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CARBON COMPOUNDS
Carbon compounds can be classified into two groups, _____________ compounds
and ______________ compounds.
Organic compounds – carbon-containing compounds
- All carbon-containing compounds qualify as organic compounds except oxides of
carbon, _____________, cyanides and metallic carbides.
Oxides of carbon, carbonates, cyanides and metallic carbides – can be obtained
from non-living things.
Inorganic compounds – all non-carbon-containing compounds and few
carbon- containing compounds.
1
Classify into organic and inorganic compounds
Organic Inorganic
Potassium cyanide
Cellulose
Starch
Natural rubber
Calcium carbide
Carbon dioxide
Protein
Ethanol
Urea
Glucose
Carbon monoxide
HYDROCARBON (HC)
Unsaturated HC
Saturated HC
C=C -C=C-
-C-C-
2
Double bond Triple bond
Single bond
2 atoms sharing:
____ pair of electrons - single covalent bond
____ pairs of electrons - double covalent bond
3 pairs of electrons - ________ covalent bond
LEARNING OUTCOMES
2.2 Analysing alkanes
State what alkane is
3
State what structural formula is
Deduce the molecular formulae of the first ten alkanes
Draw the structural formulae for the first ten straight-chain alkanes
Deduce the general formula of alkanes
Name the first ten alkanes
Relate changes in physical properties with increase in the number of carbon
atoms in alkane molecules
Explain the effect of the increase in number of carbon atoms in alkane molecules
on the molecules boiling points
Describe complete and incomplete combustion of alkanes
Describe the substitution reaction of alkanes
Write chemical equations for combustion and substitution reactions of methane
Describe how methane affects everyday life.
B) ALKANES
1: Classification of Hydrocarbons
Alkanes are saturated hydrocarbons:
· _______________ (only single C-C bonds)
· hydrocarbon (only C and H)
H H H H
H C H H C C C H
H H H H
2: Bondings in hydrocarbon
Carbon atoms has _________ valence electrons
- need 4 electrons to reach octet ________________ arrangement.
- 4 bonds to each carbon atom
Hydrogen atoms has _______ valence electron
- need 1 electron to reach _______________ electron arrangement.
- 1 bond to each hydrogen atom
4
Carbon and hydrogen atoms can bond to each other to form very extensive and
molecular systems.
3: Formulae for organic molecules:
Molecular Formula :
Shows the actual numbers and types of atom present in a molecule.
Structural Formula :
Shows how the atoms in a molecule are bonded together and by what types of bonds.
Write the molecular formula for each of the alkanes below.
Molecular Formula Structural Formula
H H
H C C H
H H
H H H H
H C C C C H
H H H H
5
3. Ending - tells the family of the compound.
No. 1 4 6 8 9
of
carbo
Root Eth Prop Pent Hept Oct Dec
n
name
atoms The root names for the first ten straight-chain alkanes
Naming Alkanes
Example : Butane
Root Ending
Name of alkane
Butane But (no. of carbon -ane (the family is
atoms = 4) alkane)
1 C Methane
H
CH4 H C H
2 C
Ethane C2H6
3 C
Propane C3H8
4 C
Butane C4H10
6
5 C
Pentane C5H12
6 C
Hexane C6H14
5: Physical Properties
Alkanes- _______________ compounds
a) Melting and Boiling Point
Low melting and boiling points because these molecules are held together by
___________________________ forces.
7
CH4 - C4H10 : ___________ C5H12 - C17H38: ___________ C18H38 : ___________
c) Solubility
• ____________ in non polar solvents (organic solvents),
• Insoluble in water.
d) Density
* The density of the alkanes increases with increasing number of carbon atoms,
BUT is ________________ than that of water.
Hence, alkanes form the upper layer in an alkane - water mixture.
e) Electrical Conductivity
• ____________ conduct electricity
• because : alkanes are covalent compounds, do not have free ions but are made up of
_________________.
6.Chemical Properties of alkanes
• _________________ compounds
• Saturated compounds.
• The strong C-C and C-H bonds must be broken for the alkanes to react.
