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Q.3 When AgNO3 is added to a solution of Co(NH3)5Cl3, the precipitate of AgCl shows two ionisable
chloride ions. This means –
(A) Two chlorine atom satisfy primary valency and one chlorine atom satisfies primary valency as well
as secondary valency.
(B) One chlorine atom satisfies primary valency.
(C) Two chlorine atoms satisfy secondary valency.
(D) Three chlorine atoms satisfy secondary valency.
Q.4 A co-ordination complex of cobalt has molecular formula containing five ammonia molecules, one nitro
group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole
ions in an aqueous solution. In reacting this solution with excess of silver nitrate solution, two moles of
AgCl get precipitated. The ionic formula of this complex would be –
(A) [(Co(NH3)4.NO2Cl].[(NH3)Cl] (B) [(Co(NH3)5Cl].[Cl(NO2)]
(C) [(Co(NH3)5(NO2)]Cl2 (D) [(Co(NH3)5].[(NO2)2Cl2]
Q.5 Which of the following complex will give white precipitate with barium chloride solution –
(A) [Cr(NH3)5Cl]SO4 (B) [Cr(NH3)SO4]Cl
(C) [Co(NH3)6]Br3 (D) None of these
Q.6 In the complex Fe(CO)x, the value of x is, if it follows sidwick EAN rule :
(A) 3 (B) 4 (C) 5 (D) 6
(A) I and II (B) I and III (C) II and IV (D) II and III
Q.6 In which of the following coordination entities, the magnitude of 0 [CFSE in octahedral field] will be
maximum? :
(A) [Co(CN)6]3– (B) [Co(C2O4)3]3– (C) [Co(H2O)6]3+ (D) [Co(NH3)6]3+
Q.10 For the t 62g e g2 system, the value of magnetic moment () is –
(A) 2.83 B.M. (B) 1.73 B.M. (C) 3.87 B.M. (D) 4.92 B.M.
DPP-2
Q.1 C Q.2 D Q.3 A Q.4 C Q.5 A
Q.6 C Q.7 C Q.8 A Q.9 C Q.10 B
DPP-3
Q.1 C Q.2 C Q.3 C Q.4 C Q.5 D
Q.6 A Q.7 A Q.8 B Q.9 B Q.10 A