Desk Handbook

Desk Handbook
Phase Diagrams for

Binary Alloys
Second Edition
Hiroaki Okamoto
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Contents
Foreword ........................................................................................................................... v
About the Editor............................................................................................................... vi
Preface............................................................................................................................. vii
Introduction to Alloy Phase Diagrams........................................................................... ix
Impossible and Improbable Forms of Binary Phase Diagrams ............................. xxxix
Binary Phase Diagrams

Actinium............................................................................................................................. 1
Silver.................................................................................................................................. 2
Aluminum......................................................................................................................... 25
Americium........................................................................................................................ 50
Arsenic............................................................................................................................. 53
Astatine............................................................................................................................ 70
Gold ................................................................................................................................. 70
Boron ............................................................................................................................... 92
Barium ........................................................................................................................... 115
Beryllium......................................................................................................................... 131
Bismuth .......................................................................................................................... 144
Berkelium ....................................................................................................................... 166
Bromine ......................................................................................................................... 167
Carbon ........................................................................................................................... 176
Calcium........................................................................................................................... 189
Cadmium ........................................................................................................................ 205
Cerium ............................................................................................................................ 222
Californium ..................................................................................................................... 241
Chlorine .......................................................................................................................... 241
Curium ............................................................................................................................ 255
Cobalt ............................................................................................................................. 257
Chromium ....................................................................................................................... 276
Cesium ........................................................................................................................... 297
Copper............................................................................................................................ 307
Deuterium ....................................................................................................................... 327
Dysprosium..................................................................................................................... 330
Erbium ............................................................................................................................ 345
Einsteinium ..................................................................................................................... 361
Europium ........................................................................................................................ 362
Fluorine........................................................................................................................... 373
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Iron ................................................................................................................................. 376

Fermium ......................................................................................................................... 395
Francium......................................................................................................................... 396
Gallium ........................................................................................................................... 396
Gadolinium ..................................................................................................................... 413
Germanium ..................................................................................................................... 428
Hydrogen ........................................................................................................................ 444
Helium ............................................................................................................................ 455
Hafnium .......................................................................................................................... 456
Mercury........................................................................................................................... 467
Copyright ASM International iii

Holmium ......................................................................................................................... 485
Iodine.............................................................................................................................. 497
Indium............................................................................................................................. 505
Iridium............................................................................................................................. 519
Potassium ....................................................................................................................... 531
Krypton ........................................................................................................................... 538
Lanthanum...................................................................................................................... 538
Lithium ............................................................................................................................ 551
Lawrencium .................................................................................................................... 563
Lutetium.......................................................................................................................... 563
Mendelevium .................................................................................................................. 574
Magnesium ..................................................................................................................... 574
Manganese..................................................................................................................... 584
Molybdenum ................................................................................................................... 597
Nitrogen .......................................................................................................................... 613
Sodium ........................................................................................................................... 617
Niobium .......................................................................................................................... 623
Neodymium .................................................................................................................... 633
Nickel.............................................................................................................................. 643
Neptunium ...................................................................................................................... 654
Oxygen ........................................................................................................................... 656
Osmium .......................................................................................................................... 662
Phosphorus .................................................................................................................... 669
Lead................................................................................................................................ 674
Palladium........................................................................................................................ 682
Promethium .................................................................................................................... 692
Praseodymium................................................................................................................ 696
Platinum.......................................................................................................................... 704
Plutonium........................................................................................................................ 712
Rubidium ........................................................................................................................ 719
Rhenium ......................................................................................................................... 723
Rhodium ......................................................................................................................... 729
Ruthenium ...................................................................................................................... 736
Sulfur .............................................................................................................................. 742
Antimony......................................................................................................................... 748
Scandium........................................................................................................................ 753
Selenium......................................................................................................................... 758
Silicon ............................................................................................................................. 763
Samarium ....................................................................................................................... 768
Tin................................................................................................................................... 772
Strontium ........................................................................................................................ 777
Tritium............................................................................................................................. 779
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Tantalum......................................................................................................................... 780
Terbium .......................................................................................................................... 784
Technetium ..................................................................................................................... 787
Tellurium......................................................................................................................... 789
Thorium .......................................................................................................................... 792
Titanium.......................................................................................................................... 796
Thallium .......................................................................................................................... 798
Thulium........................................................................................................................... 800
Uranium .......................................................................................................................... 802
Vanadium ....................................................................................................................... 804
Tungsten......................................................................................................................... 806
Yttrium ............................................................................................................................ 807
Ytterbium ........................................................................................................................ 808
Zinc................................................................................................................................. 808
Crystal Structure Tables for Systems Where

Phase Diagrams Could Not Be Found ........................................................................ 809
Copyright ASM International iv

Foreword
As Publisher of the first edition of Desk Handbook: Phase Diagrams for Binary Alloys, I am honored that Dr. Okamoto
asked me to make a few comments for this second edition. “Hiro,” as I know him, has been involved with ASM
publications for more than 30 years, and for a period of about five years, in the late 1980s and early 1990s, he was
employed by ASM as our “expert” in binary phase diagrams. He had the idea of publishing a handbook, updated, and
only including diagrams and some crystallographic data. His interest was in providing a single volume, having all
diagrams in atomic percent for the primary axis, and offering a quick look-up with key references for those who wanted
to “dig deeper” into the literature. I am pleased that ASM is publishing a second edition of the original volume, with
additional updates.
I am aware of no other living person who has evaluated, examined, and edited more diagrams than Hiro Okamoto. That
alone qualifies him to be the editor of this volume. However, his scientific background, combined with his job of
looking at every single known binary diagram, caused him to see some patterns occurring in the literature. There were
many situations where diagrams were drawn incorrectly, based on thermodynamic arguments. As a result he decided to
write, in collaboration with Professor Thaddeus Massalski* of Carnegie Mellon University, what I consider to be a
classic paper in the Journal of Phase Equilibria in 1991, regarding thermodynamically improbable diagrams (see list
below for reference).
Following this publication, Dr. Okamoto and Professor Massalski continued to write instructive articles for the phase
diagram community. Specifically, the following articles are of importance:
1991Oka2: H. Okamoto and T.B. Massalski, “Thermodynamically Improbable Phase Diagrams,” J. Phase
Equilibria, 12(2), 148–168 (1991).
1991Oka1: H. Okamoto, “Reevaluation of Thermodynamic Models for Phase Diagram Evaluation,” J. Phase
Equilibria, 12(6), 623–643 (1991.
1993Oka2: H. Okamoto and T.B. Massalski, “Guidelines for Binary Phase Diagram Assessment,” J. Phase
Equilibria, 14(3), 316–335 (1993).
1994Oka: H. Okamoto and T.B. Massalski, “Binary Alloy Phase Diagrams Requiring Further Study,” J.
Phase Equilibria, 15(5), 500–521 (1994).
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If you have not read these papers, and you are using phase diagrams, you should consult them because they are
extremely instructive. In particular, the last paper on systems requiring further study, is very revealing, pointing out
issues and contradictions in published diagrams and the need for further work in many, many systems.
Based on this background, his unique situation in having viewed every diagram, seen the problems in existing
diagrams, and his passion for improving the published binary diagrams, you can see why it was important for a second,
updated edition of the Desk Handbook to be published, I think you will find it will meet the original objectives stated
by Dr. Okamoto, and it provides another important and continuing publication for ASM, as they continue to provide
periodical publications and reference material for the phase equilibria community.
William W. Scott, Jr., Ph.D., FASM

