Paper-2: Cumulative Test-1 (Ct-1)

CODE
CUMULATIVE TEST-1 (CT-1)

(JEE ADVANCED PATTERN) 0
PAPER-2 TARGET : JEE (ADVANCED) 2014
COURSE : VIJETA (JP) / VIJAY (JR) REVISION PLAN-II
Date ¼fnuka
d ½ : 13-04-2014 Time ¼l e;½ : 3 Hours ¼?k.Vs½ Max. Marks ¼egÙke v a
d ½ : 210
Ñ i;k bu funsZ'kksad ks/;ku l si<+saA v kid ks5 feuV fo'ks"k : i l sbl d ke d sfy , fn;sx;sgSaA
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
funsZ'k / INSTRUCTIONS :
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t k;sxkA
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i<+saA
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Please read the last page of this booklet for rest of the instructions
MATHEMATICS
PART-I MATHEMATICS
MATHEMATICS
SECTION – 1 : (One or more options correct Type)
[k.M – 1 : (,d ;k v f/kd l gh fod Yi çd kj)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE are correct.
bl [k.M esa7 cgqfod Yi ç'u gSaA çR;sd ç'u esapkj fod Yi (A),(B),(C) vkSj (D) gSa] ft uesals,d ;k vf/kd
lgh gSA
2
 –1  r 15 
1. The value of  cot   is equal to
r 1  2 8 
 
2
 –1  r 15 
 cot   cjkcj gS&
r 1  2 8 
 
(A) tan
–1
1
–1
(B) tan 2
–1
(C) cot
1 –1
(D) tan 4
 
4
–1  2 17  –1 
2. Consider the equation sin  x – 6x   + cos k = , then
 2  2
(A) the largest value of k for which equation has 2 distinct solution is 1
 1 
(B) the equation must have real root if k   – ,1
 2 
 1
(C) the equation must have real root if k   –1, 
 2
1
(D) the equation has unique solution if k = –
2
Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )
P2JP&JRCT1130414C0-1
MATHEMATICS
17 
ekukfd lehd j.k sin–1  x 2 – 6x   + cos–1 k = , rc
 
MATHEMATICS
 2  2
(A) k d k vf/kd re eku 1 gSt cfd lehd j.k d snksfofHké gy gS
A
 1 
(B) lehd j.k d sokLrfod ewy gksuspkfg, ;fn k   – ,1
 2 
 1
(C) lehd j.k d sokLrfod ewy gksuspkfg, ;fn k   –1, 
 2
1
(D) lehd j.k vf}rh; gy j[krk gS;fn k = –
2
 3
(x  1) ; x 1
3. Let f:RR is defined by f(x) =  . If f(x) is invertible, then the values of
2
ln x  (b – 3b  10) ; x  1
b is/are
 3
(x  1) ; x 1
ekukfd f:RR lsifjHkkf"kr Q y u f(x) =  2
. ;fn f(x) O;q
RØ e.kh; gS] rc b d s
ln x  (b – 3b  10) ; x  1
eku gS&
(A)1 (B) 2 (C) 5 (D) 3
MATHEMATICS
1/n 1/n
4. Let fn(x) = (sin x) + (cos x) , x  R, n  N, then
MATHEMATICS
 
(A) f2(x) > 1 for all x   2k,  4k  1  ,k
 2
(B) f2(x) = 1 for x = 2k, k
 
(C) f2(x) >f3(x) for all x   2k,  4k  1  ,k
 2
 
(D) f3(x) f5(x) for all x  2k,  4k  1  ,k
 2
(Where I denote set of integers)
ekukfd fn(x) = (sin x)1/n + (cos x)1/n , x  R, n  N, rc

 
(A) f2(x)>1 lHkh x  2k,  4k  1  ,kd sfy ,
 2
(B) f2(x) = 1 lHkh x = 2k, kd sfy ,
 
(C) f2(x)>f3(x) lHkh x  2k,  4k  1  ,kd sfy ,
 2
 
(D) f3(x)f5(x) lHkh x  2k,  4k  1  ,kd sfy ,
 2
(t gk¡I iw
.kk±d ksad sleqPp; d ksO;Dr d jrk gSA)
MATHEMATICS
2
5. Let f: R  R, f(x) = x + ln(1 + x ), then
MATHEMATICS
(A) f is injective
(B) lim f(x) = +
x– 
(C) there is a point on the graph of y =f(x) where tangent is not parallel to any of the chords
(D) f is bijective
ekukfd f: R  R, f(x) = x + ln(1 + x2), rc

(A) f ,d S
d h gSA
(B) lim f(x) = +
x– 
(C) y = f(x) d svkjs

[k ij,d fcUnqgSt gk¡Li'kZjs[kk fd lh Hkh t hok d slekUrj ughagSA
(D) f ,d S
d h vkPNknd gSA
 1  1
6. Let a function f(x), x  0 be such that f(x) + f   = f(x).f   then f(x) can be
x
  x
1 1
ekuk fd Q y u f(x), x  0 bl çd kj gSfd f(x) + f   = f(x).f   rc f(x) gksld rk gS&
x x
2013  2
(A) 1 – x (B) |x| +1 (C) (D)
–1
2 tan | x | 1  k n | x |
–1 –1 2 
7. If tan A = tan (A + ) +
is satisfied by atleast one integral value of A in [0, 2]. Then the
4
possible integral value of  can not be

;fn tan–1 A = tan–1 (A2 + ) + , [0, 2] esaA d sd e lsd e ,d iw.kk±d eku d kslarq"B d jrk gSA rc  d k
4
laHkkfor iw.kk±d eku ughagksld rs
(A) –1 (B) 1 (C) 0 (D) 2
MATHEMATICS
SECTION – 2 : (Paragraph Type)
MATHEMATICS
[k.M – 2 : (v uqPN sn çd kj)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions
relate to three paragraphs with two questions on each paragraph. Each question of a paragraph
has only one correct answer among the four choices (A), (B), (C) and (D).
bl [k.M esafl) karksa] ç;ksxksavkSj vk¡d M+ksavkfn d ksn'kkZusoky s3 v uqPN sn gSA rhuksavuqPNsnksalslacaf/kr N% ç'u
gSa] ft uesalsgj vuqPNsn ij nksç'u gSaA fd lh Hkh vuqPNsn esagj ç'u d spkj fod Yi (A), (B), (C) vkSj (D) gSa]
ft uesalsd soy ,d gh lgh gSA
Paragraph for Question Nos. 8 to 9 (iz

'u 8 l s9 d sfy , v uqPN sn)
3 2
Let f : R  R; f(x) = 2x – 3(k + 2)x + 12 kx –7, – 4  k 6, k , then
ekuk fd f : R  R; f(x) = 2x3 – 3(k + 2)x2 + 12 kx –7, – 4  k 6, k , rc
8. The number of values of k for f(x) to be invertible, is

k d sekuks
ad h la[;k ft ld sfy, f(x) O;qRØ e.kh; gS&
(A) 0 (B) 1 (C) 2 (D) 3
9. The number of integral values of k for f(x) to have three real and distinct roots, is
k d siw
.kk±d ekuksad h la[;k ft ld sfy , f(x) d srhu okLrfod vkSj fofHké ewy gS&
(A) 2 (B) 4 (C) 5 (D) 6
MATHEMATICS
Paragraph for Question Nos. 10 to 11
MATHEMATICS
(iz
x 2 (x – 1)
Let a,b,c (a < b < c) be three integers satisfying the inequality 0.
(x – 3)(x 2 – 2x  5)
2
Also f(x) = 4x –3(p +2)x + 4p
x 2 (x – 1)
ekukfd a,b,c (a < b < c) rhu iw.kk±d t ksvlfed k 0 d kslarq"B d jrk gS
(x – 3)(x 2 – 2x  5)
rFkk f(x) = 4x2 –3(p +2)x + 4p
–1 –1 –1 –1 –1
10. The value of cos (a) + sin (b) + sec (c) + cosec (b) + tan (a) is equal to
(a) d k eku cjkcj gS&
–1 –1 –1 –1 –1
cos (a) + sin (b) + sec (c) + cosec (b) + tan
11 8 13 
(A) (B) (C) (D) 2
6 6 6
11. The true set of values of p for which ‘b’ lies between the roots of the equation f(x) = 0. is
p d sekuks
ad k lgh leqPp; ft ld sfy , lehd j.k f(x) = 0 d sewy ksad se/; b fLFkr gSA
(A) (–, 2) (B) (2, ) (C) (0,1) (D) (1,2)
MATHEMATICS
MATHEMATICS
(iz
Let f(x) and g(x) be two differentiable functions, defined as

