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Original Article
a r t i c l e i n f o a b s t r a c t
Article history: Keeping in view the conservation of natural resources, the power generation from the solar
Received 25 December 2016 photovoltaic system is increasing day by day to meet the demand of energy worldwide.
Accepted 12 October 2017 There are constraints of availability of space for ground mounted solar PV system for large
Available online xxx installations. In some countries water bodies are being utilized to install solar PV system to
reduce land use. Few floating systems using plastics have been developed to install a solar
Keywords: panel on it. After extensive literature studies on properties of polyolefins, High-density poly
Floating system ethylene (HDPE) is found to be better material for this purpose.
Biomodal In order to measure its sustainability, annotation of mechanical properties using bimodal
HDPE material poly ethylene under accelerated weathering condition has been carried out in different
Mechanical properties intervals till 1152 h, to perceive the lifespan of HDPE material. The change in its mechan-
ical properties like tensile strength, elongation at break, maximum load bearing capacity,
impact resistance and hardness were evaluated. It was observed that the tensile strength
was reduced from 23.22 MPa to 14.64 MPa after accelerated UV exposure. It was observed that
after 1000 h of exposure to accelerated weathering the material still has the tendency to hold
a constant load of 637.81 N without rupture, compared to non-weathered sample (955.16 N).
The elongation at break was reduced but elongation of 6.24% was maintained after 1152 h
of accelerated exposure, which depicts the elasticity of the material, is still maintained. The
impact resistance did not show a significant change during this period, the value varies in
the range of 13.54–10.06 kJ/m2 . However, the hardness was increased from 61 to 66 (Shore D)
due to deterioration of low molecular weight polymer present in bimodal PE. It is concluded
that the mechanical properties of Biomodal HDPE material after accelerated UV exposure
does not have much effect and is safe to bear the load of solar panels and other accessories
mounted over it. Further studies can be done using UV stabilized biomodal HDPE.
© 2017 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier
Editora Ltda. This is an open access article under the CC BY-NC-ND license (http://
creativecommons.org/licenses/by-nc-nd/4.0/).
∗
Corresponding author.
E-mail: sudhakar@ump.edu.my (K. Sudhakar).
https://doi.org/10.1016/j.jmrt.2017.10.002
2238-7854/© 2017 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier Editora Ltda. This is an open access
article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Please cite this article in press as: Sahu AK, Sudhakar K. Effect of UV exposure on bimodal HDPE floats for floating solar application. J Mater Res
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Table 1 – Different principle properties of bimodal HDPE Table 2 – Different mechanical properties of selected
material [8–10]. bimodal HDPE material [12].
Properties Values Sr. no. Properties Unit Value
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2.4.1. Tensile strength, maximum load and elongation at 3. Results and discussion
break
The tensile strength and elongation at break (%) of weath- 3.1. Analysis of mechanical properties
ered HDPE samples were determined using Universal Testing
Machine (Instron, USA make, Model: 3382K6825, 100 kN capac- When plastics are degraded with UV radiations (exposure), its
ity). The test was conducted according to ASTM D 638 [15] at a physical properties are affected. The original properties, i.e.,
speed of 100 mm/min, a gauge length of 115 mm at a tempera- properties before UV exposure and properties after UV expo-
ture of 23 ± 2 ◦ C and relative humidity of 50 ± 5%. The values of sures in different intervals were measured and compared.
5 specimens were taken and the average values were reported.
3.1.1. Tensile strength analysis
Tensile strength is an important property for analysis of
2.4.2. Impact strength product in terms of its mechanical strength. Uniaxial tensile
The Izod impact test (notched) was conducted in an tests were conducted to investigate the effect of UV on the
Impact testing machine (Tinius Oslen, USA make, Model- stress–strain behavior of bimodal HDPE. Figs. 5 and 6 presents
IT 504). The test was conducted according to ASTM D the stress–strain curves of the HDPE samples before and
256 [16] using hammer energy of 24.838 J at a temper- after UV exposure. Before the weathering conditions and after
ature of 23 ± 2 ◦ C and relative humidity of 50 ± 5%. The accelerated weathering (UV radiation) in different intervals of
Please cite this article in press as: Sahu AK, Sudhakar K. Effect of UV exposure on bimodal HDPE floats for floating solar application. J Mater Res
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time of HDPE samples, the variation in tensile strength have HDPE, the values of tensile stress and modulus of elasticity
been reported and shown in Fig. 7. The stress–strain behav- are practically constant.
ior depends strongly on strain rate and strain. The average
modulus of elasticity before and after UV exposure is around 3.1.4. Elongation at break analysis
685 MPa and 607 MPa respectively. A little decrease in the ten- Several authors have shown elongation at break value can
sile strength values was observed during weathering condition be a good measure to monitor the aging of polymers
in the early stages and then the deterioration is more & finally [8,18,19]. During the initial stage of exposure, the value of
the value of 14.64 MPa is recorded after 1152 h of accelerated elongation at break drops up to 60% of the initial value
UV condition. and then a continuous drop in this value is noted until
it reaches value to a minimum or constant. This type of
behavior can be explained because of the obvious reason
3.1.2. Maximum load bearing capacity
that the parental chain of HDPE separates or there is a
The maximum load bearing capacity of the samples are
division in the main chain that causes a decrease in the
also reported and the variation is shown in Fig. 8. This is
molecular weight of the material. Due to long exposure
one of the most important properties to be analyzed as the
brittleness occurs and the sample loses this property. The vari-
HDPE material used in cubical blocks are being used for
ations of the elongation at break percentage values for the
supporting structure of the different shape and size solar pan-
HDPE specimen before & after weathering are presented in
els in water bodies. From the above figure it was observed
Fig. 10.
