Sei sulla pagina 1di 2

Ci Ce qe 1/Ce 1/qe logCe logqe

150 21 32.25 0.047619 0.031008 1.322219 1.50853


200 57.6 35.6 0.017361 0.02809 1.760422 1.55145
246 96.5 37.375 0.010363 0.026756 1.984527 1.572581
299 149 37.5 0.006711 0.026667 2.173186 1.574031
354 189.2 41.2 0.005285 0.024272 2.276921 1.614897
400 229.4 42.65 0.004359 0.023447 2.360593 1.629919
446 289.7 39.075 0.003452 0.025592 2.461948 1.591899
493 341.2 37.95 0.002931 0.02635 2.533009 1.579212

Plot of Langmuir Isotherm


0.035
0.03
0.025
0.02
1/qe

y = 0.1356x + 0.0249
0.015
R² = 0.7664
0.01
0.005
0
0 0.01 0.02 0.03 0.04 0.05
1/Ce

For Langmuir Isotherm, 1/qe = (1/qm* KL)*Ce + 1/qm


So, 1/qm = 0.0249 (Intercept)

Therefore, qm = 40.1606

(1/qm*KL) =0.1356 so, KL = 0.1836

Therefore, the value of Langmuir Isotherm constant, KL = 0.1836


Plot of Freundlisch Isotherm
1.64

1.62
y = 0.077x + 1.4154
R² = 0.6974
1.6

1.58
logqe

1.56

1.54

1.52

1.5
0 1 logCe 2 3

For Freundlich Isotherm, LOG (qe) = (1/n)* LOG (Ce) + LOG (KF)

So, LOG (KF) = 1.4154 (Intercept) and (1/n) = 0.077 so, n=12.987
Therefore, KF = 10^(1.4154) = 26.0256

So, the value of Freundlich Isotherm constant, KF = 26.0256

For langmuir isotherm,


the regression coefficient value is 0.7664
which is more closer to 1
while regression coefficient
for Freundlisch isotherm is 0.6974.
Hence, langmuir isotherm is more
appropriate for the given set
of values of Ci and Ce.

Potrebbero piacerti anche