JEE MAIN

T ES T-1 6
Class: XII / XIII Date: 23-03-2018 Time: 2 Hours. Max. Marks: 240

IMPORTANT INSTRUCTIONS

1. The question paper consists of '60' objective type questions. There are '30' questions each in
Mathematics and Chemistry respectively. Please fill the OMR answer Sheet accordingly and
carefully.

2. Each question has four choices (1), (2), (3) and (4) out of which ONLY ONE is correct.

3. You will be awarded 4 marks for each question, if you have darkened only the bubble corresponding
to the correct answer and zero mark if no bubble are darkened. In all other cases, minus one (–1)
mark will be awarded.

4. There is only one correct response for each question. Filling up more than one response in each
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction 3 above.

5. Use Black or Blue Ball Point Pen only for filling particulars.

6. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

7. Rough work is to be done on the space provided at the bottom and in end of the booklet for this
purpose in the Test Booklet only.

8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator.
However, the candidates are allowed to take away this Test Booklet with them.

9. Do not fold or make any stray marks on theAnswer Sheet.

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 USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48,
Ba = 137, U = 238, Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
[Take : ln 2 = 0.693, ln 1.1 = 0.095, ln 3 = 1.09, e = 1.6 × 10–19, me= 9.1 × 10–31 kg ]
Take: 0 = 8.85 × 10–12 C2/Nm2, g = 10 m/s2, Swater = 1 cal/gm °C, Lice = 80 cal/gm. , g = 10 m/s2
unless otherwise stated

M AT H E M AT I C S
Q.1 The sum of few terms of anyratio series is 728, Q.3 The vertices of a triangle OBC are (0, 0),
if common ratio is 3 and last term is 486, then (–3, –1) and (–1, –3) respectively. Then the
first term of series will be 1
(1) 2 (2) 1 equation oflineparallel to BC whichis atunit
2
(3) 3 (4) 4
distant from origin and cuts OB and OC, is
Q.2 If PQ is a double ordinate of hyperbola (1) 2x + 2y + 2 = 0
x 2 y2 (2) 2x + 2y – 2 = 0
 = 1 such that OPQ is an equilateral
a 2 b2 (3) 2x – 2y + 2 = 0
triangle. O being the centre of the hyperbola. (4) None of these
Then the eccentricitye of the hyperbola satisfies
2 2 sin 6 x  cos 6 x
(1) 1 < e <
3
(2) e =
3
Q.4  sin 2 x cos2 x dx is equal to
(1) tan x + cot x + 3x + c
3 2
(3) e = (4) e > (2) tan x + cot x – 3x + c
2 3 (3) tan x – cot x – 3x + c
(4) tan x – cot x + 3x + c

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XII / XIII Test-16 Page # 2

Q.5 Let  and  be smallest non negative angle Q.10 The real value of k for which the system of
satisfying the equation sec2 + cosec2= 2 equations 2kx – 2y + 3z = 0, x + ky + 2z = 0,
then cot ( + ) is equal to 2x + kz = 0, has non trivial solution is
(1) 0 (2) 2 (1) 2 (2) –2
(3) 4 (4) 6 (3) 3 (4) –3

Q.6 If 2f(x) = f '(x) and f(0) = 3, then f(2) = Q.11 The number of points of intersection of the
(1) 2e3 (2) 3e4  
(3) 5e (4) 3e3 curves y = cos x, y = sin 3x, if – x
2 2
are
Q.7 If the line x + y = r (r > 0) is tangent to the
(1) 3 (2) 4
curve x2 + y2 = r, then the value of r is
(3) 5 (4) 6
(1) 4 (2) 1
(3) 2 (4) none
Q.12 Let Tn denote the number of triangles which
can be formed using the vertices of a regular
Q.8 Let f be a continuous function in [1, 4] and
polygon of n sides.
differentiable in (1, 4), f (1) = 5 and
If Tn+1 – Tn = 21, then n equals
f (4) = 8 and f '(x)  1  x  (1, 4). Then the
(1) 5 (2) 7
value of f (3) is equal to
(3) 6 (4) 4
(1) 5 (2) 6
(3) 7 (4) 8   
Q.13 If b  2î  ˆj  k̂ , c  î  3k̂ and a is a unit
Q.9 If the function f : N  N is defined by   
vector then the maximum value of [a , b, c ] is
f (25)
f (x) = x , then is equal to (1) 59 (2) 69
f (16)  f (1)
(3) 3 (4) None of these
5 5
(1) (2)
6 7
5
(3) (4) 1
3

