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SOLUTIONS
c om
of g.
ng
Mock Test 1
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(Paper-1)
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2 Mock Test 1 (Paper-1) - Answers & Hints

MOCK TEST - 1
(Paper - I)

ANSWERS
CHEMISTRY MATHEMATICS PHYSICS
1. (B) 21. (D) 41. (B)

2. (B) 22. (C) 42. (C)

3. (C) 23. (A) 43. (C)

4. (B) 24. (D) 44. (B)

om
5. (D) 25. (D) 45. (B)

6. (B) 26. (A) 46. (C)

c
g.
7. (C) 27. (A) 47. (C)
ng
8. (D) 28. (A) 48. (B)

9. (A, C) 29. (A, B, C, D) 49. (A, B, C)

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10. (A, B, C, D) 30. (B, C) 50. (B, D)

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11. (C, D) 31. (A, B) 51. (B)

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12. (A, B, D) 32. (A, C) 52. (A, B, D)

w

13. (B) 33. (A) 53. (D)

w

14. (A) 34. (B) 54. (C)

://

15. (B) 35. (D) 55. (A)

tp

16. (B) 36. (B) 56. (C)

ht

17. (C) 37. (B) 57. (A)

18. (B) 38. (A) 58. (C)

19. A – (p, q, t) 39. A → (q, s) 59. A → (p, q, r, t)

B – (p, r) B → (p) B → (q, r, t)

C – (p, q, t) C → (r) C → (s)

D – (s) D → (t) D → (r)

20. A – (p, r, t) 40. A → (p, r, s, t) 50. A → (q, s, t)

B – (p, r) B → (q, t) B → (s)

C – (p, q, r, t) C → (p, q, r, s, t) C → (q, s)

D – (p, r, s) D → (p, q, r, s) D → (p)

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Mock Test 1 (Paper-1) - Answers & Hints 3

ANSWERS & HINTS

PART - I : CHEMISTRY

1. Answer (B) 6. Answer (B)

Milliequivalents of H2 O2 = Milliequivalents of K2 Cr2 O 7 O

(i) CH3 – C ≡ CMgBr
(ii) H, ∆
+ C ≡ C — CH3
W 1
× 1000 = 10 × × 6
17 6 Lindlar's H(1 eq)
2
catalyst
CH3
w H2O2 = 0.17g H2 O 2 C C

Suppose, weight of sample = x g H H

om
CN
68 CH3
x× = 0.17
100 CN
∆

c
x = 0.25g

g.
CN
CN
2. Answer (B) 7. Answer (C)
ng
d [ I2 ] 1 d S 2 O3  d S 4O 6 
If X = 0.2 & Y = 0 then
2– 2–

– =– =
ye

dt 2 dt dt ∆T f = i × Kf × m
= 2 × 1.86 × 0.2
1 d  I 
−
.m

= = Rate of reaction. = 0.744°

2 dt
w

If X = 0 & Y = 0.2 then

3. Answer (C)
∆T f = 3 × 1.86 × 0.2
w

= 1.116°
w

O CH3
So, observed range of ∆Tf becomes 0.744° to 1.116°.
://

CH3 – C ≡ CLi
Cl O 8. Answer (D)
tp

(1 eq)
CH3 On heating, β-graphite is converted into α-graphite & on
grinding α-graphite is converted into β-graphite.
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(i) NaCN (1 aq)

CH3 + 9. Answer (A, C)
(ii) H
The n-factor of K 4 [Fe(CN) 6 ] is 3 because 3K + are
OH CH3 displaced by Ca 2+ in one mole.
H3C
Now,
Milliequivalent of Ca 2+ = milliequivalent of K4 [Fe(CN)6 ]
CN
W
4. Answer (B) × 1000 = 30 × 0.1 × 3
20
BeO is an amphoteric oxide. BeSO4 is water soluble
600 × 0.3
while Be(OH)2 is water insoluble. WCa = = 0.18g pure calcium
1000
5. Answer (D)

On adding O 2 (g), IInd equilibrium shifts in backward 0.18

% purity of calcium ore = × 100 = 18%
direction & 1st equilibrium shifts in forward direction. 1

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4 Mock Test 1 (Paper-1) - Answers & Hints

