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1A.1 Estimation of dense-gas viscosity
Table D.1 gives Tc 126.2 K , pc 33.5 atm , and
c 180 10 6 g cm s for N 2 . The reduced conditions for the
viscosity estimate are then
p
pr
1000 14.7 lb f in.2
2.06 (A)
pc 33.5 atm 14.7 lb f in.2 atm
T 273 K 68 32F 1.8 K F
Tr 2.32 (B)
Tc 126.2 K
1
1A.2 Estimation of the viscosity of methyl fluoride
CH 3 F has molecular weight M 16.04 1.008 19.00
34.03 g g-mol , Tc 4.55 273.15 277.70 K , pc 58.0 atm , and
V 34.03 g g-mol 0.300 g cm 3 113.4 cm 3 g-mol . The critical
c
using Eq. 1.5-1(b). The reduced conditions for the viscosity estimate
are Tr 370 273.15 K 277.70 K 2.32 , pr 120 atm 58.0 atm
2.07 , and the predicted valued of r from Fig. 1.5-1 is 1.1. The
resulting predicted value of the viscosity is
2
1A.3 Computation of the viscosities of gases at low density
Equation 1.6-14, with molecular parameters from Table D.1 and
collision integrals from Table D.2, gives the following results:
For O2: M 32.00 g g-mol , 3.433 Å , and K 113 K . Then
at 20ºC, KT 293.15 K 113 K 2.594 and 1.086 . Equation
1.6-14 then gives
32.00 293.15
2.6693 10 5
3.433 2 1.086
4
2.02 10 g cm s
10 1
Pa s 10 3 mPa s
g cm s Pa s
2.02 102 mPa s (A)
28.01 293.15
2.6693 10 5
3.667 2 1.0447
4
1.72 10 g cm s
10 1
Pa s 10 3 mPa s
g cm s Pa s
1.72 102 mPa s (B)
16.04 293.15
2.6693 10 5
3.780 2 1.197
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1.07 10 g cm s
10 1
Pa s 10 3 mPa s
g cm s Pa s
1.07 102 mPa s (B)
4
1A.4 Estimation of liquid viscosity
For Eq. 1.7-1, we need the following quantities at 0C and 100C :
The values predicted by Eq. 1.7-1 are in poor agreement with the
experimental values. This is not surprising, since the empirical
formula in Eq. 1.7-1 is inaccurate for water and other associated
liquids.
5
1A.5 Molecular velocity and mean free path
From Eq. 1.7-1, the mean molecular velocity in O 2 is
u
8 RT
8 8.31451 107 g cm 2 s 2 g-mol K 273.2 K
M 32.00 g g-mol
4.25 10 4 cm s (A)
From Eq. 1.7-3, the mean free path in O 2 at 1 atm and 273.2 K is
RT
82.0578 cm 3atm g-mol K 273.2 K
2 d 2 pN
2
2 3 10 8 cm 1 atm 6.02214 1023 g-mol -1
= 9.3 106 cm (B)
Hence the ratio of the mean free path to the molecular diameter is
9.3 104 cm
8
3.1 10 4 (C)
3 10 cm
6
1B.1 Velocity profiles and stress components
(a) xy yx b , and all other ij are zero.
vx vx b 2 y 2 , and all other vi v j are zero.
(b) xy yx 2 b , and all other ij are zero.
vx vx b 2 y 2 , vx vy vy vx b 2 xy , vy vy b 2 x 2 , and all
other vi v j are zero.
(c) All ij are zero.
vx vx b2 y 2 , vx vy vy vx b 2 xy , v y v y b2 x 2 and all
other vi v j are zero.
(d) xx yy b , zz 2 b , and all others are zero. The
components of vv may be given in the matrix:
vx vx 14 b 2 x 2 vx vy 14 b 2 xy vx vz 21 b 2 xz
vv vy vx 14 b 2 xy vy vy 14 b 2 y 2 vy vz 21 b 2 yz
2 2
v z v x 1
2 b 2
xz v z v y 1
2 b 2
yz v z v z b z
7
1B.2 A fluid in a state of rigid rotation
(a) A particle within a rigid body rotating with an angular velocity
vector w has a velocity given by v w r . If the angular velocity
vector is in the +z direction, then there are two nonzero velocity
components given by vx wz y and vy wz x . Hence the
magnitude of the angular velocity vector is b in Problem 1B.1(c).
