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ALUMINIUM AND ZINC ANODES

AL / ZN / IN Composistion:

Specification Code A Guard


Fe 0.09%
Si 0.08 – 0.120%
Cu 0.003%
Zn 4.5 – 5.5%
In 0.015 – 0.020%
Others (each) 0.02% max
Alluminium Remainder

Electro Chemichal:
Potential Ag/AgCI -1.05 Volts

Min Capacity 2500 Ampere. hour / kg

Zinc Composition:
Specification Code US Mil Spec 118001 K
Cu 0.05% max
Al 0.010 – 0.50%
Fe 0.05% max
Cd 0.025 – 0.07%
Pb 0.006% max
Others (total) 0.10% max
Zn Remainder

Electro Chemical:
Potential Ag/AgCI -1.05 +/- 0.05V

Capacity 780 Ampere. Hour / kg min.

1
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Weld-on Hull
Anodes

0.35/ 108 76 22 160 - - 25x3 165


AGW2 0.45

0.7/ 160 88 44 240 - - 25x3 245


AGW5 0.8

0.7/ 160 88 50 240 - - 25x3 245


AGW5R 0.8

1.1/ 170 83 41 245 - - 25x3 250


AGW7R 1.25

1.75/ 305 80 44 380 - - 25x3 385


AGW10 2

1.75/ 305 78 44 380 - - 25x3 385


AGW10R 2

2.25/ 305 114 25 380 - - 25x3 385


AGW12 2.5

2.5/ 230 152 32 295 - - 25x3 300


AGW13 2.75

2
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Weld-on Hull
Anodes

3/ 297 152 32 400 - - 40x5 405


AGW15 3.5

4/ 350 152 38 460 - - 40x5 465


AGW20 4.5

4.45/ 355 152 38 460 - - 40x5 465


AGW22 5.2

5.6/ 457 120 70 580 - - 40x5 585


AGW30 6.5

5/6 450 115 60 580 - - 40x5 585


AGW30R

5.6/ 457 120 70 570 - - 40x5 575


AGW30RS 6.5

6/7 457 120 80 570 - - 40x5 575


AGW36R

7/8 550 130 50 700 - - 40x5 705


A8

3
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Weld-on Hull
Anodes

10/ 550 130 65 700 - - 40x5 705


A11 11

7.5/ 813 102 38 913 - - 40x5 918


AGW35 9

10.5/ 813 102 50 913 - - 40x5 918


AGW45 11.5

19/ 990 90 80 1120 - - 40x5 1125


AGWS50 20.5

9/10 305 100 40 - - - 40x5 250


AGW21

3.5/ 300 150 25 300 - - 40x5 250


AGW24 4

4/ 305 152 32 - - - 40x5 250


AGW25 4.5

7.5/ 711 102 38 711 - - 40x5 210


AGW42 8

4
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Weld-on Hull
Anodes

0.9/1 108 76 22 160 - - 25x3 165


ZGW2 Galv

ZGW5 2/2.2 160 88 44 240 - - 25x3


Galv
245

ZGW5R 2/2.1 160 88 50 240 - - 25x3


Galv
245

ZGW7R 2.8/3 170 83 41 245 - - 25x3


Galv
250

ZGW10 4.25/
4.5
305 80 44 380 - - 25x3
Galv
385

ZGW10R 4.25/
4.5
305 78 44 380 - - 25x3
Galv
385

ZGW12 5.25/
5.5
305 114 25 380 - - 25x3
Galv
385

ZGW13 5.8/6 230 152 32 295 - - 25x3


Galv
300

5
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Weld-on Hull
Anodes

7.3/8 297 152 32 400 - - 40x5 405


ZGW15

ZGW20 9.4/
10
350 152 38 460 - - 40x5 465

ZGW22 11.25/
12
355 152 38 460 - - 40x5 465

ZGW30 14.5/
15.5
457 120 70 580 - - 40x5 585

ZGW30R 13/14 450 115 60 580 - - 40x5 585

ZGW30RS 14/15 457 120 70 570 - - 40x5 575

ZGW36R 15.45/
16.4
457 120 80 570 - - 40x5 575

Z20 19/20 550 130 50 700 - - 40x5 705

6
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Weld-on Hull
Anodes

24/ 550 130 55 700 - - 40x5 705


Z25 25.1

ZGW35 18/20 813 102 38 913 - - 40x5 918

ZGW45 25/27 813 102 50 913 - - 40x5 918

ZGWS50 48/50 990 90 80 1120 - - 40x5 1125

ZGW21 9/10 305 100 40 - - - 40x5 250

ZGW24 6/7 300 150 25 300 - - 40x5 250

ZGW25 10/11 305 152 32 - - - 40x5 250

ZGW42 19/20 711 102 38 711 - - 40x5 210

7
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Hull Anodes

0.4/ 140 70 20 180 - - 20x3 180


MA5 0.45

MA15 1.3/
1.5
150 100 38 250 - - 20x3 250

MA25 2.1/
2.5
305 102 40 365 - - 20x3 365

MA50 4.3/
5
445 125 40 505 - - 40x5 505

MA80 7/8 640 125 43 700 - - 40x5 700

MA116 10/
11.6
800 125 50 880 - - 40x5 880

MA155 14/
15.5
920 125 50 - - - 40x5 1020

MA210 20/
21
650 110 105 - - - 40x5 750

8
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Hull Anodes

0.95/ 140 70 20 180 - - 20x3 180


MZ10 1

MZ18 1.7/
1.8
160 80 30 205 - - 20x3 205

MZ30 2.8/3 250 80 25 300 - - 20x3 300

MZ51 4.6/
5.1
300 32 80 350 - - 40x5 350

MZ85 8.1/
8.5
400 97 35 450 - - 40x5 450

MZ108 10.2/
10.8
395 125 43 455 - - 40x5 455

MZ160 15.1/
16
550 127 43 620 - - 40x5 620

MZ220 20.6/
22
680 127 45 760 - - 40x5 760

9
Code

MZ270
Product
Ned Marine

Zinc Hull Anodes

Net/GrosWeight (Kg)
27/
30.4
A – Length (mm)
800

B – Width (mm)
125

C – Height (mm)
50

D – Overall Length (mm)


