Compressor S-01 Case Study

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Case Name: DOC-20180605-WA0001.hsc

2 Company Name Not Available
3 Bedford, MA Unit Set: NewUser19a
4 USA
Date/Time: Thu May 24 13:50:35 2018
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7 Pump: B-01
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NOTES
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Compressor: S-01
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16
DESIGN
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18
Connections
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20
Inlet Stream
21 STREAM NAME FROM UNIT OPERATION
22 Alimentacion-Aire
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Outlet Stream
25 STREAM NAME TO UNIT OPERATION
26 A-01 Mixer MIX-100
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28
Energy Stream
30 TW-01
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32
Parameters
33 Speed: --- Duty: 4.3808e+03 kW
34 Adiabatic Eff.: 68.00 * PolyTropic Eff.: 68.63
35 Adiabatic Head: 1252 m Polytropic Head: 1263 m
36 Adiabatic Fluid Head: 12.28 kJ/kg Polytropic Fluid Head: 12.39 kJ/kg
37 Polytropic Exp. 1.712 Isentropic Exp. 1.400 Poly Head Factor 1.000
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39
User Variables
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41
WORKSHEET
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43
Conditions
44 Name Alimentacion-Aire A-01 TW-01
45 Vapour 1.0000 1.0000 ---
46 Temperature (K) 298.0000 * 315.7897 ---
47 Pressure (atm) 1.0000 * 1.1500 * ---
48 Molar Flow (kgmole/h) 30371.7700 * 30371.7700 ---
49 Mass Flow (tonne/h) 873.6635 873.6635 ---
50 Std Ideal Liq Vol Flow (m3/h) 1017.1894 1017.1894 ---
51 Molar Enthalpy (kJ/kgmole) -12.48 506.8 ---
52 Molar Entropy (kJ/kgmole-C) 151.5 152.0 ---
53 Heat Flow (kJ/h) -3.7911e+05 1.5392e+07 1.5771e+07
54
55
Properties
56 Name Alimentacion-Aire A-01
57 Molecular Weight 28.77 28.77
58 Molar Density (kgmole/m3) 4.092e-002 4.440e-002
59 Mass Density (kg/m3) 1.177 1.277
60 Act. Volume Flow (m3/h) 7.423e+005 6.841e+005
61 Mass Enthalpy (kJ/kg) -0.4339 17.62
62 Mass Entropy (kJ/kg-C) 5.267 5.285
63 Aspen Technology Inc. Aspen HYSYS Version 10 Page 1 of 76
Licensed to: Company Name Not Available * Specified by user.
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7 Compressor: S-01 (continued)
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Properties
12 Heat Capacity (kJ/kgmole-C) 29.20 29.31
13 Mass Heat Capacity (kJ/kg-C) 1.015 1.019
14 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000
15 HHV Molar Basis (Std) (kJ/kgmole) 0.0000 0.0000
16 HHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000
17 CO2 Loading --- ---
18 CO2 Apparent Mole Conc. (kgmole/m3) --- ---
19 CO2 Apparent Wt. Conc. (kgmol/kg) --- ---
20 LHV Mass Basis (Std) (kJ/kg) 0.0000 0.0000
21 Phase Fraction [Vol. Basis] 1.000 1.000
22 Phase Fraction [Mass Basis] 1.000 1.000
23 Phase Fraction [Act. Vol. Basis] 1.000 1.000
24 Mass Exergy (kJ/kg) 3.541e-005 12.55
25 Partial Pressure of CO2 (atm) 0.0000 0.0000
26 Cost Based on Flow (Cost/s) 0.0000 0.0000
27 Act. Gas Flow (ACT_m3/h) 7.423e+005 6.841e+005
28 Avg. Liq. Density (kgmole/m3) 29.86 29.86
29 Specific Heat (kJ/kgmole-C) 29.20 29.31
30 Std. Gas Flow (STD_m3/h) 7.181e+005 7.181e+005
31 Std. Ideal Liq. Mass Density (kg/m3) 858.9 858.9
32 Act. Liq. Flow (m3/s) --- ---
33 Z Factor 0.9995 0.9996
34 Watson K 6.079 6.079
35 User Property --- ---
36 Partial Pressure of H2S (atm) 0.0000 0.0000
37 Cp/(Cp - R) 1.398 1.396
38 Cp/Cv 1.401 1.399
39 Ideal Gas Cp/Cv 1.399 1.397
40 Ideal Gas Cp (kJ/kgmole-C) 29.14 29.25
41 Mass Ideal Gas Cp (kJ/kg-C) 1.013 1.017
42 Heat of Vap. (kJ/kgmole) 5897 5855
43 Kinematic Viscosity (cSt) 15.95 15.35
44 Liq. Mass Density (Std. Cond) (kg/m3) --- ---
45 Liq. Vol. Flow (Std. Cond) (m3/h) --- ---
46 Liquid Fraction 0.0000 0.0000
47 Molar Volume (m3/kgmole) 24.44 22.52
48 Mass Heat of Vap. (kJ/kg) 205.0 203.6
49 Phase Fraction [Molar Basis] 1.0000 1.0000
50 Surface Tension (dyne/cm) --- ---
51 Thermal Conductivity (W/m-K) 2.589e-002 2.716e-002
52 Bubble Point Pressure (atm) --- ---
53 Viscosity (cP) 1.877e-002 1.961e-002
54 Cv (Semi-Ideal) (kJ/kgmole-C) 20.88 20.99
55 Mass Cv (Semi-Ideal) (kJ/kg-C) 0.7260 0.7299
56 Cv (kJ/kgmole-C) 20.84 20.95
57 Mass Cv (kJ/kg-C) 0.7244 0.7283
58 Cv (Ent. Method) (kJ/kgmole-C) --- ---
59 Mass Cv (Ent. Method) (kJ/kg-C) --- ---
60 Cp/Cv (Ent. Method) --- ---
61 Reid VP at 37.8 C (atm) --- ---
62 True VP at 37.8 C (atm) --- ---
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Properties
12 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 0.0000 0.0000
13 Viscosity Index --- ---
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PERFORMANCE
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Results
18 Adiabatic Head (m) 1252 Power Consumed (kW) 4381
19 Polytropic Head (m) 1263 Polytropic Head Factor 1.000
20 Adiabatic Fluid Head (kJ/kg) 12.28 Polytropic Exponent 1.712
21 Polytropic Fluid Head (kJ/kg) 12.39 Isentropic Exponent 1.400
22 Adiabatic Efficiency 68 * Speed (rpm) ---
23 Polytropic Efficiency 69 ---
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25
Power/Torque
26 Total Rotor Power (kW) 4381 Total Rotor Torque (N-m) ---
27 Transient Rotor Power (kW) 0.0000 Transient Rotor Torque (N-m) ---
28 Friction Power Loss (kW) 0.0000 Friction Torque Loss (N-m) ---
29 Fluid Power (kW) 4381 Fluid Torque (N-m) ---
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31
DYNAMICS
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33
Dynamic Specifications
34 Duty (kJ/h) 1.577e+007 Active Head (m) 1263 Not Active
35 Adiabatic Efficiency 68 * Not Active Fluid Head (kJ/kg) 12.39 Not Active
36 Polytropic Efficiency 69 Active Capacity (ACT_m3/h) 7.423e+005 Not Active
37 Pressure Increase (kPa) 15.20 Not Active Speed (rpm) --- Not Active
38 --- Use Characteristic Curves No
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40
Holdup Details
41 Phase Accumulation Moles Volume
42 (kgmole/h) (kgmole) (m3)
43 Vapour 0.0000 0.0000 0.0000
44 Liquid 0.0000 0.0000 0.0000
45 Aqueous 0.0000 0.0000 0.0000
46 Total 0.0000 0.0000 0.0000
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48 Mixer: MIX-100
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51
CONNECTIONS
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53
Inlet Stream
55 M-01 Pump B-01
56 A-01 Compressor S-01
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Outlet Stream
60 C-01 Heat Exchanger IC-01
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PARAMETERS
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7 Mixer: MIX-100 (continued)
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User Variables
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CONDITIONS
13 Name M-01 A-01 C-01
14 Vapour 0.0000 1.0000 0.9976
15 Temperature (K) 298.0079 315.7897 272.2204
16 Pressure (atm) 1.1500 * 1.1500 * 1.1500
17 Molar Flow (kgmole/h) 1125.7135 30371.7700 31497.4835
18 Mass Flow (tonne/h) 36.0700 873.6635 909.7335
19 Std Ideal Liq Vol Flow (m3/h) 45.3300 1017.1894 1062.5194
20 Molar Enthalpy (kJ/kgmole) -2.395e+005 506.8 -8069
21 Molar Entropy (kJ/kgmole-C) 7.288 152.0 148.0
22 Heat Flow (kJ/h) -2.6955e+08 1.5392e+07 -2.5416e+08
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PROPERTIES
25 Name M-01 A-01 C-01
26 Molecular Weight 32.04 28.77 28.88
27 Molar Density (kgmole/m3) 24.54 4.440e-002 5.168e-002
28 Mass Density (kg/m3) 786.2 1.277 1.493
29 Act. Volume Flow (m3/h) 45.88 6.841e+005 6.094e+005
30 Mass Enthalpy (kJ/kg) -7473 17.62 -279.4
31 Mass Entropy (kJ/kg-C) 0.2274 5.285 5.123
32 Heat Capacity (kJ/kgmole-C) 115.5 29.31 29.70
33 Mass Heat Capacity (kJ/kg-C) 3.604 1.019 1.028
34 LHV Molar Basis (Std) (kJ/kgmole) 6.381e+005 0.0000 2.281e+004
35 HHV Molar Basis (Std) (kJ/kgmole) 7.201e+005 0.0000 2.574e+004
36 HHV Mass Basis (Std) (kJ/kg) 2.247e+004 0.0000 891.1
37 CO2 Loading --- --- ---
38 CO2 Apparent Mole Conc. (kgmole/m3) 0.0000 --- ---
39 CO2 Apparent Wt. Conc. (kgmol/kg) 0.0000 --- ---
40 LHV Mass Basis (Std) (kJ/kg) 1.991e+004 0.0000 789.6
41 Phase Fraction [Vol. Basis] 0.0000 1.000 0.9972
42 Phase Fraction [Mass Basis] 0.0000 1.000 0.9974
43 Phase Fraction [Act. Vol. Basis] 0.0000 1.000 1.000
44 Mass Exergy (kJ/kg) 11.03 12.55 14.21
45 Partial Pressure of CO2 (atm) 0.0000 0.0000 0.0000
46 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000
47 Act. Gas Flow (ACT_m3/h) --- 6.841e+005 6.094e+005
48 Avg. Liq. Density (kgmole/m3) 24.83 29.86 29.64
49 Specific Heat (kJ/kgmole-C) 115.5 29.31 29.70
50 Std. Gas Flow (STD_m3/h) 2.662e+004 7.181e+005 7.447e+005
51 Std. Ideal Liq. Mass Density (kg/m3) 795.7 858.9 856.2
52 Act. Liq. Flow (m3/s) 1.274e-002 --- 8.152e-004
53 Z Factor 1.917e-003 0.9996 ---
54 Watson K 10.63 6.079 6.292
55 User Property --- --- ---
56 Partial Pressure of H2S (atm) 0.0000 0.0000 0.0000
57 Cp/(Cp - R) 1.078 1.396 1.389
58 Cp/Cv 1.374 1.399 1.393
59 Ideal Gas Cp/Cv 1.234 1.397 1.394
60 Ideal Gas Cp (kJ/kgmole-C) 43.84 29.25 29.44
61 Mass Ideal Gas Cp (kJ/kg-C) 1.368 1.017 1.019
62 Heat of Vap. (kJ/kgmole) 3.484e+004 5855 1.657e+004
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PROPERTIES
11 Name M-01 A-01 C-01
12 Kinematic Viscosity (cSt) 0.6942 15.35 ---
13 Liq. Mass Density (Std. Cond) (kg/m3) 796.4 --- ---
14 Liq. Vol. Flow (Std. Cond) (m3/h) 45.29 --- ---
15 Liquid Fraction 1.000 0.0000 2.363e-003
16 Molar Volume (m3/kgmole) 4.076e-002 22.52 19.35
17 Mass Heat of Vap. (kJ/kg) 1087 203.6 573.9
18 Phase Fraction [Molar Basis] 0.0000 1.0000 0.9976
19 Surface Tension (dyne/cm) 29.61 --- 33.78
20 Thermal Conductivity (W/m-K) 0.1798 2.716e-002 ---
21 Bubble Point Pressure (atm) 0.1662 --- ---
22 Viscosity (cP) 0.5458 1.961e-002 ---
23 Cv (Semi-Ideal) (kJ/kgmole-C) 107.2 20.99 21.39
24 Mass Cv (Semi-Ideal) (kJ/kg-C) 3.344 0.7299 0.7406
25 Cv (kJ/kgmole-C) 84.04 20.95 21.33
26 Mass Cv (kJ/kg-C) 2.623 0.7283 0.7385
27 Cv (Ent. Method) (kJ/kgmole-C) --- --- ---
28 Mass Cv (Ent. Method) (kJ/kg-C) --- --- ---
29 Cp/Cv (Ent. Method) --- --- ---
30 Reid VP at 37.8 C (atm) 0.3158 --- ---
31 True VP at 37.8 C (atm) 0.3158 --- ---
32 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 45.29 0.0000 2.994
33 Viscosity Index -2.285 --- ---
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DYNAMICS
36 Pressure Specification: Set Outlet to Lowest Inlet
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Holdup Details
41 Vapour 0.0000 0.0000 0.0000
42 Liquid 0.0000 0.0000 0.0000
43 Aqueous 0.0000 0.0000 0.0000
44 Total 0.0000 0.0000 0.0000
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46 Heat Exchanger: IC-02
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CONNECTIONS
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Tube Side Shell Side
52 Inlet Outlet Inlet Outlet
53 Name Vapor Name SE02 Name C-03 Name C-04
54 From Op. To Op. From Op. IC-01 To Op. S-02
55 Op. Type Op. Type Op. Type Heat Exchanger Op. Type Compressor
56 Temp 610.00 K * Temp 580.00 K * Temp 443.00 K * Temp 570.00 K *
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58
PARAMETERS
59
Heat Exchanger Model: Simple End Point
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61 Tube Side DeltaP: 0.0000 kPa * Shell Side DeltaP: 0.5066 kPa Passes: ---
62 UA: 1.823e+006 kJ/C-h Tolerance: 1.0000e-04
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7 Heat Exchanger: IC-02 (continued)
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11 Tube Side Data Shell Side Data
12 Heat Transfer Coeff --- Heat Transfer Coeff ---
13 Tube Pressure Drop 0.00 kPa * Shell Pressure Drop 0.51 kPa
14 Fouling 0.00000 C-h-m2/kJ Fouling 0.00000 C-h-m2/kJ
15 Tube Length 6.00 m Shell Passes 1
16 Tube O.D. 20.00 mm Shell Series 1
17 Tube Thickness 2.0000 mm Shell Parallel 1
18 Tube Pitch 50.0000 mm Baffle Type Single
19 Orientation Horizontal Baffle Cut(%Area) 20.00
20 Passes Per Shell 2 Baffle Orientation Horizontal
21 Tubes Per Shell 160 * Spacing 800.0000 mm
22 Layout Angle Triangular (30 degrees) Diameter 739.0488 mm
23 TEMA Type AE L Area 60.32 m2
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SPECS
26 Spec Value Curr Value Rel Error Active Estimate
27 E-100 Heat Balance 0.0000 kJ/h -5.512e-003 kJ/h -4.376e-011 On Off
28 E-100 UA --- 1.823e+006 kJ/C-h --- On Off
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Detailed Specifications
31 E-100 Heat Balance
32 Type: Duty Pass: Error Spec Value: 0.0000 kJ/h
33 E-100 UA
34 Type: UA Pass: Overall Spec Value: ---
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User Variables
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38
CONDITIONS
39 Name Vapor C-03 SE02 C-04
40 Vapour 1.0000 1.0000 1.0000 1.0000
41 Temperature (K) 610.0000 * 443.0000 * 580.0000 * 570.0000 *
42 Pressure (atm) 1.1500 * 1.1500 1.1500 1.1450 *
43 Molar Flow (kgmole/h) 114917.9661 31497.4835 114917.9661 31497.4835
44 Mass Flow (tonne/h) 2070.2587 909.7335 2070.2587 909.7335
45 Std Ideal Liq Vol Flow (m3/h) 2074.4366 1062.5194 2074.4366 1062.5194
46 Molar Enthalpy (kJ/kgmole) -2.310e+005 -2810 -2.321e+005 1190
47 Molar Entropy (kJ/kgmole-C) 197.3 163.1 195.5 171.0
48 Heat Flow (kJ/h) -2.6542e+10 -8.8493e+07 -2.6668e+10 3.7483e+07
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50
PROPERTIES
52 Molecular Weight 18.02 28.88 18.02 28.88
53 Molar Density (kgmole/m3) 2.303e-002 3.163e-002 2.423e-002 2.447e-002
54 Mass Density (kg/m3) 0.4149 0.9137 0.4365 0.7068
55 Act. Volume Flow (m3/h) 4.990e+006 9.957e+005 4.742e+006 1.287e+006
56 Mass Enthalpy (kJ/kg) -1.282e+004 -97.27 -1.288e+004 41.20
57 Mass Entropy (kJ/kg-C) 10.95 5.646 10.85 5.922
58 Heat Capacity (kJ/kgmole-C) 36.72 30.96 36.37 32.01
59 Mass Heat Capacity (kJ/kg-C) 2.038 1.072 2.019 1.108
60 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 2.281e+004 0.0000 2.281e+004
61 HHV Molar Basis (Std) (kJ/kgmole) 4.101e+004 2.574e+004 4.101e+004 2.574e+004
62 HHV Mass Basis (Std) (kJ/kg) 2276 891.1 2276 891.1
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PROPERTIES
12 CO2 Loading --- --- --- ---
13 CO2 Apparent Mole Conc. (kgmole/m3) --- --- --- ---
14 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- --- ---
15 LHV Mass Basis (Std) (kJ/kg) 0.0000 789.6 0.0000 789.6
16 Phase Fraction [Vol. Basis] 1.000 1.000 1.000 1.000
17 Phase Fraction [Mass Basis] 1.000 1.000 1.000 1.000
18 Phase Fraction [Act. Vol. Basis] 1.000 1.000 1.000 1.000
19 Mass Exergy (kJ/kg) 212.8 40.30 182.5 96.52
20 Partial Pressure of CO2 (atm) 0.0000 0.0000 0.0000 0.0000
21 Cost Based on Flow (Cost/s) 0.0000 0.0000 0.0000 0.0000
22 Act. Gas Flow (ACT_m3/h) 4.990e+006 9.957e+005 4.742e+006 1.287e+006
23 Avg. Liq. Density (kgmole/m3) 55.40 29.64 55.40 29.64
24 Specific Heat (kJ/kgmole-C) 36.72 30.96 36.37 32.01
25 Std. Gas Flow (STD_m3/h) 2.717e+006 7.447e+005 2.717e+006 7.447e+005
26 Std. Ideal Liq. Mass Density (kg/m3) 998.0 856.2 998.0 856.2
27 Act. Liq. Flow (m3/s) --- --- --- ---
28 Z Factor 0.9976 1.000 0.9972 1.000