Technical Director (retired)
ASM International
* Professor T.B. Massalski was the Editor-in-Chief of the Data Program for Binary Phase Diagrams for about 15 years, a joint
program between ASM and NIST (U.S. National Institute of Standards and Technology), involving about $10 million in expenditures
towards evaluating and publishing binary phase diagram information. He is one of the most knowledgeable persons in phase equilibria
in the world. As you will know from having read the other introductory materials, he is also the Editor-in-Chief of Binary Alloy Phase
Diagrams, the most important compilation of binary phase diagrams, text, and data in recent times.
Copyright ASM International v

About the Editor
Dr. Hiroaki Okamoto is co-editor of ASM’s primary binary phase diagrams reference work, the
three-volume set Binary Alloys Phase Diagrams, Second Edition [Massalski2], and the electronic
edition of this work, Binary Alloy Phase Diagrams, Second Edition, Plus Updates, on CD-ROM.
He has personally evaluated and published phase diagrams and related data for more systems than
any other living professional, completing 505 evaluations.
Dr. Okamoto has also published classic articles on common mistakes made in drawing phase
diagrams, including “Thermodynamically Improbable Phase Diagrams,” “Reevaluation of
Thermodynamic Models for Phase Diagram Evaluation,” and “Guidelines for Binary Phase
Diagram Assessment” (Journal of Phase Equilibria, 12(2), 12(6), and 14(3), respectively). He has
been Supplemental Literature Review Editor for Journal of Phase Equilibria and Diffusion since
1991.
Presently professor, Department of Information Management, Asahi University, Mizuho-shi, Gifu,

Japan, Dr. Okamoto was senior technical editor, Alloy Phase Diagram Program, ASM International,
from 1987 through 1993. He obtained his master’s degree in applied physics from Nagoya
University in 1965, and his doctorate in metallurgy from the University of Illinois in 1971. Earlier
in his career, he worked on the evaluation of binary gold systems at Carnegie-Mellon University in
Pittsburgh and on the evaluation of beryllium alloy systems at the Lawrence Berkeley Laboratory
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in California. He was editor of Phase Diagrams of Binary Iron Alloys (ASM International, 1993),
and co-editor of Phase Diagrams of Binary Gold Alloys, Phase Diagrams of Binary Beryllium
Alloys, and Phase Diagrams of Binary Indium Alloys and Their Engineering Applications (ASM
International, 1987, 1987, and 1991, respectively). He was also a co-editor of the 10-volume
Handbook of Ternary Alloy Phase Diagrams (ASM International, 1995).
Copyright ASM International vi

Preface
Binary alloy phase diagrams have been studied for more than 100 years since ca. 1900. The wealth of knowledge
accumulated experimentally and theoretically in this period was assessed and summarized in various compendia.
Binary Alloy Phase Diagrams, Second Edition, edited by T.B. Massalski, H. Okamoto, P.R. Subramanian, and L.
Kacprzak, and published by ASM International in 1990, hereinafter referred to as [Massalski2], was regarded as one of
the most extensive collection of binary alloy phase diagrams and has been used as a convenient and dependable tool in
academics and industry for research, development, design, and other purposes for various materials in wide areas
related to material sciences.
Because [Massalski2] in a three-volume set was heavy and rather difficult to handle for quick references, this author
published Desk Handbook: Phase Diagrams for Binary Alloys in 2000, in which the size of the phase diagrams was
reduced to 60 percent of that in [Massalski2] in order to accommodate three phase diagrams on each page. New or
updated phase diagrams collected in the period from 1990 to 2000 were also included. For each phase diagram, crystal
structures of phases existing in the system were listed and only one data source was usually given. In this way, key
information on binary alloy phase diagrams could be conveniently assembled in one volume.
Ten years have passed since the Desk Handbook described above was published. In the meantime, the author
introduced new and updated binary alloy phase diagrams in Section III of the Journal of Phase Equilibria and
Diffusion at a rate of approximately 50 diagrams per year. In addition, many pieces of information leading to partial
modification of phase diagrams became available. Therefore, it has become almost impossible to access the most
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up-to-date information on binary alloy phase diagrams through the first edition of the Desk Handbook and many
volumes of the Journal of Phase Equilibria and Diffusion. Accordingly, this author proposed publishing this second
edition of the Handbook. In summary, this second edition includes phase diagrams for 2,421 systems, in which about
450 phase diagrams have been updated. Among these, 87 phase diagrams were unknown when the first edition was
published.
The format and policy for presenting the phase diagram, crystal structure data, and key reference are the same as in the
first edition. The phase diagram is presented in terms of atomic percent. The weight percent scale is shown with a
secondary-axis. Among various modifications of phase diagrams available for one particular system, the “best” phase
diagram was selected by this author based on the current standard. An even better diagram will certainly become
available in the future because almost all phase diagrams have more or less unlikely features according to the criteria
summarized by this author (see below). Also, it must be noted that the updated phase diagram has not been critically
evaluated. It is recommended that the reader view the new phase diagram with caution. It may look more normal from
the thermodynamic point of view, but it is often the case that the phase boundaries are not supported experimentally.
The reference article and other articles quoted there should be helpful in judging the reliability of the updated phase
diagram. Crystal structure data for updated phase diagrams were taken from the same source as for the phase diagram
whenever available. Pearson’s Crystal Data — Crystal Structure Database for Inorganic Compounds, edited by P.
Villars and K. Cenzual (ASM International), was used as an auxiliary source. The reference was chosen so that all
information on a particular system becomes available from the minimum number of sources (typically one). Two or
more sources are given when all information cannot be reached by tracking back from either one of the sources. Two
sources are also given when the phase diagram data and crystal structure data cannot be reasonably compromised (for
example, Ge-K system).
Copyright ASM International vii

