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a r t i c l e in f o abstract
Article history: This work compares the technical, economic and environmental (GHG emissions mitigation) perfor-
Received 24 May 2010 mance of power generation and ethanol production from sugarcane residual biomass, considering
Accepted 14 October 2010 conversion plants adjacent to a sugarcane mill in Brazil. Systems performances were simulated for a
Available online 4 November 2010
projected enzymatic saccharification co-fermentation plant (Ethanol option) and for a commercial steam-
Keywords: Rankine power plant (Electricity option). Surplus bagasse from the mill would be used as fuel/raw
Cellulosic ethanol material for conversion, while cane trash collected from the field would be used as supplementary fuel at
Bioelectricity the mill. For the Electricity option, the sugarcane biorefinery (mill +adjacent plant) would produce 91 L of
CHP ethanol per tonne of cane and export 130 kWh/t of cane, while for the Ethanol option the total ethanol
production would be 124 L/t of cane with an electricity surplus of 50 kWh/t cane. The return on
investment (ROI) related to the biochemical conversion route was 15.9%, compared with 23.2% for the
power plant, for the conditions in Brazil. Considering the GHG emissions mitigation, the environmentally
preferred option is the biochemical conversion route: the net avoided emissions associated to the
adjacent plants are estimated to be 493 and 781 kgCO2eq/t of dry bagasse for the Electricity and Ethanol
options, respectively.
& 2010 Elsevier Ltd. All rights reserved.
1. Introduction occurred in the past 25 years, and the first commercial generation
plants are expected within the next 5 years (US DoE, 2009).
Bioenergy is one of the main alternatives to mitigate GHG However, to play a significant role in the sugarcane sector, the
emissions (Faaij, 2006) and enhance energy security through the biochemical conversion technology must be not only a cost-
replacement of fossil fuels. Internationally, promising options lie in effective alternative, but also competitive with the already com-
the utilization of agricultural residues as renewable energy sources mercial steam-Rankine systems for electricity generation from
(Kartha and Larson, 2000; Botha and von Blottnitz, 2006), among bagasse.
which sugarcane residues in Brazil attract special attention. The Comprehensive comparative analyses (Laser et al., 2009b) have
primary use of bagasse today is as energy source in mill’s CHP showed that the mature advanced technology to produce ethanol
systems to provide the energy requirements of sugar and ethanol from ligno-cellulosic materials (ammonia fiber expansion (AFEX)
processes. Some electricity surplus is also currently produced, and pre-treatment and consolidated bioprocessing (CBP)) would be
this option has a great potential for expansion as mills adopt more profitable and able to mitigate more GHG emissions than
modern, commercial high pressure–temperature cogeneration Rankine-cycle systems, considering switchgrass as feedstock in the
systems (NAE, 2005). Several mills are investing in these systems, US context. Different conclusions are presented by Botha and von
and electricity is consolidated as an additional product of the Blottnitz (2006) regarding environmental benefits. The authors
Brazilian sugarcane sector. In 2008, the average surplus generation analyzed the benefits of bagasse-derived electricity (replacing
for a sample of 124 mills was 10.7 kWh/t cane, and the average for coal-based electricity) and fuel ethanol (replacing gasoline and
the mills selling power was 25 kWh/t cane (UNICA, 2009). tetra-ethyl lead) on a lifecycle basis in a developing country
For the near future, the biochemical conversion of ligno- context, using South African data. For the conversion technologies
cellulosic materials to ethanol could be the main alternative modeled (electricity cogeneration and dilute acid hydrolysis), the
technology (Seabra et al., 2010). Significant RD&D efforts have electricity option would be preferred on energy and carbon balance
indicators and energy industry associated impacts (acidification
and eutrophication), while the liquid fuel option would be pre-
n
Corresponding author. Tel.: + 55 19 3521 3284. ferred in terms of resource depletion and toxicity concerns. The
E-mail address: jeaseabra@gmail.com (J.E. Seabra). authors concluded that in the near term, the environmentally
0301-4215/$ - see front matter & 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enpol.2010.10.019
422 J.E.A. Seabra, I.C. Macedo / Energy Policy 39 (2011) 421–428
a
From Seabra et al. (2010). Values estimated for a mill with capacity of 4 Mt
2.1. Sugarcane mill
cane/year.
