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IMPORTANT

Change of supplier – Safety Data Sheets

CECA SA became ARKEMA France since 1st April 2017.

Therefore, all the CECA documents are progressively being updated in the Arkema format.

In order to ensure an optimized regulatory traceability, please note that paragraph chapter
"1.3. Details of the supplier of the safety data sheet" of the attached SDS "NORUST 180"
is now erroneous.
The denomination Supplier is replaced by this one:

Supplier ARKEMA
420 rue d’Estienne d'Orves
92705 Colombes Cedex, FRANCE
Phone: +33 (0)1 49 00 80 80
Fax: +33 (0)1 49 00 83 96
e-mail: ceca.fds@arkema.com
http://www.arkema.com

Please consider the present SDS applicable as such until an updated version will be available.

We would like to apologize for the inconvenience and remain at your disposal, should you
need further information.

ARKEMA France
420 rue d’Estienne d'Orves Phone: +33 (0)1 49 00 80 80
92705 Colombes Cedex, France Fax: +33 (0)1 49 00 83 96

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Product: NORUST 180 Page: 1 / 9

SDS No.: 700159-005 (Version 1.1 ) Date 28.08.2014 (Cancel and replace : 12.05.2014)

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the product

Identification of the mixture: NORUST 180

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : Corrosion inhibitor

Research and Development

1.3. Details of the supplier of the safety data sheet

Supplier CECA
Additifs Pétroliers et Gaziers
Adresse postale : 89 Boulevard National
92250 LA GARENNE-COLOMBES
FRANCE
Téléphone : +33 (0)1 49 00 38 00
Télécopie : +33 (0)1 49 00 38 01
http://www.cecachemicals.com
E-mail address ceca.fds@ceca.fr
1.4. Emergency telephone number

+33 1 49 00 77 77
European emergency phone number : 112 (24/7)
National Chemical Emergency Centre Tel: 01865 407 333 (24/7)

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008):

Oral: Acute toxicity, 4, H302
Dermal: Acute toxicity, 4, H312
Skin corrosion, 1B, H314
Skin sensitisation, 1, H317
Serious eye damage, 1, H318
Inhalation: Acute toxicity, 4, H332
Specific target organ toxicity - repeated exposure, 2, H373
Acute aquatic toxicity, 1, H400
Chronic aquatic toxicity, 2, H411

Classification according to EU Directives 1999/45/EC :

T; R23/24/25
Xi; R38 R41
Xi; R43
N; R51/53

Additional information:
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.

2.2. Label elements

Label elements (REGULATION (EC) No 1272/2008):

Hazardous components which must be listed on the label:

thioglycolic acid

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Quaternary ammonium salt

Hazard pictograms:

Signal word: Danger

Hazard statements:
H302 : Harmful if swallowed.
H312 : Harmful in contact with skin.
H314 : Causes severe skin burns and eye damage.
H317 : May cause an allergic skin reaction.
H332 : Harmful if inhaled.
H373 : May cause damage to organs through prolonged or repeated exposure.
H410 : Very toxic to aquatic life with long lasting effects.

Precautionary statements:
Prevention:
P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER
or doctor/ physician.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Disposal:
P501 : Dispose of contents/ container to an approved waste disposal plant.

2.3. Other hazards

Physical and chemical hazards:

No special risks of flammability or explosion.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures
1
Chemical nature of the mixture :
Preparation based on fatty amines derivatives.

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Hazardous components (according to Regulation (EC) No. 1907/2006) :

Classification Classification
1 2
Chemical Name & REACH Registration Number EC-No. CAS-No. Concentration Directive REGULATION (EC) No
67/548/EEC 1272/2008
ethyleneglycol (01-3229456816-28) 203-473-3 107-21-1 < 50 % Xn; R22 Acute Tox. 4 (Oral); H302
Xn; R48/22 STOT RE 2; H373

2-Butoxyethanol (01-2119475108-36) 203-905-0 111-76-2 < 50 % Xn; R20/21/22 Acute Tox. 4 (Oral); H302
Xi; R36/38 Acute Tox. 4 (Inhalation); H332
Acute Tox. 4 (Dermal); H312
Skin Irrit. 2; H315
Eye Irrit. 2; H319

Alkylamine derivatives 500-152-2 61791-14- < 20 % Xn; R22 Acute Tox. 4; H302
8 Xi; R36 Eye Irrit. 2; H319

Mercaptoacetic acid (01-2119494933-24) 200-677-4 68-11-1 <5% T; R23/24/25 Eye Dam. 1; H318
C; R34 Acute Tox. 3 (Oral); H301
Acute Tox. 3 (Inhalation); H331
Acute Tox. 3 (Dermal); H311
Skin Corr. 1B; H314
Aquatic Chronic 3; H412

