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Relative
stress Visc
ous Viscoelastic Elastic
1
Solid Solid
Glass
-4
10 10-2 Liquid
100 102 4
10 106
Fig. 3.1 Curves showing the differences between viscous, 108
viscoelastic and elastic materials when subjected to deformation. Time of applied deformation in seconds
Shearing
In rheology, shearing of a substance is the key to knowledge of flow
behaviour and structure. A sheared flow is achieved through flow between
parallel planes, rotational flow between coaxial cylinders where one cylinder
is stationary and the other one is rotating, telescopic flow through capillaries
and pipes, and torsional flow between parallel plates.
Shear stress is defined as
To enable study of the viscosity of a material, the shearing must induce
stationary flow of the material. The flow occurs through rearrangement and F
deformation of particles and through breaking of bonds in the structure of σyx = [Pa]
A
the material.
F = Force, N
A = Area, m2
shear rate as
dv
γ· = dγ = [1/s]
dt dy
dy
Newtonian fluids γ• y
z
Newtonian fluids are those having a constant viscosity
dependent on temperature but independent of the applied x
shear rate. One can also say that Newtonian fluids have
direct proportionality between shear stress and shear rate in Fig. 3.3 Definition of shear stress and shear rate is
laminar flow. based on shearing between parallel planes.
dv ·
σyx = η · = η·γ
dy
as which is a plot of viscosity versus shear rate, will show a straight line at a
pl gha
ti c
g
pl
nin
n
o
constant value equal to η.
Bi
sc
ke
Vi ian
on
hic
t A Newtonian fluid can therefore be defined by a single viscosity value at
σ0 ew
r-t
N a specified temperature. Water, mineral and vegetable oils and pure sucrose
ea
g
nin
Sh
Non-Newtonian fluids
Materials which cannot be defined by a single viscosity value at a specified
temperature are called non-Newtonian. The viscosity of these materials
Shear must always be stated together with a corresponding temperature and
rate γ•
shear rate. If the shear rate is changed, the viscosity will also change.
Fig. 3.4 Flow curves for Newtonian and Generally speaking, high concentration and low temperature induce or
non-Newtonian fluids.
increase non-Newtonian behaviour.
Apart from being shear-rate dependent, the viscosity of non-Newtonian
fluids may also be time-dependent, in which case the viscosity is a function
not only of the magnitude of the shear rate but also of the duration and, in
most cases, of the frequency of successive applications of shear. Non-
Viscosity η
Newtonian materials that are time independent are defined as shear-
thinning, shear-thickening or plastic. Non-Newtonian materials that are time-
g dependent are defined as thixotropic, rheopectic or anti-thixotropic.
Shear-thickenin
Bingham pl
Shear-thinning flow behaviour
astic
The viscosity of a shear-thinning fluid (also known as pseudoplastic fluid)
Newtonian decreases with increasing shear rate. Most liquid food systems belong to
this category of fluids. The shear rate dependency of the viscosity can differ
substantially between different products, and also for a given liquid,
depending on temperature and concentration. The reason for shear thinning
Shear-th flow behaviour is that an increased shear rate deforms and/or rearranges
inning
Visco particles, resulting in lower flow resistance and consequently lower viscosity.
p lastic
Typical examples of shear-thinning fluids are yoghurt, cream, juice
concentrates, and salad dressings. It should be noted that although
Shear sucrose solutions show Newtonian behaviour independent of concentration,
rate γ•
Fig. 3.5 Viscosity curves for fruit juice concentrates are always significantly non-Newtonian.
Newtonian and non-Newtonian fluids. Hence a non-Newtonian fluid like yoghurt or fruit juice concentrate being
pumped in a pipe shows decreased apparent viscosity if flow rate is
increased. This means in practice that the pressure drop of a non-
Newtonian fluid in laminar flow is not directly proportional to the flow rate as
Shear
stress
σ for Newtonian fluids in laminar flow.
n
ot
ro
pi
c
wt
o nia Shear-thickening flow behaviour
hi
x Ne The viscosity of a shear-thickening fluid increases with increasing shear rate.
t i-t
An This type of flow behaviour is generally found among suspensions of very
high concentration. A shear-thickening fluid exhibits dilatant flow behaviour,
p ic i.e. the solvent acts as a lubricant between suspended particles at low
tro
ixo shear rates but is squeezed out at higher shear rates, resulting in denser
Th
packing of the particles. Typical examples of shear-thickening systems are
wet sand and concentrated starch suspensions.