10. Answer (A, B, C, D) Solution of Q13 to Q15

Cyclopentadienyl rings have aromatic character. So, it 1. NaOH
HO CHO
HO CHO
undergoes Friedel Crafts acylation & do not give 2. HCHO
+
reactions of dienes. 3 . H3 O
HO [A]
11. Answer (C, D)
O

CH3– C – CH3
(i) CHMgBr
H ,∆ H+
3 +
O +
( i i ) H3 O
H 3C O CHO
CH2
H 3C O
+ [B]
PhP
3 = CH2
H3C +
O
Wittig Reaction
S – CH 2
H3C H 3C O CH CH2
12. Answer (A, B, D)

om
(A) When a body diagonal plane is placed then 4 H3C O
corners, 2 edges, 2 faces & one body atoms are [C]
removed. Number of Na + ions removed

c
H2N CH3
1 1

g.
+
= × 2 + 1 = 1 Na C
4 2
CH 3
ng
Number of Cl– ions removed CH 3
1 1 1 –
= × 2 + × 4 = 1 Cl .
ye

2 8 2 OH
Hence, stoichiometry of NaCl remains same.
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+ H 3C O CH CH2
(B) When a rectangular plane is placed then 4 edges, 4 H 3O
faces & one body atoms are removed.
w

H3C O NH
1
× 4 + 1 = 2Na +
w

Number of Na + ion removed = C CH3

4 H 3C
w

CH3
1
Number of Cl– ions removed = × 4 = 2Cl
–
://

2
Hence, stoichiometry of NaCl remains same. OH
tp

(C) When a body diagonal line is passed then two

HO CH CH2
ht

corners & one body atoms are removed

Number of Na + ions removed = 1Na + ion HO NH

1 1 C
Number of Cl– ions removed = × 2 = Cl– ion CH 3
8 4 HC CH 3
Hence, stoichiometry of NaCl does not same [Albuterol]
(D) On passing a tetrad axis, two face atoms & 1 body 16. Answer (B)
atom are removed. Pb 3 O4 exists as 2PbO. PbO2 .
Number of Na + ions removed = 1Na + ion In (B) option, reaction proceeds as :

Number of Cl– ions removed =

1
× 2 = 1Cl– ion 2PbO + 4HCl 
→ 2PbCl2 + 2H 2O
2 (Acid - base reaction)

Hence, stoichiometry of NaCl remains same. +4 +2 0

PbO 2 + 4HCl 
→ PbCl2 + 2H 2 O + Cl2
13. Answer (B) (Redox reaction)

14. Answer (A) (A) is acid base reaction, (C) is salt displacement reaction
15. Answer (B) & (D) is only redox reaction.

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Mock Test 1 (Paper-1) - Answers & Hints 5

17. Answer (C)

F
The balanced equation is F

6H + + IO –3 + 5I – 
→ 3I 2 + 3H 2 O

So, 1 mole IO –3 produces 3 mole of I2 . (B) PCl2 F3 Cl P

I2 reacts with Na 2 S2 O3 as follows
2NaS2 O3 + I2 → Na 2 S4 O6 + 2NaI
F Cl
1 mole I2 ≡ 2 mole Na 2 S2 O3
3 mole I2 ≡ 6 mole Na 2 S2 O3 ⇓
18. Answer (B) sp3d hybridisation
The n-factor of P4 & FeC2 O4 both are 3. Trigonal bipyramidal geometry
19. Answer A(p, q, t), B(p, r), C(p, q, t), D(s)

om
NH2
+ NH3 F
(A)

c
H H Stable aromatic

g.
carbanion
(C) XeF2 Xe
ng
O O H
O
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(B) O + H2 O F
O
⇓
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O O H
sp3d hybridisation
Stabiliized by
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intramolecular Trigonal bipyramidal geometry

Hydrogen Bonding
linear shape
w

dipole moment = Zero

w

–
O O–H O O
://

NaHCO3
(C) + HO
2 + CO2
F
tp

O OH O – F
O
Stable
ht

20. Answer A(p, r, t), B(p, r), C(p, q, r, t), D(p, r, s)

(D) SF 4 S
F
Cl

F F
(A) PCl3 F2 Cl P ⇓
sp3d hybridisation
Trigonal bipyramidal geometry
F Cl see saw shape.
⇓
sp3d hybridisation
Trigonal bipyramidal geometry
dipole moment = Zero