29 Watson K --- 6.292 --- 6.292
30 User Property --- --- --- ---
31 Partial Pressure of H2S (atm) 0.0000 0.0000 0.0000 0.0000
32 Cp/(Cp - R) 1.293 1.367 1.296 1.351
33 Cp/Cv 1.297 1.369 1.301 1.352
34 Ideal Gas Cp/Cv 1.294 1.368 1.298 1.351
35 Ideal Gas Cp (kJ/kgmole-C) 36.61 30.93 36.25 32.00
36 Mass Ideal Gas Cp (kJ/kg-C) 2.032 1.071 2.012 1.108
37 Heat of Vap. (kJ/kgmole) 3.969e+004 1.657e+004 3.969e+004 1.657e+004
38 Kinematic Viscosity (cSt) 52.43 26.71 47.02 41.37
39 Liq. Mass Density (Std. Cond) (kg/m3) 1015 --- 1015 ---
40 Liq. Vol. Flow (Std. Cond) (m3/h) 2040 --- 2040 ---
41 Liquid Fraction 0.0000 0.0000 0.0000 0.0000
42 Molar Volume (m3/kgmole) 43.42 31.61 41.27 40.86
43 Mass Heat of Vap. (kJ/kg) 2203 573.9 2203 573.8
44 Phase Fraction [Molar Basis] 1.0000 1.0000 1.0000 1.0000
45 Surface Tension (dyne/cm) --- --- --- ---
46 Thermal Conductivity (W/m-K) 4.755e-002 3.520e-002 4.420e-002 4.306e-002
47 Bubble Point Pressure (atm) 138.7 --- 93.43 ---
48 Viscosity (cP) 2.176e-002 2.440e-002 2.053e-002 2.925e-002
49 Cv (Semi-Ideal) (kJ/kgmole-C) 28.40 22.65 28.05 23.70
50 Mass Cv (Semi-Ideal) (kJ/kg-C) 1.577 0.7842 1.557 0.8205
51 Cv (kJ/kgmole-C) 28.31 22.63 27.95 23.69
52 Mass Cv (kJ/kg-C) 1.572 0.7834 1.552 0.8201
53 Cv (Ent. Method) (kJ/kgmole-C) --- --- --- ---
54 Mass Cv (Ent. Method) (kJ/kg-C) --- --- --- ---
55 Cp/Cv (Ent. Method) --- --- --- ---
56 Reid VP at 37.8 C (atm) --- --- --- ---
57 True VP at 37.8 C (atm) --- --- --- ---
58 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 2040 0.0000 2040 0.0000
59 Viscosity Index --- --- --- ---
60
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DETAILS
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Overall/Detailed Performance
11 Duty: 1.260e+08 kJ/h UA Curv. Error: 0.00e-01 kJ/C-h
12 Heat Leak: 0.000e-01 kJ/h Hot Pinch Temp: 610.0 K
13 Heat Loss: 0.000e-01 kJ/h Cold Pinch Temp: 570.0 K
14 UA: 1.823e+06 kJ/C-h Ft Factor: ---
15 Min. Approach: 40.00 C Uncorrected Lmtd: 78.80 C
16 Lmtd: 69.10 C
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18
TABLES
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Shell Side - Overall Phase
21 Temperature Pressure Heat Flow Enthalpy
22 (K) (atm) (kJ/h) (kJ/kgmole)
23 443.00 1.15 0.00 -2809.52
24 570.00 1.15 125975877.21 1190.04
25 UA Molar Vap Frac Mass Vap Frac Heat of Vap.
26 (kJ/C-h) (kJ/kgmole)
27 0.00 1.0000 1.0000 ---
28 0.00 1.0000 1.0000 ---
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30
Shell Side - Vapour Phase
31 Mass Flow Molecular Wt Density Mass Sp Heat Viscosity Thermal Cond
32 (tonne/h) (kg/m3) (kJ/kg-C) (cP) (W/m-K)
33 909.73 28.88 0.91 1.07 0.02 0.04
34 909.73 28.88 0.71 1.11 0.03 0.04
35 Std Gas Flow Z Factor Pseudo Pc Pseudo Tc Pseudo Zc Pseudo Omega
36 (STD_m3/h) (atm) (K)
37 744740.25 1.00 37.93 145.21 0.29 0.05
38 744740.25 1.00 37.93 145.21 0.29 0.05
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40
Shell Side - Light Liquid Phase
41 Mass Flow Density Mass Sp Heat Viscosity Thermal Cond Surface Tens
42 (tonne/h) (kg/m3) (kJ/kg-C) (cP) (W/m-K) (dyne/cm)
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
45 Molecular Wt Sp Gravity Pseudo Pc Pseudo Tc Pseudo Zc Pseudo Omega
46 (atm) (K)
47 --- --- --- --- --- ---
48 --- --- --- --- --- ---
49
50
Shell Side - Heavy Liquid Phase
53 --- --- --- --- --- ---
54 --- --- --- --- --- ---
56 (atm) (K)
57 --- --- --- --- --- ---
58 --- --- --- --- --- ---
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Shell Side - Mixed Liquid
13 --- --- --- --- --- ---
14 --- --- --- --- --- ---
16 (atm) (K)
17 --- --- --- --- --- ---
18 --- --- --- --- --- ---
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Tube Side - Overall Phase
23 580.00 1.15 0.00 -232058.69
24 610.00 1.15 125975877.22 -230962.46
27 0.00 1.0000 1.0000 ---
28 0.00 1.0000 1.0000 ---
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Tube Side - Vapour Phase
33 2070.26 18.02 0.44 2.02 0.02 0.04
34 2070.26 18.02 0.41 2.04 0.02 0.05
36 (STD_m3/h) (atm) (K)
37 --- 1.00 218.31 647.30 0.26 0.34
38 --- 1.00 218.31 647.30 0.26 0.34
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Tube Side - Light Liquid Phase
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
46 (atm) (K)
47 --- --- --- --- --- ---
48 --- --- --- --- --- ---
49
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Tube Side - Heavy Liquid Phase
53 --- --- --- --- --- ---
54 --- --- --- --- --- ---
56 (atm) (K)
57 --- --- --- --- --- ---
58 --- --- --- --- --- ---
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Tube Side - Mixed Liquid
13 --- --- --- --- --- ---
14 --- --- --- --- --- ---
16 (atm) (K)
17 --- --- --- --- --- ---
18 --- --- --- --- --- ---
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20
---
21
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23 1.8
24
25 Tube Side
1.6 Shell Side
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Pressure (atm)
27
28
1.4
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31 1.2
32
33
34 1.0
35
36
37 0.8
38
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0.6
40
440.0 460.0 480.0 500.0 520.0 540.0 560.0 580.0 600.0 620.0
Temperature (K)
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45 Compressor: S-02
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47
48
DESIGN
49
50
Connections
51
52
Inlet Stream
55
56
Outlet Stream
58 C-05 Plug Flow Reactor R-01
59
60
Energy Stream
62 TW-02
1
4 USA
5
6
8
9
10
Parameters
11 Speed: --- Duty: 5.4132e+03 kW
13 Adiabatic Head: 1485 m Polytropic Head: 1493 m
16
17
User Variables
18
19
WORKSHEET
20
21
Conditions
22 Name C-04 C-05 TW-02
23 Vapour 1.0000 1.0000 ---
24 Temperature (K) 570.0000 * 589.2842 ---
25 Pressure (atm) 1.1450 * 1.2500 * ---
26 Molar Flow (kgmole/h) 31497.4835 31497.4835 ---
27 Mass Flow (tonne/h) 909.7335 909.7335 ---
29 Molar Enthalpy (kJ/kgmole) 1190 1809 ---
31 Heat Flow (kJ/h) 3.7483e+07 5.6971e+07 1.9488e+07
32
33
Properties
34 Name C-04 C-05
37 Mass Density (kg/m3) 0.7068 0.7464
39 Mass Enthalpy (kJ/kg) 41.20 62.62
43 LHV Molar Basis (Std) (kJ/kgmole) 2.281e+004 2.281e+004
44 HHV Molar Basis (Std) (kJ/kgmole) 2.574e+004 2.574e+004
53 Mass Exergy (kJ/kg) 96.52 114.5
61 Act. Liq. Flow (m3/s) --- ---
62 Z Factor 1.000 1.000
1
4 USA
5
6
8
9
10
Properties
11 Name C-04 C-05
12 Watson K 6.292 6.292
15 Cp/(Cp - R) 1.351 1.349
16 Cp/Cv 1.352 1.349
20 Heat of Vap. (kJ/kgmole) 1.657e+004 1.661e+004
31 Viscosity (cP) 2.925e-002 2.998e-002
34 Cv (kJ/kgmole-C) 23.69 23.84
35 Mass Cv (kJ/kg-C) 0.8201 0.8255
39 Reid VP at 37.8 C (atm) --- ---
40 True VP at 37.8 C (atm) --- ---
43
44
PERFORMANCE
45
46
Results
47 Adiabatic Head (m) 1485 Power Consumed (kW) 5413
48 Polytropic Head (m) 1493 Polytropic Head Factor 1.000
53
54
Power/Torque
55 Total Rotor Power (kW) 5413 Total Rotor Torque (N-m) ---
58 Fluid Power (kW) 5413 Fluid Torque (N-m) ---
59
60
DYNAMICS
61
62
1
4 USA
5
6
8
9 Duty (kJ/h) 1.949e+007 Active Head (m) 1493 Not Active
14
15
Holdup Details
18 Vapour 0.0000 0.0000 0.0000
19 Liquid 0.0000 0.0000 0.0000
20 Aqueous 0.0000 0.0000 0.0000
21 Total 0.0000 0.0000 0.0000
22
23 Plug Flow Reactor: R-01
24
25
CONNECTIONS
26
27
Inlet Stream
28
30 C-05 Compressor S-02
31
Outlet Stream
32
34 C-06 Compressor S-03
35
Energy Stream
36
38 Q-R-01
39
PARAMETERS
40
41
Physical Parameters
42
43 Type : User Specified Pressure Drop: 7.500 kPa *
44
Heat Transfer
45
46 Type : Direct Q Value Energy Stream : Q-R-01 Duty : 4.380e+008 kJ/h
47
Dimensions
48
49 Total Volume: 4.500 m3 Length: 3.700 m * Diameter: 5.080e-002 m * Number of Tubes: 600 *
50 Wall Thickness: 5.000e-003 m * Void Fraction: 0.4000 * Void Volume: 1.800 m3
51
Reaction Info
52
53 Reaction Set: Set-1 Initialize From: Current
54
Integration Information
55
56 Number of Segments: 20 * Minimum Step Fraction: 1.0e-06 * Minimum Step Length: 3.7e-06 m
57
Catalyst Data
58
59 Particle Diameter: 3.000e-003 m * Particle Spericity: 1.0000 * Solid Density: 1667 kg/m3 *
60 Bulk Density: 1000 kg/m3 Solid Heat Capacity: 250.0 kJ/kg-C *
61
User Variables
62
1
4 USA
5
6
7 Plug Flow Reactor: R-01 (continued)
8
9
Conditions
10
11 Length Temperature Pressure Vapour Fraction Duty
12 (m) (K) (atm) (kJ/h)
13 0.092 589.3 1.25 1.0000 21899470
14 0.277 589.3 1.24 1.0000 21899466
15 0.463 589.3 1.24 1.0000 21899461
16 0.647 589.3 1.24 1.0000 21899458
17 0.833 589.3 1.23 1.0000 21899453
18 1.018 589.3 1.23 1.0000 21899449
19 1.202 589.3 1.22 1.0000 21899444
20 1.388 589.3 1.22 1.0000 21899440
21 1.573 589.3 1.22 1.0000 21899435
22 1.758 589.3 1.21 1.0000 21899431
23 1.942 589.3 1.21 1.0000 21899426
24 2.127 589.3 1.21 1.0000 21899421
25 2.313 589.3 1.20 1.0000 21899416
26 2.498 589.3 1.20 1.0000 21899412
27 2.683 589.3 1.19 1.0000 21899407
28 2.868 589.3 1.19 1.0000 21899403
29 3.052 589.3 1.19 1.0000 21899398
30 3.237 589.3 1.18 1.0000 21899394
31 3.422 589.3 1.18 1.0000 21899389
32 3.607 589.3 1.18 1.0000 21899384
33 Length Enthalpy Entropy Inside HTC Overall HTC
34 (m) (kJ/kgmole) (kJ/kgmole-C) (kJ/h-m2-C) (kJ/h-m2-C)
35 0.092 1112 171.72 --- ---
36 0.277 417 171.99 --- ---
37 0.463 -276 172.25 --- ---
38 0.647 -968 172.49 --- ---
39 0.833 -1658 172.72 --- ---
40 1.018 -2347 172.95 --- ---
41 1.202 -3034 173.16 --- ---
42 1.388 -3719 173.37 --- ---
43 1.573 -4403 173.57 --- ---
44 1.758 -5086 173.77 --- ---
45 1.942 -5767 173.96 --- ---
46 2.127 -6446 174.14 --- ---
47 2.313 -7124 174.32 --- ---
48 2.498 -7800 174.49 --- ---
49 2.683 -8475 174.66 --- ---
50 2.868 -9148 174.83 --- ---
51 3.052 -9820 174.99 --- ---
52 3.237 -10490 175.14 --- ---
53 3.422 -11159 175.28 --- ---
54 3.607 -11826 175.42 --- ---
55
Flows
56
57 Length Molar Flow Mass Flow Volumetric Flow Heat Flow
58 (m) (kgmole/h) (tonne/h) (m3/h) (kJ/h)
59 0.092 31533.480 909.73 1223870.347 3.507e+007
60 0.277 31569.477 909.73 1228913.952 1.317e+007
61 0.463 31605.473 909.73 1233987.705 -8.728e+006
62 0.647 31641.470 909.73 1239091.873 -3.063e+007
1
4 USA
5
6
8
9
Flows
10
11 Length Molar Flow Mass Flow Volumetric Flow Heat Flow
12 (m) (kgmole/h) (tonne/h) (m3/h) (kJ/h)
13 0.833 31677.466 909.73 1244226.736 -5.253e+007
14 1.018 31713.463 909.73 1249392.565 -7.443e+007
15 1.202 31749.459 909.73 1254589.647 -9.633e+007
16 1.388 31785.456 909.73 1259818.262 -1.182e+008
17 1.573 31821.452 909.73 1265078.702 -1.401e+008
18 1.758 31857.449 909.73 1270371.253 -1.620e+008
19 1.942 31893.445 909.73 1275696.215 -1.839e+008
20 2.127 31929.442 909.73 1281053.883 -2.058e+008
21 2.313 31965.438 909.73 1286444.563 -2.277e+008
22 2.498 32001.435 909.73 1291868.556 -2.496e+008
23 2.683 32037.431 909.73 1297326.177 -2.715e+008
24 2.868 32073.428 909.73 1302817.734 -2.934e+008
25 3.052 32109.425 909.73 1308343.551 -3.153e+008
26 3.237 32145.421 909.73 1313903.943 -3.372e+008
27 3.422 32181.418 909.73 1319499.241 -3.591e+008
28 3.607 32217.414 909.73 1325129.771 -3.810e+008
29
Segment Overall Reaction Rates (kgmole/m3-s)
30
31 Length (m) Rxn-1
32 9.250e-002 2.778e-002
33 0.2775 2.778e-002
34 0.4625 2.778e-002
35 0.6475 2.778e-002
36 0.8325 2.778e-002
37 1.018 2.778e-002
38 1.202 2.778e-002
39 1.388 2.778e-002
40 1.573 2.778e-002
41 1.758 2.778e-002
42 1.942 2.778e-002
43 2.127 2.778e-002
44 2.313 2.778e-002
45 2.498 2.778e-002
46 2.683 2.778e-002
47 2.868 2.778e-002
48 3.052 2.778e-002
49 3.237 2.778e-002
50 3.422 2.778e-002
51 3.607 2.778e-002
52
Component Production Rates (kgmole/m3-s)
53
54 Length (m) Oxygen Nitrogen Methanol H2O
55 9.250e-002 -0.1667 0.0000 -0.1667 0.2778
56 0.2775 -0.1667 0.0000 -0.1667 0.2778
57 0.4625 -0.1667 0.0000 -0.1667 0.2778
58 0.6475 -0.1667 0.0000 -0.1667 0.2778
59 0.8325 -0.1667 0.0000 -0.1667 0.2778
60 1.018 -0.1667 0.0000 -0.1667 0.2778
61 1.202 -0.1667 0.0000 -0.1667 0.2778
62 1.388 -0.1667 0.0000 -0.1667 0.2778
1
4 USA
5
6
8
9
Component Production Rates (kgmole/m3-s)
10
12 1.573 -0.1667 0.0000 -0.1667 0.2778
13 1.758 -0.1667 0.0000 -0.1667 0.2778
14 1.942 -0.1667 0.0000 -0.1667 0.2778
15 2.127 -0.1667 0.0000 -0.1667 0.2778
16 2.313 -0.1667 0.0000 -0.1667 0.2778
17 2.498 -0.1667 0.0000 -0.1667 0.2778
18 2.683 -0.1667 0.0000 -0.1667 0.2778
19 2.868 -0.1667 0.0000 -0.1667 0.2778
20 3.052 -0.1667 0.0000 -0.1667 0.2778
21 3.237 -0.1667 0.0000 -0.1667 0.2778
22 3.422 -0.1667 0.0000 -0.1667 0.2778
23 3.607 -0.1667 0.0000 -0.1667 0.2778
24 Length (m) Formaldehyde CO CO2
25 9.250e-002 5.556e-002 5.556e-002 5.556e-002
26 0.2775 5.556e-002 5.556e-002 5.556e-002
27 0.4625 5.556e-002 5.556e-002 5.556e-002
28 0.6475 5.556e-002 5.556e-002 5.556e-002
29 0.8325 5.556e-002 5.556e-002 5.556e-002
30 1.018 5.556e-002 5.556e-002 5.556e-002
31 1.202 5.556e-002 5.556e-002 5.556e-002
32 1.388 5.556e-002 5.556e-002 5.556e-002
33 1.573 5.556e-002 5.556e-002 5.556e-002
34 1.758 5.556e-002 5.556e-002 5.556e-002
35 1.942 5.556e-002 5.556e-002 5.556e-002
36 2.127 5.556e-002 5.556e-002 5.556e-002
37 2.313 5.556e-002 5.556e-002 5.556e-002
38 2.498 5.556e-002 5.556e-002 5.556e-002
39 2.683 5.556e-002 5.556e-002 5.556e-002
40 2.868 5.556e-002 5.556e-002 5.556e-002
41 3.052 5.556e-002 5.556e-002 5.556e-002
42 3.237 5.556e-002 5.556e-002 5.556e-002
43 3.422 5.556e-002 5.556e-002 5.556e-002
44 3.607 5.556e-002 5.556e-002 5.556e-002
45
Transport
46
47 Length Viscosity Moleular Weight Mass Density Heat Capacity Surface Tension Z Factor
48 (m) (cP) (kg/m3) (kJ/kgmole-C) (dyne/cm)
49 9.250e-002 2.994e-002 28.85 0.7433 32.141 --- 1.000
50 0.2775 2.990e-002 28.82 0.7403 32.111 --- 1.000
51 0.4625 2.986e-002 28.78 0.7372 32.081 --- 1.000
52 0.6475 2.982e-002 28.75 0.7342 32.052 --- 1.000
53 0.8325 2.978e-002 28.72 0.7312 32.022 --- 1.000
54 1.018 2.974e-002 28.69 0.7281 31.993 --- 1.000
55 1.202 2.970e-002 28.65 0.7251 31.963 --- 1.000
56 1.388 2.966e-002 28.62 0.7221 31.934 --- 1.000
57 1.573 2.962e-002 28.59 0.7191 31.904 --- 1.000
58 1.758 2.958e-002 28.56 0.7161 31.875 --- 1.000
59 1.942 2.954e-002 28.52 0.7131 31.846 --- 1.000
60 2.127 2.951e-002 28.49 0.7101 31.817 --- 1.000
61 2.313 2.947e-002 28.46 0.7072 31.788 --- 1.000
62 2.498 2.943e-002 28.43 0.7042 31.759 --- 1.000
1
4 USA
5
6
8
9
Transport
10
11 Length Viscosity Moleular Weight Mass Density Heat Capacity Surface Tension Z Factor
12 (m) (cP) (kg/m3) (kJ/kgmole-C) (dyne/cm)
13 2.683 2.939e-002 28.40 0.7012 31.730 --- 1.000
14 2.868 2.936e-002 28.36 0.6983 31.701 --- 1.000
15 3.052 2.932e-002 28.33 0.6953 31.672 --- 1.000
16 3.237 2.928e-002 28.30 0.6924 31.644 --- 1.000
17 3.422 2.925e-002 28.27 0.6895 31.615 --- 1.000
18 3.607 2.921e-002 28.24 0.6865 31.586 --- 1.000
19
Component Molar Flowrates (kgmole/h)
20
22 9.250e-002 5679.4223 24638.3530 1071.7187 89.9912
23 0.2775 5625.4275 24638.3530 1017.7240 179.9825
24 0.4625 5571.4329 24638.3530 963.7292 269.9737
25 0.6475 5517.4381 24638.3530 909.7345 359.9650
26 0.8325 5463.4434 24638.3530 855.7398 449.9562
27 1.018 5409.4487 24638.3530 801.7450 539.9475
28 1.202 5355.4540 24638.3530 747.7503 629.9387
29 1.388 5301.4592 24638.3530 693.7555 719.9300
30 1.573 5247.4645 24638.3530 639.7608 809.9212
31 1.758 5193.4698 24638.3530 585.7660 899.9125
32 1.942 5139.4751 24638.3530 531.7713 989.9037
