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ABSTRACT
KEYWORDS
I NTRODUCTI ON
This paper provides information about the anaerobic process and UASB
reactor design for treating soluble non-complex wastewaters and complex
partially soluble wastewater. Both low - strength and high - strength
wastewaters will be considered, as well as treatment at optimal and sub
optimal temperature conditions. Thermophilic applications will not be
dis cu s sed in thi s pre sentation.
87
COMPLEX WASTEWATERS
This paper deals with the process lay-out and UASB-reactor design and the
treatment of wastewaters containing :
insoluble organic and inorganic compounds,
substrates which tend to precipitate, and
compounds which promote foaming and/or scumming occur under
specific conditions.
As the lay-out and reactor design are closely related to the way the
process is operated, attention has also been paid to operational aspects
in relation to the specific problems that can manifest.
Apart from the characteristics of the S5, also the concentration of the
dispersed matter is of big importance. It will be evident that beyond a
certain 55-concentration, depending on the characteristics of the 5S, an
anaerobic treatment system like the UA5B-reactor will become less
feasible. The same applies for other high-rate reactor systems, although
the concentration at which these systems start to suffer, as well as the
reasons why, may differ significantly from those in UASB-reactors.
It is well known that many compounds are inhibitory and/or severely toxic
for methanogenic organisms. In those cases where toxic concentrations of
one or more of these compounds occur, specific measures have to be taken,
and - fortunately - frequently can be taken. These measures consist of:
investing sufficient time to allow the sludge to adapt to the
toxic compounds,
applying dilution of the influent solution to such an extent
that the extent of toxicity is acceptable, and/or that
biodegradation of the toxic compound will proceed well,
applying some kind of pre-treatment by which the toxic compound
is eliminated, e.g. a chemical or biological treatment step, and
avoiding that air (oxygen) is entering the water phase, because
for specific wastewaters (e.g. potato starch industry, forestry
industry) it may lead to the formation of severely toxic
compounds.
We therefore recommend:
to apply only a slight pre-acidification, i.e. tentatively up to
20-40 %. (Hard figures cannot be provided because too many
factors are involved). Such an extent of pre-acidification
generally proceeds sufficiently in the wastewater sewer system
and/or in a holding or equalization tank,
to operate the system under conditions of a 'complete as
possible' adaptation, and
to maintain sludge loading rates always well below the maximum
methanogenic activity « approximately 75%). This is the best
guarantee for process stability.
Apart from the need to equalize big variations in the flow and/or in the
pollution strength of the wastewater, an additional reason for installing
an egualization tank in an anaerobic wastewater treatment scheme is to
achieve the desirable extent (i.e. 10 - 20%) of pre-acidification. In
those c�ses where the buffer capacity of the wastewater is insufficient
for achieving this goal, the system also should be equipped with supply
facilities for alkalinity in order to neutralize part of VFA formed. In
this connection it has to be understood that although acidogenic
bacteria are much less pH-sensitive than methanogens the rate of
acidogenesis also slows down rapidly at pH-values below 5.
Depending on the strength of the wastewater, this equalization pond also
has to be equipped with a settler or some other (acidogenic!) sludge
separation device. The installation of such a device may become
particularly beneficial for higher - strength wastewaters, viz. at COD
values exceeding approximately 10 gil.
When applying pre-settling, the same design criteria for the anaerobic
reactor can be applied as for the treatment of mainly soluble wastewaters,
provided the settled wastewater doesn't contain a substantial
concentration of colloidal matter, because in that case the application of
high sludge loading rates may lead to a serious drop in the specific
methanogenic activity of the sludge, perhaps even to a complete loss of
activity after a prolonged period of time.
up to 2000 10 to 30% 2 - 4 8 - 12 2 - 4
30 to 60% 2 - 4 8 - 14 2 - 4
60 to 100% * * *
Another important reason for applying relatively low space loads when a
high TSS-removal efficiency is pursued, is to achieve a satisfactory
stabilization of the accumulated solid substrate ingredients. Particularly
when operated under lower ambient temperature conditions, it �s necessary
to maintain a sufficiently long sludge detention time for that purpose.