Quaternary ammonium salt 270-325-2 68424-85- <5% Xn; R21/22 Acute Tox. 4 (Oral); H302
1 C; R34 Acute Tox. 4 (Dermal); H312
N; R50 Skin Corr. 1B; H314
Eye Dam. 1; H318
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

M-Factor Acute = 10
Hexahydro-1,3,5-trimethyl-1,3,5-triazine 203-612-8 108-74-7 <5% C; R34 Acute Tox. 4 (Oral); H302
Xn; R43 Skin Corr. 1C; H314
Xn; R48/22 Skin Sens. 1; H317
Eye Dam. 1; H318
STOT RE 2; H373

Alkylamines 262-977-1 61788-46- <1% Xn; R22-R48/22- Acute Tox. 4; H302

3 R65 STOT RE 2 (Oral); H373
C; R35 Skin Corr. 1B; H314
N; R50-R53 STOT SE 3 (Inhalation); H335
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

M-Factor Acute = 10
M-Factor Chronic = 10M-Factor
Acute = 10
M-Factor Chronic = 10
1
: See chapter 14 for Proper Shipping Name
2
:See the text of the regulation for applicable exceptions or provisions : The transition time according to REACH Regulation, Article 23, is still
not expired.
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1. & 4.2. Description of necessary first-aid measures & Most important symptoms/effects, acute and delayed:

General advice:
Under the shower: Take off immediately all contaminated clothing (including shoes).

Inhalation:
Move to fresh air. Oxygen or artificial respiration if needed. Hospitalize immediately. Delayed effects possible

Skin contact:
Wash off immediately with plenty of water. Keep under medical surveillance. Hospitalize immediately.

Eye contact:
Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.

Ingestion:

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Do not induce vomiting, rinse mouth and lips with plenty of water if the subject is conscious, then hospitalize.

4.3.Indication of immediate medical attention and special treatment needed, if necessary

Treatment: Treat symptomatically.

5. FIREFIGHTING MEASURES

5.1.Extinguishing media

Suitable extinguishing media: Foam, carbon dioxide, dry powder extinguishers., Use suitable means to extinguish
neighbouring fires.

Unsuitable extinguishing media: Water jet.

5.2. Special hazards arising from the substance or mixture:

Thermal decomposition giving flammable and toxic products:, Hydrogen sulphide, Nitrogen oxides, Sulphur oxides, Carbon oxides

5.3. Advice for firefighters:

Specific methods:
In case of fire nearby, remove exposed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Cool closed
containers exposed to fire with water spray. Ensure a system for the rapid emptying of containers.

Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus. Complete suit protecting against chemicals.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures:

Wear suitable protective clothing, gloves and eye/face protection. Ensure adequate ventilation. Evacuate area of all unnecessary personnel.

6.2. Environmental precautions:

Do not release into the environment.
Local authorities should be advised if significant spillages cannot be contained.

6.3. Methods and materials for containment and cleaning up:

Methods for cleaning up:

Keep in suitable, closed containers for disposal.

Recovery:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up to
prevent slipping hazard.

Elimination:
Dispose of in accordance with local regulations.

6.4. Reference to other sections: None.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling:

Technical measures/Precautions:
Provide water supplies, ocular fountains and showers near the point of use. Provide appropriate exhaust ventilation at machinery. Provide a
catch-tank in a bunded area.

Safe handling advice:

Open drum carefully as content may be under pressure. Strictly limit the quantities of product in the work area to those which are absolutely
necessary for the work in hand. Use only with adequate ventilation/personal protection. Do not breathe vapours/dust. Do not enter confined
spaces unless adequately ventilated. Smoking, eating and drinking should be prohibited in the application area.

Hygiene measures:
See heading 4.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.

7.2. Conditions for safe storage, including any incompatibilities:

Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Take all
necessary measures to prevent accidentalspillages of the product from entering into drains and water courses in the event of failure of
containers or transfer systems.

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Packaging material:
Recommended: Original packaging

7.3. Specific end use(s): None.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters:

Exposure Limit Values

ethyleneglycol
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EH40 WEL 12 2011 SKIN – – particulate Can be absorbed through the skin.
EH40 WEL 12 2011 SKIN – – vapour Can be absorbed through the skin.
EH40 WEL 12 2011 STEL 40 104 vapour
EH40 WEL 12 2011 TWA – 10 particulate
EH40 WEL 12 2011 TWA 20 52 vapour
EU ELV 12 2009 STEL 40 104 Indicative value
EU ELV 12 2009 SKIN – – Can be absorbed through the skin.
EU ELV 12 2009 TWA 20 52 Indicative value
ACGIH (US) 02 2012 Ceiling – 100 Aerosol