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6 Mock Test 1 (Paper-1) - Answers & Hints

PART - II : MATHEMATICS

23. Answer (A)

21. Answer (D)
The domain of the given function φ is the set of values
x−3 of x satisfying
Putting y =
x +1
1
log 2 x − 1 + log1/2 x3 + 2 > 0
⇒ xy + y = x – 3 2
3 3 1
⇒ log2 x −1 − log2 x + + > 0 ...(i)
3+ y 2 2 2
⇒ x=
1− y
and log2 x − 1 ≥ 0

 
Thus, f ( y ) + f  y − 3  = 3 + y
by solving (i) we get
 y + 1  1− y

om
⇒ 0 ≤ log2 x − 1 < 1

3+ x y−3 ⇒ 2≤ x < 4
Similarly for y = ⇒ x=

c
1− x y+1
24. Answer (D)

x −3 3 + y g.
Let S and T be the mid-points of the sides PR and QR
ng
and = respectively.
x +1 1− y
uuur uuur uuur
ye

Then, XP + XR = 2 XS
 3+ y  y−3
 + f ( y) = uuur uuur uuur
( )
.m

We have f 
 1− y  y +1 and 2 XQ + XR = 4 XT
w

uuur uuur uuur uuur uuur uur

( )
Adding them, we get
⇒ XP + 2 XQ + 3 XR = 2 XS + 2 XT = 0
w

8y  y −3  3+ y 
= 2 f ( y) +  = 2 f ( y) + y
uuur uuuur uuur uuuur
w

f + f
⇒ XS and X T are collinear and XS = 2 X T
1− y2  y +1   1− y 
://

ar ∆PTS 3 ar ( ∆ PQR) 3× 2
= and = =3
tp

4y y ⇒ ar ( PR )
⇒ f ( y) = − ar ∆PB 2 2
1− y 2
2
ht

Alternate Solution
f ( 2) =
8 8 11
⇒ −1 = − − 1 = − Let the positive vector of P, Q, R with respect to X b e
1−4 3 3 r r r
a, b , c respectively
22. Answer (C)
1 r r r r r r
x2 – 4x + 3 < 0 ⇒ x ∈(1, 3) ⇒ Area of ∆PQR = | a × b+ b× c+ c × a
2
Let f(x) = 21–x + k, g(x) = x2 – 2(k + 7)x + 5 r r r
but a + 2b + 3c = 0
When 1 < x < 3, the images of f(x) and g(x) are both
below the x-axis and since A ⊆ B, f(x) is decreasing and r r r r
⇒ 2 a × b = 3c × a ...(i)
g(x) is quadratic function. A ⊆ B iff f(1) ≤ 0, g(1) ≤ 0 and
g(3) ≤ 0 r
r r b × cr
and b × c =
⇒ –4 ≤ k ≤ – 1 2

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Mock Test 1 (Paper-1) - Answers & Hints 7

1 3r r 1r r r r ⇒ x2 – 2x + 1 = 1 + k
⇒ Area of ∆PQR = c×a + c× a+ c × a
2 2 2
⇒ x =1 ± 1+ k
3 r r
c× a
2 RS 2 = ( x1 − x2 ) 2 + ( y1 − y2 ) 2 = 5( x2 − x1 ) 2 = 20( k + 1)
1 r r
Similarly area of ∆PXR = c× a Let us pick a point (6, –5) on y = 2x – 17 and the
2 distance from the point to the line y = 2x + k is a
ratio = 3
17 + k
⇒ a= =2 5 (k + 1)
5
25. Answer (D)
⇒ k 1 = 3, k 2 = 63
We have 2+ 3 >π
⇒ a 2 = 80 or a 2 = 1280

π π π ⇒ Min (a 2 ) = 80
⇒ 0< − 2 < 3− <

om
2 2 2 27. Answer (A)

⇒ sin 2 > sin 3 15

C3 − 15 × 11C1 − 15 55

c
Required probability = 15
=
C3 91

g.
π π
and 0< 2< , < 3<π
ng
2 2 28. Answer (A)
We have φ'(x) = φ(x)
⇒ cos 2 > 0,cos 3 < 0
ye