33 2.127 5085.4804 24638.3530 477.7765 1079.8950
34 2.313 5031.4857 24638.3530 423.7818 1169.8862
35 2.498 4977.4909 24638.3530 369.7870 1259.8775
36 2.683 4923.4962 24638.3530 315.7923 1349.8687
37 2.868 4869.5015 24638.3530 261.7975 1439.8600
38 3.052 4815.5068 24638.3530 207.8028 1529.8512
39 3.237 4761.5120 24638.3530 153.8080 1619.8425
40 3.422 4707.5173 24638.3530 99.8133 1709.8337
41 3.607 4653.5226 24638.3530 45.8185 1799.8250
43 9.250e-002 17.9982 17.9982 17.9982
44 0.2775 35.9965 35.9965 35.9965
45 0.4625 53.9947 53.9947 53.9947
46 0.6475 71.9930 71.9930 71.9930
47 0.8325 89.9912 89.9912 89.9912
48 1.018 107.9895 107.9895 107.9895
49 1.202 125.9877 125.9877 125.9877
50 1.388 143.9860 143.9860 143.9860
51 1.573 161.9842 161.9842 161.9842
52 1.758 179.9825 179.9825 179.9825
53 1.942 197.9807 197.9807 197.9807
54 2.127 215.9790 215.9790 215.9790
55 2.313 233.9772 233.9772 233.9772
56 2.498 251.9755 251.9755 251.9755
57 2.683 269.9737 269.9737 269.9737
58 2.868 287.9720 287.9720 287.9720
59 3.052 305.9702 305.9702 305.9702
60 3.237 323.9685 323.9685 323.9685
61 3.422 341.9667 341.9667 341.9667
62 3.607 359.9650 359.9650 359.9650
1
4 USA
5
6
8
9
Component Mole Fractions
10
12 9.250e-002 0.1801 0.7813 0.0340 0.0029
13 0.2775 0.1782 0.7804 0.0322 0.0057
14 0.4625 0.1763 0.7796 0.0305 0.0085
15 0.6475 0.1744 0.7787 0.0288 0.0114
16 0.8325 0.1725 0.7778 0.0270 0.0142
17 1.018 0.1706 0.7769 0.0253 0.0170
18 1.202 0.1687 0.7760 0.0236 0.0198
19 1.388 0.1668 0.7751 0.0218 0.0226
20 1.573 0.1649 0.7743 0.0201 0.0255
21 1.758 0.1630 0.7734 0.0184 0.0282
22 1.942 0.1611 0.7725 0.0167 0.0310
23 2.127 0.1593 0.7716 0.0150 0.0338
24 2.313 0.1574 0.7708 0.0133 0.0366
25 2.498 0.1555 0.7699 0.0116 0.0394
26 2.683 0.1537 0.7690 0.0099 0.0421
27 2.868 0.1518 0.7682 0.0082 0.0449
28 3.052 0.1500 0.7673 0.0065 0.0476
29 3.237 0.1481 0.7665 0.0048 0.0504
30 3.422 0.1463 0.7656 0.0031 0.0531
31 3.607 0.1444 0.7648 0.0014 0.0559
33 9.250e-002 0.0006 0.0006 0.0006
34 0.2775 0.0011 0.0011 0.0011
35 0.4625 0.0017 0.0017 0.0017
36 0.6475 0.0023 0.0023 0.0023
37 0.8325 0.0028 0.0028 0.0028
38 1.018 0.0034 0.0034 0.0034
39 1.202 0.0040 0.0040 0.0040
40 1.388 0.0045 0.0045 0.0045
41 1.573 0.0051 0.0051 0.0051
42 1.758 0.0056 0.0056 0.0056
43 1.942 0.0062 0.0062 0.0062
44 2.127 0.0068 0.0068 0.0068
45 2.313 0.0073 0.0073 0.0073
46 2.498 0.0079 0.0079 0.0079
47 2.683 0.0084 0.0084 0.0084
48 2.868 0.0090 0.0090 0.0090
49 3.052 0.0095 0.0095 0.0095
50 3.237 0.0101 0.0101 0.0101
51 3.422 0.0106 0.0106 0.0106
52 3.607 0.0112 0.0112 0.0112
53
PROPERTIES
54
55 Name C-05 C-06
58 Mass Density (kg/m3) 0.7464 0.6865
60 Mass Enthalpy (kJ/kg) 62.62 -418.8
1
4 USA
5
6
8
9
PROPERTIES
10
11 Name C-05 C-06
13 LHV Molar Basis (Std) (kJ/kgmole) 2.281e+004 9873
24 Partial Pressure of CO2 (atm) 0.0000 1.314e-002
31 Act. Liq. Flow (m3/s) --- ---
32 Z Factor 1.000 ---
33 Watson K 6.292 6.242
36 Cp/(Cp - R) 1.349 1.357
37 Cp/Cv 1.349 1.358
52 Viscosity (cP) 2.998e-002 2.921e-002
55 Cv (kJ/kgmole-C) 23.84 23.26
56 Mass Cv (kJ/kg-C) 0.8255 0.8237
60 Reid VP at 37.8 C (atm) --- ---
61 True VP at 37.8 C (atm) --- ---
1
4 USA
5
6
8
9
PROPERTIES
10
11 Name C-05 C-06
13
DYNAMICS
14
15
Vessel Parameters: Initialize from Product
16
17 Single Phase: Not Activated Lag Rxn Temperature: Not Activated
18 Laminar Flow Activated Fixed Delta P Not Activated
19 Flow Equation Activated PFR Elevation (m) 0 *
20
Pressure Flow Relation Segmented Holdup Details
21
22 Segment Pressure-Flow K (kg/hr/sqrt(kPa-kg/m3)) View Holdup
23 1.000 * --- R-01:Seg-1 Holdup
24 2.000 * --- R-01:Seg-2 Holdup
25 3.000 * --- R-01:Seg-3 Holdup
26 4.000 * --- R-01:Seg-4 Holdup
27 5.000 * --- R-01:Seg-5 Holdup
28 6.000 * --- R-01:Seg-6 Holdup
29 7.000 * --- R-01:Seg-7 Holdup
30 8.000 * --- R-01:Seg-8 Holdup
31 9.000 * --- R-01:Seg-9 Holdup
32 10.00 * --- R-01:Seg-10 Holdup
33 11.00 * --- R-01:Seg-11 Holdup
34 12.00 * --- R-01:Seg-12 Holdup
35 13.00 * --- R-01:Seg-13 Holdup
36 14.00 * --- R-01:Seg-14 Holdup
37 15.00 * --- R-01:Seg-15 Holdup
38 16.00 * --- R-01:Seg-16 Holdup
39 17.00 * --- R-01:Seg-17 Holdup
40 18.00 * --- R-01:Seg-18 Holdup
41 19.00 * --- R-01:Seg-19 Holdup
42 20.00 * --- R-01:Seg-20 Holdup
43
Overall Holdup Details
44
47 Vapour 0.0000 0.0000 0.0000
48 Liquid 0.0000 0.0000 0.0000
49 Aqueous 0.0000 0.0000 0.0000
50 Total 0.0000 0.0000 0.0000
51
Direct Q
52
53 SP (kJ/h) 4.380e+008 Max. Available (kJ/h) ---
54 Min. Available (kJ/h) 0.0000
55
Heat Flow into the PFR: Cooling
56
57
58 Compressor: S-03
59
60
61
DESIGN
62
1
4 USA
5
6
8
9
10
Connections
11
12
Inlet Stream
14 C-06 Plug Flow Reactor R-01
15
16
Outlet Stream
19
20
Energy Stream
22 TW-03
23
24
Parameters
25 Speed: --- Duty: 5.3778e+04 kW
27 Adiabatic Head: 1.476e+004 m Polytropic Head: 1.538e+004 m
30
31
User Variables
32
33
WORKSHEET
34
35
Conditions
36 Name C-06 C-07 TW-03
37 Vapour 1.0000 1.0000 ---
38 Temperature (K) 589.3000 * 775.9665 ---
39 Pressure (atm) 1.1760 2.5000 * ---
41 Mass Flow (tonne/h) 909.7322 909.7322 ---
43 Molar Enthalpy (kJ/kgmole) -1.183e+004 -5817 ---
45 Heat Flow (kJ/h) -3.8102e+08 -1.8742e+08 1.9360e+08
46
47
Properties
48 Name C-06 C-07
51 Mass Density (kg/m3) 0.6865 1.108
53 Mass Enthalpy (kJ/kg) -418.8 -206.0
57 LHV Molar Basis (Std) (kJ/kgmole) 9873 9873
1
4 USA
5
6
8
9
10
Properties
11 Name C-06 C-07
17 Partial Pressure of CO2 (atm) 1.314e-002 2.793e-002
24 Act. Liq. Flow (m3/s) --- ---
25 Z Factor --- 1.001
26 Watson K 6.242 6.242
29 Cp/(Cp - R) 1.357 1.340
30 Cp/Cv 1.358 1.340
44 Bubble Point Pressure (atm) --- 288.7
45 Viscosity (cP) 2.921e-002 3.615e-002
48 Cv (kJ/kgmole-C) 23.26 24.47
49 Mass Cv (kJ/kg-C) 0.8237 0.8664
53 Reid VP at 37.8 C (atm) --- ---
54 True VP at 37.8 C (atm) --- ---
57
58
PERFORMANCE
59
60
Results
61 Adiabatic Head (m) 1.476e+004 Power Consumed (kW) 5.378e+004
62 Polytropic Head (m) 1.538e+004 Polytropic Head Factor 1.000
1
4 USA
5
6
8
9
10
Results
15
16
Power/Torque
17 Total Rotor Power (kW) 5.378e+004 Total Rotor Torque (N-m) ---
20 Fluid Power (kW) 5.378e+004 Fluid Torque (N-m) ---
21
22
DYNAMICS
23
24
25 Duty (kJ/h) 1.936e+008 Active Head (m) 1.538e+004 Not Active
30
31
Holdup Details
34 Vapour 0.0000 0.0000 0.0000
35 Liquid 0.0000 0.0000 0.0000
36 Aqueous 0.0000 0.0000 0.0000
37 Total 0.0000 0.0000 0.0000
38
40
41
42
CONNECTIONS
43
44
46 Name C-07 Name C-08 Name C-01 Name C-03
47 From Op. S-03 To Op. IC-03 From Op. MIX-100 To Op. IC-02
48 Op. Type Compressor Op. Type Heat Exchanger Op. Type Mixer Op. Type Heat Exchanger
49 Temp 775.97 K Temp 616.73 K Temp 272.22 K Temp 443.00 K *
50
51
PARAMETERS
52
53
54 Tube Side DeltaP: 0.0000 kPa Shell Side DeltaP: 0.0000 kPa * Passes: ---
58 Tube Pressure Drop 0.00 kPa Shell Pressure Drop 0.00 kPa *
1
4 USA
5
6
8
9
10
17
18
SPECS
20 E-100 Heat Balance 0.0000 kJ/h -2.619e-008 kJ/h -1.581e-016 On Off
21 E-100 UA --- 5.099e+005 kJ/C-h --- On Off
22
23
26 E-100 UA
28
29
User Variables
30
31
CONDITIONS
32 Name C-07 C-01 C-08 C-03
33 Vapour 1.0000 0.9976 1.0000 1.0000
34 Temperature (K) 775.9665 272.2204 616.7340 443.0000 *
35 Pressure (atm) 2.5000 * 1.1500 2.5000 * 1.1500
37 Mass Flow (tonne/h) 909.7322 909.7335 909.7322 909.7335
39 Molar Enthalpy (kJ/kgmole) -5817 -8069 -1.096e+004 -2810
41 Heat Flow (kJ/h) -1.8742e+08 -2.5416e+08 -3.5309e+08 -8.8493e+07
42
43
PROPERTIES
44 Name C-07 C-01 C-08 C-03
46 Molar Density (kgmole/m3) 3.924e-002 5.168e-002 4.937e-002 3.163e-002
47 Mass Density (kg/m3) 1.108 1.493 1.394 0.9137
48 Act. Volume Flow (m3/h) 8.211e+005 6.094e+005 6.526e+005 9.957e+005
49 Mass Enthalpy (kJ/kg) -206.0 -279.4 -388.1 -97.27
53 LHV Molar Basis (Std) (kJ/kgmole) 9873 2.281e+004 9873 2.281e+004
55 HHV Mass Basis (Std) (kJ/kg) 451.1 891.1 451.1 891.1
56 CO2 Loading --- --- --- ---
57 CO2 Apparent Mole Conc. (kgmole/m3) --- --- --- ---
58 CO2 Apparent Wt. Conc. (kgmol/kg) --- --- --- ---
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name C-07 C-01 C-08 C-03
12 Mass Exergy (kJ/kg) 287.1 14.21 183.2 40.30
13 Partial Pressure of CO2 (atm) 2.793e-002 0.0000 2.793e-002 0.0000
15 Act. Gas Flow (ACT_m3/h) 8.211e+005 6.094e+005 6.526e+005 9.957e+005
20 Act. Liq. Flow (m3/s) --- 8.152e-004 --- ---
21 Z Factor 1.001 --- 1.001 1.000
22 Watson K 6.242 6.292 6.242 6.292
23 User Property --- --- --- ---
25 Cp/(Cp - R) 1.340 1.389 1.354 1.367
26 Cp/Cv 1.340 1.393 1.356 1.369
27 Ideal Gas Cp/Cv 1.340 1.394 1.355 1.368
31 Kinematic Viscosity (cSt) 32.63 --- 21.68 26.71
32 Liq. Mass Density (Std. Cond) (kg/m3) --- --- --- ---
33 Liq. Vol. Flow (Std. Cond) (m3/h) --- --- --- ---
34 Liquid Fraction 0.0000 2.363e-003 0.0000 0.0000
35 Molar Volume (m3/kgmole) 25.49 19.35 20.26 31.61
36 Mass Heat of Vap. (kJ/kg) 457.8 573.9 457.8 573.9
38 Surface Tension (dyne/cm) --- 33.78 --- ---
39 Thermal Conductivity (W/m-K) 5.531e-002 --- 4.597e-002 3.520e-002
40 Bubble Point Pressure (atm) 288.7 --- --- ---
41 Viscosity (cP) 3.615e-002 --- 3.022e-002 2.440e-002
44 Cv (kJ/kgmole-C) 24.47 21.33 23.45 22.63
45 Mass Cv (kJ/kg-C) 0.8664 0.7385 0.8304 0.7834
48 Cp/Cv (Ent. Method) --- --- --- ---
49 Reid VP at 37.8 C (atm) --- --- --- ---
50 True VP at 37.8 C (atm) --- --- --- ---
51 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 0.0000 2.994 0.0000 0.0000
52 Viscosity Index --- --- --- ---
53
54
DETAILS
55
56
61 Min. Approach: 333.0 C Uncorrected Lmtd: 338.7 C
62 Lmtd: 324.9 C
1
4 USA
5
6
8
9
10
TABLES
11
12
15 272.22 1.15 0.00 -8069.22
16 273.27 1.15 3947874.75 -7943.88
17 443.00 1.15 165667475.44 -2809.52
20 0.00 0.9976 0.9974 ---
21 0.00 1.0000 1.0000 ---
22 0.00 1.0000 1.0000 ---
23
24
27 907.35 28.88 1.49 1.02 0.02 0.02
28 909.73 28.88 1.48 1.02 0.02 0.02
29 909.73 28.88 0.91 1.07 0.02 0.04
31 (STD_m3/h) (atm) (K)
32 742980.61 1.00 37.85 144.34 0.29 0.05
33 744740.25 1.00 37.93 145.21 0.29 0.05
34 744740.25 1.00 37.93 145.21 0.29 0.05
35
36
39 2.38 812.49 3.54 0.81 0.19 33.78
40 0.00 811.44 3.54 0.80 0.19 33.61
41 --- --- --- --- --- ---
43 (atm) (K)
44 32.04 0.81 72.80 512.60 0.25 0.56
45 32.04 0.81 72.80 512.60 0.25 0.56
46 --- --- --- --- --- ---
47
48
51 --- --- --- --- --- ---
52 --- --- --- --- --- ---
53 --- --- --- --- --- ---
55 (atm) (K)
56 --- --- --- --- --- ---
57 --- --- --- --- --- ---
58 --- --- --- --- --- ---
59
60
61
62
1
4 USA
5
6
8
9
10
13 2.38 812.49 3.54 0.81 0.19 ---
14 0.00 811.44 3.54 0.80 0.19 ---
15 --- --- --- --- --- ---
17 (atm) (K)
18 32.04 0.81 72.80 512.60 0.25 0.56
19 32.04 0.81 72.80 512.60 0.25 0.56
20 --- --- --- --- --- ---
21
22
25 616.73 2.50 0.00 -10959.48
26 775.97 2.50 165667475.44 -5817.31
29 0.00 1.0000 1.0000 ---
30 0.00 1.0000 1.0000 ---
31
32
35 909.73 28.24 1.39 1.13 0.03 0.05
36 909.73 28.24 1.11 1.16 0.04 0.06
38 (STD_m3/h) (atm) (K)
39 761762.60 1.00 47.09 165.18 0.29 0.06
40 761762.60 1.00 47.09 165.18 0.29 0.06
41
42
45 --- --- --- --- --- ---
46 --- --- --- --- --- ---
48 (atm) (K)
49 --- --- --- --- --- ---
50 --- --- --- --- --- ---
51
52
55 --- --- --- --- --- ---
56 --- --- --- --- --- ---
58 (atm) (K)
59 --- --- --- --- --- ---
60 --- --- --- --- --- ---
61
62
1
4 USA
5
6
8
9
10
13 --- --- --- --- --- ---
14 --- --- --- --- --- ---
16 (atm) (K)
17 --- --- --- --- --- ---
18 --- --- --- --- --- ---
19
20
---
21
22
23 2.6
24
25 2.4 Tube Side
26 Shell Side
2.2
Pressure (atm)
27
28
29 2.0
30
31 1.8
32
33
1.6
34
35
1.4
36
37
1.2
38
39
1.0
40
200.0 300.0 400.0 500.0 600.0 700.0 800.0
Temperature (K)
41
42
43
44
45
DYNAMICS
46
47
Basic Model
48
49
Model Parameters
50 Tube Volume (m3) 0.1000 Shell UA (tonne/h) ---
51 Shell Volume (m3) 0.1000 Tube UA (tonne/h) ---
52 Elevation (m) 0.0000 Minimum Flow Scale Factor 0.0000 *
53 Overall UA (kJ/C-h) 5.099e+005
54
55
Summary
56 Shell Duty: --- Tube Duty: ---
57
58
Pressure Flow Specifications
59
60
Shell Side Specification
61 Delta P (kPa) 0.0000 * Active k kg/hr/sqrt(kPa-kg/m3) --- Not Active
62 Tube Side Specifications
1
4 USA
5
6
8
10 Delta P (kPa) --- Active k kg/hr/sqrt(kPa-kg/m3) --- Not Active
11
12
Holdup
13
14
Shell Holdup
17 Vapour 0.0000 0.0000 0.0000
18 Liquid 0.0000 0.0000 0.0000
19 Aqueous 0.0000 0.0000 0.0000
20 Total 0.0000 0.0000 0.0000
21
22
Tube Holdup
25 Vapour 0.0000 0.0000 0.0000
26 Liquid 0.0000 0.0000 0.0000
27 Aqueous 0.0000 0.0000 0.0000
28 Total 0.0000 0.0000 0.0000
29
31
32
33
CONNECTIONS
34
35
37 Name Agua Fria Name SE Name C-08 Name C-09
38 From Op. To Op. From Op. IC-01 To Op. T-100
39 Op. Type Op. Type Op. Type Heat Exchanger Op. Type Absorber
40 Temp 298.00 K * Temp 349.00 K * Temp 616.73 K Temp 310.00 K *
41
42
PARAMETERS
43
44
45 Tube Side DeltaP: 0.0000 kPa * Shell Side DeltaP: 0.0000 kPa * Passes: ---
49 Tube Pressure Drop 0.00 kPa * Shell Pressure Drop 0.00 kPa *
60
61
SPECS
1
4 USA
5
6
8
9 E-100 Heat Balance 0.0000 kJ/h -7.692 kJ/h -2.157e-008 On Off
10 E-100 UA --- 4.306e+006 kJ/C-h --- On Off
11
12
15 E-100 UA
17
18
User Variables
19
20
CONDITIONS
21 Name Agua Fria C-08 SE C-09
22 Vapour 0.0000 1.0000 0.0000 0.9584
23 Temperature (K) 298.0000 * 616.7340 349.0000 * 310.0000 *
24 Pressure (atm) 1.1500 * 2.5000 * 1.1500 2.5000
26 Mass Flow (tonne/h) 1658.3686 909.7322 1658.3686 909.7322
28 Molar Enthalpy (kJ/kgmole) -2.849e+005 -1.096e+004 -2.810e+005 -2.203e+004
31
32
PROPERTIES
35 Molar Density (kgmole/m3) 55.92 4.937e-002 53.72 0.1027
36 Mass Density (kg/m3) 1007 1.394 967.8 2.900
37 Act. Volume Flow (m3/h) 1646 6.526e+005 1714 3.137e+005
38 Mass Enthalpy (kJ/kg) -1.582e+004 -388.1 -1.560e+004 -780.2
42 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 9873 0.0000 9873
45 CO2 Loading --- --- --- ---
46 CO2 Apparent Mole Conc. (kgmole/m3) 0.0000 --- 0.0000 ---
47 CO2 Apparent Wt. Conc. (kgmol/kg) 0.0000 --- 0.0000 ---
52 Mass Exergy (kJ/kg) 20.11 183.2 -304.1 80.72
53 Partial Pressure of CO2 (atm) 0.0000 2.793e-002 0.0000 2.914e-002
55 Act. Gas Flow (ACT_m3/h) --- 6.526e+005 --- 3.137e+005
60 Act. Liq. Flow (m3/s) 0.4572 --- 0.4760 7.996e-003
61 Z Factor 8.410e-004 1.001 7.475e-004 ---
62 Watson K --- 6.242 --- 6.242
1
4 USA
5
6
8
9
10
PROPERTIES
12 User Property --- --- --- ---
14 Cp/(Cp - R) 1.123 1.354 1.124 1.357
15 Cp/Cv 1.151 1.356 1.177 1.343
16 Ideal Gas Cp/Cv 1.329 1.355 1.325 1.390
20 Kinematic Viscosity (cSt) 0.8869 21.68 0.3825 ---
21 Liq. Mass Density (Std. Cond) (kg/m3) 1015 --- 1015 ---
22 Liq. Vol. Flow (Std. Cond) (m3/h) 1634 --- 1634 ---
23 Liquid Fraction 1.000 0.0000 1.000 4.158e-002
24 Molar Volume (m3/kgmole) 1.788e-002 20.26 1.861e-002 9.738
27 Surface Tension (dyne/cm) 72.13 --- 63.10 62.40
28 Thermal Conductivity (W/m-K) 0.6108 4.597e-002 0.6668 ---
29 Bubble Point Pressure (atm) 3.100e-002 --- 0.3944 ---
30 Viscosity (cP) 0.8935 3.022e-002 0.3702 ---
33 Cv (kJ/kgmole-C) 65.75 23.45 64.23 23.54
34 Mass Cv (kJ/kg-C) 3.649 0.8304 3.565 0.8337
37 Cp/Cv (Ent. Method) --- --- --- ---
38 Reid VP at 37.8 C (atm) --- --- --- ---
39 True VP at 37.8 C (atm) --- --- --- ---
40 Liq. Vol. Flow - Sum(Std. Cond) (m3/h) 1634 0.0000 1634 28.22
41 Viscosity Index 1.550 --- -14.99 ---
42
43
DETAILS
44
45
50 Min. Approach: 12.00 C Uncorrected Lmtd: ---
51 Lmtd: 82.83 C
52
53
