

C
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JEE ADVANCE- 2016 PAPER - 1 22- MAY-2016

PART II - CHEMISTRY
SECTION - 1 (Maximum Marks : 15)
(Only One Correct TYPE)
This section contains 5 questions.
Each question has four choices (A), (B), (C) and (D), out of which ONLY ONE are correct.
19. P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal
thickness, dr, at a distance r from the nucleus. The volume of this shell is 4rr2dr. The qualitative sketch
of the dependence of P on r is :

P P P P

(A) (B) (C) (D)

O r O r O r O r

19. (C) Variation of radial probability function with distance r from the nucleus is given by :

20. One mole of an ideal gas at 300 K in thermal contact with surroundings expands isothermally from 1.0
L to 2.0 L against a constant pressure of 3.0 atm. In this process, the change in entropy of surroundings
(Ssurr) in JK–1 is
(A) 5.763 (B) 1.013 (C) – 1.013 (D) – 5.763
20. (C) W = – P (V2 – V1) = – 3 × (2 – 1) = – 3 L atm
 Q = – W = 3 L-atm = heat gained by system.
Heat lost by surrounding = – 3 L.atm
= – 3 × 101.3 J
 S surrdounding = {(– 3 × 101.3) / 300 } = – 1.013 J K–1

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 1 - www. prernaclasses.com
21. Among [Ni (CO)4], [ NiCl4 ]2–, [Co(NH3)4Cl2]Cl, Na3[CoF6], Na2O2 and CsO2, the total number of
paramagnetic compounds is
(A) 2 (B) 3 (C) 4 (D) 5


21. (B) [ NiCl4 ]2– 3d8 ; paramagnetic
[Ni (CO)4] sp3; diamagnetic

C
[Co(NH3)4Cl2]Cl is low spin complex, diamagnetic
Na3[CoF6] 3d5 ; paramagnetic
peroxide diamagnetic
superoxide paramagnetic.
22. The increasing order of atomic radii of the following Group 13 elements is
(A) Al < Ga < In < Tl (B) Ga < Al < In < Tl
(C) Al < In <Ga < Tl (D) Al < Ga < Tl < ln
22. (B) Al Ga In Tl
143 135 167 170 (in pm)
23. On complete hydrogenation, natural rubber produces
(A) ethylene-propylene copolymer (B) vulcanised rubber
(C) polypropylene (D) polybutylene

CH2 CH2 CH2 CH2 CH2 CH2

C=C C=C C=C
H CH3 H CH3 H CH3
23. (A) (natural rubber)
H2/catalyst

CH2 CH2 CH2 CH2 CH2

CH CH CH CH
H CH3 H CH3
(ethylene propylene copolymer)

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 2 - www. prernaclasses.com
 SECTION - 2 (Maximum Marks : 32)
(One or More Options Correct Type)
This section contains 8 multiple choice questions.


Each question has four choices (A), (B), (C) and (D), out of which ONE OR MORE are correct.

C
24. The product(s) of the following reaction sequence is(are)

NH2
i) Acetic anhydride/pyridine
ii) KBrO3/HBr
iii) H3O+,heat
ii) NaNO2/HCl,273 - 278 K
v) Cu / HBr

Br Br
Br Br Br Br
Br Br
(A) (B) (C) (D)
Br Br Br

O
O
H C CH3
NH2 N NH C CH3
(CH3CO)2O/ KBrO3/HBr
pyridine Br2
24. (B)
Br NH2 Br

1.NaNO2 / HCl H3O+/

2.Cu / HBr

Br Br

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 3 - www. prernaclasses.com
25. The correct statement(s) about the following reaction sequence is (are)
i ) O2 CHCl3 / NaOH
Cumene(C9 H 12 )   
P    Q(major)  R(minor)
ii ) H 3 O


NaOH
Q  S
PhCH 2 Br

C
(A) R is steam volatile
(B) Q gives dark violet colouration with 1% aqueous FeCl3 solution
(C) S gives yellow precipitate with 2,4-dinitrophenylhydrazine
(D) S gives dark violet colouration with 1% aqueous FeCl3 solution.
25. (BC)

CH(CH3)2 O
OH OH OH
1.O2 C H
CHCl3 /OH
2.H3O+ +
(P) (Q) (R) C
(Major) O H
(Minor)
O
OH O CH2 Ph
C H
NaOH CHO
PhCH2Br
(Q) (S)

‘Q’ has phenolic – OH group which gives positive test with FeCl3 solution. Since – CHO group is present
in S, it gives orange -red or yellow ppt. with 2,4 -DNP
26. The crystalline form of borax has
(A) tetranuclear [ B4O5(OH)4]2– unit
(B) all boron atoms in the same plane
(C) equal number of sp2 and sp3 hybridized boron atoms
(D) one terminal hydroxide per boron atom

OH sp3
B
O sp2
O
O B OH
26. (ACD) B
HO O O
B

OH

In this structure, alternate ‘B’ lie in same plane.