For those cases where this condition cannot be met, some other adequate
measures have to betaken,e.g.:
combining the anaerobic reactor with a sludge digester. This
digester can be operated at an elevated temperature. After
stabilization, the sludge can be partially returned to the
anaerobic reactor. This measure can be applied relatively easily
for crASB-reactors and processes using a mixed tank reactor
combined with a sludge separation and return system ("Contact
process"), and
interrupting the feeding and elevating the reactor temperature
during short periods, e. g. during night time or during the
weekend, in the case wastewater is not available. This measure
can be applied for all reactor systems, and does not require a
lot of energy because only the reactor contents have to be
heated.
Both the above measures look quite appropriate for treating slaughterhouse
wastewater (Sayed, 1987) , because generally slaughtering is carried out
during day-time, and during the five or six working days (not at the
weekend) . But there are a lot more situations where no wastewater is being
produced during the weekend or during night time. In case of continuous
operation, consequently continuous production of wastewater, sometimes the
installation of a holding tank could be considered. Another possibility is
to install two anaerobic reactors which are operated in parallel;
alternately the feeding of the reactors can be interrupted for enabling
the sludge to stabilize.
The same solutions can be chosen for treating wastewaters where a heavy
substrate precipitation can occur under specific conditions. A typical
example is dairy wastewater. Under conditions of lower pH (i.e. below pH
approximately 6.2) and overloading, proteins tend to precipitate from milk
(curdling) as large agglomerates. These agglomerates accumulate between
the anaerobic sludge. Relatively much time is required for liquefying
these agglomerates, because its accessibility for enzymes and/or bacteria
is significantly worse compared to the finely dispersed (or colloidal)
proteins present in fresh milk.
series with the anaerobic reactor, the applicable space loading rates for
the granular sludge bed reactor are significantly higher as compared to
flocculent sludge bed UASB's.
So far only very little relevant information is available for the design
criteria of a liquefying reactor. The size of such a reactor depends
strongly on the objectives to be achieved. In the (rather exceptional)
case that complete liquefaction has to be accomplished, the sludge
retention time of the system should be rather long e.g. at temperatures
around 20 °C, in the range of 80 - 120 days. Bearing thi s in mind, the
required size of the reactor then will depend on the daily 55-load, the
55-removal efficiency, the non-biodegradable fraction of the 55, the
liquefaction efficiency and particularly on the sludge concentration that
can be maintained in the reactor.
At these still rather long sludge hold-up times under the higher
temperature conditions cited, it will not be possible to prevent the
occurrence of methanogenesis in this reactor. Therefore - instead of
speaking of a liquefying reactor - the pretreatment step can better be
designated as the first module of a modular 'one-step' anaerobic treatment
system.
Proper designs for acidogenic bio-reactors are not yet available. Existing
acidogenic reactors are simple flow-through systems in which generally
some mixing is applied. So far little if any attempt has been made to
retain higher concentrations of acidogenic sludge in the reactor.
The reason for this relatively poor care can be found in the fact that
acidogenesis proceeds at a higher rate, while a complete acidification of
the substrate generally is not required. Moreover the extent of
acidification can be more or less controlled by the supply of alkalinity,
i.e. by the pH, because the activity of acidogenic bacteria also drops
at decreasing pH-values.
A simple completely mixed tank reactor can be utilized for the pre
acidification. The hydraulic retention time to be utilized will be
determined by the nature of the complex organic matter, the temperature
and the degree of acidification desired. The retention time of the
acidification tank will be in the range of 6 to 24 hours.
We want to emphasize here that in may cases the acidogenic reactor has to
be followed by some sludge separating device, particularly for higher
strength wastewaters. The reason for this is that suspended matter,
including bacterial matter, may disturb the proper operation of the
granular sludge bed methanogenic reactor seriously, while it also greatly
retards the formation of granular sludge in this reactor in the case it
was seeded with a flocculent sludge.