880

E – Diameter (mm)
-
-

F – Fixing Centres (mm)

G – Insert Size (mm)


40x6

H – Insert Length (mm)


880

10
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Magnesium Hull
Anodes

0.25/ - - 25 - 100 - M12 0


MGR2 0.55

MGR5 0.75/
1.65
- - 25 - 138 - 40x5 100

MGW2 0.4/
0.5
108 76 22 - - - 25x3 0

MGS5R 0.5/
0.75
164 88 44 245 - 200 25x3 250

MGW7R 0.75/
0.95
185 83 41 245 - - 25x3 250

MGW10R 1.1/
1.5
305 88 44 - - - 25x3 390

MGS10R 1.1/
1.3
305 88 44 - - 200 30x3 255

MGW15 2/
2.75
305 152 32 - - - 40x5 405

11
Code
Product

MGW20

MGS25R

MGW30R
Anodes
Ned Marine

Magnesium Hull

Net/GrosWeight (Kg)

12

4.5
3.5

3.5/
2.6/

11.5/
A – Length (mm)

457
457
355

B – Width (mm)

120
102
152

C – Height (mm)

70
64
32

-
-

D – Overall Length (mm)


457

E – Diameter (mm)
-
-
-

-
-

F – Fixing Centres (mm)


229

G – Insert Size (mm)


40x5
40x5
40x5

H – Insert Length (mm)


580
363
460

12
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Stand Off
Anodes

148/ 2375 160 160 2675 - - 60mm 2675


M1480PA 167 DIA

M1760PA 175/ 1735 200 200 2035 - - 60mm 2035


191 DIA

M2400PA 240/ 2365 200 200 2665 - - 60mm 3225


260 DIA

M3300PA 330/ 2375 250 250 2675 - - 114mm 2675


390 DIA

M4350PA 435/ 2985 250 250 3285 - - 114mm 3285


505 DIA

M5650PA 565/ 2975 283 283 3275 - - 114mm 3275


645 DIA

M5660PA 566/ 2440 305 305 2740 - - 114mm 2740


633 DIA

13
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Tank Anodes

2.5/ 335 50 55 800 - - 12mm 800


M25TA 3.2 DIA

3.3/
M33TA 4.4 305 63 70 800 - - 12mm 800
DIA

M45TA 4.5/ 600 50 55 1100 - - 12mm 1100


5.5 DIA

M58TA 5.8/ 3.5 80 95 800 - - 12mm 800


6.5 DIA

M70TA 7.0/ 600 63 70 1100 - - 12mm 1100


8.0 DIA

M75TA 7.5/ 1000 50 55 1500 - - 12mm -


9.0 DIA

M87TA 8.7/ 762 63 70 1225 - - 12mm 1225


10 DIA

M100TA 10/ 525 80 95 1025 12mm 1025


11 DIA

14
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Tank Anodes

11.4/ 1525 50 55 2125 - - 12mm 2125


M114TA 13.3 DIA

M121TA 12.1/ 600 80 95 1100 - - 12mm 1100


13.0 DIA

M150TA 15/1 750 80 95 1250 - - 12mm 1250


6.1 DIA

M170TA 17/1 850 80 95 1350 - - 12mm 1350


8.2 DIA

M200TA 20.0/ 1000 80 95 1500 - - 12mm 1500


21.3 DIA

M252TA 25.2/ 1250 80 95 1750 - - 12mm 1750


26.7 DIA

M309TA 30.9/ 1525 80 95 2125 - - 12mm 2125


32.7 DIA

M340TA 34/ 1515 80 105 2115 16mm 2115


36.4 DIA

15
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Tank Anodes

35/ 1300 100 100 1800 - - 20mm 1800


M350TA 39.5 DIA

M445TA 44.5/ 2000 80 105 2600 - - 16mm 2600


47.5 DIA

M480TA 48/ 1480 110 110 2080 - - 25mm 2080


54 DIA

M570TA 57/ 1750 110 110 2350 - - 25mm 2350


64 DIA

M650TA 65/ 2000 110 110 2600 - - 25mm 2600


74 DIA

M700TA 70/ 1555 130 130 2155 - - 25mm 2155


80 DIA

M800TA 80/ 1775 130 130 2375 - - 25mm 2375


90 DIA

M900TA 90/ 2000 130 130 2600 25mm 2600


101 DIA

16
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Tank Anodes

100/ 220 130 130 2820 - - 25mm 2820


M1000TA 110 DIA

M1100TA 110/ 1595 160 160 2195 - - 25mm 2195


118.5 DIA

M1200TA 120/ 1740 160 160 2340 - - 25mm 2340


129 DIA

M1265TA 126.5/ 2000 117.5 200 2600 - - 25mm 2600


136.5 DIA

M1300TA 130/ 1885 160 160 2485 - - 25mm 2485


139.5 DIA

M1350TA 135/ 3000 130 130 3600 - - 25mm 3600


148 DIA

M1400TA 140/ 2030 160 160 2630 - - 25mm 2630


150 DIA

M1500TA 150/ 2175 160 160 2775 25mm 2775


160 DIA

17
Code

M1600TA
Product
Ned Marine

Aluminium Tank Anodes

Net/GrosWeight (Kg)
171
160/

A – Length (mm)
2320

B – Width (mm)
160

C – Height (mm)
160

D – Overall Length (mm)


2920
-

E – Diameter (mm)
-

F – Fixing Centres (mm)

G – Insert Size (mm)


DIA
25mm

H – Insert Length (mm)