⇒ φ(x) = ke x
⇒ cos 2 − cos 3 > 0 ⇒ φ(0) = 1 = ke0 ⇒ k = 1
.m

Hence the curve represented by the equation is an ellipse ⇒ φ(x) = e x

w

( ) (
Now, sin 2 − sin 3 − cos 2 − cos 3 ) ⇒ ψ(x) = x2 – ex
w

∫0 φ ( x ) ψ ( x ) dx = ∫0 ( x e )
1 1
2− 3  2+ 3 π 2 x
− e 2 x dx
w

Hence
= 2 2sin .sin  + <0
2  2 4
://

1
⇒ sin 2 − sin 3 < cos 2 − cos 3
1 1  e 2x  e2 3
=  x 2 e x  − 2∫ xe x dx − 
tp

 = e− −
0 0
 2 0 2 2
⇒ The foci lie on the y-axis
ht

26. Answer (A) 29. Answer (A, B, C, D)

Let R(x 1 , y 1 ) and S (x 2 , y2 ) lie on the parabola f(x) is non-negative ∀ x ∈ R

y = x2 and the equation of RS be y = 2x + k ⇒ f(x) ≥ 0, ∀ x ∈ R
⇒ 64a 2 – 16a ≤ 0
y = (2 x + k) R (x1, y1)
⇒ a(4a – 1) ≤ 0

(x2, y2)  1
S ⇒ a ∈ 0, 
Q  4
)

Integral value of a = 0
17
–

f(0) < 0 ⇒ a < 0

x
(2
=
y

P For distinct roots in (0, 1)

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8 Mock Test 1 (Paper-1) - Answers & Hints

∆>0 ⇒ a(4a – 1) > 0

Y
If α, β are the roots
T1
α+β
then 0 < <1 ⇒ 0< a < 1
2
P O X
f(0) > 0 ⇒a>0
(–2, 0)
f(1) > 0 ⇒ 4 – 7a > 0
T2
4
⇒a<
7
Let (a, 0) be the centre of the circle and the radius be r.
1 4
Hence a ∈  ,  a+2 a −2
4 7 Then = = radius of the circle = r
2 1

om
When a =
1
, min f(x) = 0 ⇒ a 2 + 4a + 4 = 2(a 2 – 4a + 4)
4
⇒

c
a 2 – 12a + 4 = 0

g.
30. Answer (B, C)
12 ± 8 2
⇒ = 6 ±4 2
ng
We have on squaring and adding a=
2
4 + 9 + 12 sin (θ + φ) = 25
( ) ( )
ye

radius = |a – 2| = 4 2 −1 , 4 2 +1
π
⇒ sin(θ + φ) = 1 = sin
.m

2 32. Answer (A, C)

The given lines are coplanar if
w

π
⇒ θ + φ = ( 4n +1) , n ∈ Z
2$i + 5k$ $i − $j + µk$ $i + µ j$ + 2k$  = 0
w

2  
w

π π
When θ + φ = ⇒ φ = −θ 2 0 5
://

2 2
⇒ 1 −1 µ = 0
tp

1 µ 2
3 4
5 sin θ = 3 ⇒ sin θ = or cos θ =
ht

5 5
5 + 33 5 − 33
⇒ µ= ,
3 4 4 4
Also cos φ = andsin φ =
5 5
33. Answer (A)
Hence φ > θ
34. Answer (B)
31. Answer (A, B) 35. Answer (D)
Since the point P(–2, 0) lies on the directrix of the Q.33 to Q35 Solution
π The equation of the tangents to the given curve
parabola, hence the angle between the tangents isand
2 y = φ(x) and y = ψ(x) at points with equal abscissae x
the equations of PT 1 a n d PT 2 are y = x + 2 and are
x + y + 2 = 0 respectively. The equation of T1 T 2 is
x–2=0 Y – φ(x) = φ'(x) (X – x)

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Mock Test 1 (Paper-1) - Answers & Hints 9

and Y – ψ(x) = ψ'(x) (X – x) ∞

1  1 a2  π
) ∫  1 + x 2 1+ a 2 x 2  2 (1+ a )
=  −  dx =
which will intersect on y-axis if
(
1−a2 0

Y – φ(x) = –x φ'(x)
π
Y – ψ(x) = –x ψ'(x) ⇒ I= ln (1 + a ) + c, at a = 0, c = 0
2