• Although alkanes do not react with most chemicals, they do react with oxygen and
halogens.
a) Combustion
• The reaction with oxygen
• ______________ combustion of methane / in the presence of sufficient oxygen :
CH4(g) + 2O2(g) CO2(g) + 2H2O(l)
• _______________ combustion / insufficient oxygen available :
2CH4(g) + 3O2(g) CO(g) + 4H2O(l)
CH4(g) + O2(g) C(s) + 2H2O(l)
b)
Halogenation
• Reaction with _______________
• Takes place readily in sunlight.
• C-H bonds-broken, formed C-halogens bonds
8
• Halogenation - example of a _______________ reaction
• Substitution reaction – when one atom or a group of atoms in a molecule is replaced
by another atom or group of atoms.
• Example - Mixture of methane and chlorine is exposed to _____________-varying
amounts of four different products are formed.
UV
• CH4 + Cl2 CH3Cl ______chloromethane
CH2Cl2 ______chloromethane
CHCl3 ______chloromethane
CCl4 ______chloromethane
CH4(g) + Cl2(g) CH3Cl(g) + HCl(g)
WORKSHEET 1
Figure 1 shows the electron arrangement of carbon atom.
x
x
x x
Cx
x
Figure 1
9
WORKSHEET 2
Answer all the questions.
1. What is the general formula for an alkanes?
_____________________________________________________________
2. Give the molecular formula for alkanes with
i) one C’s : _____________________
ii) four C’s : _____________________
iii) eight C’s : _____________________
3. Give the name for the alkanes having
i) two carbon atoms : _____________________
ii) five carbon atoms : _____________________
iii) seven carbon atoms : _____________________
4. Draw structural formulas for
i) Propane (ii) Heptane
10
LEARNING OUTCOMES
2.3 Analysing Alkenes
State what alkene is
Deduce the molecular formulae of the first nine alkenes
Deduce the general formula of alkenes
Name the first nine alkenes
Draw the structural formulae for the first nine straight-chain alkenes
Relate changes in physical properties with increase in the number of carbon
atoms in alkene molecules
Explain the effects on boiling points of alkenes due to increase in the number of
carbon atoms in alkene molecules
Describe chemical properties of alkenes
Compare and contrast alkanes with alkenes
Relate the reactivities of alkanes and alkenes to their chemical bonds
Generalise the characteristics of homologous series based on alkanes and
alkenes
11
C) ALKENES
Are members of a family of hydrocarbons containing at least one carbon-carbon
_______________/ C=C
______________ hydrocarbons
NAMING ALKENES
Example :-
12
Similar to those of alkanes.
___________ melting and boiling points.
Soluble in organic solvents, insoluble in water.
Less dense than water
______________ conduct electricity in any state.
The physical properties of the first nine straight-chain alkenes
6 -140 64 0.6750
Hept-1ene 7 -119 93 0.6980
_______________ reaction.
COMBUSTION REACTION
13
C2H4(g) + 3O2 (g) 2CO2(g) + 2H2O(l)
Alkenes burn with sootier flames as compared to alkenes.
Because alkenes have a higher percentage of _____________ in their molecules
than alkanes.
ADDITION REACTIONS
Almost all reaction of alkenes occur at the _________________
C=C + A-B -C - C-
A B
I ) Addition of hydrogen
H H HH
Ni
H-C=C-H(g) + H-H(g) H-C-C-H(g)
1800C
HH
14
H Cl
[O]
CH2=CH2(g) + H2O(l) CH2 – CH2 (l)
OH OH
Polimerization reaction
Hundred/thousands of the alkene molecules link together to form long chains
called polymers.
To form a polymer from alkene monomers – addition polymerization.
Polimerization of ethane - Heating ethene to about __________ and a
pressure of 1200 atm in the presence of trace of oxygen.
- Polymerization of ethene
H H H H H H H H
C=C + C=C + C=C or n C=C
H H H H H H H H
HHHHHH HH
-C-C-C-C-C-C- or C-C
n
HHHHHH HH
15
C=C more ______________than C-C
The soot test –alkenes burn to produce a more ____________ flame.
Alkenes have higher C content than alkanes.
