Para pH vs pCa a pKa constante

Triada 1 (ecuación lineal)

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+00
0.01 2 3.16E-02
0.001 3 3.16E-04
0.0001 4 3.16E-03 2.5 1.00E-14 14 3.16E-06
0.00001 5 3.16E-08
0.000001 6 3.16E-10
0.0000001 7 3.16E-12

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+02
0.01 2 3.16E+00
0.001 3 3.16E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 3.16E-04
0.00001 5 3.16E-06
0.000001 6 3.16E-08
0.0000001 7 3.16E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04
0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.16E-02
0.00001 5 3.16E-04
0.000001 6 3.16E-06
0.0000001 7 3.16E-08

Triada 2 (ecuación cuadrática)

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.26E+00
0.01 2 4.16E-02
0.001 3 1.31E-03
0.0001 4 3.16E-03 2.5 1.00E-14 14 1.03E-04
0.00001 5 1.00E-05
0.000001 6 1.00E-06
0.0000001 7 1.00E-07
 [H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca
0.1 1 3.16E+02
0.01 2 3.17E+00
0.001 3 3.26E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 4.16E-04
0.00001 5 1.31E-05
0.000001 6 1.03E-06
0.0000001 7 1.00E-07

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04
0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.17E-02
0.00001 5 3.26E-04
0.000001 6 4.16E-06
0.0000001 7 1.31E-07

Triada 3 (ecuación cúbica)

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.26E+00
0.01 2 4.16E-02
0.001 3 1.31E-03
0.0001 4 3.16E-03 2.5 1.00E-14 14 1.03E-04
0.00001 5 1.00E-05
0.000001 6 9.90E-07
0.0000001 7 4.61E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+02
0.01 2 3.17E+00
0.001 3 3.26E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 4.16E-04
0.00001 5 1.31E-05
0.000001 6 1.02E-06
0.0000001 7 4.62E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04

3.16E-07 6.5 1.00E-14 14

 0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.17E-02
0.00001 5 3.26E-04
0.000001 6 4.12E-06
0.0000001 7 6.06E-10

Para pa1 vs pCa a pKa constante

Triada 1 (ecuación lineal)

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+00
0.01 2 3.16E-02
0.001 3 3.16E-04
0.0001 4 3.16E-03 2.5 1.00E-14 14 3.16E-06
0.00001 5 3.16E-08
0.000001 6 3.16E-10
0.0000001 7 3.16E-12

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+02
0.01 2 3.16E+00
0.001 3 3.16E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 3.16E-04
0.00001 5 3.16E-06
0.000001 6 3.16E-08
0.0000001 7 3.16E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04
0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.16E-02
0.00001 5 3.16E-04
0.000001 6 3.16E-06
0.0000001 7 3.16E-08

Triada 2 (ecuación cuadrática)

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

 0.1 1 3.26E+00
0.01 2 4.16E-02
0.001 3 1.31E-03
0.0001 4 3.16E-03 2.5 1.00E-14 14 1.03E-04
0.00001 5 1.00E-05
0.000001 6 1.00E-06
0.0000001 7 1.00E-07

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+02
0.01 2 3.17E+00
0.001 3 3.26E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 4.16E-04
0.00001 5 1.31E-05
0.000001 6 1.03E-06
0.0000001 7 1.00E-07

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04
0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.17E-02
0.00001 5 3.26E-04
0.000001 6 4.16E-06
0.0000001 7 1.31E-07

Triada 3 (ecuación cúbica)

[H+] pH Ka pKa Kw^1/2 (25°C) pKw^1/2 (25°C) Ca

0.1 1 3.26E+00
0.01 2 4.16E-02
0.001 3 1.31E-03
0.0001 4 3.16E-03 2.5 1.00E-07 7 1.03E-04
0.00001 5 1.00E-05
0.000001 6 9.90E-07
0.0000001 7 4.61E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+02
0.01 2 3.17E+00
0.001 3 3.26E-02
0.0001 4 3.16E-05 4.5 1.00E-14 14 4.16E-04
 3.16E-05 4.5 1.00E-14 14
0.00001 5 1.31E-05
0.000001 6 1.02E-06
0.0000001 7 4.62E-10

[H+] pH Ka pKa Kw (25°C) pKw (25°C) Ca

0.1 1 3.16E+04
0.01 2 3.16E+02
0.001 3 3.16E+00
0.0001 4 3.16E-07 6.5 1.00E-14 14 3.17E-02
0.00001 5 3.26E-04
0.000001 6 4.12E-06
0.0000001 7 6.06E-10

