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This chapter is a summary of all the published is presumed to have formed by slow cool-
recommendations of the IUGS Subcommission ing. Many rocks that occur in orogenic
on the Systematics of Igneous Rocks together belts have suffered some metamorphic
with some other decisions agreed to since the overprinting, so that it is left to the discre-
last Subcommission meeting in Prague in 1999. tion of the user to decide whether to use an
igneous or metamorphic term to describe
the rock (e.g. whether to use gneissose
2.1 PRINCIPLES granite or granitic gneiss).
(4) The term volcanic rock is taken to mean an
Throughout its deliberations on the problems igneous rock with an aphanitic texture, i.e.
of classification the Subcommission has been a relatively fine-grained (< 1 mm) rock in
guided by the following principles, most of which most of the individual crystals can-
which have been detailed by Streckeisen (1973, not be distinguished with the naked eye
1976) and Le Bas & Streckeisen (1991). and which is presumed to have formed by
(1) For the purposes of classification and relatively fast cooling. Such rocks often
nomenclature the term “igneous rock” is contain glass.
taken to mean “Massige Gesteine” in the (5) Rocks should be named according to what
sense of Rosenbusch, which in English they are, and not according to what they
can be translated as “igneous or igneous- might have been. Any manipulation of the
looking”. Igneous rocks may have crystal- raw data used for classification should be
lized from magmas or may have been justified by the user.
formed by cumulate, deuteric, metasomatic (6) Any useful classification should corre-
or metamorphic processes. Arguments as spond with natural relationships.
to whether charnockites are igneous or (7) The classification should follow as closely
metamorphic rocks are, therefore, irrel- as possible the historical tradition so that
evant in this context. well-established terms, e.g. granite, basalt,
(2) The primary classification of igneous rocks andesite, are not redefined in a drastically
should be based on their mineral contentor new sense.
mode. If a mineral mode is impossible to (8) The classification should be simple and
determine, because of the presence of glass, easy to use.
or because of the fine-grained nature of the (9) All official recommendations should be
rock, then other criteria may be used, e.g. published in English, and any translation
chemical composition, as in the TAS or transliteration problems should be solved
classification. by members in their individual countries.
(3) The term plutonic rock is taken to mean an However, publications by individual Sub-
igneous rock with a phaneritic texture, i.e. commission members, in languages other
a relatively coarse-grained (> 3 mm) rock than English, were encouraged in order to
in which the individual crystals can be spread the recommendations to as wide an
distinguished with the naked eye and which audience as possible.
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4 2 Classification and nomenclature
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2.1 Principles 5
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6 2 Classification and nomenclature
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7
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8 2 Classification and nomenclature
Tuff breccia — a pyroclastic rock in which may also be further qualified by the use of any
bombs and/or blocks range in amount from other suitable prefix, e.g. air-fall tuff, flow tuff,
25% to 75%. basaltic lapilli tuff, lacustrine tuff, rhyolitic
Lapilli tuff — a pyroclastic rock in which ash, vent agglomerate etc. The terms may also
bombs and/or blocks < 25%, and both lapilli be replaced by purely genetic terms, such as
and ash < 75%. hyaloclastite or base-surge deposit, whenever
Lapillistone — a pyroclastic rock in which it seems appropriate to do so.
lapilli > 75%.
Tuff or ash tuff — a pyroclastic rock in which
ash > 75%. These may be further divided into 2.2.3 MIXED PYROCLASTIC–EPICLASTIC DEPOSITS
coarse (ash) tuff (2 mm to 1/16 mm) and fine
(ash) tuff (less than 1/16 mm). The fine ash tuff For rocks which contain both pyroclastic and
may also be called dust tuff. Tuffs and ashes normal clastic (epiclastic) material the Sub-
may be further qualified by their fragmental commission suggests that the general term
composition, i.e a lithic tuff would contain a tuffites can be used within the limits given in
predominance of rock fragments, a vitric tuff a Table 2.4. Tuffites may be further divided
predominance of pumice and glass fragments, according to their average grain size by the
and a crystal tuff a predominance of crystal addition of the term “tuffaceous” to the normal
fragments. sedimentary term, e.g. tuffaceous sandstone.
Any of these terms for pyroclastic deposits
tuff breccia
25 25
lapillistone lapilli tuff tuff or ash tuff
lapilli 25 75 ash
(64 – 2 mm) (< 2 mm)
Fig. 2.1. Classification of polymodal pyroclastic rocks based on the proportions
of blocks/bombs, lapilli and ash (after Fisher, 1966).
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2.2 Pyroclastic rocks and tephra 9
Table 2.3. Classification and nomenclature of pyroclasts and well-sorted pyroclastic rocks
based on clast size
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10 2 Classification and nomenclature
CaO
calciocarbonatite
20 20
magnesiocarbonatite ferrocarbonatite
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11
Mel
90
melilitite
olivine
melilitite
10 10
melilite-bearing volcanic rocks
Ol Cpx
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12 2 Classification and nomenclature
Mafurite – £ – £ – £ £
Katungite – – £ £ £ £ £
Venanzite £ £ £ £ £ £ –
Coppaelite £ £ – £ £ – –
£ = present; – = absent.