Soot - unburned carbon
ALKANE ALKENE
General CnH2n+2 CnH2n
Formula n=1,2,3,…. n=2,3,4,..
Functional C-C C=C
Group Single bond Double bond
Physical -Low melting and boiling points -Low melting and boiling points
Properties -Less dense than water -Less dense than water
-Cannot conduct electricity -Cannot conduct electricity
-Insoluble in water -Insoluble in water
-Soluble in organic solvent -Soluble in organic solvent
Chemical -Combustion -Combustion
Properties -Halogenation -Addition of hydrogen
-Addition of halogens
-Addition of hydrogen halides
-Addition of water
-Addition of hydroxyl group
-Polymerization
Homologue Series
Is a group or family of organic compounds that has the following:-
o Members of the series can be represented by a general formula.
o Members have similar chemical properties because they have the same functional
group.
Functional group
Is a special group of atoms attached to an organic molecule.
This group-determine the chemical properties of the molecule.
Alkanes - do not have any specific functional group.
16
Alkenes - ___________ is the functional group
LEARNING OUTCOMES
2.4 Synthesising ideas on isomerism
H-C-H
straight chain alkane
H-C-H Side chain :
molecule
H 2 C atom
17
ISOMERISME
Isomerisme – The ability of carbon atoms to form branched chains forming
molecules (isomers) with the same molecular formula but different structural formulae.
ISOMERS
Isomers – are molecules with the same _____________ formula but with
different _______________ formulae.
ISOMERS OF ALKANES
H
HHHH
H-C-H
H H
H-C-C-C-C-H
H-C-C-C-H
HHHH
HHH
ISOMERS OF ALKENES
H
HHHH HHHH H-C-H
H H
H-C=C-C-C-H H-C-C=C-C-H
H-C=C-C-H
HH H H
H
Straight-chain molecule – Different positioning Branched-chain
of double bond molecule
18
HOW TO NAME ISOMERS
1.Find the ______________ continuous carbon chain in the molecule.
2.Give the name for this longest chain.
3.Identify the ______________ (alkyl group) in the molecule.
4.Locate and name the attached alkyl group.
5.Combine the name for the longest C chain with the name of branch chain.
ALKYL GROUP
Branch / alkyl group – is an alkane from which one hydrogen atom has been
removed.
Alkyl group are named by dropping –ane from the name of the corresponding
alkane and replacing it with –yl.
H H
-H
H-C-H H-C-H
H
Methane ______________
H- C- C- C- C- H _____________
H H H H
Step 3 :
H H H
H H
Locate and name the
H-C-H attached alkyl groups.
Alkyl group The position of each
H H H alkyl group is given
the number of the
H- C- C- C- C- H C atom to which it is
20 attached on the chain.
H H H H
_____________
_______________
4 3 2 1
methyl
Step 5 :
H
Complete the name for the molecule by
H-C-H combining the 3 component parts together. Write the
name as a single word.
H H H Use hyphens to separate numbers and
4 3 2 1 words & commas to separate numbers.
H- C- C- C- C- H
_________________________
H H H H
Step 1 :
H
Find the longest
H-C-H
continuous
H H H carbon chain
in the molecule including double bond.
H- C- C= C- C- H Step 2 :
H H ____________
Step 4 :
H H _________________
Step 5 :
HH H H H H H
H
H- C- C= C- C- H H- C= C- C- C- H H-C-H
H H-C-H H H H H H
H-C-H H- C- C= C- C- H
H H H H
a) 2-methylbutane
b) 3-metilbut-1-ene
c) 2,3-dimethylhept-3-ene
23
d) 1,2-dibromobutane
3. An alkane molecule, X has the molecular formula C5H12. A student suggested its
name as 2,2-dimethylpropane.
LEARNING OUTCOMES
2.5 Analysing alcohols
24
Explain the effects of the misuse and abuse of alcohols.
E) ALCOHOLS
Example : wine is made from grape juice and rice wine is from fermented rice
Familiar alcohol : ethanol, C2H5OH
– -C-O-H
NAMING ALCOHOLS
The names of straight chain alcohols can be derived from those of the alkanes.
