polar molecule is called dipole-dipole
GAS LAWS
1
Force.Interaction energy v , 1) Introduction of absolute scale of ther-
r6
r = distance between polar molecules.
Dipole – Induced Dipole forces :-
The force of attraction between
molecule with permanent dipole and
molecule with no dipole
moment is called Dipole – Induced Dipole
forces.
1
Ÿ The interaction energy v , also
r6
depends on dipole moment of the polar
molecule and polarisability of a second
molecule.
Hydrogen Bonding :-
Ÿ The weak electrostatic attraction
that occurs between covalently
bonded hydrogen and high electro
negative atom of same molecule
or different molecule is called
hydrogen bond.
Ÿ High electro negative elements
with small size( F, O, N) form
hydrogen bonding.
Ÿ Example HF, NH 3 , H 2O, C2 H 5OH …….
Ÿ The strength of Hydrogen bond is 10 to
100 KJ/mole.
Ÿ It is strongest of all inter molecular forces
including the Dipole-Dipole attraction and
London forces.
Ÿ It is above one-tenth on a strong a
covalent bond.
Ÿ Inter molecular hydrogen bonding causes
high solubility in water, high M.P., B.P. and
molecular
association. ....H G - FG .....H G - F G ...
Ÿ In ice each water molecule is
bonded to four water molecules
by hydrogen bonding.
Ÿ It has cage like structure and
having air gaps.
Ÿ Because of this structure. It is less
denser than water, it floats on
water.
Theory based objective Problems:-
mometry is the result of:
a) Gaseous law b) Graham’s law
b) Charle’s law d) Dalton’s law
2) When gases are hated from 20 o c to
40 o c at constant pressure,the volumes:
a)increase by the same magnitude
b) become doubled
c)increase in the ratio of their molecular
masses
d) increase but to different extent
3) At constant pressure the volume of fixed
mass of an ideal gas is directly proportional
to:
a) absolute tempratureb) degree centigrade
c) degree ferhrenheit d) none of these
4)Pressure remaining the same , the volume
of agiven mass of an ideal gas increases for
every degree contigrade rise in temprature by
a definite fraction of its volume at:
a)zero degree centigrade
b) its cretical temparature
c) absolute zero
d) its Boyle’s temprature
5)Which statement is incorrect
a) A curve plotted between P and V at con-
stant temprature is called isotherm
b) A curve plotted between P and V at con-
stant volume is called isochore
c) A curve plotted between V and T at con-
stant pressure is called isobar
d) At absolute zero, the gas equation holds
good
6)A flask of methane ( CH 4 ) was
weighed,Methane was then pushed out and
the flask again weighed when filled with
oxygen at the same temparature and pres-
sure. the mass of oxygen would be:
a) the same as the me thane
15
b) half of the methane
c) double to that of methane
d) negligble in comparison to that of meth-
ane
DALTON’S LAW
7) Dalton’s law of partial pressure is not
applicable to :
a) H 2 and N 2 mixture b) H 2 and Cl2 mix-
ture
c) H 2 and CO2 mixture d) None of these
8)A vesel has twoequal compartments A and
B containing H 2 and O2 respectively, each at
1 atm pressure. If the wall separating the
compartment is removed,the pressure:
a) will remain unchanged in A and B
b) will increase in A and decrese in B
c) will decrease in A and increase in B
d) will increase in both A and B
9) which gas has the heighst partical pressure
in atmosphere
a) CO2 b) H 2 O c) O2 d) N 2
10)A bottle of dry NH 3 and bottle of dry
HCl connected through a long tube are
opened simultaneously at both ends,the
white ( NH 4 Cl )
ring first formed will be:
a) at the center of the tube
b) near the HCl bottle
c) near the ammonia bottle
d) throught the length of the tube
11)which pair of the gaseous species diffuse
through a small jet with the same rate of
diffusion at same P and T
a)NO,CO b) NO, CO2
c) NH 3 , PH 3 d) NO , C2 H 6
12)Which is valid at absolute zero
a) KE of the gas molecules becomes zero,but
molecular motion does not become zero
b) KE of the molecules becomes zero and the
molecular motion also becomes zero
c) KE of the gas decrese but does not be-
comes zero
d) None on these
MOLECULAR KINETIC ENERGY
13)The kinetic energy of molecule is zero at:
a)0 o c b)273 o c c) -273 o c d) 116
16 o c
14) At constant volume for a fixed number of
mole of a gas the pressure of gas increases if
the rise of temperature due to.
a) in crease in average molecular speed
b) increase in number of mole
c) increse in molecular attraction
d) decrese in mean free path
15)The pressure of a gas is due to:
a) the collision of gas molecules against each
other
b) the random movement of gas molecules
c) the intermolecular forces of attraction
between the gas molecules
16)consider an i deal gas contained in a
vessel. If the intermoleculer interctions
suddenly begins to act,which of the follow-
ing will happen
a) The pressure decrease
b) The pressure increased
c) The pressure remains unchanged
d) The collapses
17)Kinetic theory of gases proves :
a) only Boyle;s law
b) only Charle’s law
c) only Avogadro’s law