2-Butoxyethanol
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EH40 WEL 12 2011 SKIN – – Can be absorbed through the skin.
EH40 WEL 12 2011 STEL 50 246 –
EH40 WEL 12 2011 TWA 25 123 –
EU ELV 12 2009 TWA 20 98 Indicative value
EU ELV 12 2009 STEL 50 246 Indicative value
EU ELV 12 2009 SKIN – – Can be absorbed through the skin.
ACGIH (US) 02 2012 TWA 20 – –

Mercaptoacetic acid
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EH40 WEL 12 2011 TWA 1 3,8 –
ACGIH (US) 02 2012 TWA 1 – –
ACGIH (US) 02 2012 SKIN – – Can be absorbed through the skin.

Products of decomposition:

Hydrogen sulphide

Source Date Value type Value Value Remarks

(ppm) (mg/m3)
EH40 WEL 12 2011 TWA 5 7 –
EH40 WEL 12 2011 STEL 10 14 –
EU ELV 12 2009 TWA 5 7 Indicative value
EU ELV 12 2009 STEL 10 14 Indicative value
ACGIH (US) 02 2012 TWA 1 – –
ACGIH (US) 02 2012 STEL 5 – –

Derived No Effect Level (DNEL): No data available.

Predicted No Effect Concentration: No data available.

8.2. Exposure controls:

Appropriate engineering controls: Frequently monitor and control the working atmosphere.

Personal protective equipment:

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Respiratory protection: Recommended Filter type: ABEK-filter

, In the case of vapour formation use a respirator with an approved filter.
Avoid breathing vapor or mist.
For emergency and other conditions where there may be a potential for significant exposure, use
an approved full-face positive-pressure, self-contained breathing apparatus or positive-pressure
airline with auxiliary self-contained air supply.
Hand protection: Impervious gloves

Protective gloves complying with EN 374.

Request information on glove permeation properties from the glove supplier., The suitability for a
specific workplace should be discussed with the producers of the protective gloves.
Eye/face protection: Safety glasses with side-shields conforming to EN166, Eye wash bottle with pure water
Skin and body protection: Protective suit

Environmental exposure controls: See chapter 6

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance:
Physical state (20°C): liquid
Colour: Colourless to yellow.
Odour: No data available.
Olfactory threshold: No data available.
pH: Concentration 10 %, pH ca. 5, (as aqueous solution)
Melting point/range : -40 °C (OECD Test Guideline 102)
Boiling point/boiling range: No data available.
Flash point: > 100 °C (Standard ASTM D 93)
Evaporation rate: No data available.
Flammability (solid, gas):
Flammability: Not relevant
Vapour pressure: No data available.
Vapour density: No data available.
Relative density (Water=1): 1,00 - 1,04 at 25 °C (OECD Test Guideline 109)
Water solubility: No data available.
Partition coefficient: n-octanol/water: ETHYLENEGLYCOL : log Kow : -1,36 , at 23 °C
2-BUTOXYETHANOL : log Kow : 0,81 , at 25 °C
MERCAPTOACETIC ACID : log Kow : < 1 , at 22 °C (OECD Test Guideline 107)
QUATERNARY AMMONIUM SALT : log Kow : < 2
HEXAHYDRO-1,3,5-TRIMETHYL-1,3,5-TRIAZINE : log Kow : < 3
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity, dynamic: < 40 mPa.s , at 25 °C (DIN 53019)
< 50 mPa.s , at 4 °C (DIN 53019)
Explosive properties:
Explosivity: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.
9.2. Other data: None.

10. STABILITY AND REACTIVITY

10.1. & 10.2. Reactivity & Chemical stability:

The product is stable under normal handling and storage conditions.

10.3. Possibility of hazardous reactions: No data available.

10.4. Conditions to avoid: No data available.

10.5. Incompatible materials to avoid:

Strong acids, Halogenated compounds
Strong oxidizing agents, Hydrogen peroxide, Nitric acid, Hypochlorites, Release of : sulphur dioxide

10.6. Hazardous decomposition products:

Possible formation of :, Hydrogen sulphide, Sulphur oxides, Carbon oxides, Nitrogen oxides

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11. TOXICOLOGICAL INFORMATION

All available data on this product and/or the components quoted in section 3 and/or the analogue substances/metabolites have been taken
into account for the hazard assessment.
11.1. Information on toxicological effects:

Acute toxicity:

Inhalation: According to its composition, can be considered as : Harmful if inhaled.

Acute toxicity estimate: 4.9

Ingestion: According to its composition, can be considered as : Harmful if swallowed.

