I GATE - 1998

CHEMICAL ENGINEERING
SECTION A 6. The variation o'f thermal conducnvny of a
metal with temJ)erature ls often ｣ｯｲｾｬ｡ ｴ ･､＠
ONE MARKS QUESTIONS (1-25) using an expression of the form
Write. in the boxes provided ln your Mswer k = ku + aT
(boxes I to 2,5) the most appropriate ans\1 ar to the Where k is U1e thermal conductivity and T
followtng 111ultlple choice questions by wri ting the is the temperature (io K). TI1e units of a· ln

om
letters - A B, C or 0 - agmnsl ｾ Ｑ ･＠ subquestion the Sl system wfl l be
Jtumber. (25 x i : 25 tlJMks) a. W/ m K
b W/ m
I. '11\e ｴＮＬ ｡ｰｬ ｡ ｣ｾ Ｎ＠ transform of ｾ Ｑ･＠ Function e "' c. W/mK1
has the form· d, None: a is JUSt a number

.c
I 7 /\ liquid mixture contain$ 30% o-xyleoe,
W'lo p-);ylene and I0% m-.xylene (all
percentages in w/w), Which of the
followmg statements would be true in

ce
respect of this mixture 1
(I a. The. mix ture-exhibits an aze01rope. 31
c. 10t.3kPa.
d. .f +<I b. ｔｨｾ＠
mmpOStltQil of the llllX ture, ln
ra
The unilnomml to tbc plano 2x + y 1 11.=
fi can be expressed 1n the 1 ector form
percent by volume is · o-xylenc 30, p·
xylene 60 and m-xylene 10.
a. i3+.(2tk2 c. The composilion of the ｭｩｸｴｷﾷｾ＠ in
mole percent is o-xylene 30. p-ll)'lene
m
'1 I 2
b. 1 3- ［ Ｓｾｫ＠ 60 and m-xylene 10.
d. The mi xture conl'dins optical isomers
I 1 i s Pure ethanol vapour is fed to a reactor
(1, 1--t-;- -,. k-
xa

3 2 2 packed wtth AILtmina catalyst, at the late

of I00 l.mollh The reactor products
d. -1 -l + J-I - 11=-
'
3 3 3 comprise Ed1ylene 95 kmolth, water
x - sin2x vapour · 97,5 kmollh and diethyt ether
3. lim has the vaiLLe
.e

• ""'-\'+sin3x ｾ＠ 2.5 kmol/h.

a. I The reactions occurring can be ｲ ｰ ･ ｲ･ｳｾｮ ｴ ･､＠
b, - l/4 by I
c 0 C: H, 0 1-1 -> C,H4 + 1-110
w

<L r.o 2C:J+,- OH -+C,Ih- O- C;J'I; - l hO

4, The preferred ma1ennl of ｃｏｴ ｬ ｾ｛ｦｕｃｴ ｩ ｏｊ＠ for The percent conversion of ethanol in the
ｲ･ｾ｣ｴｯ＠ ｩｳ ｾ＠
w

stomge tlU1ks {or 98%.sulphunc actd is

a .Aiununmm a. I 00.0
b Leaa b 97.5
c. 5,0
w

c. Strunless steel 316

d. Mild steel d. 2.5
In d1e oontext of the cbetntcal process 9 Boundary layer ｳ･ｰｾｭ ｮ ｯ＠ tS characterised
industries. the term BOD ts normally by one of the conditions {,oiven below,
associated with ｾ ｨ ･ｲ＠ Re is the Reynold's number for d1e
a. Characterization of solid wastes llow Select the Ｑｰｾｯ ｰｲｩ ｡ ｴ ･＠ con eli nons.
b. The orgauics concentration in gaseous a. ｒｾ ＼＠ I. acceleratmg tlow
effluents b. Re >> I, accelel'\lti'ng flow
c. Characterlzatton of liquid emuents c. Re<< l , deceJcraclng flow
d Charactem..aticm ofboiler feed water d. Re >> I. decelerating I] ow
 "J ur9
I() A globe voh'c is most ｾ ｵ ｩ ｴ ｾ｢ ｬ･＠ fQr volume Df quiesocnt l iquid, in ｷｨｩｾ ｨ＠ D l•
llpplieahon;; In wh1<h the dif1'us1vity of the solute, is
11. the voll'e i! rcquirc<llll be either Iiiii •· D1o
Oll<'ll(ll lisU} oiOl!Cd. • b. Dl b.
b flr>w ｬ＼＾ｾ ｴ ｲｯｬ＠ is requU:ecl, c.. proportii>nallQ .JD
c, the nllid conlnin• ､ｦｾｲｴｮ ［ｾ ､＠ ｬ ｬ＾ ｲｴｩ ｣ｬｾＮ＠ d, ､ ｾＱ･ ｮ､ ･ ｮＱ＠ on the Reynold 's number
d. {)tl:!-\1 uy nuw is roq,llircd. 17. In n interphase ma.-. lr.tnsfer prqce... the
U The hydraulic ｲｯ､ｩｾｕ＠ l(lr now in o lesser U1e solubility of • gwen solute in a
rectansula• lhoct of ｣ｲｯｾ ｴ Ｍ ｳ･｣ ｴｩ ｯｮ｡ｊ＠ liquid. Uo e high,.. are the ohnnces tl1n1 !be
､ ｲ ｭｴｮ ｳ ｩ ｯ ｾ＠ II. w o$ translc r process " itll>c

om
ｾｦ＿＠
a. liquod phase resosL1nce-con1rolled
b. ｧ ｡ｾ＠ phase tesistatu:e CUI11tOited
HW c. ｩｭｰｯ ｾｳ ｩ｢ｬ ｣＠
h d. driv"" by o non lin oar driving force
l(ll •W) In distillation column des 1gn. Ul« Mol 'obe-

.c
!Hll')' 11tie11.: jll'Ocedute is itt.'ldcqUllte nnd a
0. Ponchon-Savnrit procodutc JS nooilcd
4(1-1 • W)' when
u rn- a. Jtotnrated teed Ill not used

ce
d.
(ff +W) b. an JJ:<eutrope forlllli
.:.. 11u; lalllnl heals nl' vapn uti.olion of Uul
1'2. ln e work in de:< in Bond·, l•w for crushing
of <nlid§ has the following ､ｩｮｬ･ ｾｩｯ ｮｳ＠
more and ,less volotJie components ""'
gte3lly ditT.:renl
" · No units Ｈ ､ｩｷｏｉｬＡ ｯ ｮｬｾｳＩ＠
ra
b. k.Wb u:on
., kW ton l9.
d. J luta[ cvntlensco ill u.<cu
for I'C4CltOn p I Q • R s, molar rutc or
ｾ＠ kWh m1r-/loo con>llmption e>l'l' ｩｾ＠
a. doublcofthol oro
m
13. Th" od1 anlrlgo b£ l"<ing o 1-1 sholl and
tubo hoot """hnnQcr u 1-1 l hcll nnd '"-er b. .arne n> that oi'Q
tube bent exchong-;,r t1 c. haU' ofthat of O
;t. L<m « tube side pt'essurc drop d. 213 of lh•t uf Q
xa

b. .Lower shoU side pressure drop 20. Molecul;n:ity nl';on e1emcnl1U)' l"'ff"l ion P -
-.:, }ligber lube side' lwol ｬｲｾｴｵｩｦ＠ Q -> R • Sis
co<rfl1cienl •. 1
,l. Hlgh<ll' $hell silk b..at lronsfer b. 2
3
.e