Source: Mitchell & Bergman (1991, Table 2.3).
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13
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14 2 Classification and nomenclature
nesian ilmenite and phlogopite crystals, that Group II kimberlites are mineralogically dif-
are now generally believed to originate by the ferent and petrogenetically separate rock-types.
disaggregation of mantle-derived lherzolite, A definition of Group II kimberlites has not
harzburgite, eclogite and metasomatized peri- yet been agreed as they have been insuffi-
dotite xenoliths. Most diamonds, which are ciently studied. Mitchell (1986, 1994, 1995)
excluded from the above “definition”, belong has suggested that these rocks are not kimber-
to this suite of minerals but are much less litic at all, and should be termed “orangeite”, in
common. recognition of their distinct character and unique
Megacrysts are dominated by magnesian il- occurrence in the Orange Free State of South
menite, Ti-pyrope, diopside, olivine and en- Africa. Wagner (1928) previously suggested
statite that have relatively Cr-poor that the rocks which he initially termed mica-
compositions (< 2% Cr2O3). The origin of the ceous kimberlite (Wagner, 1914) be renamed
megacrysts is still being debated (e.g. Mitchell, “orangite” (sic). The following characteriza-
1986), and some petrologists believe that they tion of the rocks currently described as Group
may be cognate. II kimberlites or micaceous kimberlites fol-
Both of these suites of minerals are included lows that of Mitchell (1995).
in the characterization because of their com- Group II kimberlites (or orangeites) belong to
mon presence in kimberlites. It can be debated a clan of ultrapotassic, peralkaline volatile-rich
whether reference to these characteristic con- (dominantly H2O) rocks, characterized by
stituents should be removed from the “defini- phlogopite macrocrysts and microphenocrysts,
tion” of kimberlite. Strictly, minerals which together with groundmass micas which vary in
are known to be xenocrysts should not be composition from “tetraferriphlogopite” to
included in a petrological definition, as they phlogopite. Rounded macrocrysts of olivine and
have not crystallized from the parental magma. euhedral primary crystals of olivine are com-
Smaller grains of both the macrocryst and mon, but are not invariably major constituents.
megacryst suite minerals also occur but may Characteristic primary phases in the ground-
be easily distinguished on the basis of their mass include: diopside, commonly zoned to,
compositions. In this respect, it is important to and mantled by, titanian aegirine; spinels rang-
distinguish pseudoprimary groundmass ing in composition from Mg-bearing chromite
diopside from macrocrystic or megacrystic to Ti-bearing magnetite; Sr- and REE-rich
clinopyroxene. Group I kimberlites do not perovskite; Sr-rich apatite; REE-rich phos-
usually contain the former except as a product phates (monazite, daqingshanite); potassian
of crystallization induced by the assimilation barian titanates belonging to the hollandite
of siliceous xenoliths (Scott Smith et al., 1983). group; potassium triskaidecatitanates
The primary nature of groundmass serpophitic (K2Ti13 O27); Nb-bearing rutile and Mn-bear-
serpentine was originally recognized by ing ilmenite. These are set in a mesostasis that
Mitchell & Putnis (1988). may contain calcite, dolomite, ancylite and
other rare-earth carbonates, witherite, nor-
sethite and serpentine.
2.6.2 GROUP II KIMBERLITES Evolved members of the group contain
groundmass sanidine and potassium richter-
Recent studies (Smith et al., 1985; Skinner, ite. Zirconium silicates (wadeite, zircon,
1989; Mitchell, 1994, 1995; Tainton & Brown- kimzeyitic garnet, Ca-Zr-silicate) may occur
ing, 1991) have demonstrated that Group I and as late-stage groundmass minerals. Barite is a
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2.6 Kimberlites 15
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16 2 Classification and nomenclature
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2.7 Lamproites 17
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18 2 Classification and nomenclature
2.8 LEUCITE-BEARING ROCKS (3) QAPF subfield 15c, leucitite sensu stricto
in which foids are 90–100% of the light-
The leucite-bearing rocks, after the elimina- coloured constituents and leucite is practi-
tion of the lamproites and kamafugites, should cally the sole feldspathoid.
be named according to the volcanic QAPF The essential mineralogy of the principal
diagram (Fig. 2.11, p.31) with the prefix leucite-bearing rocks is given in Table 2.8.
“leucite” or “leucite-bearing” as appropriate. No unambiguous chemical criteria have been
Rocks containing little or no feldspar, i.e. falling found to distinguish this group of rocks. On
into field 15 (foidite), are leucitite, which is TAS (Fig. 2.14, p.35), leucitites extend
divided into three subfields (shown in Fig. significantly beyond the foidite field into
2.12, p.32): adjacent fields (see Le Bas et al., 1992, Fig.