The biochemical conversion of ligno-cellulosic materials to Table 3 presents the overall production summary related to the
ethanol is not a commercially available technology yet. The sugarcane biorefinery, combining products from the mill and
analysis performed here is based on a projected system described adjacent plant. In the Electricity option, the total electricity surplus
in Seabra et al. (2010), which is derived from an updated process was estimated at 130 kWh/t cane, which is consistent with other
design version of the 2002 NREL report (Aden et al., 2002). The studies considering similar assumptions (NAE, 2005; Walter et al.,
process consists in the conversion of bagasse into ethanol using 2005). Alternatively, the adjacent biochemical conversion plant
dilute acid pretreatment followed by enzymatic hydrolysis and co- would lead to an additional ethanol production of about 33 L/t
fermentation (see Fig. 3). cane, but restricting the total electricity surplus at the level of
The system performance was estimated using reported Aspen 50 kWh/t cane. The total energy output of the biorefinery would be
PlusTM models, developed by NREL, with the 2012 ethanol cost around 2.4 GJ/t cane for the Electricity option and 2.8 GJ/t cane for
performance targets (Aden et al., 2002; Humbird and Aden, 2008). the Ethanol option.
As presented in Seabra et al. (2010), the ethanol yield was To compare the economics of both options, we used production
estimated at approximately 370 L/tdry of bagasse; in addition, costs and energy prices that are current in Brazil today. As
the high amount of residues that cannot be converted into ethanol presented in Table 4, the fixed capital investment (FCI) related to
leads to a high potential to export power, evaluated at 0.56 kWh/L the adjacent power plant is estimated at 51 M US$, while for the
ethanol. biochemical conversion plant it would be above 151 M US$.
Operating costs of the bioconversion plant are also estimated to
be much higher than for the Rankine-cycle power plant, leading to a
return on investment (ROI) of 15.9% for the Biochemical option, in
comparison to 23.2% verified for the Electricity option.
Table 3
Sugarcane biorefinery’s production summary.a
Mill
Ethanol 103 m3/year (L/t cane) 364 (91) 364 (91)
Electricity GWh/year (kWh/t cane) 126 (32) 126 (32)
Adjacent plant
Ethanol 103 m3/year (L/t cane) – 134 (33)
Electricity GWh/year (kWh/t cane) 392 (98) 75 (19)
Biorefineryb
Ethanol 103 m3/year (L/t cane) 364 (91) 498 (124)
Electricity GWh/year (kWh/t cane) 519 (130) 201 (50)
a
Based on a cane input of 4 Mt/year plus 224,000 t cane trash (dry).
Fig. 2. Schematic representation of the steam-Rankine power plant. b
Biorefinery ¼ mill+ adjacent plant.
Fig. 3. Process flow diagram for biochemical conversion of bagasse to ethanol (modified from Aden et al., 2002).
424 J.E.A. Seabra, I.C. Macedo / Energy Policy 39 (2011) 421–428
30% 30%
ROI
ROI
20% 20%
10% 10%
0% 0%
40% 60% 80% 100% 120% 140% 160% 40% 60% 80% 100% 120% 140% 160%
Parameter variation Parameter variation
Ethanol price Electricity price FCI Scale
Fig. 4. Sensitivity analysis for ethanol and electricity prices, fixed capital investment (FCI) and scale. Reference case (100%) as of Table 4.
20% 20%
15% 15%
ROI
ROI
10% 10%
5% 5%
0% 0%
10 20 30 40 50 10 20 30 40 50
Cane trash cost (US$/tdry) Cane trash cost (US$/tdry)
Bagasse at 0 US$/t dry Bagasse at 10 US$/t dry Bagasse at 20 US$/t dry
700 Table 5
Projected parameters for sugarcane production in 2020.a
600
Units Value
Ethanol price (US$/m3)
500 Parameter
Cane productivity t/ha 95
400 Harvested area % total area % 90
Total diesel consumptionb L/ha 350
Unburned cane harvesting % 100
300
Mechanical harvesting % 100
Total trash yield kgdry/t cane 140
200 Cane trash collection % 40
Above ground nitrogenc g/t cane 992
100 Agr. Inputs
N g/t cane 548
0 P2O5 g/t cane 32
50 60 70 80 90 K2O g/t cane 70
CaCO3 g/t cane 4,947
Electricity price (US$/MWh)
a
Values projected by CTC specialists. Parameters not presented here are
Fig. 6. Equal ROI prices for ethanol and electricity.
assumed to be equal to the current averages (Seabra and Macedo, 2010).
b
Includes diesel consumption in all activities (sugarcane farming, harvesting,
performed the analysis apart from GREET, based on aggregated transportation, etc.).
c
information from Brazilian Chemical Industry Association Estimated above ground nitrogen availability related to crop and industrial
residues returned to the soil. We assumed that 60% of the available trash would
(Abiquim, 2008).
remain on the ground after cane harvesting.
