Sei sulla pagina 1di 14

Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II (including amendments) - United Kingdom (UK)

SAFETY DATA SHEET


CGW80742P

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1 Product identifier
Product name : CGW80742P
Product code : CGW80742P
Product type : Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Corrosion Inhibitor

1.3 Details of the supplier of the safety data sheet


Baker Hughes
Kirkby Bank Road,
Knowsley Industrial Park,
Liverpool,
L33 7SY, UK

Tel: +44 (0)151 545 3899


Fax: +44 (0)151 547 3590
e-mail address of person : paul.chapman2@bakerhughes.com
responsible for this SDS

1.4 Emergency telephone number


Supplier
Telephone number : CHEMTREC Emergency Telephone within UK: 0870 820 0418
CHEMTREC Emergency Telephone outside UK: +44 870 820 0418

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : F; R11
T; R39/23/24/25
Xn; R20/21/22
C; R34
Xi; R37
N; R50/53
Physical/chemical : Highly flammable.
hazards
Human health hazards : Toxic: danger of very serious irreversible effects through inhalation, in contact with
skin and if swallowed. Harmful by inhalation, in contact with skin and if swallowed.
Causes burns. Irritating to respiratory system.
Environmental hazards : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Date of issue/Date of revision : 17 July 2013 1/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 2: Hazards identification


Flam. Liq. 2, H225
Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Corr. 1B, H314
STOT SE 1, H370
STOT SE 3, H335
Aquatic Chronic 1, H410
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Dangerous Preparations Directive [1999/45/EC]
Hazard symbol or symbols :

Indication of danger : Highly flammable, Toxic, Dangerous for the environment


Risk phrases : R11- Highly flammable.
R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
R37- Irritating to respiratory system.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61- Avoid release to the environment. Refer to special instructions/safety data
sheet.
Hazardous ingredients : Pyridinium, 1-(phenylmethyl)-, ethyl methyl derivs., chlorides
methanol
Supplemental label : Not applicable.
elements

2.3 Other hazards


Substance meets the Not applicable.
criteria for PBT according P: Not available. B: Not available. T: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII

Substance meets the Not applicable.


criteria for vPvB according vP: Not available. vB: Not available.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Not available.
not result in classification

Date of issue/Date of revision : 17 July 2013 2/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 3: Composition/information on ingredients


Substance/mixture : Mixture
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
Pyridinium, 1- EC: 272-695-0 10 - 30 C; R34 Skin Corr. 1B, H314 [1]
(phenylmethyl)-, ethyl CAS: 68909-18-2 N; R50/53 Aquatic Chronic 1,
methyl derivs., H410
chlorides
Imidazolium EC: 263-185-9 10 - 30 Xi; R36/37/38 Skin Irrit. 2, H315 [1]
compounds, 1-benzyl- CAS: 61791-52-4 Eye Irrit. 2, H319
4,5-dihydro-1- STOT SE 3, H335
(hydroxyethyl)-2-
norcoco alkyl, chlorides
methanol REACH #: 01- 10 - 30 F; R11 Flam. Liq. 2, H225 [1] [2]
2119433307-44
EC: 200-659-6 T; R23/24/25, Acute Tox. 3, H301
CAS: 67-56-1 R39/23/24/25 Acute Tox. 3, H311
Index: 603-001-00-X Acute Tox. 3, H331
STOT SE 1, H370
propan-2-ol REACH #: 01- 10 - 30 F; R11 Flam. Liq. 2, H225 [1] [2]
2119457558-25
EC: 200-661-7 Xi; R36 Eye Irrit. 2, H319
CAS: 67-63-0 R67 STOT SE 3, H336
Index: 603-117-00-0
Fatty acids, C12-20 EC: 292-846-4 10 - 30 Xi; R41, R38 Skin Irrit. 2, H315 [1]
and C12-20-unsatd., CAS: 91001-74-0 Eye Dam. 1, H318
reaction products with
2-[(2-
aminoethyl)amino]ethanol,
di-Et sulfate-
quaternized
Poly(oxy-1,2- CAS: 51811-79-1 5 - 10 Xi; R41, R38 Eye Dam. 1, H318 [1]
ethanediyl), α-
(nonylphenyl)-ω-
hydroxy-, phosphate
2-aminoethanol REACH #: 01- 1-5 Xn; R20/21/22 Acute Tox. 4, H302 [1] [2]
2119486455-28
EC: 205-483-3 C; R34 Acute Tox. 4, H312
CAS: 141-43-5 Acute Tox. 4, H332
Index: 603-030-00-8 Skin Corr. 1B, H314
STOT SE 3, H335
Nonylphenol, EC: 500-024-6 1-5 Xn; R21/22 Acute Tox. 4, H302 [1]
ethoxylated CAS: 9016-45-9 Xi; R41 Acute Tox. 4, H312
R52 Eye Dam. 1, H318
See Section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above. above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 17 July 2013 3/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 4: First aid measures


