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Fundamentals Equipment
Starting relationships Pumps
• Thermodynamic relationships • Centrifugal pumps
• Bernoulli’s equation • Reciprocating pumps
Simplifications • Gear pumps
• Pumps – constant density compression Compressors
• Compressors – reversible ideal gas • Centrifugal compressors
compression • Reciprocating compressors
Use of PH & TS diagrams • Screw compressors
Multistaging • Axial compressors
Efficiencies Turbines & expanders
Adiabatic/isentropic vs. mechanical • Expanders for NGL recovery
Polytropic • Gas turbines for power production
o What is “heat rate”?
Ê Q W
2
ˆE Uˆ u g h
2gc gc
o Enthalpy, H = U+PV, convenient for systems at constant pressure & flowing systems
2
u g
Eˆ Hˆ h
2gc gc
ˆ u2 g
H z Q W
2gc gc
ˆ Hˆ u 2
g
Ws z
2gc gc
P2
u 2
g
Vˆ dP z
P1
2gc gc
P2 P2
ˆ Vˆ dP dP
Ws P P
1 1
Ws VdP H
P1
P2 P
dP 1 2 P P
Ws dP 2 1
P1
P1
Differential form of Bernoulli’s equation for fluid flow (energy per unit mass)
d u2
2
g dz
dP
d wˆ s g d hˆf 0
If density is not constant then you need a pathway for the pressure-density
relationship – compressors
u2 P2
dP
g z wˆ s g hˆf 0
2 P1
Pumping requirement expressed in terms of power, i.e., energy per unit time
Hydraulic horsepower – power delivered to the fluid
Over entire system
u2 P
Whhp m wˆ s V
g z g hf
ˆ
2
V P V g z V g hˆf V u2
1
2
Just across the pump, in terms of pressure differential or head:
Also use the head equation usually using gpm, ft, specific gravity, and hp
lbm ft
8.33719 32.174
gal gal
W hhp hp o
2
ft sec
min sec ft lb f / sec 32.174 lbm ft
60
min 550
hp lb f sec2
1 gal
ft o
3958 min
Hydraulic power:
Whhp
360 gpm 61.2 psi 12.85 hp OR Whhp
360 gpm 0.485 291 ft 12.84 hp
1714 3958
xC i p ,i
xC i p ,i
xC i V ,i xC R
i p ,i
Use the ideal gas heat capacities, not the real gas heat capacities
Heat capacities are functions of temperature. Use the average
value over the temperature range
H2 = 462 Btu/lb
H1 = 370 Btu/lb
For methane:
= 1.3
M = 16
T1 = 40oF = 500oR
P1 = 100 psig = 114.7 psia
P2 = 400 psig = 414.7 psia
R = 1.986 Btu/lb.mol oR
1 /
RT1 P2 1.3 1.986 500 414.7 1.31/1.3
Ws 1 1 93 Btu/lb
M 1 P1
16 1.3 1 114.7
If customer wants 1,000 psig (when the inlet pressure 100 psig)…
Then pressure ratio of (1015/115) = 8.8
Discharge temperature for this ratio is ~360oF
For reciprocating compressors the GPSA Engineering Data Book
recommends
Maximum discharge temperature of 250 to 275oF for high pressure systems
AND …
Pressure ratios of 3:1 to 5:1
To obtain pressure ratios higher than 5:1 must use multistage
compression with interstage cooling
To minimize work need good interstage cooling and equal pressure ratios in
stages.
