JEE ( Main ) Examination–2019/Morning Session/09-01-2019

TEST PAPER OF JEE(MAIN) EXAMINATION – 2019

(Held On Wednesday 09th JANUARY, 2019)
CHEMISTRY
1. Which one of the following statements
regarding Henry's law not correct ?
(1) The value of KH increases with function of
the nature of the gas
(2) Higher the value of KH at a given pressure,
higher is the solubility of the gas in the
liquids.
(3) The partial of the gas in vapour phase is
proportional to the mole fraction of the gas
in the solution.
(4) Different gases have different KH (Henry's
TIME : 9 : 30 AM To 12 : 30 PM
3. Two complexes [Cr(H 2 O 6 )Cl 3 ] (A) and
[Cr(NH 3 ) 6 ]Cl 3 (B) are violet and yellow
coloured, respectively. The incorrect statement
regarding them is :
(1) D0 value of (A) is less than that of (B).
(2) D0 value of (A) and (B) are calculated from
the energies of violet and yellow light,
respectively
(3) Bothe absorb energies corresponding to
their complementary colors.
(4) Bothe are paramagnetic with three unpaired
electrons.
Ans. (2)
Sol. D0 order will be compared by spectro chemical

Ans. (2)
law constant) values at the same
temperature.
EN 4.
series not by energies of violet & yellow light
so D0 order is
[Cr(H2O)6]Cl3 < [Cr(NH3)6]Cl3
Adsorption of a gas follows Freundlich
Sol. Liquid solution adsorption isotherm. In the given plot, x is the
Pgas = KH × Xgas mass of the gas adsorbed on mass m of the
x
More is KH less is solubility, lesser solubility is adsorbent at pressure p. is proportional to
LL
m
at higher temperature. So more is temperature
more is KH.
2. The correct decreasing order for acid strength
is :- 2 unit
x
Log 4 unit
m
(1) NO2CH2COOH > NCCH 2COOH >
A

FCH2COOH > CICH2COOH

(2) FCH2COOH > NCCH2COOH > Log P

NO2CHCOOH > CICH2COOH 1 1

(1) P (2) P2 (3) P (4) P
(3) NO2CH2COOH > FCH2COOH > 4 2
Ans. (4)
CNCH2COOH > CICH2COOH
x
Sol. = K ´ P1/ n
(4) CNCH2COOH > O2NCH2COOH > m
FCH2COOH > CICH2COOH x 1
log = log K + log P
Ans. (1) m n
1 2 1
Sol. EWG increasea acidic strength m= = = Þ n= 2
n 4 2
NO2CH2COOH > NCCH 2COOH >
x
FCH2COOH > CICH2COOH So, = K ´ P1/ 2
m
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JEE ( Main ) Examination–2019/Morning Session/09-01-2019
5. Correct statements among a to d regarding 7. The major product the following reaction is :
silicones are : (i) Br 2
(a) They are polymers with hydrophobic (ii) EtOH
character OEt OEt
OEt
(b) They are biocompatible. (1) (2)
(c) In general, they have high thermal stability
and low dielectric strenth.
Br OEt
(d) Usually, they are resistant to oxidation and OEt Br
used as greases. (3) (4)
(1) (a), (b) and (c) only
Ans. (4)
(2) (a), and (b) only Sol.
Br OEt
(3) (a), (b), (c) and (d) Å
Br
Br2 EtOH
(4) (a), (b) and (d) only –HÅ
Ans. (3) 8. The alkaline earth metal nitrate that does not
crystallise with water molecules, is :

6.
EN
Sol. These are properties and uses of silicones.
For emission line of atomic hydrogen from
n i = 8 to n f = the plot of wave number
(1) Sr(NO3)2
(3) Ca(NO3)2
Ans. (4)
(2) Mg(NO3)2
(4) Ba(NO3)2