that the maximum load bearing capacity before UV radia-
Primarily, the chain was long and the molecules were
tion is nearly constant and decreases gradually in case of
entangled with weak Vander Waal forces to each other and
weathering as the exposure time increases. It was observed
the movement of entire molecules is associated with the vis-
that after 1000 h of exposure to accelerated weathering the
cous flow. This is obviously depending upon the number of
material still has the tendency to hold a constant load of
entanglements but at the time of steep drop in elongation at
637.81 N without rupture, compared to non-weathered sam-
break, these entanglements of the molecules get reduced or
ple (955.16 N). The material may fragile but do not break in this
breakdown occurs because of the chemical changes like the
region.
formation of carbonyl groups that reduces the entanglements
[2].
3.1.3. Elastic modulus analysis
The variation in elastic modulus is shown in Fig. 9 for UV sta- 3.2. Impact resistance analysis
bilized grade of HDPE that is nearly unchangeable. The value
varies in the range of 500–750 MPa showed a good sign of elas- The impact resistance of the samples before and after UV
ticity. The reduction in Young’s modulus was attributed to exposure at different intervals is shown in Fig. 11. For both the
changes in molecular mobility of the sample. For stabilized conditions before and after weathering, the Izod impact resis-
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(5) 26
24
22
20
16
14 Specimen #
12 1
2
10
4
2
0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0
18
16
14
Tensile stress (MPa)
12
Specimen #
10
1
2
8
-2
-0.01 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10
Tensile strain (mm/mm)
tance is reduced till 500 h and after that it starts increasing Bimodal HDPE is relatively hard and resistant to impact
slightly in case of the sample after UV exposure. The decrease and can be subjected to temperatures of up to 120 ◦ C without
of impact resistance in starting of HDPE samples is mainly due being affected. It has many properties that make it important
to deterioration of low molecular weight polymer present in in the manufacturing of different products opaque or translu-
bimodal PE. cent appearance. Also, HDPE does not absorb liquid readily;
making it good barrier material for liquid containers. Recyling
of HDPE is also possible making it ideal for floating solar
3.3. Hardness analysis application.
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30
10
0
0 200 400 600 800 1000 1200 1400
Duration (hrs)
1200
637.81
600
400
200
0
0 200 400 600 800 1000 1200 1400
Duration (Hrs)
that after 1000 h of exposure to accelerated weathering the molecular weight species in bimodal HDPE and to some
material still had the tendency to hold a constant load extent by the increase of crystallinity due to the effect of
of 637.81 N without rupture, compared to non-weathered UV radiation.
sample (955.16 N). The loss in tensile strength of weath- 3. The impact resistance did not show a significant change
ered samples is very less and not affected much by the during this period, the value varies in the range of
accelerated UV weathering condition. 13.54–10.06 kJ/m2 . However, the hardness is increased from
2. The elongation at break was reduced maintaining elonga- 61 to 66 (Shore D) due to increase in crystallinity. The
tion of 6.24% due to the presence of low molecular weight in increase in hardness after weathering of samples indicates
bimodal HDPE after 1152 h of accelerated exposure, which an increase in crystallinity of the material as well as cross-
depicts the elasticity of the material, was still maintained. linking of the polymer.
The gradual and progressive deterioration of the elonga- 4. Bimodal HDPE technology delivers a substantial improve-
tion at break could be mainly due to the presence of low ment in mechanical properties, which include increased
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800
725.6
689.03
700
644.76
586.07
600
400
300
200
100
0
0 200 400 600 800 1000 1200 1400
Duration (Hrs)
40 After UV exposure
Without UV exposure
35
32.7 32.7 33.1 33.5
33.4
31.752
30
Elongation at break (mm)
25
20
15
10
9.18
8.37
6.274
6.24
5
0
0 200 400 600 800 1000 1200 1400
Duration (hrs)
Fig. 10 – Variation in the elongation at break value before and after weathering in accelerated environment.
environmental stress crack resistance (ESCR), increased the load of solar panels and other accessories mounted
top load resistance for higher stacking requirements and on it.
ability to lightweight containers while maintaining drop
impact resistance. Conflicts of interest
5. It is concluded after experiments that the mechanical prop-
erties of biomodal HDPE material after accelerated UV
The authors declare no conflicts of interest.
exposure was not much affected and it is safe to bear
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20
18
16
0
0 200 400 600 800 1000 1200 1400
Duration (hours)
Fig. 11 – Variation of impact strength before and after exposure of various intervals.
70
65 66
65
63
61
Hardness
61 61 61
60 61
60
55
50
0 200 400 600 800 1000 1200 1400
Duration (hours)
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