2 2
f(x) = x + xg(1) + g(2) and g(x) = f(1) x + xf (x) + f(x).
ekuk f(x) vkS

j g(x) nksvod yuh; Q y u bl çd kj ifjHkkf"kr gSfd
2 2
f(x) = x + xg(1) + g(2) vkS
j g(x) = f(1) x + xf (x) + f(x).
12. The value of f(1) + g(–1) is
f(1) + g(–1) d k eku gS&

(A) 0 (B) 1 (C) 2 (D) 3
f(x)
13. The number of integers in the domain of the function F(x) = – –  3–x
g(x)
(A) 0 (B) 1 (C) 2 (D) infinite
f(x)
Q y u F(x) = – –  3–x d sçkUr esaiw.kk±
d ksad h la[;k gS&
g(x)
(A) 0 (B) 1 (C) 2 (D) vuUr
MATHEMATICS
SECTION - 3
MATHEMATICS
Matrix - Match Type
This section contains 3 questions. Each question contains
statements given in two columns which have to be
matched. Statements in Column  are labelled as A,B,C p q r s
and D whereas statements in Column are labelled as A p q r s
p,q,r and s. The answers to these questions have to be B p q r s
appropriately bubbled as illustrated in the following C p q r s
example. p q r s
D
If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s
and D-q,then the correctly bubbled matrix will look like the
following :
[k.M - 3
eSfVªDl &l qesy izd kj
bl [k.M esa3 iz'u gSaA izR;sd iz'u esanksd kWy e esaoDRO; (statements) p q r s
fn;sgq, gSaft ud k lqesy (match) d juk gSA d kWy e (Column-I) esafn;s A p q r s
x;soDrO;ksa(A, B, C, D) d ksd kWy e (Column-II) esafn;sx;soDrO;ksa B p q r s
(p, q, r, s) lslq esy d juk gSA bu iz'uksad smÙkj fn;sx;smnkgj.k d s C p q r s
vuql kj mfpr cqYyksad ksd ky k d jd sn'kkZuk gS A D p q r s
;fn lgh lqesy A-p, A-r, B-p, B-s, C-r, C-s rFkk D-q gSa] rkslgh fof/k
lsd ky sfd , x;scqYy ksad k 4 x 4 esafVªDl (matrix) uhpsn'kkZ;k x;k gS
A
MATHEMATICS
14. Column– Column -
MATHEMATICS
–1 –1
(A) sin x + cos y=0 (p) a square
–1 –1 –1 
(B) sin x + cos y + cos (xy) = (q) a circular arc
2
–1 –1
(C) sin 2x + cos y = 0 (r) part of an ellipse
–1 2 –1 2 
(D) sin x + cos y = (s) a pair of lines
2
LrEHk– LrEHk-
(A)
–1
sin x + cos
–1
y=0 (p) ,d oxZ

(B)
–1
sin x + cos
–1
y + cos
–1
(xy) = (q) ,d oÙ̀kh; pki
2
(C)
–1 –1
sin 2x + cos y = 0 (r) ,d nh?kZ
oÙ̀kh; Hkkx
2 –1 2 
(D)
–1
sin x + cos y = (s) js[kkvksad k ;qXe
2
MATHEMATICS
15. Column –  Column – 
MATHEMATICS
(A) If two roots of x3 – ax2 + bx –  = 0 are equal in (p) –5
magnitude but opposite in signs, then ab is equal to
(B) |x – | + |x2 – 2|  0, then x is equal to (q) –
(C) The principal value of cos–1 (cos 5) is (r) 2 – 5
(D) The value of 2 (tan–1 (1) + tan–1 (2) + tan–13)) – 5 is (s) 
LrEHk–  LrEHk– 
(A) ;fn lehd j.k x3 – ax2 + bx –  = 0 d snksewy ekikad esacjkcj gSa (p) –5
y sfd u foijhr fpUg d sgSa] rksab =
(B) ;fn |x – | + |x2 – 2|  0 gks] rks x = (q) –
(C) cos–1 (cos 5) d k eq

[; eku gS& (r) 2 – 5
(D) 2 (tan–1 (1) + tan–1 (2) + tan–13)) – 5 d k eku gS& (s) 
P2JP&JRCT1130414C0-10
MATHEMATICS
16. Column –  Column -
MATHEMATICS
4 2 3
(x  1) x
(A) If f(x) = 4x  8 3  72  4 2 is defined, then x can be (p) 0
x
(B) The least positive integral value of ‘x’ satisfying (e –2) (q) 3
   
 sin  x    (x–log22)(sin x – cos x) < 0 is
  4 
(C) The number of integral values of m for which f:RR; (r) 6
x3 2
f(x)= +(m –1)x +(m +5)x + n is bijective is
3
(D) The number of roots of equation (s) 7

 (x – 1)(x – 3)  (x  1)(x  3) 
 – e x  – e  x  x 3  cos x = 0
 
 (x – 2)(x – 4)  (x  2)(x  4) 
P2JP&JRCT1130414C0-11
MATHEMATICS
LrEHk– LrEHk-
MATHEMATICS
4 2 3
(x  1) x
x
(A) ;fn f(x) = 4  83  72  4 2 ifjHkkf"kr gS] rc x gksld rk gS& (p) 0
(B) ‘x’ d k U;w

ure /kukRed iw.kk±d eku t cfd vlfed k (ex –2) (q) 3
   
 sin  x    (x–log22)(sin x – cos x) < 0 d ksla
rq"B gksrh gS&
  4 
(C) m d siw
.kk±d ekuksad h la[;k ft ld sfy , f:RR; (r) 6
x3 2
f(x)= +(m –1)x +(m +5)x + n ,d Sd h vkPNknd gS&
3
 (x – 1)(x – 3)  (x  1)(x  3) 
(D) lehd j.k – e x  – e  x  x 3  cos x = 0
  (s) 7
 (x – 2)(x – 4)  (x  2)(x  4) 
d sewy ksad h la[;k gS&
P2JP&JRCT1130414C0-12
PHYSICS
PART-II PHYSICS
PHYSICS
SECTION-1 : (One or more option correct type)
[k.M –1 : (,d ;k v f/kd l gh fod Yi çd kj)
This section contains 7 multiple choice qustions. Each question has four choices (A), (B), (C)
bl [k.M esa7 cgqfod Yi ç'u gSA çR;sd ç'u esapkj fod Yi (A), (B), (C) v kSj (D) gS] ft uesal sd soy ,d
;k v f/kd l gh gSA
17. As shown in diagram there are two fixed uniformly charge concentric coplanar conducting rings
having radius 'R' and 4R and charges '+Q' and '–8Q' respectively. A charge particle of mass 'm' &
charge '–q' is projected along the axis of rings from point 'P' so that particle can just reach the
centre of rings (point 'O'). (Assume Qq > 0.)
–8Q
+Q
Vmin –q, m
R
O
P
4R 3R
(A) required minimum velocity is zero

(B) speed of particle at the position ‘O’ will be non zero
(C) particle perform oscillatory motion about ‘O’
(D) particle will not perform oscillatory motion about ‘O’
fp=kkuql kj nkslad sUnzh;] lery h; fLFkj pky d oy ; ft ud h f=kT;k,a'R' rFkk 4R gSrFkk bu ij vkos'k Ø e'k%
'+Q' o '–8Q' gS A fcUnq'P' lsd .k ¼nzO;eku 'm' o vkos'k '–q') d ksoy ;ksad h v{k d svuqfn'k U;wure osx bl
izd kj fn;k t krk gS] fd ft lls;g oy ;ksad sd sUnz(fcUnq'O') ij flQ Zigqap ld sA (ekfu;sQq > 0 gSA)
(A) vko';d U;w ure osx 'kwU; gSA
(B) fLFkfr ‘O’ ij d .k d h pk Space
y v'kwU;forgksxRough
hA Work / (d Ppsd k;Zd sfy , LFkku )
(C) d .k ‘O’ d slkis {k nksy u xfr d jsxkA
(D) d .k ‘O’ d slkis {k nksy u xfr ughad jsxkA
Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)
P2JP&JRCT1130414C0-13
PHYSICS
18. In a liquid, a glass prism is immersed. The curves showing the refractive index n as a function of
PHYSICS
wavelength  for glass and liquid are as given in the figure. When white light is incident on the
prism parallel to the base then :
(A) Blue ray is deviated towards vertex (B) Red ray is deviated towards base
(C) Yellow ray travels without deviation (D) there is no dispersion
nzo esa, ,d d k¡p d k fçTe Mwck gqv k gSA d k¡p o nzo d sfy , viorZukad n d ksrjaxnS/;Z d sQ y u d soØ d ks
fp=k esan'kkZ;k x;k gSA t c fçTe d svk/kkj d slekUrj lQ sn çd k'k vkifrr gksrk gSA rc :
(A) uhy k çd k'k 'kh"kZd h vks