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XII / XIII Test-16 Page # 3

Q.14 The solution of the equation Q.18 The equation of the ellipse whose vertices are
(±5, 0) and foci are (±4, 0) is
log7log5  x  5  x   0
2
  (1) 9x2 + 25y2 = 225
(2) 25x2 + 9y2 = 225
(1) x = 2 (2) x = 3
(3) 3x2 + 4y2 = 192
(3) x = 4 (4) x = –2
(4) None of these

x  2 y 1 z  2 Q.19 The number of the solutions of the equation

Q.15 Let the line   lie in the
3 5 2 z2 + z = 0 is
plane x + 3y – z +  = 0. Then (, ) (1) 1 (2) 2
equals (3) 3 (4) 4
(1) (6, –17) (2) (–6, 7)
(3) (5, –15) (4) (–5, 5) Q.20 If x1, x2, ........., x18 are observations such that
18 18
Q.16 Consider function
f (x) = [2x] – [3x] + [5x] – [7x] + [11x] – [13x]
 (x j  8)  9 and  (x j  8)2  45 ,
j1 j1
then the number of discontinuous point of then the standard deviation of these
f (x)  x  [0, 13] is observations is
(1) 400 (2) 410
(3) 455 (4) 460 18
(1) (2) 5
34
Q.17 The equation of circle which passes through
the origin and cuts off intercepts 5 and 6 from 3
(3) 5 (4)
the positive parts of the axis respectively is 2
2
 5 Q.21 If a2 + b2 + c2 = ab + bc + ca where a, b, c
 x   + (y – 3)2 = , where  is
 2 are the sides of triangleABC, then largest angle
of triangle is
61 6
(1) (2)  
4 4 (1) (2)
3 4
1
(3) (4) 0  
4 (3) (4)
6 12
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XII / XIII Test-16 Page # 4

Q.22 Let g(x) be a differeniable function for all 2
x  R then [ x ]
Q.25  sin
0
2
dx is equal to :
  1  
Lim g( x )  ln 1  g ( x )   ln g( x )  (1) 1 (2) –1
x 0   e   (3) 0 (4) None of these
is equal to
(1) eg(0) – 1 (2) g(0) Q.26 The distance between the line

g ( 0)
r  2î  2ˆj  3k̂   ( î  ĵ  4k̂ ) and the plane

(3) g(0) eg ( 0 )  1 (4)
e 1
g(0) 
r · ( î  5ˆj  k̂ ) = 5 is

Q.23 The normal to the curve 3 10

(1) (2)
5x5 – 10x3 + x + 2y + 6 = 0 at P(0, –3) 10 3
meets the curve again at the point : 10 10
(1) (–1, 1) (2) (1, –1) (3) (4)
9 3 3
(3) (–1, 5) (4) None of these

Q.24 Let the term independent of x in the expansion Q.27 The length of the latus rectum of the parabola
169{(x – 1)2 + (y – 3)}2 = (5x – 12y + 17)2
9
 2 1 is
of  x   has the value p and q be the
 x 14 12
(1) (2)
sum of the coefficients of its middle terms, then 13 13
(p – q) equals
28
(1) 0 (2) 2 · 9C4 (3) (4) None of these
9
(3) C5 (4) 9C3 13

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XII / XIII Test-16 Page # 5

Q.28 A person standing at the foot of a tower walks n
a distance 3aawayfrom the tower and observes x dy
Q.30 If y = b cos log   , then =
that the angleof elevation of the top of the tower n dx
is. He then walks a distance 4aperpendicular n
to the previous direction and observes the angle x
(1) – n b sin log  
of elevation to be . The height of the tower is n
(1) 3a tan  (2) 5a tan  n
(3) 4a tan  (4) 7a tan  x
(2) n b sin log  
n
   
