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ABSTRACT. The postweld heat treatment veloping best ductility and toughness steel (SS) is reported to be excellent de-
(PWHT) procedures for 17-4 PH stainless (Ref. 1). Either matching composition or spite its similarity to AISI 400 series
steel weldments of matching chemistry lower-strength filler metals are used, with martensitic stainless steels (Refs. 10, 11 ),
was optimized vis-a-vis its microstruc- the weldments of matching filler metals and it can be welded with any of the
ture prior to welding based on mi- attaining strengths approximating the usual arc, resistance or high-energy-den-
crostructural studies and room-tempera- base metal PH type. sity welding processes. Preheating (Refs.
ture mechanical properties. The 17-4 PH The martensitic PH stainless steel of 12-I 6) or PWHT is not required to pre-
stainless steel was welded in two differ- the Type 17-4 PH can be obtained with a vent cracking or restore ductility (Refs.
ent prior microstructural conditions wide range of mechanical properties by 10, 1[ ). In this material, the heat-affected
(condition A and condition H 1150) and suitable heat treatment in the tempera- zone (HAZ), immediately adjacent to the
then postweld heat treated to condition ture range 900°-1150°F (482°-621°C) fusion zone, is effectively annealed or
H900 or condition Hl150, using differ- (Refs. 2-5). This steel retains its useful softened by welding heating and cooling
ent heat treatment procedures. Mi- strength up to about 900°F, and is used in cycles (Refs. 12, 15, 17) because of the
crostructural investigations and room- different heat-treated conditions in nu- presence of retained austenite in the mi-
temperature tensile properties were de- clear, naval and aerospace applications, crostructure (Ref. 12). Hence, this mate-
termined to study the combined effects of where high strength and toughness, good rial can be welded in the aged conditions
prior microstructural and PWHT proce- fabrication characteristics and moderate without causing cracking (Refs. 11, 15),
dures. corrosion resistance are required. This as the heat of welding causes local soft-
material has a high strength-to-weight ening of the HAZ (Ref. 12). Further, weld-
Introduction ratio, and some of its typical applications ing in the solution-treated (ST) condition
include aircraft and missile fittings, fas- causes no appreciable precipitation
The precipitation-hardening (PH) teners, gears, jet engine parts, valve parts, hardening of the solution-treated struc-
stainless steels provide both strength and chemical process equipment, pump ture as the heating time during welding is
corrosion resistance. Chromium imparts shafts, paper mill equipment and nuclear too short (Refs. 12, 14, 15). For welding
corrosion resistance, and strength comes reactor components (Refs. 6-9). 17-4 PH SS, filler metals and electrodes
from precipitation hardening by submi- The weldability of 17-4 PH stainless of either matching composition or low-
croscopic precipitates on aging at ele- strength high-ductility stainless steel are
vated temperatures. This combination of generally preferred (Refs. 1, 11, 15, 16).
properties makes the PH stainless steels Weldments made with a matching filler
very popular for severe service condi- metal can be aged to strength levels com-
tions. The PH stainless steels are classi- parable to those of the base metal and are
fied by structure: martensitic, semi-
KEY WORDS
used for producing weldments with high
austenitic and austenitic. Of these the strength. If, however, a lower strength
martensitic types are most popular, while 17-4 Stainless Welds
level is permissible, austenitic stainless
the austenitic types are only used for spe- PWHT Procedure
steel weld metals can be used.
cial applications. Welding of PH stainless 17-4 PH Stainless In 17-4 PH SS, martensite which is sta-
steels is much like welding conventional Aging
ble at low temperatures, begins to trans-
austenitic and martensitic stainless 17-4 PH Weldability form to austenite at 1160°F (627°C) and
steels, and requires controlled proce- E630 Electrodes transformation is completed at 1300°F
dures to keep the heat input low for de- Martensite Matrix (704°C). With further increase in temper-
Delta Ferrite ature, the precipitates go into solution;
Retained Austenite this process being completed at 1900°F
A. K. BHADURI, S. SUJITH, G. SRINIVASAN,
P. S. GILL and S. L. M A N N A N are with Ma- Epsilon Copper (1038°C). On cooling from 1900°F, trans-
terials Development Division, Indira Gandhi formation from austenite to martensite
Center for Atomic Research, Kalpakkam, starts at 270°F (132°C) and the marten-
India.
1 5 4 - s l M A Y 1995
passes were made by the gas tungsten arc
welding (GTAW) process using AWS
E308 filler metal, and the subsequent
passes were made by the shielded metal
arc welding (SMAW) process using 17-
4PH SS electrodes conforming to AWS
Specification E630-I 6. However, during
subsequent preparation test specimen
blanks, the root region was completely
machined off to ensure that the weld
metal consistecl of only 17-4PH SS (i.e.,
only the SMAW deposit). The chemical
composition of the 17-4 PH SS base and
weld metal are given in Table I, and the
welding conditions employed for the fill
passes are listed in Table 2.