j fopfy r gksxkA (B) y ky çd 'k vk/kkj d h vksj fopfy r gksxkA
(C) ihy k çd k'k fcuk fopy u d sfud y t k;sxkA (D) ;gk¡d ks

bZfo{ksi.k ughagksxkA
P2JP&JRCT1130414C0-14
PHYSICS
19. W hen a dipole is placed inside a cavity in a solid neutral conducting body :
PHYSICS
(A) No charges are induced on the inner surface of cavity
(B) No charges are induced on the outer surface of conducting body
(C) Ever ywhere outside the body electric field due to dipole is zero
(D) Ever ywhere outside the body net electric field is zero
t c Bksl mnklhu lqp kyd oLrqd h xqgk d svUnj ,d f}/kzqo j[krsgSarks&
(A) xq
gk d h vkUrfjd lrg ij d ksbZvkos'k izsfjr ughagksrk gS A
(B) xq
gk d h ckgjh lrg ij d ks
bZvkos'k izsfjr ughagksrk gS A
(C) oLrqd sckgj lHkh t xg ij f}/kz
qo d sd kj.k fo|qr {ks=k 'kwU; gSA
(D) oLrqd sckgj lHkh t xg ij ifj.kkeh fo|q r {ks=k 'kwU; gSA
20. An uncharged conducting sphere of radius R is placed near a uniformly charge ring
of radius R. Total charge on ring is Q. The centre of sphere lies on axis of ring and
distance of centre of sphere form centre of ring is R.
R
KQ
(A) Potential at centre of ring is
R
KQ
(B) Potential at centre of ring is
2R
(C) Potential at centre of ring due to conducting sphere is zero
KQ
(D) Potential at centreSpace for Rough
of conducting Work is
sphere / (d Ppsd k;Zd sfy , LFkku )
2R
R f=kT;k d k vukos f'kr pkyd xksy k] R f=kT;k d h ,d leku vkos f'kr oy ; d slehi fp=kkuql kj j[kk gqv k gS
A
oy ; ij d qy vkos'k Q gSA xksy sd k d sUnzoy ; d h v{k ij fLFkr gSrFkk xksy sd sd sUnzd h oy ; d sd sUnzls
nwjh R gSA
KQ
(A) oy ; d sd s Unzij foHko gSA
R
KQ
(B) oy ; d sd s Unzij foHko gSA
2R
(C) oy ; d sd s Unzij pky d xksy sd sd kj.k foHko 'kwU; gSA
KQ
(D) xksy sd sd sUnzij foHko gS
A
2R
P2JP&JRCT1130414C0-15
PHYSICS
21. A solid spherical planet of mass 3m and radius 'R' has a very small tunnel along its diameter. A
PHYSICS
small cosmic particle of mass 2m is at a distance 2R from the centre of the planet as shown. Both
are initially at rest, and due to gravitational attraction, both start moving toward each other. After
some time, the cosmic particle passes through the centre of the planet.
(Assume the planet and the cosmic particle are isolated from other planets)
,d Bksl xksy h; xzg ft ld k nzO;eku 3m o f=kT;k 'R' gS] esaO;kl d svuqfn'k ,d NksVh lqjax gSA n'kkZ;suql kj
xzg d sd sUnzls2R nwjh ij nzO;eku 2m d k ,d NksVk vkd k'kh; d .k fLFkr gSA nksauksgh çkjEHk esafLFkj gSo
xq: Rokd "kZ.k d sd kj.k nksuksa,d &nwl jsd h vksj xfr 'kq: d jrsgSA d qN le; i'pkr~vkd k'kh; d .k xzg d s
d sUnzlsxqt jrk gSA (eku y hft , fd xz g o vkd k'kh; d .k vU; xzgksalsfoy fxr gS)
(A) Displacement of the cosmic particle till that instant is 1.2R
(B) Acceleration of the cosmic particle at that instant is zero

8Gm
(C) velocity of the cosmic particle at that instant is
3R
6Gm2
(D) Total work done by the gravitational force on both the particle till that moment is 
R
(A) bl {k.k rd vkd k'kh; d .k d k foLFkkiu 1.2 R gSA
(B) bl {k.k ij vkd k'kh; d .k d k Roj.k 'kwU; gSA
8Gm Work / (d Ppsd k;Zd sfy ,

Space for Rough LFkku )
(C) bl {k.k rd vkd k'kh; d .k d k osx gSA
3R
6Gm2
(D) xq
: Roh; cy }kjk nksuksad .kksaij fd ;k x;k d qy d k;Z  gSA
R
P2JP&JRCT1130414C0-16
PHYSICS
22. A spring mass system is in equilibrium in a uniform electric field E as shown in figure. If suddenly
PHYSICS
electric field is switched off then :
K E
m, q
qE
(A) Spring mass system performs SHM with amplitude
K
(B) Time period of SHM depends on value of E
qE
(C) If m  then instantaneous potential energy stored in spring will never be equal to zero
g
qE
(D) Maximum speed of the block during motion is
mK
,d fLizax nzO;eku fud k; fp=k esan'kkZ;svuql kj ,d leku oS| qr {kS=k E esalkE;koLFkk esagSA ;fn vpkud
oS| qr {kS=k cUn fd ;k t krk gS:
qE
(A) fLiazx nzO;eku fud k; vk;ke lsljy vkoÙkZxfr d jsxkA
K
(B) ljy vkoÙkZxfr d k vkoÙkZd ky E d seku ij fuHkZj d js
xkA
qE
(C) ;fn m  gS] rc fLiazx esalafpr rkR{kf.kd fLFkfrt Å t kZd Hkh Hkh 'kwU; ughagksxhA
g
qE
(D) xfr d snksjku Cy kWd d h vf/kd re pky gSA
mK
P2JP&JRCT1130414C0-17
PHYSICS
23. An artificial satellite is moving in a circular orbit around the earth with a speed equal to half the
PHYSICS
magnitude of escape velocity from the earth surface. Which of the following Options is/are correct :
(assume radius of the earth R = 6400 km, g at the earth surface is 10ms–2, neglect the air resistance)
(A) Height of the satellite above the earth is 6400 km
(B) If satellite is suddenly stopped in its orbit and allowed to fall freely into the earth. Then it hit the
earth surface with 8 km/s.
(C) If satellite is suddenly stopped in its orbit and allowed to fall freely into the earth. Then during
its fall total mechanical energy of satellite, in the gravitational field of the earth, remains
constant.
(D) If satellite is suddenly stopped in its orbit and allowed to fall freely into the earth. At the given
instant its acceleration is 5 m/s2
,d d f̀=ke mixzg iF̀oh d spkjksvks
j oÙ̀kkd kj d {kk esaiF̀oh d h lrg ij iy k;u osx d sifjek.k d h vk/kh pky
lspDd j y xk jgk gSA fuEu esalsd kSulk@d kSulsd Fku lgh gSA (ekfu;siF̀oh d h f=kT;k R = 6400 km, iF̀Okh
d h lrg ij g = 10ms–2, ok;qizfrjks/k ux.; gSA)
(A) iF̀oh d h lrg lsmixzg d h Å pk¡bZ6400 km gSA
(B) ;fn mixzg mld h d {kk esavpkud : d t krk gS] rFkk iF̀oh ij eqDr : i lsfxjrk gSA rc ;g iF̀oh d h
lrg ij 8 km/s d h pky lsVDd jk;sxkA
(C) ;fn mixzg mld h d {kk esavpkud : d t krk gS] rFkk iF̀oh ij eqDr : i lsfxjrk gS
A rc mixzg d sfxjus
d snksjku iF̀oh d sxq: Roh; {kS=k esamld h d qy ;kaf=kd Å t kZfu;r jgrh gSA
(D) ;fn mixzg mld h d {kk esavpkud : d t krk gS] rFkk iF̀oh ij eqDr : i lsfxjrk gSA rc fn;sx;s{k.k
ij mld k Roj.k 5 m/s2 gSA
P2JP&JRCT1130414C0-18
PHYSICS
PHYSICS
relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has
only one correct answer among the four choices (A), (B), (C) and (D).
bl [k.M esafl) karksa] ç;ksxksavkSj vk¡d M+ksavkfn d ksn'kkZusoky s3 v uqPN sn gSA pkjksavuqPNsnksalslacaf/kr N % ç'u
ft uesalsd soy ,d gh l gh gS
A
Paragraph for Questions 24 and 25