(1) QAPF subfield 15a, phonolitic leucitite in 23). They are better distinguished from
which foids are 60–90% of the light- lamproites by other compositional parameters,
coloured constituents and alkali feldspar although even here some overlap occurs. The
> plagioclase. chemical characteristics of the potassic rocks
(2) QAPF subfield 15b, tephritic leucitite in and attempts at distinguishing lamproites from
which foids are 60–90% of the light- certain leucite-bearing rocks, using a variety of
coloured constituents and plagioclase > criteria, are explored by Foley et al. (1987) and
alkali feldspar Mitchell & Bergman (1991).
£ = present; – = absent.
a These rocks may also contain some nepheline.
b Includes products of its exsolution.
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20 2 Classification and nomenclature
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21
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22 2 Classification and nomenclature
Q
quartzolite
90 90
quartz-rich
granitoid
granodiorite
60 60
tonalite
alkali feldspar quartz monzodiorite
granite granite quartz monzogabbro
quartz (syeno- (monzo- quartz diorite
alkali feldspar granite) granite) quartz gabbro
syenite quartz anorthosite
10 35 65 90
20 20
alkali feldspar quartz quartz monzodiorite
syenite syenite monzonite monzogabbro
5 5
syenite monzonite
A foid-bearing foid-bearing
P diorite
syenite monzonite gabbro
10 10
10 50 90 anorthosite
foid-bearing
alkali feldspar foid foid-bearing diorite
syenite foid monzodiorite foid-bearing gabbro
monzosyenite foid foid-bearing anorthosite
monzogabbro
foid syenite foid-bearing monzodiorite
foid-bearing monzogabbro
foid diorite
60 60 foid gabbro
foidolite
F
Fig. 2.4. QAPF modal classification of plutonic rocks (based on Streckeisen, 1976, Fig. 1a).
The corners of the double triangle are Q = quartz, A = alkali feldspar, P = plagioclase and F
= feldspathoid. This diagram must not be used for rocks in which the mafic mineral content,
M, is greater than 90%.
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2.11 Plutonic rocks 23
The location of the numerical QAPF fields are subfield 3a, whereas subfield 3b has contained
shown in Fig. 2.5. terms such as adamellite and quartz monzonite.
Field 2 (alkali feldspar granite) — rocks in In the European literature, however, granite
this field have been called alkali granite by has been used to cover both subfields, a view
many authors. The Subcommission, however, adopted by the Subcommission. The Subcom-
recommends that the term peralkaline granite mission has also recommended that the term
be used instead for those rocks that contain adamellite should no longer be used, as it has
sodic amphiboles and/or sodic pyroxenes. The been given several meanings, and does not
term alaskite may be used for a light-coloured even occur in the Adamello Massif as com-
(M < 10%) alkali feldspar granite. monly defined (Streckeisen, 1976). Although
Field 3 (granite) — the term granite has been the term quartz monzonite has also been used
used in many senses; in most English and with several meanings, the Subcommission
American textbooks it has been restricted to decided to retain the term in its original sense,
i.e. for rocks in field 8*.
Field 4 (granodiorite) — the most widespread
Q
rocks in this field are granodiorites, commonly
90 1a 90 containing oligoclase, more rarely andesine. It
seems advisable to add the condition that the
1b average composition of the plagioclase should
be An0 – An50 in order to distinguish the common
60 60
granodiorites from the rare granogabbro in which
the plagioclase is An50 – An100.
2 3a 3b 4 5 Field 5 (tonalite) — the root name tonalite
should be used whether hornblende is present
10 35 65 90
20 20 or not. Trondhjemite and plagiogranite (as
6* 7* 8* 9* 10* used by Russian petrologists) may be used for
5 5
A 6 7 8 9 10 P a light-coloured (M < 10%) tonalite.
6' 7' 8' 9' 10' Field 6' (alkali feldpar nepheline syenite) —
10 10
10 50 90
the general term agpaite may be used for per-
alkaline varieties characterized by complex Zr
11 12 13 14
and Ti minerals, such as eudialyte, rather than
simple minerals such as zircon and ilmenite.
Field 8 (monzonite) — many so-called
60 60
“syenites” fall into this field.
15 Field 9 (monzodiorite, monzogabbro) — the
two root names in this field are separated
according to the average composition of their
plagioclase – monzodiorite (plagioclase An0 –
F An50 ), monzogabbro (plagioclase An50 – An100).
Fig. 2.5. QAPF field numbers (Streckeisen, The terms syenodiorite and syenogabbro may
1976, Fig. 1a). The fields 6* to 10* are be used as comprehensive names for rocks
slightly silica oversaturated variants of fields between syenite and diorite/gabbro, i.e. for
6 to 10, respectively, while 6' to 10' are monzonites (field 8) and monzodiorite/monzo-
slightly silica undersaturated variants. gabbro, respectively.
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24 2 Classification and nomenclature
Field 10 (diorite, gabbro, anorthosite) — the monzogabbro) — the two root names in this
three root names in this field are separated field are separated according to the average
according to the colour index and the average composition of their plagioclase, i.e. foid
composition of their plagioclase – anorthosite monzodiorite (plagioclase An0 – An50), foid
(M < 10%), diorite (M > 10%, plagioclase An0 monzogabbro (plagioclase An50 – An100).