⇒ φ(x) – ψ(x) = x
d
{φ (x ) − ψ (x )} π
dx ⇒ I= ln (1 + a )
2

d (φ ( x ) − ψ ( x )) dx
37. Answer (B)
⇒ =
φ ( x ) − ψ ( x) x ∞
dI 1 1
=∫ .2ax2 . dx
da 0 1 + a x
2 2
1 + b 2x 2
⇒ ln(φ(x) – ψ(x)) = lncx

⇒ φ(x) – ψ(x) = cx ...(i) ∞

om
2a  1 1 
The equations of normals at the points with equal
= ∫ −  dx
a 2 − b 2 0  1 + b 2 x2 1 + a 2 x 2 
abscissae x to the given curves are given by

c
2ab  π  1 1  π

g.
−1 = 2   −  =
Y − φ( x) = ( X − x) a − b  2  b a  b ( a + b)
2
φ '( x )
ng
π
⇒I= ln ( a + b ) + c
ye

and Y − ψ ( x ) = − ( X − x)
1 b
ψ '( x )
.m

π
Using a = 0, I = 0 ⇒ K = − ln b
These normal intersect on x-axis, hence 2
w

X = x + φ(x) φ'(x) and X = x + ψ(x) ψ'(x)

π  a +b 
w

⇒ φ(x)φ'(x) = ψ(x)ψ'(x) Hence I = ln  

b  b 
w

⇒ (φ(x))2 – (ψ(x))2 = k
38. Answer (A)
://

k
⇒ φ(x) + ψ(x) = ∞
tp

sin mx
cx I=∫ dx
x
ht

1 K 1 K
⇒ φ(x) =  cx +  , ψ ( x ) =  cx −  ∞ ∞
2 cx  2 cx  dI sin mx
dm ∫0
⇒ = cos mxdx = , which is not defined
m 0
Since curve passes throgh (1, 1) and (2, 3),
39. Answer A–(q, s), B–(p), C–(r), D–(t)
2 2
Hence φ(x) = –x + , ψ(x) = x + A. The no. of shortest routes that must pass through
x x the junction A = 5 C2 × 8 C3
36. Answer (B) B. The no. of routes that must pass through the street
We have AB = 5 C2 × 7 C3
C. The no. of routes that pass through junctions A
∞ ∞
tan −1 ax dI 1 and C = 5 C2 × 4 C1 × 4 C2
I=∫ dx ⇒ =∫ dx
0 (
x 1+ x 2
) da 0 1+ a x
2 2
1+ x2( )( ) D. When street AB is closed, the number of possible
routes = 13 C5 – 5 C2 × 7 C3

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10 Mock Test 1 (Paper-1) - Answers & Hints

40. Answer A–(p, r, s, t), B–(q, t), C–(p, q, r, s, t), D–(p, q, C. We have a + ar + ar2 = 70
r, s) ⇒ 10ar = 4a + 4ar2
B. We have ⇒ 2r2 – 5r + 2 = 0
⇒ (r – 2) (2r – 1) = 0
1
2
ar ⇒ r = 2, , but r ≠ 2
a 2
1
⇒ r= , a = 40
2
ar
 1
D. We have a2 = 9 + 4 – 2.2.3.  −  = 13 + 6 = 19
(ar2 )2 = a2 + a 2 r2 where a = 2  2
⇒ r4 – r2 –1=0 2
120° 3
1± 5
⇒ r2 = b 60°
2 2

om
3
1+ 5 a
⇒ r2 =
2 = 19 ⇒ a = 19

c
a2

g.
1
 5 +1  and b 2 = 4 + 9 – 2.3.2. = 7
= ar 2 = 2   = 5 + 1 = 1+ 5
ng
2
 2  ⇒ b= 7