A simple but still very effective way of checking a fluid’s possible plastic Anti-thixotropic
properties is to just turn the jar upside down. If the fluid will not flow by itself
it probably has a significant yield value. If it flows by itself, but very slowly, it
probably has no yield value but a high viscosity. Information of this kind is of
vital importance to process plant design regarding the dimensions and
layout of storage and process tank outlets and pump connections. Newtonia
n
followed by the same shear rates in decreasing order. The time-dependent Fig. 3.7 Viscosity curves for
time-dependent non-Newtonian fluids.
thixotropic flow behaviour is seen from the difference between the
ascending and descending viscosity and shear stress curves. To recover its
structure, the material must rest for a certain period of time which is
characteristic for the specific material. This type of flow behaviour is shown
by all gel-forming systems. Typical examples of thixotropic fluids are
yoghurt, mayonnaise, margarine, ice cream and brush paint.
Rheopectic fluids
A rheopectic fluid can be described as a thixotropic fluid but with the
important difference that the structure of the fluid will only recover
completely if subjected to a small shear rate. This means that a rheopectic
fluid will not rebuild its structure at rest.
Anti-thixotropic fluids
An anti-thixotropic fluid can be described as a shear-thickening system, i.e. log σ log η
one where the viscosity increases with increasing shear rate, but also with Shear stress viscosity
time at a constant shear rate. As with thixotropic fluids, the flow behaviour
sl
n
pe
e
(n
(σ – σ0) = K · γ•
n
where
σ = shear stress, Pa
σ0 = yield stress, Pa
K = consistency, Pasn
γ• = shear rate, s–1
n = flow behaviour index
σ = K · γ• = η · γ•
n
For a plastic fluid, the power law equation is used in the fully generalised
form, with n < 1 for viscoplastic behaviour and n = 1 for Bingham plastic
behaviour.
For a shear-thinning or shear-thickening fluid, the power law equation
becomes:
•n
σ = K·γ
Typical data
Some typical data on shear rates, viscosities, power law constants (n and K
values), and yield stress values at around room temperature (with the
exception of molten polymers and molten glass), are shown in Table 3.1.
The unit of viscosity is Pas (Pascal second), which is equal to 1 000
mPas or 1 000 cP (centipoise). Please note also that all viscosity figures
should be regarded as examples only (around room temperature) and
should NOT be used for calculations.
Measuring equipment
The main types of viscometers are rotational and capillary. Rotational
viscometers are of the spindle, cone-plate, plate-plate or concentric cylinder
type. The latter may be of the Searle (rotating bob) or Couette (rotating cup)
type. Capillary viscometers may be of the atmospheric or pressurised type.
Generally speaking, rotational viscometers are easier to use and more
flexible than capillary viscometers. On the other hand, capillary viscometers
are more accurate at low viscosities and at high shear rates. However, for
practical use in liquid food viscometry they are less applicable due to their
sensitivity to even small particles like fruit juice fibres.
Instead, a special design of the capillary viscometer is the tubular
Measuring techniques
G (Pa) δ (°)
Viscosity measurements should always be carried out for a
representative range of shear rates and temperatures related to
G'
200 the process to be studied. The intended use of the measured data
80
should therefore be considered before measuring takes place, for
instance if the viscosity data are to be used in the design of a deep
cooler or of the heating section of a steriliser.
60
100 Due to practical limitations the maximum applicable
temperature for most viscometers is around 90 °C. At higher
G''
1/n
Q =
( n
3·n+1 ) · π · r3 ·
( r · ∆p
2·L·K )
or
n n
∆p =
( 3·n+1
n ) ( ) ·
Q
π · r3
·
2·L·K
r The parameters are:
Q = flow rate m3/s
r = duct radius m
and
∆p= pressure drop Pa
L = tube length m
γ•w =
( 3·n+1
n ) ( ·
Q
π · r3 ) γ• w = wall shear rate
n = flow behaviour index
K = consistency coefficient
s–1
Pasn
1/n
Q =
( n
4·n+2 ) ( ) 2
·w·h ·
h · ∆p
2·L·K
n n
∆p =
( 4·n+2
n ) ( ) ·
Q
w · h2
·
2·L·K
h
γ•w =
( 2·n+1
n )( ) ·
Q
w · h2
The new parameters are:
w = duct width m
h = duct height m
r·v
∆p = Kf ·
2