2920

18
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Tank Anodes

5.2/ 300 50 50 800 - - 12mm 800


M52T 6.0 DIA

M101T 10.1/
11.0
600 50 50 1100 - - 12mm
DIA
1100

ZGRE13 13/
13.5
1525 35 35 - - - 12mm
DIA
1550

M150T 15.0/
16.5
900 50 50 1500 - - 12mm
DIA
1500

M205T 20.5/
22.0
1225 50 50 1825 - - 12mm
DIA
1825

ZGT22 22/
23.5
1525 55 50 1100 - - 12mm
DIA
0

M265T 26.5/
27.5
500 80 95 1000 - - 12mm
DIA
1000

M318T 31.8/
32.7
600 80 95 1100 - - 12mm
DIA
1100

19
Code
Product

M500T
M400T
Ned Marine

Zinc Tank Anodes

Net/GrosWeight (Kg)

50/
40/

51.3
41.2

A – Length (mm)

940
750

80 B – Width (mm)
80

C – Height (mm)
95
95

D – Overall Length (mm)


1540
1350

-
-

E – Diameter (mm)
-
-

F – Fixing Centres (mm)

G – Insert Size (mm)


DIA
DIA

20mm
20mm

H – Insert Length (mm)


1540
1350

20
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Aluminium Pit Guard
Anodes

2.2/ 310 50 55 370 - - 12mm 370


M22TPA 3.1 DIA

3.2/ 430 50 55 500 - - 12mm 500


M32TPA 4.2 DIA

4.5/ 605 50 55 665 - - 12mm 665


M45TPA 5.6 DIA

5.5/ 275 80 95 335 - - 12mm 335


M55TPA 6.4 DIA

7.0/ 350 80 95 410 - - 12mm 410


M70TPA 7.9 DIA

9.0/ 450 80 95 510 - - 12mm 510


M90TPA 10.0 DIA

21
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Pit Guard
Anodes

5.0/ 290 50 50 350 - - 12mm 350


M50TP 5.9 DIA

M100TP 10/
11.1
580 50 50 640 - - 12mm
DIA
640

M120TP 12/
13
395 63 70 455 - - 12mm
DIA
455

M150TP 15/
15.9
280 80 95 340 - - 12mm
DIA
340

M170TP 17/
17.9
315 80 95 375 - - 12mm
DIA
375

M200TP 20/
21
370 80 95 430 - - 12mm
DIA
430

22
Code

AGR5
AGR2
Product

AGR15

AGWL16
Anodes
Ned Marine

Aluminium Disc Hull

Net/GrosWeight (Kg)

8.5
0.8
0.4

7.1/
2.85/
0.75/
0.35/

A – Length (mm)

-
-
-
-

B – Width (mm)

-
-
-
-

C – Height (mm)

30
25
35
25

-
-
-
-

D – Overall Length (mm)

E – Diameter (mm)

345
225
138
100

-
-
-
-

F – Fixing Centres (mm)

G – Insert Size (mm)


M16
M12

40x5
40x5

H – Insert Length (mm)


0

500
100
100

23
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Disc Hull
Anodes

0.2/ - - 20 - 65 - M10 0
ZGR250g 0.25

ZGR1 0.4/
0.5
- - 25 - 70 - M10 0

ZGR2 0.7/
0.8
- - 25 - 95 - M10 0

ZGR2S 0.9/1 - - 25 - 100 - M10 0

ZGR5 2.3/
2.5
- - 35 - 138 - M16 100

ZGR15 6.8/7 - - 25 - 225 - M16 100

ZGSR23 10.95/
11.15
- - 50 - 230 - M16 100

ZGWL16 18.4/
20
- - 30 - 345 - 40x5 500

24
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Strip Anodes

25x3
0.6/ 125 44 15 - - 75 OR 100
ZGST5 0.65 AL
TOP
HAT

25x3
ZGST6 0.5/
2.55
152 44 15 - - - OR
AL
152

TOP
HAT

25x3
ZGST6D 0.5/
2.55
152 44 15 - - - OR
AL
152

TOP
HAT

25x3
ZGST12 0.9/
1.1
305 44 15 - - - OR
AL
305

TOP
HAT

25x3
ZGST12D 0.9/
1.1
305 44 15 - - - OR
AL
305

TOP
HAT

25x3
ZGST15 1.1/
1.4
381 44 15 - - - OR
AL
380

TOP
HAT

25x3
ZGST15D 1.1/
1.4
378 44 15 - - - OR
AL
378

TOP
HAT

25x3
ZGST18 1.3/
1.65
457 44 15 - - - OR
AL
457

TOP
HAT

25
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc Strip Anodes

25x3
1.8/ 610 44 15 - - - OR 610
ZGST24 2.2 AL
TOP
HAT

25x3
ZGST36 2.7/
3.3
915 44 15 - - - OR
AL
-

TOP
HAT

25x3
ZGST39 2.9/
3.5
990 44 15 - - - OR
AL
970

TOP
HAT

ZGCP4 0.5/
0.55
112 40 12 - - 42 M16 -

26
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc ROD Anodes

0.3/- 500 - - - 10 - None 0


ZR10

ZR12 0.4/- 500 - - - 12 - None 0

ZR16 0.7/- 500 - - - 16 - None 0

ZR20 1.25/- 500 - - - 20 - None 0

ZR25 1.8/- 500 - - - 25 - None 0

ZR30 2.5/- 500 - - - 30 - None 0

ZR40 4.5/- 500 - - - 40 - None 0

ZR50 7/- 500 - - - 50 - None 0

27
D – Overall Length (mm)

F – Fixing Centres (mm)

H – Insert Length (mm)


Ned Marine

Net/GrosWeight (Kg)

G – Insert Size (mm)


Product

E – Diameter (mm)
A – Length (mm)

C – Height (mm)
B – Width (mm)
Code
Zinc ROD Anodes

10/- 500 - - - 60 - None 0


ZR60

ZR70 13.7/- 500 - - - 70 - None 0

ZR80 17.7/- 500 - - - 80 - None 0

ZR90 22.7/- 500 - - - 90 - None 0

ZR100 27.7/- 500 - - - 100 - None 0

ZR200 45/- 250 - - - 200 - None 0

ZR125 46.5/- 500 - - - 125 - None 0

ZR150 66.5 500 - - - 150 - None 0

28
Revision No.: B
MATERIAL SAFETY:
Aluminium Alloy Issue Date: 25/08/2010
MSDS-001 Pages: 1 of 3

Section 1: Product Information and Company Identification

Product Name: Aluminium Alloy Contact Information: NedMarine Services B.V.