TABLES
54
55
58 310.00 2.50 0.00 -22030.03
59 329.03 2.50 70751266.80 -19833.97
60 616.73 2.50 356664481.98 -10959.48
61
62
1
4 USA
5
6
8
9
10
13 0.00 0.9584 0.9708 ---
14 0.00 1.0000 1.0000 ---
15 0.00 1.0000 1.0000 ---
16
17
20 883.20 28.60 2.82 1.04 0.02 0.03
21 909.73 28.24 2.62 1.06 0.02 0.03
22 909.73 28.24 1.39 1.13 0.03 0.05
24 (STD_m3/h) (atm) (K)
25 730086.14 1.00 40.65 145.81 0.29 0.05
26 761762.60 1.00 47.09 165.18 0.29 0.06
27 761762.60 1.00 47.09 165.18 0.29 0.06
28
29
32 --- --- --- --- --- ---
33 0.00 902.21 3.95 0.37 0.54 58.65
34 --- --- --- --- --- ---
36 (atm) (K)
37 --- --- --- --- --- ---
38 19.87 0.90 194.64 610.24 0.26 0.33
39 --- --- --- --- --- ---
40
41
44 26.53 921.71 3.93 0.51 0.53 62.40
45 --- --- --- --- --- ---
46 --- --- --- --- --- ---
48 (atm) (K)
49 19.80 0.92 195.52 611.64 0.26 0.33
50 --- --- --- --- --- ---
51 --- --- --- --- --- ---
52
53
56 26.53 921.71 3.93 0.51 0.53 ---
57 0.00 902.21 3.95 0.37 0.54 ---
58 --- --- --- --- --- ---
60 (atm) (K)
61 19.80 0.92 195.52 611.64 0.26 0.33
62 19.87 0.90 194.64 610.24 0.26 0.33
1
4 USA
5
6
8
9
10
12 (atm) (K)
13 --- --- --- --- --- ---
14
15
18 298.00 1.15 0.00 -284914.03
19 349.00 1.15 356664474.29 -281039.53
22 0.00 0.0000 0.0000 ---
23 0.00 0.0000 0.0000 ---
24
25
28 --- --- --- --- --- ---
29 --- --- --- --- --- ---
31 (STD_m3/h) (atm) (K)
32 --- --- --- --- --- ---
33 --- --- --- --- --- ---
34
35
38 --- --- --- --- --- ---
39 --- --- --- --- --- ---
41 (atm) (K)
42 --- --- --- --- --- ---
43 --- --- --- --- --- ---
44
45
48 1658.37 1007.45 4.20 0.89 0.61 72.13
49 1658.37 967.79 4.20 0.37 0.67 63.10
51 (atm) (K)
52 18.02 1.01 218.31 647.30 0.26 0.34
53 18.02 0.97 218.31 647.30 0.26 0.34
54
55
58 1658.37 1007.45 4.20 0.89 0.61 ---
59 1658.37 967.79 4.20 0.37 0.67 ---
61 (atm) (K)
62 18.02 1.01 218.31 647.30 0.26 0.34
1
4 USA
5
6
8
9
10
12 (atm) (K)
13 18.02 0.97 218.31 647.30 0.26 0.34
14
15
---
16
17
18 2.6
19
20 2.4 Tube Side
21 Shell Side
22 2.2
Pressure (atm)
23
24 2.0
25
26 1.8
27
28
1.6
29
30
1.4
31
32
1.2
33
34
1.0
35
250.0 300.0 350.0 400.0 450.0 500.0 550.0 600.0 650.0
Temperature (K)
36
37
38
39
40 Absorber: T-100
41
42
CONNECTIONS
43
44 Inlet Stream
45 STREAM NAME Stage FROM UNIT OPERATION
46 S-M 1__Main Tower Mixer MIX-101
47 C-09 20__Main Tower Heat Exchanger IC-03
48 Outlet Stream
49 STREAM NAME Stage TO UNIT OPERATION
50 Gas de Recyclo 1__Main Tower
51 C-13 20__Main Tower Heat Exchanger IC-04
52
MONITOR
53
54 Specifications Summary
55 Specified Value Current Value Wt. Error
56
57 Wt. Tol. Abs. Tol. Active Estimate Used
58
59
SPECS
60
61
62
1
4 USA
5
6
7 Absorber: T-100 (continued)
8
9 Column Specification Parameters
10
11
12 Fix/Rang: Prim/Alter: Lower Bnd: Upper Bnd:
13
SUBCOOLING
14
15
16 Degrees of Subcooling
17 Subcool to
18
User Variables
19
20
PROFILES
21
22 General Parameters
23 Sub-Flow Sheet: T-100 (COL1) Number of Stages: 20 *
24 Profile Estimates
25 Temperature Net Liquid Net Vapour
26 (K) (kgmole/h) (kgmole/h)
27 1__Main Tower 380.0 * 1601 3.085e+004
28 2__Main Tower 309.9 1602 3.087e+004
29 3__Main Tower 309.9 1602 3.087e+004
30 4__Main Tower 309.9 1602 3.087e+004
31 5__Main Tower 309.9 1602 3.087e+004
32 6__Main Tower 309.9 1602 3.087e+004
33 7__Main Tower 309.9 1602 3.087e+004
34 8__Main Tower 309.9 1602 3.087e+004
35 9__Main Tower 309.9 1602 3.087e+004
36 10__Main Tower 309.9 1602 3.087e+004
37 11__Main Tower 309.9 1602 3.087e+004
38 12__Main Tower 309.9 1602 3.087e+004
39 13__Main Tower 309.9 1602 3.087e+004
40 14__Main Tower 309.9 1602 3.087e+004
41 15__Main Tower 309.9 1603 3.087e+004
42 16__Main Tower 309.9 1603 3.087e+004
43 17__Main Tower 309.9 1604 3.087e+004
44 18__Main Tower 310.0 1605 3.087e+004
45 19__Main Tower 310.0 1607 3.087e+004
46 20__Main Tower 380.0 * 2948 3.088e+004
47
EFFICIENCIES
48
49 Stage Efficiencies
50 Stages Overall Oxygen Nitrogen Methanol H2O
51 1__Main Tower 1.000 1.000 1.000 1.000 1.000
52 2__Main Tower 1.000 1.000 1.000 1.000 1.000
53 3__Main Tower 1.000 1.000 1.000 1.000 1.000
54 4__Main Tower 1.000 1.000 1.000 1.000 1.000
55 5__Main Tower 1.000 1.000 1.000 1.000 1.000
56 6__Main Tower 1.000 1.000 1.000 1.000 1.000
57 7__Main Tower 1.000 1.000 1.000 1.000 1.000
58 8__Main Tower 1.000 1.000 1.000 1.000 1.000
59 9__Main Tower 1.000 1.000 1.000 1.000 1.000
60 10__Main Tower 1.000 1.000 1.000 1.000 1.000
61 11__Main Tower 1.000 1.000 1.000 1.000 1.000
62 12__Main Tower 1.000 1.000 1.000 1.000 1.000
1
4 USA
5
6
8
9 Stage Efficiencies
10 Stages Overall Oxygen Nitrogen Methanol H2O
11 13__Main Tower 1.000 1.000 1.000 1.000 1.000
12 14__Main Tower 1.000 1.000 1.000 1.000 1.000
13 15__Main Tower 1.000 1.000 1.000 1.000 1.000
14 16__Main Tower 1.000 1.000 1.000 1.000 1.000
15 17__Main Tower 1.000 1.000 1.000 1.000 1.000
16 18__Main Tower 1.000 1.000 1.000 1.000 1.000
17 19__Main Tower 1.000 1.000 1.000 1.000 1.000
18 20__Main Tower 1.000 1.000 1.000 1.000 1.000
19 Stages Overall Formaldehyde CO CO2
20 1__Main Tower 1.000 1.000 1.000 1.000
21 2__Main Tower 1.000 1.000 1.000 1.000
22 3__Main Tower 1.000 1.000 1.000 1.000
23 4__Main Tower 1.000 1.000 1.000 1.000
24 5__Main Tower 1.000 1.000 1.000 1.000
25 6__Main Tower 1.000 1.000 1.000 1.000
26 7__Main Tower 1.000 1.000 1.000 1.000
27 8__Main Tower 1.000 1.000 1.000 1.000
28 9__Main Tower 1.000 1.000 1.000 1.000
29 10__Main Tower 1.000 1.000 1.000 1.000
30 11__Main Tower 1.000 1.000 1.000 1.000
31 12__Main Tower 1.000 1.000 1.000 1.000
32 13__Main Tower 1.000 1.000 1.000 1.000
33 14__Main Tower 1.000 1.000 1.000 1.000
34 15__Main Tower 1.000 1.000 1.000 1.000
35 16__Main Tower 1.000 1.000 1.000 1.000
36 17__Main Tower 1.000 1.000 1.000 1.000
37 18__Main Tower 1.000 1.000 1.000 1.000
38 19__Main Tower 1.000 1.000 1.000 1.000
39 20__Main Tower 1.000 1.000 1.000 1.000
40
SOLVER
41
42 Column Solving Algorithm: HYSIM Inside-Out
43 Solving Options Acceleration Parameters
44 Maximum Iterations: 10000 Accelerate K Value & H Model Parameters: Off
45 Equilibrium Error Tolerance: 1.000e-05
46 Heat/Spec Error Tolerance: 5.000e-004
47 Save Solutions as Initial Estimate: On
48 Super Critical Handling Model: Simple K
49 Trace Level: Low
50 Init from Ideal K's: Off Damping Parameters
51 Initial Estimate Generator Parameters Azeotrope Check: Off
52 Iterative IEG (Good for Chemicals): Off Fixed Damping Factor: 1
53
54
55
CONDITIONS
56
57 Name S-M C-09 C-13 Gas de Recyclo
58 Vapour 0.0000 0.9584 0.0000 1.0000
59 Temperature (K) 301.5709 310.0000 * 309.9881 309.5569
60 Pressure (atm) 2.5000 2.5000 2.5000 2.5000
62 Mass Flow (tonne/h) 31.1338 909.7322 58.2889 882.5772
1
4 USA
5
6
8
9
CONDITIONS
10
15
PROPERTIES
16
19 Molar Density (kgmole/m3) 47.60 0.1027 46.68 9.857e-002
20 Mass Density (kg/m3) 935.0 2.900 923.0 2.820
21 Act. Volume Flow (m3/h) 33.30 3.137e+005 63.15 3.130e+005
22 Mass Enthalpy (kJ/kg) -1.347e+004 -780.2 -1.327e+004 -402.8
26 LHV Molar Basis (Std) (kJ/kgmole) 7.045e+004 9873 7.596e+004 6670
27 HHV Molar Basis (Std) (kJ/kgmole) 1.115e+005 1.274e+004 1.170e+005 7849
29 CO2 Loading --- --- --- ---
30 CO2 Apparent Mole Conc. (kgmole/m3) 1.096e-003 --- 1.157e-003 ---
31 CO2 Apparent Wt. Conc. (kgmol/kg) 1.172e-006 --- 1.254e-006 ---
32 LHV Mass Basis (Std) (kJ/kg) 3586 349.6 3842 233.2
36 Mass Exergy (kJ/kg) 92.46 80.72 39.18 79.53
37 Partial Pressure of CO2 (atm) 0.0000 2.914e-002 0.0000 2.916e-002
39 Act. Gas Flow (ACT_m3/h) --- 3.137e+005 --- 3.130e+005
44 Act. Liq. Flow (m3/s) 9.249e-003 7.996e-003 1.754e-002 ---
45 Z Factor 2.123e-003 --- 2.106e-003 0.9985
46 Watson K 10.21 6.242 10.21 6.209
47 User Property --- --- --- ---
49 Cp/(Cp - R) 1.120 1.357 1.120 1.390
50 Cp/Cv 1.186 1.343 1.191 1.398
51 Ideal Gas Cp/Cv 1.326 1.390 1.325 1.393
55 Kinematic Viscosity (cSt) 0.6468 --- 0.5554 6.690
56 Liq. Mass Density (Std. Cond) (kg/m3) 946.2 --- 941.4 ---
57 Liq. Vol. Flow (Std. Cond) (m3/h) 32.90 --- 61.92 ---
58 Liquid Fraction 1.000 4.158e-002 1.000 0.0000
59 Molar Volume (m3/kgmole) 2.101e-002 9.738 2.142e-002 10.14
62 Surface Tension (dyne/cm) 64.60 62.40 62.54 ---
1
4 USA
5
6
8
9
PROPERTIES
10
12 Thermal Conductivity (W/m-K) 0.5319 --- 0.5322 2.644e-002
13 Bubble Point Pressure (atm) 2.231 --- 2.461 ---
14 Viscosity (cP) 0.6047 --- 0.5126 1.886e-002
17 Cv (kJ/kgmole-C) 65.27 23.54 65.33 21.18
18 Mass Cv (kJ/kg-C) 3.323 0.8337 3.304 0.7403
21 Cp/Cv (Ent. Method) --- --- --- ---
22 Reid VP at 37.8 C (atm) 0.1619 --- 0.1617 ---
23 True VP at 37.8 C (atm) 2.433 --- 2.480 ---
25 Viscosity Index -3.503 --- -6.327 ---
26
SUMMARY
27
28 Flow Basis: Molar The composition option is selected
29 Feed Composition
30 S-M C-09
31 Flow Rate (kgmole/h) 1.584860e+03 3.221741e+04
32 --- ---
33 Oxygen 0.0000 0.1444
34 Nitrogen 0.0000 0.7648
35 Methanol 0.0010 0.0014
36 H2O 0.8645 0.0559
37 Formaldehyde 0.1344 0.0112
38 CO 0.0000 0.0112
39 CO2 0.0000 0.0112
41 Feed Flows
42 S-M C-09
44 --- ---
45 Oxygen (kgmole/h) 0.0204 4.653523e+03
46 Nitrogen (kgmole/h) 0.0688 2.463835e+04
47 Methanol (kgmole/h) 1.5528 45.8185
48 H2O (kgmole/h) 1.370145e+03 1.799825e+03
49 Formaldehyde (kgmole/h) 213.0349 359.9650
50 CO (kgmole/h) 0.0012 359.9650
51 CO2 (kgmole/h) 0.0365 359.9650
52 Products
54 Product Compositions
55 Gas de Recyclo C-13
57 --- ---
58 Oxygen 0.1508 0.0000
59 Nitrogen 0.7985 0.0000
60 Methanol 0.0014 0.0010
61 H2O 0.0211 0.8539
62 Formaldehyde 0.0047 0.1449
1
4 USA
5
6
8
9
SUMMARY
10
12 CO 0.0117 0.0000
13 CO2 0.0117 0.0000
15 Product Flows
17 Flow Rate (kgmole/h) 3.085422e+04 * 2.948056e+03 *
18 --- ---
19 Oxygen (kgmole/h) 4.653502e+03 * 0.0409 *
20 Nitrogen (kgmole/h) 2.463828e+04 * 0.1378 *
21 Methanol (kgmole/h) 44.2864 * 3.0850 *
22 H2O (kgmole/h) 652.5560 * 2.517414e+03 *
23 Formaldehyde (kgmole/h) 145.6978 * 427.3021 *
24 CO (kgmole/h) 359.9638 * 0.0025 *
25 CO2 (kgmole/h) 359.9284 * 0.0731 *
27 Product Recoveries
30 --- ---
31 Oxygen (%) 99.9991 0.0009
32 Nitrogen (%) 99.9994 0.0006
33 Methanol (%) 93.4877 6.5123
34 H2O (%) 20.5856 79.4144
35 Formaldehyde (%) 25.4272 74.5728
36 CO (%) 99.9993 0.0007
37 CO2 (%) 99.9797 0.0203
38
COLUMN PROFILES
39
40 Reflux Ratio: 5.190e-002 Reboil Ratio: --- The Flows Option is Selected Flow Basis: Molar
41 Column Profiles Flows
42 Temp Pres Net Liq Net Vap Net Feed Net Draws Duty
43 (K) (atm) (kgmole/h) (kgmole/h) (kgmole/h) (kgmole/h) (kJ/h)
44 1__Main Tower 309.6 2.500 1601 --- 1585 3.085e+004 ---
45 2__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
46 3__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
47 4__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
48 5__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
49 6__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
50 7__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
51 8__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
52 9__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
53 10__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
54 11__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
55 12__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
56 13__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
57 14__Main Tower 309.9 2.500 1602 3.087e+004 --- --- ---
58 15__Main Tower 309.9 2.500 1603 3.087e+004 --- --- ---
59 16__Main Tower 309.9 2.500 1603 3.087e+004 --- --- ---
60 17__Main Tower 309.9 2.500 1604 3.087e+004 --- --- ---
61 18__Main Tower 310.0 2.500 1605 3.087e+004 --- --- ---
62 19__Main Tower 310.0 2.500 1607 3.087e+004 --- --- ---
1
4 USA
5
6
8
9
COLUMN PROFILES
10
11 Temp Pres Net Liq Net Vap Net Feed Net Draws Duty
12 (K) (atm) (kgmole/h) (kgmole/h) (kgmole/h) (kgmole/h) (kJ/h)
13 20__Main Tower 310.0 2.500 --- 3.088e+004 3.222e+004 2948 ---
14 Column Profiles Energy
15 Temperature Liq Enthalpy Vap Enthalpy Heat Loss
16 (K) (kJ/kgmole) (kJ/kgmole) (kJ/h)
17 1__Main Tower 309.6 -2.640e+005 -1.152e+004 ---
18 2__Main Tower 309.9 -2.640e+005 -1.162e+004 ---
19 3__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
20 4__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
21 5__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
22 6__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
23 7__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
24 8__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
25 9__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
26 10__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
27 11__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
28 12__Main Tower 309.9 -2.640e+005 -1.163e+004 ---
29 13__Main Tower 309.9 -2.639e+005 -1.163e+004 ---
30 14__Main Tower 309.9 -2.639e+005 -1.163e+004 ---
31 15__Main Tower 309.9 -2.639e+005 -1.163e+004 ---
32 16__Main Tower 309.9 -2.638e+005 -1.162e+004 ---
33 17__Main Tower 309.9 -2.636e+005 -1.162e+004 ---
34 18__Main Tower 310.0 -2.634e+005 -1.162e+004 ---
35 19__Main Tower 310.0 -2.630e+005 -1.162e+004 ---
36 20__Main Tower 310.0 -2.625e+005 -1.162e+004 ---
37
FEEDS / PRODUCTS
38
39 Flow Basis: Molar
40 Stream Type Duty State Flows Enthalpy Temp
41 (kcal/h) (kgmole/h) (kcal/kgmole) (C)
42 S-M Feed --- Liquid 1.58e+003 * -2.6e+005 * 301.57
*
1__Main Tower
43 Gas de Recyclo Draw --- Vapour 3.09e+004 * -1.2e+004 * 309.56
*
44 2__Main Tower
45 3__Main Tower
46 4__Main Tower
47 5__Main Tower
48 6__Main Tower
49 7__Main Tower
50 8__Main Tower
51 9__Main Tower
52 10__Main Tower
53 11__Main Tower
54 12__Main Tower
55 13__Main Tower
56 14__Main Tower
57 15__Main Tower
58 16__Main Tower
59 17__Main Tower
60 18__Main Tower
61 19__Main Tower
62 20__Main Tower C-09 Feed --- Mixed 3.22e+004 * -2.2e+004 * 310.00
*
1
4 USA
5
6
8
9
FEEDS / PRODUCTS
10
11 20__Main Tower C-13 Draw --- Liquid 2.95e+003 * -2.6e+005 * 309.99
*
12
DYNAMICS
13
14
Vessel Dynamic Specifications
15
16 Vessel
17 Diameter (m)
18 Height.0 (m)
19 Volume.0 (m3)
20 Liquid Volume Percent (%)
21 Level Calculator
22 Fraction Calculator
23 Vessel Delta P (kPa)
24 Fixed Vessel P Spec (atm)
25 Fixed P Spec Active
26
Other Equipment in Column Flowsheet
27
28
29
Holdup Details
30
31 Pressure Volume Bulk Liquid Volume
32 (atm) (m3) (m3)
33 1__Main Tower 0.0000 0.0000 * 0.0000
34 2__Main Tower 0.0000 0.0000 * 0.0000
35 3__Main Tower 0.0000 0.0000 * 0.0000
36 4__Main Tower 0.0000 0.0000 * 0.0000
37 5__Main Tower 0.0000 0.0000 * 0.0000
38 6__Main Tower 0.0000 0.0000 * 0.0000
39 7__Main Tower 0.0000 0.0000 * 0.0000
40 8__Main Tower 0.0000 0.0000 * 0.0000
41 9__Main Tower 0.0000 0.0000 * 0.0000
42 10__Main Tower 0.0000 0.0000 * 0.0000
43 11__Main Tower 0.0000 0.0000 * 0.0000
44 12__Main Tower 0.0000 0.0000 * 0.0000
45 13__Main Tower 0.0000 0.0000 * 0.0000
46 14__Main Tower 0.0000 0.0000 * 0.0000
47 15__Main Tower 0.0000 0.0000 * 0.0000
48 16__Main Tower 0.0000 0.0000 * 0.0000
49 17__Main Tower 0.0000 0.0000 * 0.0000
50 18__Main Tower 0.0000 0.0000 * 0.0000
51 19__Main Tower 0.0000 0.0000 * 0.0000
52 20__Main Tower 0.0000 0.0000 * 0.0000
53
COLUMN REFINERY ASSAY PLOTS
54
55 Single Tray : Single Tray :
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
COLUMN REFINERY ASSAY PLOTS
Boiling Point Properties Molecular Weight Properties

