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AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION
KEY
&
SOLUTIONS
VI to X CLASS
7995745189
AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION
VI CLASS
KEY
&
SOLUTIONS
1 IMPORTANCE OF CHEMISTRY
19. A, B, C
20. A, C, D
6. A 24. B
7. C 26. A
8. B 27. D
9. C
10. C
11. B
12. A
28. A
13. D
14. D
29. A
15. D
16. A
30. 5
17. C
31. D
32. B
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
33. C
18. A, B, C, D
2 NATURE OF MATTER
MATRIX MATCHING TYPE (M.M.T.):
37. A, D 38. B
39. A, D 40. C
1. C 2. A
3. A 4. C
5. C 6. A
7. D 8. C 41. 5 42. 4
9. B 10. B
18. D 19. A
22. A 23. A
4. ATOM
7. IODINE
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
8. GASEOUS
26. A & B 27. A, B, C & D
9. FREEZING
28. A & C 29. A & C
DOWN: ()
30. B & C 31. A, B & D
1. PLAZMA
32. B & C 33. B, C & D
2. MELTING
COMPREHENSION PASSAGE TYPE (C.P.T.):
5. MOLECULE
34. A 35. C 36. B 6. LIQUID
49. C
50. B
Sol: Air flow is not needed for threshing
1. B 2. D 3. C and sieving.
4. B 5. B 6. A 51. B
7. C 8. B 9. D Sol: First iron particles (Z) are separated
10. A 11. C 12. B by magnetic separation method.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Light weight particles (Y) can be
13. D 14. C 15. A separated from heavy particles (X) by
winnowing method.
16. B 17. C 18. A
52. B
19. A 20. A 21. B
Sol: Sugar dissolves in water completely
22. C 23. D 24. D
and forms a transparent solution.
25. B 26. D
53. D
Sol: When the mixture of chalk power,
sugar and water is filtered, chalk
powder is separated as residue.
MULTI CORRECT ANSWER TYPE (M.C.A.T.): If the remaining sugar solution is
29. A & C 30. A, B & C distilled, sugar will be leftover and pure
29. B & C 30. C & D water is collected separately.
31. B & C 32. A, C & D Hence: Q is Chalk powder.
33. A & C P is Sugar solution.
47. A 48. B
24. B
11. A 12. A
Oxide O –2 1. COPPER
Sulhide SO –2 2. ANTIMONEY
Nitride N –3 3. LEAD
35. D 36. E
37. B 38. A
39. C 40. D
41. A 42. B, E
43. A 44. A
45. A 46. A
ACROSS: ()
4. IRON
5. TUNGSTEN
7. POTASSIUM
9. SILVER
10. SODIUM
11. MERCURY
5 CHANGES AROUND US
7. B 8. C
9. A 10. D
11. C 12. A
44. A 45. B
13. A 14. A
17. C 18. D
48. B 49. D
19. D 20. B
21. B 22. B
ACROSS: ()