iz'u 24 v kSj 25 d sfy , vuqPNsn
In the figure shown there are two fixed spheres A and B each of radius r carr ying
uniform charges Q and 4Q. They are separated by distance 6r. A charged particle of
charge –q and mass m is projected radially towards sphere B from surface of sphere
A. Neglect gravitational interaction between spheres and particle.
fn;sx;sfp=k es anksfLFkj xks
y sA rFkk B izR;sd d h f=kT;k r gSrFkk mu ij vkos 'k Ø e'k% Q rFkk 4Q gS A xks
a y ks
ad s
e/; nwjh 6r gS
A ,d vkos
a f'kr d .k ft ld k vkos'k –q rFkk nzO;eku m gSd ksf=kT; fn'kk es axksy sB d h vks
j] xksy sA
d h lrg ls'u' pky lsfp=kkuq l kj Q s
d k x;k gS
a A xksy ks
arFkk d .k d se/; xq
: Rokd "kZ
.k d ksux.; ekfu;s A
Q,r 4 Q,r
A –q,m B
u
6r
P2JP&JRCT1130414C0-19
PHYSICS
24. The minimum energy of charge –q. On the surface of sphere A so that it lands on
PHYSICS
sphere B.
3KQ.q
(A) zero (B)
10r
3KQ.q 3KQq
(C) (D)
10r 2r
–q vkos'k d h U;wure Å t kZD;k gksrkfd ;g A xksy sd h lrg lsB xksy sd h lrg ij igq¡
p ld sA
3KQ.q
(A) 'kwU; (B)
10r
3KQ.q 3KQq
(C) (D)
10r 2r
25. The kinetic energy of charge (–q). Just before hitting on sphere B.
xksy sB lsVDd jkusd sBhd igy s(–q) vkos'k d h xfrt Å t kZD;k gksxhA
27KQq 17KQq
(A) (B)
10r 10r
13KQq 3KQq
(C) (D)
12r 2r
P2JP&JRCT1130414C0-20
PHYSICS
PHYSICS
A system of two fixed charges A and B at the position (a0, 0) and (–a0, 0) is shown in figure.
Assume that potential at the infinite distance, from the given system is zero, and system is isolated
from any other charges and other electric field.
B A
O
(–a, 0) origin q (a,0)
–4q
(a0, 0) rFkk(–a0, 0) ij
fLFkr nkst M+or vkos'k A o B d k fud k; fp=k esan'kkZ;k x;k gSA ekfu;sd h fn;sx;s
fud k; lsvUur nwjh ij foHko 'kwU; gS] rFkk fud k; vU; vkos
'kksao vU; oS| qr {kS=k lsfoyfxr gSA
B A
ewy fcUnq O
(–a, 0) q (a,0)
–4q (origin)
P2JP&JRCT1130414C0-21
PHYSICS
26. The best representation of magnitude of potential v/s x coordinate is :
PHYSICS
foHko d sifjek.k v/s x funsZ'kka
d d se/; vkjs[k d k lclslgh izn'kZu gS:
V
(A)
V=0
B origin 3a0 A x
,0 5a0
(–a, 0) 5 (a, 0) ,0
3
V
(B)
V=0
B origin 3a0 A x
–5a0 ,0 7a0
,0 (–a, 0) (a, 0) ,0
5 A
3 3
V
(C)
V=0
B origin 3a0 A x
–5a0
(–a, 0) ,0 (a, 0)
,0 5
3 A
Space for Rough VWork / (d Ppsd k;Zd sfy , LFkku )
(D)
V=0
B – 3a0 origin A 5a0 x
(–a0, 0) ,0 (a0, 0) ,0
5 A 3
P2JP&JRCT1130414C0-22
PHYSICS
27. If charge particle of mass 'm' and charge 'q0' is projected from origin with 0.6 v0 î + 0.8 v0 ĵ then the
PHYSICS
radius of curvature at the given instant :
40 m(v 0 a)2 0m(v 0 a0 )2 640m(v 0 a)2
(A) (B) (C) (D) Infinite
3qq0 qq0 125qq0
;fn 'm' nzO;eku rFkk 'q ' vkos'k d ksewy fcUnqls0.6 v
0 0
î + 0.8 v0 ĵ osx lsiz{ksfir fn;k t krk gSA
fn;sx;s{k.k ij d .k d sekxZoØ rk f=kT;k gksxh :
40 m(v 0 a)2 0m(v 0 a0 )2 640m(v 0 a)2
(A) (B) (C) (D) vuUr
3qq0 qq0 125qq0

The component of electric field in the direction say  is E  which is related with the
dV
electric potential V as E  = – . The minus sign implies that E  points in the
d
direction of decreasing V.
dV
fd lh  fn'kk esaoS| qr {kS=k d k ?kVd E  gSt ksoS| qr foHko V lslEcU/k E  = – }kjk lEcfU/kr gSA
d
_ .kkRed fpUg n'kkZrk gS] fd E  d h fn'kk esafoHko V ?kVrk gSA
P2JP&JRCT1130414C0-23
PHYSICS
28. Select the incorrect statement :
PHYSICS
(A) x, y and z components of electric field are given as
V V V
Ex = – , Ey = – and E z = – respectively.
x y z
(B) The direction  for which E  is maximum lies along the equipotential surface.
(C) The values of E in the direction for which eletric potential has constant value is zero
(D) Electric potential decreases in the direction of electric field.
v l R; d Fku d k p;u d hft , :

V V V
(A) oS
| qr {kS+=k d sx, y rFkkz ?kVd Ø e'k% Ex = – , Ey = – rFkkEz = – d s: i esafn;sx;sgSA
x y z
(B) d h fn'kk] ft ld sfy , E  vf/kd re gS] lefoHko lrg d svuqfn'k gSA
(C) ml fn'kk es aft ld sfy , oS| qr foHko fu;r eku j[krk gS
] mld sfy , E  d k eku 'kwU; gSA
(D) oS
| qr {kS=k d h fn'kk esaoS| q
r foHko ?kVrk t krk gS
A
29. If V = by 3 / 2 where b is a positive constant then

;fn V = by 3 / 2 gS] t gk¡b ,d /kukRed fu;rkad gS] rc
 3
(A) E = – b y ˆj
2
 3
(B) E = b y ˆj
2
 3
(C) E = b y ĵ
2
 3
(D) E = b y ĵ
2
P2JP&JRCT1130414C0-24
PHYSICS
PHYSICS
SECTION-3 : (Matrix - Match Type)
[k.M –3 : (eSfVªDl &l qesy izd kj)
This section contains 3 question. Each question contains p q r s
statements given in two columns which have to be matched. A p q r s
Statements in Column  are labelled as A,B,C and D whereas B p q r s
statements in Column are labelled as p,q,r and s. The C p q r s
answers to these questions have to be appropriately bubbled as D p q r s
illustrated in the following example. If the correct matches are
A-p , A-r , B-p , B-s , C-r , C-s and D-q ,
then the correctly bubbled matrix will look like the following :
bl [k.M esa3 iz'u gSaA izR;sd iz'u esanksd kWy e esaoDRO; (statements) fn;sgq, gSa p q r s
ft ud k lqesy (match) d juk gSA d kWy e (Column-I) esa fn;s x;s oDrO;ksa
A p q r s
(A, B, C, D) d ksd kW y e (Column-II) esafn;sx;soDrO;ksa(p, q, r, s) ls B p q r s
lqesy d juk gSA bu iz'uksad smÙkj fn;sx;smnkgj.k d svuql kj mfpr cqYy ksad ks C p q r s
d ky k d jd sn'kkZuk gSA ;fn lgh lqesy A-p, A-r, B-p, B-s, C-r, C-s rFkk D-q D p q r s
gSa] rkslgh fof/k lsd ky sfd , x;scqYy ksad k 4 x 4 esafVªDl (matrix) uhpsn'kkZ;k
x;k gSA
P2JP&JRCT1130414C0-25
PHYSICS
30. Figure shows a conducting sphere with a cavity. A point charge q1, is placed inside cavity, and q2 is
PHYSICS
 
placed out side the sphere. Ein is electric field due to charge induced on surface of cavity. Eout is

electric field due to charge induced on outer surface of sphere and Enet is net field at any point.
Two closed gaussian surface S1 & S2 are also drawn in the figure.
S2
q2
q1
S1
Column (I) Column (II)