Para pa1 vs pH a pKa constante

Triada 1 (ecuación lineal) Triada 2 (ecuación cuadrática)

pKa = 2.5 pKa = 2.5
[H+] pH a1 pa1 [H+] pH
0.1 1 3.16E-02 1.50031292 0.1 1
0.01 2 3.16E-01 0.50031292 0.01 2
0.001 3 3.16E+00 -0.4996871 0.001 3
0.0001 4 3.16E+01 -1.4996871 0.0001 4
0.00001 5 3.16E+02 -2.4996871 0.00001 5
0.000001 6 3.16E+03 -3.4996871 0.000001 6
0.0000001 7 3.16E+04 -4.4996871 0.0000001 7
pKa = 4.5 pKa = 4.5
[H+] pH a1 pa1 [H+] pH
0.1 1 3.16E-04 3.50031292 0.1 1
0.01 2 3.16E-03 2.50031292 0.01 2
0.001 3 3.16E-02 1.50031292 0.001 3
0.0001 4 3.16E-01 0.50031292 0.0001 4
0.00001 5 3.16E+00 -0.4996871 0.00001 5
0.000001 6 3.16E+01 -1.4996871 0.000001 6
0.0000001 7 3.16E+02 -2.4996871 0.0000001 7
pKa = 6.5 pKa = 6.5
[H+] pH a1 pa1 [H+] pH
0.1 1 3.16E-06 5.50031292 0.1 1
0.01 2 3.16E-05 4.50031292 0.01 2
0.001 3 3.16E-04 3.50031292 0.001 3
0.0001 4 3.16E-03 2.50031292 0.0001 4
0.00001 5 3.16E-02 1.50031292 0.00001 5
0.000001 6 3.16E-01 0.50031292 0.000001 6
0.0000001 7 3.16E+00 -0.4996871 0.0000001 7
 pCa
-0.499687083
1.500312917
3.500312917
5.500312917
7.500312917
9.500312917
11.50031292

pCa
-2.499687083
-0.499687083
1.500312917
3.500312917
5.500312917
7.500312917
9.500312917

pCa
-4.499687083
-2.499687083
-0.499687083
1.500312917
3.500312917
5.500312917
7.500312917

pCa
-0.5132176
1.380906669
2.882728704
3.987162775
5
6
7
 pCa
-2.499687083
-0.501059262
1.4867824
3.380906669
4.882728704
5.987162775
7

pCa
-4.499687083
-2.499687083
-0.499687083
1.498940738
3.4867824
5.380906669
6.882728704

pCa
-0.5132176
1.380906669
2.882728704
3.987162775
5
6.004364805
9.336299075

pCa
-2.499687083
-0.501059262
1.4867824
3.380906669
4.882728704
5.991399828
9.335358024

pCa
-4.499687083
-2.499687083
-0.499687083
1.498940738
3.4867824
5.385102784
9.217527376

pCa a1 pa1
-0.499687083 3.16E-02 1.50031292
1.500312917 3.16E-01 0.50031292
3.500312917 3.16E+00 -0.4996871
5.500312917 3.16E+01 -1.4996871
7.500312917 3.16E+02 -2.4996871
9.500312917 3.16E+03 -3.4996871
11.50031292 3.16E+04 -4.4996871

pCa a1 pa1
-2.499687083 3.16E-04 3.50031292
-0.499687083 3.16E-03 2.50031292
1.500312917 3.16E-02 1.50031292
3.500312917 3.16E-01 0.50031292
5.500312917 3.16E+00 -0.4996871
7.500312917 3.16E+01 -1.4996871
9.500312917 3.16E+02 -2.4996871

pCa a1 pa1
-4.499687083 3.16E-06 5.50031292
-2.499687083 3.16E-05 4.50031292
-0.499687083 3.16E-04 3.50031292
1.500312917 3.16E-03 2.50031292
3.500312917 3.16E-02 1.50031292
5.500312917 3.16E-01 0.50031292
7.500312917 3.16E+00 -0.4996871

pCa a1 pa1
 -0.5132176 3.00E-02 1.52287875
1.380906669 2.40E-01 0.61978876
2.882728704 7.60E-01 0.11918641
3.987162775 9.60E-01 0.01772877
5 9.90E-01 0.00436481
6 9.90E-01 0.00436481
7 9.90E-01 0.00436481