23. B 24. D
6. SLOW
25. A 26. B
8. IRREVERSIBLE
27. D 28. C
9. PERIODIC
29. C 30. B 10. CHEMICAL
31. A DOWN: ()
1. REVERSIBLE
2. ENDOTHERMIC
3. NONPERIODIC
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
4. FAST
32. B & C 33. A, B & C
5. EXOTHERMIC
34. A & D 35. A, B & D
7. PHYSICAL
36. A, C & D
6 WATER
1. D 2. D 43. A 44. A
3. C 4. B 45. A 46. C
5. B 6. B
7. C 8. A 47. A 48. B
9. A 10. A
11. A 49. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Note: Please inform the students to observe
the following diagram missing in the
12. C 13. A question.
14. B 15. C
16. A 17. C
18. B 19. D
20. A 21. D
22. C 23. C
24. B 25. C
50. D
51. C
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
26. A, B & C 27. A, B & C ACROSS: ()
28. A, B, C & D 29. C & D 2. COLOURLESS
30. A, C & D 31. A, B & C 8. LITERS
32. A, B & D 9. MELTING
10. BOILING
COMPREHENSION PASSAGE TYPE (C.P.T.):
DOWN: ()
33. D 34. C
1. BOILING
35. A 36. A
3. UNIVERSAL
37. A 38. B 4. SOFTENING
MATRIX MATCHING TYPE (M.M.T.): 5. WATER
39. B, D 40. C, E 6. SOFT
41. C, D 42. A 7. HARD
7 INTRODUCTION OF ATOM
MATRIX MATCHING TYPE (M.M.T.):
28. C 29. D
30. A 31. B, E
1. B 2. D
3. C 4. B
5. B 6. C
7. D 8. C 32. A 33. C
9. D 10. B 34. A
11. B
16. C 17. B
5. KANAD
6. ISOTOPES
27. A 4. THOMSON
8 AIMS OLYMPIAD ACADEMY
VI-ADVANCED-CHEMISTRY ELEMENTS AND THEIR CLASSIFICATION
VI CHEMISTRY
1. C 2. C
31. C 32. C
3. A 4. A
5. B 6. B
33. 3 34. 7
7. D 8. C
9. A
16. C 17. B
18. A 19. C
ACROSS: ()
20. D
3. SILICON
6. NEWLAND
7. LAVOISIER
MULTI CORRECT ANSWER TYPE (M.C.A.T.): 8. ELEMENT
21. A, B & C 22. A, B & C DOWN: ()
23. A, C & D
1. SCANDIUM
COMPREHENSION PASSAGE TYPE (C.P.T.): 2. TRIADS
24. B 25. A
4. SODIUM
26. C
5. WEIGHTS
MATRIX MATCHING TYPE (M.M.T.):
27. B 28. D
29. C 30. A
AIMS OLYMPIAD ACADEMY 9
ADVANCED FOUNDATION - CHEMISTRY VII - KEY AND SOLUTIONS
AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION
VII CLASS
KEY
&
SOLUTIONS
1 LANGUAGE OF CHEMISTRY
12. D 27. A, B, C, D
14. C Hydrogen H2
50. A
51. A
36. 2
Sol: H 2 S 52. A
37. 4
Sol: MgSO 4 ACROSS: ()
38. 2 3. CALCIUMOXIDE
Sol: Ca (+2), O(–2) 5. SODIUMSULPHATE
6. NITROGENDIOXIDE
39. A 7. NITRICACID
40. B 8. FERROUSCHLORIDE
42. D 1. AMMONIA
43. C 2. CALCIUMHYDROXIDE
44. A 4. LITHIUMNITRIDE
45. A
46. A
47. C
Sol: Al2SO 4
48. 1) 2
20. B
21. A
1. B
2. A
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
3. A
22. A, B & C
4. C
23. A, B & C
5. B
24. A, B & D
6. C
25. A, B & C
7. D
26. A, B & C
8. A
27. A, B & C
9. A
COMPREHENSION PASSAGE TYPE (C.P.T.):
10. B
28. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
29. D
11. A
30. D
12. D
14. D 31. A, B, D
15. B 32. D, E
6. PHYSICAL
7. PERMANENT
DOWN: ()
39. A
1. REVERSIBLE
40. C
2. CHEMICIAL
41. A
3. OXYGEN
42. D
43. A
44. D
45. A
46. B
47. A
48. C
49. C
50. C
ACROSS: ()
4. YELLOW
25. A
26. D
Sol: HNO3 is reduced and I2 is oxidised.
1. D 2. B 3. A 27. C
4. D 5. C 6. A 28. A
17. B
18. D
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
Sol: H2S is losing hydrogens hence it is
oxidised and it is reducing agent. 29. A, B & C
Sol: The ballanced chemical equation is: COMPREHENSION PASSAGE TYPE (C.P.T.):
2Pb(NO3)2 2Pb + 4NO2 + 2O2 33. C
22. C
34. D
23. A
35. C
24. B
36. D 1. REACTION
37. B 2. CORROSION
38. C 3. DISPLACEMENT
4. EQUATION
39. A
6. PRODUCT
8. REDOX
40. C
41. C
42. A
43. D
44. A
ACROSS: ()