(b) For the velocity components of Problem 1B.1(c),
(c) In Eqs. 1.2-7 through 12, we employ only the linear symmetric
combinations of derivatives of the velocity, so that in pure rotation
there would be no viscous forces present. In (b) we see that the
antisymmetric combination is nonzero in a purely rotational motion.
8
2A.1 Thickness of a falling film
(a) The volume flow rate w per unit wall width W is obtained from
Eq. 2.2-26 thus
w Re 1.0037 10 cm s 10
2 2
2.509 10 2 cm s 2 (A)
W 4 4
requested units is
w cm 2 1 gal cm s
0.02509 30.48 3600
W s 3785.3 cm 3 ft hr
gal
0.727 (B)
hr ft
(b) The film thickness is calculated from Eq. 2.2-27 and Eq. A as
13 13
3 w 3 Re
g cos W g cos 4
13
3 0.010037 cm 2 s
2 .
509 cm 2
s
980.665 cm s 2 1.0
0.009167 cm 0.00361 in (C)
9
2A.2 Determination of capillary radius by flow measurement
Assuming the flow to be laminar, we solve Eq. 2.3-23 for the
capillary radius to get
14 14
8 Lw 8 Lw
R
c 0 c L c 0 c L
14
8 4.03 10 5 m 2 s 0.5002 m 2.997 103 kg s
3.1416 4.829 10 5 kg m s 2
14
3.186 10 13 7.51 10 4 m 7.51 10 2 cm (A)
We must next get the Reynolds number in order to establish the fact
that the flow is laminar.
D vz 4w 2w
Re
D R
2 2.997 10 3
kg s
7.51 10 4 m 4.03 10 5 m 2 s 0.9552 10 3 kg m 3
66.0 (B)
Thus our assumption of laminar flow has been validated. Since the
entrance length Le 0.035DRe 0.35 cm is less than L, the entrance-
14
effect correction to R is at most of the order of 1 Le L 1 , or
0.2 percent of R in the present example.
Difficulties in this method of determination of the capillary
radius include: (1) inability to account for departures from a straight,
circular cylindrical wall geometry, and (2) inability to account for
inadvertent spatial and temporal variations of temperature, hence of
the fluid density and viscosity.
A simpler method of measuring the capillary radius is to
measure the length and mass m of a small slug of liquid mercury (or
another liquid of known density) injected into the tube, and to
10
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m L , on the
12
calculate the mean radius R of the slug from
assumption that the slug is a right circular cylinder. This method
allows for comparisons of the mean R values for various intervals of
the tube length.
11
2A.3 Volume rate of flow through an annulus
Assuming the flow to be laminar, we use Eq. 2.4-18 to
calculate the volume flow rate Q w for the following data
Here Appendix E has been used for the conversion of units. With the
above information, Eq. 2.4-18 gives
2
w 2.497 10 4 1.1 12 1 0.45 2
Q 1 0.45 4
8 3.80 10 27
2
ln 1 0.45
1 0.2025
2
0.6748 1 0.04101
ln 1 0.495
0.6748 0.1625 0.110 ft 3 s (A)
2 R 1 vz 2w
Re
R 1
2 0.110 ft 3 s 80.3 lbm ft 3 1110 (B)
1.1 12 ft 3 , 80 10 2 lbm ft s 1.4
Since this value is well within the laminar range, our assumption of
laminar flow is confirmed.
