Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
O Br
KOH alc (excess)
C OH D
COOH CH2 Ph
(1) (2) CH2
Br
OH
COOH C
O
(1) (2)
CH2 Ph Ph
COOH CH2 OH
(3) (4) CH OH
COOH 2 (3) (4)
CH2 Ph Ph
Ans. (4) Ans. (3)
E 1
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
Sol. Example of E 2 elimination and conjugated Sol. N2(g) + O2(g) 2NO(g)
diene is formed with phenyl ring in conjugation
which makes it very stable. kp Dn g
= (RT) = (RT)0 = 1
8. The total number of isomers for a square planar kc
complex [M(F)(Cl)(SCN)(NO2)] is :
N2O4(g) 2NO2(g)
(1) 12 (2) 8 (3) 16 (4) 4
Ans. (1) kp
= (RT)1 = 24.62
Sol. The total number of isomers for a square planar kc
complex [M(F)(Cl)(SCN)(NO2)] is 12.
F SCN F NCS N2(g) + 3H2(g) 2NH3(g)
M M
Cl NO2/SCN/Cl Cl NO2/NCS/Cl kp 1
= (RT) –2 = = 1.65 ´ 10 -3
(3) (3) kc (RT) 2
F SCN F NCS
M M 11. If dichloromethane (DCM) and water (H2O) are
Cl ONO/SCN/Cl Cl ONO/NCS/Cl used for differential extraction, which one of
(3) (3) the following statements is correct ?
9. Hall-Heroult's process is given by " (1) DCM and H2O would stay as lower and
(1) Cr2O3 + 2Al ® Al2O3 + 2Cr
2 E
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
14. Consider the given plots for a reaction obeying 17. Liquids A and B form an ideal solution in the
Arrhenius equation (0°C < T < 300°C) : (k and entire composition range. At 350 K, the vapor
E a are rate constant and activation energy, pressures of pure A and pure B are 7 × 103 Pa
respectively) and 12 × 103 Pa, respectively. The composition
of the vapor in equilibrium with a solution
containing 40 mole percent of A at this
k k temperature is :
E 3
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
19. The major product of the following reaction is: 21. The decreasing order of ease of alkaline
hydrolysis for the following esters is :
CH3O
CH2Cl ¾¾¾¾¾¾
(i) AlCl3 (anhyd.)
®
(ii) H O2 COOC2H5
I
CH3O
(1) Cl COOC2H5
CH3
CH3O II
(2)
O 2N COOC2H5
III
CH3O
(3) CH3O COOC2H5
IV
CH 3O
(4)
Ans. (2)
CH3 EN (1) IV > II > III > I
(2) III > II > I > IV
(3) III > II > IV > I
CH3O (4) II > III > I > IV
CH2Cl
Sol. ¾¾¾¾¾¾
®
(i)AlCl3 (H2 O)
Ans. (2)
Sol. More is the electrophilic character of carbonyl
LL
CH3O +
CH2 group of ester faster is the alkaline hydrolysis.
22. A process has DH = 200 Jmol–1 and
(1) 5 K
¾¾¾¾¾
int ra F.C.A.
® (2) 4 K
20. The electronegativity of aluminium is similar (3) 20 K
to : (4) 12 K
(1) Boron (2) Carbon
Ans. (1)
(3) Lithium (4) Beryllium
Ans. (4) Sol. DG = DH – TDS
Sol. E.N. of Al = (1.5) » Be (1.5) DH 200
T= = = 5K
DS 40
4 E
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
23. Which of the graphs shown below does not Sol. Then is no catalyst is required for combustion
represent the relationship between incident light of coal.
and the electron ejected form metal surface ?
25. The effect of lanthanoid contraction in the
(1)
number lanthanoid series of elements by and large
of e–s means :
Ans. (1)
0
Intensity of
light Sol. Due to Lanthanoid contraction both atomic
(3)
K.E. of
e– s
EN 26.
radii and ionic radii decreases gradually in the
lanthanoid series.
0
Frequency of NH2
light ¾¾¾¾¾
NaNO 2
Aq.HCl,0 -5° C
®
LL
(4)
K.E. of
e– s NO2
(1)
0
energy of OH
A
light (2)
Ans. (3)
1
Sol. E = W + mv2
2 NH2
(3)
K.E. = hn – 4n0
K.E. = hn + (–hn0)
y = mx + C
24. Which of the following is not and example of (4)
NO2
heterogeneous catalytic reaction ?
(1) Ostwald's process
Ans. (Bonus)
(2) Haber's process
(3) Combustion of coal OH
(4) Hydrogenation of vegetable oils Sol. Answer should be
Ans. (3)
E 5
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
27. The correct structure of product 'P' in the O
following reaction is :
NH 2
Asn-Ser + (CH 3CO)2 O ¾¾¾
NEt 3
® P O O
H
(excess) N
H3 C N OH
O O
O NH2 OCOCH 3
H O
N N 28. Which hydrogen in compound (E) is easily
(1) H 3C OH
H O replaceable during bromination reaction in
OCOCH3 presence of light :
O C H3 - C H2 - C H = C H2
d g b a
O NHCOCH3
H O (1) b – hydrogen
(2) H3C N N
H OH (2) g – hydrogen
O
(3) d – hydrogen
OCOCH 3 (4) a – hydrogen
OCOCH 3 Ans. (2)
O
(3) H 3C N
H O
H
N
O
O
EN
OH
NHCOCH 3
29. The major product 'X' formed in the following
reaction is :
O O
CH2–C–OCH3
¾¾¾
NaBH 4
®X
MeOH
OCOCH 3
O
H O OH
(4) H3C N N
CH2CH2OH
LL
H OH
O (1)
NH2
O
O O
Ans. (1)
Sol. Asn–Ser is dipeptide having following CH2–C–H
(2)
structure
A
O CH2OH OH
NH2 – C – C – NH – CH – CO2H CH2CH2OH
(3)
CH2
CONH2
OH O
CH2–C–OCH3
Asn - Ser + (CH3 CO)2 O ¾¾¾
NEt3
®P (4)
excess
P is
Ans. (4)
6 E
JEE ( Main ) Examination–2019/Morning Session/10-01-2019
30. A mixture of 100 m mol of Ca(OH)2 and 2g of
sodium sulphate was dissolved in water and the
volume was made up to 100 mL. The mass of
calcium sulphate formed and the concentration
of OH– in resulting solution, respectively, are
: (Molar mass of Ca(OH)2, Na2SO4 and CaSO4
are 74, 143 and 136 g mol–1, respectively; Ksp
of Ca(OH)2 is 5.5 × 10–6)
(1) 1.9 g, 0.14 mol L–1
(2) 13.6 g, 0.14 mol L–1
(3) 1.9 g, 0.28 mol L–1
(4) 13.6 g, 0.28 mol L–1
Ans. (3)
Sol. Ca(OH)2 + Na2SO4 ¾® CaSO4 + 2NaOH
100 m mol 14 m mol
— —
— —
14 m mol 28 m mol
w CaSO4 = 14 ´ 10 –3 ´ 136 = 1.9gm
EN
28
[OH–] = = 0.28M
100
LL
A
E 7