in the figure.

3. When the rod moves towards left with I


velocity v and has displacement x towards ×××××××××××××××
left from mean position ×××××××××××××××
  B v × × × × × × × × × × × × × × IB
×
q
q  C  CBv × × × × × × × × × × × × × × ×
C
dq dv ×
+q × × × × × × × × × × × ×
kx × K
×
I  CB ×××××××××××××××
dt dt
× × × × × × × ×v× × × × × × ×
dv
(IB  kx)  m ×××××××××××××××
dt
 dv  dv Mean position
   CB2  2  kx   m
 dt  dt
dv
  m  CB2  2   kx
dt
k 2k
  
m  CB2 2 3m

4. When   tan , the particle will remain at rest on the mgcos

wedge and force exerted by it on the wedge will be equal mgsin


to mg in the vertically downward direction and wedge will
remain at rest. When  < tan  the particle will slide down
the wedge and force exerted by it on wedge will be as M
shown.

The wedge will topple if,
/3 O
 0  0
Mg
 mgcos  tan  sin   mgcos  tan  cos 


Mg  0
3

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3 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

M
 m
3 sin   sin    cos  

5. From conservation of energy


q 1 qR

20

4R2  x 2  R2  x 2  mv 2 
2

20
q
 v
m 0

R  R2  x 2  4R2  x 2 
Welectric force  U  q  Vf  Vi 
q

20

R  R2  x 2  4R2  x 2 
qE q x  1 1 
a    
m m 20  R  x
2 2
4R  x 2
2

qx
 (since x << R)
40mR
q
 
40mR
1 q
f
2 40mR

6. for circular orbit of satellite


U
E    K   dE  dK
2
  kv  vdt  mvdv
V
dv kv m f dv

dt m
  dt   k Vi v
m  vf  m GM / R m
 t ln    ln  ln2
k  vi  k GM / 4R k
GMm  GmM  3 gR2m 3
Wg  Ui  Uf    =  mgR
4R  R  4 R 4
1 1  GM GM 
Wg  Wr 
2
 
m v 2f  v12  m 
2  R

4R 
3 3 3
 mgR  Wr  mgR  Wr  mgR
4 8 8

7. The block will start moving


When F > mg i.e. F > 10 N
 t 1s
The velocity of block is maximum when F  mg  0
i.e. at t = 5s
Net impulse = change in momentum
1 1
 6  30  2 10  1  10  4  m v max
2 2
 v max  20m / s

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 4

From t  1s to t  6s
1
 30  6  5  10  5  2v
2
35
 v m/s
2

8. Let velocity of centre of mass of each dumbbell be VCM and angular


vCM
velocity  as shown. 
     
 VCM       VCM 
v  v1 2  2
Since 2 1    1
u1  u2 u   u 
 2 v CM    2u …(i) 
Let the dumbbells exert average impulsive force N on each other vCM
during collision.
Nt  2m  VCM  u 
 m 2
N t
 
2 2
 2
  …(ii)
2  VCM  u 
From equation (1) & (ii)
2u


m g
9. 2g  mv1  v1 
2 2
1 g
mg(1  cos )  m ( is angular displacement of the bob when it comes to rest)
2 2
3
 cos  
4
When the bob moves in horizontal circle
g 4g
 
 cos  3
4g 7 7g
v  r   sin   
3 4 12
7g 7g
mv Q  2m  vQ 
12 3

10. Height of the bob when string slacks


 5
h    (1  cos )    
4 4
2h 5
Time t  
g 2g

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5 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

SECTION – C

11.  sin   1 sin90


1
sin  

1 1
 tan     e x /2d
2
 1 1  e x /d  1
dy
 e  x / 2d
dx

 y  2d 1  e x / 2d 
At B, y = d
50
 x  2d n2   0.7  5m
7

12. For the wedge Nsin 30  Ma …(i)


The acceleration of block perpendicular to the inclined plane is asin30°
 mgsin60  N  ma sin30 …(ii)
The net force on the block perpendicular to its direction of motion w.r.t ground should be zero.
 Ncos30  mgsin30 …(iii)
 N putting the value of N in equation (i) and (ii)
a
 mgtan30  Ma  M
…(iv)
mgsin 60  mgtan30  ma sin30
…(v)
Equating the value of a in the equation (iv) and (v) 60°
30°
m
 2  m  6kg
M

w
w A    x  g  Ag
13. a 5
w 
A
5
v 
 5x 
0 vdv  0  4    gdx
 v  3g  3  1.2  10  6 m / s

