Narayana IIT Academy

INDIA
Sec: Sr. IIT-IZ(L25) Date: 02-09-18
Time: 09:00 AM to 12:00 PM 2017_P2 Max.Marks:183
KEY SHEET

PHYSICS
1 2 3 4 5 6 7 8 9 10
C C B B A B A AC ABCD AB
11 12 13 14 15 16 17 18
BD ABCD AB BC A C C D

CHEMISTRY
19 20 21 22 23 24 25 26 27 28
A A D D D C B BC BC AD
29 30 31 32 33 34 35 36
CD AC ABD AD D A B A

MATHS
37 38 39 40 41 42 43 44 45
B C B A D B B AB ACD
46 47 48 49 50 51 52 53 54
ABC ABD ABCD CD BC D A B B
 SOLUTIONS
PHYSICS
1.

Referring to the figure, the path difference between the two waves starting
from S1 and S2 turns out to be (2 cos  )  n where n is taken as 1 to get the
point of maximum intensity which is the same as a point O. Therefore, the
above relation gives
cos   1/ 2 so that   60 and tan   PO / D  3, giving PO  D 3
2
2. Here path difference will be x    2  1  t     2  1  t


 a2 
2  
I max  I min (a1  a2 )2  (a1  a2 )2 4a1a2 2a1a2 a
3. R  2 2
 2 2
 2 2
  1 2
I max  I min (a1  a2 )  (a1  a2 ) 2(a1  a2 ) a1  a2 a 
1  2 
 a1 
2
a 
Given  2   
 a1 

2 
 R .
1 
4. Let v be the velocity of the engine and V be the velocity of sound. The
frequency of the sound heard as the engine approaches the observer is given
n0
by n1 
v
1
V
The frequency of the sound heard as the engine recedes from the observer is
n0
given by n2 
v
1
V
It is given that n2  fn1
nV nV
 0  f 0 orV  v  fV  fv
V v V v
v 1 f
V 1  f   v 1  f  or 
V 1 f
The difference in the frequencies of the sound heard is
 
 n  n0 1  f 2 
n1  n2  n1 1  f    0
 1  f  
1 1 f  2f
 1 f 
 
5. (T + dT) +  gdz  T  0
 dT = -  gdz
also T =  2
As  is independent of z
d = 0
dT =  2 d 
From equation (1) and (2), we get
d g z
    dz
  0 2

2
  g /   z
 
  o e
m
6. dm  dx
l

a l dx M l
U  GMm   Gm lh(1  )
a x l a
L
g
7. vA  4

3L
g
vB  4

vB  3v A
8. Position of minima

 1  D
yn   n  
 2 d
b
Here D  d and d  b, yn 
2
b  1  d
  n  
2  2 b
b2
  , n  1, 2,3,...
(2n  1)d
b2 b2 b2
   , , ,... .
d 3d 5d
i.e., alternatives (a) and (c) are correct.

9. order of maxima are 3,2,1,0,1,2,3

d  d 
Along x-axis :   x     x   n
2  2 

2x  n
  2 3
x1  x2  x3 
2 2 3

hence x2  x1  x3  x2 also

d cos   n

3 cos   2

2
cos  
3

5
sin  
3

r  R sin 

R 5
r
3

10. If any equation satisfying this

d2y 2
2 d y
v
dt 2 dx 2
Then it is a wave.
11. Inward gravitational pull on the layer
 GM  3M
df   3 .r  (4 r 2 p.dr ), P 
 R  4 r 3
df R 3  r 2  GM 2
dp  , P  r dp  1
4 r 2 8  R 2   R 4
V2
12. Radial acceleration  , here r is radius of curvature
r

13. Horizontal force on the block Ff  m 2 x

Total reaction R  m 2 g 2  Ff2
2
 m 2 g 2   m 2 x 
1 1 1
14. Total energy in an SHM is E  m 2 x 2  mv 2  m 2 a 2
2 2 3
 1 1
Comparing, m 2  A and m  B
2 2
1 E
E m 2 a 2  E  Aa 2  Amplitude, a 
2 A
A A E E
  vmax  a   
B B A B
2 B
Time period, T   2
 A
15 &16.