12
2A.4 Loss of catalyst particles in stack gas
(a) Rearrangement of Eq. 2.7-17 gives the terminal velocity as
D2 s g
vt (A)
18
vt 1 ft s 12 2.54 cm ft 30.48 cm s
0.045 lbm ft 3 453.59 g lbm 12 2.54 cm ft
3
7.2 10 4 g cm 3
18 vt 18 0.000026 g cm s 30.48 cm s
Dmax
s g 1.2 7.2 10 4
g cm 3 980.7 cm s 2
0.011 cm = 110 microns (A)
(b) Equation 2.7-17 was derived for Re <<1, but holds approximately
up to Re = 1. For the problem discussed here
13
2B.1 Simple shear flow between parallel plates
(a) For plates of length L and width W, a momentum balance is
LW yx LW yx 0 (A)
y y y
d yx
0 (B)
dy
yx C1 (C)
dvx
C1 (D)
dy
C1
vx y C2 (E)
v0 v0
vx y and yx (F)
b b
(b) The volume rate flow through the slit is obtained by integrating
the velocity over the cross section
14
v0
0 vx y dydz W 0 vx y dy W
W b b b
Q 0 0 ydy 21 Wbv0 (G)
b
y v0
vx v0 1 and yx (H)
b b
15
2B.2 Different choice of coordinates for the falling film problem
Set up a momentum balance as before, and obtain the
differential equation
d xz
gcos (A)
dx
Integration gives
xz x gx cos C1 (B)
x
xz x g cos 1 (C)
dvz g cos x
1 (D)
dx
g cos 1 x2 g 2 cos x 1 x 2
vz x x 2 C2 2
C2 (E)
2
16
g 2 cos x 1 x 2
vz x (F)
2
g 2cos x 1 x x
2
vz x 1 1 2 (G)
2
17
2B.3 Alternate procedure for solving flow problems
Substituting Eq. 2.2-18 into Eq. 2.2-14 gives
d dvz d 2 vz gcos
gcos or (A)
dx dx dx 2
gcos 2
vz x C1x C2 (B)
2
gcos 2 gcos 2
vz x (C)
2 2
18
2B.4 Laminar flow in a narrow slit
(a) The momentum balance in §2.2 leads to
d c c L
xz 0 (A)
dx L
Integration gives
xz x
c0 c L x C (B)
1
L
dvz c c L x C1
0 (C)
dx L
vz x
c 0 c L x 2 C1
xC (D)
2
2L
xz x
c0 c L x (E)
L
vz x
c 0 c L B2 x
1
2
(F)
2 L B
19
vz,max
c 0 c L B2
(G)
2L
and hence
vz x
2
x
1 (H)
vz,max B
0 B 1 x B 0 1 d 1 1 2
W B
dxdy
2 1 2
vz
vz,max
W B
1 3 3 (I)
0 B dxdy 0 d
w 2BW vz 2BW
c0 c L B2 2 c 0 c L B W
3
2
3 2 L
3 L
(J)
2 c0 c L B W
3
w
Q (K)
3 L
20
2B.5 Laminar slit flow with a moving wall ("plane Couette flow")
(a) Start with the velocity distribution from part (a) of Problem 2B.4
(in terms of the integration constants).
vz x
c 0 c L x 2 C1
xC (A)
2
2L
0
c 0 c L B2 C1
BC (for x B ) (B)
2
2L
c c L B C1 B C
v0 0
2
(for x B ) (C)
2
2 L
v0 c 0 c L B
2
C2 (D)
2 2L
v0
C1 (E)
2 B
vz x
c 0 c B2 x v0
1
2
1
x
(F)
2L B 2 B
c 0 c L B2 2 x v0 c0 c L v0
xz x 2 x (G)
2 L B 2B L 2B
22
2B.6 Interrelation of slit and annulus formulas
From the annular flow result in Eq. 2.4-18 we get, by
replacing by 1
c 0 c L R 4
2
1 1 2
w
8 L
1 1 4 ln 1
(A)
1 1 4 6 2 4 3 4
1 1 2 2 2
21 2 31 3 41 4
4
2
4 3 4
4 6 4
2
3 4
1 2 1 3 1 4
2 3 4
4 6 4 4 6
2 3 4 2 8
3
3 1
3
4
4 1 for small
3 4 8
3
3 1
3
4 4
3
3 1
2 (B)
c 0 c L R 4 4 3 c 0 c L R 4 3
w 1 2
1
1 21 (C)
8L 3 6L
This gives, finally, a result in agreement with Eq. 2B.6-1, which was
obtained by modifying the slit formula.
