Sei sulla pagina 1di 14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II (including amendments) - United Kingdom (UK)

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II (including amendments) - United Kingdom (UK) SAFETY

SAFETY DATA SHEET

CGW80742P

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1

Product identifier

Product name

:

CGW80742P

Product code

:

CGW80742P

Product type

:

Liquid.

1.2

Relevant identified uses of the substance or mixture and uses advised against

Recommended use

: Corrosion Inhibitor

1.3

Details of the supplier of the safety data sheet

Baker Hughes Kirkby Bank Road, Knowsley Industrial Park, Liverpool, L33 7SY, UK

 

Tel: +44 (0)151 545 3899 Fax: +44 (0)151 547 3590

e-mail address of person responsible for this SDS

: paul.chapman2@bakerhughes.com

1.4

Emergency telephone number

 

Supplier Telephone number

: CHEMTREC Emergency Telephone within UK: 0870 820 0418 CHEMTREC Emergency Telephone outside UK: +44 870 820 0418

SECTION 2: Hazards identification

2.1

Classification of the substance or mixture

 

Product definition

:

Mixture

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Classification

:

F; R11

 

T; R39/23/24/25

Xn; R20/21/22

C; R34

Xi; R37

N; R50/53

Physical/chemical

:

Highly flammable.

hazards Human health hazards

:

Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to respiratory system.

Environmental hazards

:

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Date of issue/Date of revision : 17 July 2013 1/14
Date of issue/Date of revision
:
17 July 2013
1/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 2: Hazards identification

Flam. Liq. 2, H225 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 STOT SE 1, H370 STOT SE 3, H335 Aquatic Chronic 1, H410 See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

  • 2.2 Label elements

Dangerous Preparations Directive [1999/45/EC]

Hazard symbol or symbols

:

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) CGW80742P SECTION 2:

Indication of danger Risk phrases

:

:

Highly flammable, Toxic, Dangerous for the environment

R11- Highly flammable. R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R34- Causes burns. R37- Irritating to respiratory system. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases

:

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

Hazardous ingredients

Supplemental label elements

:

Pyridinium, 1-(phenylmethyl)-, ethyl methyl derivs., chlorides methanol

: Not applicable.

  • 2.3 Other hazards

Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII

Not applicable. P: Not available. B: Not available. T: Not available.

Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Other hazards which do not result in classification

Not applicable. vP: Not available. vB: Not available.

:

Not available.

Date of issue/Date of revision : 17 July 2013 2/14
Date of issue/Date of revision
:
17 July 2013
2/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P
CGW80742P

SECTION 3: Composition/information on ingredients

Substance/mixture

:

Mixture

     

Classification

 

Product/ingredient

Identifiers

%

67/548/EEC

Regulation (EC) No.

Type

name

1272/2008 [CLP]

Pyridinium, 1-

EC: 272-695-0

  • 10 C; R34

- 30

 

Skin Corr. 1B, H314

[1]

(phenylmethyl)-, ethyl

CAS: 68909-18-2

N; R50/53

Aquatic Chronic 1,

methyl derivs., chlorides

H410

Imidazolium

EC: 263-185-9

- 30

  • 10 Xi; R36/37/38

Skin Irrit. 2, H315

[1]

compounds, 1-benzyl-

CAS: 61791-52-4

Eye Irrit. 2, H319

4,5-dihydro-1-

STOT SE 3, H335

(hydroxyethyl)-2-

norcoco alkyl, chlorides

methanol

REACH #: 01-

  • 10 F; R11

- 30

Flam. Liq. 2, H225

[1] [2]

2119433307-44

EC: 200-659-6

T; R23/24/25,

Acute Tox. 3, H301

CAS: 67-56-1 Index: 603-001-00-X

R39/23/24/25

Acute Tox. 3, H311 Acute Tox. 3, H331 STOT SE 1, H370

propan-2-ol

REACH #: 01-

  • 10 F; R11

- 30

Flam. Liq. 2, H225

[1] [2]