pCa a1 pa1
-2.499687083 3.16E-04 3.50031292
-0.501059262 3.15E-03 2.50168945
1.4867824 3.00E-02 1.52287875
3.380906669 2.40E-01 0.61978876
4.882728704 7.60E-01 0.11918641
5.987162775 9.60E-01 0.01772877
7 9.90E-01 0.00436481

pCa a1 pa1
-4.499687083 3.16E-06 5.50031292
-2.499687083 3.16E-05 4.50031292
-0.499687083 3.16E-04 3.50031292
1.498940738 3.15E-03 2.50168945
3.4867824 3.06E-02 1.51427857
5.380906669 2.40E-01 0.61978876
6.882728704 7.60E-01 0.11918641

pCa a1 pa1
-0.5132176 3.00E-02 1.52287875
1.380906669 2.40E-01 0.61978876
2.882728704 7.60E-01 0.11918641
3.987162775 9.60E-01 0.01772877
5 9.90E-01 0.00436481
6.004364805 9.90E-01 0.00436481
9.336299075 9.90E-01 0.00436481

pCa a1 pa1
-2.499687083 3.10E-04 3.50863831
-0.501059262 3.10E-03 2.50863831
1.4867824 3.00E-02 1.52287875
3.380906669 2.40E-01 0.61978876
 4.882728704 7.50E-01 0.12493874
5.991399828 9.60E-01 0.01772877
9.335358024 9.80E-01 0.00877392

pCa a1 pa1
-4.499687083 3.16E-06 5.50031292
-2.499687083 3.16E-05 4.50031292
-0.499687083 3.16E-04 3.50031292
1.498940738 3.16E-03 2.50031292
3.4867824 3.05E-02 1.51570016
5.385102784 2.31E-01 0.63638802
9.217527376 7.58E-01 0.12033079

uación cuadrática) Triada 3 (ecuación cúbica)

pKa = 2.5
a1 pa1 [H+] pH a1 pa1
3.00E-02 1.52287875 0.1 1 3.00E-02 1.52287875
2.40E-01 0.61978876 0.01 2 2.40E-01 0.61978876
7.60E-01 0.11918641 0.001 3 7.60E-01 0.11918641
9.60E-01 0.01772877 0.0001 4 9.60E-01 0.01772877
9.90E-01 0.00436481 0.00001 5 9.90E-01 0.00436481
9.90E-01 0.00436481 0.000001 6 9.90E-01 0.00436481
9.90E-01 0.00436481 0.0000001 7 9.90E-01 0.00436481
pKa = 4.5
a1 pa1 [H+] pH a1 pa1
3.16E-04 3.50031292 0.1 1 3.10E-04 3.50863831
3.15E-03 2.50168945 0.01 2 3.10E-03 2.50863831
3.00E-02 1.52287875 0.001 3 3.00E-02 1.52287875
2.40E-01 0.61978876 0.0001 4 2.40E-01 0.61978876
7.60E-01 0.11918641 0.00001 5 7.50E-01 0.12493874
9.60E-01 0.01772877 0.000001 6 9.60E-01 0.01772877
9.90E-01 0.00436481 0.0000001 7 9.80E-01 0.00877392
pKa = 6.5
a1 pa1 [H+] pH a1 pa1
3.16E-06 5.50031292 0.1 1 3.16E-06 5.50031292
3.16E-05 4.50031292 0.01 2 3.16E-05 4.50031292
3.16E-04 3.50031292 0.001 3 3.16E-04 3.50031292
3.15E-03 2.50168945 0.0001 4 3.16E-03 2.50031292
3.06E-01 0.51427857 0.00001 5 3.05E-02 1.51570016
2.40E-01 0.61978876 0.000001 6 2.31E-01 0.63638802
7.60E-01 0.11918641 0.0000001 7 7.58E-01 0.12033079
 Ecuación 6: pH vs pCa

Triada 1 (ecuación lineal)

pKa = 2.5
Li near (pK
pH pCa (pKa=2.5) pCa (pKa=4.5) pCa (pKa=6.5)
1 -0.4996870826 -2.4996870826 -4.4996870826
2 1.5003129174 -0.4996870826 -2.4996870826 f(x) = 0.5x f(x
+3
R² = 1 R²
3 3.5003129174 1.5003129174 -0.4996870826
4 5.5003129174 3.5003129174 1.5003129174

pH
5 7.5003129174 5.5003129174 3.5003129174
6 9.5003129174 7.5003129174 5.5003129174
7 11.5003129174 9.5003129174 7.5003129174