14. For refraction at first surface of the lens,


4
1.5 
1.5 4 / 3 3
 
60 u 60
 u = 48 cm
If the object is placed h cm above the water surface, after refraction at the water surface its image
4h
will be formed at distance from the surface
3
4h 27
  30  48  h  cm
3 2

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 6

15. Induced current in resistor R


2Brv
I
R
I
Magnetic force on the ring Fm  2  2r  B
2
4B2r 2 v

R
When the ring attains terminal velocity
F  0
4B 2r 2 v
 mg  0
R
mgR
 v
4B2r 2

16. Since the loop is in equilibrium    0


  
  2g  sin    2 gsin  ˆj  I 2 (  cos  ˆi  sin k)
ˆ  B (iˆ  k)
0
ˆ =0
 2 
6g
 B0 
7I

17. 
k  0  2 k    0 
 k  2 0   0
 0 10 1
 
 0 20 2
0 30
 k  20  
2 2
4 3 0
 2

3R  z  1 2

8
 z 1
9  0R

mv 2mK max
18. r 
qB qB
q2B2r 2
 K max 
2m
Putting the values of q, B, r and m
Kmax = 2 eV
Energy of emitted photon
1 1 
h = 13.6  3 2    eV = 5.95 eV
 9 16 
h =  + kmax
  = 3.95 eV  4 eV

19. a = 4t
At t = 1 sec, a = 4 = s g
 S = 0.4

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7 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

dv
 4t   k g (where v = velocity of block with respect to car)
dt
v2 2
  dv  2t 2  k gt 1
0

v 2  6  k g
From t = 2 s to t = 3s
v = u + at
0 = (6  Kg)  Kg  1
 K = 0.3
3s
 4
k

20. From conservation of mechanical energy


1 mR2 2
pE(cos90  cos0)  
2 2
4R 1 mR 2 2
 R  E  
 2 2
 E 
  4
 m 
 
SECTION – D

z2 z2
21.   0 3
 3 2 …(i)
n n
z2 z2
E  E0 2  2  4
n n
Solving (i) and (ii), n = 2 and z = 4
nh h
L = mvr = , L = t = n
2 2
n h
  1.5  10 26 Nm
t 2

22. Zero error =   50  47   0.01 mm


 0.003 cm
Measured diameter = 1.10  0.001 12
= 1.112 cm
Actual diameter = Measured diameter – Zero Error
 1.112   0.003   1.115 cm = 11.15 mm

L F N
23. F cos 37 = g
4
 3 Lg  T F
F sin 37 = T = f  N N  4 
 
3 Lg
   1/4,  min = 1/4 T
 Lg 4
4

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 8

Chemistry PART – II

SECTION – A

24. 8MnO4  3S2 O32   H2 O  8MnO2  6SO42   2OH

25. O
O O
O
O
KBrO OH 
CH3    CH3
Self decarboxylation
CH3
CH3
Haloform reaction

26. In this condition some atoms of H must be present in n = 3


13.6 13.6
So, ionization energy from n = 3, is E  2 
n 9
= 1.51 V

27. Diastereomers have different physical properties, so, we can separate them by ordinary means
such as recrystalization.

28. NaOH  cold  Cl2  NaCl  NaOCl  H2 O

Sodium hypochlorite

anion OCl
contains  bond

29. HC NO2 Na HC NO2 Na

H C OH HO C H
HC OH
H C OH  H C OH
H C OH MeNO
O  2
EtONa

HO C H HO C H
HO C H
H C OH H C OH
H C OH
H C OH H C OH
H C
CH2 OH CH2 OH
CH2 OH
D  glucopyranose

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9 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

H2 SO 4

CH2 OH CH2 OH CHOH


CHOH
H C OH HO C H HO C H
H C OH O
H C OH H C OH O  H C OH
H /Ni H C OH
HO C H  HO C H
2
 HO C H
HO C H
H C OH H C OH H C
H C
H C OH H C OH H C OH
H C OH
CH2 OH CH2 OH CH2 OH
CH2 OH
Meso form   Optically active 

30. If the temperature increases at constant pressure the gas expands, the mean free path increases,
and the collision frequency decreases, so, A, B options are wrong.
For ideal gas, the average kinetic energy is dependent only on temperature, for isothermal
change in pressure, the average kinetic energy would not change.