2119457558-25

EC: 200-661-7

Xi; R36

Eye Irrit. 2, H319

CAS: 67-63-0 Index: 603-117-00-0

R67

STOT SE 3, H336

Fatty acids, C12-20

EC: 292-846-4

- 30

  • 10 Xi; R41, R38

Skin Irrit. 2, H315

[1]

and C12-20-unsatd., reaction products with

CAS: 91001-74-0

Eye Dam. 1, H318

2-[(2-

aminoethyl)amino]ethanol,

di-Et sulfate-

quaternized

Poly(oxy-1,2-

CAS: 51811-79-1

- 10

  • 5 Xi; R41, R38

Eye Dam. 1, H318

[1]

ethanediyl), α-

(nonylphenyl)-ω-

hydroxy-, phosphate

2-aminoethanol

REACH #: 01-

- 5

  • 1 Xn; R20/21/22

Acute Tox. 4, H302

[1] [2]

2119486455-28

EC: 205-483-3 CAS: 141-43-5 Index: 603-030-00-8

C; R34

Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 STOT SE 3, H335

Nonylphenol,

EC: 500-024-6

- 5

  • 1 Xn; R21/22

Acute Tox. 4, H302

[1]

ethoxylated

CAS: 9016-45-9

Xi; R41

Acute Tox. 4, H312

R52

Eye Dam. 1, H318

See Section 16 for the full text of the R- phrases declared above.

See Section 16 for the full text of the H statements declared above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Type

[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 17 July 2013 3/14
Date of issue/Date of revision
:
17 July 2013
3/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P
CGW80742P

SECTION 4: First aid measures

4.1

Description of first aid measures

 

Eye contact

:

Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician.

Inhalation

:

Get medical attention immediately. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Skin contact

:

Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

:

Get medical attention immediately. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Chemical burns must be treated promptly by a physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Protection of first-aiders

: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2

Most important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact

:

Corrosive to eyes. Causes burns.

Inhalation

:

Harmful by inhalation. Danger of very serious irreversible effects. Irritating to respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Skin contact

:

Corrosive to the skin. Causes burns. Harmful in contact with skin. Danger of very serious irreversible effects.

Ingestion

:

Harmful if swallowed. Danger of very serious irreversible effects. May cause burns to mouth, throat and stomach.

Over-exposure signs/symptoms

Eye contact

:

Adverse symptoms may include the following:

 

pain

watering

redness

Inhalation

:

Adverse symptoms may include the following:

 

respiratory tract irritation coughing

Skin contact

:

Adverse symptoms may include the following:

 

pain or irritation redness blistering may occur

Ingestion

:

Adverse symptoms may include the following:

 

stomach pains

4.3

Indication of any immediate medical attention and special treatment needed

Notes to medical doctor

:

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

 

Not available.

Date of issue/Date of revision

:

17 July 2013

4/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

 

SECTION 4: First aid measures

 
 
 

5.1

Extinguishing media

Suitable

:

Use dry chemical, CO2, water spray (fog) or foam.

Not suitable

:

Do not use water jet.

5.2

Special hazards arising from the substance or mixture

Special exposure hazards

:

Highly flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

 

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. This material is very toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous thermal

:

Decomposition products may include the following materials:

decomposition products

carbon dioxide carbon monoxide nitrogen oxides phosphorus oxides

5.3

Advice for fire-fighters

Special protective equipment for fire-fighters

:

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Additional information

:

Not available.

SECTION 6: Accidental release measures

6.1

Personal precautions,

:

If specialised clothing is required to deal with the spillage, take note of any

protective equipment and emergency procedures

information in Section 8 on suitable and unsuitable materials. See also Section 8 for additional information on hygiene measures.

6.2

Environmental

:

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains

precautions

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

6.3

Methods and materials for containment and cleaning up

Small spill

:

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Large spill

:

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

6.4

Reference to other

:

Note: see section 8 for personal protective equipment and section 13 for waste

sections

disposal.