-6 -4 -2

Ecuación 5: pH vs pCa

Triada 2 (ecuación cuadrática)

pH pCa (pKa=2.5) pCa (pKa=4.5) pCa (pKa=6.5)

1 -0.5132176001 -2.4996870826 -4.4996870826
2 1.3809066694 -0.5010592622 -2.4996870826
3 2.8827287043 1.4867823999 -0.4996870826
4 3.9871627753 3.3809066694 1.4989407378
5 5 4.8827287043 3.4867823999
6 6 5.9871627753 5.3809066694
7 7 7 6.8827287043

Ecuación 4: pH vs pCa

Triada 3 (ecuación cúbica)

pH pCa (pKa = 2.5) pCa (pKa=4.5) pCa (pKa=6.5)

1 -0.5132176001 -2.4996870826 -4.4996870826
2 1.3809066694 -0.5010592622 -2.4996870826
3 2.8827287043 1.4867823999 -0.4996870826
4 3.9871627753 3.3809066694 1.4989407378
 5 5 4.8827287043 3.4867823999
6 6.0043648054 5.9913998282 5.385102784
7 9.3362990746 9.3353580244 9.2175273758

Ecuación 9: pa1 vs pCa

pKa = 2.5
Triada 1 (ecuación lineal) Li nea r (pK

pCa pa1 (pKa = 2.5) pCa pa1 (pKa = 4.5) pCa

-0.4996871 1.5003129174 -2.4996870826 3.5003129174 -4.499687083 f(x) = - 0.5
1.50031292 0.5003129174 -0.4996870826 2.5003129174 -2.499687083 R² = 1
f
3.50031292 -0.4996870826 1.5003129174 1.5003129174 -0.499687083 R

p1
5.50031292 -1.4996870826 3.5003129174 0.5003129174 1.5003129174
-6 -4 -2
7.50031292 -2.4996870826 5.5003129174 -0.4996870826 3.5003129174
9.50031292 -3.4996870826 7.5003129174 -1.4996870826 5.5003129174
11.5003129 -4.4996870826 9.5003129174 -2.4996870826 7.5003129174

Ecuación 8: pa1 vs pCa

Triada 2 (ecuación cuadrática)

pCa pa1 (pKa = 2.5) pCa pa1 (pKa = 4.5) pCa

-0.5132176 1.5228787453 -2.4996870826 3.5003129174 -4.499687083
1.38090667 0.6197887583 -0.5010592622 2.5016894462 -2.499687083
2.8827287 0.1191864077 1.4867823999 1.5228787453 -0.499687083
3.98716278 0.017728767 3.3809066694 0.6197887583 1.4989407378
5 0.0043648054 4.8827287043 0.1191864077 3.4867823999
6 0.0043648054 5.9871627753 0.017728767 5.3809066694
7 0.0043648054 7 0.0043648054 6.8827287043

Ecuación 7: pa1 vs pCa

 Triada 3 (ecuación cúbica)

pCa pa1 (pKa = 2.5) pCa pa1 (pKa = 4.5) pCa

-0.5132176 1.5228787453 -2.4996870826 3.5086383062 -4.499687083
1.38090667 0.6197887583 -0.5010592622 2.5086383062 -2.499687083
2.8827287 0.1191864077 1.4867823999 1.5228787453 -0.499687083
3.98716278 0.017728767 3.3809066694 0.6197887583 1.4989407378
5 0.0043648054 4.8827287043 0.1249387366 3.4867823999
6.00436481 0.0043648054 5.9913998282 0.017728767 5.385102784
9.33629907 0.0043648054 9.3353580244 0.0087739243 9.2175273758

Ecuación 9: pa1 vs pH

Triada 1 (ecuación lineal) pKa = 2.5

Li nea r (pKa

pH pa1 (pKa = 2.5) pa1 (pKa = 4.5) pa1 (pKa = 6.5) 8

1 1.5003129174 3.5003129174 5.5003129174 6
2 0.5003129174 2.5003129174 4.5003129174 R² = 1
4
3 -0.4996870826 1.5003129174 3.5003129174 R² = 1
2
4 -1.4996870826 0.5003129174 2.5003129174

p1
R² = 1
0
5 -2.4996870826 -0.4996870826 1.5003129174 0 1
6 -3.4996870826 -1.4996870826 0.5003129174 -2
7 -4.4996870826 -2.4996870826 -0.4996870826 -4

