Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
net/publication/290299875
CITATIONS READS
4 98
2 authors:
Some of the authors of this publication are also working on these related projects:
All content following this page was uploaded by Vesna Marija Potočić Matković on 07 April 2017.
Key words: coated knitted fabrics, polyurethane, elongation properties, tensile strength.
Photograph
(200× magnification)
86 Potočić Matković VM, Skenderi Z. Mechanical Properties of Polyurethane Coated Knitted Fabrics.
FIBRES & TEXTILES in Eastern Europe 2013; 21, 4(100): 86-91.
n Samples and working method Table 2. Elongation properties of knitted fabric.
Samples Sample
Elongation in the: Breaking force in the: Ball bursting
wale course wale course
Seven knitted fabrics with different of knitted
direction - direction - direction - direction -
elongation - breaking
structures (designations KF1 - KF7) were
fabric
ekw. % ekc. % Fkw. N Fkc. N
ekb. mm force - Fkb. N
chosen to cover a wide interval of values KF1 116.35 126.49 907.52 501.82 33.67 1058.30
of the characteristics of elongation and KF2 107.20 102.88 347.64 429.30 33.67 651.70
breaking forces tested (Tables 1 & 2). KF3 46.41 34.96 117.99 66.27 26.17 102.50
They were coated under the same condi- KF4 124.97 49.11 104.61 71.71 31.00 73.33
tions, on the same coating line, with three KF5 309.93 145.22 237.48 185.68 54.33 113.33
different polyurethane coatings (desig- KF6 101.15 157.93 264.29 212.09 39.83 351.67
nated PU1 - PU3). The first type of poly- KF7 65.91 151.21 384.03 212.12 29.83 581.70
urethane coating (PU1) was prepared on
the basis of hydrophilic polyester, which
Table 3. Properties of polyurethane coating.
is used to obtain polyurethane coatings
which let water vapour pass through. The Ball bursting:
Coating Mass, Thickness, Elongation,
second type (PU2) on the polyester ba- sample
Raw material composition
g/m2 mm % elongation, breaking
sis was used to obtain a coating that let mm force, N
PU on the basis of
a moderate amount of water vapour pass PU1
hydrophilic polyester
81 0.16 456.00 72.00 72.00
through, and the third type of coating PU2 PU on the basis of polyester 80 0.15 562.67 65.50 63.25
(PU3) was obtained from the copolymer PU on the basis of
of polyester and polyether, providing PU3 copolymer of polyether/ 77 0.16 680.67 62.67 45.00
an impermeable compact polyurethane polyester
FIBRES & TEXTILES in Eastern Europe 2013, Vol. 21, No. 4(100) 87
450 400
Knitted fabric Coated fabric PU1 Knitted fabric Coated fabric PU1
400 350
Coated fabric PU2 Coated fabric PU3 Coated fabric PU2 Coated fabric PU3
350
300
Elongation, %
Elongation, %
300
250
250
200
200
150
150
100
100
50 50
0 0
KF1 KF2 KF3 KF4 KF5 KF6 KF7 KF1 KF2 KF3 KF4 KF5 KF6 KF7
Figure 1. Elongation in the wale direction of the knitted fabric. Figure 3. Elongation of the test samples in the course direction of
the knitted fabric.
fabrics, are shown in Figure 1. The knit- as the same type of polyester coating for the corresponding polyurethane coated
ted fabrics elongated from 46.41% to elongation in the wale direction. knitted fabric.
309.93%, which is a consequence of their Regression analysis indicates the rela-
different structures. The coated knitted tionship between the elongation of the Elongation in the course direction
fabrics elongated in the wale direction knitted fabric and that of the polyure- Figure 3 shows individual elongations in
from 44.41% to 382.44%. the course direction of all samples of the
thane-coated knitted fabric. Linear re-
knitted fabrics tested as well as that of the
gression model ecw = 1.2312 ekw - 8.4717 coated knitted fabrics. The knitted fab-
The coated knitted fabric has a consid- explains the relationship of the occur- rics elongated from 34.96% to 157.93%,
erably higher average elongation in the rences observed, giving the possibility which is a consequence of the different
wale direction in relation to the knitted to predict the values of elongation of the structures of knitted fabrics and yarns
fabric - on average about 16%, apart from polyurethane-coated knitted fabric (ecw) used. The coated knitted fabrics elongat-
the least stretchable knitted fabric (KF3), for known values of elongation of the ed in the course direction from 96.15%
which was not affected by the coating. to 358.75%. The coated knitted fabric has
knitted fabric (ekw) (Figure 2). The co-
Namely the KF3 sample was knitted in a considerably higher average elongation
efficient of determination R2 = 0.9915
a power-net structure (Table 1), where in the course direction in relation to the
confirms that 99.15% of the elongation
elongation in the wale direction depends knitted fabric - on average about 102%.