Date of issue/Date of revision : 17 July 2013 5/14
Date of issue/Date of revision
:
17 July 2013
5/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P
CGW80742P

SECTION 7: Handling and storage

  • 7.1 Precautions for safe

handling

:

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Refer to special instructions/safety data sheet. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion- proof electrical (ventilating, lighting and material handling) equipment. Use non- sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

  • 7.2 Conditions for safe storage, including any incompatibilities

Storage

:

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well- ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Recommended Packaging materials

:

Use original container.

  • 7.3 Specific end use(s)

:

Corrosion inhibitor. Not available.

SECTION 8: Exposure controls/personal protection

  • 8.1 Control parameters

Occupational exposure limits

Product/ingredient name

Exposure limit values

methanol

EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed through skin.

STEL: 333 mg/m³ 15 minute(s). STEL: 250 ppm 15 minute(s). TWA: 266 mg/m³ 8 hour(s). TWA: 200 ppm 8 hour(s).

propan-2-ol

EH40/2005 WELs (United Kingdom (UK), 1/2012).

STEL: 1250 mg/m³ 15 minute(s). STEL: 500 ppm 15 minute(s). TWA: 999 mg/m³ 8 hour(s). TWA: 400 ppm 8 hour(s).

2-aminoethanol

EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed through skin.

STEL: 7.6 mg/m³ 15 minute(s). STEL: 3 ppm 15 minute(s). TWA: 1 ppm 8 hour(s). TWA: 2.5 mg/m³ 8 hour(s).

Recommended monitoring procedures

:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Date of issue/Date of revision : 17 July 2013 6/14
Date of issue/Date of revision
:
17 July 2013
6/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls Occupational exposure controls

:

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures

:

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Respiratory protection

:

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Hand protection

:

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Eye protection

:

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.

Skin protection

:

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

:

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

DNELs Ingredient name

Exposure

DNELs

Population

Effects

methanol

Long term

260

mg/m³

Workers

Systemic

Inhalation

Short term

260

mg/m³

Workers

Local

Inhalation

Long term

260

mg/m³

Workers

Local

Inhalation

Short term

260

mg/m³

Workers

Systemic

Inhalation

Long term

40

mg/kg

Workers

Systemic

Dermal

bw/day

 

Short term

40

mg/kg

Workers

Systemic

Dermal

bw/day

 

propan-2-ol

Long term

888

mg/kg

Workers

Systemic

Dermal

bw/day

 

Long term

500

mg/m³

Workers

Systemic

Inhalation

2-aminoethanol

Long term

1 mg/kg

Workers

Systemic

Dermal

bw/day

 

Long term

3.3 mg/m³

Workers

Local

Inhalation

DEL Summary PNECs Ingredient name

: Not available.

Compartment Detail

PNECs

Method Detail

Date of issue/Date of revision : 17 July 2013 7/14
Date of issue/Date of revision
:
17 July 2013
7/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 8: Exposure controls/personal protection

 

methanol

Fresh water

154 mg/l

Assessment Factors

Marine

15.4 mg/l

Assessment Factors

Sewage Treatment

100

mg/l

Assessment Factors

Plant Fresh water sediment

570.4 mg/kg

-

Soil

23.5 mg/kg

-

propan-2-ol

Fresh water

140.9 mg/l

-

Marine

140.9 mg/l

-

Sewage Treatment

2251 mg/l

-

Plant Sediment

552 mg/kg

-

Soil

28 mg/kg

-

Secondary Poisoning

160 mg/kg

-

2-aminoethanol

Fresh water

0.085 mg/l

-

Marine

0.0085 mg/l

-

Sewage Treatment

100

mg/l

-

Plant Fresh water sediment

0.425 mg/kg dwt

-

Marine water sediment

0.0425 mg/kg dwt

-

Soil

0.035 mg/kg dwt

-

PEC Summary

: Not available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state

:

Liquid.

Colour

:

Red. [Dark]

Odour

:

Alcohol

Odour threshold

:

Not available.

pH

:

7

Boiling point

:

>=65°C (>=149°F)

Melting point/freezing point

:

Not available.