Replacing the ending -e from the name of the alkane with –ol.
A number in front of the –ol to indicate which carbon atom the hydroxyl group is
attached to.
HHH
25
H- C-C-C-H
OHH H
Name of alkane : propane
Name of alcohol : propanol
Position of hydroxyl group : carbon 1
Full name of alcohol : __________________
ISOMERS OF ALCOHOLS
Example: C4H9OH
H HHH H H H H
H-C- C-C-C-H H-C -C- C- C-H
OHH H H H OH H H
____________ _______________
H CH3H H CH3 H
H-C-C - C-H H-C-C - C-H
H OH H HH OH
_____________ _____________
INDUSTRIAL PRODUCTION OF ETHANOL
Ethanol – most important alcohols
Its manufactured on a large scale by 2 main processes
– From sugars and starch by __________________
26
In the fermentation process, the enzyme (____________) slowly decomposes
the glucose to form ethanol and carbon dioxide.
C6H12O6(aq) 2CH3CH2OH(aq) + 2CO2(g)
Temperature : 18-200C
Catalyst : yeast (zymase)
Other condition : absence of oxygen
When the concentration of ethanol formed reaches about 15%, the yeast
__________ and the fermentation stops.
It is impossible to produce pure ethanol by natural fermentation.
The ethanol is then purified by fractional distillation.
27
Pentanol 138 2.7
Notice that none of the alcohols exists as a __________ at room temperature
and pressure.
Unlike alkanes or alkenes, simple alcohols are __________________ in water.
They have infinite solubility in water.
Physical state at
room conditions
LIQUID Smell
Boiling point SHARP
LOW BOILING POINT
(780C)
ETHANOL Colour
Volatility
VOLATILE COLOURLESS
Solubility in water
VERY SOLUBLE IN WATER.
MISCIBLE WITH WATER IN
ALL PROPORTIONS
Oxidation
28
Dehydration
I) COMBUSTION
Alcohols- very ________________ substances
Readily undergo combustion
Ethanol burns with ______________ blue flame
Complete combustion of ethanol produces ______________ and water.
C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l)
Also releases lots of ___________ – suitable for use as a fuel. Clean fuel because
it does not release pollutants into the atmosphere.
II) OXIDATION
When a substance combines with oxygen
Oxidizing agents are needed.
– Example :
• acidified potassium dichromate (VI), ____________ solution and
III) DEHYDRATION
The removal of water from a compound.
In the dehydration of alcohols, a molecule of water is eliminated from each
alcohol molecule.
The alcohol molecule becomes an ______________ molecule.
The dehydration of ethanol produces ethene.
HH H H
H-C-C-H H-C=C-H + H-OH
H OH
29
The ethene produced can be detected by the following tests:
– Decolourizes reddish-brown ___________ water
– Decolourizes purple acidified KMnO4 solution
2 methods to carry out the dehydration of ethanol in school laboratory.
– Ethanol ____________ is passed over a heated catalyst such as unglazed
porcelain chips, porous pot, pumice stone or aluminium oxide.
– Ethanol is heated under reflux at 1700C with excess concentrated ___________.
Name Product
Combustion Oxidation Dehydration
Ethanol Carbon dioxide and water Ethanoic acid and water Ethene and water
Methanol
Propanol
Butanol
USES OF ALCOHOLS
As a __________ in perfumes, cosmetics and toiletries.
As a ___________ in lacquer, varnish, shellac and ink.
As a ___________ for a compac disc and video cassette recorder head.
As a __________ – clean fuel, biofuel, gasohol
30
As a raw material in the _____________ of vinegar, fibre, explosive and plastic.
As a raw material to make _______________ products- tincture, antiseptic,
cough syrup, rubbing alcohol.
ALCOHOL-MISUSE AND ABUSE
Ethanol – toxic
– Found in alcoholic drinks
– Act as depressant on the central nervous system. It slows down both physical
and mental activity.Causes the person to feel high and to lose all shyness.
_______________.
Cause chronic liver disease and brain damage.
WORKSHEET 4
The flow chart in the figure shows the reactions of alcohol P with a few substances.