d) all of these
18)Molecular attraction and size of the
molecules in a gas are neligible at:
a) critical point
b) high pressure
c) high temprature and low pressure
d) low temprasuter and high pressure
19) The behaviour of a real gas is usaually
depicted by plotting compressibility factor Z
16
vs .P at a constant temprature .At high
temprature and high pressure, Z is usually
more than one. This fact can be explained by
van der waals’equation when:
a) the constant a is negligible and not b
b) the constant b is negligible and not a
c) bothe the constant a and b are negligible
d) both the constant a and b are not
neg;igible
20)At lower tempraters,all gases show:
a) negative deviation
b) positive deviation
c)positive and negative deviation
d) none of these
21) For real gas,deviations from ideal gas
behaviour are maximum at:
a) -10 o c and 5.0 atm
b) -10 c and 2.0 atm
o
c) 0 o c and 1.0 atm
d) 100 o c and 2.0 atm
COMPRESSIBILITY FACTOR:-
22) The compressibility factor for H 2 and
He is usually:
a) >1 b) =1 c) < 1 d) either of these
23) A real gas most closely approaches the
behaviour of an ideal gas at:
a) 15 atmosphere and 200 K
b) 1 atmosphere and 273 K
c) 0.5 atmosphere and 500 K
d) 15 atmosphere and 500 K
VAN DER WAAL’S EQUATION:-
24) In the van der Waals’ equation, the
constant “a” and “b” with temprature shows
which trend
a) Both remains same
b) ‘a’ remains same,bvaries
c) ‘a’ varies,b remains same
d) both varies
25) The pressure of real gas is less than the
pressure of an ideal gas because of:
a) increase in the number of collision
b) finite size of the molecules
c) increase in the kinetic energy
d) intermolecular forces
26)The value of van der waals’constant ‘a’
for gases O2 , N 2 , NH 3 and CH 4 are
1.360,1.390,4.170 and 2.253 l 2 atm mol 2
respectvely.The gas which can most easily be
liquefied is:
a) O2 b) N 2 c) NH 3 d) CH 4
27) In van der waals equation of state of the
gas law,the constant ‘b’ is a measure of :
a) intermolecular collisions per unit per unit
volume
b) intermolecular attractions
c) volume occupied by the molecules
d) intermolecular repulsions
28)Which gas can be liquefied most readily
a) NH 3 b) Cl2 c) SO2 d) CO2
29) Which forces of attraction are respon-
sible for liquefaction of H 2
a) Coulombic forces
b) dipole forces and vam der waals’forces
c) Hydrozen bonding
d) none of these
30) The temprature at which the second
viritial coefficent of a real gas zero is called:
a) critical temperature b) eutectic point
c) boiling point d) boyle’s tempreture
31)An ideal gas expands according to
PV=constant.On expension,the tempareture
of gas:
a) will rise
b) will drop
c) will remain constant
d) cannot be determined bacause the external
pressure is not known
32)A liquid is in eqilibrium with its vapours
at its boiling point. On the average the
molecules in the two phases have equal:
a) intermolecular forcesb) potential energy
c) total energy d) kinetic energy
17
 LIQUIDS a) 3atm b) 2 atm
33) Vapours of liquid exit only: c) 4atm d) 5atm
a) below b.pt.
b) below critical temperature 42) Calculate the resulting temperature
c) below inversion temperature change if a 52 d.m3 sample of a gas at 250C
d) above critical temperature is isobarically expanded to 104 d.m3 ?
a) 596 K b) 298 K
34) Which statement about evaporation is c) 300K d) 198 K
incorrect
a) Evaporation takes place at all temperature 43) A 100 ml flask contained H 2 at 200 Torr
b) Evaporation occurs only at the surface and 200ml flask contained He at 100 torr.
c) Evaporation produces cooling The two flask were than connected so that
d) Avegrage K.E of residual liquid molecules each gas filled their combined volume.
increase as evaporation occurs
Assuming no changing temperature, total
pressure is
35) surface tension does not variey with a) 300 torr b) 66.66 torr
a) Temperature b) Vapou pressure c) 152 torr d) 133.33 torr **
c) Size of the surface d) concentration
44) Equal weights of HF, HCl, HBr, Hi at
36) which among the following has the least 870C, and 750 mm Hgpressure taken. The
surface tension correct sequaence of these gases the
a) benzene c) acetic acid increasing volume is…
c) di ethyl ether d) chloro benzene a) HF < HCl< HBr<HI
b) HI<HBr<HCl<HF
37) Compressibility factor for a gas under c) HBr<HI<HCl< HF
critical condition is. d) HCl<HBr<HI<HF
a) 3/8 b) 8/3
c) 1 d) ¼ 45) The rate of diffusion of hydrozen and
Deuterium are in the ratio
38) At Boyle’s temperature , compressibility
factor Z for a real gas is a)1:1 b) 2 :1
a) z = 1 b) z = 0 c) 4:1 d) 1:4
c) z >1 d) z<1
46) A gas with molecular formulae Cn H 2 n  2
39) The units of compressibility factor are diffuses through a porous plug at a rate 1/6 th
a) atm.lt 1 b) atm.1 rate of diffusion of hydrogen gas under
c) lt 1 d) unit less similar conditions. The formul of the gas is
a) C2 H 6 b) C10 H 22
40) The average kinetic energy for molecule
c) C5 H12 d) C6 H14
of an ideal gas is equal to
a) 0.5 kJ b) 0.5 RT
c) 1.5 KT d) 1.5 RT2

