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2 Classification and nomenclature

This chapter is a summary of all the published is presumed to have formed by slow cool-
recommendations of the IUGS Subcommission ing. Many rocks that occur in orogenic
on the Systematics of Igneous Rocks together belts have suffered some metamorphic
with some other decisions agreed to since the overprinting, so that it is left to the discre-
last Subcommission meeting in Prague in 1999. tion of the user to decide whether to use an
igneous or metamorphic term to describe
the rock (e.g. whether to use gneissose
2.1 PRINCIPLES granite or granitic gneiss).
(4) The term volcanic rock is taken to mean an
Throughout its deliberations on the problems igneous rock with an aphanitic texture, i.e.
of classification the Subcommission has been a relatively fine-grained (< 1 mm) rock in
guided by the following principles, most of which most of the individual crystals can-
which have been detailed by Streckeisen (1973, not be distinguished with the naked eye
1976) and Le Bas & Streckeisen (1991). and which is presumed to have formed by
(1) For the purposes of classification and relatively fast cooling. Such rocks often
nomenclature the term “igneous rock” is contain glass.
taken to mean “Massige Gesteine” in the (5) Rocks should be named according to what
sense of Rosenbusch, which in English they are, and not according to what they
can be translated as “igneous or igneous- might have been. Any manipulation of the
looking”. Igneous rocks may have crystal- raw data used for classification should be
lized from magmas or may have been justified by the user.
formed by cumulate, deuteric, metasomatic (6) Any useful classification should corre-
or metamorphic processes. Arguments as spond with natural relationships.
to whether charnockites are igneous or (7) The classification should follow as closely
metamorphic rocks are, therefore, irrel- as possible the historical tradition so that
evant in this context. well-established terms, e.g. granite, basalt,
(2) The primary classification of igneous rocks andesite, are not redefined in a drastically
should be based on their mineral contentor new sense.
mode. If a mineral mode is impossible to (8) The classification should be simple and
determine, because of the presence of glass, easy to use.
or because of the fine-grained nature of the (9) All official recommendations should be
rock, then other criteria may be used, e.g. published in English, and any translation
chemical composition, as in the TAS or transliteration problems should be solved
classification. by members in their individual countries.
(3) The term plutonic rock is taken to mean an However, publications by individual Sub-
igneous rock with a phaneritic texture, i.e. commission members, in languages other
a relatively coarse-grained (> 3 mm) rock than English, were encouraged in order to
in which the individual crystals can be spread the recommendations to as wide an
distinguished with the naked eye and which audience as possible.

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4 2 Classification and nomenclature

2.1.1 PARAMETERS USED a general root name to a rock. As such root


names are often not specific enough, espe-
The primary modal classifications of plutonic cially for specialist use, the Subcommission
rocks and volcanic rocks are based on the encourages the use of additional qualifiers
relative proportions of the following mineral which may be added to any root name.
groups for which volume modal data must be These additional qualifiers may be mineral
determined: names (e.g. biotite granite), textural terms
Q = quartz, tridymite, cristobalite (e.g. porphyritic granite), chemical terms (e.g.
A = alkali feldspar, including orthoclase, mi- Sr-rich granite), genetic terms (e.g. anatectic
crocline, perthite, anorthoclase, sanidine, granite), tectonic terms (e.g. post-orogenic
and albitic plagioclase (An0 to An5) granite) or any other terms that the user thinks
P = plagioclase (An5 to An100) and scapolite are useful or appropriate. For general guidance
F = feldspathoids or foids including nephe- on the use of qualifiers the Subcommission
line, leucite, kalsilite, analcime, sodalite, makes the following points.
nosean, haüyne, cancrinite and pseudo- (1) The addition of qualifiers to a root name
leucite. must not conflict with the definition of the
M = mafic and related minerals, e.g. mica, root name. That means that a biotite gran-
amphibole, pyroxene, olivine, opaque min- ite, porphyritic granite, Sr-rich granite,
erals, accessory minerals (e.g. zircon, apa- and post-orogenic granite must still be
tite, titanite), epidote, allanite, garnet, granites in the sense of the classification.
melilite, monticellite, primary carbonate. Quartz-free granite, however, would not
Groups Q, A, P and F comprise the felsic be permissible because the rock could not
minerals, while the minerals of group M are be classified as a granite, if it contained no
considered to be mafic minerals, from the point quartz.
of view of the modal classifications. (2) The user should define what is meant by
The sum of Q + A + P + F + M must, of course, the qualifiers used if they are not self-
be 100%. Notice, however, that there can never explanatory. This applies particularly to
be more than four non-zero values, as the geochemical terms, such as Sr-rich or Mg-
minerals in groups Q and F are mutually exclu- poor, when often no indications are given
sive, i.e. if Q is present, F must be absent, and of the threshold values above or below
vice versa. which the term is applicable.
Where modal data are not available, several (3) If more than one mineral qualifier is used
parts of the classification utilize chemical data. the mineral names should be given in
In these cases all oxide and normative values order of increasing abundance
are in weight %, unless otherwise stated. All (Streckeisen, 1973, p.30; 1976, p.22), e.g.
normative values are based on the rules of the a hornblende-biotite granodiorite should
CIPW norm calculation (see p.233). contain more biotite than hornblende.
Notice that this is the opposite of the
convention often adopted by metamor-
2.1.2 NOMENCLATURE phic petrologists.
(4) The use of the suffix -bearing, as applied
During the work of the Subcommission it was to mineral names, has not been consistently
quickly realized that the classification schemes defined, as it is used with different
would rarely go beyond the stage of assigning threshold values. For example, in the

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2.1 Principles 5

QAPF classification, 5% Q in Q + A + P is (7) The prefix meta- should be used to indicate


used as the upper limit of the term quartz- that an igneous rock has been metamor-
bearing, while 10% F in A + P + F is used phosed, e.g. meta-andesite, meta-basalt etc.,
as the upper limit of the term foid-bearing. but only when the igneous texture is still
The value of 10% is also used for preserved and the original rock type can be
plagioclase-bearing ultramafic rocks (Fig. deduced.
2.6, p.25), but for glass-bearing rocks 20% (8) Volcanic rocks for which a complete min-
is the upper limit (Table 2.1, p.5). eral mode cannot be determined, and have
(5) For volcanic rocks containing glass, the not yet been analysed, may be named
amount of glass should be indicated by provisionally following the terminology
using the prefixes shown in Table 2.1 of Niggli (1931, p.357), by using their
(from Streckeisen, 1978, 1979). For rocks visible minerals (usually phenocrysts) to
with more than 80% glass special names assign a name which is preceded by the
such as obsidian, pitchstone etc. are used. prefix pheno- (Streckeisen, 1978, p.7;
Furthermore, for volcanic rocks, which 1979, p.333). Thus a rock containing
have been named according to their chem- phenocrysts of sodic plagioclase in a cryp-
istry using the TAS diagram, the presence tocrystalline matrix may be provisionally
of glass can be indicated by using the called pheno-andesite. Alternatively the
prefix hyalo- with the root name, e.g. hyalo- provisional “field” classifications could
rhyolite, hyalo-andesite etc. For some rocks be used (Fig. 2.19, p.39).
special names have been given, e.g. (9) The colour index M' is defined
limburgite = hyalo-nepheline basanite (Streckeisen, 1973, p.30; 1976, p.23) as M
(6) the prefix micro- should be used to indi- minus any muscovite, apatite, primary
cate that a plutonic rock is finer-grained carbonates etc., as muscovite, apatite, and
than usual, rather than giving the rock a primary carbonates are considered to be
special name. The only exceptions to this colourless minerals for the purpose of the
are the long-established terms dolerite and colour index. This enables the terms
diabase (= microgabbro) which may still leucocratic, mesocratic, melanocratic etc.
be used. These two terms are regarded as to be defined in terms of the ranges of
being synonymous. The use of diabase for colour index shown in Table 2.2. Note that
Palaeozoic or Precambrian basalts or for these terms are applicable only to rocks
altered basalts of any geological age should and must not be used to describe minerals.
be avoided.

Table 2.2. Colour index terms


Table 2.1. Prefixes for use with rocks
containing glass Colour index term Range of M'

% glass Prefix hololeucocratic 0 – 10


leucocratic 10 – 35
0 – 20 glass-bearing mesocratic 35 – 65
20 – 50 glass-rich melanocratic 65 – 90
50 – 80 glassy holomelanocratic 90 – 100

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6 2 Classification and nomenclature

2.1.3 USING THE CLASSIFICATION origin go to section 2.2 “Pyroclastic Rocks


and Tephra” on p.7
One of the problems of classifying igneous (2) if the rock contains > 50% of modal car-
rocks is that they cannot all be classified sensi- bonate go to section 2.3 “Carbonatites” on
bly by using only one system. For example, the p.10
modal parameters required to adequately de- (3) if the rock contains > 10% of modal melilite
fine a felsic rock, composed of quartz and go to section 2.4 “Melilite-bearing Rocks”
feldspars, are very different from those re- on p.11
quired to define an ultramafic rock, consisting (4) if the rock contains modal kalsilite go to
of olivine and pyroxenes. Similarly, lampro- section 2.5 “Kalsilite-bearing Rocks” on
phyres have usually been classified as a sepa- p.12
rate group of rocks. Also modal classifications (5) check to see if the rock is a kimberlite as
cannot be applied to rocks which contain glass described in section 2.6 on p.13
or are too fine-grained to have their modes (6) check to see if the rock is a lamproite as
determined, so that other criteria, such as chem- described in section 2.7 on p.16
istry, have to be used in these examples. (7) if the rock contains modal leucite go to
As a result several classifications have to be section 2.8 “Leucite-bearing Rocks” on
presented, each of which is applicable to a p.18
certain group of rocks, e.g. pyroclastic rocks, (8) check to see if the rock is a lamprophyre as
lamprophyres, plutonic rocks. This, however, described in section 2.9 on p.19. Note that
means that one has to decide which of the certain melilite-bearing rocks that were
classifications is appropriate for the rock in previously included in the lamprophyre
question. To do this in a consistent manner, so classification should now be classified as
that different petrologists will arrive at the melilite-bearing rocks
same answer, a hierarchy of classification had (9) check to see if the rock is a charnockite as
to be agreed upon. The basic principle in- described in section 2.10 on p.20
volved in this was that the “special” rock types (10) if the rock is plutonic, as defined in section
(e.g. lamprophyres, pyroclastic rocks) must be 2.1, go to section 2.11 “Plutonic rocks” on
dealt with first so that anything that was not p.21
regarded as a “special” rock type would be (11) if the rock is volcanic, as defined in section
classified in either the plutonic or volcanic 2.1, go to section 2.12 “Volcanic rocks” on
classifications which, after all, contain the vast p.30
majority of igneous rocks. The sequence that (12) if you get to this point, either the rock is not
should be followed is as follows: igneous or you have made a mistake.
(1) if the rock is considered to be of pyroclastic

