1 SUPPLEMENTARY MATERIAL：

2 Comparisons of steam gasification reactivity of gasification-coke and long flame coal

3 (1) Gasification conditions (0.1 MPa):

4 Table 1 Gasification conditions of gasification-coke and SFC-coke in the fixed bed reactors

Feedstocka Mass (g) Particle size (mm) Temperature ( ºC) Reaction time (h) Gasifying agents

Gasification-coke 500 mL/min H2O

10.0±0.05 10−13 950 1
SFC-coke +300 mL/min N2

a
5 : Gasification-coke refers to the coke prepared according to the blending scheme in Table 3 No. 7 in the paper (45

6 wt. % SFC+25 wt. % FC+30 wt. % GC). SFC-coke refers to the coke prepared by 100 wt. % SFC (lump coal)

7 following the same heating process as gasification-coke.

8 (2) Instantaneous gas release curves: (by Raman Laser Gas Analyzer, Rlga188a)
80 80
SFC-coke
Gas flow rate (mL min g , daf)
Gas flow rate (mL min g , daf)

70 Gasification-coke 70
-1

60
-1

60
-1
-1

50 50
H2
40 H2 40

30 30

20 20 CO CO2
CO CO2
10 10
CH4 CH4
0 0
0 10 20 30 40 50 60 0 10 20 30 40 50 60
9 Time (min) Time (min)

10 Fig. 1 Instantaneous gas release behaviors of two cokes during the steam gasification at 950 ºC

11 (3) Gasification results:

12 Table 2 Gasification results of gasification-coke and SFC-coke
Ratio of residuesa Conversion Gas yield (L h-1 g-1, daf)
Ratio of H2+CO+CH4
Feedstock >10 mm >6 mm
(%, daf) H2 CO CH4 CO2 (%)
(%) (%)
Gasification-coke 44 85 50.6 1.511 0.375 0.015 0.581 76.6

SFC-coke 29 75 65.8 1.715 0.593 0.015 0.611 79.2

a
13 : the gasified residues are sieved by a sieve-shaker after vibrating for 5 minutes.

14 (4) Conclusion

1
15 The gasification-coke achieves the good reactivity and syngas yields compared to the SFC-coke

16 at the same gasification conditions, and the gasification-coke residues after steam reaction can still

17 keep the larger particle sizes. Therefore, it is suitable for fixed bed gasification, including BGL

18 gasification.