Flammability (solid, gas)

:

May be combustible at high temperature.

Flash point

:

Closed cup: 16°C (60.8°F) [Pensky-Martens.]

Explosive properties

:

Not available.

Explosion limits

:

Not available.

Oxidising properties

:

Not available.

Vapour pressure

:

Not available.

Density

:

Not available.

Relative density

:

0.973 to 1.043 (16°C)

Solubility

:

Soluble in the following materials: cold water.

Partition coefficient: n- octanol/water

:

Not available.

Viscosity

:

Not available.

Vapour density

:

Not available.

Evaporation rate (butyl acetate = 1)

:

Not available.

Decomposition

:

Not available.

temperature Auto-ignition temperature

:

Not available.

9.2 Other information Pour point

:

Not available.

Date of issue/Date of revision : 17 July 2013 8/14
Date of issue/Date of revision
:
17 July 2013
8/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P
CGW80742P

SECTION 10: Stability and reactivity

  • 10.1 No specific test data related to reactivity available for this product or its ingredients.

Reactivity

:

  • 10.2 Chemical stability

:

The product is stable.

  • 10.3 Under normal conditions of storage and use, hazardous reactions will not occur.

Possibility of

:

hazardous reactions

  • 10.4 Conditions to avoid

:

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid release to the environment.

  • 10.5 Highly reactive or incompatible with the following materials:

Incompatible

:

materials

oxidizing materials

  • 10.6 Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Hazardous

:

decomposition products

SECTION 11: Toxicological information

Potential acute health effects Inhalation

:

Harmful by inhalation. Danger of very serious irreversible effects. Irritating to respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

 
 

Ingestion

:

Harmful if swallowed. Danger of very serious irreversible effects. May cause burns to mouth, throat and stomach.

Skin contact

:

Corrosive to the skin. Causes burns. Harmful in contact with skin. Danger of very serious irreversible effects.

Eye contact

:

Corrosive to eyes. Causes burns.

Acute toxicity

 

Product/ingredient name

Result

Species

 

Dose

Exposure

 

Pyridinium, 1- (phenylmethyl)-, ethyl methyl derivs., chlorides

LD50 Oral

Rat

50.1 mg/kg

-

 

methanol

LC50 Inhalation Vapour

Rat

128.2 mg/l

4 hours

LD50 Dermal

Rabbit

17100 mg/kg

-

LD50 Oral

Rat

>=2528 mg/kg

-

propan-2-ol

LD50 Oral

Rat

5000

mg/kg

-

LD50 Oral

Rat

5045

mg/kg

-

2-aminoethanol

LD50 Oral

Rat

1720

mg/kg

-

General

:

:

No known significant effects or critical hazards.

:

:

:

:

:

 

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Inhalation

Adverse symptoms may include the following:

Ingestion

:

respiratory tract irritation coughing Adverse symptoms may include the following:

Skin contact

:

stomach pains Adverse symptoms may include the following:

Eye contact

:

pain or irritation redness blistering may occur Adverse symptoms may include the following:

pain

watering

redness

Date of issue/Date of revision : 17 July 2013 9/14
Date of issue/Date of revision
:
17 July 2013
9/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P
CGW80742P

SECTION 12: Ecological information

12.1

Toxicity

: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Aquatic ecotoxicity Product/ingredient name

 

Result

Species

Exposure

methanol

Acute EC50 >10000 mg/l Fresh water

Daphnia

Fish

 

48 hours

Acute LC50 15400 mg/l Fresh water

96 hours

propan-2-ol

Acute LC50 10400000 ug/L Fresh water Fish - Pimephales promelas - 29 days - 20 mm - 0.103 g