41) Calculate the pressure necessary to

compress isothermally a 105 d.m3 sampl of
air at 1atmosphere to 35 d.m3 ?

18
 KEY 6) A bubble of volume V1 is at bottom of a
1) c 2)d 3) a 4) a 5) d 6) c
7) b 8) a 9) d 10)b 11) d 12) d pond at 15 0 c and 1.5atm pressure, when it
13) c 14) a 15) d 16) a 17) d 18) c comes at the surface, it observes a pressure
19) a 20) c 21) a 22) a 23) c 24) d of 1atm at 25 0 c and has volume V2 , give
25) d 26) c 27) c 28) c 29) b 30) d
31) c 32) d 33) b 34) d 35) c 36) c V2
37) a 38) a 39) d 40) c 41) a 42) b V1 -
43) d 44) b 45) b 46) c a) 15.5 b)0.155 c)155.0 d)1.55

LEVEL - 1 7) The ratio of velocities of diffusion of

GAS LAWS gases A and B is 1:4. if the ratio of their
masses present in the mixture is 2:3.
1) An open flask contains air at 27 0 c . calculate the ratio of their mole fraction
Calculate the temperature at which it should
be heated so that 1/3rd of air measured 1 3 4
a) b) 24 c) d)
escapes out. 24 9 27
a) 277 0 c b) 3000 c c) 177 0 c d) 77 0 c GRAHAM’S LAW
8) 100 cm3 of NH 3 diffuses through a pin
2) 2.5litres of a sample of a gas at 27 0 c and hole in 32.5 second. How much time will
one barpressure is compressed to a volume 60c.c of N 2 take it diffuse under the same
of 500ml keeping the temperature constant, condition
the percentage increase in pressure is a) 50sec b) 10 sec c)25 sec d)30 sec
a)100% b)400% c)500% d)80%
9) Under similar conditions which of the
3)which of the following gases will have following gases diffuse 4 times as quickly as
density of 1.8grm per litre at 760torr pressure oxygen?
and 27 0 c ? a) He b) H 2 c) N 2 d) O2
a) o2 b) co2 c) NH 3 d) so2 MOLECULAR VELOCITIES
10) At same temperature, calculate the ratio
4)10gram C2 H 6 is filled is a bulb of 1litre of average velocity of SO2 to CH 4
a) 2:3 b) 3:4 c) 1;2 d)1;6
capacity which can with stand a maximum
pressure of 10atm. At what temperature will
the pressure of a gas reach the bursting limit? 11) A what temperature is the RMS speed of
a) 76 o c b) 361.4o c c) 92.4 o c d) 120 o c H 2 molecules as same as that of oxygen
molecules at 13270 c ?
5)The molecular weights of two ideal gases a) 173K b) 100K c) 400K d) 523K
A&B are respectively 100 and 200. 1gram of
A occupies V litres of a volume at STP.what 12) The RMS velocity of nitrogen gas is ‘V
is the volume (in litres) occupied by one ‘ at a certain temperature. When the
gram of B at STP? temperature is doubled the molecules
V dissociate into individual atoms. The new
a) b) V c) V 2 d)2V RMS speed of atoms is
2
a) 2V b) 2V c) V d) 4V

19

13) A what temperature the RMS velocity of
nitrogen gas equal to that of propane gas
STP?
a) 173.7 0 c b)173.7K c) 273K d) -40K
KINETIC ENERGY
14)Atwhat temperature is the kinetic energy
of a gas molecule half of its value at 327 0 c ?
a) 13.50 c b) 150 0 c c) 27 0 c d) 1230 c
21) At a constent tempertature what should
be the percentage increase in presure for a
5% decrease in the volume of the gas?
a) 5% b) 10% c) 5.26% d) 4.26%
22) Presure remeaning constant , the volume
of the given sample of a gas at 127 o c will
be doubled at :
a) 254 o c b)527 o c c) 400 o c d) 800 o c

15) If the temperature of one mole of a gas
is increased by 50 0 c , calculate the change
is kinetic energy of the system
a) 62.32J b) 6.235J c) 623.5J d) 6235J
23) At what temperature would the volume
of a given mass of a gas at constant presure
be twice to its volume at 0 o c ?
a) 100 o c b) 273 o c c) 373 o c d) 446 o c

16) At high temperature & low temperature, 24) A gas is heated from 0 o c to 100 o c at 1.0
the vander waals equation is reduced to atm presure.If intial volume of the gas is
a 10L,its final volume would be
a) ( p  )V RT b) PV=RT
T a) 7.32L b) 10.0L c) 13.66L d) 20.0L
V2
a 25) At a constant pressure ,what should be
c)P(V-b)=RT d) ( p  )(V  b) RT
V2 the percentage increase in the temperature
( in kelven ) for a 10% increase in volume?
17)The constant ‘a’ is vander waal equation a) 10% b) 20% c) 5% d) 50%
is maximum in
a) He b) H 2 c) O2 d) NH 3 26) At 27 o c ,a gas was compressed to half is
volume.to what temprature must it be heated
18) At high pressure, vander waals so that it occupies the original volume
equations becomes (P=constant ) ?
a) 54 o c b) 600 o c c) 327K d) 327 o c
a
a) PV=RT b) PV=RT+
V
27) If pressure of a gas contained in aclosed
a vessel is increased by 0.4% when heated by
c)PV=RT- d)PV=RT+Pb
V 1 o c ,its intial temprature must be:
a) 250K b) 250 o c c) 2500K d) 25 o c
19) Vander waals equations explains the
behavior of
28) The destiny of neon will be highest at :
a) ideal gases b) real gases
c) mixture of gases d) diatomic gases a) STP b) 0 o c ,2atm
c) 273 o c ,1atm d) 273 o c 2atm
20) In vander waal equation of a state for a
non-ideal gas the term that accounts for inter 29)How many mole of of He gas occupy
molecular forces is 22.4 litre at 30 o c and one atmospheric
a 1 pressure?
a) ( p  2 ) b) V-b c) RT d)
V RT a)0.90 b) 1.11 c)0.11 d)1.0