Q.29 If a and b are unit vectors such that a  3b n
 nb x
  (3) sin log  
is perpendicular to 7a  5b , then the angle x n
 
between a and b is (4) none of these
 
(1) (2)
3 6
2 
(3) (4)
3 4

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XII / XIII Test-16 Page # 6

 C H E M I S T RY
Q.31 Equivalent massof M n3O4 disproportionating Q.35 What is the standard enthalpy change at 298
to give Mn+2 and Mn+7 is equal to : K for the following reaction?
(1) 57.25 (2) 17.61 CO2 (g) + C(diamond)  2CO(g)
(3) 132.11 (4) 12.29
Given : H of (CO, g) = –110.5 kJ/mol
Q.32 Which of the following options will definitely
increaseconcentration ofammonium ions inthe
; H of (CO2,g) = –393.5 kJ/mol
solution of NH4OH? H otransition [C(graphite)  C(diamond)]
(1)Addition of H2O into the solution.
= 2.0 kJ/mol
(2)Addition of NaOH into the solution.
(1) –172.5 kJ/mol (2) –170.5 kJ/mol
(3) Mixing NH4Cl solution with NH4OH
(3) +172.5 kJ/mol (4) 170.5 kJ /mol
solution.
(4)Adding HCl into the solution.
Q.36 An ideal gas is expanded so that the amount
Q.33 Which of followingparameters are not intrinsic of heat transferred to the gas is equal to the
parameters. decrease in its enthalpy. Now choose the
(1) Molar heat capacity incorrect option(s). [All symbols have usual
(2) Temperature coefficient of EMF meaning.]
(3) Entropy of system (1) molar heat capacity =  C P
(4) Critical volume of a gas m

 2 
Q.34 In the reaction: N2(g) + 3H2(g)  2NH3(g) +  
Heat. Initially one mole of N2 and three moles (2) PV   1  = const.
of H2 taken. If at equilibrium 'x' moles of N2   1 
 
combined with H2, then the value of 'x' in terms (3) TV   1  = const.
of KP and the total pressure of gases at
  1 
equilibrium, P, is (Kp is very small)  
(4) PV  2  = const.
3P. 3.K P 8P
(1) (2) 3 3.K
8 P

3 3.K P 8 KP
(3) (4) .
8P P 3
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XII / XIII Test-16 Page # 7

Q.37 Equal volumes of 0.02 M weak base (BOH) Q.41 Hypophosphoric acid is having ________
is mixed with 0.02 M HCl. What will be [H+] number of replaceable H-atom.
concentration at equivalence point? (1) Four (2) Two
Kb(BOH) = 10–6 (3) Three (4) One
(1) 10–5 M (2) 10–9 M
–10
(3) 10 M (4) 1.414 × 10–5 Q.42 The correct set of quantum numbers (n,l,m,s)
for last electron entering present in Lanthanum
Q.38 To an eudiometry tube 20 ml ofA(g), 40 ml of (Z = 57) is
B(g), 30 ml of D(g) & 60 ml of C(gas) is 1 1
introduced & subjected to sparking to cause (1) 5, 0, 0, + (2) 4, 3, 0, +
2 2
followingreaction with100 % extent. Calculate
the volume change involved due to sparking. 1 1
(3) 5, 2, 0, + (4) 6, 0, 0, +
2A(g) + 4B(g)  3P(g) + Q(l) 2 2
3C(g) + D(g)  2P(g) + 4R(g)
(1) 10 ml expansion (2) no volume change Q.43 The hybridization of S in SO42– is same as in
(3) 30 ml contraction (4) 50 ml expansion (1) Xe in XeF4 (2) S in SO32–
(3) C in CO32– (4) As in AsF4
Q.39 The time period of revolution in the 3rd orbit of
Li2+ ion is x sec. The time period of revolution
in the 2nd orbit of He+ ion, should be Q.44 Comment on the electronegativity (EN) ofAs
in AsF3 and AsF5.
3 (1) E.N. of As (AsF3) > E.N. of As (AsF5)
(1) x sec (2) x sec
2 (2) E.N. of As (AsF3) < E.N. of As (AsF5)
2 8 (3) E.N. ofAs is identical in both cases
(3) x sec (4) x sec (4) No comment can be predicted.
3 27
Q.45 Which of the following is sp3d2 and distorted
Q.40 0.1 mole of argon has pressure P &
octahedral ?
temperature TK in the vessel. On keeping the
(1) XeF6 (2) XeOF4
vessel at 50°C higher temperature, 0.8 gm of
(3) IF5 (4) Both (1) and (3)
argon was given out to maintain same pressure.
The original temperature was
(1) 273 K (2) 200 K
(3) 100 K (4) 300 K
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XII / XIII Test-16 Page # 8