5. REACTANTS
7. COMBINATION
9. DECOMPOSITION
44. C
Sol: Carbon dioxide is non-poisionous but
people feel suffocation in the
1. C 2. B 3. A
atmosphere of crbon dioxide because
4. A 5. B 6. C of lack of oxygen.
7. A 8. B 9. A
10. B 11. A 12. D
45. A
13. C 14. D 15. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
46. C 47. A 48. C
16. D 17. B 18. B
19. B 20. D 21. C 49. A 50. A
VII CHEMISTRY
5 WATER
1. D 2. A 3. D 36. C 37. D
4. D 5. B 6. A
7. D 8. A 9. B 38. A
39. A
10. D
Sol: When oil flowtes on water and covers
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): like a blanket, oxygen from
atomosphere cannot dissolve into
11. B 12. D 13. C
water. So, aquatic animals will because
14. A 15. C 16. B of no oxygen dissolved. Hence, oil
spilled into water can be poison for
17. A 18. C 19. C aquatic life.
43. D 44. B
ACROSS: ()
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
1. ICE
24. B, C & D 25. A, B & D
3. BOILING
26. A, B & C 27. A, B & C
6. DISTILLED
28. A, B & D 9. FREEZING
4. BOILING
MATRIX MATCHING TYPE (M.M.T.):
5. HARD
32. E 33. B
7. WATER
34. A, C 35. D
8. SOFT
17. B
18. C
1. A
19. B
2. B
Sol: For example:
3. C CaCO3 2HCl CaCl2 CO2 H 2O
4. B 20. B
5. C 21. D
7. D 22. A
8. C 23. D
9. A 24. A
10. D 25. A
11. B 26. B
12. A 27. C
13. A 28. B
14. C
35. D
37. B 4. NEUTRALISATION
38. D 6. INDICATOR
39. A 7. STRONGBASES
40. B 8. POTASHALUM
DOWN: ()
41. C, E
1. VINEGAR
2. BLUEVITRIOL
3. SALT
42. C
43. A
44. D
45. A
46. B
47. A
7 STRUCTURE OF ATOM
1. A 2. C 3. B
41. A 42. A
4. B 5. C 6. A
7. C 8. B 9. D
43. B
10. A 11. A 12. C
13. C
44. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
Sol: Most of the alpha particles move
14. C 15. C 16. B
through the gold foil straight with out
17. A 18. C 19. B any deviation.
8 CLASSIFICATION OF ELEMENTS
32. B 33. D
34. E 35. A, C
1. C 2. A
3. A 4. C
5. D 6. B
7. B 8. A
36. A
9. D 10. B
13. C 14. B
39. D 40. B
15. C 16. A
41. C 42. A
17. A 18. A
43. C 44. D
19. C 20. C
45. B
21. D 22. A
23. C 24. D
ACROSS: ()
3. SODIUM
5. POTASSIUM
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
6. CHLORINE
25. C 26. A, B & C
DOWN: ()
27. A, B, C & D 28. A, B & C
1. HYDROGEN
COMPREHENSION PASSAGE TYPE (C.P.T.):
2. ALUMINIUM
29. C 30. D 31. C
4. CARBON
AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION
VIII CLASS
KEY
&
SOLUTIONS
1 ATOMIC STRUCTURE
Mass number = 56
No. neutrons
= Mass number - Atomic number
1. B = 56 - 26 = 30
2. D 22. C
3. B 23. B
4. D Sol: The species with same number of
5. C electrons are called isoelectonics.
6. D 24. B
7. C Sol: The atoms with same mass number
Sol: Tritium (1H3) is the radioactive isotope but different atomic numbers are called
of hydrogen. It has 1 electron, 1 proton isobars.
and 2 neutrons. 25. B
8. D
26. A
Sol: Atoms with same atomic number but
different mass numbers are called 27. B
isotopes. 28. B
9. C Sol: (E1–E2) > (E2–E3) > (E3–E4) > (E4–E5) ...
10. D
29. A
11. B
c 3 108
12. B Sol: 10
6.25 1014 s 1
4800 10
13. B
30. B
14. C
Sol: E h 6.625 1034 3 1015
15. B
19.87 10 19 J 1.987 10 18 J
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
31. D
16. C
17. B
18. B
19. C
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
20. D
32. B, D
21. B
Sol: No. of electrons = No. of protons 33. A, B, C, D
= Atomic number = 26 34. B, C, D
c
C) c
52. C
40. A Sol: A neutral atom may or may not have
equal number of protons and neutrons.