In conjunction with Professor Massalski of Carnegie-Mellon University, this author published four articles for finding
unlikely features in phase diagrams:
H. Okamoto and T.B. Massalski, “Thermodynamically Improbable Phase Diagrams,” J. Phase Equilibria, 12(2),
148–168 (1991)
H. Okamoto, “Reevaluation of Thermodynamic Models for Phase Diagram Evaluation,” J. Phase Equilibria,
12(6), 623–643 (1991)
H. Okamoto and T.B. Massalski, “Guidelines for Binary Phase Diagram Assessment,” J. Phase Equilibria, 14(3),
316–335 (1993)
H. Okamoto and T.B. Massalski, “Binary Alloy Phase Diagrams Requiring Further Study,” J. Phase Equilibria,
15(5), 500–521 (1994)
Many problems pointed out in these articles have been eliminated in the diagrams updated in this edition. However,
many such unlikely features still remain. In order to help the reader find them quickly, “Impossible and Improbable
Forms of Binary Phase Diagrams” are shown in the front section of this Handbook with minor modification from that
in the first edition. Key points in the above-mentioned four articles are summarized here. Also, “Introduction to Alloy
Phase Diagrams” by the late Hugh Baker of ASM is reprinted in the front section as a convenient reference to the
knowledge of phase diagrams and crystal structures.
As in the first edition, in the last part of this handbook crystal structures are shown for the systems for which the phase
diagram data are not available. Additional research on phase diagrams is expected for these systems.
Great care was taken to eliminate errors in phase diagrams and crystal structure data with the elaborative assistance of
Japanese Alloy Phase Diagram Committee members Professor Seiji Miura of Hokkaido University and Professor
Hiroshi Ohtani of Kyushu Institute of Technology. Nevertheless, it is very likely that there are still typing errors and
drawing errors in this handbook. Information on such errors will be very helpful for possible future revision. Please
send any such information via e-mail to Books@asminternational.org.
Lastly, the author would like to express thanks to Mary Anne Fleming, Madrid Tramble, and Scott Henry of ASM
International, Materials Park, Ohio, USA; Professor T.B. Massalski of Carnegie-Mellon University, Pittsburgh,
Pennsylvania, USA; and K. Ishida of Tohoku University, Sendai, Japan, for their unchanging cooperation and
assistance in materializing this publication. The Miyata Research Grant from Asahi University, Gifu, Japan, facilitated
the publication of this Handbook. This author greatly appreciates the generous contribution.
Hiroaki Okamoto
Asahi University, Gifu, Japan
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Copyright ASM International viii

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Impossible and Improbable Forms of
Binary Phase Diagrams*
H. Okamoto
Asahi University, Gifu, Japan
and
T.B. Massalski
Carnegie-Mellon University, Pittsburgh, PA
1. Introduction [1990Mas]) and summarized the problems in

four articles [1991Oka2], [1991Oka1],
The problems observed in phase diagram [1993Oka2], and [1994Oka]. It is of interest,
graphics can be grouped into two categories. however, that there can be correct phase
Problems of the first category involve phase rule diagrams that may appear to be impossible or
(thermodynamic principle) violations. A problem improbable. These are also discussed in each
of this type contains an absolute error. This section.
category is discussed below under the title of
“Impossible Diagrams.” Problems of the second The commentary provided here is a brief
category involve errors that are generally summary of the four articles mentioned above.
acceptable from the viewpoint of the phase rule, Please consult these original articles for the
but the proposed phase boundaries have atypical thermodynamic backgrounds to the problems
or abnormal forms, or have been forced to have listed below. An approach similar to ours (to
abnormal forms in order to satisfy the phase rule, discover unlikely phase diagrams from phase
or uncertain experimental data. There are several boundary forms) was also discussed in the
types of abnormal features, and these are 1940’s by Williams [1944Wil], but the criteria
discussed in the section entitled “Improbable described there are rather limited in scope.
Diagrams.” We experienced these problems Figure 1 shows a schematic graphic
through the course of editing the Binary Alloy representation of the various reaction types
Phase Diagram volumes (T.B. Massalski, H. discussed in the following sections.
Okamoto, P.R. Subramanian, and L. Kacprzak
0 10 20 30 40 50 60 70 80 90 100
Melting
L
2
S
1 Homotectic L Critical Miscibility gap
Allotropic 3 L
Catatectic L Syntectic
Congruent
1
L
Monotectic 4
Eutectic S
5 Eutectic
S Peritectic
Temperature, °C
2 S
Peritectoid Critical 6 Melting
Min.
Monotectoid melting
S
3
Eutectoid
Congruent S
8
Polymorphic
S
7
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S
4
0 10 20 30 40 50 60 70 80 90 100
A Atomic Percent B B
Fig. 1 A hypothetical phase diagram showing reactions in binary systems
* Note: Part of “Introduction to Alloy Phase Diagrams,” in this handbook was prepared based on [1991Oka2] and [1991Oka1]. This
article is a concise summary of these two articles plus [1993Oka1], [1993Oka2], and [1994Oka]. Therefore, some figures in this
article and the previous section are similar, but different in some details.
Copyright ASM International xxxix