Sol. Smaller in size of center atoms more water

molecules will crystallize hence Ba(NO 3)2 is
æ 1 ö
(v) against ç n 2 ÷ will be (The Ry dberg answer due to its largest size of '+ve' ion.
è ø 9. Major product of the following reaction is :
constant, R H is in wave number unit). Cl
Cl NH2
(1) Linear with slope - R H
LL
+ H2 N (1) Et3N
(2) Linear with intercept - RH O O (2) Free radical
(3) Non linear polymerisation
Cl
(4) Linear with sslope R H
n O
Ans. (4) (1) NH2
O N
A

H
1 æ 1 1 ö O Cl
Sol. = v = R H z2 ç 2 - 2 ÷
l è h1 h2 ø
n
(2) HN
æ 1 1ö NH2
v = RH ´ç 2 - 2 ÷ O
è h1 8 ø
Cl O

1 RH n O
v = RH ´ - (3)
h2 82 HN
NH2
Cl
1 RH n
v = RH ´ -
h2 64 (4)
O N NH2
m = RH H
Ans. (4)
Linear with slope RH
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 JEE ( Main ) Examination–2019/Morning Session/09-01-2019
Sol. 12. 0.5 moles of gas A and x moles of gas B exert
a pressure of 200 Pa in a a container of volume
Cl
Cl NH2
Cl NH2 10 m3 at 1000 K. given R is the gas constant
NH
+ H2 N (b) Et3N
O in JK–1 mol–1m, x is :
O (a) O O
2R 2R 4–R 4+R
NH2(a) will wact as nucleophile as (b) is having (1) (2) (3) (4)
4 + 12 4–R 2R 2R
delocalised lonepair. Ans. (3)
Cl Sol. n T = (0.5 + x)
Cl NH 2 n
NH PV = n × R × T
O ¾¾¾¾¾
® Free Radical
Polymerisation N 200 × 10 = (0.5 + x) × R × 1000
O NH 2
O H 2 = (0.5 + x) R
10. The highest value of the calculated spin only 2 1
magnetic moment (in BM) among all the = +x
R 2
transition metal complexs is :
4
- 1 = 2x
(1) 5.92 (2) 3.87 (3) 6.93 (4) 4.90 R
Ans. (1) 4-R
=x
2R
Sol. m= n(n + 2) B.M.
13. Consider the reversible isothermal expansion
n = Number of unpaired electrons
n = Maximum number of unpaired electron =
5
EN of an ideal gas in a closed system at two
different temperatures T1 and T2 (T1 < T2). The
correct graphical depiction of the dependence
of work done (w) on the final volume (V) is:
|W| T2
Ex : Mn2+ complex.
T1
11. 20 mL of 0.1 MH2SO4 solution is added to 30
mL of 0.2 M NH4OH solution. The pH of the
(1)
LL
resulatant mixture is : [pkb of NH4OH = 4.7].
(1) 9.4 (2) 5.0 (3) 9.0 (4) 5.2 O In V
Ans. (3) |W| T2

Sol. 20 ml 0.1 M H2SO4 Þ hH + = 4 T1

30 ml 0.2 M NH4OH Þ hNH4OH = 6 (2)

A

O In V
ˆˆ† NH4Å
NH4OH + H+ ‡ˆˆ + H2O
|W| T2
Þ 6 4 0 0
T1
Þ 2 0 4 4
Solution is basic buffer (3)

O In V
NH +4
pOH = pKb + log
NH 4OH |W| T2

= 4.7 + log 2 T1
= 4.7 + 0.3 = 5 (4)
pH = 14 – 5 = 9
O In V
Ans. (2)

