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2. The ratio of emission of these rays can neither be increased nor be decreased by a change in temperature,
pressure, environment, or concentration. The spontaneous emission of the rays remains unchanged either
in extreme cold or at high temperature, in sunlight, or even in the dark.
3. Radioactivity is a nuclear phenomenon. It is dependent upon the nuclear particles. It is an atomic
phenomenon.
4. The radioactive process is governed by the law of radioactive decay, which states that the quantity of a
radioactive element which disintegrates in unit time is directly proportional to the amount of radioactive
element present at that instant.
6. The radiation emitted by natural radioactive substance consists of 3 types of rays-alpha, beta, and gamma
rays.
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Theory of Radioactive Disintegration
The mass number, atomic number, and other properties of the daughter elements are controlled by the
emission of only and particles. Loss of -rays does not affect these properties.
Loss of -Particle
Loss of one -particle causes a decrease of 4 units of mass number and 2 units of atomic number i.e., the
daughter element will have mass number less by 4 units and atomic number less by 2 units than its parent
element.
226
E.g.,
88 Ra 86 Rn 222 + 2 He4 (-particle)
Loss of -particle
When a radioactive element emits a -particle, no change in atomic mass of the daughter element is
observed, since the mass of electron (-particle) is negligible. But the emission causes an increase of one
unit in atomic number.
234
E.g,. 90 Th 91Pa 234 + 1e0
Disintegration Series
According to the theory of radioactive disintegration, radio elements emit or particles (but never and
simultaneously) until a non-radioactive stable isotope is formed. Most of the natural radioactive elements
exist in nature as radioactive isotopes. All the known species belong to one of three definite chains of
successive decays. These chains constitute the radioactive families. Three such radioactive disintegration
series have been recorded in nature. These are
1. Uranium series (4n + 2)
2. Actinium series (4n + 3) and
3. Thorium series (4n)
The three series are sometimes known as the 4n (Thorium), 4n + 2 (Uranium) and 4n + 3 (Actinium) series
as the mass numbers of the particular series are either divisible by 4 or divisible by 4 with remainders of 2
and 3.
237 209
2. 4n + 1 (Neptunium) series 93 Np 83 Bi 7 4
238 206
3. 4n + 2 (Uranium) series 92 U 82 Pb 8 6
227 207
4. 4n + 3 (Actinium) series 89 Ac 82 Pb 5 3
The (4n + 1) i.e., neptunium series is observed only with certain artificially radioactive elements whereas
the rest three are natural series. The end product in (4n + 1) series is bismuth but in the other three series
a stable isotope of lead is the end product. (4n + 1) series actually starts from plutonium but neptunium is
the longest lived element of this series and so it is known as neptunium series.
Half-Life Period
0.693
t1/2 =
Average or Mean Life Period ()
Average life is the reciprocal of decay constant.
0.693 1
t1/ 2 and
So, the average life period
1 t
1/ 2 1.44 t1/2
0.693
The average life of a radioactive element is 1.44 times greater than its half-life period.
Units of Radioactivity
The rate of disintegration is expressed as the number of disintegrations taking place per second, that is,
the number of atoms which split up in one second.
1 curie (C) = 3.7 1010 dps
[dps = disintegration per second]
1 millicurie (mc) = 3.7 107 dps
1 microcurie (c) = 3.7 104 dps
1 Rutherford (rd) = 106 dps
The S.I unit of radioactivity is Becquerrel (Bq).
(Bq) = 1 disintegration per second
Nuclei with a total number of 2, 8, 20, 50, 82 or 126 protons or neutrons have been found to be particularly
stable than the nuclei in their vicinity in the periodic table. These numbers are called magic numbers.
Nuclei having the number of protons or neutrons just above the magic numbers are less stable and hence
these nuclei may emit some particles to attain the magic numbers.
Nuclei having even number of protons and neutrons are more stable and hence more abundant in nature
than those with odd number of protons and neutrons.