The UASB-reactor
The admissible maximum liquid surface load (based on the wet surface area
in the settler) for granular sludge UASB-reactors can be set at
approximately 3 m/hr average over a day for soluble wastewaters and at 1 -
1.25 m/hr for partially soluble wastewaters. Temporarily, for a few hours
per day, superficial velocities up to 6 m/hr and 2 m/hr can be tolerated
for soluble and partially soluble wastewaters respectively. Under these
conditions most of the granular sludge will be retained in the reactor.
The high superficial velocities may result in the washout of poorly
settleable (smaller!) granular sludge particles, but generally this will
not be accompanied by any serious problems.
For the rather exceptional case where -instead of the organic loading
rate- the liquid surface load would represent the ��miting factor, the
allowable hydraulic retention time (e.) is determined by the surface area
and the height of the reactor, according to the equation:
A H
ea = (1)
Q
H
(2)
e
For dilute types of wastewaters (COD-levels below 1000 mg/l) and for
operational temperatures exceeding 25°C, the reactor volume generally will
be determined by the admissible hydraulic retention time, rather than by
the applicable organic space load, particularly for taller reactors.
However, for sub-optimal mesophilic and psychro�nilic temperature
conditions, generally the admissible organic space 1uQd is the limiting
factor. Figure 1 shows the relationship between the wastewater strength
and the required reactor volume (Vr).
Vr 1m3)
2000 .---
1500
1000 +-----�
0
0 2 3 4 5
( I kg CO Dim 3 )
Fig. 1. Relationship between pollution strength and reactor volume.
3
(Assumptions: e. = 4 h, Q 250 m3/h and Bv 15 kg COD/m . d)
= =
= 6. Q (3)
The allowable hydraulic retention time will depend on the type of sludge
present in the reactor (flocculent or granular) and the quality of the
gas-solids separator.
24 C Q
The lower waste concentration range at which the hydraulic retention time
dictates the reactor volume depends strongly on the applicable space
loading rate as well as the allowable (critical) superficial upflow
velocity in the reactor as indicated in Figure 2.
V, (m3)
2000..---,----r---"
1500
500
-------- ------------------ verrt= 6 m/h
O�-�-�--,--�-�
o 2 3 4 5
( (kg (OO/m3)
For industrial wastewaters generally the controlling factor for the size
of the reactor will be the admissible organic space load (in terms of
biodegradable COD) . This space load greatly depends on the sludge
activity, and thus the temperature and the treatment efficiency pursued
for the various polluting fractions on the composition and the nature of
the pollutants, the sludge concentration, the quality of the feed
distribution system ( i.e. the degree of contact) and the desired safety
factor.
15 2 - 4 1. 5- 3 1. 5- 2 ( satisfactory 88-removal)
20 4 - 6 2 - 4 2 - 3 (satisfactory 88-removal)
25 6 - 12 4 - 8 3 - 6 (reasonable 88-removal)
30 10 - 18 8 - 12 6 - 9 (moderate 88-removal)
35 15 - 24 12 - 18 9 -
14 (fairly poor 88-removal)
40 20 - 32 15 - 24 14 - 18 (poor 88-removal)
For the quoted maximum admissible surface loads, a fairly efficient 88-
removal can be accomplished from very low-strength partially soluble
wastewaters like domestic sewage. For medium-strength wastewaters the 88-
removal efficiency presumably will drop significantly when applying
surface loads in the range of 1 m/h, mainly due to the significantly
higher gas production and consequently higher liquid turbulence in the
system under these conditions.