31. In electrophoresis and electroosmosis process motion of particles occur under applied charge.

V
32.  constant (K)
T
nR
log V  logT  logK, where K 
P
For 2 graph
nR
log  0  log1
P
nR
 1 R  P 
P
n = 1 mol
for 1 graph
nR
log  log3
P
n=3
log 3 graph
nR 1
log   log2  log
P 2
1
n  mol.
2

33. Straight line eqn


y y 
 y  y1    2 1   x  x1 
 x 2  x1 

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 10

4  16 
P  16      V  6
 15  6 
PV max
3P  4V  72 For Tmax =
nR
For (PV)max
72 72
3P  , 4V 
2 2
P = 12 V=9
12  9
 Tmax   648 K .
1
2
2
SECTION – C

34. CN HC O

SnCl /Dil. HCl



2
Stephens reduction

CH3 CH3
 x
H3 C C ONa H3 C C O
2
O O
Perkin condensation 
CHO HC CH C OH

O O O
O /reductive
3
H C C OH  

CH3 CH3
z 

35. a, b, d because of unstable hydrate ‘c’ due to steric factor. ‘e’ gives a ketone.

36. M  AA 3   show optical isomerism


While in others plane of symmetry is possible.

37. 

A  H2 O 8  s  
 A  g  8H2 O  g; K p1
x y 8x



A  H2 O 8  s  
 A  g  8H2 O  s  ; K p2
 yx
Given
x + y = 0.2
8x = 0.001
8
K p1   x  y  8x 
 2  10 25
K p2  y  x
= 0.2

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11 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18



H2O  s  
 H2 O  g 
1/8
 Kp 
Vapour pressure   1 
 Kp 
 2 
1/8
 2  1025 
 1 
 2  10 
= 10-3 bar.

38. N2O4 is a dimer of NO2.


It’s correct structure is
O O

N N
O O
The correct structure of N2O is:
+
N N O

2
39. rA 2  K  A 
rA2 10 5
K 2
 2
 10 1
A  10  2

KA
K
2
K A  2K
= 2 × 10-1

40. (i), (ii), (vi)  regiospecific reaction


(ii), (iii), (iv), (v), (vii)  stereospecific reaction.

41. Product is O OCH3


H3C

42. NO2 NHOH NH2

A= ; B= ; C= ;
HO

43. (ii) , (iv)  incorrect


(i), (iii), (v)  correct
Et is more reactive
(i)
Et Cl
By an E2 mechanism due to presence of trans diaxial hydrogen. Anti periplannar transition state
is possible.
(iii) In triethyl amine, pyramidal inversion is responsible for decreasing its nucleophilicity while in
cyclic amine inversion is not possible.

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 12

SECTION – D

44. Sol. (1) HCl  H  Cl


0.2 M

Effective molarity = 0.4 M


Sol.(2) BOH  B   OH
t0 0.2 0 0
tt 0.2  x x x
x2
Kb 
 0.2  x 
x2
10 2 
0.2  x
x = 0.04
Effective molarity = 0.2 – x + x + x
= 0.2 + x
= 0.24
Sol.(3) HCl  BOH  BCl  H2 O
0.2 0.2 0
moles 0 0 0.2
0.2
 Conc. of [BCl]   0.1 M
2
Effective molarity = 0.2 M
Sol. (4) effective molarity = 0.2 × 5 = 1.0
Sol. (5) effective molarity = 0.2 × 4 = 0.8
Tf order  4  5  1  2  3
And Tf order = 4 < 5 < 1 < 2 < 3
Hence the correct code is 45123.00

45. At anode:
2Hg     2Cl  aq  Hg2 Cl2  s   2e … (1)
At cathode:
HgO  s   H2 O     2e   Hg     2OH  aq … (2)
From Eq. (1) and (2)
Cell reaction
HgO  s   H2 O     Hg     2Cl  aq 

Hg2 Cl2  s   2OH  aq 


G  nFE
 2  96500   0.1634 V 
= 31536.2 J mol-1.