Sol: Wave length ( ) = 97540 cm
53. A
c 310 10
= 0.0000307 × 1010
97540
ACROSS: ()
= 3.07 × 105 s-1
6. ORBIT
41. A
7. NEUTRON
MATRIX MATCHING TYPE (M.M.T.): 8. NUCLEONS
42. A, E 9. NEUTRON
43. B 10. KANAD
44. C, E DOWN: ()
45. D 1. ISOTOPES
2. RUTHERFORD
3. FREQUENCY
4. THOMSON
5. ELECTRON
46. 1
47. 2
2 PERIODIC CLASSIFICATION
23. B
24. B
25. D
1. B
2. B
3. B
4. A MULTI CORRECT ANSWER TYPE (M.C.A.T.):
5. D 26. A, B & C
6. D 27. A, B & D
7. B
28. A, B & D
8. B
29. A & D
9. A
Sol: After the removal of second electron
10. A
from the II A group elements, they
11. A attain stable configuration. Hence they
12. D have greater third IP.
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 30. B, C & D
13. C 31. A & C
14. A
32. A, B & D
15. B
Sol: A- 2He
COMPREHENSION PASSAGE TYPE (C.P.T.):
B- 3Li 33. A
C- 7N 34. C
D- 10
Ne 35. B
E- 30
Zn 36. A
16. C Sol: As electrons are removed from an atom,
17. A protons number will becom more than
electron number. Hence p/e ratio
18. D
increases.
19. D
37. B
20. C
Sol: IP values decreases in a group from
21. C
top to botom.
22. B
2. HELIUM
IE1 + IE2 = 178 + 348 = 526 K cal/mol
3. OCTAVES
MATRIX MATCHING TYPE (M.M.T.):
4. DECREASES
39. C
5. HALOGENS
40. E 8. SEVEN
41. A
42. B, D
43. A, D
44. C
45. B
46. E
47. A
48. B
Sol: The elements in the modern periodic
table are arranged on the basis of their
increasing atomic numbers.
49. C
Sol: The distance from the nucleus to the
outermost orbit of an atom is called its
atomic radius.
ACROSS: ()
6. FLUORINE
7. TRIADS
3 CHEMICAL BOND
17. C
2. B
3. D 4-bond pairs, 2-lone pairs
4. B
5. B
6. B 6-bond pairs, no lone pairs
7. C
8. B 18. A
9. B Sol: Methane(CH 4 ) has 4 bond pairs,
10. C ammonia(NH3) has 3, fluorine(F2) has
2 and nitrogen(N2) has 3 bond pairs.
11. C
19. D
12. A
20. D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
21. D
13. B
22. A
14. B
23. A
Sol: Given A: 2, 8, 3. A loses 3 electrons
and forms A+3. 24. A
A+3 B-2
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
A2 B3
26. A, C & D
Hence the formula of the compound is
A2B3. 27. A & B
36. D
ACROSS: ()
37. B
4. COVALENT
38. D
6. BONDPAIR
MATRIX MATCHING TYPE (M.M.T.):
DOWN: ()
39. A
1. DATIVE
40. C, D
2. GOOD
41. B, E
3. IONIC BOND
42. B, E
5. LEWIS
43. B, E
7. NEON
44. B, D
8. POLAR
45. C, D
46. A
47. A
4 CHEMISTRY OF H2 & O2
20. D
Sol: H H + + e -
2. B 21. B
11. B
12. A
31. A, B, C & D
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
32. B
15. A
17. D Protium 1 1 0
18. B Deuterium 1 1 1
19. D Tritium 1 1 2
34. A, B & C
ACROSS: ()
35. A, C & D
1. PROTIUM
36. A, B, C & D
4. OZONE
COMPREHENSION PASSAGE TYPE (C.P.T.):