  –q1
(A)  Ein .da for surface S1 (p)
0
  q1  q2
(B)  Eout .da for surface S2 (q)
0
 
(C) E net .da for surface S1 (r) zero
  q1
(D)  E net .da for surface S2 (s)
0
P2JP&JRCT1130414C0-26
PHYSICS
fp=k esa,d pky d xksy k xqgk d slkFk n'kkZ;k x;k gSA ,d fcUnqvkos'k q1 xq gk d svUnj j[kk gqv k gS] rFkk q2
PHYSICS

xksy sd sckgj fLFkr gS A xqgk d h lrg ij izsfjr vkos'k d sd kj.k oS| qr {kS=k Ein gSA xksy sd h ckg~; lrg ij
 
izsfjr vkos'k d s d kj.k oS| qr {kS=k Eout gS] rFkk fd lh fcUnq ij d qy oS| qr {kS=k Enet gSA fp=k esa nks cUn
xkmfl;u lrg S1 o S2 Hkh n'kkZbZxbZgSA
S2
q2
q1
S1
d kWy e - I d kWy e - II
  –q1
(A) lrg S1 d sfy ,  Ein .da (p)
0
  q1  q2
(B) lrg S2 d sfy , E out .da (q)
0
 
(C) lrg S1 d sfy,  E net .da (r) 'kw
U;
  q1
(D) lrg S2 d sfy, E net .da (s)
0
P2JP&JRCT1130414C0-27
PHYSICS
31. A satellite revolves around a planet, in a certain orbit of radius r0. If V0, K0, T0, P0, E0, B0 and L0
PHYSICS
represent physical quantities as given below then match the entries of Column I & Column II for
increasing radius of orbit.
V0 – orbital velocity
T0 – Time period
K0 – Kinetic Energy of Satellite.
P0 – Potential Energy of Satellite.
E0 – Total Energy of Satellite.
B0 – Binding Energy of Satellite
L0 – Angular Momentum of Satellite about the centre of planet.
Column (I) Column (II)
(A) V0K0 (p) Increase
(B) B0L0 (q) Decrease
(C) P0E0L0 4
(r) Independent of r
T0
(D) 3 (s) Proportional to r –3/2
L0
,d mixzg xzg d spkjksavks j r0 f=kT;k d h oÙ̀kkd kj d {kk esapDd j y xk jgk gSA ;fn V0, K0, T0, P0, E0, B0 rFkk
L0 uhpsnh xbZHkkS frd jkf'k;ksad ksiznf'kZr d jrk gSA rc d kWy e-I d k d kWy e-II d slkFk d {kh; f=kT;k d sc<+usd s
fy , feyku d hft ,A
V0 – d f{k; os x
T0 – vkoÙkZd ky
K0 – mixz g d h xfrt Å t kZ
P0 – mixz g d h fLFkfrt Å t kZ
E0 – mixz g d h d qy Å t kZ
B0 – mixz g d h cU/ku Å t kZ
L0 – xz g d sd sUnzd slkis{k mixzg d k d ks.kh; laosxA
d kWy e - I d kWy e - II
(A) V0K0 Space for Rough (p) c<+ Rkk gSA/ (d Ppsd k;Zd sfy , LFkku )
Work
(B) B0L0 (q) ?kVrk gS A
(C) P0E0L0 4
(r) r ij fuHkZ j ughad jrk gSA
T0
(D) (s) r –3/2 d slekuqikrh gSA
L30
P2JP&JRCT1130414C0-28
PHYSICS
32. Match the Column if deviation in the Column–II is the magnitude of total deviation (between
PHYSICS
incident ray and finally refracted or reflected ray) to lie between 0º and 180º. Here n represents
refractive index of medium.
Column–I Column–II
(A) (p) deviation in the light ray is greater than 90º
(B) (q) deviation in the light ray is less than 90º
(C) (r) deviation in the light ray is equal to 90°
(D) (s) speed of finally reflected or refracted light is

same as speed of incident light.
P2JP&JRCT1130414C0-29
PHYSICS
d kWy e d k fey ku d hft , ;fn d kWy e–II esafopy u d qy fopyu d k ifjek.k gSt ksfd vkifrr fd j.k rFkk varr%
PHYSICS
viofrZr ;k ijkofrZr çd k'k fd j.k d se/; fy ;k x;k gSA ;g 0º rFkk 180º d schp gSA ;gk¡n ek/;e d s
viorZukad d ksn'kkZrk gSA
d kWy e–I d kWy e–II
(A) (p) çd k'k fd j.k d k fopy u 90º lsvf/kd gksxkA
(B) vUrjki`"B (q) çd k'k fd j.k d k fopy u 90º lsd e gksxkA
vUrjki`"B
(C) (r) çd k'k fd j.k d k fopy u 90º gksxkA
(D) Space for Rough Work (drr%

(s) /vU Ppsijk
d kof
;Z
rZrd svFk
fy ,okLFk
ku rZ
viof)r çd k'k fd j.k d h pky
vkifrr çd k'k fd j.k d h pky d sleku gksxhA
P2JP&JRCT1130414C0-30
CHEMISTRY
PART : III CHEMISTRY
CHEMSITRY
SECTION – 1 : (One or more options correct Type)
[k.M – 1 : (,d ;k v f/kd l gh fod Yi çd kj)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C)
bl [k.M esa7 cgqfod Yi ç'u gSaA çR;sd ç'u esapkj fod Yi (A), (B), (C) vkSj (D) gSa] ft uesals,d ;k
v f/kd lgh gSA
33. Which of the following statements is correct :

(A) 0.2 moles of KMnO4 will oxidise one mole of ferrous ions to ferric ions in acidic medium.
(B) 1.5 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon
dioxide in acidic medium.
(C) 0.6 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon
dioxide in acidic medium.
(D) 1 mole of K2Cr2O7 will oxidise 2 moles of ferrous oxalate to ferric ions and carbon dioxide in
acidic medium.
fuEu esalsd kSulk d Fku lgh gS%
(A) KMnO4 d s0.2 eks y vEy h; ek/;e esa,d eksy Q sjl vk;u d ksQ sfjd vk;u esavkWDlhd r̀ d jrsgSA
(B) KMnO4 d s1.5 eks y vEy h; ek/;e esa1 eksy Q sjl vkWDlsy sV d ksQ sfjd vk;u rFkk d kcZuMkbZv kWDlkbM esa
vkWDlhd r̀ d jrsgaSA
(C) KMnO4 d s0.6 eks y vEy h; ek/;e esa1 eksy Q sjl vkWDlsy sV d ksQ sfjd vk;u rFkk d kcZuMkbZv kWDlkbM esa
(D) K2Cr2O7 d s1 eks y vEy h; ek/;e esa2 eksy Q sjl vkWDlhy sV d ksQ sfjd vk;u rFkk d kcZuMkbZv kWDlkbM esa
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CHEMISTRY
34. Which of the following is/are correct :
(A) [H+] = [OH–] = K w for a neutral solution at all temperatures
CHEMSITRY
(B) [H+] = [OH–] = 10–7 for a neutral solution at all temperatures
(C) [H+] > K w and [OH–] < K w for an acidic solution
(D) [H+] < K w and [OH–] > K w for an alkaline solution
fuEu esalsd kSuls@ d kSulk lgh gS@ gSa&

(A) lHkh rki ij mnklhu foy;u d sfy , [H+] = [OH–] = K w
(B) lHkh rki ij mnklhu foy;u d sfy , [H+] = [OH–] = 10–7 M
(C) vEy h; foy ;u d sfy , [H+] > K w rFkk [OH–] < Kw
(D) {kkjh; foy ;u d sfy , [H+] < K w rFkk [OH–] > K w
35. Precentage ionisation of weak acid can be calculated using the formula:
nqcZy vEy d svk;uu çfr'kr d ksfd l lw=k d s}kjk ekfir d j ld rsgS\
Ka 100
(A) 100 (B)
C 1  10(pK a pH)
(C) 100 K a C (D) 100  pK a  logc 
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CHEMISTRY
36. Which of the following facts is true ?
(A) If Eº (Mn+ / M) is negative, H+ will be reduced to H2 by the metal M
CHEMSITRY
(B) If Eº (Mn+ / M) is positive, Mn+ will be reduced to M by H2
(C) In a cell Mn+ / M electrode is attached to hydrogen-half cell. To produce spontaneous cell
reaction, metal M will act as negative electrode.
(D) Compounds of active metals (Zn, Na, Mg) are reducible by H2 whereas those of noble metals
(Cu, Ag, Au) are not reducible.
fuEufy f[kr esalsd kSulk rF; lR; gS\

