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Introduction:
The total dissolved solids(TDS) concentration can be related
to the conductivity (CE)of the water, but the relationship is not
a constant. The relationship between total dissolved solids
and conductivity is a function of the type and nature of the
dissolved positively charged (cations) and negatively
charged (anions) in the water and possible the nature of any
suspended materials. For example, a NaCl solution and KCl
solution with a conductivity of 10000 umhos/cm will not have
the sample concentration of NaCl or KCl and they will have
different total dissolved solids concentration.
Conductivity is a measure of water’s capability to pass
electrical flow. This ability is directly related to the
concentration of ions in the water . These conductive ions
come from dissolved salts and inorganic materials such as
alkalis, chlorides, sulfides and carbonate compounds. The
more ions that are present, the higher the conductivity of
water. Likewise, the fewer ions that are in the water, the less
conductive it is. Distilled or deionized water can act as an
insulator due to its very low (if not negligible) conductivity
value. Sea water, on the other hand, has a very high
conductivity.
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Salts dissolve in water to produce an anion and a cation. These
ions make up the basis of conductivity in water.
What is Salinity?
Salinity is an ambiguous term. As a basic definition, salinity is
the total concentration of all dissolved salts in water . These
electrolytes form ionic particles as they dissolve, each with a
positive and negative charge. As such, salinity is a strong
contributor to conductivity.
Total dissolved solids (TDS)
comprise inorganic salts and small amounts of organic matter
that are dissolved in water. The principal constituents are
usually the calcium, magnesium, sodium and potassium and the
anions carbonate, bicarbonate, chloride, sulphate and,
particularly in groundwater, nitrate TDS is expressed in units
of mg per unit volume of water (mg/L) or also referred to as
parts per million (ppm).
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TDS can also affect water taste, and often indicates a high
alkalinity or hardness.
Where do TDS and Salinity Come From?
Conductivity and salinity vary greatly between different bodies of
water. Most freshwater streams and lakes have low salinity and
conductivity values. The oceans have a high
conductivity and salinity due to the high number of the dissolved
salts present.
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and quicker, using a portable hand held instrument. EC is often
used to give an estimate of TDS as a result,
You will however see other units and need to be aware of the
relationships between them. μS/cm relates to other units as
follows:
Result
TDS=1113ppm
Temperature =20.7o C
Specification :
TDS
0.0-131.9ppm
Range 132-1319ppm
1.32-13.19ppt
13.2-66.0ppt
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