Synonym: Al/In/Zn Tinstraat 109
Chemical Name: None Allocated 2984 AN Ridderkerk
Chemical Formula: None Allocated The Netherlands
Hazchem Code: None Allocated Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: info@nedmarine.com
Web: www.nedmarine.com

Section 2: Composition and Information on Elements


Alluminium
Alloy A-Guard® G3 MIL-DTL- DNV-RP-B401 ISO 15589-2 NORSOK M-503
24779A(SH)

Elements %
Zinc 4.000%-5.000% 2.500%-0.500% 4.000%-6.500% 2.500%-5.750% 2.500%-5.750% 2.500%-5.750%
Indium 0.015%-0.020% 0.010%-0.020% 0.014%-0.020% 0.015%-0.040% 0.016%-0.040% 0.015%-0.040%
Silicon 0.080%-0.120% 0.080%-0.150% 0.080%-0.200% max. 0.120% max. 0.120% max.0.100%
Iron max. 0.090% max. 0.120% max. 0.090% max. 0.090% max. 0.90% max. 0.90%
Copper max. 0.003% max. 0.006% max. 0.004% max. 0.003% max. 0.003% max. 0.003%
Mercury - - max. 0.001% - - -
Tin - - max. 0.001% - - -
Cadmium - - - max. 0.002% max. 0.002% -
Others max. 0.100% max. 0.020% (ea.) max. 0.100% - max. 0.020% (ea.) max. 0.020% (ea.)
Aluminium Remainder Remainder Remainder Remainder Remainder Remainder

Section 3: Hazards Identification


Potential Acute Health Effects:
Slightly hazardous in case of skin contact (irritant). Non-irritating to the eyes. Non-hazardous in case of ingestion.

Potential Chronic Health Effects:


CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

The substance is toxic to lungs.

Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures


Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation occurs.

Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Serious Skin Contact: Not available.


Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Serious Inhalation: Not available.

Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities
of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

29
Revision No.: B
MATERIAL SAFETY:
Aluminium Alloy Issue Date: 25/08/2010
MSDS-001 Pages: 2 of 3

Section 5: Fire and Explosion Data


Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Some metallic oxides.

Fire Hazards in Presence of Various Substances: Not available.

Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion
of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures


Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.

Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and
allow evacuating through the sanitary system.

Section 7: Handling and Storage


Precautions: Do not ingest. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away
from incompatibles such as oxidizing agents, acids, alkalis.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Moisture sensitive.

Section 8: Exposure Controls / Personal Protection


Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Gloves.

Personal Protection in Case of a Large Spill: Safety glasses. Lab coat. Gloves.

Exposure Limits: Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. Specific Gravity: Density: 2.7 (Water = 1)

Odour: Odourless. Vapour Pressure: Not applicable.

Taste: Not available. Vapour Density: Not available.

Molecular Weight: 2700 - 2750 kg/m3 Volatility: Not available.

Colour: Silver-white Odour Threshold: Not available.

pH (1% soln/water): Not applicable. Water/Oil Dist. Coeff.: Not available.

Boiling Point: 2327°C (4220.6°F) Ionicity (in Water): Not available.

Melting Point: 660°C (1220°F) Dispersion Properties: Not available.

Critical Temperature: Not available. Solubility: Insoluble in cold water, hot water. Soluble in alkalies, Sulphuric
acid, Hydrochloric acid. Insoluble in concentrated Nitric Acid, hot Acetic
acid.

30
Revision No.: B
MATERIAL SAFETY:
Aluminium Alloy Issue Date: 25/08/2010
MSDS-001 Pages: 3 of 3

Section 10: Stability and Reactivity Data


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Incompatible materials, exposure to moist air or water.

Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.

Corrosivity: Not available.

Special Remarks on Reactivity: Moisture sensitive. Aluminium reacts vigorously with Sodium Hydroxide. Aluminium is also incompatible with strong
oxidizers, acids, chromic anhydride, iodine, carbon disulfide, methyl chloride, and halogenated hydrocarbons, acid chlorides, ammonium nitrate, ammonium
persulfate, antimony, arsenic oxides, barium bromate, barium chlorate, barium iodate, metal salts.

Special Remarks on Corrosivity: In moist air, oxide film forms which protects metal from corrosion. Aluminium is strongly electropositive so that it corrodes
rapidly in contact with other metals.

Polymerization: Will not occur.

Section 11: Toxicological Information


Routes of Entry: Not available.

Toxicity to Animals: Not available

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant). Non-hazardous in case of ingestion. Non-hazardous in case of inhalation.

Special Remarks on Toxicity to Animals: Not available.


Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:

Skin: Exposure to Aluminium may cause skin irritation.

Eyes: Not expected to be a hazard unless Aluminium dust particles are present. Exposure to Aluminium dust may cause eye irritation by mechanical action.
Aluminium particles deposited in the eye are generally innocuous. Inhalation: Not expected to be an inhalation hazard unless it is heated or if Aluminium dust is
present It heated or in dust form, it may cause respiratory tract irritation. Heating Aluminium can release Aluminium Oxide fumes and cause fume metal fever
when inhaled. This is a flu-like illness with symptoms of metallic taste, fever, chills, aches, chest tightness, and cough.

Ingestion: Acute Aluminium toxicity is unlikely.

Chronic Potential Health Effects:


Skin: Contact dermatitis occurs rarely after Aluminium exposure. Most cases of Aluminium toxicity in humans are in one of two categories: patients with
chronic renal failure, or people exposed to Aluminium fumes or dust in the workplace. The main source of Aluminium in people with chronic renal failure was
in the high Aluminium content of the water for the dialysate used for dialysis in the 1970's in America. Even though this problem was recognized and corrected,
Aluminium toxicity continues to occur in some individuals with renal who chronically ingest Aluminium-containing phosphate binders or antacids.