20
30) A and Bare two identical vessels. A 38) The rate of diffusion of methane at given
contains 15 g of ethan at 298 k and 1 atm. temprature is twice that of a gas X. The
The vessel B contains 75 G gas X 2 at the molecular weight of X ios:
a) 64 b)32 c)4.0 d)8.0
same temprature and pressure. The vapour
density of X 2 is:
39)The ratio of rates of diffusion of CO2
a) 75 b) 150 c) 37.5 d) 300
and SO2 at the same P and T is:
31) A sample of pure gas has a density of a) 4 : 11 b) 11 : 4 c) 1: 4 d) 1: 6
1.60g L1 at 26.5 o c and 680.2 mm
Hg.which of the following is present in the 40) At what temprature will be rate of effu-
sample sion of N 2 be 1.625 times the rate of effusion
a) CH 4 b) C2 H 6 c) C 02 d) Xe
of SO2 at 500 o c
a) 273K b) 893K c) 110K d) 173K
32) Density of ammonia is 0.77 g/litre at
NTP . its vapourdensity is:
a) 8.65 b) 86.5 c) 4.33 d) 43.3 41)The rates of diffusion of O2 and H 2 at
same P and T are in the ratio
33) 380mL of a gas at 27 o c ,800mm of Hg a) 1:4 b) 1:8 c) 1:16 d)4:1
weight 0.455g.The mol.mass of a gas is:
a) 27 b)28 c)29 d)30 42) Two g of hydrozen diffuses from a
container in 10 minutes . How many gram of
34) Two gasses A and B having the same oxygen would diffuse through the same
temprature T, same pressure P and same container in the same time under similar
volume V are mixed . If the mixture is at the conditions
same temprature T and occupies a volume V, a) 5g b) 4g c) 6g d)8g
the pressure of the mixture is:
a) 2P b) P c)P/2 d) 4P 43) At what temprature will be total kinetic
energy (K.E.) of 0.30 mole of he be the
same as the total K.E of 0.40 mole of Ar at
35)Air contains 79% N 2 and 21% O2 by
400K
volume . if the barometric pressure is a) 400K b) 373K c) 533K d)300K
750mm Hg the partial pressure of oxygen is:
a) 157.7mm of Hg b) 175.5mm of Hg 44) Total energy of one mole of an ideal gas
c) 315.0mm of Hg d) None of these (monoatomic) at 27 o c is:
a) 600 cal b) 900cal c) 800cal d) 300 cal
36) A gaseous mixture contains 1g of H 2 ,4g
of He, 7 g of N 2 and 8 g of O2 . The gas 45) Gas at a pressure Po is contained in a
having the higest partial pressure is : vessel. If the masses of all the molecules are
a) H 2 b) O2 c) He d) N 2 halved and theirspeed doubled,the resulting
pressure P will be equal to:
37) The vapour densities of CH 4 and O2 are
a) 4 Po b) 2 Po c) Po d) Po / 2
in the ration 1:2, The ratio of rates of
diffusioins of O2 and CH 4 at same P and T 46) The gasses are at absolute temperature
is: 300 K and 350 K respectively. The ratio of
a) 1:2 b)2:1 c) 1:1.424 d)1.414:1 averge kinetic energy of their molecules is :
21
a) 7:6 b) 6:7 c) 36:49 d) 49:36 ecule at 27 o c is 0.3 m sec 1 .The average
speed at 927 o c will be .... m sec 1
47)The ratio of the average molecular kinetic
a) 0.6 b) 0.3 c) 0.9 d) 3.0
energy of UF6 to thet of H 2 both at 300K is
: 55) The average molecular speed is greatest
a) 1:1 b) 7:2 c) 176:1 d) 2:7 in case of a gas sample of :
a) 2.0 mole of He at 140K
48)At what temprature will hydrozen b) 0.05 mole of Ne at 500K
moleculaes have the same kinetic energy as c) 0.40 mole of O2 at 400K
nitrogen molecules have at 35o C
d) 1.0 mole of N 2 at 560K
28 X 35 o 2 X 35 o
a) c b) c
2 28 56) Four particulars have speed 2,3,4 and
2 X 28 o 5cm/s respectively. their rms speed is:
c) c d) 35o c a) 3.5 cm/s b) (27/2)cm/s
35
c) 54 cm/s d) 54 / 2 cm/s
49) The ratio of average speed an oxygen
molecule to the rms speed of a nitrogen
molecule at the same temprature is: 57)The absolut temprature of agas is in-
creased 3 times.The root mean squared speed
3S 7 3 7S of the molecules will be:
a) b) c) d)
7 3S 7S 3 a) 3times b) 9 times c) 1/3 times d) 3 times