C;
cocfficic:."'Ut
14. A multiple elfect evopornwr ;os romporecl d. ,j
to • •i.I!SI" elfect evupnrotnr vi' the same 21. A change in Jtlate involVing a d4"Jeruasc in
c•p•ocity hus entro py con be • ponbtneous only if
w

ＬｾＮ＠ Lower hcot transfer area a. it is e.•otherrnic

b. l-ower ' tcnm t:COn OITII' b. ilis uenthalpic
"' Higher Steam ccono,;l': c. itlnltcs plncc isothornwlly
w

lS.
iL lliglu:r solute ＼ＺｻｦｮＮｃｾｬｲｩｯ
pro<IUCL
ｾ＠ in UH>

Po• .t ti., ed numher nt' ideal stnges in •

22.
d. it takes

..
,o,, C'U111ol ｣Ｎｾ
ｾＬＮ Ｌ＠
ｾｬ｡ ｣･＠
ｬ ＠･
ol con$t.'llll •·olnme
consists tlf the li1lluwing
w

doaillatum <!fl iUJt\!1, .._, tloe rctt1u!t ratio i! a. lwo ｩ ｳｯ ｴ｢ ｣ｭ ｬ ｾ＠ ｾｮ､＠ two ｩｾ｣Ｚ ｮｬ ｴｾｬ＾ｩ｣＠
ｩｮｾｲ･ｊｯｳｌＭ､Ｌ＠ lhe dil.tercnL't m comtiO•itiou h. two isnt>anell :ontllwo ｩ ｾ ｭｨｾｯ ｴ ［＠
t>etwcett 1he top >nd bottow ｰＱｯ､ｵ ｾ ｴ＠ c. two ｌｾｴＩ｣ｬ｜ｯｩ･Ａｊ ｮ､＠ two ｉｓ＼ＡＩ｡ｲｩＮｾ＠
ｾｴｲ･ ＳＱｩｕ＠
d. tWO isoUu:rmo Ｑ ｾ＠ •ttd IW(l ｩｊＡｯ･ ｢ ｱｲｩｾ＠
it. 0IIO<CtJ$1:1; 23. l.ocus pl()l of the rO<>Is ofthe ｣ｬｴｯｲ｡ ｨｾ Ｚｲｴ＼ ｩ ｬ＠
b. dccreAscM equation of • ｣ ｬ ｯｾ＼Ａｴ ｬ＠ loop having the:. Open
ｾ Ｎ＠ remain.\ ｵｮｾｦＺ ｣ＮＢｃ ｬ･､＠ luop lrnnsli:r function
d. passes lhr11ugh a mo:"imum
16. l'b.: mass trnnsf.:r ooeflicienl for a solid
'!pbere of ralliu• •u·, dissolving in a l argo:
 3 ur9
(Jl) Purified TcrcphOtalie Aeid
K(s · l) will hove a dofina
8(28 - l}(:!s i 1) (A) ｏ･ ｴｾｲ ｧ･ ｮｴｳ＠
(B) Soaps
nnmbor v ariation of K fmm 0 In <.t: rhe. (C) Painlll ond Pigmerus
..'"""''¢1'
b. 3
,,r loci Ｑ ｾ＠
]
(0) ｓＩＧｬｨ･ｴｩｾ＠
(S) :-<uclt:ar Puels
fohre.

(F) S)'110tctie Rubber

c. 4 30. Each or the b)'prodtwlll I c:opr<!duc"'
d. 2 mentioned in t he let! h•nd column is
24, dur svs lcm with n limo constant ofl min Is linked to r'111c: of the: main products

om
snbj;cted In fNquency analystS. AI an rnorrtianL<l in the l'iglrt hand column.
input frequency of I radian; min. the phnse. Molc b lbo byproducl\ I coproduclJi with
ｾ ｬｲｩｻＮ＠ ib the ｣ｯｾ ｰｯｮ､ｩ ｧ＠ main produc!J<.
Ｇｾ＠ ·SOQ 1Wriie both answers ｩｮｴｨ ＼ｾ＠ box provided -
h, -9o11 Bt1X 'No. 301
c. · lll011 (I) Glycerine

.c
tl. -4511 (Ill Ammonium Chlorid<>
25. For n eylindrienl intr:nrall)• pressurized (A) Rnclret l'r'Of.ellnnl
ｶｾｳ･ ｬ Ｌ＠
which ｾｦ＠ the fnllowing clr1!;rrre (B) Sodo Ash

ce
ｉ ｙ ｉ ｘＮｾ＠
would "IO!'I:rnd highos! pressure if (C) Baltr:ry grode Mn01
ｾＴ｣ｨ＠ closure i:; of Ute same m•lcrlnl llud (0) Antibiotics
thicknCSJJ 1 (E) Soap
a. Hi:mi•ph•-rio:31 (F) Sugar
lr. Ellipsoi<Lll ( l. I) or
ra c. Coni""l
rl, f71#1plate
31. l:.:rch tho tochoiqucs I processes I
uperahons mentJOned in the left lc1nd
calunm is eJosdl) rel• tcd to a specific
tndu•lr)' mantioned in the ·riglrt hontl
m
column. tvfatch ench technique I process t
operation wiUtlhe appr!lpriate industry.
26. JWritc buih ｡ｯｩｬｷ｣ｲｾ＠ in the btlx pmvidcd -
xa

21. rho diOe:,-.,tidl ｾ＼ ｉ ｕｵｴｬｮ＠ Box No. 2.6)

(I) ｏ ｲｾｮｵｬｴｩ ｯｮ＠
d l.-.:
ＭｲｬＮＱ 1 Ｍ
d:c Ｍ Ｒ Ｎ ｾ ］＠
0 'Ill
rave 4 so I u,.rem ,,.
•·••
111 (II ) Fluid Col.;! I) li" Cr•ck.ing
t./1 Jt (A) C<·uu:nL
tho loon (B) ｬＧ ･ ｴ ｲｯ ｬｾｴｵｮ＠ Refming
.e

,1, C1ell ｃＱ･ｾ＠

(C') Ammorrium ｬＧＱ ｯｾ ＩｩｨＮ Ｑ ｴ ｣ｾ＠
b. c ,e·: r +C'2c ..
,._ -JI C-;:c · ll (D) U,eo
\!, \.. I'"
(F) ｬＧｨｯ ｾ ｰｨ ｯ ｲｩ Ｂ＠ .\dd
T"

,L C1c -'6t
w

(F') (>Jo.o
where C1 irnd C: are coMr•nt. ｾ ｬＮ＠ nr
A sample: well !Y3t<:r contain• 1411 J!lm·'
28. "lbo int•gnl fa; ;.cqnvergenl ror en" toos ond 345 (lim' ｎ ｯ ｾ＠ iutts. Tire
w

• .t ｨ｡ ｲ ､ｮ ｾ＠ of ｬ｢ｾ＠ u mple of 11 ﾷｾ ﾷ＠ "-"PI'eS$od

11 no vnhre of p in term, of equlvn lent c.cn) in glmj
b. p > 1 [a;sllmmg atumic: m:1sses uf \"' · 40. 1'1• ·
w

