CLP PDF

Classification, Labelling
and Packaging (CLP)

The Implementation of the CLP Regulation for Mixtures
Understanding CLP
The Classification, Labelling and Packaging (CLP) regulation (European Regulation (EC) No 1272/2008) was
implemented on 20 January 2009, as the EU implementation of the United Nations’ Globally Harmonised
System on the classification and labelling of chemicals (GHS). Known hazards of a substance are
communicated using pictograms and hazard statements on safety data sheets and labels. The CLP regulation
replaces the Dangerous Substances Directive (DSD) and the Dangerous Preparation Directive (DPD) with full
implementation from June 2015 when mixtures must be classified in accordance with CLP. Substances have
been subject to the CLP regulation since December 2010, therefore this change has already been implemented
for the majority our products and our MSDS for these products carry the new classifications and labels.
CLP and mixtures
From 1st June 2015 the CLP regulation will begin to cover chemical mixtures (i.e. home care formulations). As
a result of this, suppliers of substances and mixtures will be required to clearly display labels on the packaging
of chemical mixtures that contain any hazardous substances above a certain threshold or where data exists on
the mixture. There will however be exemptions from displaying the hazard information on packaging smaller
than 125ml or that which is otherwise difficult to label. There will be a 2 year sell through period for any current
mixtures labelled under the DPD and are already in the supply chain before the regulation begins. In order to
help customers manage this change we have provided a summary of products carrying no classification.
New Concentration Thresholds
The CLP regulation for mixtures will alter the current classification thresholds which means some chemical
mixtures will appear to be more severely classified, or may have to carry a hazard pictogram that they didn’t
previously. For example a mixture containing 7% of a corrosive substance would carry an ‘irritant’ classification
under the DPD however with the new CLP regulation this will require a ‘corrosive’ classification.
This change will have the biggest impact on both the skin damage/irritation and eye damage/irritation
classifications.
Croda Europe Ltd. Cowick Hall Snaith Goole East Yorkshire DN14 9AA England 03/15HCDS163
Tel +44 (0)1405 860551 Fax +44 (0)1405 861767 E-mail homecare-europe@croda.com www.crodahomecare.com Page 1 of 9
Skin Damage/Irritation
Materials classified with skin damage/irritation are split into 2 categories depending on the severity. Skin
Category 1 is the most severe and materials will carry a corrosive label when used at a concentration ≥ 5% and
Skin Category 2 will carry an irritant label when used at a concentration ≥ 10%.
Table 1: Concentration limits and respective hazards of skin damage/irritation classified materials
Generic Concentration Limits Before Hazard Labelling Required

Category Hazard Code
H315 H314 None
Skin Category 1 ≥ 1% but < 5% ≥ 5% < 1%
Skin Category 2 ≥ 10% < 1%
Causes severe skins
No statement
Hazard Statement Causes skin irritation burns and eye
required
damage
Hazard Symbol No symbol required
Eye Damage/Irritation
Materials classified with eye damage/irritation are split into 2 categories depending on the severity. Eye
Category 1 is the most severe and materials will carry a corrosive label when used at a concentration ≥ 3% as
well as having irreversible eye effects. Eye Category 2 will carry an irritant label when used at a concentration
≥ 10% and is considered to have reversible eye effects.
Table 2: Concentration limits and respective hazards of eye damage/irritation classified materials
Generic Concentration Limits Before Hazard Labelling Required

Category Hazard Code
H319 H318 None
Eye Category 1 ≥ 1% but < 3% ≥ 3% < 1%
Eye Category 2 ≥ 10% < 1%
Causes serious eye Causes severe eye No statement
Hazard Statement
irritation damage required
Hazard Symbol No symbol required
Potential Outcomes
The CLP regulation provides guidance on methods for classification of a mixture, such as classifying from test
data on the mixture; using ‘bridging’ principles to read across from similar formulations; using a calculation
method for ingredients or using the translation tables in CLP Annex VII. Some businesses have already
commenced in-vitro studies to determine the effects on skin and/or eye cells with the aim of reducing the
hazard classification that their formulations will carry. Data is being generated for new and existing substances,
and hence components of mixtures, which require REACH registration in Europe. This data may have an
impact on how many products are classified in the future.
How to use this guide
The table below outlines each hazard code as well as the corresponding statement and pictogram. The hazard
statement and symbol are what is to be displayed under the new labelling system.
Please note: the information in this guide is correct on date of issue, but for complete accuracy please always
consult the current product MSDS
Table 3: Hazard codes and their respective statements and symbols
Hazard Code Hazard Statement Hazard Symbol

Skin Damage/Irritation
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
Eye Damage/Irritation
H318 Causes serious eye damage
H319 Causes serious eye irritation
Other Associated Hazards
H302 Harmful if swallowed
H330 Fatal if inhaled
H332 Harmful if inhaled
H400 Very toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
= will result in material carrying the “Exclamation mark” hazard symbol
= will result in material carrying the “Corrosive” hazard symbol
Product Listing
Current Non-classified Products – Page 4