7. CATALYST
37. B
8. HYDROGEN
38. C
9. CARBOGEN
39. A
DOWN: ()
40. A
2. REDUCING
MATRIX MATCHING TYPE (M.M.T.):
3. HALOGENS
41. E
4. OXYGEN
42. A, B
5. BASIC
43. D
6. LILAC
44. C
45. C
Sol: 4Na (s) +O2(g) 2N 2O + t
46. C
47. C
48. B
5 CHEMISTRY OF C & N2
MATRIX MATCHING TYPE (M.M.T.):
42. A, D 43. E
44. B 45. C
46. D 47. A
1. D 2. C 3. C
48. C, E 49. BS
4. C 5. C 6. B
7. D 8. B 9. A
13. A
50. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.):
26. C
ACROSS: ()
3. GRAPHITE
5. PNICOGENS
8. ALLOTROPY
27. A, B & C 28. A & D
9. AQUAREGIA
29. A & D 30. A & B
10. NITRE
31. A 32. A, B & D
11. FOUR
33. B & C 34. A & B
DOWN: ()
35. A & B
1. CATENATION
COMPREHENSION PASSAGE TYPE (C.P.T.): 2. OXIDE
36. C 37. B 38. A 4. AMMONIA
16. A
OR
17. D
The ratio of weights of oxygen
18. A combining with fixed weight of nitrogen
19. C (28) is 16 : 32 : 48 : 64 : 80.
ACROSS: ()
2. MULTIPLE
39. A
4. DALTON
40. A
7. GAYLUSSAC
8. CONSERVATION
41. 24
DOWN: ()
Sol: 1:8 3:24
1. PROUST
42. 8
3. LAVOISIER
43. 0.734
5. AVOGADRO
6. DEFINITE
44. C
Na2CO3 = 8.2 g
CO2 = 2.2 g
H2O = 0.9 g
8 NUCLEAR CHEMISTRY
231
iii) 90 Th n = 231 – 90 = 141
Isotopic number = n – p
= 141 – 90 = 51
231
iv) 91 Pa n = 231 – 91 = 140
1. A
Isotopic number = n – p
2. D
= 140 – 91 = 49
3. D 14. C
4. B
Sol: Radioactive isotope of hydrogen is
5. B tritium 31 H (e = 1, p = 1 and n = 2).
6. D 15. D
7. B 16. C
Sol: Half life of a radioactive substance is 17. C
independant of the amount of the
Sol: Magic numbers are 2, 8, 20, 28, 50,
substance.
82 & 126.
8. C 115
i) 50 Sn : Number of protons(p) = 50,
9. B
Number of neutrons(n–p) = 115 – 50
10. C = 65
206
11. D ii) 81 Pb : Number of protons(p) = 81,
Initial amount = 80 g A 4
A
Z 1 Y Z 1 Z 42
After 30 days = 40 g remained
A 4 A4
After 60 days = 20 g remained Z 1 Z Z 1 Z 00
After 90 days = 10 g remained
23. A
20. A
24. B
Sol: Half life the radioactive matter = 6
years Sol: 14
7 N 42 He 17
8 O 1H
1
=6
No. of - particles emmited =
98 Y 101 Y
difference in mass numbers
4
16
4 particles 96 Z 99 Z 99 Z 102 Z
4
238 84
Sol: 239
X 8 24 6 01
92 U 92 32 61
206
The product is 82 X 43. A
A = 206 and Z = 82 44. D
The number of protons (p) = 82
ACROSS: ()
5. ISOTOPES
6. FISSION
8. HALFLIFE
9. BECQUERREL
DOWN: ()
1. RUTHERFORD
2. MASSDEFFECT
3. ISOSTERS
4. FUSION
7. NUCLEAR
AIMS
CHEMISTRY
IIT-JEE, NEET & OLYMPIADS
ADVANCED FOUNDATION
IX CLASS
KEY
&
SOLUTIONS
1 ATOMIC STRUCTURE
6. D 18. C
Sol: Cs has the lowest IP and biggest size, Sol: = 3 × 1015 s–1
so it can release elctrons easily by E = h = 6.625 × 10–34 × 3 × 1015
passing light energy on its surface.