The avoided emissions were estimated considering the sub-
stitution of sugarcane products for the equivalent products in as presented in Table 6. Small differences are observed in the
Brazil. Anhydrous ethanol substitutes for gasoline, as E22 blends to sugarcane processing; in the Electricity option, greater direct
operate in gasohol dedicated cars, while bagasse-derived electri- emissions are verified, derived from bagasse combustion, while
city displaces natural gas thermoelectric generation, which is the Ethanol option present greater emissions associated to chemicals
main fuel of the marginal electricity generation in Brazil (Seabra production. For the Ethanol option, emissions from ethanol trans-
and Macedo, 2010). port and distribution and fuel combustion (tailpipe emissions) are
Since sugarcane production parameters are the same for both naturally greater than for the Electricity option, due to the higher
technology routes, the total GHG emissions resulted to be similar, ethanol yield per tonne of cane.
426 J.E.A. Seabra, I.C. Macedo / Energy Policy 39 (2011) 421–428
Table 6 120
GHG emissions balance for the sugarcane biorefinerya (kg CO2eq/t cane).
Table 7
GHG emissions balance for the adjacent plant (kg CO2 eq/t dry bagasse).
mitigation promoted by ethanol with respect to gasoline is
Electricity option Ethanol option
frequently used. In many cases, the conclusions about which
Total emissions 148 173 option promotes the greater mitigation are difficult: co-products
Bagasse ‘‘production’’a 120 120 credits can result in apparently greater benefits than higher ethanol
Bagasse processing 28 33 yields, since emissions are evaluated per cubic meter of fuel. For the
Ethanol T&D 14
Tailpipe emissions 6
cases evaluated here, for instance, ethanol life-cycle emissions
would be 19 and 5 g CO2eq/MJ, respectively for the Electricity
Avoided emissions 641 955
and Ethanol options. The electricity option apparently presents a
Marginal electricity displacement 641 122
Gasoline displacement 833 better environmental performance essentially because more cred-
its are assigned to ethanol, while less fuel is produced per tonne of
Net avoided emissions 493 781
cane. Therefore, comparisons leveled by the feedstock, or prefer-
a
Part of the sugarcane production emissions was allocated to the surplus ably by unit of land area, are more appropriate to evaluate the
bagasse, based on the energy content of mill’s products (ethanol, electricity and overall benefit.
bagasse surplus). Ethanol and bagasse energy flows were calculated using the
respective lower heating values, and for electricity, we considered a heat rate of
9 MJ/kWh.
5. Energy policies and the decision: ethanol or electricity from
bagasse and trash?
Despite the additional emission sources, the Ethanol option is
able to mitigate more GHG emissions. This environmental advan- Energy policies which may lead to decisions on producing more
tage is stressed in Table 7, which presents the emissions balance electricity or more ethanol from cane residues will probably be
related only to the adjacent plants. In this table, only the inputs and essentially local, Brazilian policies rather than global initiatives like
outputs of the adjacent plant are considered (i.e., the ethanol and the Clean Development Mechanism (CDM) or carbon taxes.
electricity produced at the mill are not taken into account). Since a The context for the Brazilian sugarcane industry shows a
biorefinery concept is involved, with the production of multiple strong growth: 387 Mt cane/year, in 2005/2006; 564 Mt in 2008/
products, a procedure was adopted to allocate the upstream 2009, and projected 1100 Mt cane/year, in 2020 (UNICA, 2010).
emission burdens among the products from the mill and the Sugar production will take 30% of the cane in 2020 (against 40%
adjacent plant. Emissions derived from cane production were today); ethanol (as fuel for internal market and exports,
allocated based on the energy content of mill’s products (ethanol, and less than 10% for industrial uses including plastics production)
electricity and bagasse surplus), leading to the ‘‘bagasse produc- will use the largest portion (EPE, 2010). All uses will provide
tion’’ emissions. Alternatively, emissions credits from the co- surplus bagasse and trash for electricity (or ethanol). Since 2002 a
products could be assigned to the main product using a system large number of mills is being built, and the decision to produce
expansion method. more electricity is made at this point, involving the adoption of
Though avoided emissions by the displacement of NG thermo- higher pressure boilers, condensation capacity, turbines and
electricity are significant (even for the Ethanol option), the benefits generators.