4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids. Check for and remove any contact
lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated
promptly by a physician.
Inhalation : Get medical attention immediately. Move exposed person to fresh air. Keep person
warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 15
minutes. Chemical burns must be treated promptly by a physician. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Wash out mouth with water. If material has
been swallowed and the exposed person is conscious, give small quantities of water
to drink. If vomiting occurs, the head should be kept low so that vomit does not enter
the lungs. Get medical attention if adverse health effects persist or are severe.
Chemical burns must be treated promptly by a physician. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Corrosive to eyes. Causes burns.
Inhalation : Harmful by inhalation. Danger of very serious irreversible effects. Irritating to
respiratory system. Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Skin contact : Corrosive to the skin. Causes burns. Harmful in contact with skin. Danger of very
serious irreversible effects.
Ingestion : Harmful if swallowed. Danger of very serious irreversible effects. May cause burns
to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to medical doctor : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Not available.
Date of issue/Date of revision : 17 July 2013 4/14
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 4: First aid measures

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable : Use dry chemical, CO2, water spray (fog) or foam.
Not suitable : Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Special exposure hazards : Highly flammable liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool. This material is very toxic to aquatic
organisms. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
phosphorus oxides
5.3 Advice for fire-fighters
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Additional information : Not available.

SECTION 6: Accidental release measures


6.1 Personal precautions, : If specialised clothing is required to deal with the spillage, take note of any
protective equipment and information in Section 8 on suitable and unsuitable materials. See also Section 8 for
emergency procedures additional information on hygiene measures.
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.
6.3 Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble or absorb with an inert dry material and place in an appropriate
waste disposal container. Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilt product.
6.4 Reference to other : Note: see section 8 for personal protective equipment and section 13 for waste
sections disposal.

Date of issue/Date of revision : 17 July 2013 5/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 7: Handling and storage


7.1 Precautions for safe : Put on appropriate personal protective equipment (see Section 8). Eating, drinking
handling and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist.
Do not ingest. Avoid release to the environment. Refer to special instructions/safety
data sheet. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Store and use
away from heat, sparks, open flame or any other ignition source. Use explosion-
proof electrical (ventilating, lighting and material handling) equipment. Use non-
sparking tools. Take precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during transfer by earthing and
bonding containers and equipment before transferring material. Empty containers
retain product residue and can be hazardous. Do not reuse container.
7.2 Conditions for safe storage, including any incompatibilities
Storage : Store in accordance with local regulations. Store in a segregated and approved
area. Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
Recommended Packaging : Use original container.
materials
7.3 Specific end use(s) : Corrosion inhibitor.
Not available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
methanol EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed
through skin.
STEL: 333 mg/m³ 15 minute(s).
STEL: 250 ppm 15 minute(s).
TWA: 266 mg/m³ 8 hour(s).
TWA: 200 ppm 8 hour(s).
propan-2-ol EH40/2005 WELs (United Kingdom (UK), 1/2012).
STEL: 1250 mg/m³ 15 minute(s).
STEL: 500 ppm 15 minute(s).
TWA: 999 mg/m³ 8 hour(s).
TWA: 400 ppm 8 hour(s).
2-aminoethanol EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed
through skin.
STEL: 7.6 mg/m³ 15 minute(s).
STEL: 3 ppm 15 minute(s).
TWA: 1 ppm 8 hour(s).
TWA: 2.5 mg/m³ 8 hour(s).

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.

Date of issue/Date of revision : 17 July 2013 6/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 8: Exposure controls/personal protection


8.2 Exposure controls
Occupational exposure : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.

Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
DNELs
Ingredient name Exposure DNELs Population Effects
methanol Long term 260 mg/m³ Workers Systemic
Inhalation
Short term 260 mg/m³ Workers Local
Inhalation
Long term 260 mg/m³ Workers Local
Inhalation
Short term 260 mg/m³ Workers Systemic
Inhalation
Long term 40 mg/kg Workers Systemic
Dermal bw/day
Short term 40 mg/kg Workers Systemic
Dermal bw/day
propan-2-ol Long term 888 mg/kg Workers Systemic
Dermal bw/day
Long term 500 mg/m³ Workers Systemic
Inhalation
2-aminoethanol Long term 1 mg/kg Workers Systemic
Dermal bw/day
Long term 3.3 mg/m³ Workers Local
Inhalation
DEL Summary : Not available.
PNECs
Ingredient name Compartment Detail PNECs Method Detail