96

hours

Poly(oxy-1,2-ethanediyl), α- (nonylphenyl)-ω-hydroxy-, phosphate

Acute LC50 24300 ug/L Fresh water

Crustaceans - Gammarus pulex

48 hours

2-aminoethanol

Acute EC50 32.5 mg/l Marine water

Algae - skeletonema costatum

Acute LC50 3.68 ug/L Fresh water

Acute LC50 5000 ug/L Fresh water

72 hours

Acute EC50 80000 ug/L Fresh water

Algae - Isochrysis galbana

96 hours

Acute LC50 79.3 mg/l Marine water

Crustaceans

48 hours

Acute LC50 423 mg/l Marine water

Fish - scopthalmus maximus

96 hours

Acute LC50 150 to 196 mg/L Fresh water

Fish - Oncorhynchus mykiss - Yolk-sac fry

96

hours

Nonylphenol, ethoxylated

Acute EC50 12 mg/L Fresh water

Algae - Pseudokirchneriella subcapitata

96

hours

Crustaceans - Thamnocephalus

48

hours

platyurus - Nauplii - 24 hours Fish - Danio rerio

96 hours

Chronic NOEC 35 ug/L Fresh water

Fish - Oryzias latipes - Fry - 1 days post-hatch

100 days

Conclusion/Summary

 

: Not available.

12.2

Persistence and degradability

Product/ingredient name

 

Test

Result

Dose

Inoculum

 

2-aminoethanol

-

>90 % - Readily -

  • - -

 
 
  • 21 days

 

-

  • 70 % - Readily -

  • - -

 
 
  • 28 days

Conclusion/Summary

: Not available.

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

 

2-aminoethanol

 

-

-

Readily

12.3

Bioaccumulative potential

 

Product/ingredient name

 

LogPow

BCF

Potential

 

methanol

-0.77

-

low

propan-2-ol

 

0.05

-

low

2-aminoethanol

-1.31

-

low

12.4

Mobility in soil

: Not available.

 

12.5

Results of PBT and vPvB assessment

PBT

:

Not applicable.

 

vPvB

:

P: Not available. B: Not available. T: Not available. Not applicable. vP: Not available. vB: Not available.

12.6

Other adverse effects

:

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

 

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).

13.1

Waste treatment methods

 

Product

Date of issue/Date of revision : 17 July 2013 10/14
Date of issue/Date of revision
:
17 July 2013
10/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 13: Disposal considerations

Methods of disposal

:

The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Hazardous waste

:

The classification of the product may meet the criteria for a hazardous waste.

Packaging Methods of disposal

:

The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.

13.2 Additional information

Special precautions

:

This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

International transport regulations

Regulatory

14.1 UN

14.2 Proper shipping name

14.3 Transport

14.4 PG*

Label

information

number

hazard class(es)

ADR/RID Class

UN2924

Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt)

  • 3 (8)

II

ADR/RID Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt) 3 (8) II
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label information number hazard class(es)
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label information number hazard class(es)

ADN/ADNR Class

UN2924

Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt)

  • 3 (8)

II

ADN/ADNR Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt) 3 (8) II
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label information number hazard class(es)
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label information number hazard class(es)
           
Date of issue/Date of revision : 17 July 2013 11/14
Date of issue/Date of revision
:
17 July 2013
11/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

 

SECTION 14: Transport information

 

IMDG Class

UN2924

Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt)

  • 3 (8)

II

IMDG Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt) 3 (8) II
 
CGW80742P SECTION 14: Transport information IMDG Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary
CGW80742P SECTION 14: Transport information IMDG Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary

IATA Class

UN2924

Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt)

  • 3 (8)

II

IATA Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary salt) 3 (8) II
CGW80742P SECTION 14: Transport information IMDG Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary
CGW80742P SECTION 14: Transport information IMDG Class UN2924 Flammable liquid, corrosive, n.o.s.(contains aliphatic alcohol & quaternary

PG* : Packing group

Regulatory

14.5

14.6 Special precautions for user

 

Additional

 

information

Environmental

 

information

hazards

ADR/RID Class

Yes.

Tunnel code

-

(D/E)

ADN/ADNR Class

Yes.

-

-

IMDG Class

Yes.