- This contains any product that is not classified as hazardous and typically used within cleaning
formulations
Current Classified Products – Pages 5 & 6

- This contains all the products and their respective hazard codes, statements and symbols
Other Non-classified Products – Pages 7 & 8
- This contains all the remaining products that are not classified as hazardous and are not associated
with cleaning formulations
Current Non-classified Products
Table 4: Products that currently carry no hazard classification and are typically used within cleaning
formulations
Product Name Product Name
Nonionic Surfactants Brij S20
Sorbitan Esters and Ethoxylated Sorbitan Esters Brij S100
Span™ 20 Alkoxylated Synthetic Alcohols
Span 40 Synperonic™ A20
Span 60 Synperonic LF/30
Span 65 Synperonic NCA 830
Span 80 Other Alkoxylates
Span 83 Synperonic PE/25R2
Span 85 Synperonic PE/F87
Tween™ 20 Synperonic PE/F108
Tween 21 Synperonic PE/L44
Tween 65 Synperonic T/304
Ethoxylated Triglycerides Synperonic T/908
Croduret™ 7 Synperonic T/1301
Croduret 40 Performance Additives
Croduret 50 Cirrasol™ Expel
Croduret 60 Cirrasol PE113
Etocas™ 29 Crodamide™ EBS
Etocas 35 Crodastat™ 400
Etocas 40 NatraGem™ S140
Etocas 200 NatraSense™ LF8
Ethoxylated Fatty Acids Permalose™ TM
Myrj™ S8 Prifer™ 6813
Myrj S20 Rheology Modifiers
Myrj S40 Crothix™ Liquid
Myrj S50 CrystaSense™ HP4
Myrj S100 CrystaSense HP5
Ethoxylated Natural Fatty Alcohols CrystaSense LP1
Brij™ C20 CrystaSense LP2
Brij CS20 CrystaSense LP3
Brij CS25 CrystaSense MP
Brij L23 CrystaSense Sapphire
Brij LT23 Lanolin and Derivatives
Brij O5 Solan™ 75/50
Fatty Acids Prifac™ 7923
Prisorine™ 3501 Prifac 8944
Prisorine 3508 Glycerine
Pristerene™ 4916 Pricerine™ 9091
Priolene™ 6907
Current Classified Products
Table 5: Hazardous products and their respective active content
Hazard Category
Product Name Hazard Code(s) Active Content (% approx.)
Skin Eye
Performance Additives
Cirrasol ST H412 - - 100
Cirrasol ST Ultra H319 - 2 100
Coltide™ Radiance H302, H319 - 2 25
Crodafos™ 810A H315, H318 2 2 100
Crodasinic™ HT H315 2 - 30
Crodasinic TG H302, H318 - 1 55
Crodastat™ 200 H315, H318 2 1 100
Crodateric™ LIDP H314 1 - 30
CrystaSense IM700 H318 2 1 100
CrystaSense IM800 H318 2 1 100
Forestall™ H302, H315, H318 2 1 37
ModiSurf™ Clarity H318 - 1 30
Mona AT-1200 H315, H318 2 1 41
Multitrope™ 810 H315, H319 2 2 45
Multitrope 1214 H314 1 - 100
Multitrope 1620 H318 - 1 100
NatraSense AG-810 H319 - 2 70
NatSurf™ 265 H315, H318 2 1 100
Primasurf™ SC50 H302, H315, H318, H332 2 1 58
Promidium™ CO H315, H319, H400 2 2 100
Speciality Proteins and Protein Derivatives
Coltide HQS H319 - 2 25
Coltide HSi H302, H319 - 2 25
Coltide SQM H315, H319 2 2 25
Anionic Surfactants
Crodasinic C H318 - 1 100
Crodasinic CS30 H318 - 1 30
Crodasinic LS30 H319, H332 - 2 30
Crodasinic LS35 H315, H318, H332 2 1 35
Crodasinic LS95 H315, H318, H330 2 1 95
Crodasinic MS30 H318 - 1 30
Crodasinic O H315, H318, H332, H400 2 1 100
Nonionic Surfactants
Ethoxylated Natural Fatty Alcohols
Brij CS12 H302, H318 - 1 100
Brij LT3 H318, H400 - 1 100
Brij LT4 H318, H400 - 1 100
Brij O10 H302, H318 - 1 100
Brij O20 H318 - 1 100
Brij S2 H400, H411 - - 100
Brij S10 H318 - 1 100
Brij L4 H318 - 1 100
NatSurf 125 H318, H400, H412 - 1 100
NatSurf 205 H318 - 1 100
Alkoxylated Synthetic Alcohols
Synperonic 13/5 H318 - 1 100
Synperonic 13/6 H318 - 1 100
Synperonic 13/6.5 H302, H318 - 1 100
Hazard Category
Product Name Hazard Code(s) Active Content (% approx.)
Skin Eye
Synperonic 13/7-85 H302, H318 - 1 100
Synperonic 13/8 H302, H318 - 1 100
Synperonic 13/9 H302, H318 - 1 100
Synperonic 13/10 H302, H318 - 1 100
Synperonic 13/12 H302, H318 - 1 100
Synperonic 91/2.5 H318 - 1 100
Synperonic 91/5 H318 - 1 100
Synperonic 91/6 H302, H319 - 2 100
Synperonic 91/8 H302, H318 - 1 100
Synperonic 91/10 H302, H318 - 1 100
Synperonic A2 H318, H400 - 1 100
Synperonic A7L H315, H319, H400 2 2 100
Synperonic A11 H302, H318 - 1 100
Synperonic LF/26 H400 - - 100
Synperonic NCA 810 H315 2 - 100
Synperonic NCA 850 H318 - 1 100
Polymeric Surfactants
Hypermer™ LP1 H315 2 - 100
Waxes
Cosmowax™ D H302, H318 - 1 100
Crodex™ N H318 - 1 100
= will result in material carrying the “Exclamation mark” hazard symbol
= will result in material carrying the “Corrosive” hazard symbol
Other Non-classified Products
Table 6: Remaining products that currently carry no hazard classification