Feed inlet system. The feed inlet distribution system constitutes a crucial
part of the reactor. For utilizing the retained reactor sludge, it
is important to accomplish an optimal contact between sludge and wastewater,
i.e. channelling of the wastewater through the sludge-bed or the formation
of dead corners in the reactor should be avoided. The danger of channelling
becomes bigger at lower ga s production rates, v iz. less than approximately
3 3
1 m /m .d for a 4-6 m tall reactor, because the gas production contributes
substantially to the mixing of the sludge bed. The ga s production obviously
remains low when the imposed organic loading rate has to be kept low, e.g.
when very dilute wastewaters are treated and the temperature is in the
psychrophilic or low sub-mesophilic range. However, for soluble types of
wastes, even in that case, a fairly good contact between sludge and
wastewater can be accomplished by applying taller reactors, and taller
sludge beds. Generally a granular type of sludge will be present (or will
develop) in the reactor, when treating soluble types of wastewaters.
Table 5 provides rough guidelines for the number of feed inlet points
required.
principle the design of the GSS-device can be fairly simple, i.e. it does
not necessarily constitute a very expensive part of the reactor. Relatively
a lot of research has been spent in recent years for developing new, more
exclusive, systems. Some different designs are shown in the Figures 4 and
5. The last word on the design of the GSS-device certainly has not yet been
said. It is an area of continuous innovation. The objectives of the GSS
device are summarized in Table 6, at least as far as they are relevant for
the treatment of soluble non-complex types of wastewaters.
treated
effluent
gas
�"*�"t-- collection
dome
sludge
blarilet rising
biogas
The formation of a thick scum layer in the gas bowl may sometimes give some
problems, because it hampers the easy release of the biogas. This may
occasionally result in a partial escape of biogas via the settler, which
obviously is quite detrimental for settling out the sludge. In those cases
where heavy scum layer formation cannot be avoided, specific provisions
have to be taken to remove the floating matter from the reactor and/or to
agitate it sufficiently in order to get it settled down. So far the problems
never were so serious that any specific measures were really needed,
although prolonged operation very likely would have made necessary specific
operative interferences. For removing the scum layers, suction could be
applied using a bent pipe which can be brought beneath the gas-bowl and
moved while sucking slowly over the total length of the GSS-device. A
similar (or the sam&) pipe could be used for recirculating biogas through
the scum layer, i.e. by returning it in the reactor immediately beneath the
scum layer.
Scum layer formation generally also occurs at the liquid interface in the
settler, particularly if a baffle has been placed in front of the effluent
weir. In the case where the installation of a baffle in front of the
effluent weir is omitted, floating particles very likely including floating
granular sludge, will rinse out of the reactor. The liquid surface area will
As at a certain fixed space load, the specific gas production rate (m3/m2• d)
increases proportionally with the reactor height. Special attention has to
be given to the construction of the GSS device in the case of taller
reactors in order to prevent foaming problems. Table 7 presents general
guidelines for the construction of GSS-devices.
2. The surface area of the apertures between the gas collectors should be
15-20% of the reactor surface area.
The discharge of the excess (flocculent) sludge should be done from the
upper part of the sludge bed.
The experience with full - scale reactors in the Netherlands showed that
corrosion can represent a major problem. All reactors constructed at the end
of the seventies and beginning of the eighties appeared to be severely
damaged by corrosion after 5 to 6 years of operation. The biggest problem
occurs in the upper part of the reactor, where H2S is oxidized to sulfate by
air (oxygen) . This can lead to very low local pH conditions. Both concrete
and steel will be affected by this. Corrosion by dissolved CO2 will occur
under the water level; CaO from concrete will dissolve as a result of the
presence of carbonic acid. Depending on the construction materials used some
corrosion of the settler plates may occur as a result of the presence of
CO2•
Depending on the t ype of waste tre ated, equipment has to be inst alled for
supplying essential nutrient s , like ammonia, phosphat e, sulphate or
sulphide, and of alkalinity.
In the case where waste heat can be obt ained from t he f act ory or from
elsewhere, or heat can be recovered from t he e ffluent, it may be profitable
to install heat exchange r s . The i n s t a l l at i on of heat exchanger s is also
desirable for occasional heating of the reactor cont ents when accumulated
biodegradable s olids have to be removed from the s ludge.
CONCLUSI ONS
REFERENCES