(A) ;fn Eº (Mn+ / M) _ .kkRed gSrc /kkrqM }kjkH+ vk;u]H2 es avipf;r gksaxsA
(B) ;fn Eº (M / M) /kukRed gSrc H2 }kjkM ,M es
n+ n+
avipf;r gksxsA
(C) ,d ls y esaMn+ / M by SDVªkWM gkbMªkst u v) Zl sy lsla;ksft r gSA Lor% vfHkfØ ;k mRiUu d jkusd sfy , /kkrq
M, _ .kkRed by S DVªkWM d sleku O;ogkj d jsxkA
(D) lfØ ; /kkrq v ksa(Zn, Na, Mg) d s;kSfxd H2 }kjk vipf;r gksld rsgSt cfd mRÑ "V /kkrqv ksa(Cu, Ag, Au)
d s;kSfxd vipf;r ugh gksrsgS A
37. Indicate the correct statements :

(A) conductivity cells have cell constant values independent of the solution filled into the cell
(B) DC (direct current) is not used for measuring the resistance of a solution.
(C) Kohlrausch law is not valid both for strong and weak electrolytes.
(D) The k decreases but M and E increase on dilution.
l gh oDrO; d ksbafxr d hft , &
(A) p ky d rk l s
y d sfy , l sy fu;rkad eku l sy esaHkjsgq, foy ;u ij fuHkZj ughad jrk gSA
(B) ,d foy ;u es a fn"V /kkjk (D.C. current) d k m i;ksx izfrjks/k d s ekiu esa ugha fd ;k x;k
gSA
(C) d kW
y jkÅ 'k fu;e izcy rFkk nqcZy fo| qr v i?kV~; nksu ksad sfy , ekU; ughagSA
(D) ruq r k ij k ?kVsx k] fd UrqM rFkk E c<+r sgSaA
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CHEMISTRY
38. Which of the following pairs will form a buffer solution
(A) NaHCO3 + HCl (1 : 1 mole ratio)
CHEMSITRY
(B) CH3COOH + CH3COONa (1 : 1 mole ratio)
(C) Na2HPO4 + Na3PO4 (1 : 1 mole ratio)
(D) H3PO4 + NaH2PO4 (1 : 1 mole ratio)
fuEu esad kSu l k ;qXe cQ j foy ;u cukrk gSA

(A) NaHCO3 + HCl (1 : 1 eks y v uqikr )
(B) CH3COOH + CH3COONa (1 : 1 eks y v uqikr )
(C) Na2HPO4 + Na3PO4 (1 : 1 eks y v uqikr )
(D) H3PO4 + NaH2PO4 (1 : 1 eks y v uqikr )
39. Choose the correct statement(s)

(A) pH + pOH = pkW is applicable for dilute acid and dilute base aqueous solution as well as for
pure water.
(B) The appropriate indicator for an acid base titration should have its indicator constant (pKln)
equal to or nearly equal to the pH at equivalence point.
(C) No chemical reaction takes place when 0.1 mol of H3PO4 and 0.1 mol of Na2HPO4 is mixed in
enough water to form 1 L solution.
(D) Relative acidic strength of HCl, HClO4, HBr and HI can not be determined in water.
lgh d Fkuksad k p;u d hft ,A
(A) pH + pOH = pkW ruqvEy rFkk ruq{kkj d slkFk lkFk 'kq ) t y d sfy , Hkh iz;qDr fd ;k t krk gSA
(B) ,d vEy ] {kkj vuq ekiu d sfy , iz;qDr] mi;qDr lqp d d sfy , bld k lwp d fu;rkad (pKIn) rqY;kad fcUnq
ij pH d scjkcj vFkok y xHkx cjkcj gksuk pkfg;sA
(C) t c H3PO4 d s0.1 eks y rFkk Na2HPO4 d s0.1 eksy d ksi;kZIr t y esa1 L foy ;u cukusd sfy , fey k;k
t krk gSA rc fd lh iz
d kj d h jklk;fud vfHkfØ ;k lEiUu ughagksrh gSA
(D) HCl, HClO4, HBr rFkk HI d h vkis f{kd vEy lkeF;Zrk d kst y esafu/kkZfjr ughafd ;k t k ld rk gSA
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CHEMISTRY

CHEMSITRY
relate to three paragraphs with two questions on each paragraph. Each question of a paragraph
has only one correct answer among the four choices (A), (B), (C) and (D).
bl [k.M esafl) karksa] ç;ksxksavkSj vk¡d M+ksavkfn d ksn'kkZusoky s3 v uqPN sn gSA pkjksavuqPNsnksalslacaf/kr N % ç'u
ft uesalsd soy ,d gh l gh gS
A

iz'u 40 l s41 d sfy , v uqPN s
n
Concentration of H2O2 aqueous solution may be expressed in various concentration terms. One
useful method for expressing the concentration of H2O2 solution is volume strength.
Hydrogen peroxide solution (20 ml) reacts quantitatively with a solution of KMnO4 (20 ml)
acidified with dil. H2SO4. The same volume of the KMnO4 solution is just decolourised by 10 ml of
MnSO4 in neutral medium simultaneously forming a dark brown ppt. of hydrated MnO2. The brown
ppt. of MnO2 is dissolved in 10 ml of 0.2 M sodium oxalate under boiling condition in the presence
of dil H2SO4.
H2 O 2 t y h; foy ;u d h lkUnz rk fofHkUu lkUnzrk inksaesaO;Dr d jrsgSA H2O2 foy ;u d h lkUnzrk d ksO;Dr
d jusd sfy , ,d mi;ksxh fof/k vk;ru lkeF;ZgS A
gkbMªkst u ijvkWDlkbM foy ;u (20 ml) ruq-H2SO4 lsvEy hÑ r KMnO4 (20 ml) foy ;u d slkFk
ek=kkRed : i lsfØ ;k d jrk gSA KMnO4 d k leku vk;ru mnklhu ek/;e esas10 ml MnSO4 esafojat hÑ r
fd ;k t krk gSlkFk gh t y ;ksft r MnO2 d k ,d xgjk Hkwjk vo{ksi curk gSA MnO2 d k Hkw
jk vo{ksi ruqH2SO4
d h mifLFkfr esa0.2 M lksfM;e vkWDlsy sV d s10 ml esamcky usij ?kqy t krk gSA
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CHEMISTRY
40. Molarity of KMnO4 used for titration of H2O2 is :
H2O2 d svuq
ekiu d sfy , iz;qDr KMnO4 d h eksy jrk gS%
CHEMSITRY
 (A) 0.02 M  (B) 0.04 M  (C) 0.06 M  (D) 0.08 M

41. Volume strength of H2O2 solution is :
H2O2 foy ;u d k vk;ru lkeF;ZgS%
 (A) 1.12 (B) 2.24  (C) 11.2 (D) 5.6

iz'u 42 l s43 d sfy , v uqPN sn
During the electrolysis of 1L of dilute aq. solution of NaCl using Pt electrodes for 10 minutes, 224
ml of Cl2 is liberated with 56 ml of O2 at STP.
(Given that : log 2 = 0.3, log 3 = 0.48)
10 feuV d sfy ,] Pt by SDVªkWM iz;qDr d jrsgq, STP ij]NaCl d s1 y hVj ruqt y h; foy ;u d soS| qr vi?kV~u
d snkSjku] O2 d s56 ml d slkFk] Cl2 d k224 ml, eqDr gksrk gS
A
(fn;k gS%log 2 = 0.3, log 3 = 0.48)
42. Calcualte pH of resulting solution at STP.