The region within this steep graph where all stable nuclei (non radioactive elements) lie is known as zone
or belt of stability. The majority of radioactive isotopes lie outside this belt.
(a) It has been observed that for light elements of atomic number upto 20, n/p ratio is 1.0.
E.g., 20Ca40 contains 20 protons and 20 neutrons (n/p = 1).
(b) If the n/p ratio of a nucleus exceeds 1.5, the nucleus becomes unstable and emits or rays and attains
stability by adjusting its n/p ratio below 1.5.
(c) If the (n/p) ratio of a nucleus occurs below or above the belt of stability, the nucleus will be
unstable and would disintegrate in such a way so as to approach the actual n/p plot. Two cases of radioactive
decay are considered below.
n1 H1 + e0
0 1 –1
neutrons proton -particle (electron)
Thus, a radio iodine of mass number 133 of n/p ratio 1.51 emits a -particle and attains stability.
133 133 0
53I 54Xe + –1e
Both the modes of decay decrease the number of protons and increase the number of neutrons.
Thus
(a) Sodium-20 or Nitrogen-13 of very low n/p ratio suffer positron emission.
20 20 0
11Na 10Na + +1e
Positron
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13 13 0
7N 6C + +1 e
(b) Rb-82 captures an electron from the K shell.
82 0 82
37Rb + –1 e 36Kr
(c) -emission occurs from the nuclei of elements having atomic number more than 83 (actinium-89).
These nuclei lie beyond the upper right edge of zone of stability. The heavy nuclei are generally -emitter.
235 231 4
92U 90 Th + 2He
-particle
232 228 4
90Th 88Ra + 2He
The daughter nuclei in the above case are not stable; they emit or -particle and by successive
disintegration finally change into non-radioactive lead.
Fission reaction.
The nucleus breaks into two or more fragments with the release of huge amount of energy
235 + 0 n1 141 92
92U 56Ba + 36Kr + 2 or 3 0n1 + 200 MeV
The neutrons in turn attack other uranium-235 nuclei, thus setting up a chain reaction.
Fusion reaction.
It involves the formation of a bigger nucleus by the fusion of nuclei of very light elements.
2 + 1 H3 4 + 0n1 + 17.8 MeV
1H 2He
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OBJECTIVE QUESTIONS
3. A radioisotope undergoes decomposition which follows two parallel paths as shown below
k1 B
k1 = 1.26 10–4 s–1
A
k2 = 3.8 10–5 s–1
k2
C
The percentage distribution of ‘B’ and ‘C’ are
(A) 80% of ‘B’ and 20% of ‘C’ (B) 76.83% ‘B’ and 23.17% ‘C’
(C) 90% ‘B’ and 10% ‘C’ (D) 60% ‘B’ and 40% ‘C’
4. An old piece of wood has 25.6% as much C14 as ordinary wood today has t1/2 of 14C is 5760 years. The
age of the wood is :
(A) 11329 y (B) 2880 y (C) 26800 y (D) 12420 y
5. If uranium (mass number 238 and atomic number 92) emits an ‘’ particle, the product respectively has
mass number and atomic number as :
(A) 236, 92 (B) 234, 90 (C) 238, 90 (D) 236, 90
7. The half-life period of a radio element is 140 days. After 560 days, 1 g of the element will reduce to :
(A) 1/2 g (B) 1/4 g (C) 1/8 g (D) 1/16 g
9. Which of the following isotopes is used in establishing the reaction mechanism of photosynthesis in plants?
(A) 12
6 C (B) 13
6 C (C) 14
6 C (D) 12 H
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12. Consider the reaction 84 Po 210 82 Pb 206 2 He 4 , and find out the position of polonium in the periodic
table. Lead belongs to group 14.