= 19.878 × 10–19 J
= 1.9878 × 10–18 J
7. B
19. A
8. C
Sol: Wave length ( ) = 97540 cm
9. A
Sol: According to De broglie’s wavelength c 31010
= 0.0000307 × 1010
equation 97540
10. C 21. D
28. A 32. A, D
33. A, B, C
Sol: n + l value of 3d = 3 + 2 = 5
n + l value of 4p = 4 + 1 = 5
MULTI CORRECT ANSWER TYPE (M.C.A.T.):
n + l value of 5s = 5 + 0 = 5
29. A, C, D
n + l value of 5p = 5 + 1 = 6
Sol: Bohr’s theory is applicable only
species with one electron COMPREHENSION PASSAGE TYPE (C.P.T.):
30. B, C, D 34. B
Sol: Heisenberg’s principle is applicable Sol: For l = 0, possible m value is 0 but not –1.
only for micro particles which are
moving with high velocity. 35. C
= 1.104 10–33m
40. A 43. D
Sol: The energy of radiation must be equal Sol: Principal quantum number
to or greater than the work functions determaines the energy and size of the
of metals to show photoelectric effect. orbits but not orientation.
We need to convert wavelength of 44. A
radiation into energy expressed in eV
units.
45. A
2 PERIODIC CLASSIFICATION
elements.
IE1 + IE2 = 178 + 348 = 526 K cal/mol
COMPREHENSION PASSAGE TYPE (C.P.T.):
41. A
29. A
42. B
30. C or D
Sol: When an electron is removed from an
Sol: 6 and 7 periods contain 32 elements
th th atom the number of electrons decreases,
each. nuclear attraction on the remaining
electrons increases and hence second
31. D IP will greater than first IP.
36. C 1) TRIADS
2) ALKALIMETALS
Sol: I: Al has an unpaired electron in 3s
orbital where as Mg has paired 3) SEVEN
electrons in 3s.
4) OXIDATION
II: Mg+ has an unpaired electron in 3s
orbital where as Na + has paired 5) DECREASES
electrons in 2p. 7) INCREASES
37. A 8) SCANDIUM
38. B 9) ANGSTROM
I: E.N decreases as size increases. Sol: Add “9. An unit of atomic radius:” in
II: Reducing power (electron loosing down.
tendency) increases as size increases.
3 CHEMICAL BOND
15. C
16. D
1. D
17. B
2. A
18. D
3. A
4. A 19. A
7. B
8. D 21. A
9. A 22. C
10. B Sol: Percentage of p charactar
Sol: SO2 has two bond pairs and one lone
pair on its central atom. no.of p - orbitals
= ×100
total no.of orbitals
11. A 3
= ×100 = 75%
Sol: NH3 - Pyramidal 4
28. A, B, C & D
30. A, B, C & D
47. D
31. A, C & D
48. C
32. A & C
49. D
Sol: As bond length increases, bond energy
decreases.
ACROSS: ()
33. A, B, C & D
3. TWO
COMPREHENSION PASSAGE TYPE (C.P.T.):
6. COVALENTBOND
34. A
7. PYRAMIDAL
Note: Change the question as “Which of
the following elements cannot form 9. IONICBOND
hydrogen bonding?” 10. HYDROGENBOND
Sol: The atoms with high electronegativity DOWN: ()
can participate in hydrogen bonding.
1. POLARBOND
35. B
2. DATIVEBOND
36. D 4. CHEMICALBOND
MATRIX MATCHING TYPE (M.M.T.): 5. SIGMABOND
37. A, E 8. PIBOND
38. C, D
39. C, E
40. B, E
41. C, E
42. B, C, E
43. A, C, D
44. A, C, D
4 MOLE CONCEPT
14. A
Sol: Weight of 1 atom of helium = 4 amu At. Wt. of carbon× No.of atoms of carbon
= ×100
Mol. Wt.