50)Which of the following gases would
have the higest rms speed at o c
a) o3 b) co2 c) so3 d) co
51) At 27 o c the ratio of root mean square
speeds of zone to oxygen is :
a) (3/ 5) b) (4 / 3) c) (2 / 3) d) 0.25
52) The temprature of an ideal gas is in-
creased from 140 K to 560K .if at 140K the
root mean square velocity of the gas mol-
ecules u , at 560K it becomes:
a) 5u b) 2u c) u/2 d) u/4
53) Among the following gases which one
has the lowest root mean square speed at
25 o c
a) so2 b) N 2 c) O2 d) Cl2
54) The average speed of an ideal gas mol-
58)A sample of gas is at 0o c .The temprature
at which its rms speed of the molecules will
be doubled is:
a) 103 o c b) 273 o c c) 723 o c d) 819 o c
59)The root mean squared speed of hydrozen
molecules at room temprature is
2400 ms 1 .At room temprature,the root mean
square speed of oxygen molecules would be:
a) 400 ms 1 b) 300 ms 1 c) 600 ms 1 d)
1600 ms 1
60)The temprature at which H 2 has same
rms speed (at 1 atm) as that of O2 at NTP is:
a) 37 K b) 17 K c)512 K d) 27 K
61) The root mean square speed of the
molecules diometic gas is u.when the
temprature is doubled ,the molecules dissoci-
ates into two atoms. the new rms speed of
the atom is:
a) 2u b) u c) 2u d) 4u

22
 originally Present which goes out of it is
62) The rms speed of Hydrozen is 7 times
a) 3/4 b)1/4 c)2/3 d)1/8
the rms speed nitrozen. If Tis the temprature
of the gas, then 70)Which of the following will give a linear
a) TH 2 TN b) TH 2 ! TN2 plot at constant pressure
2

a) V vs T b) V vs 1/ T c) T vs 1/ V d) None of
c) TH 2  TN2 d) TH 2  TN2 these

63)As the temprature is raised from 20 o c to 71)For n moles of ideal gas ,the equation of
state may be written as
40 o c ,the average kinetic energy of neon
atoms changes by afactor: a) PT / n RV b) PV ( RT ) 2
c) P / T nR / V d) PV RT / n
313 313 1
a)2 b) c) d)
293 293 2 72)The molar mass of an ideal gas can be
calculated from the expression
64)The ratio of the rate diffusion of helium
dRT RT
and methane under identical conditions of a) M b) M
pressure and temprature is: PV Pd

a) 10 seconds : He b) 20 seconds : O2 Pd dRT

c) M d) M
RT P
c) 25 seconds : Co d) 55 seconds : CO2
73)8.2L of an ideal gas weights 9.0 gram at
66)Density of air at NTP is 0.001293 g/ml.lts 300 k and 1 atm pressure. molecular mass of
vapour density is: the gas is
a) 0.001293 b)1.293 c)14.18 d)cannot be a) 9 b) 27 c) 54 d) 81
calculated
74) A 2.24 L cylinder of oxygen at N.T.P is
67) 10g of hydrofluric acid gas occupies 5.6 found to develop a leakage.when the leakege
litre of volume at STP.If the empirical for- was plugged the pressure dropped to 570
mula of the gas is HF, then its molecular mm of Hg. The number of moles of gas that
formula in the gaseous state will be: escaped will be
a)HF b) H 2 F2 c) H 3 F3 d) H 4 F4 a) 0.025 b) 0.050 c)0.075 d)0.09

75)Which of the following does not repre-

68) If Vo is the volume of a given mass of sents ideal gas equation
gas at 273 K at a constant pressure then a) PV 1/ 2mNu 2 b) PV=nRT
according then to Charle’s law,at the volume
c) P= U RT / M d) PV=RT
at 10 o c will be
1 76) A 0.5 dm3 flask contains gas A and
a) 11 Vo b) (Vo  10)
273
1 dm3 flask contains gas B at the same
10 283 temprature .if density of A=3.0g dm 3 and
c) Vo  d) V0
273 273
that of B = 1.5g dm 3 and molar mass A= 1/
69)An open vesel containing air is heated 2 of B,then ratio of pressure exerted by the
gas is
from 27 o c to 127 o c .The fraction of air
a) PA / PB 2 b) PA / PB 1
23
c) PA / PB 4 d) PA / PB 3 LEVEL - 2
1)at a constant temperature a gas occupies a
volume of 200 ml at a pressure 0.72 bar. It is
77)Equal masses of SO2 , CH 4 and O2 are subjected to an external pressure of 0.9 bar.
mixed in emty container at 298 K ,when total What is the resultant volume of the gas ?
pressure is 2.1 atm. The partial pressure of a) 160 ml. b) 320ml
CH 4 in the mixture is c) 180ml d) 16 ml.
2) what is the increase in volume when the
a) 0.5atm b) 0.75atm
temperature of 600ml of an increases from
c) 1.2 atm d) 0.6atm
27 0 C to 47 0 C under constant pressure?
78)The increasing order of effusion among a) 80 ml. b) 40 ml
c) 20 ml d) 100ml
the gases H 2,O2, NH 3 and CO2 is
a) H 2 , Co2 , NH 3 , O2 b) H 2 , NH 3 , O2 , Co2 3) Calculate number of nitrogen molecules
present in 2.8 gr. Of nitrogen
c) H 2 , O2 , NH 3 , Co2 d) Co2 , O2 , NH 3 , H 2
a) 6.022 u10 20 b) 6.022 u10 21
c) 3.01 u10 23 d) 6.022 u1023
79)Two flasks A and B of 1 L capacity each
contains SO2 and Br2 gases respectively 4) Is the density of a gas at the sea level at
maintained at 340 k and pressure of 1.5 3
00 C is 1.29 kg.m . What is its molar mass ?
atmosphere,If number of Br2 molecules in (Assume that pressure is equal to 1bar)
flask B is N,the total number of atoms in a) 2.6 gr / mole b) 29.3 gr / mole
flask A wile be
a) N b) 2N c) N/2 d) 3N c) 60 gr / mole d) 80 gr / mole