variance in the wale direction in the
directly on elongation properties of the
samples of coated knitted fabrics stud- The t-test shows that there is no statisti-
vertically laid yarn (and not formed into
ied is explained with the elongation of cally considerable difference between the
loops).
the samples of the same knitted fabrics mean values of elongation of the knitted
studied. With such a high coefficient of fabrics coated with three different types
It is interesting to investigate whether
determination R2, it can be concluded of PU coating (p = 0.72) for the elonga-
there is a difference between the knitted
that it is possible to use the regression tion in the course direction.
fabrics coated with three different types
of PU coating. However, the t-test shows model obtained for easy prediction of Regression analysis showed that the re-
that there is no statistically consider- the behaviour of the coated knitted fabric lationship between the elongation of the
able difference between the mean values and the choice of an appropriate knitted knitted fabric and the coated knitted fab-
of elongation of the groups of samples fabric substrate, which accelerates and ric in the course direction have only a
tested (p = 0.92) or they can be observed simplifies the manufacturing process of medium correlation (r = 0.79).
y = 1.2312x - 8.4717
350 350 4
R2 = -0.9915 R2 = 0.6262 y = 5.9156x-0.882
Elongation of coated fabric, %
3.5
300 300 R2 = 0.7885
3
Elongation ratio
250 250
2.5
200 200
2
150 150
1.5
100 100
1
50 50 0.5
0 0 0
0 50 100 150 200 250 300 350 0 50 100 150 200 0 1 2 3 4 5 6
Figure 2. Elongation: Scatter diagram and Figure 4. Elongation: Scatter diagram Figure 5. Relationship between the ratio of
linear regression model in the wale direc- and model of exponential regression in the knitted fabric thickness and coating thick-
tion of the knitted fabric. course direction of the knitted fabric. ness and that of the elongation of the coated
fabric and fabric.
88 FIBRES & TEXTILES in Eastern Europe 2013, Vol. 21, No. 4(100)
Figure 6. Elon- as the mean values of elongations of the
60 gation of the test coated knitted fabrics (PU1-PU3) are
Knitted fabric Coated fabric PU1
samples of knitted
50
Coated fabric PU2 Coated fabric PU3
fabric and coated shown in Figure 6. The knitted fabrics
knitted fabric dur- elongated from 26 to 68 mm until ball
Elongation, mm
R2 = 0.9292
the elongation of the coated fabric and in the course direction and the two vari-
40
uncoated fabric (Figure 4, Table 5) ables observed. The so-called aggregate
and more significantly deviate from the test of the significance of the regression 35
adapted theoretical curve of the exponen- model confirms that the model is statisti- 30
tial model. By further research it could cally significant. The P-value of the em-
be concluded that these coated knitted pirical F-ratio (Significance F) = 0,0304 25
FIBRES & TEXTILES in Eastern Europe 2013, Vol. 21, No. 4(100) 89
1200 800
Knitted fabric Coated fabric PU1
Knitted fabric Coated fabric PU1
Coated fabric PU2 Coated fabric PU3
Coated fabric PU2 Coated fabric PU3 700
1000
600
800
500
Force, N
Force, N
600 400
300
400
200
200
100
0 0
KF1 KF2 KF3 KF4 KF5 KF6 KF7 KF1 KF2 KF3 KF4 KF5 KF6 KF7
Figure 8. Breaking forces measured in the test samples in the wale Figure 10. Breaking forces measured in the test samples in the
direction of the knitted fabric. course direction of the knitted fabric.
spherical elongation will show poorer tween the breaking forces of the three forces in the course direction of the knit-
characteristics. polyurethane-coated groups of samples ted fabric - on average about 27%.
tested (p = 0.93).