10
11
12
13 10.00 10.00
14
15
16 8.00 8.00
17
18
Molecular Weight
19
Temperature
6.00 6.00
20
21
22
23 4.00 4.00
24
25
26 2.00 2.00
27
28
29
0.00 0.00
30
0.00 2.00 4.00 6.00 8.00 10.00 0.00 2.00 4.00 6.00 8.00 10.00
31
32 Percent Composition Percent Composition
33
Density Properties
34 Single Tray :
35
36
37 10.00
38
39
40 8.00
41
42
43
6.00
44
Density
45
46
47 4.00
48
49
50 2.00
51
52
53
0.00
54
0.00 2.00 4.00 6.00 8.00 10.00
55
56 Percent Composition
57
58
COLUMN REFINERY ASSAY TABLES
59
60
Boiling Point Assay
61
62 Single Tray : Assay Basis : Molar
1
4 USA
5
6
8
9
10
11
Boiling Point Assay
12
13 Assay Percent
14
15 0.0 %
16 1.0 %
17 2.0 %
18 3.5 %
19 5.0 %
20 7.5 %
21 10.0 %
22 12.5 %
23 15.0 %
24 17.5 %
25 20.0 %
26 25.0 %
27 30.0 %
28 35.0 %
29 40.0 %
30 45.0 %
31 50.0 %
32 55.0 %
33 60.0 %
34 65.0 %
35 70.0 %
36 75.0 %
37 80.0 %
38 85.0 %
39 90.0 %
40 92.5 %
41 95.0 %
42 96.5 %
43 98.0 %
44 99.0 %
45 100.0 %
46
Molecular Weight Assay
47
49 Assay Percent
50
51 0.0 %
52 1.0 %
53 2.0 %
54 3.5 %
55 5.0 %
56 7.5 %
57 10.0 %
58 12.5 %
59 15.0 %
60 17.5 %
61 20.0 %
62 25.0 %
1
4 USA
5
6
8
9
10
11
Molecular Weight Assay
12
13 Assay Percent
14
15 30.0 %
16 35.0 %
17 40.0 %
18 45.0 %
19 50.0 %
20 55.0 %
21 60.0 %
22 65.0 %
23 70.0 %
24 75.0 %
25 80.0 %
26 85.0 %
27 90.0 %
28 92.5 %
29 95.0 %
30 96.5 %
31 98.0 %
32 99.0 %
33 100.0 %
34
Density Assay
35
37 Assay Percent
38
39 0.0 %
40 1.0 %
41 2.0 %
42 3.5 %
43 5.0 %
44 7.5 %
45 10.0 %
46 12.5 %
47 15.0 %
48 17.5 %
49 20.0 %
50 25.0 %
51 30.0 %
52 35.0 %
53 40.0 %
54 45.0 %
55 50.0 %
56 55.0 %
57 60.0 %
58 65.0 %
59 70.0 %
60 75.0 %
61 80.0 %
62 85.0 %
1
4 USA
5
6
8
9
10
11
Density Assay
12
13 Assay Percent
14
15 90.0 %
16 92.5 %
17 95.0 %
18 96.5 %
19 98.0 %
20 99.0 %
21 100.0 %
22
User Properties
23
24 Assay Percent
25
26 0.0 %
27 1.0 %
28 2.0 %
29 3.5 %
30 5.0 %
31 7.5 %
32 10.0 %
33 12.5 %
34 15.0 %
35 17.5 %
36 20.0 %
37 25.0 %
38 30.0 %
39 35.0 %
40 40.0 %
41 45.0 %
42 50.0 %
43 55.0 %
44 60.0 %
45 65.0 %
46 70.0 %
47 75.0 %
48 80.0 %
49 85.0 %
50 90.0 %
51 92.5 %
52 95.0 %
53 96.5 %
54 98.0 %
55 99.0 %
56 100.0 %
57
58
59
60
61
62
1
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5
6
8
9
TRAY by TRAY PROPERTIES PLOTS
Temperature vs. Tray Position from Top