(A) 2.0 (B) 4.0 (C) 6.0 (D) 16
15. When 14
7 N is bombarded with -particles, the product formed is
(A) 9 F17 0 n1 (B) 8 O17 1 H1 (C) 8 O18 1 e0 (D) none of the above
16. When a 92 U 235 nuclide is bombarded with slow neutrons, the uranium nuclide undergoes
(A) fusion (B) fission (C) radioactive decay (D) no change
20. In the reaction 3 Li6 (?) 2 He4 13 H, the missing particle is
(A) electron (B) neutron (C) proton (D) deutron
21. How many alpha particles are emitted in the nuclear transformation :
215
84 Po 82 Pb 211 ?
(A) 0 (B) 1 (C) 2 (D) 3
22. A radioactive element has a half-life of 20 minutes. How much time should elapse before the element is
reduced to 1/8th of the original mass?
(A) 40 minutes (B) 60 minutes (C) 80 minutes (D) 160 minutes
1
23. A radioactive substance disintegrates to th of its original mass in 160 days. Its half-life period is
16
(A) 30 days (B) 40 days (C) 50 days (D) 60 days
24. What is the half-life of a radioactive substance, if 87.5 % of a given amount of substance disintegrates in 40
minutes?
(A) 10 minutes (B) 20 minutes
(C) 160 minutes (D) 13 minutes and 20 seconds
(A) 14
6 C (B) 18
8 O (C) 92 U 235 (D) 56 Ba141
28. The atomic mass and atomic number of lead are 208 and 82 respectively. The atomic mass and atomic
number of bismuth are 209 and 83 respectively. The ratio of neutrons to protons is
(A) higher in lead (B) higher in bismuth (C) same in both (D) cannot be obtained
40 40
29. 20 Ca and 19 K are
(A) isomers (B) isotopes (C) isotones (D) isobars
32. If 2.0 g of a radioactive isotope has a half-life of 20 hours, the half life of 0.5 g of the same substance is
(A) 20 h (B) 80 h (C) 5 h (D) 10 h
238
34. The nucleus resulting from 92 U after successive loss of two alpha and four beta particles is
(A) the decay rate of 6 C14 is studied (B) the rate of accumulation of 6 C14 is studied
(C) the rate of formation of 6 C12 is studied (D) the rate of formation of 6 C13 is studied
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39. Starting with 10 g of a radioactive substance 0.1 g is left after 10 days. The disintegration constant is
(A) 0.92 12 day–1 (B) 0.4606 day–1 (C) 100 day–1 (D) 0.001 day–1
40. If three-fourth quantity of a radioactive substance disintegrates in 2 hours, its half life will be
(A) one hour (B) 45 minutes (C) 30 minutes (D) 15 minutes
41. A certain nuclide has a half-life period of 30 min. If a sample containing 600 atoms is allowed to decay for
90 minutes in a vessel, how many atoms will be left in the vessel?
(A) 200 atoms (B) 450 atoms (C) 75 atoms (D) 150 atoms
1
42. The half-life period of a radioelement is 30 min. th of the original quantity of the element will remain
16
unchanged after
(A) one hour (B) sixteen hours (C) four hours (D) two hours
43. The activity of a radio nuclide (X 100) is 6.023 curie at a time ‘t’. If the disintegration constant is
3.7 104 sec–1, the mass of ‘X’ after ‘t’ seconds is
(A) 10–3 g (B) 10–6 g (C) 10–14 g (D) 10–15 g
44. The half-life period of polonium is 140 days. If one starts with 1.0 g of polonium, 75% of it will have undergone
disintegration in
(A) 420 days (B) 280 days (C) 105 days (D) 35 days
47. In the nuclear reaction 238 206 The number of and particles emitted are–
92 U 82 Pb
49. Element ZMA emits one (alpha) particle followed by two (beta) particles. Which of the following is daughter
element ?