Performance Additives Coronet™ Lanolin
Cirrasol 900XP Fluilan™
Cirrasol 910XS Medilan™
Cirrasol 920XR Esters and Oils
Cirrasol PP842 Crodamazon™ Andiroba
Cirrasol PP844 Crodamazon Babacu
Crodasoft™ TBS Crodamazon Castanha do Brazil
Crodasoft TSW Crodamazon Cupuaçu
Crodasoft TZ Crodamazon Maracuja
Speciality Proteins and Protein Derivatives Crodamazon Murumuru
Coltide Cashmere Crodamazon Pequi
Coltide Cotton Crodamol™ CAP
Coltide (H) Wheat Crodamol CP
Coltide HPVP Crodamol GTCC
Coltide Silk Crodamol IPM
Botanical Extracts Crodamol IPP
Cleanliness Crodamol MM
Crodarom™ Eucalyptus Crodamol OS
Crodarom Green Tea GL Crodamol PTC
Phytofleur Water Lily NP Crodamol SS
Freshness Cropure™ Avocado
Crodarom Apple EC Cropure Babassu
Phytexcell Cucumber Cropure Borage
Fruitliquid Orange GL Cropure Cupuaçu
Exotic Dreams Cropure Evening Primrose
Crodarom Blue Lotus GL Cropure Meadowfoam
Crodarom Purple Orchid Cropure Olive
Phytofleur Japanese Cherry Cropure Safflower
Shine Cropure Sweet Almond
Crodarom Amethyst Cropure Wheatgerm
Crodarom Rock Crystal Supermol™ L
Pearl Extract Fatty Alcohols
Mildness Crodacol™ C90
Sweet Almond Extract PS Crodacol CS50
Camomile Flower Extract EC Crodacol CS90
Crodarom Nordic Cotton Crodacol S95
Protection Novol™
Crodarom Sandalwood Prisorine 3515
Phytexcell Echinacea PEG
Phytexcell St John’s Wort Renex™ PEG 1500
Lanolin and Derivatives Renex PEG 2000
Acylan™ Renex PEG 6000
Corona™ 8 & 9 Renex PEG 12000
Waxes Syncrowax ERLC
Polawax™ GP200 Syncrowax HGLC
Polawax NF Syncrowax HRC
Syncrowax™ BB4
Non-warranty
The information in this publication is believed to be accurate and is given in good faith, but no representation or warranty as to its completeness or accuracy is
made. Suggestions for uses or applications are only opinions. Users are responsible for determining the suitability of these products for their own particular
purpose. No representation or warranty, expressed or implied, is made with respect to information or products including, without limitation, warranties of
merchantability, fitness for a particular purpose, non-infringement of any third party patent or other intellectual property rights including, without limit, copyright,
trademark and designs. Any trademarks identified herein are trademarks of the Croda group of companies. Information correct at the time of writing, this can
change with new test data so confirm with current MSDS.
©2015 Croda Europe Ltd

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Classification, Labelling

and Packaging (CLP)

CLP and mixtures

New Concentration Thresholds

Generic Concentration Limits Before Hazard Labelling Required

Hazard Symbol No symbol required

Generic Concentration Limits Before Hazard Labelling Required

Hazard Symbol No symbol required

Table 3: Hazard codes and their respective statements and symbols

Hazard Code Hazard Statement Hazard Symbol

H314 Causes severe skin burns and eye damage

H315 Causes skin irritation

H318 Causes serious eye damage

H319 Causes serious eye irritation

Other Associated Hazards

H302 Harmful if swallowed

H330 Fatal if inhaled

H332 Harmful if inhaled

H400 Very toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects

H412 Harmful to aquatic life with long lasting effects

= will result in material carrying the “Exclamation mark” hazard symbol

= will result in material carrying the “Corrosive” hazard symbol

Current Non-classified Products – Page 4

Current Classified Products – Pages 5 & 6

Other Non-classified Products – Pages 7 & 8

Current Non-classified Products

= will result in material carrying the “Exclamation mark” hazard symbol

= will result in material carrying the “Corrosive” hazard symbol

Table 6: Remaining products that currently carry no hazard classification

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