2. Impossible Diagrams (minimum congruent point or monotectic
Various impossible phase relationships are reaction in this case).
summarized in Fig. 2. These problems are as M. A local maximum point in the lower part of
follows: a single-phase field cannot be drawn without
a monotectic, monotectoid, syntectic, and
A. The liquidus and solidus must meet at the syntectoid reaction occurring at a lower
melting point of the pure element. temperature. Alternatively, a solidus curve
B. Two liquidus curves must meet at one must be drawn to touch the liquidus at point
composition at a eutectic temperature. M. (If the maximum is not local, as in a
C. A tie line must terminate at a phase miscibility gap, this is not a phase rule
boundary. violation.)
D. Two solvus boundaries (or two liquidus or N. The temperature of an invariant reaction
two solidus, or a solidus and a solvus) of the must be constant. (The reaction line must be
same phase must intersect at one horizontal.)
composition at an invariant temperature. O. A phase boundary cannot terminate within a
E. A phase boundary must extrapolate into a phase field (except the case when the
two-phase field after crossing an invariant boundary is unknown beyond this point).
point. P. The liquidus should not have a
F. A two-phase field cannot be extended to a discontinuous sharp peak at the melting
pure element end. point of a compound. (See exceptions,
G. Two boundaries of γ must not be continuous below.)
at the invariant temperature. They must Q. The compositions of all three phases at an
cross one another. invariant reaction must be different.
H. An invariant temperature line should involve R. Temperatures of liquidus and solidus (or any
equilibrium among three phases. two boundaries) must either increase or
I. There should be a two-phase field between decrease together from one point on the pure
two single-phase fields. element line as the content of a second
J. When two phase boundaries touch at a point, element increases.
they should touch at an extremity of S. A four-phase equilibrium is not allowed in a
temperature. binary system. (See exceptions, below.)
K. A touching liquidus and solidus (or any two T. Two separate phase boundaries that create a
touching boundaries) must have a horizontal two-phase field between two phases in
common tangent at the congruent point. In equilibrium should not cross one another.
this case, the solidus at the melting point
appears to be discontinuous. Although phase rules are not violated, three
L. A local minimum point in the lower part of a additional unusual situations (X, Y, and Z) are
single-phase field cannot be drawn without also included in Fig. 2. These unlikely situations
an additional boundary in contact with it are discussed in section 3.
Liquid K P
A L M
X
Q
B N
α C R
D
β1
Temperature
ε Y
T
E G S
β2
H I
δ J μ
γ
Z
F λ O
ζ
0 10 20 30 40 50 60 70 80 90 100
Fig. 2 Hypothetical phase diagram showing violations of phase rules and thermodynamically impossible
situations (points A-T). Very unlikely changes of slopes are also added (points X-Z)
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Copyright ASM International xl

2.1. An additional problem, not shown in Fig. in the liquid phase as it does in the solid
2 state. The apparent sharpness of the peak
• A continuous solid solution phase between varies depending on the degree of
two phases with different crystal structures. association of the liquid molecules.
For example, a fcc phase and a bcc
phase cannot form a continuous phase. 3. Improbable Diagrams
There must be a two-phase field First, it must be noted that an abrupt change of
between them. In this handbook, there slope of a phase boundary, as shown by X, Y,
are many diagrams involving binary and Z in Fig. 1, is thermodynamically unlikely.
combinations between rare-earth An abrupt change of slope can occur only if the
elements showing a continuous solid thermodynamic property of either one of the two
solution field between a Mg-type phases in equilibrium suddenly changes at the
hexagonal phase and an αLa-type corresponding temperature or composition.
double hexagonal phase. A symbol “?” Because the thermodynamic properties are
is added to each such phase diagram to expected to change gradually in one phase field,
attract attention. the phase boundary slope is also expected to
change gradually. If an abrupt change of slope is
2.2. Exceptions real, it must be related to a unique situation
• A four-phase reaction in appearance, as “S” affecting a phase associated with this phase field,
in Fig. 1, may occur if temperatures of two such as the onset of an order-disorder
invariant reactions with an overlapping transformation, or a magnetic transition.
composition range are very close to one
another. Now, Fig. 3 shows various types of improbable
• A sharp peak as “P” in Fig. 1 may occur if phase boundaries.
this phase exists in the same molecular state
G p
q
β4
a L
e r
i
c f k
j
b l β3
λ2 g
Temperature
m β2 s
γ o t
δ λ1
n
ε
AmBn
σ
α β1
h
0 10 20 30 40 50 60 70 80 90 100
Fig. 3 Hypothetical phase diagram indicating improbable phase boundaries. Note that phase rules are not
violated explicitly.
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`
Copyright ASM International xli

The problems at each point in Fig. 3 are as j) The congruent melting point of AmBn
follows: compound is too far away from its
a) G + L two-phase field is too narrow. The stoichiometric composition.
opening angle of G + L at 0 at.% must be k) The liquidus is too asymmetric. According
much larger than that of L + α because the to our rough criterion, a liquidus is already
heat of vaporization of an element is too asymmetric if the liquidus width ratio to
generally much greater than the heat of the left and right of a compound exceeds
fusion. 2:3.
b) Extrapolation of the liquidus should not l) The transformation temperature of ε to β2
cross the 0 at.% line. Otherwise, problem F should be higher than the melting point of ε.
of Fig. 1 occurs. Otherwise, the β2 phase is stable above point
c) The liquidus of γ at point c is too flat in j.
comparison with the liquidus of δ at point e. m) Extrapolation of two boundaries of L + β2
Problems c, d, and e are related. Because should not cross. Problem T of Fig. 2.
entropy of fusion of elements and n) A two phase field must be narrower at
compounds cannot differ much (Charles’ higher temperatures
law), curvatures of liquidus curves for o) The slope is too flat to have a maximum
compounds in a binary system must be point at the composition of σ.
similar. A phase with a shaper liquidus tends p) The liquid miscibility gap is too close to the
to decompose into two neighboring phases edge of a phase diagram. According to our
at low temperatures. rough criterion, the peak composition of a
d) A compound with a flat liquidus is stable liquid miscibility gap should fall in the
and will not decompose at low temperatures. range 25 to 75 at.%.
e) Liquidus at point e is too sharp in q) The liquidus slope is too steep. The initial
comparison with the liquidus at point c. slope of a liquidus is, as a rule, determined
f) Extrapolation of the liquidus of λ2 must have by the van’t Hoff relationship. If no
a peak at the composition of λ2. Otherwise solubility can be assumed for the solid
problem P of Fig. 2 occurs. phase, extrapolation of the initial liquidus
g) Change of liquidus slope associated with an should go through the horizontal axis at 0 K
allotropic transformation must be small. near approximately 110 at.% [1993Pau]
h) Two compounds having similar (empirically, 130 at.% at –500 °C
compositions cannot be stable over a wide [1991Oka2]) for most metallic elements
temperature range. (Fig. 4a). If there is some solid solubility
i) A phase field of a compound cannot extend that cannot be neglected, the distance (not
over a neighboring phase. Problem T of Fig. the angle) to the solidus from 0 at.% line is
2 occurs. subtracted from the distance to the liquidus.
Then the same rule can be applied (Fig. 4b).
M.P.
L
Temperature, °C
Liq
uid
us
ini
tial M.P.
slo Liqu L
pe idus
initi
al sl
α+L
Temperature, °C
ope
c
a b d
So
lid α+L
0 us
0 100 in
Atomic Percent iti
al
α slo
pe
Di
spl
ace
dl
+ (110%, 0 K) iqu
idu
s
0
0 Atomic Percent 100
Fig. 4a When the solid solubility of the solid + (110%, 0 K)