10
11
12
13 310
14
310
15
16
310
17
18
310
Temperature (K)
19
20 310
21
22 310
23
24 310
25
26 310
27
28 310
29
310
30
0 2 4 6 8 10 12 14 16 18 20
31
32
Pressure vs. Tray Position from Top

33
34
35
36 7.00
37
6.00
38
39 5.00
40
41 4.00
42
Pressure (atm)
3.00
43
44 2.00
45
46 1.00
47
0.000
48
49 -1.00
50
51 -2.00
52
-3.00
53
0 2 4 6 8 10 12 14 16 18 20
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
Flow vs. Tray Position from Top

10
11
12
13 3.50e+004
Vapour
14
Liquid
15 3.00e+004
16
Net Molar Flow (kgmole/h)
17
2.50e+004
18
19
20 2.00e+004
21
22
1.50e+004
23
24
25 1.00e+004
26
27 5.00e+003
28
29
0.000
30
0 2 4 6 8 10 12 14 16 18 20
31
32
Column Properties vs. Tray Position from Top

33
34
35
36 929 19.8
Density(Light)
37
Mol Weight(Light)
38 928 19.8
39
40
927 19.7
41
Density (kg/m3)
42
43 926 19.7
44
45
925 19.7
46
47
48 924 19.7
49
50 923 19.7
51
52
922 19.6
53
0 2 4 6 8 10 12 14 16 18 20
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
Composition vs. Tray Position from Top

10
11
12
13 0.900
Oxygen (Light)
14
0.800 Nitrogen (Light)
15
Methanol (Light)
16
0.700 H2O (Light)
17
18
0.600
19
Mole Fraction
20 0.500
21
22 0.400
23
24 0.300
25
26 0.200
27
28 1.00e-001
29
0.000
30
0 2 4 6 8 10 12 14 16 18 20
31
32
K-Value vs. Tray Position from Top

33
34
35
36 2.00e+004
Oxygen
37
1.80e+004 Nitrogen
38
Methanol
39 1.60e+004
H2O
40
41 1.40e+004
42
1.20e+004
43
K Value
44 1.00e+004
45
46 8.00e+003
47
6.00e+003
48
49 4.00e+003
50
51 2.00e+003
52
0.000
53
0 2 4 6 8 10 12 14 16 18 20
54
55
56
57
58
59
60
61
62
1
4 USA
5
6
8
9
Component Ratio vs. Tray Position from Top

10
11
12
13 6.50
Light
14
15 6.40
16
17
6.30
18
Mole Fraction Ratio
19
20 6.20
21
22
6.10
23
24
25 6.00
26
27 5.90
28
29
5.80
30
0 2 4 6 8 10 12 14 16 18 20
31
32
33
34
TRAY by TRAY PROPERTIES TABLES
35
36
Column Temperature / Pressure Profile
37
38 Column Stage Temperature Pressure
39 (K) (atm)
40 1__Main Tower 309.6 2.500
41 2__Main Tower 309.9 2.500
42 3__Main Tower 309.9 2.500
43 4__Main Tower 309.9 2.500
44 5__Main Tower 309.9 2.500
45 6__Main Tower 309.9 2.500
46 7__Main Tower 309.9 2.500
47 8__Main Tower 309.9 2.500
48 9__Main Tower 309.9 2.500
49 10__Main Tower 309.9 2.500
50 11__Main Tower 309.9 2.500
51 12__Main Tower 309.9 2.500
52 13__Main Tower 309.9 2.500
53 14__Main Tower 309.9 2.500
54 15__Main Tower 309.9 2.500
55 16__Main Tower 309.9 2.500
56 17__Main Tower 309.9 2.500
57 18__Main Tower 310.0 2.500
58 19__Main Tower 310.0 2.500
59 20__Main Tower 310.0 2.500
60
Column Flow Profile
61
62 Options Selected
1
4 USA
5
6
8
9
10
11
Column Flow Profile
12
13 Molar flow is selected Net is selected as flow basis
14 Tray Number Vapour Bulk Liquid
15 (kgmole/h) (kgmole/h)
16 1__Main Tower 3.085e+004 1601
17 2__Main Tower 3.087e+004 1602
18 3__Main Tower 3.087e+004 1602
19 4__Main Tower 3.087e+004 1602
20 5__Main Tower 3.087e+004 1602
21 6__Main Tower 3.087e+004 1602
22 7__Main Tower 3.087e+004 1602
23 8__Main Tower 3.087e+004 1602
24 9__Main Tower 3.087e+004 1602
25 10__Main Tower 3.087e+004 1602
26 11__Main Tower 3.087e+004 1602
27 12__Main Tower 3.087e+004 1602
28 13__Main Tower 3.087e+004 1602
29 14__Main Tower 3.087e+004 1602
30 15__Main Tower 3.087e+004 1603
31 16__Main Tower 3.087e+004 1603
32 17__Main Tower 3.087e+004 1604
33 18__Main Tower 3.087e+004 1605
34 19__Main Tower 3.087e+004 1607
35 20__Main Tower 3.088e+004 2948
36
Column Properties Profile
37
38 Options Selected
39 Mass basis is selected
40 Stage Surf Tens Mol Wt Dens Visc Therm Con Heat Cap
41 L-Liq L-Liq L-Liq L-Liq L-Liq
42 (dyne/cm) (kg/m3) (cP) (W/m-K) (kJ/kg-C)
43 1__Main Tower 63.1 19.6 928 0.529 0.538 3.96

44 2__Main Tower 63.1 19.6 928 0.526 0.539 3.96
45 3__Main Tower 63.1 19.6 928 0.526 0.539 3.96
46 4__Main Tower 63.1 19.6 928 0.526 0.539 3.96
47 5__Main Tower 63.1 19.6 928 0.526 0.539 3.96
48 6__Main Tower 63.1 19.6 928 0.526 0.539 3.96
49 7__Main Tower 63.1 19.6 928 0.526 0.539 3.96
50 8__Main Tower 63.1 19.6 928 0.526 0.539 3.96
51 9__Main Tower 63.1 19.6 928 0.525 0.539 3.96
52 10__Main Tower 63.1 19.6 928 0.525 0.538 3.96
53 11__Main Tower 63.1 19.7 928 0.525 0.538 3.96
54 12__Main Tower 63.1 19.7 928 0.525 0.538 3.96
55 13__Main Tower 63.1 19.7 928 0.525 0.538 3.95
56 14__Main Tower 63.0 19.7 928 0.525 0.538 3.95
57 15__Main Tower 63.0 19.7 927 0.524 0.538 3.95
58 16__Main Tower 63.0 19.7 927 0.524 0.538 3.95
59 17__Main Tower 63.0 19.7 927 0.522 0.537 3.95
60 18__Main Tower 62.9 19.7 926 0.521 0.536 3.95
61 19__Main Tower 62.7 19.7 925 0.517 0.535 3.94
62 20__Main Tower 62.5 19.8 923 0.513 0.532 3.94
1
4 USA
5
6
8
9
10
11
12
13
Column Composition Profile
14
15 Options Selected
16 Fraction is selected as the composition basis Net is selected as flow basis
17 Molar basis is selected
18 Stage Oxygen Nitrogen Methanol H2O
19 L-Liq L-Liq L-Liq L-Liq
20 1__Main Tower 0.0000 0.0000 0.0012 0.8642
21 2__Main Tower 0.0000 0.0000 0.0012 0.8642
22 3__Main Tower 0.0000 0.0000 0.0012 0.8642
23 4__Main Tower 0.0000 0.0000 0.0012 0.8642
24 5__Main Tower 0.0000 0.0000 0.0012 0.8642
25 6__Main Tower 0.0000 0.0000 0.0012 0.8642
26 7__Main Tower 0.0000 0.0000 0.0012 0.8642
27 8__Main Tower 0.0000 0.0000 0.0012 0.8642
28 9__Main Tower 0.0000 0.0000 0.0012 0.8642
29 10__Main Tower 0.0000 0.0000 0.0012 0.8641
30 11__Main Tower 0.0000 0.0000 0.0012 0.8641
31 12__Main Tower 0.0000 0.0000 0.0012 0.8640
32 13__Main Tower 0.0000 0.0000 0.0012 0.8638
33 14__Main Tower 0.0000 0.0000 0.0012 0.8636
34 15__Main Tower 0.0000 0.0000 0.0012 0.8632
35 16__Main Tower 0.0000 0.0000 0.0012 0.8626
36 17__Main Tower 0.0000 0.0000 0.0012 0.8617
37 18__Main Tower 0.0000 0.0000 0.0012 0.8602
38 19__Main Tower 0.0000 0.0000 0.0011 0.8578
39 20__Main Tower 0.0000 0.0000 0.0010 0.8539
40
Heavy/Light Key Component Ratios
41
42 Options Selected
43 Molar basis is selected
44
Key Components
45
46 Light Key Chosen Heavy Key Chosen
47 Oxygen On Oxygen Off
48 Nitrogen On Nitrogen Off
49 Methanol On Methanol Off
50 H2O On H2O Off
51 Formaldehyde Off Formaldehyde On
52 CO Off CO On
53 CO2 Off CO2 Off
54 Stage Light Liq
55 1__Main Tower 6.436
1
4 USA
5
6
8
9
10
11
Heavy/Light Key Component Ratios
12
13 Stage Light Liq
15 10__Main Tower 6.431
16 11__Main Tower 6.428
17 12__Main Tower 6.423
18 13__Main Tower 6.415
19 14__Main Tower 6.402
20 15__Main Tower 6.381
21 16__Main Tower 6.349
22 17__Main Tower 6.298
23 18__Main Tower 6.217
24 19__Main Tower 6.092
25 20__Main Tower 5.899
26
Column K-Values Profile
27
28 Tray Number Oxygen Nitrogen Methanol H2O
29 1__Main Tower 1.132e+004 1.806e+004 1.165 2.447e-002
30 2__Main Tower 1.135e+004 1.810e+004 1.175 2.497e-002
31 3__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
32 4__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
33 5__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
34 6__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
35 7__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
36 8__Main Tower 1.135e+004 1.810e+004 1.176 2.500e-002
37 9__Main Tower 1.135e+004 1.810e+004 1.177 2.500e-002
38 10__Main Tower 1.135e+004 1.809e+004 1.177 2.500e-002
39 11__Main Tower 1.135e+004 1.809e+004 1.178 2.500e-002
40 12__Main Tower 1.134e+004 1.808e+004 1.180 2.500e-002
41 13__Main Tower 1.134e+004 1.806e+004 1.183 2.499e-002
42 14__Main Tower 1.132e+004 1.804e+004 1.187 2.499e-002
43 15__Main Tower 1.131e+004 1.800e+004 1.193 2.500e-002
44 16__Main Tower 1.128e+004 1.794e+004 1.204 2.500e-002
45 17__Main Tower 1.123e+004 1.784e+004 1.221 2.501e-002
46 18__Main Tower 1.116e+004 1.769e+004 1.250 2.502e-002
47 19__Main Tower 1.105e+004 1.745e+004 1.297 2.504e-002
48 20__Main Tower 1.087e+004 1.708e+004 1.378 2.507e-002
Heat Exchanger: IC-04