1 2
y  D gt
2
Speed of screen is = gt
dx
x  d sin   d tan  
y
dx
2 
 1 2
 D  gt 
 2 
2  1 2
x  D  gt 
d  2 
 2 gt  ˆ
Velocity of 2nd maxima is =  i
 d 
 2cms 1iˆ

W   D  gt 
d

17 & 18.

l ( S1P)air   S1 P  t air l  st

yd
 s1 p  s2 p air 
D
tD  q 
y   1
d  l 
tD  T  4 
y  
d  10  T 
2  Dt  dy Dt 6
y (T  0)     Velocity v = 
5 d  dt d 10  T 2
Y=0 at T= 4sec
 CHEMISTRY
19. 2 A2 B  2 A2  B2

1 
2

 2.  P 3 
2 2
P  1     1  
 2 2
1    1   
2

 2
2
 
3
20. PH2 O  16  1012
4

PH2 O  2  103 atm

7.6
V .P.   102 atm
760
 P  V 102  2  103  1
 M   18  6.4 mg
RT 2.0821 274
21. CaCO3  CaCO  s   CO2  g 
Px
C  s  CO2  g   2CO  g 
P x 2x
2
PCO 2 2
 K P2  PCO 
K P1 10
22. At pH = 8, OH    106 M
K ip  Mg  OH  2   3 1012  K sp
Hence, pH=8 is the minimum pH.
23. pH of water changes with temperature because degree of dissociation and hence,
k also changes.
1014
k  H 2 O 298 K   1.8 10 16
1000
18
24.  H 2CO3   0.034
 CO32    HCO3 
CO32    HCO3  becaue k1  k2
 H     HCO3 
25. The given sample is hard water. There cannot be CO32 or HCO3 because its pH=7
As a result, the hardness is permanent.
4 2 KP
26. (B) K P  2
 
1 4P  K P
(C) Addition of inert gas at constant P, increases the volume, thus, forcing the reaction
in backward direction.
27. A  g   3B  g   C  g  ; H  0; PTotal  1bar;
 T  400 K
(B) Inert gas addition at constant volume, does not affect the equilibrium.
o
(C) G400  0 and not G400 .
(D) As volume  , pressure  even though the equilibrium shifts forward.
28. (D) Keq depends on T.
(A) At equilibrium, as P  , reaction moves in backward direction.
29. AnCN  Ag   CN 
CN   H   HCN
AgCN is more soluble than pure water in NH3 and buffer of pH < 7
30. pH1  p ka  log y / x
pH 2  p ka  log x / y
pH 2  pH1  2 log x / y  1
 x / y  10  3.162
1010
31. For pptn of AgCl,  Ag     2 109 M
5 102
4 1018
For pptn pf AgI,  Ag    2
 8 1017 M
5 10
32. (A) HCl  NaOH  NaCl  H 2O
102  V 102  V
  pH  7
95
(B) pH   7.0
2
33 & 34.
1 1
KP  1
1
PCl5  PCl3  Cl2
2 2 2
2 y 2 y 2 x y
 V1 V2 
6  x  y  12   
 n1 n2 
x y  6
8 2  y
KP   3 1
12  2  y 
4 2y  2  y
2  3y
2 20
y x
3 3
 0.01 0.5 
35. 8.26  9.26  log  n  
 NH 4 
0.05
 n NH 4  0.05 or  NH 4  2 SO4 
2
36. I : AcO   H   AcOH
1 1 
  1
 1
pH   pH a  log1
2

MATHS
2 100
5200  5 
100

37.  
 1  24 
8 8 8
2 100
1  C1.24  C2  24   .... 100 C100  24 
100 100


8
200
1 5  1
  int eger   
8  8  8
1000 999 999 998
38. Let, S  1  x   2 x 1  x   2 x 1  x   3x 2 1  x   .....  1001 x1000
x 999 998
S  x 1  x   2 x2 1  x   ......
1 x
1001x1001
1000 x1000 
1 x
Subtract above equations,
 x  1000 999
1   S  1  x   1  x  
 1 x 
998 1001x1001
x 2 1  x   ....  x1000 
1 x
1001 1000 999
 S  1  x   x 1  x   x 2 1  x 
........  x1000 1  x   100] x1001
1001  x 1001 
1  x     1
  1  x    1001 x1001
x
1
1 x
[sum of G.P]
1002
 1  x   x1002  1002 x1001
1002
 coefficient of x50 in S= coefficient of x50 in  1  x   x1002  1002 x 1001  1002 C50
 
6k 3k  2k
39. 
 3k  2k  3k 1  2k 1   3k  2k  3k 1  2k 1 
3k 3k 1
 
3k  2k 3k 1  2 k 1

3k 3k 1 3 32
 k
k 1 3  2
k

3k 1  2k 1
  Lt n
3  2 n 3  2n
 3 1  2
40.     d ,     2d ,     3d
D D
d 2  21  22
a p
41. Use “f(x) = x has non real roots  f(f(x)) = x also has non-real roots”
42. On solving, we get a   13  13  7  20
b 7
43.
 