80)Four one litre flasks are separately filled 5) A 2.5 L glass contains 0.25 mole each of
with the gases O2 , F2 , H 2 and CO2 under the SO2 & N 2 gas at 27 0 C . Calculate the total
same conditions of temparature and pressure pressure of the gaseous mixture ?
the number moles in these gases a) 4.98 u105 Pa b) 4.98 u104 Pa
a) 2:2:4:3 b) 1:1:1:1 c) 5.6 u 104 Pa d) 7.5 u 105 Pa
c) 1:2:3:4 d) 2:2:3:4
KEY
1) c 2) b 3) b 4) c 5) a 6) d 6) Which of the two gases NH 3 and HCl
7) a 8)c 9) b 10)c 11)b 12) b will diffuse faster and by what factor.
13)b 14) c 15) c 16) b 17) d 18) d a) 2.46 b) 7.42
19) b 20) a 21) c 22) b 23) b 24) c c) 1.46 d) 3.2
25) a 26) d 27) a 28) b 29) a 30) a
31) c 32) a 33) b 34) a 35) a 36) c 7) what will be the minimum pressure
37) c 38) a 39) a 40) b 41) a 42) d required to compress 500 dm3 of air at 1bar
43) c 44) b 45) b 46) b 47) a 48) d
to 200dm3 at 30 0 C .
49) b 50) d 51) c 52) b 53) d 54) a
a) 2.5 bar b) 1 bar
55) a 56) d 57) d 58) d 59) c 60) b
c) 2.0 bar d) 3 bar
61) c 62) c 63)c 64) b 65) b 66) c
67) b 68) d 69) b 70) a 71) c 72) d
8) A vessel of 120ml capacity contains a
73) b 74) a 75) a 76) c 77) c 78) d
certain amount of is
gastransferred
at 350 C and
to1.2
79)d 80) d bar
pressure. The gas another
vessel of volume 180ml at 350 C , what
24
would be its pressure ? 15) 34.05 ml phosphorous vapour weights
a) 1 bar b) 0.9 bar 0.0625 gr. at and 1bar pressure. What is the
c) 0.8 bar d) 0.6 bar molar mass of phosphorous ?
9) at 0 C the density of gaseous oxide at 2
0 a) 125 gr/mole b) 250 gr/mole
bar is same as that of nitrogen at 5 bar, what c) 12.5 gr/mole d) 64 gr/mole
is the molecular mass of the oxide.
a) 80 b) 70 16) A student forgot to add the reaction
c)90 d)100 mixture to the round bottomed flask at 27 0 C
but put it on the flame. After a lapse of time,
10) Pressure of 1 gr.of an ideal gas A at he realized his mistake using a pyrometer he
27 0 C is found to the 2 bar , when 2 gr.s of found the temperature of the flask was
another ideal gas B is introduced in the same 4770C. What fraction of air would have been
flask at same temperature, the pressure expelled out?
becomes 3bar. Find relation between their a) 3/5 b) 5/3
molecular masses. c) 1/5 d) 5/2
a) MA=4MB b) MB=4MA
c) MA=MB d)MB=3MA 17) Caluculate the temperature of 4 moles of
a gas occupying 5 d.m3 at 3.32 bar (R=0.083
11) the drain cleaner, drainex contains small bar.d.m3/mole.kelvin)?
bits of alluminium which reacts with caustic a) 100K b) 50K
soda to produce Hydrgen gas. What volume c) 10K d) 75 K
of hydrogen at 200 C and 1 bar will be
18) Calculate the number of electrons
released when 0.15 gr.s of alluminium reacts present in 1.4 gr. of Nitrogen gas ?
?
a) 4.2 u 1023 b) 0.42 u1023
a) 187 ml b) 187 L.
c) 18.7 ml d) 1.87 L. c) 8.4 u 10 23 d) 4.2 u 1022

12) What will be the pressure exerted by a 19) How much time would it take to
mixture of 3.2 gr. of methane and 4.4 gr. of distribute one Avogadros number of wheat
carbon dioxide contained in 9 dm3 flask. at grains. If 1010 grains are distributed each
27 0 C .? second ?
a) 0.821 atm b) 8.21 atm a) 6 u 1010 sec b) 3 u 1011 sec
c) 4.105 atm d) 0.4105 atm c) 6 u 1011 sec d) 2 u1011 sec