49
50
51
52
53
CONNECTIONS
54
55
57 Name Agua R Name SE10 Name C-13 Name C-18
58 From Op. To Op. From Op. T-100 To Op. TEE-100
59 Op. Type Op. Type Op. Type Absorber Op. Type Tee
60 Temp 298.00 K * Temp 309.00 K * Temp 309.99 K Temp 298.00 K *
61
62
PARAMETERS
1
4 USA
5
6
8
9
10
11 Tube Side DeltaP: 0.0000 kPa * Shell Side DeltaP: 0.0000 kPa * Passes: ---
15 Tube Pressure Drop 0.00 kPa * Shell Pressure Drop 0.00 kPa *
26
27
SPECS
29 E-101 Heat Balance 0.0000 kJ/h 5.729e-005 kJ/h 2.087e-011 On Off
30 E-101 UA --- 3.251e+007 kJ/C-h --- On Off
31
32
35 E-101 UA
37
38
User Variables
39
40
CONDITIONS
41 Name Agua R C-13 SE10 C-18
42 Vapour 0.0000 0.0000 0.0000 0.0000
43 Temperature (K) 298.0000 * 309.9881 309.0000 * 298.0000 *
44 Pressure (atm) 1.2000 * 2.5000 1.2000 2.5000
46 Mass Flow (tonne/h) 59.0032 58.2889 59.0032 58.2889
51
52
PROPERTIES
55 Molar Density (kgmole/m3) 55.92 46.68 55.46 47.20
56 Mass Density (kg/m3) 1007 923.0 999.1 933.2
57 Act. Volume Flow (m3/h) 58.57 63.15 59.05 62.46
58 Mass Enthalpy (kJ/kg) -1.582e+004 -1.327e+004 -1.577e+004 -1.332e+004
62 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 7.596e+004 0.0000 7.596e+004
1
4 USA
5
6
8
9
10
PROPERTIES
13 HHV Mass Basis (Std) (kJ/kg) 2276 5918 2276 5918
14 CO2 Loading --- --- --- ---
15 CO2 Apparent Mole Conc. (kgmole/m3) 0.0000 1.157e-003 0.0000 1.170e-003
16 CO2 Apparent Wt. Conc. (kgmol/kg) 0.0000 1.254e-006 0.0000 1.254e-006
17 LHV Mass Basis (Std) (kJ/kg) 0.0000 3842 0.0000 3842
21 Mass Exergy (kJ/kg) 25.86 39.18 -57.84 115.7
22 Partial Pressure of CO2 (atm) 0.0000 0.0000 0.0000 0.0000
24 Act. Gas Flow (ACT_m3/h) --- --- --- ---
29 Act. Liq. Flow (m3/s) 1.627e-002 1.754e-002 1.640e-002 1.735e-002
30 Z Factor 8.775e-004 2.106e-003 8.533e-004 2.166e-003
31 Watson K --- 10.21 --- 10.21
32 User Property --- --- --- ---
34 Cp/(Cp - R) 1.123 1.120 1.123 1.121
35 Cp/Cv 1.151 1.191 1.157 1.187
36 Ideal Gas Cp/Cv 1.329 1.325 1.328 1.326
40 Kinematic Viscosity (cSt) 0.8869 0.5554 0.7069 0.6719
41 Liq. Mass Density (Std. Cond) (kg/m3) 1015 941.4 1015 941.4
42 Liq. Vol. Flow (Std. Cond) (m3/h) 58.14 61.92 58.14 61.92
43 Liquid Fraction 1.000 1.000 1.000 1.000
44 Molar Volume (m3/kgmole) 1.788e-002 2.142e-002 1.803e-002 2.119e-002
45 Mass Heat of Vap. (kJ/kg) 2200 2142 2200 2142
47 Surface Tension (dyne/cm) 72.13 62.54 70.22 64.70
48 Thermal Conductivity (W/m-K) 0.6108 0.5322 0.6262 0.5227
49 Bubble Point Pressure (atm) 3.100e-002 2.461 5.822e-002 2.196
50 Viscosity (cP) 0.8935 0.5126 0.7063 0.6270
53 Cv (kJ/kgmole-C) 65.74 65.33 65.82 64.92
54 Mass Cv (kJ/kg-C) 3.649 3.304 3.654 3.283
57 Cp/Cv (Ent. Method) --- --- --- ---
58 Reid VP at 37.8 C (atm) --- 0.1617 --- 0.1617
59 True VP at 37.8 C (atm) --- 2.480 --- 2.480
61 Viscosity Index 1.550 -6.327 -1.982 -2.841
62 DETAILS
1
4 USA
5
6
8
9 DETAILS
10
11
16 Min. Approach: 0.0000 C Uncorrected Lmtd: ---
17 Lmtd: 8.443e-002 C
18
19
TABLES
20
21
24 298.00 2.50 0.00 -263387.63
25 309.99 2.50 2744801.19 -262456.58
28 0.00 0.0000 0.0000 ---
29 0.00 0.0000 0.0000 ---
30
31
34 --- --- --- --- --- ---
35 --- --- --- --- --- ---
37 (STD_m3/h) (atm) (K)
38 --- --- --- --- --- ---
39 --- --- --- --- --- ---
40
41
44 --- --- --- --- --- ---
45 --- --- --- --- --- ---
47 (atm) (K)
48 --- --- --- --- --- ---
49 --- --- --- --- --- ---
50
51
54 58.29 933.20 3.90 0.63 0.52 64.70
55 58.29 922.95 3.94 0.51 0.53 62.54
57 (atm) (K)
58 19.77 0.93 195.93 612.29 0.26 0.33
59 19.77 0.92 195.93 612.29 0.26 0.33
60
61
62
1
4 USA
5
6
8
9
10
13 58.29 933.20 3.90 0.63 0.52 ---
14 58.29 922.95 3.94 0.51 0.53 ---
16 (atm) (K)
17 19.77 0.93 195.93 612.29 0.26 0.33
18 19.77 0.92 195.93 612.29 0.26 0.33
19
20
23 298.00 1.20 0.00 -284913.94
24 309.00 1.20 2744801.19 -284075.89
27 0.00 0.0000 0.0000 ---
28 0.00 0.0000 0.0000 ---
29
30
33 --- --- --- --- --- ---
34 --- --- --- --- --- ---
36 (STD_m3/h) (atm) (K)
37 --- --- --- --- --- ---
38 --- --- --- --- --- ---
39
40
43 --- --- --- --- --- ---
44 --- --- --- --- --- ---
46 (atm) (K)
47 --- --- --- --- --- ---
48 --- --- --- --- --- ---
49
50
53 59.00 1007.46 4.20 0.89 0.61 72.13
54 59.00 999.13 4.23 0.71 0.63 70.22
56 (atm) (K)
57 18.02 1.01 218.31 647.30 0.26 0.34
58 18.02 1.00 218.31 647.30 0.26 0.34
59
60
61
62
1
4 USA
5
6
8
9
10
13 59.00 1007.46 4.20 0.89 0.61 ---
14 59.00 999.13 4.23 0.71 0.63 ---
16 (atm) (K)
17 18.02 1.01 218.31 647.30 0.26 0.34
18 18.02 1.00 218.31 647.30 0.26 0.34
19
20
---
21
22
23 2.6
24
25 2.4 Tube Side
26 Shell Side
2.2
Pressure (atm)
27
28
29 2.0
30
31 1.8
32
33
1.6
34
35
1.4
36
37
1.2
38
39
1.0
40
298.0 300.0 302.0 304.0 306.0 308.0 310.0
Temperature (K)
41
42
43
44
45
DYNAMICS
46
47
Basic Model
48
49
Model Parameters
50 Tube Volume (m3) 0.1000 Shell UA (tonne/h) ---
51 Shell Volume (m3) 0.1000 Tube UA (tonne/h) ---
52 Elevation (m) 0.0000 Minimum Flow Scale Factor 0.0000 *
53 Overall UA (kJ/C-h) 3.251e+007
54
55
Summary
56 Shell Duty: --- Tube Duty: ---
57
58
Pressure Flow Specifications
59
60
Shell Side Specification
1
4 USA
5
6
8
11
12
Holdup
13
14
Shell Holdup
17 Vapour 0.0000 0.0000 0.0000
18 Liquid 0.0000 0.0000 0.0000
19 Aqueous 0.0000 0.0000 0.0000
20 Total 0.0000 0.0000 0.0000
21
22
Tube Holdup
25 Vapour 0.0000 0.0000 0.0000
26 Liquid 0.0000 0.0000 0.0000
27 Aqueous 0.0000 0.0000 0.0000
28 Total 0.0000 0.0000 0.0000
29
30 Tee: TEE-100
31
32
33
CONNECTIONS
34
35
Inlet Stream
38
39
Outlet Stream
41 C-15 Pump B-02
42 C-19 Pump B-03
43
44
PARAMETERS
45 Flow Ratios Dynamic Valve Openings
46 C-15 0.5000 * 50.00
47 C-19 0.5000 * 50.00
48
49 Valve Control: Multiple Stream
50
51
User Variables
52
53
CONDITIONS
54 Name C-18 C-15 C-19
55 Vapour 0.0000 0.0000 0.0000
56 Temperature (K) 298.0000 * 298.0000 298.0000
57 Pressure (atm) 2.5000 2.5000 2.5000
59 Mass Flow (tonne/h) 58.2889 29.1444 29.1444
61 Molar Enthalpy (kJ/kgmole) -2.634e+005 -2.634e+005 -2.634e+005
1
4 USA
5
6
7 Tee: TEE-100 (continued)
8
9
10
CONDITIONS
11 Heat Flow (kJ/h) -7.7648e+08 -3.8824e+08 -3.8824e+08
12
13
PROPERTIES
14 Name C-18 C-15 C-19
16 Molar Density (kgmole/m3) 47.20 47.20 47.20
17 Mass Density (kg/m3) 933.2 933.2 933.2
18 Act. Volume Flow (m3/h) 62.46 31.23 31.23
19 Mass Enthalpy (kJ/kg) -1.332e+004 -1.332e+004 -1.332e+004
23 LHV Molar Basis (Std) (kJ/kgmole) 7.596e+004 7.596e+004 7.596e+004
24 HHV Molar Basis (Std) (kJ/kgmole) 1.170e+005 1.170e+005 1.170e+005
25 HHV Mass Basis (Std) (kJ/kg) 5918 5918 5918
26 CO2 Loading --- --- ---
27 CO2 Apparent Mole Conc. (kgmole/m3) 1.170e-003 1.170e-003 1.170e-003
28 CO2 Apparent Wt. Conc. (kgmol/kg) 1.254e-006 1.254e-006 1.254e-006
29 LHV Mass Basis (Std) (kJ/kg) 3842 3842 3842
33 Mass Exergy (kJ/kg) 115.7 115.7 115.7
36 Act. Gas Flow (ACT_m3/h) --- --- ---
39 Std. Gas Flow (STD_m3/h) 6.971e+004 3.485e+004 3.485e+004
41 Act. Liq. Flow (m3/s) 1.735e-002 8.675e-003 8.675e-003
42 Z Factor 2.166e-003 2.166e-003 2.166e-003
43 Watson K 10.21 10.21 10.21
46 Cp/(Cp - R) 1.121 1.121 1.121
47 Cp/Cv 1.187 1.187 1.187
48 Ideal Gas Cp/Cv 1.326 1.326 1.326
51 Heat of Vap. (kJ/kgmole) 4.235e+004 4.235e+004 4.235e+004
52 Kinematic Viscosity (cSt) 0.6719 0.6719 0.6719
53 Liq. Mass Density (Std. Cond) (kg/m3) 941.4 941.4 941.4
54 Liq. Vol. Flow (Std. Cond) (m3/h) 61.92 30.96 30.96
55 Liquid Fraction 1.000 1.000 1.000
56 Molar Volume (m3/kgmole) 2.119e-002 2.119e-002 2.119e-002
57 Mass Heat of Vap. (kJ/kg) 2142 2142 2142
59 Surface Tension (dyne/cm) 64.70 64.70 64.70
60 Thermal Conductivity (W/m-K) 0.5227 0.5227 0.5227
61 Bubble Point Pressure (atm) 2.196 2.196 2.196
62 Viscosity (cP) 0.6270 0.6270 0.6270
1
4 USA
5
6
7 Tee: TEE-100 (continued)
8
9
10
PROPERTIES
11 Name C-18 C-15 C-19
14 Cv (kJ/kgmole-C) 64.92 64.92 64.92
15 Mass Cv (kJ/kg-C) 3.283 3.283 3.283
18 Cp/Cv (Ent. Method) --- --- ---
19 Reid VP at 37.8 C (atm) 0.1617 0.1617 0.1617
20 True VP at 37.8 C (atm) 2.480 2.480 2.480
22 Viscosity Index -2.841 -2.841 -2.841
23
24
DYNAMICS
25
26
Holdup Details
29 Vapour 0.0000 0.0000 0.0000
30 Liquid 0.0000 0.0000 0.0000
31 Aqueous 0.0000 0.0000 0.0000
32 Total 0.0000 0.0000 0.0000
33
34 Pump: B-02
35
36
37
CONNECTIONS
38
39
Inlet Stream
40 Stream Name From Unit Operation
41 C-15 Tee TEE-100
42
43
Outlet Stream
44 Stream Name To Unit Operation
45 R Recycle RCY-1
46
47
Energy Stream
49 PW-02
50
51
PARAMETERS
52 Adiabatic Efficiency (%): 68.00 * Delta P: 10.13 kPa Duty: 0.1293 kW
53
54
CURVES
55 Delta P: 10.13 kPa Duty: 0.1293 kW
56 Coefficient A: 0.0000 * Coefficient B: 0.0000 * Coefficient C: 0.0000 *
57 Parameter Preferences Units for Delta P: m Flow Basis ActVolFlow Units for Flow: m3/h
58
59
User Variables
60
61
CONDITIONS
62 Name C-15 R PW-02
1
4 USA
5
6
7 Pump: B-02 (continued)
8
9
10
CONDITIONS
11 Vapour 0.0000 0.0000 ---
12 Temperature (K) 298.0000 298.0022 ---
13 Pressure (atm) 2.5000 2.6000 * ---
15 Mass Flow (tonne/h) 29.1444 29.1444 ---
17 Molar Enthalpy (kJ/kgmole) -2.634e+005 -2.634e+005 ---
19 Heat Flow (kJ/h) -3.8824e+08 -3.8824e+08 4.6536e+02
20
21
PROPERTIES
22 Name C-15 R
24 Molar Density (kgmole/m3) 47.20 47.20
26 Act. Volume Flow (m3/h) 31.23 31.23
27 Mass Enthalpy (kJ/kg) -1.332e+004 -1.332e+004
33 HHV Mass Basis (Std) (kJ/kg) 5918 5918
35 CO2 Apparent Mole Conc. (kgmole/m3) 1.170e-003 1.170e-003
36 CO2 Apparent Wt. Conc. (kgmol/kg) 1.254e-006 1.254e-006
37 LHV Mass Basis (Std) (kJ/kg) 3842 3842
44 Act. Gas Flow (ACT_m3/h) --- ---
49 Act. Liq. Flow (m3/s) 8.675e-003 8.675e-003
50 Z Factor 2.166e-003 2.253e-003
51 Watson K 10.21 10.21
54 Cp/(Cp - R) 1.121 1.121
55 Cp/Cv 1.187 1.187
61 Liq. Mass Density (Std. Cond) (kg/m3) 941.4 941.4
62 Liq. Vol. Flow (Std. Cond) (m3/h) 30.96 30.96
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name C-15 R
13 Molar Volume (m3/kgmole) 2.119e-002 2.119e-002
14 Mass Heat of Vap. (kJ/kg) 2142 2124
16 Surface Tension (dyne/cm) 64.70 64.70
17 Thermal Conductivity (W/m-K) 0.5227 0.5227
18 Bubble Point Pressure (atm) 2.196 2.196
19 Viscosity (cP) 0.6270 0.6270
22 Cv (kJ/kgmole-C) 64.92 64.92
23 Mass Cv (kJ/kg-C) 3.283 3.283
27 Reid VP at 37.8 C (atm) 0.1617 0.1617
28 True VP at 37.8 C (atm) 2.480 2.480
30 Viscosity Index -2.841 -2.842
31
32
PERFORMANCE
33
34
Results
35 Total Head --- Velocity Head -4.292e-006 m
36 Total Fluid Head ---
37 Pressure Head 1.107 m Delta P excluding Static Head Results ---
38
39
DYNAMICS
40
41
42 Head (m) --- Not Active Power (kJ/h) 465.4 Not Active
43 Fluid Head (kJ/kg) --- Not Active
Capacity (m3/h) 31.31
44 Adiabatic Efficiency (rpm) --- Not Active
Use Characteristic Curves Not Active
45 Polytropic Efficiency (%) 68.00 * Active
46 Pressure Increase (kPa) 10.13 Active Pump is Acting as a Turbine Not Active
47
48
Holdup Details
51 Vapour 0.0000 0.0000 0.0000
52 Liquid 0.0000 0.0000 0.0000
53 Aqueous 0.0000 0.0000 0.0000
54 Total 0.0000 0.0000 0.0000
55
56 Recycle: RCY-1
57
58
59
CONNECTIONS
60
61
Inlet Stream
1
4 USA
5
6
7 Recycle: RCY-1 (continued)
8
9 R Pump B-02
10
11
Outlet Stream
13 1 Mixer MIX-101
14
15
TOLERANCE
16 Vapour Fraction: 10.00 * Temperature: 10.00 * Pressure: 10.00 *
17 Flow: 10.00 * Enthalpy: 10.00 * Composition: 10.00 *
18
19
NUMERICAL
20 Acceleration Type: Wegstein Iteration Type: Nested
21 Maximum Iterations: 10 * Iteration Count: 0
22 Wegstein Count: 3* Q Minimum: -20.00 * Q Maximum: 0.0000 *
23
24
Iteration History
25 Iteration Variable Outlet Value Inlet Value
26 3 * Converged --- ---
27
28
User Variables
29
30
CONDITIONS
31 Name R 1
32 Vapour 0.0000 0.0000
33 Temperature (K) 298.0022 298.0022 *
34 Pressure (atm) 2.6000 * 2.6000 *
35 Molar Flow (kgmole/h) 1474.0279 1473.8421 *
36 Mass Flow (tonne/h) 29.1444 29.1338
37 Std Ideal Liq Vol Flow (m3/h) 31.3142 31.2976
38 Molar Enthalpy (kJ/kgmole) -2.634e+005 -2.634e+005
39 Molar Entropy (kJ/kgmole-C) 30.00 29.98
40 Heat Flow (kJ/h) -3.8824e+08 -3.8828e+08
41
42
PROPERTIES
43 Name R 1
1
4 USA
5
6
7 Recycle: RCY-1 (continued)
8
9
10
PROPERTIES
11 Name R 1
19 Act. Liq. Flow (m3/s) 8.675e-003 8.670e-003
20 Z Factor 2.253e-003 2.252e-003
21 Watson K 10.21 10.21
24 Cp/(Cp - R) 1.121 1.121
25 Cp/Cv 1.187 1.187
40 Viscosity (cP) 0.6270 0.6276
43 Cv (kJ/kgmole-C) 64.92 64.92
44 Mass Cv (kJ/kg-C) 3.283 3.284
48 Reid VP at 37.8 C (atm) 0.1617 0.1619
49 True VP at 37.8 C (atm) 2.480 2.481
52
53 Mixer: MIX-101
54
55
56
CONNECTIONS
57
58
Inlet Stream
60 C-14
61 1 Recycle RCY-1
62 Outlet Stream
1
4 USA
5
6
8
9
10
CONNECTIONS
11 Outlet Stream
13 S-M Absorber T-100
14
15
PARAMETERS
16
17
User Variables
18
19
CONDITIONS
20 Name C-14 1 S-M
21 Vapour 0.0000 0.0000 0.0000
22 Temperature (K) 350.0000 * 298.0022 * 301.5709
23 Pressure (atm) 2.5000 * 2.6000 * 2.5000
24 Molar Flow (kgmole/h) 111.0180 1473.8421 * 1584.8601
25 Mass Flow (tonne/h) 2.0000 * 29.1338 31.1338
29 Heat Flow (kJ/h) -3.1192e+07 -3.8828e+08 -4.1947e+08
30
31
PROPERTIES
32 Name C-14 1 S-M
34 Molar Density (kgmole/m3) 53.68 47.22 47.60
35 Mass Density (kg/m3) 967.0 933.4 935.0
37 Mass Enthalpy (kJ/kg) -1.560e+004 -1.333e+004 -1.347e+004
41 LHV Molar Basis (Std) (kJ/kgmole) 0.0000 7.575e+004 7.045e+004
43 HHV Mass Basis (Std) (kJ/kg) 2276 5909 5676
44 CO2 Loading --- --- ---
45 CO2 Apparent Mole Conc. (kgmole/m3) 0.0000 1.169e-003 1.096e-003
46 CO2 Apparent Wt. Conc. (kgmol/kg) 0.0000 1.253e-006 1.172e-006
47 LHV Mass Basis (Std) (kJ/kg) 0.0000 3832 3586
51 Mass Exergy (kJ/kg) -204.0 120.7 92.46
54 Act. Gas Flow (ACT_m3/h) --- --- ---
57 Std. Gas Flow (STD_m3/h) 2625 3.485e+004 3.747e+004
59 Act. Liq. Flow (m3/s) 5.745e-004 8.670e-003 9.249e-003
60 Z Factor 1.622e-003 2.252e-003 2.123e-003
61 Watson K --- 10.21 10.21
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name C-14 1 S-M
13 Cp/(Cp - R) 1.124 1.121 1.120
14 Cp/Cv 1.177 1.187 1.186
15 Ideal Gas Cp/Cv 1.325 1.326 1.326
20 Liq. Mass Density (Std. Cond) (kg/m3) 1015 941.6 946.2
22 Liquid Fraction 1.000 1.000 1.000
23 Molar Volume (m3/kgmole) 1.863e-002 2.118e-002 2.101e-002
26 Surface Tension (dyne/cm) 62.91 64.72 64.60
27 Thermal Conductivity (W/m-K) 0.6676 0.5229 0.5319
28 Bubble Point Pressure (atm) 0.4111 2.197 2.231
29 Viscosity (cP) 0.3654 0.6276 0.6047
32 Cv (kJ/kgmole-C) 64.20 64.92 65.27
33 Mass Cv (kJ/kg-C) 3.563 3.284 3.323
36 Cp/Cv (Ent. Method) --- --- ---
37 Reid VP at 37.8 C (atm) --- 0.1619 0.1619
38 True VP at 37.8 C (atm) --- 2.481 2.433
40 Viscosity Index -15.33 -2.829 -3.503
41
42
DYNAMICS
43 Pressure Specification: Set Outlet to Lowest Inlet
44
45
Holdup Details
48 Vapour 0.0000 0.0000 0.0000
49 Liquid 0.0000 0.0000 0.0000
50 Aqueous 0.0000 0.0000 0.0000
51 Total 0.0000 0.0000 0.0000
52
53 Pump: B-03
54
55
56
CONNECTIONS
57
58
Inlet Stream
60 C-19 Tee TEE-100
61
62
Outlet Stream
1
4 USA
5
6
8
10 C-20 Product Blender M-01
11
12
Energy Stream
14 PW-03
15
16
PARAMETERS
18
19
CURVES
23
24
User Variables
25
26
CONDITIONS
27 Name C-19 C-20 PW-03
28 Vapour 0.0000 0.0000 ---
29 Temperature (K) 298.0000 298.0022 ---
30 Pressure (atm) 2.5000 2.6000 * ---
32 Mass Flow (tonne/h) 29.1444 29.1444 ---
36 Heat Flow (kJ/h) -3.8824e+08 -3.8824e+08 4.6536e+02
37
38
PROPERTIES
39 Name C-19 C-20
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name C-19 C-20
15 Act. Liq. Flow (m3/s) 8.675e-003 8.675e-003
16 Z Factor 2.166e-003 2.253e-003
17 Watson K 10.21 10.21
20 Cp/(Cp - R) 1.121 1.121
21 Cp/Cv 1.187 1.187
36 Viscosity (cP) 0.6270 0.6270
39 Cv (kJ/kgmole-C) 64.92 64.92
40 Mass Cv (kJ/kg-C) 3.283 3.283
44 Reid VP at 37.8 C (atm) 0.1617 0.1617
45 True VP at 37.8 C (atm) 2.480 2.480
48
49
PERFORMANCE
50
51
Results
52 Total Head --- Velocity Head -4.292e-006 m
55
56
DYNAMICS
57
58
60
61
62
1
4 USA
5
6
8
Power (kJ/h) 465.4 Not Active
13
14
Holdup Details
17 Vapour 0.0000 0.0000 0.0000
18 Liquid 0.0000 0.0000 0.0000
19 Aqueous 0.0000 0.0000 0.0000
20 Total 0.0000 0.0000 0.0000
21
Material Stream: M-01