phase is negligible, the initial slope of the
liquidus goes through a point (110 at.%, 0 K).
This rule cannot be applied to some non-metallic Fig. 4b When the solid solubility of the solid
elements (B, Si, etc. [1991Oka2]). For quick phase is not negligible, the same rule as above
check, however, the check point may be moved can be applied by displacing the liquidus so that
to (100 at.%, 0 °C) if the melting point of the the distance cd becomes equal to the distance ab.
element is high (> ∼1000 K).
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Copyright ASM International xlii

r) Extrapolation of two boundaries of L + β3 solid-solid two-phase field, the
should cross at the 100 at.% line, not at solubility range of each solid phase
some composition exceeding 100 at.%. generally increases as the temperature
Problem A of Fig. 2. increases. Accordingly, the two-phase
s) Two phase boundaries should have different field between these two solid phases
initial slopes. The entropy of an allotropic narrows at higher temperatures.
transformation is not zero. Example: (γCe) + (βCe,αPr) two-phase
t) The slopes of two phase boundaries are too field in the Ce-Pr system (p. 232).
far apart. The entropy of an allotropic • A compound with a wide solubility range
transformation is generally small. forming by a peritectic, or peritectoid
reaction.
Some problems described above may be solved This is related to the problem described
if an abrupt change of slope is introduced in above. Peritectic, or peritectoid,
phase boundaries. However, this may not be a formation of a broad compound almost
good solution because unlikely thermodynamic inevitably results in the neighboring
properties must be assumed, as explained two-phase field widening at higher
already. temperatures. Example: Np4Zr and
NpZr2 in the Np-Zr system (p. 655).
3.1. Other improbable phase relationships not • Occurrence of two segments of a common
shown in Fig. 3 phase boundary not connectable without
• The occurrence of two line compounds introducing unusual inflections.
neighboring close to one anther and both Example: The relationship between the
stable over a wide temperature range. upper and lower segments of (Mo) +
This would be understandable by the (Ru) boundaries in the Mo-Ru phase
fact that only one compound would be diagram in the first edition was a typical
stable at any temperature if the distance example. This problem was solved in
(composition difference) between the this edition. (Cr) + (Ru) in the Cr-Ru
two line compounds was reduced to system is another example (p. 290).
zero. Example: βIn2Se3 and γIn2Se3 in • Two phases separated by a narrow two-
the In-Se system (p. 513). phase field over a wide composition range
• A syntectic reaction involving a line having dissimilar boundary trends in other
compound forming at a composition very areas.
similar to the composition of the peak of the A narrow two-phase field implies that
boundary representing the miscibility gap the thermodynamic properties of the
above the syntectic reaction. two phases are very similar.
Only Mn23Y6 in the Mn-Y system Accordingly, their boundaries with
[1991Pal] indicates this feature (p. 596). respect to another phase must be
For all other syntectic reactions in this similar. Example: In the Cr-Ni system
Handbook, a compound forms at a (p. 285), the (Ni) + γ’ two-phase field is
composition far away from the peak very narrow. Therefore, trends of the
composition of the miscibility gap. A boundaries of the (Cr) + (Ni) two-phase
miscibility gap is formed because field and that of the (Cr) + γ’ two-phase
element A and element B repel one field must be similar.
another in the liquid state and the peak • Strongly retrograde solidus.
composition of a miscibility gap It means that the solid element is very
represents where the repelling force is soluble in the liquid at high
strongest. It is unlikely therefore that a temperatures and insoluble at low
compound of a similar composition temperatures. The enthalpy of mixing of
(signaling A and B attraction) should be the solid phase may require
formed in the solid state. Therefore, the unrealistically large temperature
syntectic formation of Mn23Y6 is dependence. Example: (Ta) phase in the
doubtful. Pu-Ta system (p. 715).
• A two-phase field widening as the • Intermediate phase with a nearly constant
temperature increases. width over a wide temperature range
A liquid-solid two-phase field always This unlikely feature is still observed in
narrows to zero at higher temperature many phase diagrams in this handbook.
because only the liquid phase remains at Example: most compounds in the Hf-Ir
sufficiently high temperatures. For a system (p. 457). The width may be very
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Copyright ASM International xliii

narrow (line compound) or gradually described above are applied. Nevertheless, even
changing without sudden change in the with existing problems here and there, phase
curvature of the phase boundary. diagrams are very useful tools in materials
• Intermediate phase with a solubility range at science, just as a rough road map is useful for
high temperatures, line compound at low quick travelers. At the same time, it is always
temperatures important to discover problem areas in phase
Example: Ir2Sc in the Ir-Sc system (p. diagrams to avoid possible complications when
526). It is likely that the compound they are used, and we hope that this small
decomposes eutectoidally when the line summary of problems that may be encountered
compound part in the figure begins on will be helpful for this purpose and also for
cooling. improving in the future the accuracy of already
existing diagrams.
The rules described in this section are also
applicable to metastable states. Therefore, when
examining phase boundary trends for possible Cited References
problems, it is always helpful to apply these 1944Wil: A.J.C. Wilson, “Binary Equlibrium,”
rules by extrapolating the proposed phase J. Inst. Met., 70, 543–556 (1944)
boundaries into metastable ranges to see if any 1990Mas: T.B. Massalski, H. Okamoto, P.R.
phase diagram rules are violated. Subramanian, and L. Kacprzak, ed., Binary Alloy
Phase Diagrams, Second Edition, ASM
For several other cases, including unrealistic International, Materials Park, OH (1990)
thermodynamic models, please refer to articles 1991Oka1: H. Okamoto, “Reevaluation of
[1991Oka2], [1991Oka1], [1993Oka2], and Thermodynamic Models for Phase Diagram
[1994Oka]. Evaluation,” J. Phase Equilibria, 12(6), 623–643
(1991)
3.2. Exceptions 1991Oka2: H. Okamoto and T.B. Massalski,
• The peak composition of a liquid miscibility “Thermodynamically Improbable Diagrams,” J.
gap may be displaced closer to a pure Phase Equilibria, 12(2), 148–168 (1991)
element side in a rare situation in spite of the 1993Oka1: H. Okamoto, “A Two-Peak
above-mentioned criterion n) when the Miscibility Gap,” J. Phase Equilibria, 14(3),
enthalpy of mixing is strongly positive near 336–339 (1993)
one element and strongly negative near the 1993Oka2: H. Okamoto and T.B. Massalski,
other element. The Bi-Zn (p. 162) system “Guidelines for Binary Phase Diagram
may be an example of this type. Assessment,” J. Phase Equilibria, 14(3), 316–
• The peak composition of a liquid miscibility 335 (1993)
gap may also be displaced closer to a pure 1993Pau: E. Paul, “The Paper
element side even when the enthalpy of ‘Thermodynamically Improbable Phase
mixing is positive for the entire composition diagrams’,” J. Phase Equilibria, 14(2), 135
range if the miscibility gap is a two-peak (1993)
type (one peak may be hidden by other 1994Hil: M. Hillert, “Historic Note on the Two-
reactions). Although the existence of a two- Peak Miscibility Gap,” J. Phase Equilibria,
peak miscibility gap was theoretically 15(1), 35–36 (1994)
predicted [1993Oka1, 1994Hil], no 1994Oka: H. Okamoto and T.B. Massalski,
experimental evidence has been reported so “Binary Alloy Phase Diagrams Requiring
far. Further Studies,” J. Phase Equilibria, 15(5),
500–521 (1994)
4. Conclusions
Very few phase diagrams in this handbook are
flawless in the fine detail when the criteria
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Copyright ASM International xliv