STP ij ifj.kkeh foy ;u d spH d h x.kuk d hft ;s\
(A) 1.7 (B) 12.3 (C) 2.5 (D) 11.5
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CHEMISTRY
43. If the above solution after electrolysis is mixed with 10L of a buffer solution containing 0.1 mole
each of CH3COOH and CH3COONa. Calculate pH of resulting solution pKa (CH3COOH) = 4.7
CHEMSITRY
;fn oS| qr vi?kVu d si'pkr~mDr foy ;u d ks] CH3COOH rFkkCH3COONa çR;sd d s0.1 eksy ;qDr] ,d
cQ j foy ;u d s10 y hVj vk;ru d slkFk fefJr fd ;k t krk gSrc çkIr ifj.kkeh foy ;u d spH d h x.kuk
d hft ,A pKa (CH3COOH) = 4.7
(A) 4.52 (B) 4.7 (C) 2.5 (D) 4.88

iz'u 44 l s45 d sfy , v uqPN sn
An aqueous solution of H2A (weak diprotic acid) is titrated with highly concentrated solution of
NaOH. Initially 100 ml 0.12 M H2A was given. Assume change in volume on adding NaOH is
negligible and temperature remains constant during the experiment.
Given : H2A (aq.) H+ (aq.) + HA— (aq) ; K1 = 4 × 10–4
HA (aq.)
—
H (aq.) + A (aq)
+ 2—
; K2 = 5 × 10–8
At any time H2A, HA– and A2– exist in solution. Answer the following questions with valid
approximate.
H2A (nq
cZy f}çksfVd vEy ) d s,d t y h; foy ;u] d ksNaOH d s,d vf/kd lkanzfoy ;u d slkFk vuqekfir
fd ;k x;kA çkjEHk esa0.12 M H2A d k 100 ml foy ;u fn;k x;k gSA ekuk fd ] ç;ksx d snkSjku fey k;sx;s
NaOH d sd kj.k] vk;ru es aifjorZu ux.; gSrFkk rkieku fu;r cuk jgrk gSA
fn;k gS% H2A (aq.) H+ (aq.) + HA— (aq) ; K1 = 4 × 10–4
HA— (aq.) H+ (aq.) + A2— (aq) ; K2 = 5 × 10–8
fd lh Hkh le; foy ;u esa]H2A, HA– rFkkA2– vfLrRo j[krsgSaA rc ekU;] lfUud V fof/k(approximate) y sd j]
fuEu ç'uksad smÙkj nhft ;s\
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CHEMISTRY
44. Which of the following is correct
CHEMSITRY
(A) NaOH react with H2A & HA– simultaneously.
(B) Degree of ionisation of H2A after adding 4 m.moles of given NaOH is 0.01
(C) pH of solution after adding 3 m.moles of given NaOH is 3.48
(D) pOH of solution after adding 12 m.moles of given NaOH is 9.35.
fuEu esalsd kSulk d Fku lgh gS\
(A) NaOH, H2A rFkkHA– nks

uksad slkFk] ,d lkFk vfHkfØ ;k d jrk gSA
(B) fn;sx;s
]NaOH d s4 fey heksy fey kusd si'pkr~H2A d svk;uu d h ek=kk0.01 gSaA
(C) fn;sx;sNaOH d s3 fey heks

y fey kusd si'pkr~foy ;u d hpH 3.48 gksrh gSA
(D) fn;sx;s
]NaOH d s12 fey heksy fey kusd si'pkr~foy ;u d hpOH 9.35 gksrh gSA
45. Milli moles of NaOH to make the solution of pH = 4.
pH = 4 oky k foy ;u cukusd sfy , vko';d NaOH d sfeyheksy gS&
(A) 12 (B) 24 (C) 6 (D) 9.6
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CHEMISTRY
SECTION - 3
Matrix - Match Type
CHEMSITRY
This section contains 3 questions. Each question contains
statements given in two columns which have to be
matched. Statements in Column  are labelled as A,B,C p q r s
and D whereas statements in Column are labelled as A p q r s
p,q,r and s. The answers to these questions have to be B p q r s
appropriately bubbled as illustrated in the following C p q r s
example. p q r s
D
If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s
and D-q,then the correctly bubbled matrix will look like the
following :
[k.M - 3
eSfVªDl &l qesy izd kj
bl [k.M esa3 iz'u gSaA izR;sd iz'u esanksd kWy e esaoDRO; (statements) p q r s
fn;sgq, gSaft ud k lqesy (match) d juk gSA d kWy e (Column-I) esafn;s A p q r s
x;soDrO;ksa(A, B, C, D) d ksd kWy e (Column-II) esafn;sx;soDrO;ksa B p q r s
(p, q, r, s) lslq esy d juk gSA bu iz'uksad smÙkj fn;sx;smnkgj.k d s C p q r s
vuql kj mfpr cqYyksad ksd ky k d jd sn'kkZuk gS A D p q r s
;fn lgh lqesy A-p, A-r, B-p, B-s, C-r, C-s rFkk D-q gSa] rkslgh fof/k
lsd ky sfd , x;scqYy ksad k 4 x 4 esafVªDl (matrix) uhpsn'kkZ;k x;k gS
A
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CHEMISTRY
46. Column- I Column- II
(A) NaHCO3 (aq.) (p) Significant cationic hydrolysis
CHEMSITRY
(B) CH3COONH4 (aq.) (q) Significant anionic hydrolysis
(C) K2SO4. Al2(SO4)3(aq.) (r) Acidic (pH < 7)
(D) NaCN (aq) (s) Basic (pH > 7)
Given : K1 = 5 × 10–7, K2 = 5 × 10–11 for H2CO3

K (CH3 COOH) = 1.8 × 10–5 , K (NH4OH) = 1.8 × 10–5
d kWy e- I d kWy e- II
(A) NaHCO3 (aq.) (p) i;kZ

Ir /kuk;fud t y -vi?kVu
(B) CH3COONH4 (aq.) (q) i;kZ

Ir _ .kk;fud t y -vi?kVu
(C) K2SO4. Al2(SO4)3(aq.) (r) vEyh; (pH < 7)
(D) NaCN (aq) (s) {kkjh; (pH > 7)
fn;k x;k gS: K1 = 5 × 10–7, K2 = 5 × 10–11 for H2CO3

K (CH3 COOH) = 1.8 × 10–5 , K (NH4OH) = 1.8 × 10–5
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CHEMISTRY
47. Match the following
Column I represents equilibrium among CH3COOH (Weak acid), CH3COO– and H+ . The system is
externally disturbed by adding substances shown (in small amount)
CHEMSITRY
Column II represents the responses by the system under external disturbance and final equlibrium
is established.
Column- I Column- II
(A) CH3COOH CH3COO– + H+ (p) [H+] is increased
Small amount of NaOH is added
(B) CH3COOH CH3COO– + H+ (q) [H+] is decreased
Small amount of HCl is added
(C) CH3COOH CH3COO– + H+ (r) [CH3COOH] is increased
Small amount of CH3COONa is added
(D) CH3COOH CH3COO– + H+ (s) [CH3COOH] is decreased
Small amount of more concentrated
CH3COOH is added
fuEu d kslqesfy r d hft ;sA
d kWy e I CH3COOH (nqcZy vEy ) d k CH3COO– vkSj H+ esalkE; d ksn'kkZrk gSA bl ra=k esackgj ls¼d qN
ek=kk esa½ n'kkZ;sx;s] inkFkZfeykd j lkE;koLFkk d ksfopfy r fd ;k t krk gSA
d kWy e II esa ckg~; ifjorZu d s }kjk ra=k esa gksus oky s ifjorZu ¼;k izfrfØ ;k½ d s i'pkr~] vUrr% lkE;koLFkk
LFkkfir gkst krh gSrFkk bld sifjorZu ¼;k izfrfØ ;k½ d ksd kWy e-II esaçnf'kZr fd ;k x;k gSA
d kWy e- I d kWy e- II
(A) CH3COOH CH3COO– + H+ (p) [H+] c<rk gS
NaOH d h d q N ek=kk feykrsgS
(B) CH3COOH CH3COO– + H+ (q) [H+] ?kVrk gS
HCl d h d qN ek=kk fey krsgS
(C) CH3COOH CH3COO– + H+ (r) [CH3COOH] c<rk gS
CH3COONa d h d q N ek=kk fey krsgS
(D) CH3COOH CH3COO– + H+ (s) [CH3COOH] ?kVrk gS
vf/kd lkanzCH3COOH d h d q N ek=kk fey krsgS
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CHEMISTRY
48. Column-I Column-II
M
CHEMSITRY
(A) 0.1 M H3PO4 (p) eq. wt. = (where M = molar mass)
3
pKa1
(B) MnO4– (q) pH = + 0.5
2
(As an Oxidising agent in neutral medium)
(C) aq. solution of 0.1 M CO2 (r) sp3 hybridised (central atom)
(D) Cu2+ + 4F–  [CuF4]2– (s) 4NA oxygen atoms in 1 gm-molecule of

compound
d kWy e– I d kWy e– II
M
(A) 0.1 M H3PO4 (p) rqY;kad h Hkkj = (M = eks
yj nzO;eku)
3
pKa1
(B) MnO4– (mnklhu ek/;e esavkWDlhd kjd ) (q) pH = + 0.5
2
(C) 0.1 M CO2 d k t yh; foy ;u (r) sp3 la

d fjr (d sUnzh; ijek.kq)
(D) Cu2+ + 4F–  [CuF4]2– (s) ;kSfxd d s1 xzke-v.kqesa4NA vkWDlht u ijek.kq
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CODE
PAPER-2 COURSE : VIJETA JP) / VIJAY (JR)