-6

Ecuación 8: pa1 vs pH

Triada 2 (ecuación cuadrática)

6
pH pa1 (pKa = 2.5) pa1 (pKa = 4.5) pa1 (pKa = 6.5) 5 f(x) = 0.036
R² = 0.9982
1 1.5228787453 3.5086383062 5.5003129174
4
2 0.6197887583 2.5086383062 4.5003129174
f(x) = 0.121
3 0.1191864077 1.5228787453 3.5003129174 3
p1

R² = 0.9956
4 0.017728767 0.6197887583 2.5003129174 2
5 0.0043648054 0.1249387366 1.5157001607
1 f(x) = 0.085
R² = 0.9455
0
0 1 2
 3 f(x) = 0.121

p1
R² = 0.9956
2

1 f(x) = 0.085
6 0.0043648054 0.017728767 0.6363880201 R² = 0.9455
7 0.0043648054 0.0087739243 0.1203307944 0
0 1 2

Ecuación 7: pa1 vs pCa

Triada 3 (ecuación cúbica)

pH pa1 (pKa = 2.5) pa1 (pKa = 4.5) pa1 (pKa = 6.5) 6

1 1.5228787453 3.5086383062 5.5003129174 5 f(x) = 0.0130
R² = 0.99975
2 0.6197887583 2.5086383062 4.5003129174 4
3 0.1191864077 1.5228787453 3.5003129174 f(x) = 0.0108
3

p1
4 0.017728767 0.6197887583 2.5003129174 R² = 0.99790
2
5 0.0043648054 0.1249387366 1.5157001607
6 0.0043648054 0.017728767 0.6363880201 1 f(x) = - 0.02
R² = 0.99824
7 0.0043648054 0.0087739243 0.1203307944 0
0 1 2
 Ecuación 6: pH vs pCa
pKa = 2.5 Li near (pKa = 2.5) pKa = 4.5
Li near (pKa = 4.5) pKa = 6.5 Li nea r (pKa = 6.5)
8
7
f(x) = 0.5x f(x)
+ 3.2498435413
= 0.5x f(x)
+ 2.2498435413
= 0.5x + 1.2498435413
R² = 1 R² = 1 6 R² = 1
5
4
pH

3
2
1
0
-6 -4 -2 0 2 4 6 8 10 12 14
pCa

Ecuación 5: pH vs pCa
pKa = 2.5 Pol ynomia l (pKa = 2.5)
pKa = 4.5 Pol ynomia l (pKa = 4.5)
pKa = 6.5 Pol ynomia l (pKa = 6.5)
8
7
f(x) = 0.0049339526x^2 f(x) = 0.0465308912x^2
+ 0.5065345867x
f(x) = 0.0285373652x^2 + +0.50830766x
+ 3.2116452466
+ 0.481765621x + 1.2245151449
2.116438362
R² = 0.9994264759 6R² = 0.9993491763
R² = 0.9973725033
5
4
pH

3
2
1
0
-6 -4 -2 0 2 4 6 8
pCa

Ecuación 4: pH vs pCa
pKa = 2.5 Pol ynomi a l (pKa = 2.5)
pKa = 4.5 Pol ynomi a l (pKa = 4.5)
pKa = 6.5 Pol ynomi a l (pKa = 6.5)
10
f(x) = 80.0863552012x^3 - 0.9824699124x^2 + 4.5713924336x - 4.2967762436
R² = 0.9945832203
f(x) = - 0.0038729552x^3
f(x) = - 0.0016748008x^3 + 0.0353395762x^2
6 + 0.0017414292x^2 + 0.5347667671x
+ 0.5349719183x + 2.118246385
+ 3.2476137383
R² = 0.9953029609
R² = 0.9993843654
4
pH

0
-6 -4 -2 0 2 4 6 8 10 12
 10
f(x) = 80.0863552012x^3 - 0.9824699124x^2 + 4.5713924336x - 4.2967762436
R² = 0.9945832203
f(x) = - 0.0038729552x^3
f(x) = - 0.0016748008x^3 + 0.0353395762x^2
6 + 0.0017414292x^2 + 0.5347667671x
+ 0.5349719183x + 2.118246385
+ 3.2476137383
R² = 0.9953029609
R² = 0.9993843654
4
pH
2