– An50), gabbro (M > 10%, plagioclase An50 – Wherever possible, replace the term foid with
An100). Gabbros may be further subdivided, as the name of the most abundant feldspathoid.
shown below. Either of the two synonymous The term essexite may be applied to nepheline
terms dolerite or diabase may be used for monzodiorite or nepheline monzogabbro.
medium-grained gabbros rather than the term Field 14 (foid diorite, foid gabbro) — again
microgabbro, if required. the two root names in this field are separated
Gabbroic rocks — the gabbros (sensu lato) of according to the average composition of their
QAPF field 10, may be further subdivided plagioclase, i.e. foid diorite (plagioclase An0 –
according to the relative abundances of their An50), foid gabbro (plagioclase An50 – An100).
orthopyroxene, clinopyroxene, olivine and Wherever possible, replace the term foid with
hornblende as shown in Fig. 2.6. Some of the the name of the most abundant feldspathoid.
special terms used are: Two special terms may continue to be used,
Gabbro (sensu stricto) = plagioclase and theralite for nepheline gabbro and teschenite
clinopyroxene for analcime gabbro.
Norite = plagioclase and orthopyroxene Field 15 (foidolite) — this field contains
Troctolite = plagioclase and olivine rocks in which the light-coloured minerals are
Gabbronorite = plagioclase with almost equal almost entirely foids and is given the root
amounts of clinopyroxene and orthopyroxene name foidoliteto distinguish it from the volcanic
Orthopyroxene gabbro = plagioclase and equivalent which is called foidite. As these rocks
clinopyroxene with minor amounts of are rather rare the field has not been subdivided.
orthopyroxene Again note that the most abundant foid should
Clinopyroxene norite = plagioclase and appear in the name, e.g. nephelinolite (urtite,
orthopyroxene with minor amounts of ijolite, melteigite).
clinopyroxene Leuco- and Mela- variants — for rocks in the
Hornblende gabbro = plagioclase and horn- QAPF classification the Subcommission sug-
blende with pyroxene < 5%. gests (Streckeisen, 1973, p.30; 1976, p.24) that
Field 11 (foid syenite) — although foid syenite the prefixes leuco- and mela- may be used to
is the root name, the most abundant foid present designate the more felsic (lower colour index)
should be used in the name, e.g. nepheline and mafic (higher colour index) types within
syenite, sodalite syenite. each rock group, when compared with the
Field 12 (foid monzosyenite) — the root “normal” types in that group.As the threshold
name foid monzosyenite may be replaced by values of M' varies from rock group to rock
the synonym foid plagisyenite. Wherever pos- group, the limits are shown diagrammatically
sible, replace the term foid with the name of the in Fig. 2.7 and Fig. 2.8 for the rock groups to
most abundant feldspathoid. Miaskite, which which the terms may be applied. The prefixes
contains oligoclase, may also be used. should precede the root name, e.g. biotite
Field 13 (foid monzodiorite, foid leucogranite, biotite melasyenite.
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2.11 Plutonic rocks 25
anorthosite
Plag
ANORTHOSITES
90 90
(LEUCO-)
65 65
gabbro
gabbronorite troctolite
norite olivine gabbro GABBROIDS
olivine gabbronorite
olivine norite
35 35
(MELA-)
10 10
plagioclase-bearing ultramafic rocks ULTRAMAFIC ROCKS
Px Ol
Plag Plag
norite gabbronorite gabbro
clinopyroxene orthopyroxene
norite gabbro
10 10
5 95
plagioclase-bearing pyroxenite
Opx Cpx
Plag
anorthosite
ANORTHOSITES
90 90
(LEUCO-)
gabbro 65 65
gabbronorite hornblende gabbro
norite GABBROIDS
pyroxene hornblende
gabbro/gabbronorite/norite
35 35
Fig. 2.6. Modal classification of gabbroic rocks based on the proportions of plagioclase
(Plag), pyroxene (Px), olivine (Ol), orthopyroxene (Opx), clinopyroxene (Cpx), and
hornblende (Hbl) (after Streckeisen, 1976, Fig. 3). Rocks falling in the shaded areas of either
triangular diagram may be further subdivided according to the diagram pointed to by the
arrows.
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26 2 Classification and nomenclature
Q = 60 to 20 Q = 20 to 5
Field 2 3 4 5 6* 7* 8* 9* 10*
anorthosite
granite
10
granite
granodiorite
quartz
quartz syenite
quartz monzonite
20 quartz monzodiorite
tonalite
quartz monzogabbro
quartz diorite
30
40 quartz gabbro
50
60
Fig. 2.7. Use of the terms mela- and leuco- with QAPF plutonic rocks with Q > 5%
(after Streckeisen, 1976, Fig. 5). Abbreviations: P' = 100 * P / (A + P); M' = colour
index; An = anorthite content of plagioclase.
