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SANDS NATIONAL ACADEMY International 9-12

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Academic Year 2016-2017
Respect Learn Achieve
1st Semester

Worksheet
Work sheet No: 7 Week No: 18
Student Name: Grade: 12SAT
Topic: Acids & Bases Skills:
Subject: Chemistry Day/Date: 26/2/2017
Teacher(s): Alaa Al- Hamed Due Date: Sunday

Question 1-3 refer to the following aqueous solution

(A) 10ml of 0.01 M H2SO4


(B) 10ml of 0.01 M HCl
(C) 10ml of 0.001 M HCl
(D) 10ml of 0.001 M NH4Cl
(E) 10ml of 0.01 M NH3

1. Has a pH greater than7 E


2. After 10 ml of 0.001 M NaOH(aq) is added , has a pH of 7 C
3. after 10 ml of 0.01 M NaOH(aq) is added , has a pH less than 6 A

Questions 21-24 refer to the lettered solutions in the laboratory schemes represented below.

4. Has a hydroxide ion concentration 10-7 M at 298 k. C


5. Has the highest pH at 298 K. B
6. Has a pH greater than 7, but less 13 at 298 K. E
7. Has a pH greater than 2, but less than 7 at 298 K. D

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Questions 8-10 refer to solutions for which the pH is given below.
(A) pH equal to 1
(B) pH between 2 and 6
(C) pH equal to 7
(D) pH between 8 and 12
(E) pH equal to 13
8. 0.1 M KCl. C

9. 0.1 M HC2H3O2. B

10. 0.1 M NH3 D

Question 18-21 refer to the following process

(A) Oxidation
(B) Sublimation
(C) Reduction
(D) Neutralization
(E) Condensation

1. Process by which acid rain reacts with limestone.D


2. Process by which purple vapor is formed above iodine crystals B
3. Process by which solid C is converted to CO2 gas A
4. Process by which chromium (VI) is converted chromium metal C

Questions 10-13 refer to the processes represented by the following equations.

(A) H3O+(aq) + OH-(aq)  2H2O(I)


(B) H2(g) + ½O2(g)  H2O(I)
(C) 2H2O(I) 2H2(g) + O2(g)
(D) H2O(I)  H2O(g)
(E) 2H2O(I)  H3O+(aq) + OH-(aq)

10. The reaction of a strong acid with a strong base.A

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11. The electrolysis of H2O(I) C

12. The ionization of water E

13. The process associated with the enthalpy of vaporization (Hvap) of water. D

Questions 17-20 refer to the following solution


(A) 0.1 M Ba(OH)2
(B) 0.1 M NaOH
(C) 0.1 M CH3OH (methanol)
(D) 0.1 M HC2H3O2 (acetic acid)
(E) 0.1 M HNO3

17. Neutralizes an equal volume of 0.2 M HCl A

18. Has a hydrogen ion concentration of 1×10-1 E

19. Has a pH greater than 2 but less than 6. D

20. Has the lowest electrical conductivity of the all C

1. . The acid dissociation constant of acetic acid, HC2H3O2 , is 1.8˟10-5 .Which of the following
can be concluded from this information ?

(A) In an aqueous solution of HC2H3O2 at equilibrium , [HC2H3O2] = [H3O+]


(B) The pH of a 1.0 M solution of HC2H3O2 is 1
(C) A solution of HC2H3O2 is a buffer solution
(D) HC2H3O2 is a weak acid
(E) HC2H3O2 is a strong electrolyte

2. A newly synthesized compound is thought to be Brosted-Lowry acid.This hypothesis is verified if


the compound is shown to

(A) Be soluble in water


(B) Contain oxygen
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(C) Contain hydrogen
(D) Neutralize sodium hydroxide
(E) Burn in air

3 . A certain solution of hydrochloric acid has a pH of 3.0. Correct statements concerning this solution
include which of the following?

I. It could be diluted to obtain a solution with a pH of 2.0.

II. The concentration of the hydrogen ion, H+, (hydronium ion, H3O+) is 1x10-3 M

III. The solution is more acidic than one that has a pH of 4.0.

(A) I only
(B) III only
(C) I and II only
(D) II and III only
(E) I,II, and III

ZnCO3(s) + H+(aq)

4. When ZnCO3(s) reacts with excess aqueous acid solution as represented above , the products include
which of the following ?