.:. p"' l 23. C : I hod 0: J6] is

.1. #lll·alues ofp •. 350
29. Ｆｾ ｨ＠ of ｬｲｾ＠ choutic:1 b mO!II.IiOJieU in Ulo b. 485
lell hind colurutJ is wry doscly linked c. 140
with one $pecific lomrstry mentioned in II. 3-15
tlte right ｨｾｲｵ ｬ＠ cc,lrunn. Mutch each 33. Air, ini.tiolly at 101.3 kPa and 40"C. and
cbcmic.oJ with th\1 l:<ltn:spondiug iuc.lustry. with a Relative Humiditv or SU'l•. i;
[\\'<ite boUt :mswcm in Ute box pro\oidcd cuoled at coustant P'"""",; to JO''C'. '!1re·
Box No. 2<>1 ｣ｯｬｾ､＠ •ir bu
(I) 'l'itonium di<>lliclc a. . \ htglrer d"w point
 I ul' '>
b 1\ h•Qh'T ｡｢ｾｯｬｵｴ｣＠ Ｈｳ ｰ ･ｾｩｊｬ＠ humldity 38 For the .\It-W•ter >ISI•'Tlt under •mbic:nt
ｾ Ｎ＠ A hiQher ｲ｣ｬｾｴｩｶ＠ humidity conditio•ns. the ｾ､ｩｯ ｨｮｴｩ ｣＠ "ituralion
d. A hi!lh'1' 1\cl hulb lcrnpc:rntwc lcmll<"""tur-e nnd the 11 ｴｬﾷ｢ｵ ﾷ ｴ｣ｭｾ Ｇｬｯ ｬｵｲ ･＠
34. AI IOI\ ｒ｣ｾ ｮｬ､ Ｇ＠ numiK.""' the powc1 (P) are nc.arl) c:qu.;L ｢｣ＺＮｾｵ＠
rc:q111red fi1r ｮｧｵｳｴｾ＠ n fluill in • >tirred • woter ｉ ｾ＾＠ ｾ＠ ｨｩｾＱ＠ lotenl he.t nf
ｴＺｭｾ＠ he'XllnC$ indepcnd<:11 t ol mcrli.•l "'>poralum
for.:cs. In llus hmil. tndlc•tc "luth of !be b. Lc11 ｩｾ＠ number ｩｾ＠ ｾｊｑＬ･＠ Ill unit)
f'ollo11 ing relat.on• i•l•tilfted c. ｴｨ･ｾ＠ arc 3)\\a}s equal uodcr all
n l'onlk t O ､ｲ｣ｵＮｮ ｬ ｾ＠
b. J>ua Rc41.• d. $llluhilit) of the c.omp;tncnt; or oiT on

om
c. r. .. Rc..., w•trris \Cf'\ a moll.
d P0 u Rc 1 " 311. If the Pr.mdtJ ｾｵｭ｢･ｲ＠ Ill grcat.:r llton the

P, P tiN'D' ＱＧｾＬ＠ nuntll<.-r Schmidt number,

Ｑ
Re ＬＮｾｭ Ｑ＠ • R..}nold's uumb.r a. the th=l bouncbn· '"'"" lo.!> on.ode
N it tl1c ｩｭｰ ｾｬ｣ｲ＠ rotation•! •peed, •nd l) i• ｴｨ ｾ＠ ｣ｯｾ ｬｲＮｴｩｃＡｉ＠ ｢ｯｾｮ ﾷ＠ L'l) cr.
b. the concentrotion boond:uy Ioyer hcs

.c
the 1mpell.:r di•m•1er
35 Ou: dcp<ndo:n.:c of the volumetric flo" inside the tho:rmal boundan• 13\,.-
rotc: (Q) t>n the prL"-'""' drop IS gi"cn b} c. tbe thennal •ml ｾｮ｣ｬｲｯ ｴ ｩｵｮ＠
boundar)• layers = of cqunl ｴｨｩ ｣ ｾｮ｣ ｵ＠ •
•\1' a. <t.

ce
d the hydrodynomic (o.e •• mo•pentuno l
fnr clifTttt:nt flow regime$ 1\. lau:h th<
bou11dary t..yer ,. thtcl.:er than the other
""Jl<l!lcnt n tr1 ｯｾ ｨ＠ nf the llow rcgitnc•
two.
gi1 en ｬ＾｣ｾＧ＠
40. So:.ood orc:kr consecutive irn::vc:rslblc
[\\' rite both ｯｮｳｷ｣ｾ＠
ra in the bo'< provided:
roactions
l'li•S No. 2. 10 I
(I ) Lnmmar It1m 1 --. 8 - . C
(rf) T urbulent llow were ｾ･､＠ out In n con•tant volume
lsothermol batch r.mctor with cliflcn:nt
m
(J\) n ' tl,S
!H) n = \LS lnitU..I fucd ＼ｬｯ ｭ ｰｯＬｩｴｮｾ Ｎ＠ Roactot
1.0 lcmpernluro wa.• Jome in all tho ｣ｮｾＮ Ｎ＠ ln
((') II
experinoeul;; wheoe Uoe ｲｾ ｬ ｩＱ＠ of
(0) 1\ 1.0
xa

36 A Ions tron rod mtltofly lit 3 ｲ｣ｭｰｾｬＧｯｌｵ＠ C<ln.,.,tttration of B lu lllllt of A in initial

ｲ ｾ･ ､＠ 1\ ._. less tluu 0 5, tllo conccnlrntion ur
llf 20"C ｨ｡ｾ＠ one end ｾ ｨｰＨ ｬｃ ､＠ '" boiling
114K"!' ( IOO"C) 111 tunc 1 0. 1l1c l!urvea B m cre.oed ftrst, reocbed • maximum and
-unoeo of the rod i.• ｩｮｾｵｬｴﾷ､＠ "' \hot hen! then declined 11 ilh time; llull C\.CI', fior all
ｾＭｲｩＺｭｴｮｓ＠ \\ltcrc thi; conccntrolion rodu
.e

｣ｯｮ､ｵｾ ｬｩ ｮ＠ is ｬｾｃＭ＼ ｉｩｭ ｣ｮｳ ｯ ｮ ｮｯｬ＠ io the nxi•!

\\'M 0.5 or Jbove. eonc.cntratiun or B
u ii\.'CIIOil. ｔｨｾ＠ IC'"JlcrDllll'<! ｾﾷ＠ • ､ｯｳｬｮ｣ｾ＠
100 mm fro;n l11o dippod end becomlll deerc:&'lcd munCJiilnicolly \11111 lime right
1o•c at t 200 •· l h" .. mo tc:mponrturc i; fum• the heginnmg. What " the rat10 nr
w

ochiC\-ed ot • diStance 200 mm from the lbc 111 >J ralc ｇｏＡｓｗｕｾ＠ !1-t k1l ｾ＠
o. ｉｾ＠
1hpp<d end at lund
"- I 283> b. 112
w

b t -J56o c. 2
ｾ＠ I - .llkls d. ｾ＠
d. Ill)(); ｾ ｉ＠ A ｾ｢･ｮＣ＠ I porouo cal.ll}'ll ponocle of
w