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2.11 Plutonic rocks 27
Q = 0 to 5 or F = 0 to 10 F = 10 to 60 F =
60 to 100
P' 0–10 10–35 35–65 65–90 90–100 0–10 10–50 50–90 90–100
Field 6 7 8 9 10 11 12 13 14 15
10
syenite
foid syenite
These are leuco- varieties of the rocks below
italite
urtite
syenite
20
30
monzodiorite
diorite
monzogabbro
fergusite
ijolite
gabbro
50
60
70
shonkinite
80
Fig. 2.8. Use of the terms mela- and leuco- with QAPF plutonic rocks with Q < 5% or
F > 0% (after Streckeisen, 1976, Fig. 5). Abbreviations: P' = 100 * P / (A + P); M' = colour
index; An = anorthite content of plagioclase; neph* = nepheline is the predominant foid;
leuc* = leucite is the predominant foid. Note: some special names are applicable in certain
parts of the diagram.
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28 2 Classification and nomenclature
2.11.2 ULTRAMAFIC ROCKS (M > 90%) (Streckeisen, 1973, 1976) recommended two
diagrams, both of which are shown in Fig. 2.9.
The ultramafic rocks are classified according One is for rocks consisting essentially of olivine,
to their content of mafic minerals, which consist orthopyroxene, and clinopyroxene, and the
essentially of olivine, orthopyroxene, other for rocks containing hornblende,
clinopyroxene, hornblende, sometimes with pyroxenes, and olivine.
biotite, and various but usually small amounts Peridotitesare distinguished from pyroxenites
of garnet and spinel. The Subcommission by containing more than 40% olivine. This
Ol
dunite
90 90
harzburgite wehrlite
PERIDOTITE
lherzolite
olivine 40 40
orthopyroxenite olivine
clinopyroxenite
olivine websterite PYROXENITE
orthopyroxenite clinopyroxenite
websterite
Opx 10 90 Cpx
Ol
dunite
90 90
pyroxene hornblende
peridotite peridotite
PERIDOTITE
pyroxene
hornblende
peridotite
olivine 40 40
pyroxenite olivine
olivine olivine hornblendite
hornblende pyroxene PYROXENITE AND
pyroxenite hornblendite HORNBLENDITE
pyroxenite hornblendite
Px 10 90 Hbl
hornblende pyroxenite pyroxene hornblendite
Fig. 2.9. Modal classification of ultramafic rocks based on the proportions of olivine (Ol),
orthopyroxene (Opx), clinopyroxene (Cpx), pyroxene (Px) and hornblende (Hbl) (after
Streckeisen, 1973, Figs. 2a and 2b).
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2.11 Plutonic rocks 29
value, rather than 50%, was chosen because 2.11.3 PROVISIONAL “FIELD” CLASSIFICATION
many lherzolites contain up to 60% pyroxene.
The peridotites are basically subdivided into The “field” classification of plutonic rocks
dunite (or olivinite if the spinel mineral is should be used only as a provisional measure
magnetite), harzburgite, lherzolite and wehrlite. when an accurate mineral mode is not yet
The pyroxenites are further subdivided into available. When available, the plutonic QAPF
orthopyroxenite, websterite and clinopyrox- diagram should be used.
enite. The classification is based on a simplified
Ultramafic rocks containing garnet or spinel version of the plutonic QAPF diagram (Streck-
should be qualified in the following manner. If eisen, 1976) and is shown in Fig. 2.10. If the
garnet or spinel is less than 5% use garnet- suffix “-oid” is felt to be linguistically awk-
bearing peridotite, chromite-bearing dunite etc. ward then the alternative adjectival form “-ic
If garnet or spinel is greater than 5% use garnet rock” may be used, i.e. use syenitic rock in
peridotite, chromite dunite etc. place of syenitoid.
60 60
granitoid
65
20 20
dioritoid
syenitoid gabbroid
A anorthosite P
10 10
foid foid dioritoid
syenitoid foid gabbroid
60 60
foidolite
F
Fig. 2.10. Preliminary QAPF classification of plutonic rocks for field
use (after Streckeisen, 1976, Fig. 6).
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30 2 Classification and nomenclature
2.12 VOLCANIC ROCKS both fields 3a and 3b. Liparite may be used as
a synonym. The term rhyodacite, which has
This classification should be used only if the been used ambiguously for rocks of fields 3b
rock is considered to be volcanic, i.e. it is and 4, can be used for transitional rocks be-
assumed to have been associated with volcan- tween rhyolite and dacite without attributing it
ism and has a relatively fine-grained texture in to a distinct field.
which most of the individual crystals cannot be Fields 4 and 5 (dacite) — rocks in both these
seen with the naked eye. fields are covered by the root name dacite in the
The classification of volcanic rocks is di- broad sense. Volcanic rocks of field 5, to which
vided into three parts: terms such as “plagidacite” and “quartz andes-
(1) if a mineral mode can be determined, use ite” have been applied, are frequently also
the QAPF classification (Fig. 2.11) of sec- described as dacite, which is the recommended
tion 2.12.1 name.