= 4×1.67×10 – 24
g
12× 2
= 6.64×10-24 g = ×100 = 40 %
60
5. B
17. A
18. A
Sol: We have, Percentage mass
Sol: ZnCO3 ZnO CO 2
AW No.of atoms of the element per molecule 1mol 1mol 1mol
100
MW
From the balanced equation
No. of atoms of the element per
MW percentage mass 125 g of ZnCO3 produces 81 g of ZnO
molecule
AW 100
xg of ZnCO3 produces 10 g of ZnO
6. A
125 10
7. A x 15.43g
81
8. B 19. C
9. B Sol: CaCO3
CaO CO 2
1mol 1mol 1mol
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): 100 g of CaCO3 liberates 22.4 L of CO2
Sol: 2C 2 H 6 7 O 2
4 CO 2 6H 2 O
732g 444g
26. A, B & D
176 16
x 12.57g
224 27. A & B
Sol: SiO 2 3 C
SiC 2CO At.wt No.of atoms of the element per molecule
60g 312g 100
Mol.Wt
From the balanced equation
60 g of SiO2 needs 36 g of C 12 1
C % in CO 2 100 27.27
44
20 g of SiO2 needs x g of C
16 2
O % in CO 2 100 72.73
36 20 44
x 12 g
60
28. B & D
22. D 12 3
Sol: C % in C3H6 = 100 85.71
42
Sol:
12 1
A) C % in CH4 = 100 75
16
Element W % W% / At.Wt. Least ratio
H 25 25 / 1 = 25 25 / 6.25 = 4 12 2
C 75 75 / 12 = 6.25 6.25 / 6.25 = 1 B) C % in C2H4 = 100 85.71
28
29. D
From the balanced equation,
30. C
28 g of CO needed 2 22.4 L of H2
Sol: Weight of 1 mole of H 2O 18g
56 g of CO needed x 4 L of H2
Weight of 4 moles of H 2O 18 4 72g
2 22.4 56
x = 89.6 L
28 31. A
33. A
34. C
35. B
36. A
37. A
39. E
40. D
41. B
ACROSS: ()
1. ISOTOPES
6. MOLECULAR
8. AMU
9. STOICHIOMETRY
10. MOLE
DOWN: ()