The model of linear regression The t-test shows again that there is no
ecb = 0.7468 ekb + 6.1557, with coef- Linear regression model Fcw = 1.098 Fkw + statistically significant difference be-
ficient of determination R2 = 0.9292, tween the breaking forces of the three
+ 48.736, with the coefficient of determi-
explains the relationship between the polyurethane-coated groups of samples
nation R2 = 0.9802, explains the relation-
occurrences observed, giving the possi- tested (p = 0.88).
ship between the occurrences observed,
bility to predict the values of elongation
giving the possibility to predict the val-
of the polyurethane-coated knitted fabric Regression model
ues of breaking forces in the wale direc-
(ecb) for known values of elongation of
tion of the polyurethane-coated knitted Fcc = 99.51×1,0039Fkc,
the knitted fabric (ekb) (Figure 7).
fabric (Fcw) for known values of break- with the coefficient of determination
Breaking force of the coated and ing forces of the knitted fabric (Fkw) R2 = 0.9367, explains the relationship
uncoated knitted fabrics (Figure 9). between the occurrences observed, giv-
Breaking force in the wale direction ing the possibility to predict the values
Breaking force in the course direction of breaking forces in the course direction
The individual breaking force measured
of the knitted fabric of the polyurethane-coated knitted fabric
in the wale of all the samples of the knit-
ted fabrics tested as well as that of the The individual breaking forces measured (Fcc) for known values of breaking forces
coated knitted fabrics are shown in Fig- in the course direction of the samples of of the knitted fabric (Fkc) (Figure 11).
ure 8. Breaking forces from 104.6 N to knitted fabrics tested as well as those of
907.5 N were measured in the knitted the coated knitted fabrics are shown in Breaking force of the spherical burst
fabric of different structures. Breaking Figure 10. of the knitted fabric and coated knitted
forces from 136.7 N to 1053 N were fabric
measured in the coated knitted fabrics. Breaking forces from 66.27 N to 501.8 N The mean breaking force measured in
The coating caused slightly higher break- were measured in the knitted fabric. The all samples of the knitted fabric tested as
ing forces – on average 24%. bursting of the coated knitted fabrics in well as that of the coated knitted fabrics
the course direction occurred at break- are shown in Figure 12. Breaking forces
The t-test shows again that there is no ing forces from 108.1 N to 672.2 N. The from 73 N to 1058 N were measured
statistically significant difference be- coating caused an increase in breaking in the knitted fabrics and from 91 N to
1228 N in the coated knitted fabrics.
y = 1.2312x - 8.4717
350 350 2
R = 0.6262
is no statistically significant difference
R2 = -0.9915
Elongation of coated fabric, %
90 FIBRES & TEXTILES in Eastern Europe 2013, Vol. 21, No. 4(100)
Figure 12. Break- It is possible to use the regression mod-
1400
Knitted fabric Coated fabric PU1
ing forces meas- el obtained for simple prediction of the
ured in the samples
1200
Coated fabric PU2 Coated fabric PU3
tested - ball burst- behaviour of coated knitted fabric and
1000
ing. choice of an appropriate knitted fabric
substrate to accelerate and simplify the
Breaking force, N
800
manufacturing process.
600
400
Acknowledgement
200
This work was supported by the Ministry of
0
KF1 KF2 KF3 KF4 KF5 KF6 KF7
Science, Education and Sports of the Repu-
blic of Croatia [grant number 117-0000000-
2984].
breaking forces in the samples of coated with great certainty knowing that of the
knitted fabrics (Fcb) studied is explained knitted fabric and the ratio of knitted fab-
with the breaking forces of the samples ric thickness and coating. A multiple lin- References
ear regression model, with a coefficient
of multiple correlation R = 0.91, explains 1. Poje-Stella M. Tekstil 2002; 51; 10: 470-
477.
4.5 the relationship between the elongation
2. Skenderi Z. et al. Knitted fabric and pol-
4
y = 5.9156x-0.882
of the knitted fabric and coated knitted yurethane composites. In: 3rd Scientific-
3.5
R2 = 0.7885
fabric. Profesional Symposium Textile Science
3
and Economy, Zagreb, 2010.