L .... ,o
The plates welded in condition A Fi,q. ~ - - Location o f transverse weld specimen blanks. All dimensions are in ram.
(subsecluently referred to as "condition A
weldments') were postweld heat treated
either to condition H900 (i.e., aging at rite was observed as stringers along the crostructure for all the conctitions con-
900°F for I h followed by air cooling) prior working direction in the unaffected tains retained austenite (lightly etched re-
using two different PWHT procedures, base metal. The martensite obtained after gions in Figs. 5-7) and retransformed
viz: I ) direct H900 and 2) ST + H900, or the solution treatment is supersaturated martensite, with the martensite (darkly
to condition H1150 using two different with copper and, on aging at 900°F cop- etched regions in Figs. 5-7) being
PWHT procedures, viz: I ) direct HI 150 per-rich precipitation occur. On overag- aged/overaged to varying degrees de-
and 2) ST + HI 150. The plates welded in ing these coherent precipitates transform pending on the PWHT. Also, the delta-
condition H1150 (subsequently referred from bcc structure to incoherent fcc ep- ferrite stringers present in the base metal
to as "condition H1150 weldments") silon-copper precipitates. During weld- become discontinuous in the HAZ in the
were either retained in the as-welded ing, in the HAZ immediately adjacent to regions near the weld interface, because
condition, or postweld heat treated to the weld metal, the martensite transforms of transformation of a part of the delta fer-
condition H1150 using two different to austenite during the heating cycle; rite in this region at the high temperatures
PWHT procedures, viz: I ) direct H 1150 during the subsequent cooling cycle, experienced during welding.
and 2) ST + H1150. A schematic of the some of this austenite transforms back to Figure 5A-B shows the microstructure
heat treatment procedures employed is martensite (called retransformed-marten- of the HAZ near the weld interface for
given in Fig. 2. site) and some of it is retained as austen- condition A weldments subjected to
Transverse weld specimen blanks ite (retained-austenite). In an earlier in- condition H900 PWHT. The HAZ mi-
with the weld located at the center were vestigation (Ref. 19), it was found that the crostructure after the direct H900 PWHT
obtained as shown in Fig. 3. These were HAZ in the as-welded condition A bead- shows nonuniformly distributecl large
metallographically polished and etched on-plate weld is comprisecl of three dif- grains (Fig. 5A), while after the ST + H900
with Fry's reagent for optical microscopic ferent microstructural zones, narnely, PWHT shows uniformly distributed
examination and determination of mi- zones of 1) retransformed martensite and smaller grains (Fig. 5B) caused by trans-
crohardness profiles across the weld in- retained austenite, 2) overaged marten- formation during the ST step.
terface and HAZ. The microhardness site, and 3) underaged martensite. In con- Overaging at 1075°F (635°C) and
measurements (in VPN) were made at in- trast, the as-welded overaged-condition above results in retransformation of a sig-
tervals of 0.25 mm (0.01 in.) using a load bead-on-plate weld is composed of al- nificant amount of the martensite to
of 500 g. Transverse weld tensile speci- most entirely heavily overaged marten- austenite, which forms predominantly
mens, as shown in Fig. 4, were machined site, i.e., Zone 2 of Ref. 19. along the martensite lath boundaries
from the specimen blanks, and three Microscopic examination showed (Ref. 20); on subsequent air cooling,
specimens per condition were tested at that near the weld interface, the HAZ mi- much of this austenite is retained in the
room temperature using a nominal strain
rate of 3.2 x 10-4S-1. The tensile proper-
ties, as well as the stress-strain behavior
of these weldments, were analyzed as a
~ T
(YP)
function of prior microstructure and
PWHT.
•
.... ,. , / / ; /Z'Z .... ....,/
i_l
.
I
HAZ HAZ r
The microstructure of the unaffected 28.6 _ _ 10.3
base metal in weldments after the condi- -i- (TYP)
tion H900 PWHT consists of a matrix of r"- /,9.2
equiaxed aged martensite, while that in
weldments after the condition H l 1 5 0
Fi,~. 4 Geometry o f transverse weld round tensile specimens. Location o f weld and
PWHTs consists of heavily overaged H A Z are shown schematically. All dimensions are in ram.