Inhalation: Chronic exposure to Aluminium dust may cause dyspnoea, cough, asthma, chronic obstructive lung disease, pulmonary fibrosis, pneumothorax,
pneumoconiosis, encephalopathy, weakness, in-coordination and epileptiform seizures and other neurological symptoms similar to that described for chronic
ingestion. Hepatic necrosis is also a reported effect of exposure to airborne particulates carrying Aluminium.

Ingestion: Chronic ingestion of Aluminium may cause Aluminium Related Bone Disease or Aluminium-induced Osteomalacia with fracturing Osteodystrophy,
microcytic anemia, weakness, fatigue, visual and auditory hallucinations, memory loss, speech and language impairment (dysarthria, stuttering, stammering,
anomia, hypofluency, aphasia and eventually, mutism), epileptic seizures(focal or grand mal), motor disturbance (tremors, myoclonic jerks, ataxia, convulsions,
asterixis, motor apraxia, muscle fatigue), and dementia (personality changes, altered mood, depression, diminished alertness, lethargy, 'clouding of the
sensorium', intellectual deterioration, obtundation, coma), and altered EEG.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Aluminium is considered stable under normal handling conditions. Keep Aluminium metal clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.

31
Revision No.: B
MATERIAL SAFETY:
Copper Issue Date: 25/08/2010
MSDS-003 Pages: 1 of 3

Section 1: Product Information and Company Identification

Product Name: Copper Contact Information: NedMarine Services B.V.


Synonym: Copper Metal Tinstraat 109
Chemical Name: Copper 2984 AN Ridderkerk
Chemical Formula: Cu The Netherlands
Hazchem Code: None Allocated Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: info@nedmarine.com
Web: www.nedmarine.com

Section 2: Composition and Information on Elements


Copper: % by weight – 100%

Section 3: Hazards Identification


Potential Acute Health Effects: Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. Slightly
hazardous in case of skin contact (irritant).

Potential Chronic Health Effects:


CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

The substance is toxic to lungs, mucous membranes.

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures


Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an
emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin Contact: Not available.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation: Not available. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the
victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data


Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Some metallic oxides.

Fire Hazards in Presence of Various Substances: Not available.

Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not
available.

Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special Remarks on Explosion Hazards: Not available.

32
Revision No.: B
MATERIAL SAFETY:
Copper Issue Date: 25/08/2010
MSDS-003 Pages: 2 of 3

Section 6: Accidental Release Measures


Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.

Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow evacuating through the sanitary system. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage


Precautions: Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust. Avoid contact with eyes Wear suitable protective clothing In
case of insufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label when
possible.

Storage: Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents.

Section 8: Exposure Controls / Personal Protection


Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.

Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.

Exposure Limits: TWA: 1 (mg/m3) from ACGIH [1990]

Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. Specific Gravity: 8.94 (Water = 1)

Odour: Not available. Vapour Pressure: Not applicable.

Taste: Not available. Vapour Density: Not available.

Molecular Weight: 8960 kg/m3 Volatility: Not available.


Colour: Pinkish-red Odour Threshold: Not available.
pH (1% soln/water): Not applicable. Water/Oil Dist. Coeff.: Not available.
Boiling Point: 2595°C (4703°F) Ionicity (in Water): Not available.
Melting Point: 1083°C (1981.4°F) Dispersion Properties: Not available.
Critical Temperature: Not available. Solubility: Insoluble in cold water.

Section 10: Stability and Reactivity Data


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.


Polymerization: No.

33
Revision No.: B
MATERIAL SAFETY:
Copper Issue Date: 25/08/2010
MSDS-003 Pages: 3 of 3

Section 11: Toxicological Information


Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Not available.

Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.

Other Toxic Effects on Humans: Very hazardous in case of ingestion. Hazardous in case of inhalation. Slightly hazardous in case of skin
contact (irritant).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Passes through the placenta, excreted in maternal milk.

Special Remarks on other Toxic Effects on Humans: Not available.


Section 12: Ecological Information
Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.

Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.

Special Remarks on the Products of Biodegradation: Not available.


Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
Special Provisions for Transport: Marine Pollutant
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.

34
Revision No.: B
MATERIAL SAFETY:
Zinc Alloy Issue Date: 25/08/2010
MSDS-002 Pages: 1 of 4

Section 1: Product Information and Company Identification

Product Name: Zinc Alloy Contact Information: NedMarine Services B.V.


Synonym: Zn/Al Tinstraat 109
Chemical Name: None Allocated 2984 AN Ridderkerk
Chemical Formula: None Allocated The Netherlands
Hazchem Code: None Allocated Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: info@nedmarine.com
Web: www.nedmarine.com

Section 2: Composition and Information on Elements


Zinc Alloy
MIL-A-18001K ASTM B 418 Type II ASTM B 418 Type I
Elements %
Aluminium 0.100% - 0.500% max. 0.005% 0.100% - 0.500%
Cadmium 0.025% - 0.070% max. 0.003% 0.025% - 0.070%
Iron max. 0.005% max. 0.0014% max. 0.005%
Copper max. 0.005% max. 0.002% max. 0.005%
Lead max. 0.006% max. 0.003% max. 0.006%
Others max. 0.100% - max. 0.100%
Zinc min. 99.314% Remainder Remainder

Section 3: Hazards Identification


Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:


CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures


Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.

Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Serious Skin Contact: Not available.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Serious Inhalation: Not available.

Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.

Serious Ingestion: Not available.

35
Revision No.: B
MATERIAL SAFETY:
Zinc Alloy Issue Date: 25/08/2010
MSDS-002 Pages: 2 of 4

Section 5: Fire and Explosion Data


Flammability of the Product: Flammable.

Auto-Ignition Temperature: 480°C (896°F)

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of heat, of
oxidizing materials, of acids, of alkalis, of moisture. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not
available. Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or
fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.