Q.46 Statement-1 : In sp3d hybridisation for TBP Q.50 The correct order of surface tension for the
followingmolecule.
geometry only d z 2 orbital is the most suitable
(I) Ethylene glycol (CH2OH – CH2OH)
among all other d-orbitals. (II) Ethyl alcohol (CH3CH2OH)
Statement-2 : All d-orbitals are degenerate. (III) Glycerol (CH 2 OH – CH(OH)–
(1) Statement-1 is true, statement-2 is true and CH2OH)
statement-2 is correct explanation for (1) I > II > III (2) III > I > II
statement-1. (3) III > II > I (4) I > III > II
(2) Statement-1 is true, statement-2 is true and
statement-2 is NOT the correct explanation for Q.51 Which of the following order of Keto content
statement-1. is correct.
(3) Statement-1 is true, statement-2 is false.
(4) Statement-1 is false, statement-2 is true. O

(1)
Q.47 How manynumber of isomers are possible for O O O
cyanogen?
(1) 1 (2) 2 O O
(3) 3 (4) 4
(2)
Q.48 IF7 + BF3  [X]
What is the shape of cationic and anionic part O
O ||
in ionic compound [X] respectively? (3) Me  C  OMe
(1) Trigonal bipyramidal and Octrahedral
O
(2) Trigonal bipyramidal & Tetrahedral
(3) Octahedral & Tetrahedral
(4) Pentagonal bipyramidal & Tetrahedral
(4)
Q.49 Which of following species follows the octet O O O O
rule for all of its atoms.
(1) BeH2-dimer (2) TeF6
(3) XeF6 (4) C2F6

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XII / XIII Test-16 Page # 9

Q.52 Select the pair of chain isomers. Q.56 Which of the following is most contributing
COOH resonating structure of prop-2-enal
(1) COOH 
and (1) CH 2  CH  CH  O 
OH  
(2) OH (2) CH 2  CH  CH  O
and

Et (3) CH 2  CH  CH  O
(3) and Et (4) None of these
NH2
(4) N
and Q.57 CH 3  CH  CH 2  NH 2 ,
|
Q.53 The geometrical isomerism is shown by CH 3
( I)
(1) (2)
NH 2
|
CH 3  C  CH 3 ,
|
(3) (4) CH 3
(II)
Q.54 Which of the following is/are incorrect IUPAC
CH 3  CH 2  NH  CH 2  CH 3
names (III)
(1) 2-Ethyl-3-methyl pentane
Which statement is False.
(2) 1-Chloro 4-methyl pentan-1-ene
(1) I and II are position isomers
(3) Spiro [3.4] octan-5-oic acid
(2) II and III are position isomers
(4) All are correct
(3) I and III are functional group isomers
Q.55 Out of following the most basic isomers of the (4) I and II are primary amines
formula C4H7N is
(1) CC–C–C–NH2 (2) C–CC–C–NH2

N
(3) C–C–CC–NH2 (4) |
H
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XII / XIII Test-16 Page # 10

 COOH Q.60 For –CH3 as substituent , Keq = 18
| CH 3
Q.58 HOOC  CH  CH 2  COOH
COOH CH 3
|
HOOC  CH 2  CH  COOH
then for –C(CH3)3 as a substituent, Keq is
What is the relationship of the two compounds. expected
(1) Chain isomerism (2)Positionisomerism (1) less than 18 (2) equal to 18
(3) Identical (4) Homologues (3) more than 18 (4) Can not say

Q.59

Among these compounds which of the

following is the correct order of their heats of
hydrogenation:
(1) I > II > III (2) III > II > I
(3) II > I > III (4) II > III > I

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XII / XIII Test-16 Page # 11

 ROUGH WORK

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XII / XIII Test-16 Page # 12