(2) if a mineral mode cannot be determined Fields 6 (alkali feldspar trachyte), 7 (trach-
and a chemical analysis is available, use yte), 8 (latite) — rocks with these root names,
the TAS classification of section 2.12.2, which contain no modal foids but do contain
p.33 nepheline in the norm, may be qualified with
(3) if neither a mineral mode nor chemical “ne-normative” to indicate that they would fall
analysis is yet available, the “field” classi- in subfields 6'–8', respectively. Peralkaline tra-
fication of section 2.12.3, p.39, may be chyte, rather than alkali trachyte, should be
used provisionally. used for trachytes containing sodic pyroxene
and/or sodic amphibole.
Fields 9 and 10 (basalt, andesite)— these two
2.12.1 VOLCANIC QAPF CLASSIFICATION fields contain the large majority of volcanic
(M < 90%) rocks. Basalt and andesite are tentatively sepa-
rated using colour index, at a limit of 40 wt %
This classification should be used only if the or 35 vol %, and 52% SiO2 as shown in Table
rock is considered to be volcanic and if a 2.11. A plagioclase composition (at a limit of
mineral mode can be determined (Streckeisen, An50) is less suitable for the distinction be-
1978 and 1979). The root names for the classi- tween basalt and andesite, because many an-
fication are given in Fig. 2.11. desites commonly contain “phenocrysts” of
The numbers of the QAPF fields are the same
as those for the plutonic rock classification Table 2.11. Classification of QAPF fields 9
(see Fig. 2.5, p.23) except that field 15 has been and 10 volcanic rocks into basalt and
divided into three subfields (Fig. 2.12, p.32). andesite, using colour index and wt % SiO2
Field 2 (alkali feldspar rhyolite) — the root
name corresponds with alkali feldspar granite. Colour index SiO2 wt %
The term peralkaline rhyolite, in preference to vol % wt % < 52 > 52
alkali rhyolite, can be used when the rock
contains alkali pyroxene and/or amphibole. > 35 > 40 basalt mela-andesite
The name rhyolite may be replaced by the
synonym liparite. < 35 < 40 leuco-basalt andesite
Fields 3a and 3b (rhyolite) — in an analogous
manner to the granites, this root name covers Source: Streckeisen (1978, Fig. 2).
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2.12 Volcanic rocks 31
90 90
60 60
quartz
alkali feldspar
trachyte 20 10 35 65 90 20
quartz quartz
alkali feldspar trachyte latite
trachyte 5 basalt
trachyte latite andesite
A foid-bearing foid-bearing
P
foid-bearing trachyte latite
alkali feldspar 10 50 90
10
trachyte
tephritic
phonolite basanite (olivine > 10%)
phonolite tephrite (olivine < 10%)
phonolitic basanite
(olivine > 10%)
60 60
phonolitic tephrite
(olivine < 10%)
90 90
foidite
F
Fig. 2.11. QAPF modal classification of volcanic rocks (based on Streckeisen, 1978, Fig. 1).
The corners of the double triangle are Q = quartz, A = alkali feldspar, P = plagioclase and F =
feldspathoid. This diagram must not be used for rocks in which the mafic mineral content, M,
is greater than 90%.
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32 2 Classification and nomenclature
labradorite or bytownite. Although this may Field 14 (basanite, tephrite) — these two root
seem rather unsatisfactory, it is unlikely that names are separated on the amount of olivine
many of these rocks will be classified using the in the CIPW norm. If normative olivine is
QAPF diagram, as the modes of most basalts greater than 10% the rock is called a basanite;
and andesites are difficult to determine accu- if less than 10% it is a tephrite. The nature of the
rately so that the TAS classification will have dominant foid should be indicated in the name,
to be used. e.g. nepheline basanite, leucite tephrite etc.
Field 11 (phonolite) — the root name phono- Field 15 (foidite sensu lato) — the general
lite is used in the sense of Rosenbusch for rocks root name of this field is foidite, but as these
consisting essentially of alkali feldspar, any rocks occur relatively frequently the field has
feldspathoid and mafic minerals. The nature of been subdivided into three: fields 15a , 15b and
the predominant foid should be added to the 15c as shown in Fig. 2.12.
root name, e.g. leucite phonolite, analcime Field 15a (phonolitic foidite) — wherever
phonolite, leucite-nepheline phonolite (with possible replace the term foidite with a more
nepheline > leucite) etc. Phonolites containing specific term, such as phonolitic nephelinite.
nepheline and/or haüyne as the main foids are Alternatively, the term alkali feldspar foidite
commonly described simply as “phonolite”. could be used as the root name, which would
Phonolites that contain sodic pyroxene and/or give specific terms such as sanidine nepheli-
sodic amphibole may be called peralkaline nite.
phonolite. Field 15b (tephritic foidite, basanitic foidite)
Field 12 (tephritic phonolite) — these rocks — these two root names are separated accord-
are rather rare. Although it was originally sug- ing to their olivine content, as in field 14.
gested that the term tephriphonolite is a syno- wherever possible replace the term foidite with
nym (Streckeisen, 1978), it is probably better a more specific term, such as tephritic leucitite,
to reserve this term for the root name of TAS basanitic nephelinite.