Ac Weight Percent Boron
Ac-B
0 10 20 30 40 60 100
2800
2600
2400 Ac-B
L Struktur-
2200 Composition, Pearson Space bericht
2092°C Phase at.% B symbol group designation Prototype
2000
(Ac) 0 cF4 Fm 3 m A1 Cu
AcB4 80 … … … …
1800
AcB6 85.7 … … … …
1600
(bB) 100 hR108 R 3m … …
1400 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1200 1-2 (1990)
(bB)
1051°C
1000
800
(Ac)
600
0 10 20 30 40 50 60 70 80 90 100
Ac Atomic Percent Boron B
0
Weight Percent Chromium
10 20 30 40 50 60 70 80 90 100
Ac-Cr
2000
1900
1863°C
1800
Ac-Cr
1700
Struktur-
Phase at.% Cr symbol group designation Prototype
1500 L
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1400
(Cr) 100 cI2 Im 3 m A2 W
1300
1200 M. Venkatraman, J.P. Neumann, and D.E. Peterson, Bull. Alloy Phase Diagrams,
6(5), 413–414 (1985)
1100
1051°C
1000
900
800
700°C
700
30
600 (Ac) (Cr)
500
0 10 20 30 40 50 60 70 80 90 100
Ac Atomic Percent Chromium Cr
0 10
Weight Percent Molybdenum
20 30 40 50 60 70 80 90 100
Ac-Mo
3500
3000 L2
L1 Ac-Mo
Struktur-
2623°C
L1 + L2 Composition, Pearson Space bericht
2500
Phase at.% Mo symbol group designation Prototype
2000 (Mo) ? to 100 cI2 Im 3 m A2 W
(Mo) L. Brewer and R.H. Lamoreaux, Phase Diagrams of Binary Actinide Alloys,
1500 M.E. Kassner and D.E. Peterson, ed., ASM International, Materials Park, OH, 7
(1995)
1051°C
1000
500 (Ac)
0
0 10 20 30 40 50 60 70 80 90 100
Ac Atomic Percent Molybdenum Mo
Copyright ASM International Desk Handbook: Phase Diagrams for Binary Alloys 1
Ac
0 10 20
Weight Percent Platinum
30 40 50 60 70 80 90 100
Ac-Pt
2200
2000
Ac-Pt
Struktur-
Composition, Pearson Space bericht
L Phase at.% Pt symbol group designation Prototype
1800
1769°C
Ac7Pt3 30 … … … …
1600 Ac3Pt2 40 … … … …
AcPt 50 … … … …
Ac3Pt4 57.1 … … … …
1400 AcPt2 66.6 to ? … … … …
AcPt5 83.3 … … … …
(Pt) 100 cF4 Fm 3 m A1 Cu
1200
D.E. Peterson, Phase Diagrams of Binary Actinide Alloys, M.E. Kassner and
1051°C (Pt) D.E. Peterson, ed., ASM International, Materials Park, OH, 8-9 (1995)
1000
(Ac)
800
0 10 20 30 40 50 60 70 80 90 100
Ac Atomic Percent Platinum Pt
0 10
Weight Percent Aluminum
20 30 40 50 60 70 80 90 100
Ag-Al
1000
961.93°C
900
Ag-Al
778°C Struktur-
800 L
17.4
21.6 726°C Composition, Pearson Space bericht
20.5
32.7
Phase at.% Al symbol group designation Prototype
29.8
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
700 b 32.1 (Ag) 0 to 20.4 cF4 Fm 3 m A1 Cu