Acute toxicity estimate: 600

Dermal: According to its composition, can be considered as : Harmful in contact with skin.
Acute toxicity estimate: 1900

Local effects ( Corrosion / Irritation / Serious eye damage ):

Skin contact: According to its composition, can be considered as : Causes severe skin burns and eye
damage.

Eye contact: According to its composition, can be considered as : Causes serious eye damage.

Respiratory or skin sensitisation:

Inhalation: Based on available data, the classification criteria are not met. not a respiratory sensitizer

Skin contact: According to its composition, can be considered as : May cause an allergic skin reaction.

CMR effects :

Mutagenicity: Results from tests do not lead to considering the product as genotoxic

Carcinogenicity: Based on the available data, the substance is not suspected of having carcinogenic potential

Reproductive toxicity:

Fertility: Based on the available data, the substance is not suspected of having reprotoxic potential.

Foetal development: Based on the available data, the substance is not suspected of having developmental toxicity
potential.

Specific target organ toxicity :

Single exposure :

Inhalation: Based on available data, the classification criteria are not met.

Repeated exposure: May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard: Not relevant

12. ECOLOGICAL INFORMATION

Ecotoxicology Assessment: According to its composition, can be considered as : Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. Do not dispose large quantities into the natural or aquatic
environment.

12.1. Toxicity : No data available.

12.2. Persistence and degradability :

Biodegradation (In water): There is no data available for this product.

12.3. Bioaccumulative potential :

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Bioaccumulation: There is no data available for this product.

ETHYLENEGLYCOL :
Partition coefficient: n-octanol/water: log Kow : -1,36 , at 23 °C
2-BUTOXYETHANOL :
Partition coefficient: n-octanol/water: log Kow : 0,81 , at 25 °C
MERCAPTOACETIC ACID :
Partition coefficient: n-octanol/water: log Kow : < 1 , at 22 °C (Method: OECD Test Guideline 107)
QUATERNARY AMMONIUM SALT :
Partition coefficient: n-octanol/water: log Kow : < 2
HEXAHYDRO-1,3,5-TRIMETHYL-1,3,5-TRIAZINE :
Partition coefficient: n-octanol/water: log Kow : < 3

12.4. Mobility in soil - Distribution among environmental compartments: No data available.

12.5. Results of PBT and vPvB assessment : None.

12.6. Other adverse effects:

Global warming potential (GWP): Not relevant (due to the chemical structure)

Ozone depletion potential: Not relevant (due to the chemical structure)

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment:

Disposal of product: Do not release into the natural environment or aquatic environment the pure or concentrated product.
Incinerate in suitable incineration plant, observing local authority regulations.

Disposal of packaging: Must be dumped or incinerated in accordance with local regulations.

According to the European Waste Catalogue, Waste Codes are not product specific, but application
specific. Waste codes should be assigned by the user based on the application for which the product
was used.

14. TRANSPORT INFORMATION

Sample code : 700159

UN Environmentally
Regulation
number
Proper shipping name Class Label PG
hazardous
Other information
CORROSIVE LIQUID, ACIDIC, ORGANIC, yes
ADR 3265 8 8 II
N.O.S.(THIOGLYCOLIC ACID)
ADN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 8 II yes
(THIOGLYCOLIC ACID)
RID 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 8 II yes
(THIOGLYCOLIC ACID)
IATA Cargo 3265 Corrosive liquid, acidic, organic, n.o.s. 8 8 II yes
(THIOGLYCOLIC ACID)
IATA Passenger 3265 Corrosive liquid, acidic, organic, n.o.s. 8 8 II yes
(THIOGLYCOLIC ACID)
IMDG 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 8 II Marine pollutant EmS Number: F-A, S-B
(THIOGLYCOLIC ACID) Mark: MP

15. REGULATORY INFORMATION

Safety data sheets: according to Regulation (EC) No. 1907/2006

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:

UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002

15.2. Chemical Safety Assessment: None.

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INVENTORIES:
EINECS: Conforms to
TSCA: Does not conform
AICS: Conforms to
DSL: This product contains one or several components that are not on the Canadian DSL nor NDSL lists.
ENCS (JP): Does not conform
KECI (KR): Does not conform
PICCS (PH): Conforms to
IECSC (CN): Conforms to

16. OTHER INFORMATION

Full text of R, H, EUH-phrases referred to under sections 2 and 3

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R21/22, R22 Harmful in contact with skin and if swallowed., Harmful if swallowed.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R35 Causes severe burns.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Update:

Safety datasheet sections which have been updated: Type:

12 12. ECOLOGICAL INFORMATION Additions

Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight
vPvB : very Persistent and very Bioaccumulative
PBT : Persistent, Bioaccumulative and Toxic

This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a
new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet
shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice
documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official
documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass
on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality
of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

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