0
-6 -4 -2 0 2 4 6 8 10 12
-2
pCa

Ecuación 9: p1 vs pCa

pKa = 2.5 Li near (pKa = 2.5) pKa =4.5
Li nea r (pKa =4.5) pKa = 6.5 Li near (pKa = 6.5)
8
pa1 (pKa = 6.5) 6
5.5003129174 f(x) = - 0.5x + 3.2504693761
4
4.5003129174 R² = 1
f(x) = - 0.5x + 2.2504693761
3.5003129174 R² = 1 2
p1

f(x) = - 0.5x + 1.2504693761

2.5003129174 0 R² = 1
-6 -4 -2 0 2 4 6 8 10 12 14
1.5003129174 -2
0.5003129174
-4
-0.4996870826
-6
pCa

Ecuación 8: p1 vs pCa

pKa = 2.5 Polynomi al (pKa = 2.5)
pKa = 4.5 Polynomi al (pKa = 4.5)
pKa = 6.5 Polynomi al (pKa = 6.5)

pa1 (pKa = 6.5) 6

5.5003129174 f(x) = 0.0049504415x^2 - 0.4934266499x
5 + 3.2121972734
R² = 0.9993280854
4.5003129174 4
3.5003129174 f(x) = 0.0284540681x^2 - 0.5175804374x + 2.1193824041
3
p1

2.5016894462 R² = 0.993366344
1.5142785735 2

0.6197887583 1f(x) = 0.0468326088x^2 - 0.4939404146x + 1.2312251512

R² = 0.9903408523
0.1191864077 0
-6 -4 -2 0 2 4 6 8
pCa

Ecuación 7: p1 vs pCa

pKa = 2.5 Polynomia l (pKa = 2.5)
pKa = 4.5 Polynomia l (pKa = 4.5)
pKa = 6.5 Polynomia l (pKa = 6.5)
6
 Ecuación 7: p1 vs pCa
pKa = 2.5 Polynomia l (pKa = 2.5)
pKa = 4.5 Polynomia l (pKa = 4.5)
pKa = 6.5 Polynomia l (pKa = 6.5)
pa1 (pKa = 6.5) 6
5.5003129174 R² = 0.9993423918 5
4.5003129174
4
3.5003129174
R² = 0.9987454686
3
2.5003129174
p1

1.5157001607 2
0.6363880201 1R² = 0.9967639261
0.1203307944
0
-6 -4 -2 0 2 4 6 8 10 12
pCa

Ecuación 9: p1 vs pH
pKa = 2.5 Li nea r (pKa = 2.5) pKa = 4.5
Li nea r (pKa = 4.5) pKa = 6.5 Li nea r (pKa = 6.5)
8

6
R² = 1
4
R² = 1
2
p1

R² = 1
0
0 1 2 3 4 5 6 7 8
-2

-4

-6
pH

Ecuación 8: p1 vs pH
pKa = 2.5 Pol ynomi al (pKa = 2.5)
pKa = 4.5 Pol ynomi al (pKa = 4.5)
pKa = 6.5 Pol ynomi al (pKa = 6.5)
6

5 f(x) = 0.0363562816x^2 - 1.2141505715x + 6.7400010314

R² = 0.9982350057
4

3 f(x) = 0.1210054009x^2 - 1.5708772153x + 5.0507416357

p1

R² = 0.995699635
2

1 f(x) = 0.0856505839x^2 - 0.8959622185x + 2.1983624955

R² = 0.9455942642
0
0 1 2 3 4 5 6 7 8
pH
 3 f(x) = 0.1210054009x^2 - 1.5708772153x + 5.0507416357

p1
R² = 0.995699635
2

1 f(x) = 0.0856505839x^2 - 0.8959622185x + 2.1983624955

R² = 0.9455942642
0
0 1 2 3 4 5 6 7 8
pH

Ecuación 7: p1 vs pH
pKa = 2.5 Pol ynomi al (pKa = 2.5)
pKa = 4.5 Pol ynomi al (pKa = 4.5)
pKa = 6.5 Pol ynomi al (pKa = 6.5)
6
5 f(x) = 0.0130154314x^3 - 0.1198288954x^2 - 0.6805178834x + 6.2714455005
R² = 0.9997581611
4
3 f(x) = 0.0108051435x^3 - 0.0086563211x^2 - 1.1278663318x + 4.6617564697
p1

