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HELIOS EDUCORE 1

TEST SERIES JEE-2018


JEE-MAIN
Topic : Stoichiometry & Atomic Structure

Time : 90 Min Max. Mark : 60

* +3 for correct and –1 for incorrect. BEST OF LUCK

1. If two samples of 2 mole ferrous oxalate are treated separately with

(i) Acidic KMnO4 and moles of KMnO4 used are x

(ii) Acidic K2Cr2O7 and moles of K2Cr2O7 used are y

Then correct is about the moles of KMnO4 and K2Cr2O7


(a) x > y (b) y > x (c) x = y (d) y = x

2. If 2 moles of Ba(OH)2 reacts with 2 moles of H3PO4 then moles of product


Ba3(PO4)2 formed are
(a) 21 (b) 7 (c) 6 (d) 14

3. The atomic spectrum of Li+2-ion arises due to the transition of an electron from
n2 to n1. If n1 + n2 = 4 and (n2 – n1) = 2, find the wavelength of 3rd line of this
series in Li+2-ion ?
(a) 1.08 nm (b) 10.8 nm (c) 1080 nm (d) none

4. Find out moles of acidic KMnO4 are used to oxidise 1 mole of Fe(CNS)2 to Fe+3,
NO2–, SO3, CO2
(a) 0.2 (b) 5.8 (c) 1 (d) None of these

5. Which is more (by weight)


(a) 2240 ml O2 at NTP (b) 40 g H2
(c) 400 amu He (d) 1 mole CH4

6. Which has maximum number of atoms ?


(a) 2 mole S8 (b) 6 mole CH4
(c) 44.8 of CO2 at STP (d) 0.80 g O2
HELIOS EDUCORE 2

7. Which is containing same % of carbon as in HCHO


(I) CH3COOH (II) C6H12O6

COOH
(III) CH3CHO (IV)
COOH
(a) I, II (b) III (c) II, III (d) III, IV
e2
8. If an electron is moving in an orbit with total energy U = − r is radius of the
r
orbit then find out speed of the electron
e e e 2 2e
e
(a) (b) (c) (d)
mr mr r m mr

9. If an electron is moving in an orbit of He+ then which is not correct for this :
(a) pr = 4l (b) 2pr = l (c) 4pr = l (d) 2pr = 5l

10. Consider the following statements


I : The spin angular momentum of the electron is constant and cannot be changed
3h
II : For spin = +1/2, spin angular momentum is

III : Spin angular momentum is a vector quantity and can have only two orientations
relative to a chosen axis.
Of these the correct statements are :
(a) I, II (b) II, III (c) I, III (d) I, II, III

11. Highest electron probability in 1s orbital exists at a point in the vicinity of


(a) spherical nodes (b) circumference (c) nucleus (d) plane

12. Consider the following statements


I : | y |2 is a measure of electron density at a point in an atom.
II : Radial probability function (= 4pr2R2) gives the probability of finding the
electron at a distance r (atomic radius) from the nucleus regardless of direction.
III : The shape of an orbital is defined as a surface of constant probability density
that encloses some large fraction of the probability of finding the electron.
Select the correct statement(s).
(a) I, II (b) II, III (c) I, III (d) I, II, III

13. For Balmer series in the spectrum of atomic hydrogen, the wave number of each
 1 1
line is given by v = R H  2 − 2  where, RH is a constant and n1 and n2 are
 n1 n2 
integers.
HELIOS EDUCORE 3

Which of the following statement(s) is (are) correct ?


I. As wavelength decreases, the lines in the series converge.
II. The integer n1 is equal to 2.
III. The ionisation energy of hydrogen can be calculated from the wave number of
these lines.
IV. The lines of longest wavelength corresponds to n2 = 3.
(a) I, II and III (b) II, III and IV (c) I, II and IV (d) II and IV

14. In the following reaction,


MnO2 + 4HCl → MnCl2 + 2H2O + Cl2
2 moles of MnO2 reacts with 4 moles of HCl to form 11.2 L Cl2 at STP. Thus, per
cent yield of Cl2 is
(a) 25% (b) 50% (c) 100% (d) 75%

15. MnO2 + 2KClO3 → K2MnO4 + Cl2 + 2O2


Cl2 + K2MnO4 → 2KCl + MnO2 + O2
Each reaction takes place to the extent of 50%. 11.2 L of O2 at STP is obtained
from KClO3 using
(a) 0.67 mol (b) 1.12 mol (c) 1.33 mol (d) 2.66 mol

16. All the oxygen in a 0.5434 g sample of a pure oxide of iron is removed by reduction
in a stream of H2. The loss in weight is 0.1210 g. Hence, formula of the iron oxide
is (Fe = 56)
(a) FeO (b) Fe2O3 (c) Fe3O4 (d) FeO2

17. A bivalent metal has 37.2 equivalent weight. The molecular weight of its chloride
tis
(a) 216.6 (b) 148.8 (c) 145.4 (d) 172.8

18. Certain compound has the molecular formula X4O6 having 57.2% X. Thus
1. atomic mass of X is 32 2. X may contain five valence electrons
3. X is an electro-positive metal 4. X can be a non-metal
(a) 1, 2, 3 (b) 1, 2, 4 (c) 1, 3, 4 (d) 2, 3, 4

19. Find out equivalent weight of K3CrO8 converting into Cr2O3 (M = molecular
weight of K3CrO8)
(a) M (b) M/3 (c) M/2 (d) M/10

20. The ionisation energy of hydrogen is 13.6 eV and the first ionisation energy of
helium is 24.6 eV. What is enthalpy change of the following process ?
He2+(g) + 2e– → He(g)
(a) –13.6 eV (b) –24.6 eV (c) –79.0 eV (d) –38.2 eV

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