Date of issue/Date of revision : 17 July 2013 7/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 8: Exposure controls/personal protection


methanol Fresh water 154 mg/l Assessment Factors
Marine 15.4 mg/l Assessment Factors
Sewage Treatment 100 mg/l Assessment Factors
Plant
Fresh water sediment 570.4 mg/kg -
Soil 23.5 mg/kg -
propan-2-ol Fresh water 140.9 mg/l -
Marine 140.9 mg/l -
Sewage Treatment 2251 mg/l -
Plant
Sediment 552 mg/kg -
Soil 28 mg/kg -
Secondary Poisoning 160 mg/kg -
2-aminoethanol Fresh water 0.085 mg/l -
Marine 0.0085 mg/l -
Sewage Treatment 100 mg/l -
Plant
Fresh water sediment 0.425 mg/kg dwt -
Marine water sediment 0.0425 mg/kg dwt -
Soil 0.035 mg/kg dwt -
PEC Summary : Not available.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Physical state : Liquid.
Colour : Red. [Dark]
Odour : Alcohol
Odour threshold : Not available.
pH : 7
Boiling point : >=65°C (>=149°F)
Melting point/freezing : Not available.
point
Flammability (solid, gas) : May be combustible at high temperature.
Flash point : Closed cup: 16°C (60.8°F) [Pensky-Martens.]
Explosive properties : Not available.
Explosion limits : Not available.
Oxidising properties : Not available.
Vapour pressure : Not available.
Density : Not available.
Relative density : 0.973 to 1.043 (16°C)
Solubility : Soluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Not available.
Vapour density : Not available.
Evaporation rate (butyl : Not available.
acetate = 1)
Decomposition : Not available.
temperature
Auto-ignition temperature : Not available.
9.2 Other information
Pour point : Not available.

Date of issue/Date of revision : 17 July 2013 8/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
release to the environment.
10.5 Incompatible : Highly reactive or incompatible with the following materials:
materials oxidizing materials
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information


Potential acute health effects
Inhalation : Harmful by inhalation. Danger of very serious irreversible effects. Irritating to
respiratory system. Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Ingestion : Harmful if swallowed. Danger of very serious irreversible effects. May cause burns
to mouth, throat and stomach.
Skin contact : Corrosive to the skin. Causes burns. Harmful in contact with skin. Danger of very
serious irreversible effects.
Eye contact : Corrosive to eyes. Causes burns.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Pyridinium, 1- LD50 Oral Rat 50.1 mg/kg -
(phenylmethyl)-, ethyl methyl
derivs., chlorides
methanol LC50 Inhalation Vapour Rat 128.2 mg/l 4 hours
LD50 Dermal Rabbit 17100 mg/kg -
LD50 Oral Rat >=2528 mg/kg -
propan-2-ol LD50 Oral Rat 5000 mg/kg -
LD50 Oral Rat 5045 mg/kg -
2-aminoethanol LD50 Oral Rat 1720 mg/kg -
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : Adverse symptoms may include the following:
stomach pains
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Eye contact : Adverse symptoms may include the following:
pain
watering
redness

Date of issue/Date of revision : 17 July 2013 9/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 12: Ecological information


12.1 Toxicity : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Aquatic ecotoxicity
Product/ingredient name Result Species Exposure
methanol Acute EC50 >10000 mg/l Fresh water Daphnia 48 hours
Acute LC50 15400 mg/l Fresh water Fish 96 hours
propan-2-ol Acute LC50 10400000 ug/L Fresh water Fish - Pimephales promelas - 29 96 hours
days - 20 mm - 0.103 g
Poly(oxy-1,2-ethanediyl), α- Acute LC50 24300 ug/L Fresh water Crustaceans - Gammarus pulex 48 hours
(nonylphenyl)-ω-hydroxy-,
phosphate
2-aminoethanol Acute EC50 32.5 mg/l Marine water Algae - skeletonema costatum 72 hours
Acute EC50 80000 ug/L Fresh water Algae - Isochrysis galbana 96 hours
Acute LC50 79.3 mg/l Marine water Crustaceans 48 hours
Acute LC50 423 mg/l Marine water Fish - scopthalmus maximus 96 hours
Acute LC50 150 to 196 mg/L Fresh Fish - Oncorhynchus mykiss - 96 hours
water Yolk-sac fry
Nonylphenol, ethoxylated Acute EC50 12 mg/L Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute LC50 3.68 ug/L Fresh water Crustaceans - Thamnocephalus 48 hours
platyurus - Nauplii - 24 hours
Acute LC50 5000 ug/L Fresh water Fish - Danio rerio 96 hours
Chronic NOEC 35 ug/L Fresh water Fish - Oryzias latipes - Fry - 1 100 days
days post-hatch
Conclusion/Summary : Not available.
12.2 Persistence and degradability
Product/ingredient name Test Result Dose Inoculum
2-aminoethanol - >90 % - Readily - - -
21 days
- 70 % - Readily - - -
28 days
Conclusion/Summary : Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
2-aminoethanol - - Readily
12.3 Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
methanol -0.77 - low
propan-2-ol 0.05 - low
2-aminoethanol -1.31 - low
12.4 Mobility in soil : Not available.
12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
P: Not available. B: Not available. T: Not available.
vPvB : Not applicable.
vP: Not available. vB: Not available.
12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product