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7

2.2 PYROCLASTIC ROCKS AND called “reworked pyroclasts”, or “epiclasts” if


TEPHRA their pyroclastic origin is uncertain.
The various types of pyroclasts are mainly
This classification has been slightly modified distinguished by their size (see Table 2.3, p.9):
from that given in the 1st edition. Bombs — pyroclasts the mean diameter of
It should be used only if the rock is consid- which exceeds 64 mm and whose shape or
ered to have had a pyroclastic origin, i.e. was surface (e.g. bread-crust surface) indicates that
formed by fragmentation as a result of explosive they were in a wholly or partly molten condition
volcanic eruptions or processes. It specifically during their formation and subsequent transport.
excludes rocks formed by the autobrecciation Blocks — pyroclasts the mean diameter of
of lava flows, because the lava flow itself is the which exceeds 64 mm and whose angular to
direct result of volcanic action, not its subangular shape indicates that they were solid
brecciation. during their formation.
The nomenclature and classification is purely Lapilli — pyroclasts of any shape with a
descriptive and thus can easily be applied by mean diameter of 64 mm to 2 mm
non-specialists. By defining the term Ash grains — pyroclasts with a mean
“pyroclast” in a broad sense (see section 2.2.1), diameter of less than 2 mm They may be
the classification can be applied to air fall, flow further divided into coarse ash grains (2 mm to
and surge deposits as well as to lahars, 1/16 mm) and fine ash (or dust) grains (less
subsurface and vent deposits (e.g. intrusion than 1/16 mm).
and extrusion breccias, tuff dykes, diatremes).
When indicating the grain size of a single
pyroclast or the middle grain size of an 2.2.2 PYROCLASTIC DEPOSITS
assemblage of pyroclasts the general terms
“mean diameter” and “average pyroclast size” Pyroclastic deposits are defined as an
are used, without defining them explicitly, as assemblage of pyroclasts which may be
grain size can be expressed in several ways. It unconsolidated or consolidated. They must
is up to the user of this nomenclature to specify contain more than 75% by volume of pyroclasts,
the method by which grain size was measured the remaining materials generally being of
in those examples where it seems necessary to epiclastic, organic, chemical sedimentary or
do so. authigenic origin. When they are predominantly
consolidated they may be called pyroclastic
rocks and when predominantly unconsolidated
2.2.1 PYROCLASTS they may be called tephra. Table 2.3 shows the
nomenclature for tephra and well-sorted
Pyroclasts are defined as fragments generated pyroclastic rocks.
by disruption as a direct result of volcanic However, the majority of pyroclastic rocks
action. are polymodal and may be classified according
The fragments may be individual crystals, or to the proportions of their pyroclasts as shown
crystal, glass or rock fragments. Their shapes in Fig. 2.1 as follows:
acquired during disruption or during subsequent Agglomerate — a pyroclastic rock in which
transport to the primary deposit must not have bombs > 75%.
been altered by later redepositional processes. Pyroclastic breccia — a pyroclastic rock in
If the fragments have been altered they are which blocks > 75%.

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8 2 Classification and nomenclature

Tuff breccia — a pyroclastic rock in which may also be further qualified by the use of any
bombs and/or blocks range in amount from other suitable prefix, e.g. air-fall tuff, flow tuff,
25% to 75%. basaltic lapilli tuff, lacustrine tuff, rhyolitic
Lapilli tuff — a pyroclastic rock in which ash, vent agglomerate etc. The terms may also
bombs and/or blocks < 25%, and both lapilli be replaced by purely genetic terms, such as
and ash < 75%. hyaloclastite or base-surge deposit, whenever
Lapillistone — a pyroclastic rock in which it seems appropriate to do so.
lapilli > 75%.
Tuff or ash tuff — a pyroclastic rock in which
ash > 75%. These may be further divided into 2.2.3 MIXED PYROCLASTIC–EPICLASTIC DEPOSITS
coarse (ash) tuff (2 mm to 1/16 mm) and fine
(ash) tuff (less than 1/16 mm). The fine ash tuff For rocks which contain both pyroclastic and
may also be called dust tuff. Tuffs and ashes normal clastic (epiclastic) material the Sub-
may be further qualified by their fragmental commission suggests that the general term
composition, i.e a lithic tuff would contain a tuffites can be used within the limits given in
predominance of rock fragments, a vitric tuff a Table 2.4. Tuffites may be further divided
predominance of pumice and glass fragments, according to their average grain size by the
and a crystal tuff a predominance of crystal addition of the term “tuffaceous” to the normal
fragments. sedimentary term, e.g. tuffaceous sandstone.
Any of these terms for pyroclastic deposits

blocks and bombs


(> 64 mm)
pyroclastic breccia (blocks)
agglomerate (bombs)
75 75

tuff breccia

25 25
lapillistone lapilli tuff tuff or ash tuff

lapilli 25 75 ash
(64 – 2 mm) (< 2 mm)
Fig. 2.1. Classification of polymodal pyroclastic rocks based on the proportions
of blocks/bombs, lapilli and ash (after Fisher, 1966).

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2.2 Pyroclastic rocks and tephra 9

Table 2.3. Classification and nomenclature of pyroclasts and well-sorted pyroclastic rocks
based on clast size

Average Pyroclastic deposit


Clast size Pyroclast Mainly unconsolidated: Mainly consolidated:
in mm tephra pyroclastic rock
agglomerate
agglomerate
bomb, block bed of blocks or
pyroclastic breccia
bomb, block tephra
64
layer, bed of lapilli
lapillus lapillistone
or lapilli tephra
2
coarse ash grain coarse ash coarse (ash) tuff
1/16
fine ash grain fine (ash) tuff
fine ash (dust)
(dust grain) (dust tuff)

Source: After Schmid (1981, Table 1).

Table 2.4. Terms to be used for mixed pyroclastic–epiclastic rocks

Average Tuffites Epiclastic


clast size Pyroclastic (mixed pyroclastic (volcanic and/or
in mm –epiclastic) non-volcanic)
agglomerate,
pyroclastic breccia tuffaceous conglomerate, conglomerate,
64 tuffaceous breccia breccia
lapillistone
2
coarse tuffaceous sandstone sandstone
1/16 (ash) tuff
fine tuffaceous siltstone siltstone
1/256
tuffaceous mudstone, shale mudstone, shale
Amount of
pyroclastic 100% to 75% 75% to 25% 25% to 0%
material
Source: After Schmid (1981, Table 2).

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10 2 Classification and nomenclature

2.3 CARBONATITES Qualifications, such as dolomite-bearing, may


be used to emphasize the presence of a minor
This classification should be used only if the constituent (less than 10%). Similarly, igneous
rock contains more than 50% modal carbon- rocks containing less than 10% of carbonate
ates (Streckeisen, 1978, 1979). Carbonatites may be called calcite-bearing ijolite, dolomite-
may be either plutonic or volcanic in origin. bearing peridotite etc., while those with be-
Mineralogically the following classes of tween 10% and 50% carbonate minerals may
carbonatites may be distinguished: be called calcitic ijolite or carbonatitic ijolite
Calcite-carbonatite — where the main car- etc.
bonate is calcite. If the rock is coarse-grained If the carbonatite is too fine-grained for an
it may be called sövite; if medium- to fine- accurate mode to be determined, or if the
grained, alvikite. carbonates are complex Ca–Mg–Fe solid solu-
Dolomite-carbonatite — where the main car- tions, then the chemical classification shown
bonate is dolomite. This may also be called in Fig. 2.2 can be used for carbonatites with
beforsite. SiO2 < 20%.
Ferrocarbonatite — where the main carbon- However, if SiO2 > 20% the rock is a
ate is iron-rich. silicocarbonatite. For a more detailed chemi-
Natrocarbonatite — essentially composed of cal classification of calciocarbonatites,
sodium, potassium, and calcium carbonates. magnesiocarbonatites and ferrocarbonatites
At present this unusual rock type is found only refer to Gittins & Harmer (1997) and Le Bas
at Oldoinyo Lengai volcano in Tanzania. (1999).

CaO
calciocarbonatite

20 20

magnesiocarbonatite ferrocarbonatite

MgO 50 FeO + Fe2O3+ MnO


Fig. 2.2. Chemical classification of carbonatites with SiO2 < 20%
using wt % oxides (Woolley & Kempe, 1989). Carbonatites in which
SiO2 > 20% are silicocarbonatites.

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11

2.4 MELILITE-BEARING ROCKS nepheline and pyroxene. If these minerals


comprise > 10% of the rock and melilite is <
This classification is used for rocks which 65% then the following names may be used:
contain > 10% modal melilite and, if feld- 1) if perovskite > 10% then it is an afrikandite
spathoids are present, melilite > feldspathoid. 2) if olivine > 10% then it is a kugdite
The general term for plutonic melilite-bearing 3) if haüyne > 10% and melitite > haüyne
rocks is melilitolite, and for volcanic melilite- then it is an okaite
bearing rocks it is melilitite. For rocks with > 4) if nepheline > 10% and melitite > nepheline
10% melilite and/or containing kalsilite go to then it is a turjaite
section 2.5 “Kalsilite-bearing Rock” on p.12. 5) if pyroxene > 10% then it is an
uncompahgrite.
If a third mineral is present in amounts greater
2.4.1 MELILITOLITES than 10% then it can be applied as a modifier,
e.g. magnetite-pyroxene melilitolite.
The plutonic melilitic rocks, melilitolites, are
classified according to their mineral content.
Those with melilite < feldspathoid and with 2.4.2 MELILITITES
feldspathoid > 10% are classified by QAPF as
melilite foidolites. However, the majority of If a mode can be determined, the appropriate
melilitolites have M > 90 and may be classified name can be obtained from Fig. 2.3. However,
according to their mineral content, e.g. pyrox- if it falls in the foidite field of QAPF (Fig. 2.11,
ene melilitolite. p.31) the name melilite should precede the
In a recent paper on the classification of appropriate foidite name, e.g melilite nepheli-
melilitic rocks, Dunworth & Bell (1998) sug- nite, if the predominant foid is nepheline.
gested that melilitolites with melilite > 65% be If the mode cannot be determined and a
termed “ultramelilitolites”. chemical analysis is available, then the TAS
Besides melilite, other principal mineral com- classification should be used (see description
ponents include perovskite, olivine, haüyne, of field F on p.38).