610°C 660.452°C b 20.5 to 29.8 cI2 Im 3 m A2 W
20.3 m 21 to 24 cP20 P41 32 A13 bMn
600 603°C,24.4
(Ag) 567°C
61 76.5
d 22.9 to 41.9 hP2 P63/mmc A3 Mg
41.9
(Al)
d (Al) 76.5 to 100 cF4 Fm 3 m A1 Cu
500 450°C
20.4 23.5
A.J. McAlister, Bull. Alloy Phase Diagrams, 8(6), 526-533 (1987)
400
300 m
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Aluminum Al
0 10 20
Weight Percent Arsenic
30 40 50 60 70 80 90 100
Ag-As
1000
961.93°C
900
Ag-As
L
800
817°C Struktur-
Phase at.% As symbol group designation Prototype
700 (Ag) 0 to 7.8 cF4 Fm 3 m A1 Cu
z 9.5 to 11 hP2 P63 /mmc A3 Mg
(As) 100 hR2 R 3m A7 aAs
600 582°C
7.8
10 21.5
540°C M.R. Baren, Bull. Alloy Phase Diagrams, 11(2), 113-116 (1990)
(Ag) 11 25.3
500
z
7 446°C
9.5
400
(As)
300
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Arsenic As
2
Copyright ASM International Desk Handbook: Phase Diagrams for Binary Alloys
Ag
0 10 20 30 40
Weight Percent Gold
50 60 70 80 90 100
Ag-Au
1075
1064.43°C
1050
L Ag-Au
Struktur-
1025 Phase at.% Au symbol group designation Prototype
(Ag,Au) 0 to 100 cF4 Fm 3 m A1 Cu
H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 4(1), 30-38 (1983)
1000
(Ag,Au)
975
961.93°C
950
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Gold Au
0
Weight Percent Boron
10 20 30 40 50 60 80100
Ag-B
2500
L1 L2
L1 + L2
2092°C
2000 Ag-B
Struktur-
Phase at.% B symbol group designation Prototype
1500 (Ag) 0 cF4 Fm 3 m A1 Cu
AgB2 66.6 hP3 P6/mmm C32 AlB2
(bB) 100 hR108 R 3m … …
1000
961.93°C
H. Okamoto, J. Phase Equilibria, 13(2), 211-212 (1992)
?
500
(Ag) (bB)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Boron B
0 10 20 30
Weight Percent Barium
40 50 60 70 80 90 100
Ag-Ba
1000
961.93°C
900
Ag-Ba
800 Struktur-
770°C L
715°C,16.7 727°C
700 700°C Phase at.% Ba symbol group designation Prototype
14
655°C
19 23.5 (Ag) 0 cF4 Fm 3 m A1 Cu
600 Ag5Ba 13 to 19 hP6 P6/mmm D2d CaCu5
560°C 51 Ag2Ba 33.3 oI12 Imma … CeCu2
500
AgBa 50 oP8 Pnma B27 FeB
Ag2Ba3 60 hR45 R3 … Er3Ni2
400
(Ba) 100 cI2 Im 3 m A2 W
360°C 71
340°C
78 H. Okamoto, J. Phase Equilibria, 13(4), 434-435 (1992)
300
(Ag)
200 (Ba)
100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Barium Ba
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ag
0
Weight Percent Beryllium
10 20 30 40 50 70 100
Ag-Be
1300
1289°C
(bBe) 1270°C
1200
Ag-Be
L Struktur-
1100 Phase at.% Be symbol group designation Prototype
(Ag) 0 to 0.3 cF4 Fm 3 m A1 Cu
1010°C
d 73 cF24 Fd 3 m C15 Cu2Mg
1000 (bBe) 100 cI2 Im 3 m A2 W
961.93°C (aBe) 100 hP2 P63 /mmc A3 Mg
d
900 H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
880°C
0.3 10.5 73 Okamoto and L. Tanner, ed., ASM International, Materials Park, OH, 4-8 (1987)
(aBe)
(Ag)
800
760°C
700
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Beryllium Be
0 10 20 30 40
Weight Percent Bismuth
50 60 70 80 90 100
Ag-Bi
1000
961.93°C
900
Ag-Bi
800
Struktur-
L
700 Phase at.% Bi symbol group designation Prototype
(Ag) 0 to 2.76 cF4 Fm 3 m A1 Cu
600 (Bi) 100 hR2 R 3m A7 aAs
(Ag)
I. Karakaya and W.T. Thompson, J. Phase Equilibria, 14(4), 525-530 (1993)
500
400
300
262.5°C 271.442°C
0.99 95.05
(Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Bismuth Bi
0 0.001
Weight Percent Carbon
0.002 0.003 0.004 0.005
Ag-C
1500
1300 Ag-C
Struktur-
L + (C)
Phase at.% C symbol group designation Prototype
1100 (Ag) 0 to 0.036 cF4 Fm 3 m A1 Cu
(C) ? to 100 hP4 P63/mmc A9 C (graphite)
962.23°C
961.93°C 0.036
I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9(3), 226-227
900
(Ag) (1988)
700 (Ag) + (C)
500
0 0.01 0.02 0.03 0.04 0.05
Ag Atomic Percent Carbon

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
4
Ag
0 10
Weight Percent Calcium
20 30 40 50 60 70 80 90 100
Ag-Ca
1000
961.93°C
900 Ag-Ca
Struktur-
L 842°C Composition, Pearson Space bericht
Phase at.% Ca symbol group designation Prototype
800
(Ag) 0 cF4 Fm 3 m A1 Cu
725°C
Ag9Ca2 18.2 … … … …
Ag7Ca2 22.2 … … … …
700 687 Ag2Ca 33.3 oI12 Imma … Hg2K
666°C
655°C AgCa 50 oC8 Cmcm Bf CrB
14 Ag3Ca5 62.5 tI32 I4/mcm D8 l Cr5B 3
600 597°C AgCa3 75 … … … …
(bCa)
555°C
(bCa) 100 cI2 Im 3 m A2 W
545°C
39.5 (aCa) 100 cF4 Fm 3 m A1 Cu
(Ag)
500
475°C 470°C
80 M.R. Baren, Bull. Alloy Phase Diagrams, 9(3), 228-231 (1988)
443°C
(aCa)
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Calcium Ca
0 10 20 30
Weight Percent Cadmium
40 50 60 70 80 90 100
Ag-Cd
1000
961.93°C
Ag-Cd
900
Struktur-
800 L Phase at.% Cd symbol group designation Prototype
37.4
736 43.5 (Ag) 0 to 42.2 cF4 Fm 3 m A1 Cu
700 b 40 to 55 cI2 Im 3 m A2 W
640 63.1 b’ 48.5 to 50 cI* … … …
b
600 590°C 71.2 z 49.5 to 56 hP* … … …
g g’ 57 to 62.5 … … … …
500
470°C
470°C
g 57 to 62.5 cI52 I 4 3m D82 Cu5Zn8
(Ag) 440°C
41.55
48.5 50 436 e 64.5 to 81 hP2 P63/mmc A3 Mg
400
(Cd) 93 to 100 hP2 P63/mmc A3 Mg
z 343°C 97.4
e 93 321.108°C
300 g' (Cd) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
42.2 240°C 49.5 Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
48.5 230°C
200 22-23 (1990)
b'
100
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ag Atomic Percent Cadmium Cd
0 10 20 30 40
Weight Percent Cerium
50 60 70 80 90 100
Ag-Ce
1200
1040°C Ag-Ce
1000 L Struktur-
961.93°C Composition, Pearson Space bericht
848°C 35.3 850°C Phase at.% Ce symbol group designation Prototype
8.9 816°C (dCe) (Ag) 0 cF4 Fm 3 m A1 Cu
800 797
798°C
8.2 791°C 41.2 Ag4Ce 20 … … … …
726°C
Ag51Ce14 21.5 hP65 P6/m … Ag51Gd 14
85.7 Ag2Ce 33.3 oI12 Imma … CeCu2
600 619°C AgCe 50 cP2 Pm 3 m B2 CsCl
516°C
(dCe) 95 to 100 cI2 Im 3 m A2 W
78.6
(gCe) 98 to 100 cF4 Fm 3 m A1 Cu
400
(gCe) (bCe) 100 hP4 P6 3/mmc A3’ aLa
(aCe)* 100 cF4 Fm 3 m A1 Cu
(Ag) * Not shown.
200
H. Okamoto, J. Phase Equilibria, 24(2), 195 (2003)
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Cerium Ce
Ag
0 10 20
Weight Percent Cobalt
30 40 50 60 70 80 90 100
Ag-Co
1700
L1 L1 + L2 L2
1500 1489°C 1495°C