Date of issue/Date of revision : 17 July 2013 10/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 13: Disposal considerations


Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Significant quantities of waste product
residues should not be disposed of via the foul sewer but processed in a suitable
effluent treatment plant. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers.

Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not
feasible.
13.2 Additional information
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information


International transport regulations
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label
information number hazard class(es)
ADR/RID Class UN2924 Flammable liquid, corrosive, 3 (8) II
n.o.s.(contains aliphatic alcohol
& quaternary salt)

ADN/ADNR Class UN2924 Flammable liquid, corrosive, 3 (8) II


n.o.s.(contains aliphatic alcohol
& quaternary salt)

Date of issue/Date of revision : 17 July 2013 11/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 14: Transport information


IMDG Class UN2924 Flammable liquid, corrosive, 3 (8) II
n.o.s.(contains aliphatic alcohol
& quaternary salt)

IATA Class UN2924 Flammable liquid, corrosive, 3 (8) II


n.o.s.(contains aliphatic alcohol
& quaternary salt)

PG* : Packing group


Regulatory 14.5 14.6 Special precautions for user Additional
information Environmental information
hazards
ADR/RID Class Yes. Tunnel code -
(D/E)
ADN/ADNR Class Yes. - -

IMDG Class Yes. - -

IATA Class Yes. - -

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Europe inventory : Not determined.
Black List Chemicals : Not listed
Priority List Chemicals : Not listed

Date of issue/Date of revision : 17 July 2013 12/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 15: Regulatory information

15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

SECTION 16: Other information


16.1 Revision comments : Not available.
Indicates information that has changed from previously issued version.
16.2 Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
16.3 Key literature : Not available.
references and sources for
data
16.4 Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 2, H225
Acute Tox. 4, H302
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Corr. 1B, H314
STOT SE 1, H370
STOT SE 3, H335
Aquatic Chronic 1, H410
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 2, H225 On basis of test data
Acute Tox. 4, H302 Calculation method
Acute Tox. 4, H312 Calculation method
Acute Tox. 4, H332 Calculation method
Skin Corr. 1B, H314 Calculation method
STOT SE 1, H370 Calculation method
STOT SE 3, H335 Calculation method
Aquatic Chronic 1, H410 Calculation method
16.5 Full text of abbreviated : H225 Highly flammable liquid and vapour.
H statements H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H370 Causes damage to organs.
H410 Very toxic to aquatic life with long lasting effects.

Date of issue/Date of revision : 17 July 2013 13/14


Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
CGW80742P

SECTION 16: Other information


Full text of classifications : Acute Tox. 3, H301 ACUTE TOXICITY: ORAL - Category 3
[CLP/GHS] Acute Tox. 3, H311 ACUTE TOXICITY: SKIN - Category 3
Acute Tox. 3, H331 ACUTE TOXICITY: INHALATION - Category 3
Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4
Acute Tox. 4, H312 ACUTE TOXICITY: SKIN - Category 4
Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4
Aquatic Chronic 1, H410 AQUATIC TOXICITY (CHRONIC) - Category 1
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
STOT SE 1, H370 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) - Category 1
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) [Respiratory tract irritation] - Category 3
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) [Narcotic effects] - Category 3

16.5 Full text of abbreviated : R11- Highly flammable.


R phrases R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25- Toxic: danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed.
R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R21/22- Harmful in contact with skin and if swallowed.
R34- Causes burns.
R41- Risk of serious damage to eyes.
R36- Irritating to eyes.
R37- Irritating to respiratory system.
R38- Irritating to skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52- Harmful to aquatic organisms.

Full text of classifications : F - Highly flammable


[DSD/DPD] T - Toxic
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
16.6 Training advice : Not available.
16.7 Further information
Date of issue/ Date of : 17 July 2013
revision

Version : 1
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.

Date of issue/Date of revision : 17 July 2013 14/14

Potrebbero piacerti anche