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Sep 30 2018 |

Logged in as : Leonardo Orozco


Block 2 of 2

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CHE-122 Quiz 08 C

Multiple Choice Questions

Select the answer choice that best


completes the sentence or
answers the question. (10 points
each)

Question
1 of 10
What is the equilibrium constant expression for dissolving iron (III) hydroxide in water?
Ksp = [Fe+3] + [OH-]3
Ksp = [Fe+3] [OH-]3
Ksp = [Fe+3] [OH-]
Ksp = [Fe+3] [OH-]2
Ksp = [Fe+3]3 [OH-]

Question
2 of 10

The following anions can be separated by precipitation as silver salts: Cl–, Br–, I–,
CrO42–. If Ag+ is added to a solution containing the four anions, each at a
concentration of 0.10 M, in what order will they precipitate?

Compound Ksp
AgCl 1.8 x 10–10
Ag2CrO4 1.1 x 10–12
AgBr 5.4 x 10–13
AgI 8.5 x 10–17

AgI à AgBr à Ag2CrO4 à AgCl


AgI à AgBr à AgCl à Ag2CrO4
AgCl à Ag2CrO4 à AgBr à AgI
Ag2CrO4 à AgCl à AgBr à AgI
Ag2CrO4 à AgI à AgBr à AgCl

Question
3 of 10

A flask contains the following chemical system at equilibrium:

CuCO3(s) Cu2+(aq) + 2 CO32–(aq)

Addition of which of the following substances will increase the solubility of


CuCO3(s) in water?

(1) aqueous hydrochloric acid


(2) aqueous sodium carbonate
(3) solid copper(II) carbonate

(1) only
(2) only
(3) only
(1) and (3)
(1), (2), and (3)

Question
4 of 10
The solubility of strontium carbonate (FW=147.6 g/mol) is 0.0011 g/100 mL at
20°C. Calculate the Ksp value for this compound.

1.5 x 10-3
1.5 x 10-4
5.6 x 10-9
7.5 x 10-5
7.5 x 10-6

Question
5 of 10
The molar solubility of silver sulfate Ag2(SO4) is 1.5 x 10-2 mol/L. What is the
Ksp for this compound?

1.4 x 10-5
1.5 x 10-2
2.3 x 10-4
2.8 x 10-14
3.5 x 10-6

Question
6 of 10
Calculate the silver ion concentration in a saturated solution of silver(I) carbonate
(Ksp = 8.1 x 10-12).

1.3 x 10-4 M
2.0 x 10-4 M
2.5 x 10-4 M
5.0 x 10-5 M
8.1 x 10-4 M

Question
7 of 10
The Ksp of BaSO4 is 1.1 x 10–10 at 25 °C. What mass of BaSO4 (molar mass =
233.4 g/mol) will dissolve in 1.0 L of water at 25°C?
1.0 x 10-5 g
1.6 x 10-4 g
2.4 x 10-3 g
2.6 x 10-8 g
4.5 x 10-8 g

Question
8 of 10
What is the molar solubility of Mn(OH)2(s) in a solution that is buffered at pH
8.00 at 25°C? The Ksp of Mn(OH)2 is 1.9 x 10–13 at 25°C.

1.9 x 10–7 mol/L


1.9 x 10–1 mol/L
1.9 x 103 mol/L
3.6 x 10–8 mol/L
3.6 x 10–5 mol/L
Question
9 of 10
At what pH will an aqueous solution of 0.200 M Ni2+ begin to precipitate as
Ni(OH)2 at 25°C? The Ksp of Ni(OH)2 is 5.5 x 10–16 at 25°C.
6.37
6.72
7.28
7.63
7.93

Question
10 of 10
What mass of KCl (molar mass = 74.55 g/mol) must be added to 1.0 L of 0.0180
M Pb2+(aq) to initiate precipitation of PbCl2(s)? The Ksp of PbCl2 is 1.7 x 10–5.
Assume no volume change occurs upon addition of KCl.
0.041 g
0.070 g
2.3 g
2.5 g
6.6 x 10–5 g

Question

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