R² = 0.9979012055
2
1 f(x) = - 0.021896344x^3 + 0.3484067121x^2 - 1.7937123233x + 2.9866308802
R² = 0.9982445047
0
0 1 2 3 4 5 6 7 8
pH
pKa Ecuación R
2.5 y = 0.5x + 1.2498 1
4.5 y = 0.5x + 2.2498 1
6.5 y = 0.5x + 3.2498 1

pKa Ecuación R
2.5 y = 0.0465x2 + 0.5083x + 1.2245 0.9993
4.5 y = 0.0285x2 + 0.4818x + 2.1164 0.9974
6.5 y = 0.0049x2 + 0.5065x + 3.2116 0.9994

pKa Ecuación R
2.5 y = 0.0864x - 0.9825x2 + 4.5714x - 4.2968
3
0.9946
4.5 y = -0.0039x3 + 0.0353x2 + 0.5348x + 2.1182 0.9953
6.5 y = 0.0864x3 - 0.9825x2 + 4.5714x - 4.2968 0.9994
pKa Ecuación R
2.5 y = -0.5x + 1.2505 1
4.5 y = -0.5x + 2.2505 1
6.5 y = -0.5x + 3.2505 1

pKa Ecuación R
2.5 y = 0.0468x2 - 0.4939x + 1.2312 0.9903
4.5 y = 0.0285x2 - 0.5176x + 2.1194 0.9934
6.5 y = 0.005x2 - 0.4934x + 3.2122 0.9993
pKa Ecuación R
2.5 y = -0.0044x3 + 0.0901x2 - 0.5847x + 1.2125 0.9968
4.5 y = 0.0024x3 + 0.0075x2 - 0.5127x + 2.23 0.9987
6.5 y = 0.0023x3 + 0.0004x2 - 0.5392x + 3.245 0.9993

pKa Ecuación R
2.5 y = -0.0219x3 + 0.3484x2 - 1.7937x + 2.9866 0.9982
4.5 y = 0.0108x3 - 0.0087x2 - 1.1279x + 4.6618 0.9979
6.5 y = 0.013x3 - 0.1198x2 - 0.6805x + 6.2714 0.9998

pKa Ecuación R
2.5 y = 0.0857x2 - 0.896x + 2.1984 0.9456
4.5 y = 0.121x2 - 1.5709x + 5.0507 0.9957
6.5 y = 0.0364x2 - 1.2142x + 6.74 0.9982
pKa Ecuación R
2.5 y = -0.0219x + 0.3484x2 - 1.7937x + 2.9866
3
0.9982
4.5 y = 0.0108x3 - 0.0087x2 - 1.1279x + 4.6618 0.9979
6.5 y = 0.013x3 - 0.1198x2 - 0.6805x + 6.2714 0.9998
 Gráfica Densidad vs Temperatura

Temperatura (°C) Densidad (g/cm^3)

0 0.99987
5 0.99999 Densidad vs Temperatu
10 0.99973 1.01
15 0.99919
1
20 0.99829 f(x) = - 3.60815477428746E-06x^2 - 7.233776932450
0.99 R² = 0.9990305346
25 0.99713

Densidad (g/cm^3)
30 0.99571 0.98
35 0.99408 0.97
40 0.99225
0.96
45 0.99064
50 0.98802 0.95
55 0.98565 0.94
60 0.98313
0.93
65 0.98045 0 20 40 60
70 0.97705 Temperatura (°C)
75 0.97468
80 0.9716
85 0.96839
90 0.96506
95 0.96162
100 0.95805

Gráfica pKw/2 vs Temperatura

Temperatura (°C) pKw/2

5 7.3515 pKw/2 vs Tempera
10 7.259 8
15 7.1695
7 f(x) = - 0.014147193x + 7.361754386
20 7.0835 R² = 0.9942624819
25 7 6

30 6.919 5
35 6.8415
pKw/2

4
40 6.766
3
45 6.6925
50 6.6215 2
55 6.553 1
60 6.486 0
65 6.4215 0 10 20 30 40 50 60
70 6.3585 Temperatura (°C)
75 6.2975
80 6.238
85 6.1805
90 6.1245
95 6.07
 Densidad vs Temperatura

477428746E-06x^2 - 7.23377693245019E-05x + 1.0007342744

46

40 60 80 100 120
Temperatura (°C)

pKw/2 vs Temperatura

47193x + 7.361754386
4819

30 40 50 60 70 80 90 100
Temperatura (°C)