0
12. fod Yi d ksu feVk,a@ u Ld zsp d jsavkSj u gh xyr (X) fpUg Neither try to erase / rub / scratch the option nor make the
d ksHkjsaA ORS d ksd kVsu gh Q kMsu gh xUnk ughad jsarFkk Cross (X) mark on the option once filled. Do not scribble,
d ksbZHkh fu'kku ;k lQ snh ORS ij ughayxk,aA smudge, cut, tear, or wrinkle the ORS. Do not put any stray
marks or whitener anywhere on the ORS.
13. ;fn ORS esafd lh izd kj d h fy [ksx, vkad MksarFkk xksy sfd , If there is any discrepancy between the written data and the
vkad Mksaesafojks/kkHkkl gSrksxksy sfd , vkad Mksad ksghlghekuk bubbled data in your ORS, the bubbled data will be taken as
final.
t kosxkA
C. iz'u&i=k d k izk: i C. Question Paper Format
bl iz'u&i=k d srhu Hkkx ¼xf.kr] HkkSfrd foKku vkSj The question paper consists of three parts
jlk;u foKku½ gSaA gj Hkkx d srhu [k.M gSaA (Mathematics, Physics and Chemistry). Each part
consists of three sections.
14. [kaM 1 esa7 cgqfod Yi iz'u gSaA gj iz'u esapkj fod Yi Section 1 contains 7 multiple choice questions. Each
j (D) gSaft uesals,d ;kv f/kd l ghgSA question has four choices (A), (B), (C) and (D) out of
(A), (B), (C) vkS
which ONE or MORE are correct.
15. [kaM 2 esafl) ka
rks]iz;ks
xksvkSj vk¡d M+ksvkfn d ksn'kkZusoky s Section 2 contains 3 paragraphs each describing
3 v uq aA rhuksavuqPNsnksalslacaf/kr N % iz'u gSa
PN sn gS ]ft uesa theory, experiment, data etc. Six questions related to
three paragraphs with two questions on each paragraph.
lsgj vuq PNs
n ij nksiz 'u gSA fd lhHkhvuq
a PNsn esagj iz'u Each question of a paragraph has ONLY ONE correct
d spkj fod Yi (A), (B), (C) vkSj (D) gSaft uesalsd soy answer among the four choices (A), (B), (C) and (D).
,d l gh gSaA
16. [kaM 3 esa3 iz'u gSA izR;sd iz'u esanksd kWy e esaoDRO; Section 3 contains 3 questions. Each question
(statements) fn;sgq , gSaft ud klqesy (match) d jukgSA contains statements given in two columns which have
d kWy e (Column-I) esafn;sx;soDrO;ksa(A, B, C, D) d ks to be matched. Statements in Column  are labelled as
d kWy e (Column-II) esafn;sx;soDrO;ksa(p, q, r, s) ls A,B,C and D whereas statements in Column  are
labelled as p,q,r and s. The answers to these questions
lqesy d juk gSA bu iz'uksad smÙkj fn;sx;smnkgj.k d s
have to be appropriately bubbled as illustrated in the
vuql kj mfpr cqYy ksad ksd ky k d jd sn'kkZuk gSA following example.
D. v ad u ;kst uk D. Marking Scheme
17. [kaM 1 esagj iz'u esad soy lgh mÙkjksa¼mÙkj½ oky slHkh For each question in Section 1, you will be awarded
cqy cqy s(BUBBLES) d ksd ky k d jusij 4 v ad vkSj d ksbZ 4 marks if you darken the bubble(s) corresponding to
Hkhcqy cw y kd kykughad jusij (0) va d iznku fd , t k;sxs
a A only the correct answer and zero mark if no bubbles
are darkened. No negative marks will be awarded for
bl [ka M d siz 'uks
aes
axyr mÙkj ns usij d ks
bZ_ .kkRed v a d incorrect answers in this section.
ughafn;st k;saxsA
18. [ka M 2 esa gj iz'u esa d soy l gh m Ùkj oky s For each question in Section 2, you will be awarded
cqy cqy s(BUBBLES) d ky k d jusij 3 v ad vkSj d ksbZHkh 3 marks if you darken all the bubble(s) corresponding
cqy cwy k d ky k ughad jusij (0) v ad iznku fd , t k;saxsA to only the correct answer and zero mark if no bubbles
are darkened. In all other cases, minus one (–1) mark
vU; lHkhfLFkfr;ksaesa_ .kkRed ,d (–1) v ad iz nku fd ;k will be awarded.
t k;sxkA
19. [kaM 3 esagj ,d iz'u esaçR;sd iafDr esa;fn d soy lghmÙkj For each question in Section–3, you will be awarded
d k cqy cqy k ¼cqy cqy s½ d ky k fd ;k x;k gksrks2 v ad iznku 2 marks for each row in which you have darkened the
bubble corresponding to the correct answer. Thus, each
fd ;k t k;sxkA vr% bl [k.M d k çR;sd ç'u vf/kd re 8 question in this section carries a maximum of 8 marks.
v ad ksad k gksxkA bl [k.M esaxy r mRrj d scqYy sd ksd kyk There is no negative marking for incorrect answer(s) in
d jusij _ .kkRed v ad ughafn;k t k;sxkA this section.
ijh{kkFkhZd kuke jksy uEcj

Name of the Candidate Roll Number
eSauslHkhfunsZ'kksad ki<+fy ;kgSvkSj eSamud k ijh{kkFkhZ}kjk Hkjh xbZlkjh t kud kjh d kseSusa
vo'; iky u d : ¡xk@d : ¡xhA t k¡p fy ;k gSA
I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
....................................................... .......................................................
ijh{kkFkhZd sgLrk{kj ijh{kd d sgLrk{kj
Signature of the Candidate Signature of the Invigilator

Paper-2: Cumulative Test-1 (Ct-1)

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CUMULATIVE TEST-1 (CT-1)

DO NOT BREAK THE SEALS WITHOUT BEING

d ì;k 'ks"k funsZ'kksad sfy ;sbl iqfLrd k d sv fUre i`"B d ksi<+sA

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

ekukfd fn(x) = (sin x)1/n + (cos x)1/n , x  R, n  N, rc

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

ekukfd f: R  R, f(x) = x + ln(1 + x2), rc

(C) y = f(x) d svkjs

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

SECTION – 2 : (Paragraph Type)

Paragraph for Question Nos. 8 to 9 (iz

8. The number of values of k for f(x) to be invertible, is

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

(A) (–, 2) (B) (2, ) (C) (0,1) (D) (1,2)

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Let f(x) and g(x) be two differentiable functions, defined as

ekuk f(x) vkS

12. The value of f(1) + g(–1) is

f(1) + g(–1) d k eku gS&

(A) 0 (B) 1 (C) 2 (D) infinite

(A) 0 (B) 1 (C) 2 (D) vuUr

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

(B) |x – | + |x2 – 2|  0, then x is equal to (q) –

(C) The principal value of cos–1 (cos 5) is (r) 2 – 5

(D) The value of 2 (tan–1 (1) + tan–1 (2) + tan–13)) – 5 is (s) 

(B) ;fn |x – | + |x2 – 2|  0 gks] rks x = (q) –

(C) cos–1 (cos 5) d k eq

(D) 2 (tan–1 (1) + tan–1 (2) + tan–13)) – 5 d k eku gS& (s) 

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

(C) The number of integral values of m for which f:RR; (r) 6

(D) The number of roots of equation (s) 7

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

(B) ‘x’ d k U;w

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

(A) required minimum velocity is zero

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)

(C) Yellow ray travels without deviation (D) there is no dispersion

(A) uhy k çd k'k 'kh"kZd h vks

(C) ihy k çd k'k fcuk fopy u d sfud y t k;sxkA (D) ;gk¡d ks

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)

(A) Displacement of the cosmic particle till that instant is 1.2R

(B) Acceleration of the cosmic particle at that instant is zero

(B) bl {k.k ij vkd k'kh; d .k d k Roj.k 'kwU; gSA

8Gm Work / (d Ppsd k;Zd sfy ,

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Paragraph for Questions 24 and 25

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

26. The best representation of magnitude of potential v/s x coordinate is :

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)

Paragraph for Questions 28 and 29

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku)

Space for Rough Work / (d Ppsd k;Zd sfy , LFkku )

28. Select the incorrect statement :

v l R; d Fku d k p;u d hft , :