𝐿𝑛 �=𝐴−𝐵/(𝐶+𝑇) �^𝑆𝐴𝑇=𝑒^(𝐴−𝐵/

(𝐶+𝑇))
T= ºC ; P=Kpa

a b c
temperatura ºc 63 n-Pentano 13.7667 2451.88 232.014

n-Heptano 13.8622 2910.26 216.432

a) Presion vs (XI,YI) a 63 ºc
XI P YI
0 31.415044129 0 P1 SAT=
0.1 51.680927814 0.4529212 P1 SAT=
0.2 71.946811499 0.65068591 P1 SAT=
0.3 92.212695185 0.76152382 P1 SAT=
0.4 112.47857887 0.83242119 P1 SAT=
0.5 132.74446256 0.88167098 P1 SAT=
0.6 153.01034624 0.91787472 P1 SAT=
0.7 173.27622993 0.94560989 P1 SAT=
0.8 193.54211361 0.96753674 P1 SAT=
0.9 213.8079973 0.98530689 P1 SAT=
1 234.07388098 1 P1 SAT=

b) Grafique T vs (X1 ,YI) a 95 Kpa

Psat= 95 Kpa
T1SAT= 34.1237486
T2SAT= 96.219373

T P1SAT P2SAT XI YI
95 96.219373 542.81630947 95.000 0 0
95 88.219373 450.41025412 74.399168 0.0547878315 0.259757906
95 80.219373 370.17801517 57.5025382 0.1199245369 0.4672992321
95 72.219373 301.1149573 43.8131384 0.1989370376 0.6305570271
95 64.219373 242.22021128 32.8692498 0.2967779549 0.7566907256
95 56.219373 192.50475472 24.2465933 0.4205050508 0.8520970702
95 48.219373 150.9997435 17.5599367 0.5803370461 0.9224288959
95 40.219373 116.76493404 12.4640564 0.7913254948 0.9726217811
95 36.219373 102.08990334 10.4157945 0.9226618789 0.9915206529
95 34.1237486 95 9.45913145 1 1

C) Temperatura y XI para una presion de 85 Kpa y una composicion YI=.86

Presion (P)= 85 Kpa

 T1sat= 30.94901826
T2sat= 92.527598729

T P1sat XI YI
𝑋�=(𝑌_�∗�)/ 〖� 1 〗 ^𝑆𝐴𝑇
85 92.5275987 542.81630947 0.13466802 0.86
85 84.5275987 411.93345657 0.16229648 0.86
85 76.5275987 336.98026952 0.19747256 0.86
85 68.5275987 272.73344102 0.24276443 0.86
85 60.5275987 218.19654621 0.3017915 0.86
85 52.5275987 172.38882959 0.37973088 0.86
85 44.5275987 134.35360006 0.48410678 0.86
85 36.5275987 103.1666332 0.62604412 0.86
85 33.5275987 93.05528634 0.71603555 0.86
85 30.9490183 85 0.76947368 0.86
 P1 SAT= 234.073881
250 Grafica P vs X1,Y1
200
P2SAT= 31.41504413
150

P
100
234.073881
234.073881 50
234.073881
234.073881 0
0 0.2 0.4 0.6 0.8 1 1.2
234.073881
234.073881 X1,Y1

234.073881
234.073881
234.073881
234.073881
234.073881

Grafica T vs X1,Y1
120

100

80

60
P

40

20

0
0 0 0 1 1 1 1
X1,Y1
𝑋�=(𝑌_�∗�)/ 〖� 1 〗 ^𝑆𝐴𝑇
1

1 1.2
 a b c
temperatura ºc 54 Acetona 14.3145 2756.22 228.06 P1 SAT=

Acetonitrilo 14.895 3413.1 250.523 P2SAT=

a) Presion vs (XI,YI) a 54 ºc
XI P YI
0 39.9240775 0 P1 SAT= 93.9487395
0.1 45.3265437 0.20727091 P1 SAT= 93.9487395
0.2 50.7290099 0.37039453 P1 SAT= 93.9487395
0.3 56.1314761 0.50211795 P1 SAT= 93.9487395
0.4 61.5339423 0.61071166 P1 SAT= 93.9487395
0.5 66.9364085 0.70177607 P1 SAT= 93.9487395
0.6 72.3388747 0.7792386 P1 SAT= 93.9487395
0.7 77.7413409 0.84593495 P1 SAT= 93.9487395
0.8 83.1438071 0.9039638 P1 SAT= 93.9487395
0.9 88.5462733 0.95491162 P1 SAT= 93.9487395
1 93.9487395 1 P1 SAT= 93.9487395

b) Grafique T vs (X1 ,YI) a 95 Kpa En este problema no se

Psat= 95 Kpa pidio esta parte
T1SAT= 54.3215621
T2SAT= 79.5281912

T P1SAT P2SAT XI YI
95 79.5281912 211.400169 95.000 0 0
95 71.5281912 166.412751 73.4786889 0.23157614 ###
95 63.5281912 129.290213 56.0938721 0.53153105 0.72338697
95 55.5281912 99.0284332 42.2221124 0.92908477 0.9684822
95 47.5281912 74.6845477 31.2997917 1.46826246 1.15427913
95 39.5281912 55.3828334 22.8229549 2.21674798 1.29231352
95 31.5281912 40.3195612 16.3463592 3.28089843 1.39246721
95 23.5281912 28.7666388 11.4817345 4.83186163 1.46312019
95 19.5281912 24.1003007 9.54755548 5.87191236 1.48963004
95 54.3215621 95 40.3988876 1 1

C) Temperatura y XI para una presion de 65 Kpa y una composicion YI=.4

 Presion (P)= 65 Kpa

T1sat= 43.7535462
T2sat= 67.8449969

T P1sat XI YI
𝑋�=(𝑌_�∗�)/ 〖� 1 〗 ^𝑆𝐴𝑇
65 67.8449969 211.400169 0.12298949 0.4
65 65.8449969 139.29189 0.15623803 0.4
65 63.8449969 130.623399 0.20109797 0.4
65 61.8449969 122.385822 0.26255086 0.4
65 59.8449969 114.564007 0.34813092 0.4
65 57.8449969 107.143046 0.46945955 0.4
65 55.8449969 100.108282 0.64484829 0.4
65 53.8449969 93.4453144 0.90382475 0.4
65 51.8449969 87.1400062 1.07882471 0.4
65 43.7535462 65 0.27368421 0.4
93.9487395

39.9240775
〖� 1 〗 ^𝑆𝐴𝑇