13) What will be the pressure of gas mixture 20) Calculate the volume occupied the 8.8
when 0.5 Lt. of Hydrogen at 0.8 bar and 2 lt.
gr. of CO2 at 31.10 C and 1 bar pressure,
of Oxygen at 0.7 bar are introduced in a 1 lit.
(R=0.083 bar.d.m3/mole.kelvin)?
vessel at 27 0 C ?
a) 10 L. b) 4.8 L
a) 18 bar b) 1.8 bar c) 5.05 L d) 2.02 L
c) 3.6 bar d)0.36 bar
21 ) 2.9 gr, of a gas at 950C occupied the
14) The density of a gas is found to be 5.46 same volume as 0.184 gr. of hydrogen at
gr / d .m3 at at 2 bar pressure. What will be 170C, at the same pressure . what is the
its density at STP ? Molar mass of the gas?
a) 3 b) 1.5 c) 0.3 d) 0.6 a) 20 b) 30
c) 80 d) 40
25
22) Through two ends of a glass tube of
lengths 200cm, hydrogen chloride and
ammonia gas are allowed to enter. At what 29) Strong inter molecular forces exists in
distance ammonium chloride will first a) gases b) Liquids
appear ? c) amorphous solids d) crystalline solids
a) 81 cm from NH 3 end
30) Which of the following statements is
b) 81 cm from HCl end
wrong ?
c) 119 cm from NH 3 end a) Evaporation is a spontaneous process
d) 119cm from HCl end b) Evaporation is a surface phenomenon
c) Vapour pressure decreases with increase
23) Equal volumes of two gases A nad B of temperature
diffuse through a porous pot in 20 and 10sec d) The vapour pressure of solution is always
respectively. If the molar mass of A be 80. less that of pure solvent
Find Molar mass of B?
a) 40 b) 20 31) Normal boiling point of a liquid is that
c) 80 d) 100 temperature at which vapour pressure of the
liquid is equal to
24) Calculate the total average kinetic energy a) zero b) 380 mm of Hg
of 32 gr. of methane molecules at 27 0 C in c) 760 mm of Hg d) 100 mm of Hg
joule ?
a) 7382.6 b) 738.26 32) When a student was given a viscometer,
c) 73.826 d) 7.3826 the liquid was sucked with difficulty, the
liquid may be
25) A mixture of hydrogen and oxygen at 1 a) Benzene b) Toluene
bar pressure contains 20% by weight of c) Water d) Glycerine
hydrogen. Calculate the partial pressure of
hydrogen? 33) which the increasing molecular moss of a
a) 0.8 bar b) 1.6 bar liquid the viscocity
c) 0.4 bar d) 3.4 bar a) Decreases b) Increses
c) No effect d) All are wrong
26) The temperature at which real gases obey
the ideal gas laws over a wide range of 34) The viscosity of which liquid is the
pressure is called maximum ?
a) critical temp. b) Boyle’s temp. a) Water b) Glycol
c) Invertion temp. d) Reduced temp. c) Acetone d) Ethanol

27) 1gr. molecule of an ideal gas 35) The rise of a liquid in a capillary tube is
due to
PV 3 PV a) Viscosity b) Osmosis
a) cal b) 2cal
T 2 T c) Diffusion d) Surface tension
PV PV
c) 8.31cal d) 0.0821cal 36) With the increasing temperature the
T T
fluidity of a liquids
a) Increases b) Decreases
28) The non compressible volume of a gas is
c) May increases or decrease
_____ times the actual volume of gas
d) remains constant
molecules
a) 2 b) 4
c) 3 d) 2.5
26
 45) Pressure of Mixture of 4 gr. of O2 and 2
37) Which one is amorphous solid ?
a) Diamond b) Graphite gr. of H 2 confined in a bulb of one litre at
c) Common salt d) Glass 00 c is
a) 25.215 atm b) 31.205 atm
38) Which one of the following is a non c) 45.215 atm d) 15.210 atm
conductor in solid state but becomes a good
conductor on melting ? 46) The density ratio of O2 and H 2 is 16 : 1
a) Sodium b) Ice
the ratio of their RMS velocities will be
c) Potasium chloride d) Diamond
a) 4 : 1 b) 1 : 16
c) 1 : 4 d) 16 : 1
39) Which of the following solids shows
electrical conduction ?
47) the rate of diffusion of a gas having
a) Graphite b) Potasium chloride
c) Diamond d) Sodium chloride molecular weight just double of Nitrigen gas
is 56 mLs 1 . The rate of diffusion of nitrogen
40) Gas having Minimum value of ‘b’. will be
a) O2 b) He a) 79.19 mLs 1 b) 112 mLs 1
c) H2 d) all are same c) 56 mLs 1 d) 90 mLs 1

41) The RMS velocity of an ideal gas at a 48) If 300 ml of a gas at 270C is cooled to
constant pressure varies with density as 70C, at constant pressure, its final volume
a) d 2 b) d will be
a) 135 ml b) 540 ml
1
c) d d) c) 350 ml d) 280 ml
d
49) For an ideal gas the number of moles/lt
42) which of the following expression interms of its pressure P, gas constant R, and
correctly represents the relation ship between temperature T is
1) KECO KEN2 2) KECO ! KEN2 a) PT/R b) PTR
c) P/RT d) RT/P
3) KECO  KE N2 4) can not be predicted
50) The vandar wall equation reduces itself
to the ideal gas equation at
43) The compressibility of a gas is less than
a) High pressure and low temperature
unity at STP then
b) low pressure and low temperature
a) Vm ! 22.4 litre c) Vm  22.4 litre c) low pressure and high temperature
c) Vm 22.4 d) Vm 44.8 d)high pressure allown

