tempo [B]

0 0 1
10 0.326 0.9 f(x) = 0.02204x + 0.0668
R² = 0.9719679725
20 0.572
0.8
30 0.75
0.7
40 0.89
0.6
11.20 0.5

0.4

0.3

0.2

0.1

0
0 5 10 15 20 25 30 35 40 45
Vel(L/s) ordem 0 [KI] Ordem 1 ln[KI] Ordem 2 1/[KI]
1.5E-06 0.033 -3.4112477175 30.303030303
2.97E-06 0.033 -3.4112477175 30.303030303
3.06E-06 0.066 -2.718100537 15.1515151515

ordem 0 [KI] Ordem 1 ln[KI]

0.07 0
0.06 1.0E-06 1.5E-06 2.0E-06 2.5E-06 3.0E-06 3.5E-06
-0.5
0.05 -1
0.04 f(x) = 11830.2698474775x + 0.0143060227 -1.5
R² = 0.2957567462 -2
0.03
0.02 -2.5
0.01 -3
-3.5 f(x) = 248488.430001285x - 3.8039046166
0 R² = 0.2957567462
1.0E-06 1.5E-06 2.0E-06 2.5E-06 3.0E-06 3.5E-06 -4

Ordem 2 1/[KI]
35
30
f(x) = - 5431712.51032026x + 38.8861236534
25
R² = 0.2957567462
20
15
10
5
0
1.0E-06 1.5E-06 2.0E-06 2.5E-06 3.0E-06 3.5E-06
T (min) (mol/L) ln [] 1/[]
0 0.2 -1.60944 5 Ordem 0
5 0.171 -1.76609 5.847953 0.25
10 0.146 -1.92415 6.849315
15 0.125 -2.07944 8 0.2

20 0.106 -2.24432 9.433962 0.15

25 0.0909 -2.398 11.0011
0.1
30 0.0777 -2.5549 12.87001
35 0.0664 -2.71206 15.06024 0.05
40 0.057 -2.8647 17.54386
0
0 5 10 15 20 25 30 35 40 45

Ordem 2 Ordem 1
20 0
0 5 10 15 20 25 30 35 40 45
15 -0.5

10 -1
-1.5
5
f(x) = - 0.0314634012x - 1.6099645929
-2
0
0 5 10 15 20 25 30 35 40 45 -2.5
-3
-3.5

11.48
t(dias) mol/l LN [ ] 1/[ ]
0 4.14E-06 -12.3948 2.42E+05
7 3.70E-06 -12.5072 2.70E+05 Ordem 0
14 3.31E-06 -12.6186 3.02E+05 5.00E-06
21 2.94E-06 -12.7371 3.40E+05 4.00E-06
f(x) = - 4.46666666666667E-08x + 3.97511111111111E-06
28 2.61E-06 -12.8562 3.83E+05 3.00E-06

35 2.30E-06 -12.9826 4.35E+05 2.00E-06

42 2.05E-06 -13.0977 4.88E+05 1.00E-06

49 1.82E-06 -13.2167 5.49E+05 0.00E+00

0 10 20 30 40 50 60
56 1.65E-06 -13.3147 6.06E+05

Ordem 1
Ordem 2 -11.8
0 10 20 30 40 50 60
-12
05 -12.2
0E+
0
6. +05 -12.4
E f(x) = - 0.0166949719x - 12.3909294215
00
4. +05 -12.6
E
00 -12.8
2. +00 0 10 20 30 40 50 60
E -13
00
0.
-13.2
-13.4

11.49
t(s) P (torr) ln P 1/[ ]
0 491.7 6.197869 0.002034
185.3 549.6 6.309191 0.00182 Ordem 0
242.8 566.6 6.339654 0.001765 700
600
304.5 584.1 6.370072 0.001712 500
362.7 599.9 6.396763 0.001667 400
429.5 617.2 6.425193 0.00162 300
200
509.7 637 6.45677 0.00157 100
606.3 659.5 6.491482 0.001516 0
0 100 200 300 400 500 600 700

Ordem 2 Ordem 1
0.0025 6.6
0.002 6.5
f(x)==0.9873603502
R² 0.0004802915x + 6.2148299145
R² = 0.9741824098 6.4
0.0015
6.3
0.001 6.2
0.0005 6.1
0 6
0 100 200 300 400 500 600 700 0 100 200 300 400 500 600 700

11.50
k(s-1) T(k) 1/T ln k
3.50E-05 298 3.36E-03 -10.2602
2.20E-04 308 0.003247 -8.42188
6.80E-04 318 3.14E-03 -7.29342
3.10E-03 328 0.003049 -5.77635

1/t vs ln k
0
3.00E-03 3.05E-03 3.10E-03 3.15E-03 3.20E-03 3.25E-03 3.30E-03 3.35E-03 3.40E-03
-2

-4

-6
f(x) = - 14262.9516551002x + 37.6888449924
-8

-10

-12

11.57
k(l/mol s) T (k) 1/T ln k
1.30E+06 200 0.005 14.07787
4.40E+06 250 0.004 15.29712
9.90E+06 300 0.003333 16.10805

ln k
16.5

16 f(x) = - 1218.1921361975x + 20.1691349721

15.5

15

14.5

14

13.5

13
0.0032 0.0034 0.0036 0.0038 0.004 0.0042 0.0044 0.0046 0.0048 0.005 0.0052

11.58
k(L/mol s) T (k) 1/T ln (k)
4.40E+02 2000 0.0005 6.086775
2.50E+05 3000 0.000333 12.42922
5.90E+06 4000 0.00025 15.59046

1/T vs ln (k)
18
16
f(x) = - 38020.4521695314x + 25.0984256721
14
12
10
8
6
4
2
0
0.0002 0.00025 0.0003 0.00035 0.0004 0.00045 0.0005 0.00055

11.59