3 7, !he rJdi.tion hc;n Ou>t from a bcalinJ! rado"" It os ruhJCCiod to react•nt ..\ "h1ch
clement al n temperature of ｧＨＩｾ ｃＮ＠ on • atact.• 1J) form B b) • Lcro order ｵｲｴ＾ｾ･＠
ｉｕｮｾ＠ moonloined ot 300"1' is 8 k\\' m' R!>ction A -> B . Film m;m, tnnsfa"
n.e Du>. \\ b.n UIO ､｣Ｚ ｭ ｾＧｬ ｬ＠ tcmp.:ralurc iJ n:sisuru:e ;. negligible nod porC! diiTmion
inc:rcJScd to 1OI)U"C for t!oc umc funucc of A os rate conlrolhng The eflectivcnes•
tcmpcrotUI'(! « ｲ｡ｾｴｯ･＠ of Ute catllyst i5 rc:portcd 3, 7 8
• 11 .21:\\'n\ 1 \\'hicb of llic following .stah:mcnb ts trud •!
b. 120 1.. \\' m 1 a. Inner caUI)'51 con: of rod in• R 8 doe.
a. 14.6 ｾ＠ \\' rn' not partidp>te 111 reaction.
d. lfi.S I:Wim'
 5 or9
b. Inner ｾ ｴ ｯｬｹ ｴ＠ oore vf rndius lt 2 doe1 1>. T inc:t'¢:1ses trt a linear rate of I
not participate fn reaction mlvmin.
c. Inner ｃＡ ｴ Ｇ＼ｾ ｬ ｹ ｳ ｴ＠ c.ore llf radius 1R'8 l.l(>cs C. I Jumps to 18 m.-\ llncl Urcn l'a lb
nut pnrtic_.ipatc in ｴｾｊ ｾ｣ ｬｩ ｯ ｮ Ｎ＠ <Xp<!ueuti• lly • t the r•tc ･ ｾ Ｑ＠
cl F.llectivene.• foctur t<w • zero Qrder d. 1 jumps ｩｍ｢ｮ ｾＡｬ ｴＺｏ｜ｬ ｾ ｬ ｹ＠ to 11 mA und
l'tl:tction cnnnc1t he 71!1 >S it mlll\1 then inureases ｬ ｭ ･Ｎｾ ｲｬ ｹ＠ M the r•ie of 1
lllwavl! be I, mi\Jmin.
42 ft ｾ＠ dC!I ｩ ｾｴ ､＠ Ｑ ｾ＠ bring about u amain ehans.: -16. The frequency response 111' a clynomic
in the l!bte <•f a ｾｹ ｳ ｴ ･Ｚｭ＠ by p erforming d cmcul shows :t const;Jn& ruagJtillHic rntir,
IHJrk lin t.h.: >}'j;te.m omiCI' adiab:ttie at all lrequencie$, ll)e e lement ｣ Ｍ､ｬｩ｢ｯｴ ｾ＠ •

om
l!undilinut-. 11egntive plt>.'!c shtft at all ｬ ｴ｣［＼ ｴｕ ｾ ｦｬ ＢＡｾ Ｎ＠ 'lice
:.. 'rhe! :1lllOUnl o f work ｮ ｯ ､ ｾ ､＠ is palh- ｵ ｾｯ ｬｵｩ ｣＠ w luc u( .!lre ｰ ｨＮ ｡ｾ｣Ｍ slu n
derendent. ｩｮｾ･ｳ＠ linearly witlt frcquen.:y. Th•
h Work alone .:.>nll!ll bring ab11ui such. a eltmenl hmo she ｬｲ｡ｮ ｾ･＠ lhnclion
clutnge nf ' lat.,, a. e '"
c. 'lbc nmo uot or " 'ork needed i•

.c
r ts• I
independent of poth. b.
d. ｍｯ ｴ ｾ＾＠ uuouuatluu is nooded to
r,. - 1
＼ｘｾ ｮ ＼＾ ｬｵ､ Ｂ＠ anything Jboul tho path c. _£_

ce
､ ･ｰ ｮ､ ｯ ｮ ｾ＠ o r O!berwise of the wo rt< r,.r+ I
tteeded,
lf U1e beat of 1olulion of• n id<lal gas in 11 d. &:..:..'.
liquid is nogaliw . then its solubility ol u
-17. Titc second order system 11lth lllc tran•fer
ra
giYen partial pressure vnnes with the
temperature os
a. w htbility ""' ''cases as ｴ ･ｭｴ ＾＼Ｚ ｲｮｴｵ ｲｾ＠
.on
fu ncto
4
2s , It itS n dnmpmg
51
. •
ratoo
1
inctc38CS.. of
m
h. solubility decre.s<S as t.ernpernhJre a. 2.0
increases b. tt,S
ｾ Ｍ •ulubillty ｩｾ＠ in& pendeolt of c. tO
d. 4.0
xa

lcmp<.rnture.
11. onluhility ｩ ｮ ｾｦｏｊｒ･＼＠ llr ､ｾｬＮＧ･＠ with IJJ u dosed loop syslem. lbe process lo be
temperature dqlt:ndirtg ml the Ｈｊ ｩ ｾｴ＾ Ｇｳ＠ (;()ntroUcd i• :ut ｩ ｮ ｴ ･ｧｲ｡ｴｩ ｮ ｾ＠ process with
free eroef!\Y ch;mgd Of$O[ution. n lC
ｴｲ ｮｮ ｴｾ＠ I.er "4u.nctmn-
· . I . ｴＺ ｜ ｾ Ｑ ｲＱ＾＠ II l.!r'
lh 4n ｩ ｮｴ ･ｲｰｨ ｾ ｾ･＠ ｨ･Ｎｾ ｴ＠ transfer prO<IC>I<. the 2.$
.e

eqo1hllli llm •tnte corresponds t\1 t.tuality tJrvtlose<l to ｾ＠ ｕ ｎ ｾ､＠ " (to mt.,gral
o\f ｴ｣ｾｨｊ ｬ＼ｲ ｡ｬ ｾ＠ in the tii'O phaocs. wltilc
the condition lot uqullib•·ium in •u ｃ＼ｾ ｮｴｲ ｬ ｴｲ＠ with ｴｲ
1
ｯ ｾｓ ｉＧ･ｲ＠
fuijcliop - - , When
1;s
w

intoov luTNc ｭ ｾ＠ trnnsfer ptOe""• ｩｾ＠

a step clranllc rn s et point Is •pplicd to s uch
.o, c<junlity ｮｦ ｾ Ｍｮ ｮ ｣･ ｮｴｲ ｬ ｴｩ Ｈｬ ｮｷ＠
b. CtJunl ity Qfchemi.:a l tJIIlqru•ls a do.sed loop ;-ystem, the controlled
vatiable with exlciliil
w