HH Acidified
Reaction W
Alcohol P Dehydration KMnO4 H H H
H-C-C-C-OH Substance X Substance Y Q H-C –C –C -H
C3H8O
HHO H OHOH
31
LEARNING OUTCOMES
2.6 Analysing carboxylic acids
State the general formula of carboxylic acids
Identify the functional group of carboxylic acids
List the names and molecular formulae of the first four members of carboxylic
acid
Draw the structural formulae of the first four members of carboxylic acid and
name them using the IUPAC nomenclature.
Describe the preparation of ethanoic acid in the laboratory
State the physical properties of carboxylic acids
State the chemical reactions of ethanoic acid with other chemicals
Predict the chemical properties for other members of carboxylic acid
Explain with the examples the uses of carboxylic acids in everyday life.
F) CARBOXYLIC ACID
EXAMPLES ORGANIC ACIDS:
32
The general formula –
– CnH2n+1 COOH
– n= 0, 1, 2, 3,…,
The functional group ___________ (carboxyl group)
Structure functional group :
O
-C
O-H
O
Carboxyl group
-C-C- C
O-H
Carbon no. 1
In carboxylic acids, the carboxyl C atom is always the start of the longest C
chain.
Carboxyl C is the number 1 C and ____________ is needed to locate the
carboxyl group.
Example :
CH3-CH-COOH
CH3
2-methylpropanoic acid
33
Oxidation of _______________
By refluxing ethanol with ________________ such as K2Cr2O7 solution or KMnO4
solution.
HH K2Cr2O7 H O
H-C-C-OH + 2[O] H-C-C + H2O
reflux
HH H OH
Ethanol ethanoic acid
heat
Physical Properties
Carboxylic acid with
34
– low molecular mass
Boiling points are ___________ than that of alkanes with the same number of
carbon atoms.
More energy is required to overcome the stronger force of attraction between
the larger carboxylic acid molecules.
Within the carboxylic acid family, the boiling points increase with increasing
number of ________________________________.
Physical properties
Physical Properties
35
Like simple alcohol, the smaller carboxylic acid molecules with 4 C atoms or
fewer are _________________ in water.
The high solubility is due to water molecules being strongly attracted to the
carboxyl group.
The solubility _______________ with increasing number of C atoms per
molecule.
The longer carboxylic acid molecules tends to be alkane-like and becomes
insoluble in water.
Chemical properties
Acid properties
Ethanoic acid – __________monoprotic acid
Only __________ atom in the –COOH can ionize in water to produce H +.
CH3COOH(aq) CH3COO-(aq) + H+(aq)
Ethanoic acid ____________ hydrogen ion
Partial dissociation occurs.
The presence of H+ causes ethanoic acid to turn moist blue litmus paper red and
react just like any typical acid.
Reacts slowly with _______________________________________.
36
Reactions with carbonates
React with metal carbonate to produce a salt, carbon dioxide and water.
2CH3COOH(aq) + CaCO3(s) Ca(CH3COO)2(aq) +CO2(g) +H2O(l)
________________
Reactions with alcohols
Reacts with alcohol to form _____________ and water – Esterification
Carboxylic acid + alcohol ester + water.
O O
CH3-C-O-H + H-O-C4H9 CH3-C-O-C4H9 + H-O-H
Ethanoic Butan-1-ol _______________
acid
CH3COOH + C4H9OH CH3COOC4H9 + H2O
Concentrated __________________ - catalyst
Butyl ethanoate is a colourless sweet smelling liquid.
37
Vinegar – solution containing 5% ethanoic acid
Used with other chemicals to make drugs, dyes, paints, insectisides and
plastics.
It can be converted into esters for use as solvents.
Methanoic acid (formic acid) is used to coagulate latex.
Fatty acids are long chain carboxylic acids used in making soaps.
Carboxylic acids are used in the manufacture of polyesters and polyamides which
are fibres used in the textile industry.
_________________ is a preservative in foods.
WORKSHEET 5
1.a) Name the elements found in carboxylic acids. ______________________________
b) What is the general formula for the carboxylic acid family?____________________
c) Name the functional group of this homologous series.________________________
3. Figure shows a reaction scheme involving compound P. Compound P and Q have the
same number of carbon atoms. Compound P is neutral, whereas compound Q is
acidic.