-

-

IATA Class

Yes.

-

-

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Proper shipping name

:

Not available.

Ship type

:

Not available.

Pollution category

:

Not available.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern

None of the components are listed.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

:

Not applicable.

Other EU regulations Europe inventory

:

Not determined.

Black List Chemicals

:

Not listed

Priority List Chemicals

:

Not listed

Date of issue/Date of revision

:

17 July 2013

12/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 15: Regulatory information

  • 15.2 Chemical Safety

Assessment

:

This product contains substances for which Chemical Safety Assessments are still required.

SECTION 16: Other information

  • 16.1 Revision comments

: Not available.

Indicates information that has changed from previously issued version.

Indicates information that has changed from previously issued version.

  • 16.2 Abbreviations and

:

ATE = Acute Toxicity Estimate

acronyms

CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.

1272/2008]

DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number

  • 16.3 Key literature

:

Not available.

references and sources for

data

  • 16.4 Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Flam. Liq. 2, H225 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 STOT SE 1, H370 STOT SE 3, H335 Aquatic Chronic 1, H410

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification

Justification

Flam. Liq. 2, H225 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 STOT SE 1, H370 STOT SE 3, H335

On basis of test data Calculation method Calculation method Calculation method Calculation method Calculation method Calculation method

Aquatic Chronic 1, H410

Calculation method

  • 16.5 Full text of abbreviated

:

H225

Highly flammable liquid and vapour.

H statements

H301

Toxic if swallowed.

H302

Harmful if swallowed.

H311

Toxic in contact with skin.

H312

Harmful in contact with skin.

H314

Causes severe skin burns and eye damage.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H331

Toxic if inhaled.

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

H336

May cause drowsiness or dizziness.

H370

Causes damage to organs.

H410

Very toxic to aquatic life with long lasting effects.

Date of issue/Date of revision : 17 July 2013 13/14
Date of issue/Date of revision
:
17 July 2013
13/14

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

CGW80742P

SECTION 16: Other information

 

Full text of classifications [CLP/GHS]

:

Acute Tox. 3, H301 Acute Tox. 3, H311 Acute Tox. 3, H331 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Aquatic Chronic 1, H410 Eye Dam. 1, H318 Eye Irrit. 2, H319 Flam. Liq. 2, H225 Skin Corr. 1B, H314 Skin Irrit. 2, H315 STOT SE 1, H370

ACUTE TOXICITY: ORAL - Category 3 ACUTE TOXICITY: SKIN - Category 3 ACUTE TOXICITY: INHALATION - Category 3 ACUTE TOXICITY: ORAL - Category 4 ACUTE TOXICITY: SKIN - Category 4 ACUTE TOXICITY: INHALATION - Category 4 AQUATIC TOXICITY (CHRONIC) - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 FLAMMABLE LIQUIDS - Category 2 SKIN CORROSION/IRRITATION - Category 1B SKIN CORROSION/IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE

 

STOT SE 3, H335

EXPOSURE) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE

STOT SE 3, H336

EXPOSURE) [Respiratory tract irritation] - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] - Category 3

  • 16.5 Full text of abbreviated

:

R11- Highly flammable.

R phrases

R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R21/22- Harmful in contact with skin and if swallowed. R34- Causes burns. R41- Risk of serious damage to eyes. R36- Irritating to eyes. R37- Irritating to respiratory system. R38- Irritating to skin. R36/37/38- Irritating to eyes, respiratory system and skin. R67- Vapours may cause drowsiness and dizziness. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52- Harmful to aquatic organisms.

Full text of classifications [DSD/DPD]

:

F - Highly flammable T - Toxic C - Corrosive Xn - Harmful Xi - Irritant N - Dangerous for the environment

  • 16.6 Training advice

:

Not available.

  • 16.7 Further information

Date of issue/ Date of revision

:

17 July 2013

Version Notice to reader

:

1

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Date of issue/Date of revision : 17 July 2013 14/14
Date of issue/Date of revision
:
17 July 2013
14/14