1l.. etlu• li ty of :cctivity coo.fficio11ts

d. ･ Ｇｬｾ ｬｩ ｴｹ＠ of mru;s tt• n•f.,- ｾ ｯ･ ｦｬ ｜｣ｩ ･ｮ ｬＤ＠
a. 6vcrdaJnped r""pnnse
45. ,' \ rroportiunaJ phi>! intcgr.1l e<mlrollerwith b. Llnd<;rdamped response
c. l!n<bmped respoose
w

pi'Opoc,tlonnJ sensitivity K, l (ll}VmA

nnd mtegral tUuu T , I miu is initially at
steady •toto with 01TOr SlgPOI It = II and
controller outpull at 10 mA.. AI time I = tt.
a step change of I rnA is giv(ll co the error
" 'gn• L Tho conlro lloc output will sbow one
of the rollowrng respons.,.., Ident ifY lhe
corred oue.
IL 1 j umps inslllutaueously Lo II mA :end
l'l>mains otlhnl \'aluo lhoro::cflcr.
d. Llns labJe I'CSJ)OOSO
ol!l. A ccrb ln pressure vessel m:cnufacturor
avoids doing remtb rcement .calculations
for opeoin@S by always providin3 a
,..,infotcing pad extending up lo double tltt
!lilomuter of U1• or enin!l !llld of the ｳ ｾｲｮ ｣＠
ｭ ｾ ｴ ･ｲｩ ｡ ｬ＠ and ｴｨ ｩ｣ｫｮｾ＠ ｡ｾ＠ titat of the shell
"all. ll' orca ｣ｯ ｭ ｰ｣ ｮ ｾ ｴ ｩｯ ｮ＠ "' accepteil ｾ＠ a
code guideline. ｨ ｩｾ＠ Qllt@•ch ｬ ･ｮ ｾ＠ Ill safe
design
 () ur9
11 only if UlC r.pening is on lite ｾ ｰｨ･ｲｩ ･Ｎ ｯｬ＠ oonstant ｾｮｊ＠ V is Ute ｾｶ｣ｲ｡ｳ･＠ velocit} in
ves>el. the pipe. 'llle pump he3d (H) vcn;us tlr'"
b. unly ir the ｨｰ＼ ｮ ｩ ｮ ｾ＠ i" 11n ｾ＠ ve.tiCill mtc IQ) ｨ ｣ ｡ｲＳ｣ｬｩｾｴ＾･＠ is given bV
.,yliudric;,l vcssul. II Ct. I3Q
c, only if lite opening is on • ｨ ｮｬＧｾ｣ｭｴｲ＠ "ltcrc a JtJJd p att eotuiAnt>.
cylin(lric3l \1\:sij¢\. a. Ohu in an expression for U1e pres•ure
tL irrc:sp<H!lrvo of the shaJJi! gf the vessel. drop on the pipe ( \P} In lenns of the
SO. For a ｾｹｬｩｮ､ｲ･＾ｊ＠ ｖ｣Ｚ｢ｾ ｬ＠ of moderAte 1 ulurue llow rnte I()}.
helghl. the weld joint ｾｴｦｲ｣･ｮｹ＠ t'or joiniS b. Obtain an exprc'fisioo Jb r the sh:ody
ｰｾｭｬ･＠ to the cylinder ｡ｸｩ ｾ＠ is si"e" as 1.0 opcratlng now rote in tbe sy•t"111,

om
"hilc li"' joinl• nloug tloc !!irth llSsumin9 thnt the only pressure h•ss ln
Ｈ｣ｩｲ ｵｭｦ ｾＺｲ･ｮ｣Ｉ＠ it is given liS 0.8. lli lltcsyst<:m ｉＮｾ＠ due to the ptp<: Oow.
calculating the shell wall ｾＱ ｩ｣ｫｮ･ｳ＠ u.<ing 53. fl1 U1c lowcJ' JlOition of J • pray tower. or®
ll<lde ｦ ｩｭｮ ｵｬｾ Ｎ＠ ｦｯｲｾ＠ intemaUy pressurU.ed pelletx Ｈ ､ ｩＺｾｭ･ｴ｣ ｲ＠ D = 2 mm) are CXl<lle<lby
cylindriCAl ' 'tss<IL wbat valu<1 of ｷｾｬ､＠ joint •lr ·at a tem perururd T, = 20 " C". 111e
dlicicncy should be used? ｊ ＾ｃ ｬ ･ｬｾ＠ ore tollins. Ill theiJ' lerm.inal volocity

.c
ｾ Ｎ＠ 0.11 ｾ Ｌ＠ =- 6.9 rn/$. Tllll to.mpc:roture willtin the
h. (),9 ttellcl$ is unifrmn at oil time$, and the
c.. LO initiul ｴ ｣ｭｰ･ｲ｡ｵｾ＠ of the pclltts as so•c.

ce
d, ｯＮｳＩＢｾ＠ｴ 11\c hc•t ｴｲ｡ｮｾｦ｣＠ c:ocllieicnt fot • pellet
f•lling in nit is h = 208 \V1m: K,
PIYIIIAJDC:I Q_._llt & I I) 11. ｏ ｢ｩＮｾ＠ in an. ＼Ｚｾｰｩｮ ｯ＠ for t.he chnnge of
ra t"'npcnil.un: ()f 3 ｰ･ｬｾｴ＠ with tin"' rqt)].
5L Ethyl•ne Oxide ;., pt•oduccd by U1<! b. C11hmlotc the height of the tower Ｇｦｾｲ＠ 4
uxidalion of EU•yleuo o\u a CJJb lysL pellet l'l "'JOI to 60° C.
::iafaty co 0sidemtipns dicbti! tlmt the 54. IIKI ｭｯ ｬ ･ｾ＠ of on Acetonitrile
gaseous mixture e111ering the ｲ ･ｾｴＺｯｲ＠ nitro>ll<>thane ｭｩＮｾｴ］＠ i• dinen:utially
m
ｾｨｯｴ ､＠ contttin 10 mol alt- pa mol di•liUcd in • batch ｾｴｩｬ＠ ut • pressure of 71)
ｅＡ ｴｨ ｹ ｬ ｾ ｮ ｣ Ｎ＠ The conversion per pasS t:s 22fJo, kPo, Tho food rontaioJI Ｗｾ＠ mole •.
rhe l::thylene oxide fonned is completely acetonitrile. DistillatiQn ls .:ontlnued tlll
xa

condensed out ·and the: remninlng gases lhe liquid let bdlind in tbd slllt ｾｯｵｴ｡ｩｲ［＠ 32
I'I."Cvcled mole •o acetonilril<!. Tho vapour-liquid
ll lnie up oxygen U. oddod to mainbm the equilibria for the S)'Jitcm at thi• Jl"""'""'
l'eqUL$J!c oxygen levels. for n p lant are ｣ｯｲ･ ｬｾｴ ･､＠ ｾﾷ＠ lollo"'s :
ｰｲｯ､ｵ｣ｬｮｾ＠ 440 ki h of ｅｴｬＱｹ･ｮＭｯｾｩ､｣Ｎ＠ y+ I.OSx - 0.13 for 0.3 ｾ＠ x s O.S2
.e

(i1 Ollcu!nte the> I(Unntit)' uf J)urc ntllk<.rull y' - fl.71x. 0.2S l6r 0.52 ｾ＠ x ｾ＠ 0,8,
o>.'YS"" to he ｵｊ＾ｬＮｩ･＼ｾ＠ in kglh, in stcody whert X ｾｮ､＠ y• refer to ｴｨｾ＠ mole ｦｲｵｾｴＮｬｯｮ ｬ＠
Slate Qp erill inn. of acetonitrile in tho liquid and tquilibrium
w

(iii Draw • t!Coat blocl.. diaJ!,r•m ＮＱ ｨｯｷｩｮｾｴ＠ varour. rtsp<:eltvely.

tho- t!llljor units, iltJW& and ｣ｯｭ ｰ ｯｾｩｴｮｳＮ＠ Find the average c<HUJiusitinn uf lhc
nnd jndicote the ･ｮｶ ｬ ｾ｣＠ bO\Indary di•tillate c(>llected.
w

ｾｴｲｯｵ ｮ､＠ which the ,quisitc mollS balnncc:(s) 55, i\ liquid phose. tin;t order. reversible
ｩ ｾ＠ I arc bcinS mode. rcac(1on A 1:. B i• curried flU! in a
·n,erelevant rooctlun il rcptC.1entcd by coot.iouo"-' ｾ｜ｩｔ｣ Ｇｴｬ＠ ｾｯｬＮ＠ >vu.:tor (CSTR).
w

K':..t t.; • a, • 2c,u..o Mol>• dt.t3ilicy of A and B rue ;ome.