Mel
90

melilitite

olivine
melilitite

10 10
melilite-bearing volcanic rocks
Ol Cpx

Fig. 2.3. Modal classification of volcanic rocks containing melilite


(after Streckeisen, 1978, Fig. 5) based on the values of melilite (Mel),
olivine (Ol) and clinopyroxene (Cpx).

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12 2 Classification and nomenclature

2.5 KALSILITE-BEARING ROCKS cation system, the presence of essential me-


lilite and/or leucite indicates that either the
The principal minerals of the kalsilite-bearing classification of melilite-bearing or leucite-
rocks include clinopyroxene, kalsilite, leucite, bearing rocks should be applied. However, the
melilite, olivine and phlogopite, as shown in presence of kalsilite and leucite is considered
Table 2.5. Rocks with kalsilite but no leucite or petrogenetically so distinctive and important
melilite may be called kalsilitite. If the rock is that the accepted term kamafugite should be
plutonic the term pyroxenite may be more retained for this consanguineous series of rocks.
appropriately employed. Table 2.6 indicates their nomenclature as a
The rock types mafurite and katungite, function of mineral assemblage.
together with the closely associated leucite- Plutonic kalsilite-bearing rocks of the Aldan
bearing rock ugandite (which is excluded from and North Baikal petrological provinces of
Table 2.5, as it does not contain kalsilite and is Russia, which are not kamafugitic, may be
more logically classified as an olivine leucitite), distinguished by the prefix “kalsilite”. Thus,
are the principal constitutents of the kamafugitic the rock type synnyrite becomes kalsilite
series of Sahama (1974). syenite, and yakutite becomes kalsilite-biotite
From the point of view of the IUGS classifi- pyroxenite.

Table 2.5. Mineral assemblages of kalsilite-bearing volcanic rocks

Rock Phlogopite Clinopyroxene Leucite Kalsilite Melilite Olivine Glass

Mafurite – £ – £ – £ £
Katungite – – £ £ £ £ £
Venanzite £ £ £ £ £ £ –
Coppaelite £ £ – £ £ – –

£ = present; – = absent.
Source: Mitchell & Bergman (1991, Table 2.3).

Table 2.6. Nomenclature of the kamafugitic rock series

Historical name Recommended name

Mafurite Olivine-pyroxene kalsilitite


Katungite Kalsilite-leucite-olivine melilitite
Venanzite Kalsilite-phlogopite-olivine-leucite melilitite
Coppaelite Kalsilite-phlogopite melilitite
Ugandite Pyroxene-olivine leucitite

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2.6 KIMBERLITES presence of macrocrysts (a general term for


large crystals, typically 0.5–10 mm diameter)
Kimberlites are currently divided into Group I and, in some cases, megacrysts (larger crystals,
and Group II (Smith et al., 1985; Skinner, typically 1–20 cm) set in a fine-grained matrix.
1989). The Group I kimberlites corresponds The macrocryst–megacryst assemblage, at
with archetypal rocks from Kimberley, South least some of which are xenocrystic, includes
Africa, which were formerly termed “basaltic anhedral crystals of olivine, magnesian
kimberlites” by Wagner (1914). The Group II ilmenite, pyrope, diopside (sometimes
kimberlites, on the other hand, correspond to subcalcic), phlogopite, enstatite and Ti-poor
the micaceous or lamprophyric kimberlites of chromite. Olivine macrocrysts are a
Wagner (1914). characteristic and dominant constituent in all
Petrologists actively studying kimberlites but fractionated kimberlites.
have concluded that there are significant pet- The matrix contains a second generation of
rological differences between the two groups, primary euhedral-to-subhedral olivine which
although opinion is divided as to the extent of occurs together with one or more of the fol-
the revisions required to their nomenclature. lowing primary minerals: monticellite,
Some wish to retain the status quo (Skinner, phlogopite, perovskite, spinel (magnesian ul-
1989), whereas others (e.g. Mitchell, 1986; vospinel-Mg-chromite-ulvospinel-magnetite
Mitchell & Bergman, 1991; Mitchell, 1994) solid solutions), apatite, carbonate and ser-
believe that the terminology should be com- pentine. Many kimberlites contain late-stage
pletely revised (see below). However, the poikilitic micas belonging to the barian
Subcommission agreed that, because of the phlogopite–kinoshitalite series. Nickeliferous
mineralogical complexity of the rocks, a sin- sulphides and rutile are common accessory
gle succinct definition cannot be used to de- minerals. The replacement of earlier-formed
scribe both rock types, but that olivine, phlogopite, monticellite and apatite
characterizations can be given (Woolley et al., by deuteric serpentine and calcite is common.
1996). Evolved members of Group I may be poor in,
Following a concept originally developed by or devoid of, macrocrysts, and composed
Dawson (1980), the rocks may be recognized essentially of second-generation olivine,
as containing a characteristic mineral calcite, serpentine and magnetite, together with
assemblage. The following characterization minor phlogopite, apatite and perovskite.
of Group I kimberlites is after Mitchell (1995) It is evident that kimberlites are complex
which is based essentially on that of Mitchell hybrid rocks in which the problem of distin-
(1986, 1994) and evolved from earlier guishing the primary constituents from the
“definitions” given by Clement et al. (1984) entrained xenocrysts precludes simple defini-
and Mitchell (1979). tion. The above characterization attempts to
recognize that the composition and mineral-
ogy of kimberlites are not entirely derived
2.6.1 GROUP I KIMBERLITES from a parent magma, and the non-genetic
terms macrocryst and megacryst are used to
Group I Kimberlites are a group of volatile- describe minerals of cryptogenic, i.e. unknown
rich (dominantly CO2) potassic ultrabasic rocks origin.
commonly exhibiting a distinctive Macrocrysts include forsteritic olivine, Cr-
inequigranular texture resulting from the pyrope, almandine-pyrope, Cr-diopside, mag-

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14 2 Classification and nomenclature

nesian ilmenite and phlogopite crystals, that Group II kimberlites are mineralogically dif-
are now generally believed to originate by the ferent and petrogenetically separate rock-types.
disaggregation of mantle-derived lherzolite, A definition of Group II kimberlites has not
harzburgite, eclogite and metasomatized peri- yet been agreed as they have been insuffi-
dotite xenoliths. Most diamonds, which are ciently studied. Mitchell (1986, 1994, 1995)
excluded from the above “definition”, belong has suggested that these rocks are not kimber-
to this suite of minerals but are much less litic at all, and should be termed “orangeite”, in
common. recognition of their distinct character and unique
Megacrysts are dominated by magnesian il- occurrence in the Orange Free State of South
menite, Ti-pyrope, diopside, olivine and en- Africa. Wagner (1928) previously suggested
statite that have relatively Cr-poor that the rocks which he initially termed mica-
compositions (< 2% Cr2O3). The origin of the ceous kimberlite (Wagner, 1914) be renamed
megacrysts is still being debated (e.g. Mitchell, “orangite” (sic). The following characteriza-
1986), and some petrologists believe that they tion of the rocks currently described as Group
may be cognate. II kimberlites or micaceous kimberlites fol-
Both of these suites of minerals are included lows that of Mitchell (1995).
in the characterization because of their com- Group II kimberlites (or orangeites) belong to
mon presence in kimberlites. It can be debated a clan of ultrapotassic, peralkaline volatile-rich
whether reference to these characteristic con- (dominantly H2O) rocks, characterized by
stituents should be removed from the “defini- phlogopite macrocrysts and microphenocrysts,
tion” of kimberlite. Strictly, minerals which together with groundmass micas which vary in
are known to be xenocrysts should not be composition from “tetraferriphlogopite” to
included in a petrological definition, as they phlogopite. Rounded macrocrysts of olivine and
have not crystallized from the parental magma. euhedral primary crystals of olivine are com-
Smaller grains of both the macrocryst and mon, but are not invariably major constituents.
megacryst suite minerals also occur but may Characteristic primary phases in the ground-
be easily distinguished on the basis of their mass include: diopside, commonly zoned to,
compositions. In this respect, it is important to and mantled by, titanian aegirine; spinels rang-
distinguish pseudoprimary groundmass ing in composition from Mg-bearing chromite
diopside from macrocrystic or megacrystic to Ti-bearing magnetite; Sr- and REE-rich
clinopyroxene. Group I kimberlites do not perovskite; Sr-rich apatite; REE-rich phos-
usually contain the former except as a product phates (monazite, daqingshanite); potassian
of crystallization induced by the assimilation barian titanates belonging to the hollandite
of siliceous xenoliths (Scott Smith et al., 1983). group; potassium triskaidecatitanates
The primary nature of groundmass serpophitic (K2Ti13 O27); Nb-bearing rutile and Mn-bear-
serpentine was originally recognized by ing ilmenite. These are set in a mesostasis that
Mitchell & Putnis (1988). may contain calcite, dolomite, ancylite and
other rare-earth carbonates, witherite, nor-
sethite and serpentine.
2.6.2 GROUP II KIMBERLITES Evolved members of the group contain
groundmass sanidine and potassium richter-
Recent studies (Smith et al., 1985; Skinner, ite. Zirconium silicates (wadeite, zircon,
1989; Mitchell, 1994, 1995; Tainton & Brown- kimzeyitic garnet, Ca-Zr-silicate) may occur
ing, 1991) have demonstrated that Group I and as late-stage groundmass minerals. Barite is a

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2.6 Kimberlites 15

common deuteric secondary mineral. differences in the compositions and overall


Note that these rocks have a greater minera- assemblage of minerals, as detailed above, to
logical affinity to lamproites than to Group I permit their discrimination from lamproites
kimberlites. However, there are significant (Mitchell 1994, 1995).