Special Remarks on Fire Hazards: Zinc + NaOH causes ignition. Oxidation of zinc by potassium proceeds with incandescence. Residues
from zinc dust /acetic acid reduction operations may ignite after long delay if discarded into waste bins with paper. Incandescent reaction
when Zinc and Arsenic or Tellurium, or Selenium are combined. When hydrazine mononitrate is heated in contact with zinc, a flaming
decomposition occurs at temperatures a little above its melting point.

Contact with acids and alkali hydroxides (sodium hydroxide, postasium hydroxide, calcium hydroxide, etc.) results in evolution of
hydrogen with sufficient heat of reaction to ignite the hydrogen gas.

Zinc foil ignites if traces of moisture are present.

It is water reactive and produces flammable gases on contact with water. It may ignite on contact with water or moist air.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures


Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.

Large Spill: Flammable solid that, in contact with water, emits flammable gases. Stop leak if without risk. Do not get water inside
container. Do not touch spilled material. Cover with dry earth, sand or other non-combustible material. Prevent entry into sewers, basements
or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow evacuating through the sanitary system.

Section 7: Handling and Storage


Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust.
Keep away from incompatibles such as oxidizing agents, acids, alkalis, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep from any possible contact with water. Do not
allow water to get into container because of violent reaction.

Section 8: Exposure Controls / Personal Protection


Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.

Exposure Limits: Not available.

36
Revision No.: B
MATERIAL SAFETY:
Zinc Alloy Issue Date: 25/08/2010
MSDS-002 Pages: 3 of 4

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. (Lustrous solid. Metal solid.) Specific Gravity: Not available.

Odour: Not available. Vapour Pressure: Not applicable.

Taste: Not available. Vapour Density: Not available.

Molecular Weight: 7103 kg/m3 Volatility: Not available.

Colour: Bluish-grey Odour Threshold: Not available.

pH (1% soln/water): Not applicable. Water/Oil Dist. Coeff.: Not available.

Boiling Point: 907°C (1664.6°F) Ionicity (in Water): Not available.

Melting Point: 419°C (786.2°F) Dispersion Properties: Not available.

Critical Temperature: Not available. Solubility: Insoluble in cold water, hot water, methanol, diethyl
ether, n-octanol, acetone.

Section 10: Stability and Reactivity Data


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, incompatible materials, moisture

Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis. Slightly reactive to reactive with moisture. The
product may react violently with water to emit flammable but non toxic gases.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Incompatible with acids, halogenated hydrocarbons, NH4NO3, barium oxide, Ba(NO3)2, Cadmium, CS2,
chlorates, Cl2, CrO3, F2, Hydroxylamine, Pb(N3)2, MnCl2, HNO3, performic acid, KClO3, KNO3, N2O2, Selenium, NaClO3, Na2O2,
Sulfur, Te, water, (NH4)2S, As2O3, CS2, CaCl2, chlorinated rubber, catalytic metals, halocarbons, o-nitroanisole, nitrobenzene, non
metals, oxidants, paint primer base, pentacarbonoyliron, transition metal halides, seleninyl bromide, HCl, H2SO4, (Mg +Ba(NO3)2
+BaO2), (ethyl acetoacetate +tribromoneopentyl alcohol. Contact with Alkali Hydroxides(Sodium Hydroxide, Potassium Hydroxide,
Calcium Hydroxide, etc) results in evolution of hydrogen. Ammonium nitrate + zinc + water causes a violent reaction with evolution of
steam and zinc oxide. May react with water.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

37
Revision No.: B
MATERIAL SAFETY:
Zinc Alloy Issue Date: 25/08/2010
MSDS-002 Pages: 4 of 4

Section 11: Toxicological Information


Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals: Not available.


Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.


Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:

Skin: May cause skin irritation. Dermal exposure to zinc may produce leg pains, fatigue, anorexia and weight loss.
Eyes: May cause eye irritation.
Ingestion: May be harmful if swallowed. May cause digestive tract irritation with tightness in throat, nausea, vomiting, diarrheal, loss of
appetite, alaise, abdominal pain. fever, and chills. May affect behaviour/central nervous system and autonomic nervous system with ataxia,
lethargy, staggering gait, mild derangement in cerebellar function, light headiness, dizziness, irritability, muscular stiffness, and pain. May
also affect blood.

Inhalation: Inhalation of zinc dust or fumes may cause respiratory tract and mucous membrane irritation with cough and chest pain. It can
also cause "metal fume fever", a flu-like condition characterized appearance of chills, headache fever, maliase, fatigue, sweating, extreme
thirst, aches in the legs and chest, and difficulty in breathing. A sweet taste may also be present in metal fume fever, as well as a dry throat,
aches, nausea, and vomiting, and pale grey cyanosis.

The toxicological properties of this substance have not been fully investigated.
Section 12: Ecological Information
Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products
may arise.

Toxicity of the Products of Biodegradation: Not available.

Special Remarks on the Products of Biodegradation: Not available.


Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Zinc is considered stable under normal handling conditions. Keep Zinc metal clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.

38
Revision No.: B
MATERIAL SAFETY:
Mild Steel Issue Date: 25/08/2010
MSDS-004 Pages: 1 of 3

Section 1: Product Information and Company Identification

Product Name: Mild Steel Contact Information: NedMarine Services B.V.


Synonym: Carbon and Alloy Steel, AISI-SAE Tinstraat 109
Chemical Name: None Allocated 2984 AN Ridderkerk
Chemical Formula: None Allocated The Netherlands
Hazchem Code: None Allocated Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: info@nedmarine.com
Web: www.nedmarine.com

Section 2: Composition and Information on Elements

Elements % % by weight Elements % % by weight


Aluminium <0.01% - 0.50% Lead <0.15% - 0.35%
Bismuth <0.20% - 0.50% Manganese <0.04% - 0.70%
Boron <0.01% - 1.00% Molybdenum <0.15% - 1.10%
Carbon <0.10% - 1.50% Nickel <0.10% - 10.00%
Chromium <0.40% - 100% Phosphorous <0.04% - 0.12%
Columnium <0.15% - 0.35% Silicon <0.15% - 2.00%
Copper <0.30% - 1.90% Sulphur <0.05% - 0.35%
Iron <86.50% - 99.50% Vanadium <0.01% - 0.15%
The above is a summary of elements used in alloying steel. Various grades of steel will contain different combinations of these elements. Trace elements may
also be present in minute amounts.