51) The major binding force of diamond,

44) The gas equation PV=nRT is obied by
silicon and quartz is
a) only Isothermal process
a) electro static force b) electrical attraction
b) Only adiabatic process
c) covalent bond forced) non covalent bond
c) Both A nad B
force
d) None of these
52) In the equation of state of an ideal gas
PV=nRT
a) thethe
nature of value
gas of Rb)would depend
pressure of theonly
gas
on the
27
c) units of measurementd) none of the above KEY
1) a 2) b 3) d 4) b 5) a 6) c
53)A certain sample of a gas has a volume of 7) a 8) c 9) b 10) b 11) a 12) a
0.2 Lt measured at 1atm pressure and 00C at 13) b 14) a 15) a 16) a 17) b 18) a
the same pressure but 2730c its volume will 19) c 20) c 21) d 22) b 23) b 24) a
be 25) a 26) b 27) b 28) b 29) d 30) c
a) 0.4 lt b) 0.8 lt 31) c 32) d 33) b 34) b 35) d 36) a
c) 27.8 lt d) 55.6 lt 37) d 38) c 39) a 40) b 41) d 42) a
43) b 44) c 45) a 46) c 47) a 48) d
54) A gas can be liquefied 49) c 50) c 51) c 52) c 53) a 54) c
a) above its critical temperature 55) c 56) b 57) c 58) b
b) At its critical temperature HINTS
c) below its critical temperature 1) PV PV
1 1 2 2
d) at any temperature
V1 V2
2) T T2
55) The surface tension of which of the 1
following liquids is maximum
3)28 gr. of nitrogen contains 6.023 u10 23
a) C2 H 5OH b) CH 3OH molecules
c) H 2O d) C6 H 6 dRT
4) M
P
56) Dominance of strong repulsive forces
among the molecules of the gas 5) PSO2 Ptot . X SO2 , PN2 Ptot . X N 2
a) depends on Z andindicated by Z=1
b) depends on Z and Z>1 Ptot PSO2  PN 2
c) depends on Z and Z<1
d) is independent of Z r1 M2
6)
r2 M1
57) Equal masses of methane and oxygen are
7) PV PV
mixed in an empty containor at 250C. The 1 1 2 2

fraction of the total pressure exerted by 8) PV

1 1 PV
2 2
oxygen is .. 9) PM P2 M 2
1 1
a) ½ b) 2/3
10) p Ptot .mole fraction
1 273
c) 1/3 d) u 11)11.2 lt. of Hydrogen is released from 9gm
3 298
of Al
58) The term that corrects for the attractive (n1  n2 )
12) p .RT
forces present in a real gas in the vandarwall V
equations is PV
1 1  PV
2 2
2
an 13) total pressure = final volume
a) n.b b)
V2
P1 P2
an2 14) d T d 2T2
c)  d) – n.v. 1 1
V2
w
15) PV .RT
M
16) n1T1 n2T2

28
17) PV = nRT
18) 28 gr. of N2 contains 14 x 6.023x1023
electrons
19) conceptual r1 M2
47)
r2 M1
w
20) PV .RT
M V1 V2
48) T T2
w1T1 w2T2 1
21) M M2 49) PV=nRT
1
50) conceptual
rNH3 rNH3 51) conceptual
22) 52) conceptual
rHCl rHCl
V1 V2
53) T T2
1
dis tan ce travelled by NH 3 M HCl
dis tan ce travelled by HCl M NH 3 54) conceptual
55) molecular interactions more due to
Hydrogen bond
t1 M1
23) 56) conceptual
t2 M2 57) p=P.mole fraction
58) conceptual
3
24) K .E. nRT ASSERTION and REASONING
2 1) Assertion : One mole of helium atoms
25) PH 2 Ptot . X H 2 should occupy 22.4 litres volume at STP
26)conceptual Reason : Taking 31 Pm as radius of helium
27) PV=nRT ,n= 1, R=2 atoms,if we pack together a mole of helium
28) conceptual atoms, the mole of atoms should have a
29) conceptual volume of 22.4 litre.
30) conceptual a) Both A and R are true and R is the correct
31) conceptual explanation of A
32) conceptual b) Both A and R are true but R is not a
33) conceptual correct explanation of A
34) conceptual c) A is true but R is false
35) conceptual d) A is false but R is true
36) conceptual
37) conceptual 2) Assertion : The pressure of a gas is
38) conceptual inversely proportional to the volume at
39) conceptual constant temperature and n.
40) conceptual Reason : The gas volume is directly
proportional to n at constant temperature and
3P pressure.
41) RMS
d a) Both A and R are true and R is the correct
42) K.E depends on temperature explanation of A
43) conceptual b) Both A and R are true but R is not a
44) conceptual correct explanation of A
45) PV=nRT c) A is true but R is false
d) A is false but R is true
C1 d2
46)
C2 d1
3) Assertion : The value of vander waals’
constant a,is large for ammonia than for 29
nitrogen.
Reason : Hydrogen bonding is present in
ammonia
a) Both A and R are true and R is the correct
explanation of A
b) Both A and R are true but R is not a
correct explanation of A
c) A is true but R is false
d) A is false but R is true

4) Assertion : At zero kelvin the volume

occupied by a gas is negligible.
Reason : All translational molecular motion
cease at OK.
a) Both A and R are true and R is the correct
explanation of A
b) Both A and R are true but R is not a
correct explanation of A
c) A is true but R is false
d) A is false but R is true

5) Assertion : The pressure of real gases is

less than the pressure of the ideal gas.
Reason : The intermolecular forces of
attraction in real gases are greater than those
of ideal gas.
a) Both A and R are true and R is the correct
explanation of A
b) Both A and R are true but R is not a
correct explanation of A
c) A is true but R is false
d) A is false but R is true

6)Assertion : For a certain fixed amount of

gas the product PV is always constant
Reason : Real gases deviate from ideal
behaviour of low pressure and high
temperature.
a) Both A and R are true and R is the correct
explanation of A
b) Both A and R are true but R is not a
correct explanation of A
c) A is true but R is false
d) A is false but R is true
KEY
1) c 2) b 3) a 4) d 5) a 6) d

30