martensite. Further, in all cases, delta fer-
martensite matrix (Ref. 7), while the re- direct Hl150 PWHT - - Fig. 7B. The silon-copper precipitates. The hardness
maining is retransformed to unaged lower amount of retained austenite ob- trough in the HAZ near the weld interface
martensite (Refs. 7, 21). In fact, after 4 h served after the ST + Hl150 PWHT (Fig. obtained after the direct Hl150 PWHT
overaging at 1100° and 1150°F, respec- 7C) is due to the ST step, which trans- can be attributed to the presence of an in-
tively, about 6 and 16 vol-% retained forms a greater amount of the retained creased amount of the retained austenite
austenite is reported to be present (Ref. austenite. and nondissolution of copper-rich pre-
21). cipitates in the absence of the ST step,
Figure 6A-B shows the microstructure Microhardness Profile which almost evens out the hardness
of condition A weldments subjected to variations in the HAZ as observed after
condition Hl150 PWHT, the HAZ of Figure 8A shows the microhardness the ST + H l l 50 PWHT.
which is comprised of regions of retrans- profile across the weld interface and HAZ Figure 8C shows the microhardness
formed martensite and retained austenite for condition A weldments subjected to profile across the weld interface and
and of overaged martensite. Both the condition H900 PWHT. The formation of HAZ for the condition Hl150 weld-
PWHT procedures to condition Hl150 the hardness peak in the HAZ after the di- ments. The hardness trough in the as-
result in the formation of retained austen- rect H900 PWHT is due to aging of the welded HAZ is due to the presence of
ite in the HAZ, with its amount after the unaged region in the HAZ, i.e. ,Zone 3 of heavily overaged martensite containing
direct Hl150 PWHT (Fig. 6A) being Ref. 19. The aging process results in an coarse incoherent epsilon-copper pre-
higher than after the ST + H l l 50 PWHT increase in the hardness due to precipita- cipitates, i.e., Zone 2 of Ref. 19. The ef-
-- Fig. 6B. The reduced amount of re- tion of coherent copper-rich precipitates. fect of welding induced overaging in the
tained austenite present after the ST + On the other hand, the ST step in the ST as-welded HAZ decreases (i.e., the hard-
Hl150 PWHT is due to transformation + H900 PWHT results in dissolution of ness increases) with increasing distance
during the ST step. the copper-rich precipitates, thereby ef- from the weld interface; the initial dip in
Figure 7A-C shows the microstruc- fectively evening out almost all the hard- hardness near the weld interface can be
ture of condition H1150 weldments, the ness variation of the HAZ. attributed to the retained-austenite
HAZ of which is also comprised of re- Figure 8B shows the microhardness formed and the complete/partial dissolu-
gions of retransformed martensite and re- profile across the weld interface and tion of coarse epsilon-copper precipi-
tained austenite and of overaged marten- HAZ for condition A weldments sub- tates in the HAZ during welding interfer-
site. In all the cases, retained austenite is jected to condition Hl150 PWHT. Both ing with the overaging process• The
present in the HAZ in varying degrees; its the PWHT procedures overage the HAZ; direct Hl150 PWHT results in partial re-
amount being lowest in the as-welded the overaging process involving forma- covery of hardness near the weld inter-
condition (Fig. 7A) and highest after the tion and coarsening of incoherent ep- face due to reprecipitation of incoherent
F / g6.- -
Microstructure o f
H A Z in condition
A weldments.
A - - After direct
H l 1 5 0 PWHT;
B -- after ST +
H 1 1 5 0 PWHT.
i
ii
epsilon-copper precipitates in this re- tensile properties determined for the base RA values for the weldment subjected to
gion, where these were likely to have metal in conditions H900 and H l l 50 are the ST + H900 PWHT are higher. Hence,
been completely dissolved due to more also presented in Table 3 for comparison. for better tensile properties of condition
pronounced effect of heating during For condition A weldments subjected A weldments for use in condition H900,
welding. However, the direct Hl150 to condition H900 PWHT, both the the ST + H900 PWHT procedure is
PWHT does not have any significant ef- PWHT procedures result in adequate preferable to the direct H900 PWHT pro-
fect on the hardness of the as-welded yield strength (YS) and ultimate tensile ced u re.