Section 3: Hazards Identification


Potential Acute Health Effects: Excessive inhalation of metallic fumes and dust may result in irritation of eyes, nose and throat. High concentrations of fumes
and dust of iron-oxide, manganese, copper, zinc and lead may result in metal fume fever. Typical symptoms last from 12 to 48 hours and consist of a metallic
taste in the mouth, dryness and irritation of the throat, chills and fever.

Potential Chronic Health Effects: Chronic and prolonged inhalation of high concentrations of fumes or dust of the following elements may lead to the
conditions listed opposite the element.

Aluminium: May initiate fibrotic changes to lung tissue. Manganese: Bronchitis, pneumonitis, lack of coordination.

Bismuth: No chronic debilitating symptoms indicated. Molybdenum: Respiratory tract irritation, possible liver and kidney damage,
bone deformity.
Boron: No chronic debilitating symptoms indicated.
Nickel: Lesions of the skin and mucous membranes, possible cancer of the
Chromium: Lesions of the skin and mucous membranes, possible cancer of nose or lungs-bronchogenic carcinoma.
the nose or lungs-bronchogenic carcinoma
Phosphorous: Necrosis of the mandible.
Copper: No chronic debilitating symptoms indicated.
Sulphur: (as Sulphur Dioxide) Edema of the lungs.
Iron: Siderosis, pulmonary effects.
Vanadium: (as Vanadium Pentoxide) Emphysema, pneumonia.
Lead: Anemia, urinary dysfunction, weakness, constipation, nausea, nervous
disorder. Zinc: Gastrointestinal inflammation reported in animal studies.

Section 4: First Aid Measures


Eye Contact: Flush thoroughly with running water to remove particulate; obtain medical attention.

Skin Contact: Remove particles by washing thoroughly with soap and water. Seek medical attention if condition persists.

Serious Skin Contact: Not available.

Inhalation: If inhaled, remove to fresh air; if condition continues, consult a physician..

Serious Inhalation: Not available.

Ingestion: If significant amounts of metal are ingested, consult a physician.

Serious Ingestion: Not available.

39
Revision No.: B
MATERIAL SAFETY:
Mild Steel Issue Date: 25/08/2010
MSDS-004 Pages: 2 of 3

Section 5: Fire and Explosion Data


Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not available

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not available Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances: Steel products do not present fire or explosion hazards under normal conditions. Fine metal particles
such as produced in grinding or sawing can burn. High concentrations of metallic fines in air may present an explosion hazard.

Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder or sand.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures


Small Spill: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse.

Large Spill: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse.

Section 7: Handling and Storage


Precautions: Keep away from heat and direct sunlight. Do not breathe dust.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep from any possible contact with water.

Section 8: Exposure Controls / Personal Protection


Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection: Appropriate dust/mist/fume respirator should be used to avoid excessive inhalation of particulates. If exposure limits are reached or
exceeded, use NIOSH approved equipment. Safety glasses should be worn when grinding or cutting. Face shields should be worn when welding or cutting.
Protective gloves should be worn as required for welding, burning or handling operations.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. Specific Gravity: (H2O = 1): Approx. 1.47.

Odour: Odourless. Vapour Pressure: Not applicable.

Taste: Not available. Vapour Density: Not available.

Molecular Weight: 7850 kg/m3. Volatility: Not available.

Colour: Silver-grey Odour Threshold: Not available.

pH (1% soln/water): Not applicable. Water/Oil Dist. Coeff.: Not available.

Boiling Point: Not applicable Ionicity (in Water): Not available.

Melting Point: 1,426–1,538°C (2,599–2,800°F) Dispersion Properties: Not available.

Critical Temperature: Not available. Solubility: Not applicable.

40
Revision No.: B
MATERIAL SAFETY:
Mild Steel Issue Date: 25/08/2010
MSDS-004 Pages: 3 of 3

Section 10: Stability and Reactivity Data


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Steel at temperatures above the melting point may liberate fumes containing oxides of iron and alloying elements. Avoid generation
of airborne fumes and dust.

Incompatibility with various substances: Reacts with strong acids to form Hydrogen gas.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Metallic dust or fumes may be produced during welding, burning, grinding and possible machining.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information


Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects:

Skin: May cause skin irritation. Eyes: May cause eye irritation. Ingestion: May be harmful if swallowed.

Inhalation: Inhalation of steel dust or fumes may cause respiratory tract and mucous membrane irritation with cough and chest pain.

The toxicological properties of this substance have not been fully investigated.
Section 12: Ecological Information
Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Not available

Toxicity of the Products of Biodegradation: Not available.

Special Remarks on the Products of Biodegradation: Not available.


Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Mild Steel is considered stable under normal handling conditions. Keep Mild Steel clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.

41
Revision No.: B
MATERIAL SAFETY:
Magnesium Alloy Issue Date: 25/08/2010
MHP-005 Pages: 1 of 3

Section 1: Product Information and Company Identification

Product Name: Magnesium Alloy Contact Information: NedMarine Services B.V.


Synonym: Mg/Al/Zn Tinstraat 109
Chemical Name: None Allocated 2984 AN Ridderkerk
Chemical Formula: None Allocated The Netherlands
Hazchem Code: None Allocated Tel: +31 (0) 180 420 055
Fax: +31 (0) 180 499 810
Email: info@nedmarine.com
Web: www.nedmarine.com

Section 2: Composition and Information on Elements

Elements % M-Guard Alloy


Alluminium 5.30% - 6.70%
Zinc 2.50% - 3.50%
Copper max. 0.080%
Silicon max. 0.300%
Iron max. 0.005%
Maganese max. 0.250%
Nickel max. 0.003%
Lead max. 0.030%
Magnesium Remainder

Section 3: Hazards Identification


Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:


CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures


Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation occurs.

Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Serious Skin Contact: Not available.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult,
administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.

Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities
of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

42
Revision No.: B
MATERIAL SAFETY:
Magnesium Alloy Issue Date: 25/08/2010
MHP-005 Pages: 2 of 3

Section 5: Fire and Explosion Data


Flammability of the Product: Flammable.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: Some metallic oxides.

Fire Hazards in Presence of Various Substances: Highly flammable in presence of open flames and sparks, of heat. Flammable in presence of acids, of
moisture. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion
of the product in presence of static discharge: Not available. Explosive in presence of acids, of moisture.

Fire Fighting Media and Instructions: Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing
vessels with water jet in order to prevent pressure build-up, auto ignition or explosion.

Special Remarks on Fire Hazards: Magnesium turnings, chips or granules, ribbons, are flammable. They can be easily ignited. They may reignite after fire is
extinguished. Produces flammable gases on contact with water and acid. May ignite on contact with water or moist air. Magnesium fires do not flare up
violently unless moisture is present.

Special Remarks on Explosion Hazards: Reacts with acids and water to form hydrogen gas with is highly flammable and explosive

Section 6: Accidental Release Measures


Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill: Flammable solid. Stop leak if without risk. Do not touch spilled material. Use water spray curtain to divert vapour drift. Prevent entry into sewers,
basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.

Section 7: Handling and Storage


Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust. Keep away from
incompatibles such as oxidizing agents, acids, moisture.

Storage: Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition
(spark or flame). Moisture sensitive. Dangerous when wet.

Section 8: Exposure Controls / Personal Protection


Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure
limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties


Physical state and appearance: Solid. (metal solid) Specific Gravity: (H2O = 1) : Approx. 1.74.

Odour: Odourless. Vapour Pressure: Not applicable.

Taste: Not available. Vapour Density: Not available.

Molecular Weight: 2431 kg/m3 Volatility: Not available.

Colour: Silver-white Odour Threshold: Not available.

pH (1% soln/water): Not applicable. Water/Oil Dist. Coeff.: Not available.

Boiling Point: 1100°C (2012°F) Ionicity (in Water): Not available.

Melting Point: 651°C (1203.8°F) Dispersion Properties: Not available.

Critical Temperature: Not available. Solubility: Slightly soluble in hot water. Insoluble in cold water. Insoluble in
chromium trioxides, and mineral acids, alkalis. Soluble in concentrated
hydrogen fluoride and ammonium salts.

43
Revision No.: B
MATERIAL SAFETY:
Magnesium Alloy Issue Date: 25/08/2010
MHP-005 Pages: 3 of 3

Section 10: Stability and Reactivity Data


Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, incompatible materials, water or moisture, moist air.

Incompatibility with various substances: Reactive with oxidizing agents, acids, moisture

Corrosivity: Non/corrosive in presence of glass

Special Remarks on Reactivity: Violent chemical reaction with oxidizing agents. Reacts with water to create hydrogen gas and heat. Must be kept dry.

Reacts with acids to form hydrogen gas which is highly flammable and explosive. Magnesium forms hazardous or explosive mixtures with aluminium and
potassium perchlorate; ammonium nitrate; barium nitrate, barium dioxide and zinc; beryllium oxide; boron phosphodiiodide; bromobenzyl trifluoride; cadmium
cyanide; cadmium oxide; calcium carbide; carbonates; carbon tetrachloride; chlorine; chlorine trifluoride; chloroform; cobalt cyanide; copper cyanide; copper
sulphate(anhydrous), ammonium nitrate, potassium chlorate and water; cupric oxide; cupric sulphate; fluorine; gold cyanide; hydrogen and calcium carbonate;
hydrogen iodide; hydrogen peroxide; iodine; lead cyanide; mercuric oxide; mercury cyanide; methyl chloride; molybdenum trioxide; nickel cyanide; nitric acid;
nitrogen dioxide; oxygen (liquid); performic acid; phosphates; potassium chlorate; potassium perchlorate; silver nitrate; silver oxide; sodium perchlorate;
sodium peroxide; sodium peroxide and carbon dioxide; stannic oxide; sulphates; trichloroethylene; zinc cyanide; zinc oxide.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information


Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: May cause skin irritation by mechanical action. May get
mechanical injury or embedding of chips/particles in skin. The particles that are embedded in the wounds may retard healing.

Eyes: May cause eye irritation by mechanical action. Mechanical injury may occur. Particles or chips may embed in eye and retard healing.

Ingestion: Low hazard for usual industrial handling. There are no known reports of serious industrial poisonings with Magnesium. Ingestion of large amounts
of chips, turnings or ribbons may cause gastrointestinal tract irritation with nausea, vomiting, and diarrhoea. Acute ingestion may also result in Hypermagnesia.
Hypermagnesia may cause hypotension, bradycardia, CNS depression, respiratory depression, and impairment of neuromuscular transmission (hyporeflexia,
paralysis).

Inhalation: Low hazard for ususal industrial handling. It may cause respiratory tract irritation. However, it is unlikely due to physical form. When Magnesium
metal is heated during welding or smelting process, Metal Fume Fever may result from inhalation of magnesium fumes. Metal Fume Fever is a flu-like
condition consisting of fever, chills, sweating, aches, pains, cough, weakness, headache, nausea, vomiting, and breathing difficulty. Other symptoms may
include metallic taste, increased white blood cell count. There is no permanent ill-effect.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
Transport: Magnesium Alloy is considered stable under normal handling conditions. Keep clean and dry during transport.
DISCLAIMER
The information above is believed to be accurate and represents the best information currently available to NedMarine Services B.V.
However, NedMarine Services B.V. make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall NedMarine Services B.V. be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NedMarine
Services B.V. has been advised of the possibility of such damages.

44

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