 3   1   1  1
Tn  cot 1  n2    tan 1    tan 1  n    tan 1  n  
 4 3  2  2
 n2  
 4
n
 1 1  1 1
S n   t n  tan 1  n    tan 1  S   tan 1  cot 1  Tan 1 2
n 1  2 2 2 2 2

7
 7 Ck 14
r  7  7C 14
r 14 
44.   14  C k . 14C r     k  k 14  k  . 
k 0  Ck r k  k 0  14 rk k r  k r 14  r 
7 14 k
 14  k  7 7
1
   7 Ck  Cr k    7 Ck . 214 k  214  7 C k  
k 0  r k  k 0 k0 2
7
 1
 214 .  1    67  76
 2
n
45. 
If  4 5 
n
Let g   4  15  , then 0 < g < 1
3
I  f  n C0 4n  n C1 4n 1 5  n C 2 4n  2 15  n C 3 4n 3  15   ...
3
g  n C0 4n  n C1 4n 1 15  n C2 . 4n  2. 15  n C3 4n 3  15   ...
 I  f  g  2  n C 0 4n  n C 2 4n  2.15  ...  even integer
 0f g2  f  g 1  1 f  g
Thus I is an odd integer
n
1 – f = g =  4  15 
(I + f) (1 – f) = (I + f). g = 1
3 4 5
46. f ( x)   
x2 x3 x 4
 f (2 )   

and f (3 )   
 f ( x )  0 has exactly one root in (2,3)
f (3 )   
Again   f ( x)  0
and f (4 )   
Has exactly one root in (3,4)

47. A) 0
 Use

B)

Similarly,
On multiplication of (1) & (2) and expanding, we get the desired result.

D)

48. The solution of y  y is y = 0 or y = 1

If sin 1 sin x  1  x  1 or   1 (in the interval (0, ) )
But y  sin 1 sin x is periodic with period  , so x  n  1 or n  1
Again if sin 1 sin x  0  x  n
 m   (m  1)  
6
sin        
 4   4 
49. 
m 1  (m  1)  m  
4
sin   4
.sin    
4  
 
     2   5   6 
 cot   cot      cot      cot      ...  cot      cot    4
 4  4  4   4   4 
cot   tan   4
 5
  or
12 12
50. Let A.P be A, A  d , A  2d ,........ Then
t2n 1  A   2n  2  d  x  say  , Then
xA
 n  1 d 
2
x  A A x
 a  tn  A   n  1 d  a  
2 2
Let G.P be A, AR, A R 2 , ………. Then
1
2 n 2 n 1  x 2
t2 n 1  A R xR  
 A
1
n 1  x 2
b  tn  A R  A    Ax
 A
1 1
Let H.P be A , .........then
1 1
D  2D
A A
1
t2 n 1   x then
1
  2n  2 
A
 11 1 
 n  1 D    
2 x A
1 1
 c  tn  
1 1 11 1 
  n  1 D    
A A 2 x A
1

11 1 
  
2 x A
Clearly a,b, and c are A.M ., G.M and H.M between the numbers , x and A respectively
Hence a  b  c also b 2  ac
51. . No.of terms in the expansion of ( x1  x2      xr ) n  n r 1cn
 No.of terms in ( a  b  c  d )10  10  41c10  13 c10  13 c3
10!
52. Greatest coefficient =  25200
2!2!3!3!
Greatest coefficient occurs in 6 terms. They are a 2b2 c3d 3 , a 2b3c 2 d 3 , a 2b3c3d 2 , a3b 2c 2 d 3 ,
a3b 2c3d 2 and a3b3c 2 d 2 .
53 & 54.
Let  ,  ,  ,  be roots of the given equation
        12 ----(1)
  b ----(2)
  c ----(3)
  81 ----(4)
AS AM  GM
    
  ( )1/4
4
12
 (81)1/4
4
But as AM = GM
        3
(B) b    6  9  54
(B) c    4  27  108