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PHÁP CƠ
ThS. Hoàng Minh Sơn
08/2018
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MỘT SỐ THUẬT NGỮ
- Chemical pulp: bột hóa
- Mechanical pulp: bột cơ
- Grinding processes: quá trình mài
- Stone groundwood (SGW): phương pháp mài
- Pressure groundwood (PGW): phương pháp mài áp suất
- Thermo groundwood (TGW): phương pháp mài nhiệt
- Refiner Mechanical Pulp (RMP): bột nghiền cơ
- Thermo Machenical Pulp (TMP ): bột cơ nhiệt
- Disintegration: phân hủy, tan rã, duỗi sợi
- Wood log: gỗ khúc
- Grinding Process: quá trình nghiền
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MECHANICAL PULPING
• Mechanical pulping
Fibres mechanically removed from wood matrix
• Mechanical pulping
Ligin holding fibres together is dissolved
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COMPARISON OF MECHANICAL AND
CHEMICAL PULPING
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DEBARKING – DRUM DE-BARKER
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DEBARKING – RING DEBARKING
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3.1. MECHANICAL PULPING
• Mechanical pulping is the process by which fibers are
produced through mechanical methods:
• Grinding-Stone Groundwood (SGW)
• Logs (very occasionally chips) are pressed into a turning stone
thus releasing fibers.
• Refining-Refiner Pulp
• Chips are fed between 2 disks. One disk is always turning while
the other can be fixed or turning.
• Often heat or a chemical pretreatment is utilized.
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3.1. MECHANICAL PULPING
• Raw Material Quality
» Pulps cannot be brightened very much; therefore good quality
material must be used
- Chips used should be less than 2 weeks old (oxidation and
biological decay darken chips after this point).
- Low bark and dirt tolerance (color and machinery wear
issues).
• Species Dependence
» Different wood species work better in different processes.
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PROPERTIES OF MECHANICAL PULP
• Relatively cheap
• High yield of product (85-95%)
• Low capital costs relative to Kraft mill
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PROPERTIES OF MECHANICAL PULP
• Relatively weak product
» Not strong enough to get through printing press
» Need to add chemical fibers to product
- Can use recycle fibers
• Limited brightness
» Bleached with lignin retaining bleaching agents
• Photoyellowing
» Formation of chromophores from lignin compounds through the
reaction with light and oxygen
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Ký hiệu
Tên tiếng Anh Đặc trưng
bột
Áp suất khí quyển, nhiệt độ nuớc tưới 70-75oC, hiệu suất
SGW Stone groundwood
98%.
PGW Pressure groundwood Áp suất 2,5 bar, nhiệt độ nuớc tưới > 100oC, hiệu suất 98%.
PGW-S Super pressure groundwood BÁp suất 2,5 bar, nhiệt độ nuớc tưới > 100oC, hiệu suất 98%.
Áp suất khí quyển, nhiệt độ nuớc tuới > 80oC, hiệu suất >
TGW Thermo groundwood
98,5%
Bột suấtnghiền 97%. đĩa sản xuất từ dăm ở áp suất khí quyển,
RMP Refiner mechanical pulp
hiệu
Pressure Refiner mechanical
PRMP Tuơng tự RMP có áp suất và nhiệt độ cao, hiệu suất 97 % .
pulp
TMP Thermomechanical pulp Áp suất 3,5 bar, nhiệt độ 140-155oC, hiệu suất 97%.
Gỗ được xử lý với hóa chất, hiệu suất 80-95%
Chemimechanical pulp
Dăm được xử lý sơ bộ với hóa chất rồi được nghiền ở áp
CMP (phương
suất cao hay áp suất khí quyển
pháp mài hoặc nghiền)
Hiệu suất < 90%.
Nghiền chấtđượcdăm thựchay hiệnbột ở ápthô suất đãkhí qua
CTMP Chemithermomechanical pulp
quyển, xử hiệu lý sơsuất bộ> 90 với %.
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3.2. STONEGROUND WOOD
• Pulp produced by
pressing logs against
rotating grindstone
• Unchanged for 15 years
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3.2. STONEGROUND WOOD
• Circuferential speed 30m/s
• Grinding pressure 250kPa
• Grits deform fibre-lignin
matric
• Repeated visco-elastic
deformation creates heat
increased heat wood
• Heat softens lignin that’s
found in between fibres and
the fibres
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3.2. STONEGROUND WOOD
• The surface of the stones are cut with patterns (burrs) using
a metal burr.
• Patterns are 1.6 mm deep.
