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FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – X
PAPER-2
1. B 24. C 47. B
ALL INDIA TEST SERIES
2. C 25. C 48. C
3. C 26. C 49. A
4. A, C 27. A, B, D 50. A, C, D
5. A, C, D 28. A, B, C 51. B, C
6. A, C, D 29. A, B, C, D 52. A, C, D
7. A, C 30. A, B, D 53. A, D
8. B, C 31. B, D 54. A, B, C
9. A 32. A 55. D
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 2
Physics PART – I
SECTION – A
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3 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
M
m
3 sin sin cos
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 4
From t 1s to t 6s
1
30 6 5 10 5 2v
2
35
v m/s
2
m g
9. 2g mv1 v1
2 2
1 g
mg(1 cos ) m ( is angular displacement of the bob when it comes to rest)
2 2
3
cos
4
When the bob moves in horizontal circle
g 4g
cos 3
4g 7 7g
v r sin
3 4 12
7g 7g
mv Q 2m vQ
12 3
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5 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
SECTION – C
w
w A x g Ag
13. a 5
w
A
5
v
5x
0 vdv 0 4 gdx
v 3g 3 1.2 10 6 m / s
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 6
17.
k 0 2 k 0
k 2 0 0
0 10 1
0 20 2
0 30
k 20
2 2
4 3 0
2
3R z 1 2
8
z 1
9 0R
mv 2mK max
18. r
qB qB
q2B2r 2
K max
2m
Putting the values of q, B, r and m
Kmax = 2 eV
Energy of emitted photon
1 1
h = 13.6 3 2 eV = 5.95 eV
9 16
h = + kmax
= 3.95 eV 4 eV
19. a = 4t
At t = 1 sec, a = 4 = s g
S = 0.4
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7 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
dv
4t k g (where v = velocity of block with respect to car)
dt
v2 2
dv 2t 2 k gt 1
0
v 2 6 k g
From t = 2 s to t = 3s
v = u + at
0 = (6 Kg) Kg 1
K = 0.3
3s
4
k
z2 z2
21. 0 3
3 2 …(i)
n n
z2 z2
E E0 2 2 4
n n
Solving (i) and (ii), n = 2 and z = 4
nh h
L = mvr = , L = t = n
2 2
n h
1.5 10 26 Nm
t 2
L F N
23. F cos 37 = g
4
3 Lg T F
F sin 37 = T = f N N 4
3 Lg
1/4, min = 1/4 T
Lg 4
4
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 8
Chemistry PART – II
SECTION – A
25. O
O O
O
O
KBrO OH
CH3 CH3
Self decarboxylation
CH3
CH3
Haloform reaction
27. Diastereomers have different physical properties, so, we can separate them by ordinary means
such as recrystalization.
Sodium hypochlorite
anion OCl
contains bond
H C OH HO C H
HC OH
H C OH H C OH
H C OH MeNO
O 2
EtONa
HO C H HO C H
HO C H
H C OH H C OH
H C OH
H C OH H C OH
H C
CH2 OH CH2 OH
CH2 OH
D glucopyranose
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9 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
H2 SO 4
30. If the temperature increases at constant pressure the gas expands, the mean free path increases,
and the collision frequency decreases, so, A, B options are wrong.
For ideal gas, the average kinetic energy is dependent only on temperature, for isothermal
change in pressure, the average kinetic energy would not change.
31. In electrophoresis and electroosmosis process motion of particles occur under applied charge.
V
32. constant (K)
T
nR
log V logT logK, where K
P
For 2 graph
nR
log 0 log1
P
nR
1 R P
P
n = 1 mol
for 1 graph
nR
log log3
P
n=3
log 3 graph
nR 1
log log2 log
P 2
1
n mol.
2
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 10
4 16
P 16 V 6
15 6
PV max
3P 4V 72 For Tmax =
nR
For (PV)max
72 72
3P , 4V
2 2
P = 12 V=9
12 9
Tmax 648 K .
1
2
2
SECTION – C
34. CN HC O
CH3 CH3
x
H3 C C ONa H3 C C O
2
O O
Perkin condensation
CHO HC CH C OH
O O O
O /reductive
3
H C C OH
CH3 CH3
z
35. a, b, d because of unstable hydrate ‘c’ due to steric factor. ‘e’ gives a ketone.
37.
A H2 O 8 s
A g 8H2 O g; K p1
x y 8x
A H2 O 8 s
A g 8H2 O s ; K p2
yx
Given
x + y = 0.2
8x = 0.001
8
K p1 x y 8x
2 10 25
K p2 y x
= 0.2
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11 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
H2O s
H2 O g
1/8
Kp
Vapour pressure 1
Kp
2
1/8
2 1025
1
2 10
= 10-3 bar.
N N
O O
The correct structure of N2O is:
+
N N O
2
39. rA 2 K A
rA2 10 5
K 2
2
10 1
A 10 2
KA
K
2
K A 2K
= 2 × 10-1
A= ; B= ; C= ;
HO
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 12
SECTION – D
45. At anode:
2Hg 2Cl aq Hg2 Cl2 s 2e … (1)
At cathode:
HgO s H2 O 2e Hg 2OH aq … (2)
From Eq. (1) and (2)
Cell reaction
HgO s H2 O Hg 2Cl aq
2.18 – 2.16801
46. % of unoccupied sites 100
2.18
0.01199
100 0.55%
2.18
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13 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
SECTION – A
AI b c AI bc
48.