23
2B.7 Flow of a film on the outside of a circular tube
(a) The momentum balance is the same as that in §2.3, leading to Eq.
2.3-12. When the pressure-difference term is omitted, because the film
is moving solely to the force of gravity, we get
d
r rz gr 0 (A)
dr
d dvr
r gr 0 (B)
dr dr
gr 2
vz r C1ln r C2 (C)
4
C2 gR 2 4 g aR 2 . When these constants are put into
2
gR 2 r r
2
vz r 1
2 a 2
ln (D)
4 R R
2 aR aR
w 0 R vz r rdrd 2 R vz r rdr (E)
24
In the second expression, we have taken the density outside of the
integral, assuming that the fluid is incompressible. We have also
performed the integration over the angular variable. It is a little easier
to continue if we use the dimensionless variable r R . Then Eq. E
becomes
a
2 R 2 1 vz d (F)
We next insert the expression for the velocity from Eq. D, but written
in terms of the dimensionless variable of integration.
gR 2
w 2 R2 1
a
4
1 2 2 a 2ln d (G)
2 gR 2 1 2 1 4
4 2 1
a
w 2 a 2
1 2
1 2
ln
2 2 4
2 gR 2
8
1 4 a 2 3 a 4 4 a 4ln a (H)
2 gR 4 1 4 1 2 3 1 4 6 4
2 2 3 4
w (I)
8 4 1 4 6 2 4 3 4 1 2 1 3 1 4
2 3 4
Here we have use the Taylor series expansion for ln 1 in Eq. C.2-
3. We find that the terms without sum to zero, as do the terms in
and 2 . Thus we get
2 gR 4 16 3 2 2 gR 4 3
w O
4
(J)
8 3 3
25
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Now, does this simplify to the result in Eq. 2.2-26? If we make the
identification W 2 R for the width of the film, and R for the
film thickness, then Eq. J is indeed equivalent to Eq. 2.2-26 (provided
that cos 1, that is, the film is on a vertical surface).
26
2B.8 Annular flow with inner cylinder moving axially
(a) The momentum balance is the same as that in Eq. 2.4-2, but with
the pressure-difference term omitted. We can substitute Newton's
law of viscosity into this equation to get
dvz C1
(A)
dr r
whence
C1 vz r r
vz r ln r C2 or D1ln D2 (B)
v0 R
vz ln r R
(C)
v0 ln
(b) The mass rate of flow w is obtained by integrating the mass flux
vz over the cross section of flow
v0 R 2 1 v0 R 2
ln 2
2 1
R vzrdrd 2 ln ln d 2 ln
R 2
w 0 1
2
1
4
v R2 1 2
ln
2 0 21 2 ln 41 1 2 R 2 v0
2 ln 1
2
(D)
27
L 2 L 2 dvz
Fz 0 0 rz r R Rd dz 0 0
dr r R
Rd dz
2 RL v0
1 R 2 L v0 (E)
ln ln 1
2 L v0
Fz
ln1 ln 1
1
2 L v0
21 2 31 3 41 4
2 L v0 1
1 1
2 31 2 41 3
2 L v0
1 1
2 121 2 (F)
To get this last result, one can expand the fraction 1 1 , where
21 31 2 14 3 , in a Taylor series about 0 using Eq. C.2-1.
28
2B.9 Analysis of a capillary flowmeter
Designate the water by fluid "I" and the carbon tetrachloride
by "II". Label the distance from B to C as "J". The mass rate of flow in
the tube section "AB" is given by
c A c B R 4 I pA pB I gh R I
4
w (A)
8 L 8 L
pA I gh I g J H pB I gJ II gH (B)
pA pB I gh II I gH (C)
Insertion of this into the first equation above gives the expression for
the mass rate of flow in terms of the difference in the densities of the
two fluids, the acceleration of gravity, and the height H
II I gH R 4 I
w (D)
8L
w
8 1.0019 10 3 Pa s 120 in.
4 6 2
0.0254 m 100 cm 1 kg 1 Pa m 1 N s
2 2
in. m 1000 g 1 N 1 kg m
29
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