2.18 – 2.16801
46. % of unoccupied sites   100
2.18
0.01199
  100  0.55%
2.18

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13 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

Mathematics PART – III

SECTION – A

47. C(h, k) divides AB into the ratio 5 : 4 y C2


 4  20 5  20 
  h, k    ,
 9 9  4 B(4, )
AB = 9  ( – 4)2 + ( – 5)2 = 92
C(h, k)
 h  4 2  k  5  4
  1 A(, 5)
42 52
5 C1
 x  4 2  y  5 2 0
x
Locus of point of contact is  1
16 25
x2 y 2
We shift the axes to (4, 5), so that curve become   1 and point (9, 5) become (5, 0)
16 25
16
Chord of contact is x 
5
 16 
Solving with conic, we get Q and R as  ,  3 
 5 
27
 Area of PQR =
5

AI b  c AI bc
48.   
A I a AA  a  b  c
BI ac CI ab
Similarly,  and 
BB  a  b  c CI a  b  c
AI  BI  CI  b  c  a  c  a  b 
 
AA   BB  CC  a  b  c 3
bc ca ab 1/3
    a  b  b  c  c  a  
Now, a  b  c a  b  c a  b  c  
3
3   a  b  c  
 
 a  b  b  c  c  a  8
 3

a  b  c  27

49. a2e2 = 36  a2 – b2 = 36 C
A
Using r = (s – a) tan in OCF
2 A O F B
1 = (s – a) (a = CF = OB)
 2 = 2s – 2a D
 2 = 2s – AB
AB CD
 2  6   AB
2 2
 AB – CD = 8
 a – b = 4 also a2 – b2 = 36
 2a = 13; 2b = 5

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 14

2 2 D C(3, 0, 0)
50. v
3
ˆi ˆj kˆ 4 h
M(2, 0, 0)
1 1 2 2
  0 1 1 h
3 2 3 A(1, 1, 1) E
2 1 1 B(1, 0, 0)
h=2
Also ABC is right angled
Now let E divides AM in the ratio  : 1
 2  1 1 1  2 2 2
E , ,  and AE + DE = AD
   1   1   1 
2 2 2
 2  1   1   1 
   1   1    1    4  16
   1     1     1
 Two values of 
2016 2016
r
51. Re  r   cos 2017  0
r 1 r 1
2016 2016
r
  r   r   2  cos 2017  0
r 1 r 1

1
52. Equation of tangent to the hyperbola at P is x   y  2

 2
 Q  (2, 0) and R   0, 
 
1
Equation of normal to the hyperbola at P is y   2  x   

 4  1   1  4 
 M 3
, 0  and N   0, 
     
Now, area of OQR = area of OMN
 (1 – 4)2 = 44
 2  2  1
a a
53. Let roots are , , a, ar, ar 2
r2 r
1 1 
Now, a  2   1  r  r 2   40
r r 
1 2 1 1
r  r  1   2   10
a  r r 
Dividing both  a2 = 4  a = 2
As product of roots = a5 = –
  = 32 or –32
sin xdy  y cos xdx 1
54.   2 dx
sin2 x x
 y  1
 d    2 dx
 sin x  x
sin x
 y  c sin x
x

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15 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

 y  0, x    c = 0
sin x
f  x 
x
i2k1 i2k 2 
55. Let z  A and   B then z  e 18 , e 48 k 1, k 2  I
i2   8k  3k 2  i2k
 k1 k 2  i2 1 
e6  144 
 z =    = e  e 144 where k = 8k1 + 3k2
3 8 
 z can have 144 different values
i 2k 1 
56. Let Ck  e n , k = 1, 2, ....., n then |Ck – C1| = |cos  + isin  – 1|
 2k  1  
where   = 2sin
n 2
  2  n  1  
 |C2 – C1| + |C3 – C1| + ..... + |Cn – C1| = 2 sin  sin  .....  sin 
 n n n 
º
 180º 5
= 2cot = 2cot  2cot  
2n 2  144 8
SECTION – C
1 2 1 1
 f  x  2
57.   x 
  dx  2  f  x  dx   x dx  0
0 0 0
1 2
 f  x 
    x  dx  0
0
x 
 f(x) = x2
58. If even letters goes to even envelopes but none goes to correct envelop, then the number of ways
 1 1 1
= 3! 1      2
 1! 2! 3! 
Now for L1 L2 L5 L7
E1 E3 E5 E2
Total number of without restriction = 4! = 24
Again if L1, L3, L5 goes to their correct envelope number of ways = 1
If any two of them goes to their correct envelope, number of ways = 3C2  1 = 3
If any one goes to correct envelope, number of ways = 3C1  3 = 9
Total number of required ways for odd letters = 24 – 13 = 11
 Required ways = 11  2 = 22 = N
59. |z2 + iz1| = |z1| + |z2|
 z1 is perpendicular to z2
z  z1
Also, let z3  z1  2
1 i
 z2 – z3 = i(z1 – z3)

