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Article history: In this paper, unidirectional SiC fiber (SiCf) reinforced geopolymer composites (SiCf/geopolymer) were
Received 4 April 2016 prepared and effects of fiber contents on the microstructure and mechanical properties of the composites
Received in revised form in different directions were investigated. The XRD results showed that addition of SiCf retarded geopo-
26 April 2016
lymerization process of geopolymer matrix by weakening the typical amorphous hump. SiCf in all the
Accepted 27 April 2016
composites were well infiltrated by geopolymer matrix, but microcracks which were perpendicular to
the fiber axial direction were noted in the interface area due to the thermal shrinkage of matrix during
Keywords: the curing process. With the increases in fiber contents, although Young's modulus of the composites
SiC fiber increased continuously, flexural strength, fracture toughness and work of fracture increased at first,
Geopolymer
reached their peak values and then decreased. And when fiber content was 20 vol%, the composites
Composites
showed the highest flexural strength, fracture toughness and work of fracture, which were 14.2, 15.2 and
Mechanical properties
Fracture behavior 81.6 times as high as those of pristine geopolymer, respectively, indicating significant strengthening and
toughening effects from SiCf. Meanwhile, SiCf/geopolymer composites failed in different failure modes in
the different directions, i.e., tensile failure mode in the x direction (in-plane and perpendicular to the
fiber axial direction) and shear failure mode in the z direction (laminate lay-up direction).
& 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
1. Introduction Recently, many studies have been carried out in order to im-
prove mechanical performance and crack tolerance of geopolymer
Geopolymer is a unique three-dimensional inorganic material materials. Typically, geopolymer based composites have been de-
that offers multiple valuable properties including easy-processing veloped with the presence of second phases, including graphene
and environmentally friendly nature, low CO2 emission, low den- [15–18], nanotube [19,20], particle [21–25], epoxy [5,26–28], short
sity, higher mechanical performance and anti-permeability than fiber [29–36] and continuous fiber [25,37–41]. Among them, fibers
traditional Portland cement, high melting point (1200–1600 °C) showed the best strengthening effect. Ranjbar et al. [42] reported
[1–9]. And thus it has been considered as a promising alternative that flexural strength of 3 wt% steel fiber reinforced geopolymer
to cement in the fields of infrastructure, hazard element en- based composite was more than 3 times as high as that of neat
capsulation, and heat resistant component, among others [10–14]. geopolymer; Assaedi et al. [43] prepared flax fabric reinforced
However, like other brittle materials such as cement and ceramic, geopolymer composites, and flexural strength, compressive
neat geopolymer materials showed disadvantages of both low strength, and fracture toughness were 411.1%, 369.1% and 350.0%
mechanical performance and catastrophic fracture behavior, higher than those of pure geopolymer, respectively; Lin et al. [31]
which were the insurmountable obstacle when they were applied prepared short carbon fiber reinforced geopolymer composites,
as structural components. and improved mechanical properties together with non-brittle
failure behavior were noticeable. In our previous research [38] we
n prepared continuous carbon fiber reinforced geopolymer compo-
Corresponding authors at: Institute for Advanced Ceramics, Harbin Institute of
Technology, Harbin, China. sites. Combined with the post high-temperature treatment, the
E-mail addresses: peiganghe@hit.edu.cn (P. He), dcjia@hit.edu.cn (D. Jia). resulted composites showed comparable mechanical performance
http://dx.doi.org/10.1016/j.ceramint.2016.04.168
0272-8842/& 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i
2 P. He et al. / Ceramics International ∎ (∎∎∎∎) ∎∎∎–∎∎∎
Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i
P. He et al. / Ceramics International ∎ (∎∎∎∎) ∎∎∎–∎∎∎ 3
Fig. 2. XRD patterns of SiC fiber (a), metakaolin, geopolymer and SiCf/KGP composites (b).
(a) (b)
400 m 400 m
(c) (d)
400 m 400 m
Fig. 3. Microstructure of SiCf/KGP composites with different fiber contents: (a) 10 vol%, (b) 15 vol%, (c) 20 vol% and (d) 25 vol%.
Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i
4 P. He et al. / Ceramics International ∎ (∎∎∎∎) ∎∎∎–∎∎∎
Fig. 4. Magnified microstructure of SiCf/KGP composites: (b) and (c) correspond to the areas B and C, respectively.
200 6 6000
30 1/2
Fracture toughness,MPa· m
-2
5 Work of fracture(J·m ) 5000
)
160 25
1/2
Flexural strength (MPa)
3 3000
15
80
2 2000
10
40
1 1000
5
0 0 0
0 5 10 15 20 25 0 10 15 20 25
Fiber content (vol %) Fiber content (vol %)
Fig. 5. Flexural strength and Young's modulus of SiCf/KGP composites in x Fig. 7. Fracture toughness and work of fracture of SiCf/KGP composites.
direction.