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 4 - www. prernaclasses.com
27. The reagent(s) that can selectively precipitate S2– from a mixtue of S2– and SO42– in aqueous solution
is (are)
(A) CuCl2 (B) BaCl2 (C) Pb(OOCCH3)2 (D) Na2[Fe(CN)5NO]


27. (A) CuCl2 forms Cus (black) ppt.
Ba2+ forms ppt. with SO42–

C
Pb2+ forms ppt. with both assuming Pb2+ is added in excess.
Na2[Fe(CN)5 (NO)] form violet coloration with S2– ion.
28. A plot of the number of neutrons (N) against the number of protons (P) of stable nuclei exhibits upward
deviation from linearity for atomic number, Z > 20. For an unstable nucleus having N/P ratio less than
1, the possible mode(s) of decay is (are)
(A)  – -decay ( emission) (B) orbital or K-electron capture
(C) neutron emission (D)  + - decay (positron emission)
28. (BD) If n / p < 1 then
i. K - electron capture occurs
 n 1
1
P  10e 01n  new ratio =    n / p
1
 p  1
ii.  + -emission occurs
 n 1
1
P  01n  10e  new ratio =    n / p
1
 p  1

29. Positive Tollen's test is observed for

H O OH
CHO Ph O
H Ph
(A) H (B) (C) (D)
H O Ph Ph

29. (ABC) Both contains – CHO group. So they will reduce Tollen’s reagent. In (C), there is -hydroxy
ketonic group but it can not tautomerise to aldehyde group. So it will not give Tollen’s reagent test.
30. The compound(s) with TWO lone pairs of electrons on the central atom is (are)
(A) BrF5 (B) ClF3 (C) XeF4 (D) SF4

Cl F F
F F F F
F Cl Xe Br S
30. (BC) F F F F F
F F F

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 5 - www. prernaclasses.com
31. According to the Arrhenius equation
(A) A high activation energy usually implies a fast reaction.
(B) rate constant increases with increase in temperature. This is due to a greater number of collisions


whose energy exceeds the activation energy.
(C) higher the magnitude of activation energy, stronger is the tempreture dependence of the rate

C
cosntant.
(D) the pre-exponential factor is a measure of the rate at which collisions occur, irrespective of their
energy.
31. (BCD) Based on COLLISION THEORY

SECTION - 3 (Maximum Marks : 32)

(SINGLE DIGIT INTEGER Type)
This section contains a group of 5 questions.
Each question, when worked out will result in one integer from 0 to 9 (both inclusive)
32. In the following monobromination reaction, the number of possible chiral products is

CH2CH2CH3
Br2 (1.0 mole)
H Br
300°C

CH3
’
(1.0 mole)
(enantionmerically pure)

Br
32. (5) 2 4 at position 1 = 1 (optically active)
1 3 5

at position 2 = 1 (inactive)
at position 3 = 2 (optically active)
at position 4 = 2 (1 active + 1 inactive)
at position 5 = 1 (1 active)
33. The mole fraction of a solule in a solution is 0.1. At 298 K, molarity of this solution is the same as its
molality. Density of this solution at 298 K is 2.0 g cm–3. The ratio of the molecular weights of the solute
 MWsolute 
and solvent,  
 MWSolvents 

33. (9) V = {(0.1 × MB + 0.9 × MA) / 2 } [ A = solvent ; B = solute]

 molarity = {(0.1 × 2 ×1000) / (0.1 × MB + 0.9 × MA) }
and molality = {(0.1 ×1000) / ( 0.9 × MA) }
 as molarity = molality  MB / MA = 9

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 6 - www. prernaclasses.com
34. The number of geometric isomers possible for the complex [ CoL 2Cl2]– (L= H2NCH2CH2O] is

Cl Cl Cl Cl Cl


O O N O O Cl N Cl N Cl
Co Co Co Co Co
34. (5)

C
N N O N N O O N O O
Cl Cl N O N

35. In neutral or faintly alkaline solution, 8 moles of permanganate anion quantitatively oxidize thiosulphate
anions to produce X moles of a sulphur containing product. The magnitude of X is
35. (6) Eq. of KMnO4 = Eq. of S2O32–
8×3=x×8
 x = 3 = number of moles of S2O32–
 number of of SO42– produced = 2 × 3 = 6.
36. The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The
absolute temperature of an ideal gas is increased 4 times and its pressure is increased 2 times, As a
result , the diffusion coefficient of this gas increases x times. The value of x is
36. (4) Diffusion coefficient   . Cavg
 ( T3/ 2 / P)
= Diffusion coeffient = (4 )3/ 2 / (2) = 4
[  T is increased 4 times and pressure is increased 2 times]

JEE Advanced 2016 (22-May-16) Question & Solutions Paper-I - 7 - www. prernaclasses.com