HAZ farther away from the weld inter- strength (UTS) compared to those for the The tensile properties of condition A
face line as it only coarsens the partially base metal in condition H900. The ST + weldments after direct Hl150 PWHT
dissolved coarse incoherent epsilon-cop- H900 PWHT results in slightly higher (Table 3) show that an overmatched
per precipitates. As expected, the hard- total elongation (TE) and reduction in weldment (i.e., with failure occurring in
ness trough, in the as-welded HAZ is area (RA) compared to the base metal in the base metal) is obtained after the di-
completely evened out by the ST step in the same condition. In fact, the ST + rect averaging PWHT, as this PWHT
the ST + H1150 PWHT; this PWHT pro- H900 PWHT results in the highest YS, TE route results in YS and UTS values that
cedure results in complete dissolution and RA values among all the PWHTs are slightly higher than those for the base
and reprecipitation of the incoherent ep- used, while the UTS values are slightly metal in condition H l l 50. This is associ-
silon-copper precipitates throughout the lower than that after the direct H900 ated with a TE value identical to that for
HAZ. PWHT. Further, tensile fracture occurs in the base metal in the same condition. The
the HAZ, which is known from earlier true stress/true strain plots (Fig. 9B) show
Tensile Properties studies (Refs. 12, 17, 19, 22) to be a soft that, compared to the direct Hl150
zone. The slightly higher ductility after ST PWHT, the ST + Hl150 PWHT results in
The average room-temperature ten- + H900 is also attributed to the soft HAZ. a markedly lower weldment strength and
sile properties of transverse weld speci- The true stress/true strain plots (Fig. 9A) ductility. Further, Table 3 shows that the
mens in the various PWHT conditions show that the strength and ductility of the ST + Hl150 PWHT results in consider-
are presented in Table 3, while their true weldments are not significantly affected ably lower strength and ductility values
stress/true strain plots are given in Fig. by the PWHT procedure. However, from in comparison to the weldment sub-
9A-C. The room-temperature transverse Table 3, it is observed that the YS, TE and jected to the direct H l l 50 PWHT, as well
~. o o
~- ~,mo-
n
=
375-
~ 375- 375-
g
"~ 350-
~ 350, 350.
300-
275- ~
~
~
foooo~ rior Condition A
- - - - -
Direct H9OO PWHT
o_=_no_(ST + HgO0) I;~VHT
~ ~r 1
300.
ooooo
Prior Condition A
Direct H1150 PWHT
n_n_o_nn_(ST+ Hl150) PWHT
300.
Prior Condition H l 1 5 0
All-Welded
g.qga_o_Direct Hl150 PWHT
~.Q.,I.~#_(s'r+ Hl150) PWHT
275 , i , J , , r , i , i , J , i r
275 , j , ~ , , = , i , J , i , i ,
-3 -2 -1 1 2 3 4. 5 6 -3 -2 -1 0 1 2 3 4- 5 -3 -2 -1 O 1 2 3 4 5
Distance f r o m Fusion Line ( r a m ) Distance f r o m F u s i o n Line ( r a m ) Distance f r o m Fusion Line ( m m )
A B C
Fig. 8 - - Microhardness (500-g load) profiles measured across the weld interface and HAZ. A - - Condition A weldments after condition H900
PWHT; B - - condition A weldments after condition H1150 PWHT; C - - condition H1150 weldments.
1200 12oo~
~1000 %1ooo- /
~- // //
/
v 800-
==
soo- / / " /
,
P" 400 /t 4oo-
I i
Prior Condition / PHor Condition A
200 // A 2001 2oo-I ,~ I. _ _ ~,-W,~=d
| # I [;Hrect Hl150 PWHT
]/ l
.... (ST+ Hl1501
0
" I....
i
(ST + HgO0) PWHT 01 ~". . . . . . . . . . [.... ( S T + Hl150)
Ot , , , i , , , i , , . i , , , i , , , j , , ,
0.00 0.02 0.04 0.06 0.08 0,10 0.12 0,00 0.02 0.04 0.06 0.08 0.~0 0.12 0,00 0.02 0.04 0.06 0.08 0,10 0,12
True Strain True Strain True Strain
A B C
Fig. 9 - - True stress/strain curves at room temperature. A - - Condition A weldments after condition H 9 0 0 PWHT; B - - condition A weldments after
condition H 1 1 5 0 PWHT; C - - condition H I 150 weldments.
1 5 8 - s l M A Y 1995
welded in condition A, while no PWHT 6. Mathur, D. D., and Ananda Rao, M. No. 9. United Eng. Center, New York.
needs to be given if welded in condition 1981. Selection of stainless steel materials for 15. Welding Hanctbook. 1982. 7th Edn.,
H1150 (note, however, that corrosion re- use in fueling machine of CANDU-type reac- W~I. 4, p. 129. Ameri(an Welding Society,
tors. Workshol) on experience in the fabrica~ Miami, Fla.
sistance is not optimum in the H l 1 5 0 as-
lion and use of stainless sleel equipment in 16. Metals Handbook. 1983.9th Edn., W~I.
welded condition). The optimal combi- DAE projects, Dept. of Atomic Energy, 6, p. 349. Materials Park, Ohio.
nation of tensile properties for use in Kalpakkam, India, Preprints, Vol. 1, Paper No. 17. Hiroshi, I., Shigeo, S., Kiroshi, F., and
condition H1150 is achieved by welding c2. Mitsuali, Y. 1971. Metallurgical research on
in c o n d i t i o n A and using the direct 7. Retting, T.W. 1980. Low pressure steam behaviour of weld heat-affected zone 17-4PH
H 1150 PWHT procedure. turbine blade failure. Report No. WS 78-114, stainless steel. Techno Report, pp. 441-459
pp. 4-7. Electrical Power Resear(h Institute, and 995-1026. Osaka University, Japan.
California. 18. Aerospace Structurals Metals Hand-
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