200
180 x direction
z direction
160
Flexural strength,(MPa)
140
120
100
80
60
40
20
0
0 10 20 25
Fiber content (vol %)
Fig. 6. Flexural strength of SiCf/KGP composites in x and z direction. Fig. 8. Stress and displacement curves of SiCf/KGP composites in x direction.
than Cf/geopolymer composite prepared through similar process matrix to the fiber during crack propagation. Therefore, at higher
[47], indicating a better interfacial state in SiCf/geopolymer than fiber content of 25 vol%, the possibility of both defects in-
that in Cf/geopolymer. However, when SiC fiber content was tensification and failure in load transferring would be higher, re-
25 vol%, the flexural strength showed a 17.5% drop to 133.3 MPa, sulting in the decrease in flexural strength.
compared to that of composites with 20 vol% fiber content. In the Young's modulus of the SiCf/geopolymer composites showed a
present investigation, higher fiber content indicated higher fiber- continuing rising trend with the increase in fiber content. Young's
matrix interfacial area, where defects such as microcracks and modulus can be calculated according to the Halpin-Tsai model as
micropores would gather as shown in Fig. 4. Meanwhile, with shown in Eqs. (6) and (7), where Ec, Ef and Em were Young's
respect to SiCf, geopolymer matrix was much weaker in strength, modulus of the composites, fiber and matrix; ξ was a parameter
and there might be not enough matrix to transfer the load from related to fiber morphology. Therefore, in this investigation,
Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i
P. He et al. / Ceramics International ∎ (∎∎∎∎) ∎∎∎–∎∎∎ 5
Fig. 9. Images of bar specimens of SiCf/KGP composites in (a) x direction, (b) z direction, and (c) geopolymer matrix.
Fig. 10. Fractograph of SiCf/KGP composites in different directions. (a)–(c) x direction, (d)–(e) z direction.
Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i
6 P. He et al. / Ceramics International ∎ (∎∎∎∎) ∎∎∎–∎∎∎
modulus of SiC fiber (200 GPa) was much higher than that of geopolymer composite (SiCf/geopolymer) is prepared by a simple
matrix (8 GPa), resulting in the increase in modulus of composites ultrasonic-assisted slurry infiltration method. Effects of fiber con-
with fiber content. tent on the microstructure and mechanical properties of the
composites are studied. The results proved that with proper SiC
Ec 1 + ξηVf
= fiber content, the obtained SiCf/geopolymer composites showed
Em 1 + ξηVf (6)
greatly enhanced mechanical properties together with non-cata-
strophic fracture behavior. The main conclusions could be drawn
Ef /Em − 1 + ξηVf
η= as below:
Ef /Em + ξ (7)
Fig. 6 compared flexural strengths of SiCf/geopolymer compo- (1) The composites showed homogeneous microstructure and SiCf
sites in x and z directions. It can be noted that the composite were well infiltrated by geopolymer matrix. Meanwhile, mi-
showed anisotropic characteristic, i.e., higher flexural strength in crocracks in the interfacial area were observed, which was due
the x direction than that in z direction. But with the increase in to the thermal shrinkage of the matrix during the curing
fiber contents, the strength difference between two directions process.
decreased. In the z direction where fiber plies laid up, the gap (2) When fiber content was 20 vol%, the related composite
between two layers was the matrix-rich area, which was weak and showed the highest flexural strength, fracture toughness and
stress concentrated, leading to the strength decreasing in this di- work of fracture, which were 14.2, 15.2 and 81.6 times as high
rection. In this investigation, fiber content control was achieved as those of geopolymer matrix, respectively, indicating sig-
through applying different pressing stress. With increasing nificant strengthening and toughening effect from SiCf. All the
pressing stress, the gap between two layers (along z direction) SiCf/geopolymer composites showed non-brittle failure modes
decreased, and thus the strength difference between two direc- rather than the catastrophic failure as observed in neat geo-
tions became not evident. polymer. Meanwhile, the composites failed in tensile failure
Fig. 7 shows fracture toughness and work of fracture of mode in the x direction and shear failure mode in the z
SiCf/geopolymer composites, which showed similar trends to direction.
flexural strength. When fiber content was 20 vol%, the composite
exhibited the highest fracture toughness and work of fracture,
Acknowledgements
4.26 MPa m1/2 and 4421.4 J m 2, which were 15.2 and 81.6 times
as high as those of pristine geopolymer. The work of fracture of the
SiCf/geopolymer composites was much higher than monolithic This work was supported by the Fundamental Research Funds
ceramics such as alumina, silica, Si3N4 and ZrO2, and was com- for the Central Universities (Grant no. HITNSRIF20165), and the
parable with high-temperature sintered Cf/soda, Cf/LAS compo- National Natural Science Foundation of China (NSFC, Nos.
sites. This implied that geopolymer provides a low-cost route to 51372048, 51502052, 51321061 and 51225203).
prepare advanced composites of high reliability.
Fig. 8 shows typical stress-displacement curves of geopolymer
and SiCf/geopolymer composites. Geopolymer exhibited the brittle References
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Please cite this article as: P. He, et al., SiC fiber reinforced geopolymer composites, part 2: Continuous SiC fiber, Ceramics International
(2016), http://dx.doi.org/10.1016/j.ceramint.2016.04.168i