I. H2(g)

II. Zn2+(aq)

III. CO2 (g)

(A) I only
(B) I and II only
(C) I and III only
(D) II and III only
(E) I, II, and III

2CrO42-(aq) + 2 H+(aq)  Cr2O72-(aq) + H2O(l)

Yellow Orange

5. On the basis of the information above, which of the following reagents,when added to a K2CrO4 (aq)
solution, would cause a color change from yellow to orange?
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(A) 1M NaOH
(B) 1M C2H5OH
(C) 1M HCl
(D) 1M NaCl
(E) 1M NH3

6. The pH of 0.01 M hydrochloric acid is closest to


(A) -2.0
(B) 0.005
(C) 0.01
(D) 2.0
(E) 12

7. The relative acidities of solutions are most often determined by use of


(A) Electrolytes
(B) Paper chromatography
(C) Indicators
(D) Calorimeters
(E) Thermometers

8. A system that is in a state of chemical equilibrium is characterized by which of the following ?


I. The observable properties of the system are constant
II. The rate of the forward reaction is equal to the rate of the reverse reaction
III. The concentration of the products is equal to the concentration of the reactants
(A) II only
(B) III only
(C) I and II only
(D) II and III only

9. In an acid-base titration, 30.0 ml of 0.10M KOH (aq) was required to titrate 60.0 ml of a solution containing
an unknown monoprotic acid. What is the molarity of the acid?
(A) 0.018M
(B) 0.050M
(C) 0.18M
(D) 0.20M
(E) 0.50M

10. Correct statements about a 0.10-molar solution of a typical strong acid include which of the
following?

I. It is a better conductor of electricity than water is.


II. it reacts with magnesium metal to produce hydrogen.
III. It has a pH greater than 8.
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(A) I only
(B) II only
(C) I and II only
(D) II and III only
(E) I, II, and III.

111. An aqueous solution of NaOH is basic BECAUSE NaOH produces an excess of OH- ions in
T water T CE

101. A 0.1 M solution of HCI has a greater BECAUSE the chlorine atom is less electronegative
concentration of H3O+ than a 0.1 M than the carbon atom is
solution of acetic acid ,HC2H3O2 , has F
T

102. All indicators are colorless in neutral BECAUSE Indicators develop color only in
solution the presence of a strong acid or
F a strong base
F

103. In 0.1 M acetic acid, [H+] is smaller BECAUSE a molecule of acetic acid
than [H+] is in 0.1 M hydrochloric acid contains more atoms than does a
T molecule of hydrogen chloride
T

104. The Cl- concentration in a 0.1M BECAUSE HCl is a weak acid. F


solution of HCl is much less than 0.1M. F

106. Acetic acid, HC2H3O2, is a strong acid F BECAUSE Each molecule of acetic acid contains four
hydrogen atoms.T

113. NH4Cl dissolves in water to give a BECAUSE NH4+ ions react with water to form NH3
basic solution. T and H3O+. F

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106. Acetic acid, HC2H3O2, is a stronger acid than BECAUSE 1 mol of acetic acid molecules contains more
water is.T hydrogen atoms than I mol of water molecules.
T

11. Given solution with the following pH values, which has the greatest concentration of H+ions?
(A) 1
(B) 5
(C) 7
(D) 9
(E) 11

12. Which of the following solutions has the highest pH?


(A) 0.1 MNH3
(B) 0.1 MNaOH
(C) 0.1 MHOCl
(D) 0.1 M H3PO4
(E) 0.1 M HC2H3O2 (acetic acid)

13. f 100 mL of 0.50MNaOH(aq) exactly neutralizes 50 mL of solution of HCl(aq), the molarity of the
HCl(aq) is:
(A) 0.10 M
(B) 0.25 M
(C) 0.50 M
(D) 1.0 M
(E) 2.0 M

14. If a student were to accurately analyze a mixture of solid NaCl and solid NaOH by titration of the
hydroxide ion with a standardized solution of HCl, which of the following would be LEAST useful?
(A) Bunsen burner
(B) Analytical balance
(C) Buret
(D) Erlenmeyer flask
(E) Indicator

Question 15-18

(A) NH3

(B) CH3OH

(C) HC2H3O2

(D) H2O2

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(E) HNO3

15. A commonly used antiseptic whose decomposition is catalyzed by light D


16. A gas that dissolves in water to form a basic solution A
17. An acid that is found in vinegar C
18. A strong acid that acts as an oxidizing agent in concentrated solution E