Compound P Compound Q
Ethyl
ethanoate
38
c) Compound P reacts with compound Q to form ethyl ethanoate. Name process II.
________________________________________________________________________
LEARNING OUTCOMES
2.7 Analysing esters
State the general formula of esters
Identify the functional group of esters
List the names and molecular formulae of simple esters
Draw structural formulae of simple esters and name them using the IUPAC
nomenclature.
Describe the preparation of ester in the laboratory
State the physical properties ethyl ethanoate
Predict the ester produced from the esterification reaction
Write the equations for the esterification reactions
39
State the natural sources of ester
State the uses of ester in everyday life.
G) ESTERS
• ______________ compound
• Most esters are found in fruits and are responsible for the distinctive and
pleasant fruity aromas.
• Example : ester isoamyl acetate is the main chemical that produces the smell of
bananas.
THE ESTER FAMILY
• Containing ______________
• The general formula contains the group _____________. This is known as the
_______________ group (functional group).
NAMING ESTERS
• CnH2n+1-C
40
O-CmH2m+1
• The name of the alcohol part of the ester is given first and is followed by a
separate word giving the name of the acid part of the ester.
• The name of alcohol part of the ester is the name of the __________ group
• The name of the acid part of the ester is the name of the carboxylate anion
derived from the acid; the _______ acid in the name of the parent acid is replaced by
_____.
Eg :
• Esterification
41
acid
Example :
• Predict the ester produce from an esterification between propanoic acid and
ethanol and write an equation for the esterification reaction.
PHYSICAL PROPERTIES OF ESTERS
• ________________liquids
• _______________ compounds.
• Are responsible for the fruity smells and pleasant fragrances associated with
most fruits and flowers.
42
• Animal fats such as milk fat –___________ esters
• Volatile liquid
• Simple esters - ethyl ethanoate are excellent solvents for organic compound.
43
• Sunburn lotions, nail polish removers and glues use esters as solvents. Example,
• The long chain polyester molecules are ____________and have great tensile
strength. Hence they are used to make polyester threads in the production of synthetic
fabrics.
LEARNING OUTCOMES
2.8 Evaluating Fats
State what oils are
State what fats are
State the importance of oils and fats for body processes
State the sources of oils and fats
List the uses of oils and fats
State the differences between oils and fats
Identify structural formulae for fat molecules of certain fatty acids
State what saturated fats are
State what unsaturated fats
Compare and contrast between saturated and unsaturated fats
Describe the process of changing unsaturated fats to saturated fats
Describe the effects of eating food high in fats on health
Describe the industrial extraction of palm oil
Justify the use of palm oil in food production
H) FATS
44
WHAT ARE OILS AND FATS?
Chemically very similar, but differ in their physical states.
Fats found in - _________ at room temperature
Fats from – liquid -called ________
• Oils and fats are natural esters formed through ________________ reaction
between ______ glycerol molecule and __________fatty acid molecules.
• Fatty acids –
• Esterification
THE DIFFERENCE
45
PROPERTIES OILS FATS
Physical state at
Room temperature
• SOURCE OF NUTRIENTS
– Fats help to carry fat-soluble vitamins like vitamins A, D, E and K which are
essential for good health.
46
TWO TYPES OF FATS
SATURATED UNSATURATED
SIMILARITY
DIFFERENCES
Source
Animals Source Plants
Melting point
Melting point Lower
47
Saturated fat Unsaturated fat
– glycerol + _____________ fatty – glycerol + ________________ fatty
acids acids
– Eg : Tristearin and tripalmitin – Eg : triolein
– Eg : butter and animal fats – Eg : groundnut oil, olive oil and palm
oil
48
• Palm kernel oil –extracted from the _________________________.
• The extraction of oil has to be carried out within 24 hours from the time the
fruits are harvested – because the fruits quickly deteriorate and spoilt.