Elongation ratio
2.5 Elongation of coated knitted fabrics in 3. Soljačić I. Tekstil 1974; 23; 11: 829-844.
2 ball bursting decreases in comparison 4. Fung W. Coated and laminated textiles.
1.5 to the same non-coated knitted fabrics Woodhead Publishing, Cambridge,
1 by about 8%. It is possible to conclude 2002, pp. 7-9.
0.5 that polyurethane coating prevents fabric 5. Kovacevic S. et al. The impact of nano-
pur coating on fabric properties. In: III In-
0 stitches from taking a favorable position
0 1 2 3 4 5 6 ternational Expert Conference Safety at
Thickness ratio
for the spherical application of force, Work and Health Safety, Zadar, 2010.
thereby providing greater resistance. 6. Farboodmanesh S. et al. Rubber Chem-
Figure 13. Breaking forces: Scatter dia-
A model of linear regression explains istry and Technology 2006; 79; 2: 199-
gram and model of linear regression in ball 92.92% of the relationship between the 216.
bursting. elongation of the knitted fabric in ball 7. Minami H, Motobayashi S. Journal of In-
bursting and that of the coated fabric. dustrial Textiles 1981; 11; 1: 24.
of the same knitted fabrics investigated Coating caused an increase in the break- 8. Chen S. et al. Textile Research Journal
ing force during the bursting of the 2007; 77; 6: 369-74.
(Fkb).
9. Mewes H. Journal of Industrial Textiles
samples of coated knitted fabrics in the
1989; 19; 2: 112.
course direction by about 27% and in the 10. Hu H, Xu Y. Autex Research Journal
n Conclusions wale direction by about 24%. 2008; 8 1: 13-16.
Although coating significantly changes 11. Luo Y, Hu H. Composite Structures
the mechanical properties of knitted Breaking forces in the wale direction of 2009; 89: 536-542.
fabrics, the properties of coated knitted the coated knitted fabrics may be pre- 12. Kovacevic S. et al. Coated Textile Ma-
dicted with great certainty. A linear re- terials in Dobnik Dubrovski P. (ed.) Wo-
fabrics are primarily determined by the
gression model explains 98.02% of the ven Fabric Engineering, InTech, Rijeka,
properties of the knitted substrate. 2010, pp. 241-254.
variance of breaking forces in the wale
13. Potocic Matkovic VM. et al. Effect of knit-
Elongation in the course direction of the direction of the samples of coated knitted ted substrate on the composite of knitted
knitted fabric significantly increases af- fabrics studied. fabric and a polyurethane. In: 4th Scien-
ter coating - on average by about 102%, tific-Profesional Symposium Textile Sci-
while the increase in elongation by Breaking forces in the course direction of ence and Economy, Zagreb, 2011.
coating in the wale direction is lower, the coated knitted fabrics can also be pre- 14. Soljačić I. Umjetna koža (Artificial leath-
amounting to about 16%. dicted. An exponential regression model er) in Tehnička enciklopedija, Leksiko-
explains 93.67% of the variance of the grafski zavod Miroslav Krleža, Zagreb,
Elongation in the wale direction of breaking forces in the course direction 1997, pp. 344.
15. Instruction manual Recomo; Recomo
coated knitted fabrics can be predicted in the of coated knitted fabrics samples
S.P.A., Sovizzo, 2002.
with great certainty knowing that of the studied. 16. ISO 1421: 1998.
knitted fabric. A linear regression model 17. EN 12332-1:1998.
explains 99.15% of the relationship be- Coating caused greater resistance to 18. ASTM D 3787 – 89.
tween the elongation of the knitted fabric spherical bursting - on average 13%. A lin- 19. EN ISO 2286-2:1998.
and coated knitted fabric. ear regression model explains 99.56% of 20. EN ISO 5084:1996.
the relationship between breaking forces
Elongation in the course direction of measured in the knitted fabric and those
coated knitted fabrics can be predicted in the polyurethane-coated knitted fabric. Received 23.05.2012 Reviewed 01.10.2012
FIBRES & TEXTILES in Eastern Europe 2013, Vol. 21, No. 4(100) 91