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16 2 Classification and nomenclature

2.7 LAMPROITES ticellite, kalsilite, nepheline, Na-rich alkali feld-


spar, sodalite, nosean, haüyne, melanite, schor-
The lamproite classification system described lomite or kimzeyite.
by Mitchell & Bergman (1991) is recommended
and involves both mineralogical and
geochemical criteria. 2.7.2 CHEMICAL CRITERIA

Lamproites conform to the following chemical


2.7.1 MINERALOGICAL CRITERIA characteristics:
(1) molar K2O / Na2O > 3, i.e. they are
Lamproites normally occur as dykes or small ultrapotassic
extrusions. Mineralogically they are charac- (2) molar K2O / Al2O3 > 0.8 and often > 1
terized by the presence of widely varying (3) molar (K 2O + Na2O) / Al2O 3 typically
amounts (5 – 90 vol %) of the following pri- > 1, i.e they are peralkaline
mary phases: (4) typically FeO and CaO are both < 10%,
(1) titanian, Al-poor phenocrystic phlogopite TiO 2 1% – 7% , Ba > 2000 ppm (com-
(TiO2 2% – 10%; Al2O3 5% – 12%) monly > 5000 ppm), Sr > 1000 ppm,
(2) groundmass poikilitic titanian “tetraferri- Zr > 500 ppm and La > 200 ppm.
phlogopite” (TiO2 5% – 10%)
(3) titanian potassium richterite (TiO2 3% –
5%; K2O 4% – 6%) 2.7.3 NOMENCLATURE
(4) forsteritic olivine
(5) Al-poor, Na-poor diopside (Al2O3 < 1%; The subdivision of the lamproites should fol-
Na2O < 1%) low the scheme of Mitchell & Bergman (1991),
(6) non-stoichiometric iron-rich leucite (Fe2O3 in which the historical terminology is dis-
1% – 4%) carded in favour of compound names based on
(7) Fe-rich sanidine (typically Fe2O3 1% – the predominance of phlogopite, richterite, oli-
5%). vine, diopside, sanidine and leucite, as given in
The presence of all the above phases is not Table 2.7. It should be noted that the term
required in order to classify a rock as a lam- “madupitic” in Table 2.7 indicates that the rock
proite. Any one mineral may be dominant and contains poikilitic groundmass phlogopite, as
this, together with the two or three other major opposed to phlogopite lamproite in which
minerals present, suffices to determine the phlogopite occurs as phenocrysts.
petrographic name. The complex compositional and mineralogi-
Minor and common accessory phases in- cal criteria required to define lamproites result
clude priderite, wadeite, apatite, perovskite, from the diverse conditions involved in their
magnesiochromite, titanian magnesiochromite genesis, compared with those of rocks that can
and magnesian titaniferous magnetite with less be readily classified using the IUGS system.
commonly, but characteristically, jeppeite, The main petrogenetic factors contributing to
armalcolite, shcherbakovite, ilmenite and the complexity of composition and mineralogy
enstatite. of lamproites are the variable nature of their
The presence of the following minerals metasomatized source regions in the mantle,
precludes a rock from being classified as a depth and extent of partial melting, coupled
lamproite: primary plagioclase, melilite, mon- with their common extensive differentiation.

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2.7 Lamproites 17

Table 2.7. Nomenclature of lamproites

Historical name Recommended name

Wyomingite Diopside-leucite-phlogopite lamproite


Orendite Diopside-sanidine-phlogopite lamproite
Madupite Diopside madupitica lamproite
Cedricite Diopside-leucite lamproite
Mamilite Leucite-richterite lamproite
Wolgidite Diopside-leucite-richterite madupitica lamproite
Fitzroyite Leucite-phlogopite lamproite
Verite Hyalo-olivine-diopside-phlogopite lamproite
Jumillite Olivine-diopside-richterite madupitica lamproite
Fortunite Hyalo-enstatite-phlogopite lamproite
Cancalite Enstatite-sanidine-phlogopite lamproite

a Madupitic = containing poikilitic groundmass phlogopite.

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18 2 Classification and nomenclature

2.8 LEUCITE-BEARING ROCKS (3) QAPF subfield 15c, leucitite sensu stricto
in which foids are 90–100% of the light-
The leucite-bearing rocks, after the elimina- coloured constituents and leucite is practi-
tion of the lamproites and kamafugites, should cally the sole feldspathoid.
be named according to the volcanic QAPF The essential mineralogy of the principal
diagram (Fig. 2.11, p.31) with the prefix leucite-bearing rocks is given in Table 2.8.
“leucite” or “leucite-bearing” as appropriate. No unambiguous chemical criteria have been
Rocks containing little or no feldspar, i.e. falling found to distinguish this group of rocks. On
into field 15 (foidite), are leucitite, which is TAS (Fig. 2.14, p.35), leucitites extend
divided into three subfields (shown in Fig. significantly beyond the foidite field into
2.12, p.32): adjacent fields (see Le Bas et al., 1992, Fig.
(1) QAPF subfield 15a, phonolitic leucitite in 23). They are better distinguished from
which foids are 60–90% of the light- lamproites by other compositional parameters,
coloured constituents and alkali feldspar although even here some overlap occurs. The
> plagioclase. chemical characteristics of the potassic rocks
(2) QAPF subfield 15b, tephritic leucitite in and attempts at distinguishing lamproites from
which foids are 60–90% of the light- certain leucite-bearing rocks, using a variety of
coloured constituents and plagioclase > criteria, are explored by Foley et al. (1987) and
alkali feldspar Mitchell & Bergman (1991).

Table 2.8. Mineralogy of the principal groups of leucite-bearing volcanic rocks a

Rock Clinopyroxene Leucite Plagioclase Sanidine b Olivine

Leucitite £ £ – – > 10%


Tephritic leucitite £ £ plagioclase > sanidine £
Phonolitic leucitite £ £ plagioclase < sanidine £
Leucite tephrite £ £ £ – < 10%
Leucite basanite £ £ £ – > 10%
Leucite phonolite £ £ – £ –

£ = present; – = absent.
a These rocks may also contain some nepheline.
b Includes products of its exsolution.

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19

2.9 LAMPROPHYRES (5) hydrothermal alteration of olivine, pyrox-


ene, biotite, and plagioclase, when present,
Lamprophyres are a diverse group of rocks that is common
chemically cannot be separated easily from (6) calcite, zeolites, and other hydrothermal
other normal igneous rocks. Traditionally they minerals may appear as primary phases
have been distinguished on the following char- (7) they tend to have contents of K2O and/or
acteristics: Na2O, H2O, CO2, S, P2O5 and Ba that are
(1) they normally occur as dykes and are not relatively high compared with other rocks
simply textural varieties of common plu- of similar composition.
tonic or volcanic rocks The Subcommission no longer endorses the
(2) they are porphyritic, mesocratic to melano- terms “lamprophyric rocks”, or “lamprophyre
cratic (M' = 35 – 90) but rarely holomelano- clan”, as used by Le Maitre et al. (1989) and
cratic (M' > 90) Rock (1991) to encompass lamprophyres, lam-
(3) feldspars and/or feldspathoids, when proites and kimberlites, because lamproites
present, are restricted to the groundmass and kimberlites are best considered independ-
(4) they usually contain essential biotite (or ently of lamprophyres.
Fe-phlogopite) and/or amphibole and The recommended mineralogical classifica-
sometimes clinopyroxene tion of these rocks is given Table 2.9.

Table 2.9. Classification and nomenclature of lamprophyres based on their mineralogy

Light-coloured constituents Predominant mafic minerals


biotite > hornblende, hornblende, brown amphibole,
feldspar foid ±diopsidic augite, diopsidic augite, Ti-augite,
(±olivine) ±olivine olivine, biotite

or > pl – minette vogesite –


pl > or – kersantite spessartite –
or > pl feld > foid – – sannaite
pl > or feld > foid – – camptonite
– glass or foid – – monchiquite

or = alkali feldspar; pl = plagioclase; feld = feldspar; foid = feldspathoid.


Source: Modified from Streckeisen (1978, p.11).
Note: Alnöite and polzenite are no longer in the lamprophyre classification and rocks of this
type should now be named according to the melilite-bearing rock classification (p.11).

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20 2 Classification and nomenclature

2.10 CHARNOCKITIC ROCKS may be applied to certain fields.


However, as one of the characteristics of
This classification should be used only if the charnockites is the presence of various types
rock is considered to belong to the charnockitic of perthite, this raises the common problem of
suite of rocks, which is characterized by the how to distribute the perthites between A and
presence of orthopyroxene (or fayalite plus P. The Subcommission has, therefore, recom-
quartz) and, in many of the rocks, perthite, mended that in charnockitic rocks the perthitic
mesoperthite or antiperthite (Streckeisen, 1974, feldspars should be distributed between A and
1976). They are often associated with norites P in the following way:
and anorthosites and are closely linked with Perthite — assign to A as the major component
Precambrian terranes. is alkali feldspar.
Although many show signs of metamorphic Mesoperthite — assign equally between A and
overprinting, such as deformation and recrys- P as the amounts of the alkali feldspar and
tallization, they conform to the group of “igne- plagioclase (usually oligoclase or andesine)
ous and igneous-looking rocks” and have, components are roughly the same.
therefore, been included in the classification Antiperthite — assign to P as the major compo-
scheme. nent is andesine with minor albite as the
The classification is based on the QAP trian- alkali feldspar phase.
gle, i.e. the upper half of the QAPF double To distinguish those charnockitic rocks that
triangle (Fig. 2.4, p.22). The general names for contain mesoperthite it is suggested that the
the various fields are given in Table 2.10, prefix m-, being short for mesoperthite, could
together with a number of special names that be used, e.g. m-charnockite.