 ACB  and |z2 – z3| = |z1 – z3|
2
 AC = BC
 AB2 = AC2 + BC2
AB 2
 AC2 
2

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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 16

1 AB 2 7  9
 Area of ABC =   4
2 2 4

1 2 2
60.
k

k k

k  k 1
2  k  k 1 
1 1 1
Putting k = 2, 3, ....., 10,000 and adding
2

3
 ..... 
10,000
2  10,000  1 
 A < 2  99  A < 198
1 2 2
Similarly
k

k k

k 1 k
2  k 1 k 
 A2  10,000  2  197
 [A] = 197
  A 
  3
 50 

61. 2m + 2n + 2p = (3 – 1)m + (3 – 1)n + (3 – 1)p = 3 + (–1)m + (–1)n + (–1)p,   I


 Number of possible triplets = 50  25  12 + 50  25  13 = 31250

  
62. Let cos–1 x = a, sin–1 y = b, a  [0, ], b    , 
 2 2
2 4 2
p    
a  b2  , a  b2  , b2  0, 
4 16  4
2
  
 a  b2  0,   
 4
2 2
p  4
 0    O  p  1
4 4 
 p = 0, 1 or 2 but if p = 0, a = b = 0, not true
 p2  4
Also, a   a 
 4  16
 16a2 – 4p2a + 4 = 0
 a  R, D  0  16p24 – 644  0  p2  4  p  2
 Possible value of p is 2
63. f(x)·f(y(f(x)) = f(x + y)
 f(x)·f(yf(x)) + f(x)·f(yf(x))·yf(x) = f(x + y)
Putting x = 0 and then replacing y by x
 –f(x) – xf(x) = f(x) ( f(0) = 1, f(0) = –1)
f  x 1
 
f  x 1 x
Integrating ln|f(x)| = –ln|1 + x| + ln|c|
c 1
 f x   f x  ( f(0) = 1)
1 x 1 x

1
 Required area =  2
dx  1
0 1  x 

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17 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18

64. Let ex = t
2
2t 3  t 2  1 dt
 I 3 2 =
2
  
t 3t 2  2t  1  t 3  t 2  t  1  dt
t   3 2

1 t  t  t 1 1 t t  t  t 1
2 2 2
3t  2t  1 dt 2 2 11
=  t3  t2  t  1   = ln t 3  t 2  t  1   ln t  = ln
t   1 1 4
1 1

65. Eccentricity of the hyperbola in nCr


Possible value of nCr will be 2C1, 3C1, 4C1, 5C1, 4C2 and 5C2
66. AB = I
(AB)C1 = C1, (AB)2C2 = C2 ..... and so on
tr(Cr) = r·3r + (r – 1)·3r = (2r – 1)3r
50
 tr   AB    AB  C   .....  t  AB  
r 2 50
Cr  tr   AB  C1   t r 2 r C50
r 1
= tr(C1) + tr(C2) + ..... + tr(C50)
= 1·3 + 3·32 + 5·33 + ..... + 99·350 (AGP)
 S = 3 + 49·351
 a + b = 100
SECTION – D
67. Let roots be 1, 2, ....., 8
1
1 + 2 + ..... + 8 = 4, 12 ..... 8 =
28
 A.M. and G.M. of 1, 2, ....., 8 are equal
1
 1 = 2 = ..... = 8 =
2
6
 1 1 1
 a 2  8 C 6    , a 4  8 C 4  4 , a 6  8 C2  2
2
  2 2
 8 31
68. Reflection of (4, 5) w.r.t lines y = x and y = 2x are (5, 4) and  ,  respectively minimum value
5 5 
 8 31 
of PA + PB + AB = distance between (5, 4) and  ,   16.4
5 5 
 
 2x ; 0x
2

  3
69. Let g(x) = sin–1|sin x| + cos–1(cos x) =   ; x
 2 2
 3
4  2x ; 2  x  2

  3 
g(x) is periodic with period 2 and is constant in the interval  2n  , 2n  ,nI
 2 2 
Now f(x) = g(x)
 2n  2n 3 
 f(x) is constant in   , 
  2  2 
3 
 2  
2 2
1
 
2

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