19. At 25o C an aqueous solution has a pH of 10.What is the hydrogen-ion concentration in the solution?
(A) 10 M
(B) 4 M
(C) 10-4 M
(D) 10-10 M
(E) 10-14 M

20. Hydrogen can be prepared by the reaction of dilute sulfuric acid with which of the following?
(A) Gold
(B) Zinc
(C) Silicon
(D) Silver
(E) Carbon

21. Which of the following is NOT an example of an acid and its conjugated base?
(A) H2SO4 and HSO4-
(B) NH3 and NH2-
(C) H2O and OH-
(D) H3O+ and H2O
(E) H2O2 and H2O

22. According to the equation above when it is completed and balanced,how many moles of HCI are
needed to react completely with 1 mole of Al (OH) 3 to form the products?
(A) 1
(B) 2
(C) 3
(D) 4
(E) 5

Questions 23-24 refer to the solution prepared as follows:


An acid is added to pure water until the hydrogen ion concentration, [H+], is 1 × 10-4M. (The ion
product for water, Kw = [H+][OH-], equals 1 × 10-14).

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23. The hydroxide ion concentration, [OH-], in the solution described above is
(A) i × 10-4M
(B) 1 × 10-7M
(C) 1 × 10-10M
(D) 1 × 10-18M
(E) 0 M

24. The pH of the solution is


(A) 0
(B) 4
(C) 7
(D) 10
(E) 14

25. Carbon dioxide can be generated by the addition of sulfuric acid to


I. NaHCO3
II. Ca CO3
III. CaCl2
(A) II only
(B) III only
(C) I and II only
(D) II and III only
(E) I, II, and III

26. Which of the following compounds reacts with H2O to form an acidic solution?
(A) Li2O
(B) CO2
(C) NaCl
(D) NaOH
(E) MgO

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…HgCl2(s) + … H2S (g)

27. When the equation for the reaction represented above is completed and balanced with all
coefficients reduced to lowest whole-number terms, the coefficient for H2S(g) is
(A) 1
(B) 2
(C) 3
(D) 4
(E) 5

28. The pH of a 0.01 M sodium chloride solution is about

(A) 1
(B) 2
(C) 7
(D) 10
(E) 12

54. Bubbling gaseous hydrogen chloride into distilled water produces a

(A) precipitate
(B) basic solution
(C) solution with pH < 7
(D) solution that does not conduct an electric current
(E) solution that turns litmus paper blue

65. If a nitric acid solution has a nitrate ion concentration of 0.01 M , the pH of the solution is
(A) 1
(B) 2
(C) 4
(D) 9
(E) 12

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63. In the table above, several acids and their conjugate bases are listed according to their
relative strengths. In solution which of the following reactions takes place to greatest
extent?
(A) OH- + H3PO4  H2O + H2PO4-
(B) HS- + HNO2  H2S + No2-
(C) NO2- + H2O  HNO2 + OH-
(D) OH- + H2S  H2O + HS-
(E) H2PO4- + HNO2 H3PO4 + NO2-

65. …… Na(s) + ….. H2O(l) 


The reaction represented above would result in the formation of which of the
following?
I. Na+ (aq)
II. Na2O(s)
III. OH-
IV. H2(g)
(A) II only
(B) I and III only
(C) II and III only
(D) II and IV only
(E) I, III, and IV only

69. When a 0.1-molar CuSO4 solution is gradually added to a 0.1-molar Ba(OH)2 solution, a
precipitate forms. During this experiment, which of the following occurs?

(A) The pH of the solution remains constant.


(B) The pH of the solution increases.
(C) The density of the solution increases.
(D) The conductance of the solution increases.
(E) The conductance of the solution decreases.

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70. If 30.0 g of NaOH(s) (molar mass 40.0 g/mol) is added to 70.0mL of H2O(I) so that the final volume of the
solution is 75.3 mL, what is the molarity of the NaOH?

30.0
(A) 𝑀
40.0 ×0.0700
30.0
(B) 40.0 ×0.0753 𝑀
30.0
(C) 𝑀
40.0 ×75.3
30.0×40.0
(D) (D) 𝑀
70.0

(E) (E) 30.0×40.0


0.0753
𝑀

71. The pH of a 0.01 M solution of potassium hydroxide is

(F) (A) 0
(G) (B) 1
(H) (C) 2
(I) (D) 7
(J) (E) 12

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