Table 2.10. Nomenclature of charnockitic rocks


QAPF
General name Special name
field
2 orthopyroxene alkali feldspar granite alkali feldspar charnockite
3 orthopyroxene granite charnockite
4 orthopyroxene granodiorite opdalite or charno-enderbite
5 orthopyroxene tonalite enderbite
6 orthopyroxene alkali feldspar syenite –
7 orthopyroxene syenite –
8 orthopyroxene monzonite mangerite
9 monzonorite (orthopyroxene monzodiorite) jotunite
10 norite (orthopyroxene diorite), anorthosite (M < 10) –

Source: Modified from Streckeisen (1974, p.355).

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21

2.11 PLUTONIC ROCKS IUGS Subcommission (Streckeisen, 1973,


1976). The diagram is based on the fundamen-
This classification should be used only if the tal work of many earlier petrologists, which is
rock is considered to be plutonic, i.e. it is fully summarized by Streckeisen (1967).
assumed to have formed by slow cooling and The root names for the classification are
has a relatively coarse-grained ( > 3 mm) given in Fig. 2.4 and the field numbers in Fig.
texture in which the individual crystals can 2.5.
easily be seen with the naked eye. To use the classification the modal amounts
There is, of course, a gradation between plu- of Q, A, P, and F must be known and recalcu-
tonic rocks and volcanic rocks and the Sub- lated so that their sum is 100%.
commission suggests that, if there is any uncer- For example, a rock with Q = 10%, A = 30%,
tainty as to which classification to use, the P = 20%, and M = 40% would give recalculated
plutonic root name should be given and pre- values of Q, A, and P as follows:
fixed with the term “micro”. For example, Q = 100 £ 10 / 60 = 16.7
microsyenite could be used for a rock that was A = 100 £ 30 / 60 = 50.0
considered to have formed at considerable P = 100 £ 20 / 60 = 33.3
depth even if many of the individual crystals Although at this stage the rock can be plotted
could not be seen with the naked eye. directly into the triangular diagram, if all that is
The classification is based on modal param- required is to name the rock it is easier to
eters and is divided into three parts: determine the plagioclase ratio where:
(1) if M is less than 90% the rock is classified plagioclase ratio = 100 £ P / (A + P)
according to its felsic minerals, using the as the non-horizontal divisions in the QAPF
now familiar QAPF diagram (Fig. 2.4), diagram are lines of constant plagioclase ratio.
often simply referred to as the QAPF clas- The field into which the rock falls can then
sification or the QAPF double triangle easily be determined by inspection.
(section 2.11.1) In the above example rock the plagioclase
(2) if M is greater or equal to 90%, it is an ratio is 40 so that it can be seen by inspection
ultramafic rock and is classified according that the rock falls into QAPF field 8* (Fig. 2.5)
to its mafic minerals, as shown in section and should, therefore, be called a quartz
2.11.2, p.28 monzonite (Fig. 2.4).
(3) if a mineral mode is not yet available, the Similarly, a rock with A = 50%, P = 5%, F =
“field” classification of section 2.11.3, 30%, and M = 15% would recalculate as fol-
p.29, may be used provisionally. lows:
A = 100 £ 50 / 85 = 58.8
P = 100 £ 5 / 85 = 5.9
2.11.1 PLUTONIC QAPF CLASSIFICATION F = 100 £ 30 / 85 = 35.3
(M < 90%) Plagioclase ratio = 9
This rock falls into QAPF field 11 and should,
The modal classification of plutonic rocks is therefore, be called a foid syenite. Further-
based on the QAPF diagram and was the first more, if the major foid in the rock is nepheline,
to be completed and recommended by the it should be called a nepheline syenite.

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22 2 Classification and nomenclature

Q
quartzolite
90 90

quartz-rich
granitoid
granodiorite
60 60
tonalite
alkali feldspar quartz monzodiorite
granite granite quartz monzogabbro
quartz (syeno- (monzo- quartz diorite
alkali feldspar granite) granite) quartz gabbro
syenite quartz anorthosite
10 35 65 90
20 20
alkali feldspar quartz quartz monzodiorite
syenite syenite monzonite monzogabbro
5 5
syenite monzonite
A foid-bearing foid-bearing
P diorite
syenite monzonite gabbro
10 10
10 50 90 anorthosite
foid-bearing
alkali feldspar foid foid-bearing diorite
syenite foid monzodiorite foid-bearing gabbro
monzosyenite foid foid-bearing anorthosite
monzogabbro
foid syenite foid-bearing monzodiorite
foid-bearing monzogabbro

foid diorite
60 60 foid gabbro

foidolite

F
Fig. 2.4. QAPF modal classification of plutonic rocks (based on Streckeisen, 1976, Fig. 1a).
The corners of the double triangle are Q = quartz, A = alkali feldspar, P = plagioclase and F
= feldspathoid. This diagram must not be used for rocks in which the mafic mineral content,
M, is greater than 90%.

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2.11 Plutonic rocks 23

The location of the numerical QAPF fields are subfield 3a, whereas subfield 3b has contained
shown in Fig. 2.5. terms such as adamellite and quartz monzonite.
Field 2 (alkali feldspar granite) — rocks in In the European literature, however, granite
this field have been called alkali granite by has been used to cover both subfields, a view
many authors. The Subcommission, however, adopted by the Subcommission. The Subcom-
recommends that the term peralkaline granite mission has also recommended that the term
be used instead for those rocks that contain adamellite should no longer be used, as it has
sodic amphiboles and/or sodic pyroxenes. The been given several meanings, and does not
term alaskite may be used for a light-coloured even occur in the Adamello Massif as com-
(M < 10%) alkali feldspar granite. monly defined (Streckeisen, 1976). Although
Field 3 (granite) — the term granite has been the term quartz monzonite has also been used
used in many senses; in most English and with several meanings, the Subcommission
American textbooks it has been restricted to decided to retain the term in its original sense,
i.e. for rocks in field 8*.
Field 4 (granodiorite) — the most widespread
Q
rocks in this field are granodiorites, commonly
90 1a 90 containing oligoclase, more rarely andesine. It
seems advisable to add the condition that the
1b average composition of the plagioclase should
be An0 – An50 in order to distinguish the common
60 60
granodiorites from the rare granogabbro in which
the plagioclase is An50 – An100.
2 3a 3b 4 5 Field 5 (tonalite) — the root name tonalite
should be used whether hornblende is present
10 35 65 90
20 20 or not. Trondhjemite and plagiogranite (as
6* 7* 8* 9* 10* used by Russian petrologists) may be used for
5 5
A 6 7 8 9 10 P a light-coloured (M < 10%) tonalite.
6' 7' 8' 9' 10' Field 6' (alkali feldpar nepheline syenite) —
10 10
10 50 90
the general term agpaite may be used for per-
alkaline varieties characterized by complex Zr
11 12 13 14
and Ti minerals, such as eudialyte, rather than
simple minerals such as zircon and ilmenite.
Field 8 (monzonite) — many so-called
60 60
“syenites” fall into this field.
15 Field 9 (monzodiorite, monzogabbro) — the
two root names in this field are separated
according to the average composition of their
plagioclase – monzodiorite (plagioclase An0 –
F An50 ), monzogabbro (plagioclase An50 – An100).
Fig. 2.5. QAPF field numbers (Streckeisen, The terms syenodiorite and syenogabbro may
1976, Fig. 1a). The fields 6* to 10* are be used as comprehensive names for rocks
slightly silica oversaturated variants of fields between syenite and diorite/gabbro, i.e. for
6 to 10, respectively, while 6' to 10' are monzonites (field 8) and monzodiorite/monzo-
slightly silica undersaturated variants. gabbro, respectively.

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24 2 Classification and nomenclature

Field 10 (diorite, gabbro, anorthosite) — the monzogabbro) — the two root names in this
three root names in this field are separated field are separated according to the average
according to the colour index and the average composition of their plagioclase, i.e. foid
composition of their plagioclase – anorthosite monzodiorite (plagioclase An0 – An50), foid
(M < 10%), diorite (M > 10%, plagioclase An0 monzogabbro (plagioclase An50 – An100).
– An50), gabbro (M > 10%, plagioclase An50 – Wherever possible, replace the term foid with
An100). Gabbros may be further subdivided, as the name of the most abundant feldspathoid.
shown below. Either of the two synonymous The term essexite may be applied to nepheline
terms dolerite or diabase may be used for monzodiorite or nepheline monzogabbro.
medium-grained gabbros rather than the term Field 14 (foid diorite, foid gabbro) — again
microgabbro, if required. the two root names in this field are separated
Gabbroic rocks — the gabbros (sensu lato) of according to the average composition of their
QAPF field 10, may be further subdivided plagioclase, i.e. foid diorite (plagioclase An0 –
according to the relative abundances of their An50), foid gabbro (plagioclase An50 – An100).
orthopyroxene, clinopyroxene, olivine and Wherever possible, replace the term foid with
hornblende as shown in Fig. 2.6. Some of the the name of the most abundant feldspathoid.
special terms used are: Two special terms may continue to be used,
Gabbro (sensu stricto) = plagioclase and theralite for nepheline gabbro and teschenite
clinopyroxene for analcime gabbro.
Norite = plagioclase and orthopyroxene Field 15 (foidolite) — this field contains
Troctolite = plagioclase and olivine rocks in which the light-coloured minerals are
Gabbronorite = plagioclase with almost equal almost entirely foids and is given the root
amounts of clinopyroxene and orthopyroxene name foidoliteto distinguish it from the volcanic
Orthopyroxene gabbro = plagioclase and equivalent which is called foidite. As these rocks
clinopyroxene with minor amounts of are rather rare the field has not been subdivided.
orthopyroxene Again note that the most abundant foid should
Clinopyroxene norite = plagioclase and appear in the name, e.g. nephelinolite (urtite,
orthopyroxene with minor amounts of ijolite, melteigite).
clinopyroxene Leuco- and Mela- variants — for rocks in the
Hornblende gabbro = plagioclase and horn- QAPF classification the Subcommission sug-
blende with pyroxene < 5%. gests (Streckeisen, 1973, p.30; 1976, p.24) that
Field 11 (foid syenite) — although foid syenite the prefixes leuco- and mela- may be used to
is the root name, the most abundant foid present designate the more felsic (lower colour index)
should be used in the name, e.g. nepheline and mafic (higher colour index) types within
syenite, sodalite syenite. each rock group, when compared with the
Field 12 (foid monzosyenite) — the root “normal” types in that group.As the threshold
name foid monzosyenite may be replaced by values of M' varies from rock group to rock
the synonym foid plagisyenite. Wherever pos- group, the limits are shown diagrammatically
sible, replace the term foid with the name of the in Fig. 2.7 and Fig. 2.8 for the rock groups to
most abundant feldspathoid. Miaskite, which which the terms may be applied. The prefixes
contains oligoclase, may also be used. should precede the root name, e.g. biotite
Field 13 (foid monzodiorite, foid leucogranite, biotite melasyenite.