(A) Z–2MA–4 (B) Z–2MA (C) ZMA–4 (D) Z+2MA–4
50. -emission is caused by the transformation of one neutron into a proton. This results in the formation of a
new element having –
(A) Nuclear charge higher by 1 unit (B) Nuclear charge lower by 1 unit
(C) Same nuclear charge (D) None of these
51. What are the and particles are emitted in the nuclear reaction 90Th228 83Bi212
(A) Four alpha and one beta (B) Three alpha and seven beta
(C) Eight alpha and one beta (D) One alpha and four beta
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52. In the decay series
A –
B C D
– –
53. A radioactive element has atomic mass 90 amu and a half-life of 28 years. The number of disintegrations
per second per gm of the element is–
(A) 5.24 × 1010 (B) 5.24 × 108 (C) 5.24 × 10–10 (D) 5.24 × 1012
54. If 8.0 g of a radioactive isotope has a half life of 10 h, the half-life of 2.2 g of the same substance is –
(A) 2.6 h (B) 5 h (C) 10 h (D) 40 h
55. If the amount of radioactive substance is increases three times, the number of disintegrating atoms per
unit time will be–
(A) Doubled (B) One - third (C) Triple (D) Uncharged
56. A human body required the 0.01 µ activity of radioactive substance after 24 hours. Half life of adioactive
is 6 hours. Then injection of maximum activity of radioactive substance that can be injected :
(A) 0.08 (B) 0.04 (C) 0.16 (D) 0.32
57. An old sample of wood from an archaeological excavation was found to have a radioactivity of about
8.8 counts per minute due to 14C (t1/2 = 5700 years) as against 15.3 counts per minute for that of a freshly
cut piece of wood. The age of the old sample of wood is nearly–
(A) 9000 years (B) 7000 years (C) 4500 years (D) 2500 years
61. 1 mole of an -emitting nuclide zXA(t1/2 = 10 hours) was placed in a sealed container. The time required
for the accumulation of 4.52 × 1023 helium atoms in the container is–
(A) 4.52 hrs. (B) 9.40 hrs. (C) 10.0 hrs. (D) 20.0 hrs.
63. Which one of the following particles is used to bombarded 13Al28 to give 15P31 and a neutron–
(A) 1H2 (B) (C) (D)
(A) 11 H (B) 1
0n (C) (D) 10 e
66. The activity of radioactive nuclide (X100) is 6.023 Curie. If its disintegration constant is 3.7 × 104 sec–1, the
mass of X is–
(A) 10–3 g (B) 10–15 g (C) 10–6 g (D) 10–14 g
69. 232 decays to 208 through a number of and emissions. Which of the following is true ?
90 Th 82 Pb
(A) Number of -particles emitted is 8 (B) Number of -particles emitted is 6
(C) Number of -particles emitted is 8 (D) Number of -particles emitted is 6.
71. A radioactive nuclide emits one -particle and two -particles, in succession. The daughter nuclide formed
has–
(A) same number of protons as the parent nuclide
(B) same number of nucleons as the parent nuclide
(C) mass number less by four than the parent nuclide
(D) same number of neutrons as the parent nuclide
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True/False Type Questions
73. In the reaction, 7 7 1
3 Li + Z 4 Be + 0n the bombarding particle Z is deutron.
75. When an alkaline earth element emits an-particles, the daughter element formed belongs to group 18.
76. A radioactive element has decay constant of 6.93 × 10–3 s–1. Its half-life is ...... minutes.
82. The activity of 1 g of radium is 0.5 curie. Calculate the half-life period of radium and the time required for the
decay of radium from 2.0 g to 0.25 g.
83. What mass of 14C isotope will have an activity equal to one curie? t1/2 of 14C is 5730 years.
A-4
84. A certain radioisotope A (t = 10 days) decays to give
Z X 1/2
YZ-2 . If 1.0 g atom of X A
Z is kept in a sealed
vessel, how much helium will collect in 20 days?
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232 208
85. In nature a decay chain series starts with Th 90 and terminates at Pb82 . A thorium ore sample was found
to contain 8 10–5 mL of helium at STP and 5 10–7 g of 232Th. Find the age of the ore sample, assuming
the source of helium to be only due to decay of 232Th. Also, assume complete retention of He within the ore.