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JEE ( Main ) Examination–2019/Morning Session/09-01-2019
17. A water sample has ppm level concentration of
V2
Sol. w = -nRT ln V the following metals: Fe= 0.2; Mn = 5.0; Cu = 3.0;
1 Zn = 5.0. The metal that makes the water sample
unsuitable drinking is :
Vb
w = -nRT ln V (1) Zn (2) Fe (3) Mn (4) Cu
i Ans. (3)
Sol. (i) Zn = 0.2 (ii) Fe = 0.2
Vb
| w | = nRT ln (iii) Mn = 5.0 (iv) Cu = 3.0
Vi 18. The increasing order of pKa of the following
amino acids in aqueous solution is :
| w | = nRT (ln Vb - ln Vi )
Gly Asp Lys Arg
| w | = nRT ln Vb - nRT ln Vi (1) Asp < Gly < Arg < Lys
Y=mx–C (2) Arg < Lys < Gly < Asp
So, slope of curve 2 is more than curve 1 (3) Gly < Asp < Arg < Lys
and intercept of curve 2 is more negative then (4) Asp < Gly < Lys < Arg
curve 1. Ans. (4)
14. The major product of following reaction is : Sol. Order of acidic strength :
HOOC–CH2–CH–COOH > NH2–CH2–COOH >

(1) RCHO
(3) RCH2NH2
Ans. (1)
(1)AlH(i–Bu 2 )
R – C º N ¾¾¾¾¾(2)H 2O
¾ ® ?
(2) RCOOH
(4) RCONH2
EN NH
NH2
Aspartic acid

O
Glycine

AlH(i- Bu )
Sol. R–CºN ¾¾¾¾ 2
¾ ® R–CH=N– ¾¾¾
H O
® R–CH=O
2

H2N–C–NH–CH2CH2CH2–CH–C–OH
15. In general, the properties that decrease and NH2
increase down a group in the periodic table,
respectively, are : Arginine
LL
(1) electronegativity and electron gain enthalpy. So, pKa
(2) electronegativity and atomic radius. Asp < Gly < Arg < Lys
(3) atomic radius and electronegativity. 19. According to molecular orbital theory, which
(4) electron gain enthalpy and electronegativity.
Ans. (2) of the following is true with respect to Li2+ and
Sol. Electronegativity decreases as we go down the
Li2- ?
A

group and atomic radius increases as we go

down the group. (1) Both are unstable
16. A solution of sodium sulfate contains 92 g of (2) Li2+ is unstable and Li2- is stable
Na+ ions per kilogram of water. The molality
of Na+ ions in that solution in mol kg–1 is: (3) Li2+ is stable and Li2- is unstable
(1) 16 (2) 8 (3) 4 (4) 12 (4) Both are stabel
Ans. (4) Ans. (4)
92 Sol. Both Li +2 and Li –2 has 0.5 bond order and hence
Sol. n Na+ = =4
23 both are stable.
So molality = 4

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 JEE ( Main ) Examination–2019/Morning Session/09-01-2019
20. The following results were obtained during Sol.
kinetic studies of the reaction :
OH
2A + B ® Products
O
Experment [A] [B] Initial Rate of reaction Br KOH OH CrO3
Å
(in mol L -1) (in mol L-1 ) (in mol L–1 min–1) H
Br Br Br
(I) 0.10 0.20 6.93 × 10–3 H
Å

(II) 0.10 0.25 6.93 × 10–3

(III) 0.20 0.30 1.386 × 10–2

O
The time (in minutes) required to consume half Br
of A is : During AES Br is o/p directing and major
(1) 10 (2) 5 (3) 100 (4) 1 product will be formed on less hindrance p
Ans. (2)
position :
Sol. 6.93 × 10–3 = K × (0.1)x (0.2)y
22. Arrange the following amines in the decreasing
6.93 × 10–3 = K × (0.1)x (0.25)y order of basicity:
So y = 0
and 1.386 × 10–2 = K × (0.2)x (0.30)y

1 æ1ö
=ç ÷
2 è2ø
x

x=1

So r = K × (0.1) × (0.2)0
EN (I)
N N

H
(II)
N

H
(III)
6.93 × 10–3 = K × 0.1 × (0.2)0 (1) I > II > III (2) III > II > I
(3) I > III > II (4) III > I > II
K = 6.93 ´10-2
Ans. (4)
Sol. Order of basic strength :
LL
0.693 0.693 10
t1/ 2 = = -1 = =5
2K 0.693 ´ 10 ´ 2 2
> >
21. The major product of the following reaction is:
N N N