• The stones must be sharpened every 50-150 hours.
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STONE SHARPENING
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STONEGROUND WOOD: MECHANISM
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OPERATING PARAMETERS
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PULP CONSTITUENTS
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PULP PROPERTIES
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CONTINUES GRINDER
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3.3. PRESSURE GROUND WOOD
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3.4. REFINIER PULPING
• Refiner Mechanical Pulping
(RMP)
• Thermo-mechanical Pulping
(TMP)
• Chemi-mechanical Pulping
(CMP)
• Chemi-thermomechanical
Pulping (CTMP)
• The differences between
these systems are
discussed in the notes Small laboratory refiner
section and on the next
slide.
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3.4. REFINIER PULPING
Process Heating Temp Chemicals pH Pretreatment Pretreatment
Time (C) Time Temp
(min) (min) (C)
RMP NA NA NA NA NA NA
CMP
- Cold NaOH NA NA NaOH Bath 12+ 120 30
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TYPES OF REFINES
• Single disc
Moving rotor stationary stator
1.7m Dia 15MW
• Double Disc
Two counter – rotating discs
More power delivered
Less energy required per ton
(Higher shives, less long fibres
• Twin refiner
One rotor, two stator…more
Refining surface
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REFINER PLATES
• The refiners contain
opposing plates that shred
the chips. These plate are
separated into different
sections
• 1st section (inlet) rips
chips into wood slivers.
• Each subsequent step
reduces the size of the
bundles.
• Water carries the fibers
through the disk.
REFINER PLATES
First Stage
Refiner
Reject
Refiner
Second Stage
Refiner
Screens
Screens Thickener
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REFINER MECHANICAL PULP (RMP)
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EFFECT OF CHIP SIZE
• Over size chips
• Unenven feed in refine
• Reduces quality
• Fines Fraction
• Lowers energy consumption
• Decreases strength, sheet density, brightness and light
scattering
• Creates linting problems and increase shive content
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CHIP WASHING
• Immersed in a tank fed by paddle wheel (sunds)
• Removes: rocks, metal, sawdust, bark
• Add moisture
• Raises temperature
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CHIP SCREENING
• Chips are passed through a series of screens
• Oversize: left on screen with 45mm holes
• Overthick: left on screen with 7mm slots
• Accept: left on screen with 7mm holes
• Pin chips: left on screen with 3mm holes
• Fines: pass through last screen
• Overthick chips don’t react weel to pre-treatment, lower
yield
• Fines and pin chips produce too many shives ( not refined)
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CHIP STEAMING/PREHEATING
• Atmospheric type
Steam to 80 – 95C
• Most are pressurized (50kPa to 110kPa over pressure)
• Objective is to warm chip and equalize the moisture content
• Can optimize a bit:
Higher temperature gives longer fibres, higher tensile
Lower temperatures give better optical properties
• Chip impregnation systems
Used in CTMP processes
Compresses chips
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SELF PRESSURIZATION
• Refining imposes cyclic
compression of visco – elastic material
• Generates tremendous amount
of heat and steam
• Dilution required to maintain
approx 30% consistency
• Steam pressure reaches max
and flow both ways
• Can cause blow-back 43
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3.5. THERMAL – MECHANICAL PULP (TMP)
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USUAL MEANS IS SULPHONATION USING SODIUM SULPHITE OR SODIUM
BISULPHITE
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A CHIP PRE-TREATMENT FOR TMP CALLED CTMP IS
SHOWN BELOW
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DETERMINATION OF ENDPOINT
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PULP PROPERTIES
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PULP PROPERTIES
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LATENCY REMOVAL
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EFFECT OF LATENCY REMOVAL
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CHEMICAL PULPING VERSUS MECHANICAL PULPING
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CHEMICAL PULPING VERSUS MECHANICAL PULPING
Chemical Mechanical
Yield Fibre/Wood Low 40-70% High 90-98%
- High - lignin
Cellulose Purity Low - lignin remains
dissolved
High quality papers Low quality
(eg., books). High volume paper
End Uses
Dissolving pulp (e.g. newsprint)
Reinforcement pkg. Molded products
Raw Material
Low High
Sensitivity
Chemical Mechanical
Strength High - fibres intact Low - fibres damaged
High - few and less
Bulk Low - more flexible fibres flexible
fibres
Bright but hard to bleach
Dark but bleachable
Optical high
Poor light scattering
Good light scattering
Poor - short fibres, many
Drainability Good - long fibres few fines
fines
Permanence
Good Poor
(optical) 61