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2.11 Plutonic rocks 25

anorthosite
Plag
ANORTHOSITES
90 90

(LEUCO-)

65 65
gabbro
gabbronorite troctolite
norite olivine gabbro GABBROIDS
olivine gabbronorite
olivine norite
35 35

(MELA-)

10 10
plagioclase-bearing ultramafic rocks ULTRAMAFIC ROCKS
Px Ol

Plag Plag
norite gabbronorite gabbro
clinopyroxene orthopyroxene
norite gabbro
10 10
5 95
plagioclase-bearing pyroxenite
Opx Cpx
Plag
anorthosite
ANORTHOSITES
90 90

(LEUCO-)

gabbro 65 65
gabbronorite hornblende gabbro
norite GABBROIDS
pyroxene hornblende
gabbro/gabbronorite/norite
35 35

plagioclase-bearing plagioclase-bearing (MELA-)


hornblende pyroxenite pyroxene hornblendite
10 10
ULTRAMAFIC ROCKS
Px plagioclase-bearing plagioclase-bearing Hbl
pyroxenite hornblendite

Fig. 2.6. Modal classification of gabbroic rocks based on the proportions of plagioclase
(Plag), pyroxene (Px), olivine (Ol), orthopyroxene (Opx), clinopyroxene (Cpx), and
hornblende (Hbl) (after Streckeisen, 1976, Fig. 3). Rocks falling in the shaded areas of either
triangular diagram may be further subdivided according to the diagram pointed to by the
arrows.

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26 2 Classification and nomenclature

Q = 60 to 20 Q = 20 to 5

P' 0 – 10 10 – 65 65 – 90 90 – 100 0 – 10 10 – 35 35 – 65 65 – 90 90 – 100

Field 2 3 4 5 6* 7* 8* 9* 10*

M' An < 50 An > 50 An < 50 An > 50


0
These are leuco- varieties of the rocks below
quartz
alkali feldspar syenite
alkali feldspar

anorthosite
granite

10
granite

granodiorite

quartz

quartz syenite

quartz monzonite

20 quartz monzodiorite
tonalite

quartz monzogabbro

quartz diorite
30

40 quartz gabbro

50

These are mela- varieties of the rocks above

60

Fig. 2.7. Use of the terms mela- and leuco- with QAPF plutonic rocks with Q > 5%
(after Streckeisen, 1976, Fig. 5). Abbreviations: P' = 100 * P / (A + P); M' = colour
index; An = anorthite content of plagioclase.

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2.11 Plutonic rocks 27

Q = 0 to 5 or F = 0 to 10 F = 10 to 60 F =
60 to 100
P' 0–10 10–35 35–65 65–90 90–100 0–10 10–50 50–90 90–100

Field 6 7 8 9 10 11 12 13 14 15

M' An<50An>50 An<50An>50 neph* leuc*


0
anorthosite
alkali feldspar

10
syenite

foid syenite
These are leuco- varieties of the rocks below

italite
urtite
syenite

20

foid monzodiorite and foid monzogabbro


foid monzosyenite
monzonite

30
monzodiorite

diorite
monzogabbro

foid diorite and foid gabbro


40
malignite

fergusite
ijolite
gabbro

50

60

70
shonkinite

These are mela- varieties of the rocks above


missourite
melteigite

80

Fig. 2.8. Use of the terms mela- and leuco- with QAPF plutonic rocks with Q < 5% or
F > 0% (after Streckeisen, 1976, Fig. 5). Abbreviations: P' = 100 * P / (A + P); M' = colour
index; An = anorthite content of plagioclase; neph* = nepheline is the predominant foid;
leuc* = leucite is the predominant foid. Note: some special names are applicable in certain
parts of the diagram.

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28 2 Classification and nomenclature

2.11.2 ULTRAMAFIC ROCKS (M > 90%) (Streckeisen, 1973, 1976) recommended two
diagrams, both of which are shown in Fig. 2.9.
The ultramafic rocks are classified according One is for rocks consisting essentially of olivine,
to their content of mafic minerals, which consist orthopyroxene, and clinopyroxene, and the
essentially of olivine, orthopyroxene, other for rocks containing hornblende,
clinopyroxene, hornblende, sometimes with pyroxenes, and olivine.
biotite, and various but usually small amounts Peridotitesare distinguished from pyroxenites
of garnet and spinel. The Subcommission by containing more than 40% olivine. This

Ol
dunite
90 90

harzburgite wehrlite
PERIDOTITE

lherzolite

olivine 40 40
orthopyroxenite olivine
clinopyroxenite
olivine websterite PYROXENITE
orthopyroxenite clinopyroxenite
websterite
Opx 10 90 Cpx

Ol
dunite
90 90

pyroxene hornblende
peridotite peridotite
PERIDOTITE
pyroxene
hornblende
peridotite
olivine 40 40
pyroxenite olivine
olivine olivine hornblendite
hornblende pyroxene PYROXENITE AND
pyroxenite hornblendite HORNBLENDITE
pyroxenite hornblendite

Px 10 90 Hbl
hornblende pyroxenite pyroxene hornblendite

Fig. 2.9. Modal classification of ultramafic rocks based on the proportions of olivine (Ol),
orthopyroxene (Opx), clinopyroxene (Cpx), pyroxene (Px) and hornblende (Hbl) (after
Streckeisen, 1973, Figs. 2a and 2b).

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2.11 Plutonic rocks 29

value, rather than 50%, was chosen because 2.11.3 PROVISIONAL “FIELD” CLASSIFICATION
many lherzolites contain up to 60% pyroxene.
The peridotites are basically subdivided into The “field” classification of plutonic rocks
dunite (or olivinite if the spinel mineral is should be used only as a provisional measure
magnetite), harzburgite, lherzolite and wehrlite. when an accurate mineral mode is not yet
The pyroxenites are further subdivided into available. When available, the plutonic QAPF
orthopyroxenite, websterite and clinopyrox- diagram should be used.
enite. The classification is based on a simplified
Ultramafic rocks containing garnet or spinel version of the plutonic QAPF diagram (Streck-
should be qualified in the following manner. If eisen, 1976) and is shown in Fig. 2.10. If the
garnet or spinel is less than 5% use garnet- suffix “-oid” is felt to be linguistically awk-
bearing peridotite, chromite-bearing dunite etc. ward then the alternative adjectival form “-ic
If garnet or spinel is greater than 5% use garnet rock” may be used, i.e. use syenitic rock in
peridotite, chromite dunite etc. place of syenitoid.

60 60

granitoid
65
20 20
dioritoid
syenitoid gabbroid
A anorthosite P
10 10
foid foid dioritoid
syenitoid foid gabbroid

60 60
foidolite

F
Fig. 2.10. Preliminary QAPF classification of plutonic rocks for field
use (after Streckeisen, 1976, Fig. 6).

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30 2 Classification and nomenclature

2.12 VOLCANIC ROCKS both fields 3a and 3b. Liparite may be used as
a synonym. The term rhyodacite, which has
This classification should be used only if the been used ambiguously for rocks of fields 3b
rock is considered to be volcanic, i.e. it is and 4, can be used for transitional rocks be-
assumed to have been associated with volcan- tween rhyolite and dacite without attributing it
ism and has a relatively fine-grained texture in to a distinct field.
which most of the individual crystals cannot be Fields 4 and 5 (dacite) — rocks in both these
seen with the naked eye. fields are covered by the root name dacite in the
The classification of volcanic rocks is di- broad sense. Volcanic rocks of field 5, to which
vided into three parts: terms such as “plagidacite” and “quartz andes-
(1) if a mineral mode can be determined, use ite” have been applied, are frequently also
the QAPF classification (Fig. 2.11) of sec- described as dacite, which is the recommended
tion 2.12.1 name.
(2) if a mineral mode cannot be determined Fields 6 (alkali feldspar trachyte), 7 (trach-
and a chemical analysis is available, use yte), 8 (latite) — rocks with these root names,
the TAS classification of section 2.12.2, which contain no modal foids but do contain
p.33 nepheline in the norm, may be qualified with
(3) if neither a mineral mode nor chemical “ne-normative” to indicate that they would fall
analysis is yet available, the “field” classi- in subfields 6'–8', respectively. Peralkaline tra-
fication of section 2.12.3, p.39, may be chyte, rather than alkali trachyte, should be
used provisionally. used for trachytes containing sodic pyroxene
and/or sodic amphibole.
Fields 9 and 10 (basalt, andesite)— these two
2.12.1 VOLCANIC QAPF CLASSIFICATION fields contain the large majority of volcanic
(M < 90%) rocks. Basalt and andesite are tentatively sepa-
rated using colour index, at a limit of 40 wt %
This classification should be used only if the or 35 vol %, and 52% SiO2 as shown in Table
rock is considered to be volcanic and if a 2.11. A plagioclase composition (at a limit of
mineral mode can be determined (Streckeisen, An50) is less suitable for the distinction be-
1978 and 1979). The root names for the classi- tween basalt and andesite, because many an-
fication are given in Fig. 2.11. desites commonly contain “phenocrysts” of
The numbers of the QAPF fields are the same
as those for the plutonic rock classification Table 2.11. Classification of QAPF fields 9
(see Fig. 2.5, p.23) except that field 15 has been and 10 volcanic rocks into basalt and
divided into three subfields (Fig. 2.12, p.32). andesite, using colour index and wt % SiO2
Field 2 (alkali feldspar rhyolite) — the root
name corresponds with alkali feldspar granite. Colour index SiO2 wt %
The term peralkaline rhyolite, in preference to vol % wt % < 52 > 52
alkali rhyolite, can be used when the rock
contains alkali pyroxene and/or amphibole. > 35 > 40 basalt mela-andesite
The name rhyolite may be replaced by the
synonym liparite. < 35 < 40 leuco-basalt andesite
Fields 3a and 3b (rhyolite) — in an analogous
manner to the granites, this root name covers Source: Streckeisen (1978, Fig. 2).