Extraction process of palm oil
Oil palm
fruits Sterilizer Stripper
bunches
Sterilising Stripping the Breaking down
the fruits fruits from oil-bearing cells
bunches
Hydraulic
Filter Press Nut
cracker
Removing Separating the Pressing
coarse fibre oil from water Extracting
out the oil
oil
Purifier Vacuum
Purifying Drying
the oil the oil
49
Describe how the presence of sulphur atoms changes the properties of
vulcanized rubber
Compare and contrast the properties of vulcanized and unvulcanised natural
rubber
I) NATURAL RUBBER
NATURAL POLYMERS
NATURAL RUBBER
Rubber tree
50
Production of latex
MONOMER OF NATURAL RUBBER
or
Task! Find out the monomer for protein, cellulose and starch …
51
NATURAL POLYMERS
Natural rubber
Starch
Cellulose
Protein
Properties of natural rubber
Property Description
Elasticity Natural rubber is _________. It will return to
(decreases over time) its original shape after you stretch it.
• Do you know that natural rubber is used to make household product, medicine,
engineering as well as in the construction and automobile industries ?
52
LATEX
• Latex is a __________________ that flows out after the bark of the rubber tree
is cut.
• Latex is a _____________.
• The rubber particles are so __________ that they remain suspended in water.
Do you know that latex is a waste product of rubber tree?
RUBBER PARTICLE
Rubber particle
53
1. The repulsion between the _________________ particles prevents the rubber
particles from coming close to each other. Hence, latex could not coagulate.
3. The rubber particles can now come close together. This enables them to
_____________ with one another resulting in the ____________ of the protein
membranes.
4. The ___________________ combine with one another and entangle and thus
causing the latex to coagulate.
• This is because the __________________ from the air enter the latex.
• The growth and spread of bacteria produce ______________ that causes the
coagulation of latex.
54
• If latex can coagulate by using acid such as ethanoic acid,CH 3COOH,
• Latex can be preserved in the liquid state if ammonia, NH3 solution is added.
Vulcanization of rubber
55
Properties of vulcanized and unvulcanized rubber
Unvulcanized
Vulcanized
rubber
rubber
Similarities
Differences
Harder Hardness
56
Does not become soft Effect of organic solvent
and sticky easily
Vulcanisation of rubber
Vulcanized rubber
• When vulcanized rubber is stretched and released, the cross linkages pull the
chain back to their original arrangement.
57
WORKSHEET 6
1. The flow chart in Figure 2 shows the conversion of latex to vulcanized rubber
through Step P and Q.
________________________________________________________________
________________________________________________________________
________________________________________________________________
b) Draw the structural formula of the polymeric chain of unvulcanised rubber. Give
its IUPAC name. (2 M)
c) i) Name process Q. (1 M)
________________________________________________________________
________________________________________________________________
d) List down three differences in the properties between unvulcanised rubber and
vulcanised rubber. (3 M)
58
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
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WORKSHEET 7
Figure shows a flow chart for a series of changes on an alcohol R with the molecular
formula C3H8O.
X V Propyl
Alcohol P
propanoate
Carbon dioxide VI
III II Acidified
+ water K2Cr2O7 Sodium
Alcohol R propanoate
C3H8O
I
Propene
IV Acidified KmnO4
[2 marks]
59
b) A mixture of alcohol R and acidified potassium dichromate (VI) solution is heated
in step II.
________________________________________________________________
[1 mark]
ii) Write the chemical equation for the reaction in step II.
________________________________________________________________
[1 mark]
c) Describe briefly how you can carry out step III in the laboratory.
________________________________________________________________
________________________________________________________________
________________________________________________________________
[2 marks]
d) Draw the structural formula of compound Y.
[1 mark]
e) i) Name a catalyst that is used in step V.
________________________________________________________________
[1 mark]
ii) Describe briefly how you can carry out step V in the laboratory.
________________________________________________________________
________________________________________________________________
[2 marks]
iii) Give two differences in the physical properties between propyl propanoate
and alcohol R.
________________________________________________________________
________________________________________________________________
________________________________________________________________
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________________________________________________________________
[2 marks]
f) Name the reagents used in step VI.
________________________________________________________________
[1 mark]
61