field U3, to indicate that the name has been Field 15c (foidite sensu stricto) — the root
given chemically and may not be identical to name is foidite and should be distinguished by
those of QAPF field 12. the name of the predominant foid, e.g. nephe-
Field 13 (phonolitic basanite, phonolitic linite, leucitite, analcimite.
tephrite) — these two root names are separated
on the amount of olivine in the CIPW norm. If A P
normative olivine is greater than 10% the rock
is called a phonolitic basanite; if less than 10% 60 60
it is a phonolitic tephrite. Although it was
originally suggested that the term phonote- 15a 15b
phrite was a synonym of phonolitic tephrite
(Streckeisen, 1978), it is probably better to
reserve this term for the root name of TAS field 90 90
15c
U2, to indicate that the name has been given
chemically and may not be identical to those of
F
QAPF field 13. There is no conflict if the term
phonobasanite is used as a synonym for pho- Fig. 2.12. Subdivision of volcanic QAPF
nolitic basanite, as the term is not used in TAS. field 15 into fields 15a, 15b and 15c.
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2.12 Volcanic rocks 33
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34 2 Classification and nomenclature
al. (1985), who found that many low-grade As previously explained not all rock types
metavolcanic rocks could be satisfactorily fall neatly into the TAS fields so that one must
classified. check to see if the rock being classified is one
Before using the classification the two follow- of these types before using Fig. 2.14 directly.
ing procedures must be adopted: The rocks in question are the “high-Mg” vol-
(1) analyses must be recalculated to 100% on canic rocks, i.e. picrite, komatiite, meimechite
an H2O and CO2 free basis or boninite and the nephelinites and
(2) if a CIPW norm has to be calculated to melanephelinites which fall in fields F and U1.
determine the correct root name, the “High-Mg” volcanic rocks — these are may
amounts of FeO and Fe2O3 should be left be distinguished by the following criteria as
as determined. If only total iron has been shown in Fig. 2.13:
determined, it is up to the user to justify the (1) if SiO2 > 52%, MgO > 8% and TiO2 <
method used for partitioning the iron be- 0.5%, the rock is a boninite
tween FeO and Fe2O3. One method that (2) if 52% > SiO2 > 30%, MgO > 18% and
can be used to estimate what the FeO and (Na2O + K2O ) < 2%, then the rock is a
Fe2O3 would have been is that of Le Maitre komatiite if TiO2 < 1% or a meimechite if
(1976). Remember, it is the feeling of the TiO2 > 1%
Subcommission that rocks should be (3) if 52% > SiO2 > 30%, MgO > 12%, and
named according to what they are, and not (Na2O + K2O ) < 3%, it is a picrite.
according to what they might have been. Note that this scheme is different from that
Na2 O + K2 O wt %
4 basanite andesite
tephrite basaltic
3 andesite
2 foidite picrobasalt basalt
1 boninite
(MgO > 8% and TiO2 < 0.5%)
0
37 41 45 49 53 57 61 65
SiO2 wt %
Na2 O + K2 O wt %
3
2
picrite
komatiite TiO2 < 1%
1
meimechite TiO2 > 1%
0
12 18 24 30
MgO wt %
Fig. 2.13. Chemical classification and separation of the “high-Mg” volcanic rocks boninite,
komatiite, meimechite and picrite prior to using the TAS classification. If a rock falls in the
shaded rectangle of the TAS (upper) diagram, check in the lower diagram to see that it is not a
komatiite, meimechite or picrite, before naming it as a foidite, picrobasalt or basalt. Similarly, a
rock with SiO2 > 52% should be checked to see that it is not a boninite (after Le Bas, 2000).
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2.12 Volcanic rocks 35
Na2 O + K2 O wt %
15
phonolite
13
tephriphonolite trachyte
11 (q < 20%)
trachydacite
foidite (q > 20%)
phonotephrite
9 rhyolite
trachyandesite
tephrite
(ol < 10%) basaltic
7 basanite trachy-
(ol > 10%) trachy- andesite
basalt
5 dacite
basaltic andesite
3 andesite
picro- basalt
basalt
1
37 41 45 49 53 57 61 65 69 73 77
SiO2 wt %
ULTRABASIC BASIC INTERMEDIATE ACID
45 52 63
Fig. 2.14. Chemical classification of volcanic rocks using TAS (total alkali–silica diagram)
(after Le Bas et al., 1986, Fig. 2). Rocks falling in the shaded areas may be further subdivided
as shown in the table pointed to by the arrow. The line between the foidite field and the
basanite–tephrite field is dashed to indicate that further criteria must be used to separate these
types. Abbreviations: ol = normative olivine; q = normative 100 * Q / (Q + or + ab + an).
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36 2 Classification and nomenclature
Na2 O + K2 O wt%
15
(52.5, 14) Ph
13
37 41 45 49 53 57 61 65 69 73 77
SiO2 wt%
Fig. 2.15. Field symbols and coordinate points of TAS (after Le Bas et al., 1986, Fig. 1).
The numbers in brackets are the coordinates of the intersections of the lines.
published in Le Maitre et al. (1989, Fig. B.12). The field letters of the TAS diagram shown
The lowering of MgO for picrite from 18% to above are now described in further detail.