2. EMPERICAL
3. HYDROGEN
4. MOLECULE
5. ATOMICITY
7. GAYLUSSAC
5 BEHAVIOUR OF GASES
Final volume V2 = 26 L
Final pressure P2 = ? atm
We have P1V1 = P2V2
1. C 2. A 3. A P1V1 1 196
P2 =
4. A 5. A 6. C V2 = 26 = 7.538 atm
7. C 8. A 9. C The final pressure of the gas P2 = 7.538 atm
10. D 11. D 17. A
SINGLE CORRECT ANSWER TYPE (S.C.A.T.): Sol: 35oC = (35 + 273) K = 308 K
12. B 18. A
13. A Sol: Given data:
14. A Initial volume V1 = 5 L
Sol: Given data: Initial pressure P1 = 2 atm
Initial volume V1 = 5 L Initial temperature T1 = 273oC
Initial pressure P1 = 2 atm = (273 + 273) K = 2(273) K
Final volume V2 = ? L Final volume V2 = ? L
Final pressure P2 = 2+3 = 5 atm Final pressure P2 = 1 atm
We have P1V1 = P2V2 Final temperature T2 = 273 K
P1V1 2 5 P1V1 P2 V2
V2 = We have T T
P2 = 5 = 2 L 1 2
V1 V2
VT
T2 = 2 1 = 5 300 = 150 K = –123OC We have T T
1 2
V1 10
The final temperature of the gas T2 V2 T1 2V 273
T2 =
= 150 K or –123OC. V1 = V
30. A, B, C & D = 546 K = 273OC
31. A, B & C The final temperature of the gas T2
32. A&C = 546 K or 273OC.
Sol: Molecular mass of N2O = 44 MATRIX MATCHING TYPE (M.M.T.):
Molecular mass of CO2 = 44 36. D 37. A, B
Molecular mass of He = 4 38. E 39. C
Molecular mass of Ne = 20
Molecular mass of N2 = 28
Molecular mass of CO = 28
COMPREHENSION PASSAGE TYPE (C.P.T.):
33. B 40. 0.5
Sol: Given data: Sol: Given data:
Initial volume V1 = V mL Initial volume V1 = 2 L
Initial pressure P1 = 1 atm Initial pressure P1 = 380 mm
Final volume V2 = ? L Initial temperature T1 = 273oC
Final pressure P2 = 3 atm = 2 273 K
We have P1V1 = P2V2 Final volume V2 = ? L
Final pressure P2 = 760 mm
P1V1 1 V
V2 = Final temperature T2 = 273 K
P2 = 3 = V/3 mL
P1V1 P2 V2
The final volume of the gas V2 = V/3 mL We have T T
1 2
34. A
Sol: Given data: P1V1 T2 380 2 273
V2 =
Initial volume V1 = 48 L T1 P2 = 2 273 760 = 0.5 L
Initial pressure P1 = 99.3 kPa
The final volume of the gas V2 = 0.5 L
Final volume V2 = 16 L 41. 2
Final pressure P2 = ? kPa Sol: Given data:
We have P1V1 = P2V2
Rate of diffusion of Oxygen rO2 = r
PV
P2 = 1 1 = 99.3 48 = 297.9 kPa
V2 16 Rate of diffusion of gas X rX = 4r
The final pressure of the gas P2 = 297.9 kPa Molecular mass of Oxygen = 32 u
35. C Molecular mass of gas X = M u
Sol: Given data:
rX MO2
Initial volume V1 = V We have
rO2 MX
Initial temperature T1 = 0OC = 273 K
Final temperature T2 = 2T K V2
V1
Vol (L)
Temp T
V1 V2
We have T T
1 2
V1 < V2 < V3
N 1. HYDROCARBON
Quinoline 3. CARBON
25. A, B & D 5. BUTANE
Sol: C7H16 - Hept 6. ETHENE
7 SOLUTIONS
Mole fraction of
n NaOH
NaOH X NaOH
n NaOH n H2O
0.1 0.1
0.05
1. A 0.1 1.9 2
2. B 13. A
3. A
wt.of solute
4. C Sol: w% 100
wt.of solute
5. A 10
100
120
6. B
1000
( 83.33)
7. D 120
8. B
14. A
Mol.wt
Sol: Eq. wt. of H2SO4 = Basicity Sol: 3.5% by weight means 3.5g of NaCl
present in 100g of sea water
= 98/2 = 49
24. B
Weight of solute
Sol: Mass%
Weight of solution wt 1000 49 1000
Sol: N 10N
15 Eq.wt V ml 49 100
100 20
15 60
20. B
wt 1000
Sol: m Mol.wt wt.of solvent MULTI CORRECT ANSWER TYPE (M.C.A.T.):
25. A, C & D
3.42 1000
= 0.04m 26. A & D
342 250
27. A & B
21. C
28. A, B & D
Normality
Sol: Molarity = Valencyfactor COMPREHENSION PASSAGE TYPE (C.P.T.):
29. A
1.0
A) M HCl 1M
1
No.of Moles of solute
So l : M
0.4 v.of solution in L
B) M H2SO4 0.2M
2
36. B, E
Strength 2
0.0188 M
Molecular weight 100
37. B, D
32. A 38. B, E
Sol: S = 40 20 180
= = 36g
100
Wt of solute = 10g
Wt.of solvent (water) = 180-36 = 144g
3. DILUTE
Density = 1g /c.c
4. MOLALITY
Volume of solution = mass / density
7. SOLUBILITY
= 40 c.c ( d= m / v)
8. NORMALITY
4 1000
i) Molarity M 2.5M 9. SOLVENT
40 40
41. D 6. SOLUTIONS
30 1000
Molality (m) = 7.14m
60 70
42. D
N
Sol: M
Valency factor
N 2
M HCl 2M
1 1
N 2
C) M H2SO4 1M
2 2
N 4
D) M H2SO4 2M
2 2
8 CHEMICAL KINETICS
15. D
7. D r2 = K[2P][2Q]
8. B
r 2 = 4 r1
Sol: p P + q Q r R + s S
13. A
14. C
Sol: 2A + 3B P
1 1
– r1 r2
2 3
3r1 = 2r2
20 AIMS OLYMPIAD ACADEMY