(t1/2 of 232Th = 1.39 1010 y)
88. 227AC has a half-life of 22.0 years w.r.t. radioactive decay. The decay follows two parallel paths. One leads
to 227Th and the other to 223Fr. The percentage yield of these two daughter nuclides are 2.0 and 98.0
respectively. What are the decay constants for each separate paths?
2. A positron is emitted from 23 . The ratio of the atomic mass and atomic number of the resulting
11 Na
nuclide is : [IIT-2007]
(A) 22/10 (B) 22/11 (C) 23/10 (D) 23/12
Passage
Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of
14C by neutron capture in the upper atmosphere 14 1 14
6 C 1 p1 ,
14
7 N 0 n
C is absorbed by living
organisms during photosynthesis. The 14C content is constant in living organism once the plant or animal
dies, the uptake of carbon dioxide by it ceases and the level of 14C in the dead being, falls due to the decay
which 14C undergoes 14 N . The half life period of 14C is 5770 years. The decay constant () can be
6 C
.693
calculated by using the following formula –
t 1 / 2 . The comparison of the activity of the dead matter with
that of the carbon still in circulation enables measurement of the period of the isolation of the material from the
living cycle. The method however, ceases to be accurated over periods longer than 30,000 years. The proportion
of 14C to 12C in living matter is 1 : 1012. [IIT-2006]
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4. What should be the age of fossil for meaningful determination of its age ?
(A) 6 years (B) 6000 years
(C) 60,000 years (D) It can be used to calculate any age
5. A nuclear explosion has taken place leading to increase in concentration of 14C in nearby areas. 14C
concentration is C1 in nearby areas and C2 in areas far away. If the age of the fossil is determined to be
T1 and T2 at the places respectively then :
1 C1
(A) The age of the fossil will increase at the place where explosion has taken place and T1 – T2 = n
C2
(B) The age of the fossil will decrease at the place where explosion has taken place and T1 – T2 =
1 C1
n
C2
(C) The age of fossil will be determined to be same.
T1 C1
(D)
T2 C 2
6. The total number of and particles emitted in the nuclear reaction 238 214 is. [IIT-2009]
92 U 82 Pb
235 142 90
7. The number of neutrons emitted when 92 U undergoes controlled nuclear fission to 54 Xe and 38Sr is -
[IIT-2010]
8. The nuclidic ratio of 1H3 to 1H1 in a sample of water is 8.0 × 10–18: 1. Tritium undergoes decay with a half life
period of 12.3 year. How many tritium atoms would 10.0 g of such a sample contains 40 year after the
original sample is collected ? [IIT-1992]
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ANSWER KEY
EXERCISE # 1
1. (A) 2. (C) 3. (B) 4. (A) 5. (B) 6. (D) 7. (D)
8. (B) 9. (C) 10. (B) 11. (B) 12. (D) 13. (D) 14. (B)
15. (B) 16. (B) 17. (C) 18. (C) 19. (C) 20. (B) 21. (B)
22. (B) 23. (B) 24. (D) 25. (A) 26. (B) 27. (B) 28. (A)
29. (C) 30. (A) 31. (D) 32. (A) 33. (B) 34. (D) 35. (D)
36. (C) 37. (A) 38. (C) 39. (B) 40. (A) 41. (C) 42. (D)
43. (D) 44. (B) 45. (D) 46. (C) 47. (D) 48. (D) 49. (C)
50. (A) 51. (A) 52. (C) 53. (D) 54. (C) 55. (C) 56. (C)
57. (C) 58. (A) 59. (B) 60. (C) 61. (D) 62. (B) 63. (C)
64. (B) 65. (C) 66. (B) 67. (A) 68. (CD) 69. (BD) 70. (AB)
71. (AC) 72. (BCD) 73. False 74. True 75. True 76. 1.67
3
82. 3 3164 = 9492 years 82. 0.2244 g 83. 16,800 cm3
4
84. 4.89 × 1010 y 85. 4224.47 years 86. 500 dis. per second
EXERCISE # 2