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2.12 Volcanic rocks 31

90 90

60 60

alkali feldspar rhyolite


rhyolite dacite

quartz
alkali feldspar
trachyte 20 10 35 65 90 20
quartz quartz
alkali feldspar trachyte latite
trachyte 5 basalt
trachyte latite andesite
A foid-bearing foid-bearing
P
foid-bearing trachyte latite
alkali feldspar 10 50 90
10
trachyte

tephritic
phonolite basanite (olivine > 10%)
phonolite tephrite (olivine < 10%)

phonolitic basanite
(olivine > 10%)
60 60
phonolitic tephrite
(olivine < 10%)

phonolitic foidite tephritic foidite

90 90

foidite
F
Fig. 2.11. QAPF modal classification of volcanic rocks (based on Streckeisen, 1978, Fig. 1).
The corners of the double triangle are Q = quartz, A = alkali feldspar, P = plagioclase and F =
feldspathoid. This diagram must not be used for rocks in which the mafic mineral content, M,
is greater than 90%.

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32 2 Classification and nomenclature

labradorite or bytownite. Although this may Field 14 (basanite, tephrite) — these two root
seem rather unsatisfactory, it is unlikely that names are separated on the amount of olivine
many of these rocks will be classified using the in the CIPW norm. If normative olivine is
QAPF diagram, as the modes of most basalts greater than 10% the rock is called a basanite;
and andesites are difficult to determine accu- if less than 10% it is a tephrite. The nature of the
rately so that the TAS classification will have dominant foid should be indicated in the name,
to be used. e.g. nepheline basanite, leucite tephrite etc.
Field 11 (phonolite) — the root name phono- Field 15 (foidite sensu lato) — the general
lite is used in the sense of Rosenbusch for rocks root name of this field is foidite, but as these
consisting essentially of alkali feldspar, any rocks occur relatively frequently the field has
feldspathoid and mafic minerals. The nature of been subdivided into three: fields 15a , 15b and
the predominant foid should be added to the 15c as shown in Fig. 2.12.
root name, e.g. leucite phonolite, analcime Field 15a (phonolitic foidite) — wherever
phonolite, leucite-nepheline phonolite (with possible replace the term foidite with a more
nepheline > leucite) etc. Phonolites containing specific term, such as phonolitic nephelinite.
nepheline and/or haüyne as the main foids are Alternatively, the term alkali feldspar foidite
commonly described simply as “phonolite”. could be used as the root name, which would
Phonolites that contain sodic pyroxene and/or give specific terms such as sanidine nepheli-
sodic amphibole may be called peralkaline nite.
phonolite. Field 15b (tephritic foidite, basanitic foidite)
Field 12 (tephritic phonolite) — these rocks — these two root names are separated accord-
are rather rare. Although it was originally sug- ing to their olivine content, as in field 14.
gested that the term tephriphonolite is a syno- wherever possible replace the term foidite with
nym (Streckeisen, 1978), it is probably better a more specific term, such as tephritic leucitite,
to reserve this term for the root name of TAS basanitic nephelinite.
field U3, to indicate that the name has been Field 15c (foidite sensu stricto) — the root
given chemically and may not be identical to name is foidite and should be distinguished by
those of QAPF field 12. the name of the predominant foid, e.g. nephe-
Field 13 (phonolitic basanite, phonolitic linite, leucitite, analcimite.
tephrite) — these two root names are separated
on the amount of olivine in the CIPW norm. If A P
normative olivine is greater than 10% the rock
is called a phonolitic basanite; if less than 10% 60 60
it is a phonolitic tephrite. Although it was
originally suggested that the term phonote- 15a 15b
phrite was a synonym of phonolitic tephrite
(Streckeisen, 1978), it is probably better to
reserve this term for the root name of TAS field 90 90
15c
U2, to indicate that the name has been given
chemically and may not be identical to those of
F
QAPF field 13. There is no conflict if the term
phonobasanite is used as a synonym for pho- Fig. 2.12. Subdivision of volcanic QAPF
nolitic basanite, as the term is not used in TAS. field 15 into fields 15a, 15b and 15c.

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2.12 Volcanic rocks 33

2.12.2 THE TAS CLASSIFICATION determined contours of 10% normative F


in QAPF
The TAS (Total Alkali – Silica) classification (7) the boundary between the S fields and O
should be used only if: (for silica Oversaturated) fields was chosen
(1) the rock is considered to be volcanic where there was a density minimum
(2) a mineral mode cannot be determined, between volcanic rock series that were
owing either to the presence of glass or to alkaline and those that were calc-alkaline
the fine-grained nature of the rock (8) the boundaries between fields S1–S2–S3–
(3) a chemical analysis of the rock is avail- T were all made parallel to a pronounced
able. edge found in the distribution of analyses
The root names for the classification are of rocks that had been called trachyte
shown in Figs. 2.13 and 2.14, while the field (9) similarly, the boundaries between fields
symbols are given in Fig. 2.15. The classifica- U1–U2–U3–Ph were also drawn parallel
tion is easy to use as all that is required for most to each other. They are not at right angles
rocks are the values of Na2O, K2O and SiO2. to the line separating fields S from U.
However, if the analysis falls in certain fields, However, after the TAS classification was
additional calculations, such as the CIPW norm published, the Subcommission considered
(see Appendix C), must be performed in order whether or not it was possible to include some
to arrive at the correct root name. of the olivine- and pyroxene-rich (“high-Mg”)
The TAS classification was originally con- volcanic rocks, e.g. picrites, komatiites,
structed with the more common rock types in meimechites and boninites, into the scheme.
mind, using the following principles summa- After lengthy discussions this has been done
rized by Le Bas & Streckeisen (1991): by using MgO and TiO2 in conjunction with
(1) each field was chosen to accord as closely TAS (see Fig. 2.13, p.34). As a result these
as possible with the current usage of the rocks must be considered first, as they are not
root name with the help of data from the “normal” type of volcanic rocks for which
24 000 analyses of named fresh volcanic the TAS classification was originally designed.
rocks from the CLAIR and PETROS Similarly it has been found that nephelinites
databases (Le Maitre, 1982) and melanephelinites both fall in fields F and
(2) fresh rocks were taken to be those in which U1 and must therefore be excluded before
H2O+ < 2% and CO2 < 0.5% using theTAS classification.
(3) each analysis was recalculated to 100% on It must also be stressed that the TAS
an H 2O and CO2 free basis classification is purely descriptive, and that no
(4) wherever possible, the boundaries were genetic significance is implied. Furthermore,
located to minimize overlap between adja- analyses of rocks that are weathered, altered,
cent fields metasomatized, metamorphosed or have
(5) the vertical SiO2 boundaries between the undergone crystal accumulation should be used
fields of basalt, basaltic andesite, andesite with caution, as spurious results may be
and dacite were chosen to be those in obtained. As a general rule it is suggested that
common use only analyses with H2O+ < 2% and CO2 < 0.5%
(6) the boundary between the S (for silica should be used, unless the rock is a picrite,
Saturated) fields and the U (for silica komatiite, meimechite or boninite, when this
Undersaturated) fields was chosen to be restriction is withdrawn. The application of
roughly parallel with the empirically TAS to altered rocks is discussed by Sabine et

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34 2 Classification and nomenclature

al. (1985), who found that many low-grade As previously explained not all rock types
metavolcanic rocks could be satisfactorily fall neatly into the TAS fields so that one must
classified. check to see if the rock being classified is one
Before using the classification the two follow- of these types before using Fig. 2.14 directly.
ing procedures must be adopted: The rocks in question are the “high-Mg” vol-
(1) analyses must be recalculated to 100% on canic rocks, i.e. picrite, komatiite, meimechite
an H2O and CO2 free basis or boninite and the nephelinites and
(2) if a CIPW norm has to be calculated to melanephelinites which fall in fields F and U1.
determine the correct root name, the “High-Mg” volcanic rocks — these are may
amounts of FeO and Fe2O3 should be left be distinguished by the following criteria as
as determined. If only total iron has been shown in Fig. 2.13:
determined, it is up to the user to justify the (1) if SiO2 > 52%, MgO > 8% and TiO2 <
method used for partitioning the iron be- 0.5%, the rock is a boninite
tween FeO and Fe2O3. One method that (2) if 52% > SiO2 > 30%, MgO > 18% and
can be used to estimate what the FeO and (Na2O + K2O ) < 2%, then the rock is a
Fe2O3 would have been is that of Le Maitre komatiite if TiO2 < 1% or a meimechite if
(1976). Remember, it is the feeling of the TiO2 > 1%
Subcommission that rocks should be (3) if 52% > SiO2 > 30%, MgO > 12%, and
named according to what they are, and not (Na2O + K2O ) < 3%, it is a picrite.
according to what they might have been. Note that this scheme is different from that

Na2 O + K2 O wt %
4 basanite andesite
tephrite basaltic
3 andesite
2 foidite picrobasalt basalt

1 boninite
(MgO > 8% and TiO2 < 0.5%)
0
37 41 45 49 53 57 61 65
SiO2 wt %

Na2 O + K2 O wt %
3

2
picrite
komatiite TiO2 < 1%
1
meimechite TiO2 > 1%
0
12 18 24 30
MgO wt %
Fig. 2.13. Chemical classification and separation of the “high-Mg” volcanic rocks boninite,
komatiite, meimechite and picrite prior to using the TAS classification. If a rock falls in the
shaded rectangle of the TAS (upper) diagram, check in the lower diagram to see that it is not a
komatiite, meimechite or picrite, before naming it as a foidite, picrobasalt or basalt. Similarly, a
rock with SiO2 > 52% should be checked to see that it is not a boninite (after Le Bas, 2000).