(g) (g) (g) 0 01.:t thins• (Auch as space lime, 11ow rntc,
IAl>swnc atmtLic m•sses os: C - 12,0 ｾ＠ J<i. lcnJ]l<:nlturo) remaining Ihe ｾ｡＠ me, a f.;cd of
(! lj. pllfc A tv U!c red<"hlr ｲｯｬ｜ｾ＠ in .J0°o
52, A nuid is ｾｵｭｰ･､＠ through ｾ＠ long convenoion ur 1\. while J Iced of ·pure B
ｨｯｲｩｺｮｾＱ＠ piJlC' of di>meter I) ond lengUt ｮＺｾ ｵｬ ｴｸ＠ in ｳｯｾＮ＠ cunvcnoiQn of R Estimate
L. u!tng o centrifuga l pump. ｔｨｾ＠ flow in tlte rc:acticm ･ｱｵｩｈｾｲ ｩ ｵｭ＠ cQnsllit•l. ａｬｾｵ ｭ ｣Ｚ＠
tho pipo is L'tininar with Utd J'nnning S(o;td} & told Ut1"'alion UL both ｾｬ ｃ＠ Cll$0$.
friction factor given by f = >VKe wh= Re
= 1:>1 ｰＮｬｾｴ＠ tS- th"' Reynold"s number. A >S Q
 I ol'9
81!CTIOH IS ( I) Urea
FJvw Marila au..u- (55 t. T1) (IJ) Phenol
Answor any TEN questions fix>m tltis aeclirut. (A)Atr
(B) Toluene
Write all your SllSWilts in the ans\veJ' book. Ali
<Jllesti ons t'lll:ly eqlllll. marks. (C) Carb.on dioxide
(D) Nihit oxidfr
( I 0 ｾ＠ ｾ ］ ＵＰ＠ Mad>s)
(E) ｍ･ｴｦ Ｌ ｾｭｯ ｬ＠
(F) Ammonia
56. The Wd$• lmlartce ･ｱｬｩｯｮｾ＠ of ｾ＠ blender
ar<!·
(G) Pn>pylcnc
(H)Gnmene

om
0.21'1 + 0,8 F) = 0.5 F
60. Wluah of ·the following gaseoos ftJels is
F,+ F2= F
likely fu have the lrighest Gross cnlorili.c
Express the equation set given above m a
value ?
matrix furu1 AX= b where
a. Sewage Gas
ｸ ｾ ｬｦ y ｩ＠ ｾ P' ｊｲ＠ b. LPG
c. Protlu!X'l' Oas

.c
rina clte inverse of the malll:X A. ｵｾ･＠ d. NaturJl Gas
61. LOOO Kg/IL of 1111 aqueous solUiion of 20%
F; and
N'a1C0 3 js cooled graduilly ro t °C, tu

ce
P'
cryst:illize uill ｎｾ Ｐ ＳＮ ｬｏ ﾷ ｨ ｏＮ＠ 11Je
!:L ｾｯ ｬ ｵｨｩｬｹ＠ o[111<•2C0 1 al f C IS ｾ Ｍ ｉ＠ o/o.
F' Calcula.t e the percentage of Na2C03
57. ｾＱｭＡ＠ the dlmenl!ion• ,,f n, hollow ll}1inder recovered ci11 the fom1 "r erystals.
wifh hoih ends d ose<l 1vhich C"'J hold
ra 4
- m1 o f water aud. has .nunlmonl
-27Tt . . outer
(Assnme. no loss of N<J,C03 ｬ ｬｾｲｯｵｧｨ＠
mor.lter Uqoor adhering to the crystals and
110 •'llrl)' OVet or ｃｉＩＧｓｕ
lhe

ｾ ｳ＠ wi!l1 LhelTJOlhe;
surface area. Uquo(). Draw u ｮ･ ｾｴ＠ btock diagram
m
58, Eacl1 item of equ.lpmen.t mentipned in ｾｴ･＠ •lmwing tile inlet and exit cnmpo•itiollS
left hand column ls identified witl1 U1c ｡ｮｾ＠ flow rates.
manufucturing process for one of lite [Molooulllr wc1ght of Nu2CO:;- can be
produci:s mentioned in me. tigllic hand
xa

assumed to be J 06 and Utat of water to be

-oolumn. Match the equipment with. tlte t8j,
｣ｯｲ･ｾｰｭ､ｕ ｊ ｧ＠ product 6'2. 1000 kg.lll of a thcnuicfhtid. ta be osetl as,
(I) l"emtenior a :heat transfer medinm, Ｎｩ ｾ＠ ｢ｾｩｮｧ＠ wdU·ectly
(U) Membnute Cell heated in a heater, from 380 K to 550 K.
.e

( Ill) ｗ｡ｳｴｾ＠ heat boiler Calculate ill<'' hoot Jollil. on Ute Jtcat<.'r, w
( IV) Rollil)' l:i ln k.W. A'lso &sfin·,atl! !lie.mean ILeat ｃｬｰ｡｣ｩｾ＠
(V) Prl Ulng Tower of U•e tnemrlt' l111fd over the telil]letalltre.
w

(A) Ammonium nitrate range oflntor((s!.

(13) ｾ Ｍ ｨ｡ｮ ｬ＠ ｴ from mt1lusses 1-'he l1eal Cllpacity equaticnt ftJr 'the thennic
(C) C::aUlitic soda ｦｴｵＮｩ ｾ＠ i•
C.= 1"43<1 + 0,002 I8 T,
w

(D) Di A.mmonium phosphate

(E) Sulphunc. acid. wl1ere <; is in ｫｊｦｾ＠ K, ru1d Tis in K,
(F) cement 63. A mum! fhliJ jel imping.S on u ·nat ph11e
w

(G) YeUow p.ho;;phoru.s ami Ａ｜ｰｲ･｡､ｾ＠ out radiall:y tQ fOTJll a film of

(H) Sodium ｭｾ ｴ ｬＳＱＮ＠ decrea;;ing thickness as shown below,
59, Al••wer thtl following ! I
a. Each C>f dte products m<'I!tioneii in dte -. ｾ Ｎ＠