A I a AA a b c
BI ac CI ab
Similarly, and
BB a b c CI a b c
AI BI CI b c a c a b
AA BB CC a b c 3
bc ca ab 1/3
a b b c c a
Now, a b c a b c a b c
3
3 a b c
a b b c c a 8
3
a b c 27
49. a2e2 = 36 a2 – b2 = 36 C
A
Using r = (s – a) tan in OCF
2 A O F B
1 = (s – a) (a = CF = OB)
2 = 2s – 2a D
2 = 2s – AB
AB CD
2 6 AB
2 2
AB – CD = 8
a – b = 4 also a2 – b2 = 36
2a = 13; 2b = 5
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 14
2 2 D C(3, 0, 0)
50. v
3
ˆi ˆj kˆ 4 h
M(2, 0, 0)
1 1 2 2
0 1 1 h
3 2 3 A(1, 1, 1) E
2 1 1 B(1, 0, 0)
h=2
Also ABC is right angled
Now let E divides AM in the ratio : 1
2 1 1 1 2 2 2
E , , and AE + DE = AD
1 1 1
2 2 2
2 1 1 1
1 1 1 4 16
1 1 1
Two values of
2016 2016
r
51. Re r cos 2017 0
r 1 r 1
2016 2016
r
r r 2 cos 2017 0
r 1 r 1
1
52. Equation of tangent to the hyperbola at P is x y 2
2
Q (2, 0) and R 0,
1
Equation of normal to the hyperbola at P is y 2 x
4 1 1 4
M 3
, 0 and N 0,
Now, area of OQR = area of OMN
(1 – 4)2 = 44
2 2 1
a a
53. Let roots are , , a, ar, ar 2
r2 r
1 1
Now, a 2 1 r r 2 40
r r
1 2 1 1
r r 1 2 10
a r r
Dividing both a2 = 4 a = 2
As product of roots = a5 = –
= 32 or –32
sin xdy y cos xdx 1
54. 2 dx
sin2 x x
y 1
d 2 dx
sin x x
sin x
y c sin x
x
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15 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
y 0, x c = 0
sin x
f x
x
i2k1 i2k 2
55. Let z A and B then z e 18 , e 48 k 1, k 2 I
i2 8k 3k 2 i2k
k1 k 2 i2 1
e6 144
z = = e e 144 where k = 8k1 + 3k2
3 8
z can have 144 different values
i 2k 1
56. Let Ck e n , k = 1, 2, ....., n then |Ck – C1| = |cos + isin – 1|
2k 1
where = 2sin
n 2
2 n 1
|C2 – C1| + |C3 – C1| + ..... + |Cn – C1| = 2 sin sin ..... sin
n n n
º
180º 5
= 2cot = 2cot 2cot
2n 2 144 8
SECTION – C
1 2 1 1
f x 2
57. x
dx 2 f x dx x dx 0
0 0 0
1 2
f x
x dx 0
0
x
f(x) = x2
58. If even letters goes to even envelopes but none goes to correct envelop, then the number of ways
1 1 1
= 3! 1 2
1! 2! 3!
Now for L1 L2 L5 L7
E1 E3 E5 E2
Total number of without restriction = 4! = 24
Again if L1, L3, L5 goes to their correct envelope number of ways = 1
If any two of them goes to their correct envelope, number of ways = 3C2 1 = 3
If any one goes to correct envelope, number of ways = 3C1 3 = 9
Total number of required ways for odd letters = 24 – 13 = 11
Required ways = 11 2 = 22 = N
59. |z2 + iz1| = |z1| + |z2|
z1 is perpendicular to z2
z z1
Also, let z3 z1 2
1 i
z2 – z3 = i(z1 – z3)
ACB and |z2 – z3| = |z1 – z3|
2
AC = BC
AB2 = AC2 + BC2
AB 2
AC2
2
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AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18 16
1 AB 2 7 9
Area of ABC = 4
2 2 4
1 2 2
60.
k
k k
k k 1
2 k k 1
1 1 1
Putting k = 2, 3, ....., 10,000 and adding
2
3
.....
10,000
2 10,000 1
A < 2 99 A < 198
1 2 2
Similarly
k
k k
k 1 k
2 k 1 k
A2 10,000 2 197
[A] = 197
A
3
50
62. Let cos–1 x = a, sin–1 y = b, a [0, ], b ,
2 2
2 4 2
p
a b2 , a b2 , b2 0,
4 16 4
2
a b2 0,
4
2 2
p 4
0 O p 1
4 4
p = 0, 1 or 2 but if p = 0, a = b = 0, not true
p2 4
Also, a a
4 16
16a2 – 4p2a + 4 = 0
a R, D 0 16p24 – 644 0 p2 4 p 2
Possible value of p is 2
63. f(x)·f(y(f(x)) = f(x + y)
f(x)·f(yf(x)) + f(x)·f(yf(x))·yf(x) = f(x + y)
Putting x = 0 and then replacing y by x
–f(x) – xf(x) = f(x) ( f(0) = 1, f(0) = –1)
f x 1
f x 1 x
Integrating ln|f(x)| = –ln|1 + x| + ln|c|
c 1
f x f x ( f(0) = 1)
1 x 1 x
1
Required area = 2
dx 1
0 1 x
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17 AITS-FT-X (Paper-2)-PCM (Sol)-JEE(Advanced)/18
64. Let ex = t
2
2t 3 t 2 1 dt
I 3 2 =
2
t 3t 2 2t 1 t 3 t 2 t 1 dt
t 3 2
1 t t t 1 1 t t t t 1
2 2 2
3t 2t 1 dt 2 2 11
= t3 t2 t 1 = ln t 3 t 2 t 1 ln t = ln
t 1 1 4
1 1
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