( )
ye

= a + b ⇒ a = 1, b = 5 Perimeter = 2 19 + 7

⇒
.m

a 2 + b 2 = 26 a + b = 19 + 7 = 26
w

PART - III : PHYSICS

w
w

41. Answer (B) 44. Answer (B)

://

By conservation of energy Restoring torque on small displacement θ

= – (kR2 θ + 0.6 mgRθ)
tp

17 2  2 7
pE = mr  ω = mv 2  k 0.6 g 
2  5
ht

⇒ α = − + θ = − ω2 θ
 10
m R 

k 0.6 g 100 0.8 × 10

10 pE ⇒ ω= + = + = 256 = 16 rad/s
⇒ =v m R 0.5 3/28
7m
45. Answer (B)
42. Answer (C) F is equals to gravitational force at different points

r r 46. Answer (C)

vcm = 4iˆ + 8 ˆj v A,cm = − 2iˆ − 4 ˆj
1 2
U = Li
⇒ λA, cm = 3λ 2

43. Answer (C) di

⇒ U ′ = Li = iV
dt
4r r
tan θ = in critical case and tan37° = ⇒ tanθ = 3 ⇒ U ′ ∝ e−t / τ (1 − e− t /τ )
h h

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Mock Test 1 (Paper-1) - Answers & Hints 11

47. Answer (C) 52. Answer (A, B, D)

4s Linear momentum is conserved if particle strikes at
Initial pressure in bubble = P +
r 2L
x= as in this case reaction at hinge is zero.
 4s  1 3
Final pressure = 8  P +  , as volume becomes th
 r  8 r
As τ about hinge is zero, L = constant about hinge.
and T is constant.
53. Answer (D)
 4s  4s  3s 
⇒ Outside pressure = 8  P +  − = 8 P + 
 r  r / 2  r  FBD of body is as shown.

48. Answer (B)

acmcosθ B A
1 1 1  1 θ
= (1.5 − 1)  − =
f  5 10  20
acm acm sinθ θ
O

om
v
⇒ m= =2 f
u
vmeniscus = 2 gh = 2× 9.8 × 0.1 = 1.4 m/s (down)

c
By τ = Iα about instantaneous axis at O

g.
vobject/meniscus = 1.4 m/s (upward)
g
α=
ng
vimage/meniscus = m2 vobject/meniscus
6R
= 4 × 1.4 = 5.6 m/s (upward)
ye

⇒ vimage = 5.6 + 1.4 = 7 m/s ⇒ a x = acm cos θ

49. Answer (A, B, C)
.m

= α.OB cos θ
For refraction at AB, µ1 sin90° = µ2 cosα ...(i)
For refraction at AC, µ3 sin90° = µ2 sinα
w

...(ii) g 2R
= . 5R .
Eq (i) & (ii) 6R 5R
w

µ1 2 + µ3 2 = µ2 2
w

g
For emergence of ray from AC, α ≤ C at the face =
://

3
−1  µ 
tp

⇒ α ≤ sin  3  54. Answer (C)

 µ2 
ht

2Mg
for T.I.R α > C f = m.a x =
3
⇒ µ1 2 + µ3 2 < µ2 2
50. Answer (B, D) 55. Answer (A)

Orbital speed and orbital angular momentum independent By conservation of energy

of mass of revolving particle
1 2 2 g
51. Answer (B) 2 MgR = (4MR ) ω ⇒ ω =
2 R
r r v
As | v1 | = |v2 |, v′ = 56. Answer (C)
2
r r For any point P on surface A if |S2 P – S1 P| = constant,
⇒ Angle between v1 and v2 = θ = 60°
locus of P is circle.
R R For any point P on surface B if |S 2 P – S 1 P| = constant,
⇒ a= 3 and b = ⇒ a = 3b
2 2 locus of P is hyperbola.

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12 Mock Test 1 (Paper-1) - Answers & Hints

57. Answer (A) 60. Answer A–(q, s, t), B–(s), C–(q, s), D–(p)
For maxima, path difference = n λ (p) Energy is lost due to friction

λ ρl ρ l2
For maxima path difference = (2n − 1) (q) Resistance = =
2 A volume
58. Answer (C) (r) Use Bernoull's theorem

r λ.v ˆ (s) Direction of rτ (about O) charges as particle moves

v fringe = −vjˆ − ˆ − v ˆi
i = − vj
3λ 3 from A to B
(t) Internal energy increase on dissociation as n
10v
⇒ v fringe = 3
th
3 becomes double while f becomes
5
59. Answer A –(p, q, r, t), B–(q, r, t), C–(s), D–(r)
6
r r ⇒ U′ = U
r d θ r dL v2 5
ω = , τ = and aradial =

om
Use
dt dt r By PV = nRT, P increases

c
q q q
g.
ng
ye
.m
w
w
w
://
tp
ht

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