The number of stages is calculated using
ln P2 / P1
1/ m
P
RP 2 m
P1 ln RP
Total work
Ws
1.3 1.986 500 341.2
1.3 1 /1.3
1014.7 1.31/1.3
1 1
16 1.3 1 114.7 341.2
153.9 Btu/lb
H S 0 WS 0
IS Wfluid
H fluid IS
Wfluid Wfluid W
mech Wtotal S 0
Wtotal mech mech IS
1 /
P2
1
T S 0 P
So: T act T1 1
IS IS
P 1/
2 1
P
T2, act T1 T act T1 1 1
IS
P
1 /
1 /
1ˆ
WRT P 1/
ˆ
W p1
2 1
act
p p M 1 P1
Note:
ˆ
W Wˆ
ˆ
Wact p
S 0
p IS
Compress methane from 40oF & 100 psig to 400 psig @ 80%
isentropic efficiency & 10% mechanical losses
Actual work required is:
1 /
1 RT1 P2 1 1.986 500 1.3 414.7
1.3 1 /1.3
ˆ
W 1 1
fluid
IS M 1 P1
0.8 16 1.3 1 114.7
116 Btu/lb
Discharge temperature:
P 1/ 414.7 1.31/1.3
2
1 1
P
1 114.7
T2, act T1 1 500 1 716R 256F
IS 0.8
ln T2 / T1 ln 716 / 500
0.2792
ln P2 / P1 ln 414.7 / 114.7
1 1
1.387
1 1 0.2792
P
1 / 1.3 1 / 1.3 0.827
1 / 1.387 1 / 1.387
1 /
1 RT1 P2 1 1.986 500 1.387 414.7
1.387 1 /1.387
ˆ
W 1 1
fluid
p M 1 P1 0.827 16 1.387 1 114.7
116 Btu/lb
Can use either expression for the power to the fluid to determine
the total power to the compressor
Wfluid 116
Wtotal 129 Btu/lb
mech 1 0.1
5 4
1
Pressure
p0
2 3
Volume
Suction
1 2 3 4 5
Discharge
Courtesy of Nuovo Pignone Spa, Italy
https://www.youtube.com/watch?v=E6_jw841vKE
Oil-free Oil-injected
First used in steel mills because handles “dirty” Higher throughput and discharge pressures
gases
Has two exit ports
Max pressure ratio of 8:1 if liquid injected with
Axial, like oil-free
gas
Radial, which permits 70 to 90% turndown
High availability (> 99%) without significant efficiency decrease
Leads to low maintenance cost
Pressure ratios to 23:1
Volumetric efficiency of ~100%
Tight tolerances can limit quick restarts
Small footprint (~ ¼ of recip)
Requires oil system to filter & cool oil to 140oF
Relatively quiet and vibration-free
Oil removal from gas
Relatively low efficiency
70 – 85% adiabatic efficiencies Oil compatibility is critical
Relatively low throughput and discharge Widely used in propane refrigeration systems,
pressure low pressure systems, e.g., vapor recovery,
instrument air
Centrifugal
High volumes, high discharge pressures
Axial
Very high volumes, low discharge pressures
Use together in gas processing
Centrifugal for compressing natural gas
Axial for compressing air for gas turbine driving centrifugal compressor
Bett,K.E., et al
Thermodynamics for Chemical Engineers
Page 226
Siemens https://www.youtube.com/watch?v=s-bbAoxZmBg
https://www.energy.siemens.com/br/en/compression-
expansion/product-lines/single-stage/stc-sof.htm
Exhaust
Gas Low Pressure Gas
Air
Combustion
Turbine
2544
Thermal efficiency 0.3732
6816
Fuel
Combustion P3
chamber
P2
P1 shaft shaft
Compressor Turbine Load
P4 Combustion
Atmospheric air products
Assumptions
1) All gases are ideal, and compression processes are reversible and adiabatic (isentropic)
3 Patm = P1 = P4
T
Temperature
2
4
Entropy S
Note the equations apply to both the compressor and the turbine,since
thermodynamically the turbine is a compressor running backwards
Neglecting the differences in mass flow rates between the compressor and
the turbine, the net work is:
Temperature
°F 3
Fuel Gas
Exhaust
Combustion Gas (~950°F)
Chamber Real Cycle
~650 - 950°F 3 4
2 4
~1800 - 2
1 2300°F
Air Axial Centrifugal
Compressor Compressor
1
H.P./L.P. Turbine
A B
Entropy
Simple Cycle Gas Turbine
Ideal Cycle Efficiency
1 /
T T P
id 1 4 1 1 1
T3 T2 P2
Updated: February 6, 2018
66
Copyright © 2017 John Jechura (jjechura@mines.edu)
Modeling Gas Turbine with Aspen Plus
Work expression for pump developed Need to limit the compression ratio on a
assuming density is not a function of gas
pressure
• Interstage cooling will result in
Work of compression is much greater than decreased compression power required
that for pumping – a great portion of the
energy goes to increase the temperature
• Practical outlet temperature limitation –
usually means that the maximum
of the compressed gas
compression ratio is about 3
There are thermodynamic/adiabatic &
mechanical efficiencies
• Heat lost to the universe that does
affect the pressure or temperature of
the fluid is the mechanical efficiency
Line
backflow; this can
become cyclic as the
Stonewall Line
Surg
Centrifugal
compressor tries to adjust.
The resulting pressure
oscillations are called
SURGE Reciprocating
Stonewall
• When gas flow reaches
sonic velocity flow cannot
be increased.
Updated: February 6, 2018
79
Copyright © 2017 John Jechura (jjechura@mines.edu)
Air & Hot Gas Paths
A compressor that takes in clean outside air and then compresses it through a series of rotating and
stationary compressor blades
FRESH AIR EXHAUST
COMPRESSION
MECHANICAL
ENERGY
A combustion section where fuel is added to the pressurized air and ignited. The hot pressurized combustion
gas expands and moves at high velocity into the turbine section.
FRESH AIR EXHAUST
COMBUSTION
COMPRESSION
MECHANICAL
ENERGY
A turbine that converts the energy from the hot/high velocity gas flowing from the combustion chamber into
useful rotational power through expansion over a series of turbine rotor blades
FRESH AIR EXHAUST
COMBUSTION
EXPANSION
COMPRESSION TURBINE
MECHANICAL
ENERGY