12% and increasing the alkalis from 2% to 3% Field B (basalt) — the root name may be
makes many rocks into picrites that previously divided into alkali basalt and subalkali basalt
were classified as picrobasalt. according to the state of silica saturation – if the
Nephelinites and melanephelinites — it has CIPW norm contains nepheline (ne) the rock is
been found that nephelinites, melanephelinites an alkali basalt, if not the rock is a subalkali
and certain leucitites fall in both fields U1 and basalt. This is based on the principle of the
F, which is why the boundary between the two basalt tetrahedron (Yoder & Tilley, 1962)
fields is dashed. They are distinguished by the The subalkali basalt group includes a large
following rules (after Le Bas, 1989): number of basalt varieties such as calc-alkali
(1) if normative ne > 20% the rock is a basalt (high-alumina basalt), mid-ocean ridge
nephelinite. basalt, tholeiitic basalt, transitional basalt etc.
(2) if normative ne < 20% and ab is present Although none of these have been defined, but
but is < 5% the rock is a melanephelinite. only categorized, the Subcommission does rec-
If the rock is none of these six types you can use ommend that tholeiitic basalt should be used in
TAS diagram in Fig. 2.14 directly. preference to the term tholeiite (see Glossary).
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2.12 Volcanic rocks 37
K2 O wt %
4 high-K
dacite and rhyolite
basaltic andesite
3
68, 2.9
andesite
basalt
medium-K
2
48, 1.2
1 68, 1.2 low-K
48, 0.3
45 49 53 57 61 65 69 73 77
SiO2 wt %
Fig. 2.17. Division of the basalt–rhyolite series into low-K, medium-K and high-K types.
Note that high-K is not synonymous with potassic. The thick stippled lines indicate the
equivalent position of some of the fields in the TAS diagram.
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38 2 Classification and nomenclature
20 Al2O3 wt%
comenditic rhyolite (= comendite)
comenditic trachyte 4.4
15
3 F eO + .4
> 1.
3 +4
FeO
Al 2O < 1.33
3
10
Al 2O
3
0
0 2 4 6 8 10 12
Total iron as FeO wt%
Fig. 2.18. Classification of trachytes and rhyolites into comenditic and pantelleritic types
using the Al2O3 versus total iron as FeO diagram (after Macdonald, 1974). The coordinates of
the bottom left of the line are (0.45, 5.0) and the top right are (10.98, 19.0).
term high-K is not synonymous with potassic, salt according to the relative amounts of Na2O
as high-K rocks can have more Na2O than K2O. and K2O. If Na2O – 2 is greater than K2O the
Field R (rhyolite) — the root name may be rock is considered to be “sodic” and is called
further subdivided into peralkaline rhyolite, if hawaiite; if Na2O – 2 is less than K2O the rock
the peralkaline index, which is the molecular is considered to be “potassic” and is called
ratio (Na2O + K2O) / Al2O3, is greater than 1. potassic trachybasalt (see Fig. 2.14, p.35).
Field T (trachyte, trachydacite) — these two Field S2 (basaltic trachyandesite) — using
root names are separated by the function the same criterion as for field S1, the root name
100 * Q / (Q + an + ab + or) which is the may be divided into mugearite (“sodic”) and
normative equivalent of Q in QAPF. If the shoshonite (“potassic”).
value is less than 20% the rock is trachyte; if Field S3 (trachyandesite) — using the same
greater than 20% it is trachydacite. Trachytes criterion as for field S1, the root name may be
may be further subdivided into peralkaline divided into benmoreite (“sodic”) and latite
trachytes, if the peralkaline index > 1. (“potassic”).
Peralkaline rhyolites and trachytes — the Field U1 (basanite, tephrite) — if normative
Subcommission has considered it useful to ol > 10 % the rock is a basanite, if ol < 10% it
further subdivide these rocks into comenditic is a tephrite.
rhyolite (= comendite), comenditic trachyte, Field F (foidite) — before deciding that the
pantelleritic rhyolite (= pantellerite), and pan- rock should be named a foidite check to see if
telleritic trachyte according to the method of it is a melilitite, using the following rules:
Macdonald (1974), which is based on the rela- 1) if the rock does not contain kalsilite but has
tive amounts of Al2O3 versus total iron as FeO normative cs (dicalcium silicate or larnite)
as shown in Fig. 2.18. > 10% and K2O < Na2O, then it is a
Field Ph (phonolite) — phonolites may be melilitite (modal olivine < 10%) or an
further subdivided into peralkaline phonolites, olivine melilitite (modal olivine > 10%)
if the peralkaline index > 1. 2) if normative cs > 10%, K2O > Na2O and
Field S1 (trachybasalt) — the root name may K2O > 2%, then it is a potassic melilitite
be divided into hawaiite and potassic trachyba- (modal olivine < 10%) or a potassic olivine
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2.12 Volcanic rocks 39
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40 2 Classification and nomenclature
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2.13 References 41
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42 2 Classification and nomenclature
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