left ltand .c olumn requites one or more

oftlte raw materials I starting omterials
ｭ ｾ ｬｴｩ ｯ ｮ･､＠ in lJteiig)Ji ｨｷｴｾ＠ coltlllllL
Match tlte products wilh tile
appropriate .:aw ma!erial{s) f !!lartlng
materi.nl(s).
 11 o(' ')
64. The rndin• of the jet far from the a. ｏ｢ｾ ｩｮ＠ nn expre<sion for the l<:ngth of
ｾｬ｡ｧｮｴｩ ｯｮ＠ j)Otnl (0) is 11. :md the ｜｣ｬ ＨＩ ｾｩｴｹ＠ the heat exChanger re<tulred t\! CUrt)'
is u. ａｳＮｾｵ ｭ ･＠ Ute lluw Ill be ＧＢ Ｇ Ｇ ｩ ｾ､ ､＠ find uul the hc•li!li illltt.Jtitm. ａｾｷ ｭ ｣＠ IJ,;t
ｬｾｩｳｹｮｵｯｴ Ｎ ｲｫＬ＠ and ncijlccl g ravity. Also ur
the uutcr diumclct the ittnat• pipe ﾷｾ＠
ＢｾＧＱ＠ tluu the w looity prqfiles •1" Ant nc.1rly •><tun I to i!JI i11Ki!le !li:t1neter. 11•e
(iotirom the ＿ ｴ ｾｧ ｮｵｴｩ＼ ｊ ｮ＠ ｰｾｩｮｌ＠ fhe presl!Uttt specific heat ｣ ｯｰ ｾ､ ｴ Ｌｹｮｦ＠ tho 11uid ｩｾ＠ C.,
llulSi(lt> the ,icl iR :iUitoSphCJic UIIU tlle •ud its ､ ･ｯ ｾｯ ｬ ｹ＠ is p.
d<'llilily of lllec11u[d tl') is cmllllrutl b. Obt3iu an ""pression for the optitnum
;.. Obl.'lin the velodlv of tho fluid in IJI., diamelllr al whkh Lbe heal o:<clmnger
film (-v(r)) nnd the ｬｩｵ､ｮ･Ａｾ＠ or film length is minimum asnm1iog h1=t 'I) 11

om
(t(r)) at • ny t'ildial ､ ｩｳ ｬ ［ ｭ ｾＮ･＠ t for from wher.; C ;, • oorulanL
th\,.' ｾｴｬ｡ｧｮ［ｩｯ＠ point 68. A plU'c gas is bubbling througb o c<>lllnm
b. ｏ ｾｴｯｩｮ＠ the norm• I mrce act.ing on tllo of llcjuid ol o ｾ ｵｦｬＱ｣ ｩ｣ｮｴ ｬ ｹ＠ slow r>l'll thntthe
plate, bubhles OI'C well separated rrom each
I>S. A oon".:oltah:d suspension of spl\crlcul other. T he bubbl<:l! are spl•e•ical ru·e 3 •ncu
<1u:u1z pru•ticl'"' in \Vole< •cllk'S wtdc;r in ､ｩ｡ｲｵ Ｎ ｣ ｬ ｾｲ＠ .. and rise '' ltb consto.nt velocity

.c
ｧ ｲｾｶ ｩｴｹ Ｌ＠ 1'he particle din.meter los 0 0= Ui"'m of 0 U .mls, A! •ny given time. len bubble$
:tnd lh.: '(l)l1icle den•ity is ｴ＾ ｾ＠ = 265() ＼Ｚｾｮ＠ be seen in Ihe liquid. Ute ll<1uld volume
kg/Jlt' . l,'he iniltltl voiWig" in tl1c being 3.14 HJ- 1 n11 11t" li•1uid conlJiin.•

ce
ｾ ｕｓＡｉ･ｮｬｩＨＩ＠ is Ｑ Ａｾ＠ O.R. 110 dissolvocl !\M 19 -•t.-11 will1. nnd n1ay be
n. Ohl• in the ｣Ｎｾｰｲ･ｳ Ｎ ＼ ｩｯｮ＠ tor tho te.minnl ｡Ｎ ｾ ｵｭ･､＠ to be well mixed at ｯ ｬｴｩｭ ･Ｎｾ＠ The
velc)<lily (u,) of n ｾｩ ｮ ｧＩ･＠ p:trlicle ｭ ｾ＠ transfer ooenidenl tor this siruatocm
Assuming Stoke's law tel he ｶｾ ｬｩ＼ｌ＠ is ｾｙ ･ｮ＠ by ｈｩ ｾ ｢ｩ ･＠ 's PcnctratiOrl tliCOI)' It$

k-r D
ra
1:1. 'Fmd the initfzil setting velocity (u.) of
the partlcle in the ｾｕ ｩｦｐｴｮ ｯｩｮ＠ gi\'en I- .T/•
u, = ul s-Hi
"h..re
.:. ＨＺ ｮｫｵｬｴ the ｵｰｷｾｲ､＠ ｾ＠
velodty uf "ater
m
D : dtlfcsivil) ofthcga.• in ｾ ｣＠ li4uid.
ia the •tl!;p.:nsion l<:>ulting from tho: ｾ＠ 2 Ｑｻ ｾ＠ m 1l4. und
setting of the particles for c; 0.8.
f' ｾ＠ time of conuoc.t hetw""" ll(tllld
l'lte ｷｾ ｬ＠ of • cold •forage ·unrl contpn•"'' a olcm<11tS ｾ ｮ､＠ the gas. s.
xa

bri"k l:oyet ｬｨ｣ｫｮ･＼ ｾ＠ /Ia = tl.l m. thermal Odcnninc ll•c tirno il takes for the liquid
conductivity k.o "' 1:4 W'•t•K) l!Jtd no inn.,. In nllo in 50'!, Of lh<> ａ ｮｨＺｾｴｩｯ＠
lAyct nf (lOlyul'CIIUniC l<>3nc Ｈ ｴ ｨ｣ｫｾ･ｳＮ＠ Ｐｾ＠ ･ｯｮ｣ｴｲｾ ｬ ｩ ＼ｭ＠
0,05 nt, Uu:nnul conductivit) k11 = 0,015 The ｣ｾｲ ｢ｮ＠
diox.tdc Ｑｳｾｮｩｧ＠ c)ul of' •
.e

\V/111K) ａＮｾｳ Ｑｵｮ ･＠ \Inc lli.men.<ion>l hent F'crm<;nllrr con!Jli.tt 0.01 mol l't•ction <>f
U'ilnster by conduction Utrough the ｣ｴｨｮｵｾ＠ whiol; has to l•c 1\lduced to 0.011{) I
｣ｴＮ ｭｰｯｳ ｩｴ ｾ＠ w•ll •nd tbnl thd [ru,.,,. Jurfncd mole fhtction by •crobbing with waoer in a
of Ute ｰｯｬｹｮｲ｣ｕｾ･＠ layer is •ltnnp=tutc counteJ'Cuoreot packed to" er. .l11e gas
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·r. ond the nuter surfnce or the brick l•yer D()wralc ;,. 227.3 ｫｲｵｯｌｾｬ＠ and UIO)' be
ｩ ｾ＠ nl ｴｾｰｯＺｲｵ･＠ '!'.,. ｡ｳｾｷｮ｣､＠ constJtol lhroughouo the tower
!4 Derive 011 I:XJll'es•ioo fru· Utu h dOl nux 'fl1e t;qnillbrium mol• G-.ction of eth>nol
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per unit area Utrough the w•lL

b r nleu late the ｲｯｴ･ｾ＠
he• I ｧ［ｾｩ ｮ＠ whil11 1',
in llte gos pltase()
llc1uid (lt) ns
·,is
related tO that in U1e