of ethanol substitution for gasoline determines the preference for The experience to date shows that:
the liquid fuel production. Nevertheless, power generation is
preferred if more carbon intensive fuels (coal, for instance) are 1. There have been no significant government policies to promote
considered for the marginal electricity generation, as illustrated in (or support) ethanol since 1990. The only policy remaining from
Fig. 7. Similarly to the economics, these results are sensitive to the the Pro-Alcool program is the mandatory 20–25% blend with
products yields (net avoided emissions and yields have a practically gasoline (which accounts for a relatively small portion of the
linear relationship), and differences in the assumed process ethanol used). Ethanol became competitive with gasoline at
efficiencies may change the final results. relatively low oil prices (BNDES, CGEE, 2008). Growth has been
For different biorefinery concepts (and feedstocks) producing assured by technological innovation (like the flex-fuel car,
ethanol (or other biofuel), the comparison between the emissions today).
J.E.A. Seabra, I.C. Macedo / Energy Policy 39 (2011) 421–428 427
2. Ethanol is not considered eligible for any carbon credit (like needs and annual expenses for the Ethanol option would be far
CDM, for instance). Surplus electricity is eligible, but the values greater than the values for the conventional power plant, resulting in a
paid are not significant (today) to lead to a positive response considerably lower return on investment (ROI). The economics for the
from the investors. biochemical conversion may improve as technology advances, lead-
3. Today the technology for producing electricity is commercial, ing to lower capital needs and greater yields; and better integration of
well known in Brazil, and the extra cost for a new mill to these systems with the sugarcane mill may also improve results even
incorporate it is acceptable. The technologies for 2nd genera- in the short-term. The sensitivity analyses show that the biomass cost
tion ethanol are not available, and they may not become fully has a significant impact on the economic performance, especially for
tested, commercial, before 2015 in Brazil (Seabra, 2008). Even the Electricity option. For high bagasse (or trash) costs the return on
then, the ethanol costs may be higher than the 1st generation investment for the Electricity option would be lower than for the
ethanol. This means: it may need subsidies for some time, and Ethanol option.
this will be very difficult to obtain in Brazil. For the baseline conditions assumed here, the environmentally
4. The most important point: the Brazilian electricity supply preferred option, with respect to GHG emissions mitigation, is the
system is 85% from hydro power; the 15% from thermal biochemical conversion route. Ethanol substitution for gasoline
power complements the demand (for both the Integrated and leads to greater emissions mitigation than the displacement of the
Isolated systems). Projections (EPE, 2009) indicate that from natural gas thermoelectricity by bagasse derived electricity. In this
2008 to 2017 the installed capacities for hydroelectricity will case, the establishment of a carbon market embracing fuel ethanol
decrease from 81.9% to 70.9%, increasing in fuel oil-based power can improve the biochemical conversion route competitiveness,
(0.9 to 5.7%). The affluent energy for hydroelectricity is highly even though the necessity to rapidly expand the power generation
seasonal: in the dry season it drops to 30–40% of the rain season capacity in Brazil is also an important factor to be considered in this
(Castro et al., 2010). New hydro units have much smaller water comparison.
reservoirs: in 1970 the reservoirs corresponded to 28 months of
operation, and in 2008 only 6 months. This leads to increasing
dispatch of thermal power to help the supply system. The Acknowledgements
bagasse based units are inflexible thermal based systems (they
are always dispatched). They are in the lowest range of CVU The authors thankfully acknowledge UNICA for helping in the
(unit variable cost) for the thermal systems (Castro et al., 2010). revision of this work. Specialists of the Centro de Tecnologia
The bagasse based power generation happens in the dry season Canavieira (CTC) are also gratefully acknowledged for the data
(May–November), in complementation to the hydro affluent provision and assistance in the analysis. Discussion with specialists
energy. from the Argonne National Laboratory (IL, USA) and the National
5. For the reasons above, the Brazilian government started (a few Renewable Energy Laboratory (CO, USA) in the context of the
years ago) to promote the use of bagasse-generated electricity. Brazil-USA bilateral collaboration on advanced biofuels was also
This includes long-term contracts (15 year), lower interest rates very important for this work.
in financing equipment specific for higher efficiency in power
generation in cane processing units, specific auctions to buy
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