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rA = MB rate of effusion/diffusion
rB MA
dA = MB distance travelled
dB MA
tA = MB time of effusion/diffusion
tB M A
Exercises:
1. A 2.2 x 10-4 mol N2(g) effuses through a tiny hole in
105 seconds. How much H 2(g) would effuse through
the same orifice in 105 seconds?
2. A sample of Kr(g) escapes through a tiny hole in 87.3
seconds and an unknown gas requires 42.9 seconds
under identical conditions. What is the molar mass
of the unknown gas?
Exercise:
1. Use the Van der Waals Equation to calculate the
pressure exerted by 1.00 mol Cl 2(g) when it is
confined to a volume of 2.00 L at 273.0 K (a = 6.49
L2-atm/mol2; b = 0.0562 L/mol)