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2.12 Volcanic rocks 35

Na2 O + K2 O wt %
15
phonolite
13

tephriphonolite trachyte
11 (q < 20%)
trachydacite
foidite (q > 20%)
phonotephrite
9 rhyolite
trachyandesite
tephrite
(ol < 10%) basaltic
7 basanite trachy-
(ol > 10%) trachy- andesite
basalt
5 dacite
basaltic andesite
3 andesite
picro- basalt
basalt
1

37 41 45 49 53 57 61 65 69 73 77
SiO2 wt %
ULTRABASIC BASIC INTERMEDIATE ACID

45 52 63

Further subdivisions trachybasalt basaltic trachyandesite


of shaded fields trachyandesite

Na2O – 2.0 ≥ K2O hawaiite mugearite benmoreite

Na2O – 2.0 < K2O potassic shoshonite latite


trachybasalt

Fig. 2.14. Chemical classification of volcanic rocks using TAS (total alkali–silica diagram)
(after Le Bas et al., 1986, Fig. 2). Rocks falling in the shaded areas may be further subdivided
as shown in the table pointed to by the arrow. The line between the foidite field and the
basanite–tephrite field is dashed to indicate that further criteria must be used to separate these
types. Abbreviations: ol = normative olivine; q = normative 100 * Q / (Q + or + ab + an).

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36 2 Classification and nomenclature

Na2 O + K2 O wt%
15
(52.5, 14) Ph
13

(48.4, 11.5) U3 (57.6, 11.7)


11
F T
(45, 9.4) U2 (53, 9.3) R
9
S3 (69, 8)
7 (41, 7) (49.4, 7.3) S2 (63, 7)
U1
S1 (57, 5.9)
5
(45, 5) (52, 5) O3
O2
3 (41, 3) (45, 3) O1
B
Pc
1

37 41 45 49 53 57 61 65 69 73 77
SiO2 wt%

Fig. 2.15. Field symbols and coordinate points of TAS (after Le Bas et al., 1986, Fig. 1).
The numbers in brackets are the coordinates of the intersections of the lines.

published in Le Maitre et al. (1989, Fig. B.12). The field letters of the TAS diagram shown
The lowering of MgO for picrite from 18% to above are now described in further detail.
12% and increasing the alkalis from 2% to 3% Field B (basalt) — the root name may be
makes many rocks into picrites that previously divided into alkali basalt and subalkali basalt
were classified as picrobasalt. according to the state of silica saturation – if the
Nephelinites and melanephelinites — it has CIPW norm contains nepheline (ne) the rock is
been found that nephelinites, melanephelinites an alkali basalt, if not the rock is a subalkali
and certain leucitites fall in both fields U1 and basalt. This is based on the principle of the
F, which is why the boundary between the two basalt tetrahedron (Yoder & Tilley, 1962)
fields is dashed. They are distinguished by the The subalkali basalt group includes a large
following rules (after Le Bas, 1989): number of basalt varieties such as calc-alkali
(1) if normative ne > 20% the rock is a basalt (high-alumina basalt), mid-ocean ridge
nephelinite. basalt, tholeiitic basalt, transitional basalt etc.
(2) if normative ne < 20% and ab is present Although none of these have been defined, but
but is < 5% the rock is a melanephelinite. only categorized, the Subcommission does rec-
If the rock is none of these six types you can use ommend that tholeiitic basalt should be used in
TAS diagram in Fig. 2.14 directly. preference to the term tholeiite (see Glossary).

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2.12 Volcanic rocks 37

Na2 O + K2 O wt % consists of various planar surfaces (one for


5
48.5 52 each normative type) none of which is perpen-
alkali dicular to the TAS surface, so that an exact
basalt correlation between TAS and silica saturation
4 97% can never be achieved.
overlap Bellieni et al. (1983) have investigated this
3 problem using 7594 basalt analyses as defined
by TAS. A synopsis of their results is shown in
subalkali basalt
2.2 Fig. 2.16 which is divided into three fields.
89%
2 Assuming a basalt is equally likely to be alkali
1.4 or subalkali, an analysis falling in the alkali
1 basalt field has a 97% chance of being cor-
45 46 47 48 49 50 51 52 rectly classified, while one falling in the
SiO2 wt % subalkali basalt field has an 89% chance of
Fig. 2.16. Likelihood of correctly classifying being correctly classified. An analysis falling
alkali basalt and subalkali basalt using TAS in the overlap field is three times more likely to
(after Bellieni et al. 1983) assuming equal
be an alkali basalt than a subalkali basalt.
chances of a basalt being alkali or subalkali.
Subdivision of fields B (basalt), O1 (basaltic
andesite), O2 (andesite), O3 (dacite), R (rhyo-
lite) — the root names may be qualified using
The TAS diagram has also been used many the terms low-K, medium-K, and high-K as
times to separate alkali basalt from subalkali shown in Fig. 2.17. This is in accord with the
basalt, resulting in numerable lines and curves concept developed by Peccerillo & Taylor
being proposed. This is due to the fact that the (1976), but the lines have been slightly modi-
undersaturation plane in the basalt tetrahedron fied and simplified. It must be stressed that the

K2 O wt %
4 high-K
dacite and rhyolite
basaltic andesite

3
68, 2.9
andesite
basalt

medium-K
2

48, 1.2
1 68, 1.2 low-K
48, 0.3

45 49 53 57 61 65 69 73 77
SiO2 wt %

Fig. 2.17. Division of the basalt–rhyolite series into low-K, medium-K and high-K types.
Note that high-K is not synonymous with potassic. The thick stippled lines indicate the
equivalent position of some of the fields in the TAS diagram.

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38 2 Classification and nomenclature

20 Al2O3 wt%
comenditic rhyolite (= comendite)
comenditic trachyte 4.4
15
3 F eO + .4
> 1.
3 +4
FeO
Al 2O < 1.33
3
10
Al 2O
3

pantelleritic rhyolite (= pantellerite)


5 pantelleritic trachyte

0
0 2 4 6 8 10 12
Total iron as FeO wt%
Fig. 2.18. Classification of trachytes and rhyolites into comenditic and pantelleritic types
using the Al2O3 versus total iron as FeO diagram (after Macdonald, 1974). The coordinates of
the bottom left of the line are (0.45, 5.0) and the top right are (10.98, 19.0).

term high-K is not synonymous with potassic, salt according to the relative amounts of Na2O
as high-K rocks can have more Na2O than K2O. and K2O. If Na2O – 2 is greater than K2O the
Field R (rhyolite) — the root name may be rock is considered to be “sodic” and is called
further subdivided into peralkaline rhyolite, if hawaiite; if Na2O – 2 is less than K2O the rock
the peralkaline index, which is the molecular is considered to be “potassic” and is called
ratio (Na2O + K2O) / Al2O3, is greater than 1. potassic trachybasalt (see Fig. 2.14, p.35).
Field T (trachyte, trachydacite) — these two Field S2 (basaltic trachyandesite) — using
root names are separated by the function the same criterion as for field S1, the root name
100 * Q / (Q + an + ab + or) which is the may be divided into mugearite (“sodic”) and
normative equivalent of Q in QAPF. If the shoshonite (“potassic”).
value is less than 20% the rock is trachyte; if Field S3 (trachyandesite) — using the same
greater than 20% it is trachydacite. Trachytes criterion as for field S1, the root name may be
may be further subdivided into peralkaline divided into benmoreite (“sodic”) and latite
trachytes, if the peralkaline index > 1. (“potassic”).
Peralkaline rhyolites and trachytes — the Field U1 (basanite, tephrite) — if normative
Subcommission has considered it useful to ol > 10 % the rock is a basanite, if ol < 10% it
further subdivide these rocks into comenditic is a tephrite.
rhyolite (= comendite), comenditic trachyte, Field F (foidite) — before deciding that the
pantelleritic rhyolite (= pantellerite), and pan- rock should be named a foidite check to see if
telleritic trachyte according to the method of it is a melilitite, using the following rules:
Macdonald (1974), which is based on the rela- 1) if the rock does not contain kalsilite but has
tive amounts of Al2O3 versus total iron as FeO normative cs (dicalcium silicate or larnite)
as shown in Fig. 2.18. > 10% and K2O < Na2O, then it is a
Field Ph (phonolite) — phonolites may be melilitite (modal olivine < 10%) or an
further subdivided into peralkaline phonolites, olivine melilitite (modal olivine > 10%)
if the peralkaline index > 1. 2) if normative cs > 10%, K2O > Na2O and
Field S1 (trachybasalt) — the root name may K2O > 2%, then it is a potassic melilitite
be divided into hawaiite and potassic trachyba- (modal olivine < 10%) or a potassic olivine

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2.12 Volcanic rocks 39

melilitite (modal olivine > 10%). The lat-


ter has been termed katungite, which Q
mineralogically is a kalsilite-leucite-
olivine melilitite
3) if normative cs is present but is < 10%,
then the rock is a melilite nephelinite or a 60 60
melilite leucitite according to the nature of
the dominant feldspathoid mineral.
The rock should now be named a foidite but rhyolitoid dacitoid
wherever possible this term should be replaced 20 65 20
with a more specific term according to the
andesitoid
dominant feldspathoid mineral. trachytoid
basaltoid
A P
10 10

2.12.3 PROVISIONAL “FIELD” CLASSIFICATION phonolitoid tephritoid

The “field” classification of volcanic rocks


should be used only as a provisional measure
60 60
when neither an accurate mineral mode nor a
foiditoid
chemical analysis is yet available. When either
become available, the volcanic QAPF diagram
or the TAS diagram should be used.
The classification is based on a simplified F
version of the volcanic QAPF diagram (Streck-
Fig. 2.19. Preliminary QAPF classification
eisen, 1978, 1979) and is shown in Fig. 2.19. If
of volcanic rocks for field use (after
the suffix “-oid” is felt to be linguistically
Streckeisen, 1976, Fig. 6).
awkward then the alternative adjectival form
“-ic rock” may be used, i.e. use dacitic rock in
place of dacitoid.

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40 2 Classification and nomenclature

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