H H
(1) KOH (aqueous)
Br 3
sp N
2
sp N delocalised
A

+
(2) CrO3/H lp of N
Br (3) H2SO4/D

23. Which amongst the following is the strongest

O O acid ?
(1) CHI3 (2) CHCI3
(1) (2) (3) CHBr3 (4) CH(CN)3
Ans. (4)
HO Br Sol. CN makes anino most stable so answer is
CH(CN)3
24. The anodic half-cell of lead-acid battery is
recharged unsing electricity of 0.05 Faraday.
O O The amount of PbSO4 electrolyzed in g during
the process in : (Molar mass of PbSO4 = 303
(3) (4) g mol-1)
(1) 22.8 (2) 15.2 (3) 7.6 (4) 11.4
OH Br
Ans. (2)
Ans. (2)
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JEE ( Main ) Examination–2019/Morning Session/09-01-2019
Me
Sol. (A) PbSO4(s) + 2OH–¾® PbO2 + H2SO4 + 2e– Sol. (A) Chloroxylenol Cl
FeCl3
0.05/2 mole 0.05F HO Me test
(C) PbSO4 + 2e– + 2H+¾® Pb(s) + H2SO4
0.05/2 mole 0.05 F OH
n T (PbSO 4 ) = 0.05 mole (B) Norethindrone
CºCH
Bayer's
mPbSO 4 = 0.05 ´ 303 = 15.2 gm O
test

25. The one that is extensively used as a

piezoelectric material is :
(1) Quartz (C) Sulphapyridine SO2
NH N Carbylamine
(2) Amorphous silica H2N test
(3) Mica
(4) Tridymite
Ans. (1) NH S
Sodium hydrogen
Sol. Quartz (Information) (D) Penicllin O N
carbonate test
26. Aluminium is usually found in +3 oxidation COOH

stagte. In contarast, thallium exists in +1 and

+3 oxidation states. This is due to :
(1) lanthanoid contraction
(2) lattice effect 28. The ore that contains both iron and copper is:
(3) diagonal relationship (1) malachite
(4) inert pair effect
Ans.
Sol.

27.
(4) EN
Inert pair effect is promenent character of p-
block element.
The correct match between Item -I and Item-
II is :
(2) dolomite
(3) azurite
(4) copper pyrites
Ans. (4)
Sol. Copper pyrites : CuFeS 2
Item – I Item – II
Malachite : Cu(OH)2 . CuCO3
(drug) (test)
(A) Chloroxylenol (P) Carbylamine Azurite Cu(OH)2 . 2CuCO3
LL
Test Dolomite CaCO3 . MgCO3
(B) Norethindrone (Q) Sodium Hydrogen
carbonateTest
(C) Sulphapyridine (R) Ferric chloride test
(D) Penicillin (S) Bayer’s test

(1) A®Q ; B®P ; C®S ; D®R

A

(2) A®R ; B®P ; C®S ; D®Q

(3) A®R ; B®S ; C®P ; D®Q
(4) A®Q ; B®S ; C®P ; D®R
Ans. (3)

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 JEE ( Main ) Examination–2019/Morning Session/09-01-2019
29. The compounds A and B in the following
reaction are, respectively:
HCHO+HCI AgCN
A A
(1) A = Benzyl alcohol, B = Benzyl isocyanide
(2) A = Benzyl alcohol, B = Benzyl cyanide
(3) A = Benzyl chloride, B = Benzyl cyanide
(4) A = Benzyl chloride, B = Benzyl isocyanide
Ans. (4)
30. The isotopes of hydrogen are :
(1) Tritium and protium only
(2) Deuterium and tritium only
(3) Protium and deuterum only
(4) Protium, deuterium and tritium
Ans. (4)
Sol. Isotopes of hydrogen is :
Proteium Deuterium Tritium

CH2–Cl CH2–N==C

Sol. HCHO AgCN

HCI (covalent)

EN
LL
A

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