Fluid Package: Basis-1
22
23 Property Package: NRTL - PR
24
25
CONDITIONS
26 Overall Liquid Phase
27 Vapour / Phase Fraction 0.0000 1.0000
28 Temperature: (K) 298.0 298.0
29 Pressure: (atm) 1.150 * 1.150
30 Molar Flow (kgmole/h) 1126 1126
31 Mass Flow (tonne/h) 36.07 36.07
32 Std Ideal Liq Vol Flow (m3/h) 45.33 45.33
33 Molar Enthalpy (kJ/kgmole) -2.395e+005 -2.395e+005
34 Molar Entropy (kJ/kgmole-C) 7.288 7.288
35 Heat Flow (kJ/h) -2.696e+008 -2.696e+008
36 Liq Vol Flow @Std Cond (m3/h) 45.29 * 45.29
37
38
PROPERTIES
44 Mass Enthalpy (kJ/kg) -7473 -7473
50 HHV Mass Basis (Std) (kJ/kg) 2.247e+004 2.247e+004
52 CO2 App ML Con (kgmole/m3) 0.0000 0.0000
53 CO2 App WT Con (kgmol/kg) 0.0000 0.0000
54 LHV Mass Basis (Std) (kJ/kg) 1.991e+004 1.991e+004
58 Mass Exergy (kJ/kg) 11.03 ---
59 Partial Pressure of CO2 (atm) 0.0000 ---
1
4 USA
5
6
Material Stream: M-01 (continued)

7
9
10
PROPERTIES
15 Act. Liq. Flow (m3/s) 1.274e-002 1.274e-002
16 Z Factor 1.917e-003 1.917e-003
17 Watson K 10.63 10.63
19 Partial Pressure of H2S (atm) 0.0000 ---
20 Cp/(Cp - R) 1.078 1.078
21 Cp/Cv 1.374 1.374
25 Heat of Vap. (kJ/kgmole) 3.484e+004 ---
31 Mass Heat of Vap. (kJ/kg) 1087 ---
35 Bubble Point Pressure (atm) 0.1662 ---
36 Viscosity (cP) 0.5458 0.5458
39 Cv (kJ/kgmole-C) 84.04 84.04
40 Mass Cv (kJ/kg-C) 2.623 2.623
44 Reid VP at 37.8 C (atm) 0.3158 0.3158
45 True VP at 37.8 C (atm) 0.3158 0.3158
47 Viscosity Index -2.285 ---
48
49
COMPOSITION
50
51
Overall Phase Vapour Fraction 0.0000
52 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
53 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
54 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
55 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
56 Methanol 1125.7135 1.0000 36070.0000 1.0000 45.3300 1.0000
57 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
58 Formaldehyde 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
59 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
60 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
61 Total 1125.7135 1.0000 36070.0000 1.0000 45.3300 1.0000
62
1
4 USA
5
6
Material Stream: M-01 (continued)

7
9
10
COMPOSITION
11
12
Liquid Phase Phase Fraction 1.000
13 COMPONENTS MOLAR FLOW MOLE FRACTION MASS FLOW MASS FRACTION LIQUID VOLUME LIQUID VOLUME
14 (kgmole/h) (kg/h) FLOW (m3/h) FRACTION
15 Oxygen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
16 Nitrogen 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
17 Methanol 1125.7135 1.0000 36070.0000 1.0000 45.3300 1.0000
18 H2O 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
19 Formaldehyde 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
20 CO 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
21 CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
22 Total 1125.7135 1.0000 36070.0000 1.0000 45.3300 1.0000
23
24
K VALUE
25 COMPONENTS MIXED LIGHT HEAVY
26 Oxygen --- --- ---
27 Nitrogen --- --- ---
28 Methanol 0.0000 0.0000 ---
29 H2O --- --- ---
30 Formaldehyde --- --- ---
31 CO --- --- ---
32 CO2 --- --- ---
33
34
UNIT OPERATIONS
35 FEED TO PRODUCT FROM LOGICAL CONNECTION
36 Mixer: MIX-100 Pump: B-01
37
38
UTILITIES
39 ( No utilities reference this stream )
40
41
PROCESS UTILITY
42
43
44
DYNAMICS
45 Pressure Specification (Active): 1.150 atm *
46 Flow Specification (Inactive) Molar: 1126 kgmole/h Mass: 36.07 tonne/h Std Ideal Liq Volume: 45.33 m3/h
47
48 Pump: B-04
49
50
51
CONNECTIONS
52
53
Inlet Stream
55 C-21 Product Blender M-01
56
57
Outlet Stream
59 Producto Tank V-100
60
61
Energy Stream
1
4 USA
5
6
8
9 PW-04
10
11
PARAMETERS
13
14
CURVES
18
19
User Variables
20
21
CONDITIONS
22 Name C-21 Producto PW-04
23 Vapour 0.0000 0.0000 ---
24 Temperature (K) 362.9501 362.9540 ---
25 Pressure (atm) 2.6000 2.7000 * ---
27 Mass Flow (tonne/h) 44.8719 44.8719 ---
31 Heat Flow (kJ/h) -4.4914e+08 -4.4914e+08 8.6281e+02
32
33
PROPERTIES
34 Name C-21 Producto
45 HHV Mass Basis (Std) (kJ/kg) 1.039e+004 1.039e+004
53 Mass Exergy (kJ/kg) -138.5 -134.4
61 Act. Liq. Flow (m3/s) 1.608e-002 1.608e-002
62 Z Factor 2.530e-003 2.628e-003
1
4 USA
5
6
8
9
10
PROPERTIES
11 Name C-21 Producto
12 Watson K 10.20 10.20
15 Cp/(Cp - R) 1.103 1.103
16 Cp/Cv 1.103 1.103
31 Viscosity (cP) 0.1608 0.1608
34 Cv (kJ/kgmole-C) 81.07 81.07
35 Mass Cv (kJ/kg-C) 3.609 3.609
39 Reid VP at 37.8 C (atm) 9.688e-002 9.688e-002
40 True VP at 37.8 C (atm) 0.7047 0.7047
43
44
PERFORMANCE
45
46
Results
47 Total Head --- Velocity Head 3.538e-005 m
50
51
DYNAMICS
52
53
59
60
Holdup Details
61
62
1
4 USA
5
6
8
11 Vapour 0.0000 0.0000 0.0000
12 Liquid 0.0000 0.0000 0.0000
13 Aqueous 0.0000 0.0000 0.0000
14 Total 0.0000 0.0000 0.0000
15
16 Tank: V-100
17
18
19
CONNECTIONS
20
21
Inlet Stream
23 Producto Pump: B-04
24
25
Outlet Stream
27 W
28 QQ
29
30
Energy Stream
32
33
34
PARAMETERS
35 Vessel Volume: --- Level SP: 50.00 % Liquid Volume: ---
36 Vessel Pressure: 2.700 atm Pressure Drop: 0.0000 kPa Duty: 0.0000 kJ/h Heat Transfer Mode: Heating
37
38
User Variables
39
40
CONDITIONS
41 Name Producto QQ W
42 Vapour 0.0000 0.0000 1.0000
43 Temperature (K) 362.9540 362.9540 362.9540
44 Pressure (atm) 2.7000 * 2.7000 2.7000
46 Mass Flow (tonne/h) 44.8719 44.8719 0.0000
50 Heat Flow (kJ/h) -4.4914e+08 -4.4914e+08 0.0000e-01
51
52
PROPERTIES
55 Molar Density (kgmole/m3) 34.50 34.50 9.162e-002
56 Mass Density (kg/m3) 774.9 774.9 2.339
58 Mass Enthalpy (kJ/kg) -1.001e+004 -1.001e+004 -4486
62 LHV Molar Basis (Std) (kJ/kgmole) 1.922e+005 1.922e+005 1.039e+005
1
4 USA
5
6
7 Tank: V-100 (continued)
8
9
10
PROPERTIES
13 HHV Mass Basis (Std) (kJ/kg) 1.039e+004 1.039e+004 5004
14 CO2 Loading --- --- ---
15 CO2 Apparent Mole Conc. (kgmole/m3) 6.312e-004 6.312e-004 ---
16 CO2 Apparent Wt. Conc. (kgmol/kg) 8.145e-007 8.145e-007 ---
17 LHV Mass Basis (Std) (kJ/kg) 8559 8559 4070
18 Phase Fraction [Vol. Basis] 0.0000 --- 1.000
20 Phase Fraction [Act. Vol. Basis] 0.0000 0.0000 ---
21 Mass Exergy (kJ/kg) -134.4 -134.4 45.20
22 Partial Pressure of CO2 (atm) 0.0000 0.0000 3.676e-002
24 Act. Gas Flow (ACT_m3/h) --- --- 0.0000
25 Avg. Liq. Density (kgmole/m3) 38.26 38.26 ---
27 Std. Gas Flow (STD_m3/h) 4.724e+004 4.724e+004 0.0000
29 Act. Liq. Flow (m3/s) 1.608e-002 1.608e-002 0.0000
30 Z Factor 2.628e-003 --- ---
31 Watson K 10.20 10.20 7.478
34 Cp/(Cp - R) 1.103 1.103 1.327
35 Cp/Cv 1.103 1.103 1.347
36 Ideal Gas Cp/Cv 1.307 1.307 1.333
41 Liq. Mass Density (Std. Cond) (kg/m3) 855.8 855.8 554.3
43 Liquid Fraction 1.000 1.000 0.0000
44 Molar Volume (m3/kgmole) 2.898e-002 2.898e-002 10.92
47 Surface Tension (dyne/cm) 40.98 40.98 ---
48 Thermal Conductivity (W/m-K) 0.3925 0.3925 2.601e-002
49 Bubble Point Pressure (atm) 1.253 1.253 ---
50 Viscosity (cP) 0.1608 0.1608 1.346e-002
53 Cv (kJ/kgmole-C) 81.07 81.07 25.03
54 Mass Cv (kJ/kg-C) 3.609 3.609 0.9802
57 Cp/Cv (Ent. Method) --- --- ---
58 Reid VP at 37.8 C (atm) 9.688e-002 9.688e-002 ---
59 True VP at 37.8 C (atm) 0.7047 0.7047 ---
61 Viscosity Index -60.13 -60.13 ---
62 DYNAMICS
1
4 USA
5
6
7 Tank: V-100 (continued)
8
9 DYNAMICS
10
11
Vessel Parameters: Initialize from Product
12 Vessel Volume (m3) --- Level Calculator Vertical cylinder
13 Vessel Diameter (m) --- Fraction Calculator Use levels and nozzles
14 Vessel Height (m) --- Feed Delta P (kPa) 0.0000
15 Liquid Level Percent (%) 50.00 Vessel Pressure (atm) 2.700
16
17
Holdup: Vessel Levels
18 Phase Level Percent Volume
19 (m) (%) (m3)
20 Vapour --- --- 0.0000
21 Liquid --- --- 0.0000
22 Aqueous --- --- 0.0000
23
24
Holdup: Details
27 Vapour 0.0000 0.0000 0.0000
28 Liquid 0.0000 0.0000 0.0000
29 Aqueous 0.0000 0.0000 0.0000
30 Total 0.0000 0.0000 0.0000
31
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Compressor S-01 Case Study

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Case Name: DOC-20180605-WA0001.hsc

Boiling Point Properties Molecular Weight Properties

Temperature vs. Tray Position from Top

Pressure vs. Tray Position from Top

Flow vs. Tray Position from Top

Column Properties vs. Tray Position from Top

Composition vs. Tray Position from Top

K-Value vs. Tray Position from Top

Component Ratio vs. Tray Position from Top

43 1__Main Tower 63.1 19.6 928 0.529 0.538 3.96

Heat Exchanger: IC-04

Material Stream: M-01

Material Stream: M-01 (continued)

Material Stream: M-01 (continued)

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