- w•c anti Th - ｾｯ ﾷ｣ＮＺ＠ Tho surfuco y • = L(l7 X

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ahm for heat ltansfer 0.260 m:. Determine the minunum li<1uid mle
67. A fluid ﾷｾ＠ ｨ･Ｚｾｴｯ､＠ fmm ｾ＠ tompcr.ttun> '1'1 to
r. in • dmthle pipe heat exchnnger with needed. •••II
lh• number of ovcnoll gas-side:
ttonsfcr tutil!l nuodcd nl 1.5 timl!!l the
sterun condeu•ing in the outet• pif><: ol a minimum liquid rote. 'l1te entering liquid
tcmpcnturc r,. l'ho flow rnlc of fluid UL may b;: asRumad 1<1 IJU free of et11anol,
Ute mner 11ipe (inside di;tmeler I}) i• (,!. 70. ｓ ｴｾ［｡､ ｹ＠ s tate ｰｬｵｾ＠ Do\\ Nnetor (PFR) dallt
nnd tltd heal transfer c:oeffietenl ls b,. -rhe for i..otherjm I irrvvcrsiblc ,..,.ction
1:i1m ｢｣ｴｾｬ＠ tr:uufer cocfl'ieMtt fo1 tho A B
co•!dcn•ing $leone iii h(l. und U1o 1\ •U
ｾ｣Ｚｳｴｬ ｮ ｣･＠ and fouling :rre negJigiltle.
 9 o t<l
,. os •hnwn m the ｬＮ｢ｾ＠ ｒｾｴｯｲ＠ fJlllCC mole "• Olcyf!<"n. 77 mole "• nitrogen end
tnne •• as I0 •CC<Jnd• m both the C35e-. Ihe rest inerls 11te "andanl Gibl> ·s f'm:
O Uter Uoin11• su.:lt a. IC.:d and produ.:t ｅｮ＼ｾＸｙ＠ ､ｴｮｾＢＧ＠ for the rc:.diun '' 11.'.8.l
dcn>tty. rcaetm ll:nopc:tatuoc ct". ore-"'"'" IJ mol< ut litis lcntllCNturc. As•uming
in h<Jih the CA>;CA ideal gos hehnviuur, col<ul•tc the ｰｾｲｩ｡ｬ＠
('olnrcn trnllfolt of ,\(11 mollm-1 JlfCM$Un:s Of oil Kp<.'\:ies lll C<lllillflrium.
In fo'erd In Product 74. ·nu: cbnr;o.otcri•lic l.'lluutiou of ｾ＠ ｾ ｾ ｾｳ ･､＠
CtlSc: 1 I 05 loot! ooturol ｾｹｳｴ･ｭ＠ i•
Cuc U 2 o.sss 11.25 s' • (1.8 ｾＧ Ｍ S.6ll I O..'S 1\ = 0.
f the ｲ｣Ｚｾｴｩｯｮ＠ i• blown lo be of noo-zem l' ind lite lim il mg \IIIIUc vf 1\ - " - · ahU\ e

om
mteger order. lind the rcocbon order and "hicb the clu•ed luvp >)slern ,.ill be
!be UIC IXlllSI.lnt ucuublc
71. .\ P"l1icuLu- ｭｾｴｯｬ＠ rcacl> \lith ｾ＠ ccrtJWJ 75 A photoele<:tric pyromdl!r u u.•e.d to
loquid •nd the product p,...,, into solution. m..asure the lemp<nlurc of bot billru
I hree nnn ·porous solon ｾｰ｢･ｲｳ＠ nr same ha' ing • tcmpcr.tluN of!XIo• C and pLte<:d
on • moving grnte. lnQ pyrometer b.1s a

.c
ｭｾｴ｡ｬ＠ ond of diomotc-rs I0. 20 onu 30 tnllL
r-."'pc:ctivoly were ptoc,d in • very l!rgo li,..t llffier '"'Jlonse wilh • time <:onslnnl of
ｾ ｴｩｲ ･､＠ pool of n:acbve liquid ot the ••me I s. hacl, billet is lu the lield or voew o(
time. Aller an houo , it was lbund !hat the pyrcnn"'"'' for 2s. Tho bill.rts a.re so pbccd

ce
pool bad only two ｳｰ ｨｾｲ｣ｳ＠ of di:unctcr 10 on tile ur11te Lhnl thC'I'C' 1.1 a one second
and 2ll mm, rcsplldl\cl) . .\llcr onnther loterv•l between the exit of ｯ･ＭｾＱｬｴ＠ from
hour. the 1)1101 hod oonl) nne •ph= nf lhc field of VIC\\ of p) ｲｯｭｾｴＮＬ＠ onJ entry
lliamch:r Ill mm. 11tb Jphtrc >l<o
ra of the: next bilk:t in line. The ambient
ｬｩｾｰ･Ｎ＾ｲ｣､＠ aOcr iftolht> hour. lcmpaoiUre is 50"C A11.•umc lh•t !he
E."pl.o in tho:<c nb•CT\ •lion• through •yslem is 1n operaltott ft>r • fe\\ hours.
•ppl'l)pri:ate ｴｬ｣ｲｩｶ｡ ｾｯｮ＠ ll!tn.s > mOre ｾｫＢｬＩ＠ Write: tqualio!b for llo rumg :r.nd Collins
rate cuntrollin11 llcp uul ill' the lillluwing portit>IIJ of the pyromctor rOSJIOOSc.
m
7!•. fJor a O•oged jQinl, ;, prop011cd co ,,.. bolts
'"'"·
(i) Film m•s• trnnorli:r o n a !lange with bolt 1'001 doumeter of 12. 5
(it) Surfocen:JJeticm nun. Titc AIIOWahlc •tr"-!1• fm lite 1>1111
m>Lc:riAI ｾ＠ 150 ｾｉｎ＠ 'ml , 11to ｬｾ＠
xa

72. .-\ mixture of A and U l:{ottlomu ｣ｬｯｾｽ＠ L<J I bllll kl•d

ＡｏｯｵｬｴＢｾ＠ Llw The pure oompon,,ll. 'apour i< I .6 \11\ Rt:l!nmonc:nd • minimum
pn!'>Sun>. PA.. •nd I'D.. m IJ>a trc gj\.cn numher ofbnlt• thot<hould be pro• rdcd.
h) (tin ｾ ｣Ｉ＠ n. Copiul cOSt ofa pi reline of c:.'(I)Lic m•LL-rial
i> ｾ ｬｴｭ｣､＠ ., 3 o•>Rs on. "here 1) ;,
Ill P4"'" ｬｾ Ｎ＠ 21 -
2945
.e

11224
pipe diameter m mm The ｡ｮｾ＠ I
rnaintcnan"" ｌＧｬＩｾ＠ "' t:!>lintotod .., IO• .. uf
Itt ｰ ｾﾷ＠ t 4. 2()
ＲＹＷ
ｾ＠ the 111111 COfliiJI I I!IISI. 1\rtttiUII IIIIC'I:Ilutg
it 2()9
"'"t nfthe>pipc i• pi,·cn n• lirllnw• ,
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rf lite bubble point of·' \lCr'lnm nti.xlure of

. ' ｉＨｾＧ＠ 10
A 1111d B'" 76 I' •• a tola l pressure of 80 Annusl opcratmg c:u•t - -::-i'. _....;.;:___
kl'a. rend t.he conoroslhon or
the litsl D 111 l>t<ll
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,,.pour tbot form•. Eslim;ste the mosl eoonunuc: PII.C di.:unctc.."'l

73. J'h\1 roction ｾＬ＠ 0: 2)':0 lakes plAt<! m ll••ed on the le..l ｾｮｭｵｬ［ＨＡ＠ "Prnuch to
the gas pha<e at :now c and 2025 ld'a. lhc ncoftl;l mulltplc nf lllmm [O.<timated
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l11e ""'ction ｭｩＮＬ［ｴｵｲｾ＠ onito•lly .:ompris.::s 15 omOo1JZ3tion ｾＭｲｩｯ､＠ '' I 0 yeor>