Ag-Co
Struktur-
1300 Phase at.% Co symbol group designation Prototype
(Ag) 0 to 0.81 cF4 Fm 3 m A1 Cu
(aCo) 100 cF4 Fm 3 m A1 Cu
1100 (eCo) 100 hP2 P63/mmc A3 Mg
967°C
961.93°C 0.81
900
(1986)
700 (Ag) (aCo)
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Cobalt Co
0 10
20 30 40 50 60 70 80 90 100
Ag-Cr
2000
L1 L2
1863°C
L1 + L2
Ag-Cr
Struktur-
1500
1450°C Phase at.% Cr symbol group designation Prototype
3 97 Fm 3 m
(Ag) 0 to 0.01 cF4 A1 Cu
(Cr) 100 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 11(3), 263-265
(1990)
1000 960.9°C
961.93°C
(Ag) (Cr)
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Chromium Cr
0 10 20
Weight Percent Copper
30 40 50 60 70 80 90 100
Ag-Cu
1200
1084.87°C
1000
L Ag-Cu
961.93°C Struktur-
Phase at.% Cu symbol group designation Prototype
800 779.1°C
(Ag) 0 to 14.1 cF4 Fm 3 m A1 Cu
(Ag) (Cu)
14.1 39.9 95.1 (Cu) 95.1 to 100 cF4 Fm 3 m A1 Cu
P.R. Subramanian and J.H. Perepezko, Phase Diagrams of Binary Copper

600 Alloys, P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed., ASM
International, Materials Park, Ohio, 5-17 (1994)
400
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Copper Cu
6
Ag
0 10 20 30 40
Weight Percent Dysprosium
50 60 70 80 90 100
Ag-Dy
1500
(bDy)
1400 1412°C
1381°C
Ag-Dy
1300 L Struktur-
1200 1182°C Phase at.% Dy symbol group designation Prototype
1100
Ag51 Dy14 21.5 to 25.5 hP65 P6/m … Ag51Gd14
905°C
Ag2Dy 32.5 to 34.3 tI6 I4/mmm C11b MoSi2
1000 990°C
970°C Pm 3 m
961.93°C 950°C AgDy 50 cP2 B2 CsCl
37.5
900 885°C
(bDy) 100 cI2 Im 3 m A2 W
28.6
71 (aDy) 100 hP2 P63/mmc A3 Mg
800
802°C (a’Dy) 100 oC4 Cmcm … …
1.3 12
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
700 K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(1),
(Ag) (aDy) 15-17 (1985)
600
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Dysprosium Dy
0 10 20 30 40
Weight Percent Erbium
50 60 70 80 90 100
Ag-Er
1600
1529°C
1400 Ag-Er
L Struktur-
1195°C Phase at.% Er symbol group designation Prototype
1200
Ag51 Er14 21.5 to 25.5 hP65 P6/m … Ag51Gd14
1020°C Ag2Er 33.3 tI6 I4/mmm C11b MoSi2
1000 993°C
961.93°C 37 AgEr 50 cP2 Pm 3 m B2 CsCl
930°C 932°C
890°C 76 (Er) 100 hP2 P63/mmc A3 Mg
26.5
800 795°C
3.6 11.5 K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(1),
17-19 (1985)
(Er)
600 (Ag)
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Erbium Er
0 10 20 30
Weight Percent Europium
40 50 60 70 80 90 100
Ag-Eu
1000
961.93°C
900
Ag-Eu
L 822°C
800 792°C Struktur-
722°C
745°C
712°C Phase at.% Eu symbol group designation Prototype
700 12.5 699°C
25.5 673°C (Ag) 0 cF4 Fm 3 m A1 Cu
648°C
48 Ag5Eu 16.7 hP6 P6/mmm D2d CaCu5
600 Ag4Eu 20 tI10 I4/m D1a MoNi4
570°C
Ag2Eu 33.3 to 38 oI12 Imma … CeCu2
(Ag) AgEu 50 oP8 Pnma B27 FeB
500 Ag2Eu3 60 tP10 P4/mbm D5a U3Si2
429°C (Eu) 100 cI2 Im 3 m A2 W
79
400
K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(1),
(Eu) 19-21 (1985)
300
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Europium Eu
Ag
0 10 20
Weight Percent Iron
30 40 50 60 70 80 90 100
Ag-Fe
L1 L1 + L2 L2
1600
1533°C 1538°C
0.9 Ag-Fe
(dFe) Struktur-
1400
1398°C
1394°C
0.5
Phase at.% Fe symbol group designation Prototype
(dFe) 100 cI2 Im 3 m A2 W
1200
(gFe) 100 cF4 Fm 3 m A1 Cu
(gFe)
(aFe) 100 cI2 Im 3 m A2 W
1000
961.93°C
961°C L.J. Swartzendruber, Bull. Alloy Phase Diagrams, 5(6), 560-564 (1984)
911.5°C
912°C
800 Tc 770°C
771°C
(Ag) (aFe)
600
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Iron Fe
0 10 20
Weight Percent Gallium
30 40 50 60 70 80 90 100
Ag-Ga
1000
961.93°C
800 Ag-Ga
L Struktur-
611°C 27
Phase at.% Ga symbol group designation Prototype
600 18.7
(Ag) 0 to 18.7 cF4 Fm 3 m A1 Cu
z z 22.1 to 36.1 hP2 P63 /mmc A3 Mg
(Ag)
z’ 24.6 to 33.1 hP9 P3 Bb zAgZn
419°C Ag3Ga2 40 … … … …
400 16.4 36.1 58.4
393°C (Ga) 100 oC8 Cmca A11 aGa
301°C
z' 33.1 H. Okamoto, J. Phase Equilibria Diffusion, 29(1), 111 (2008)
200
29°C (Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Gallium Ga
0 10 20 30 40
Weight Percent Gadolinium
50 60 70 80 90 100
Ag-Gd
1400
1300 (bGd) 1313°C
1235°C
Ag-Gd
1200 Struktur-
1100°C
1100 Phase at.% Gd symbol group designation Prototype
(Ag) 0 to 0.95 cF4 Fm 3 m A1 Cu
1000 975°C Ag51Gd 14 21.5 to 25 hP65 P6/m … Ag51Gd 14
961.93°C Ag2Gd 33.3 tI6 I4/mmm C11 b MoSi2
900 AgGd 50 cP2 Pm 3 m B2 CsCl
805°C
830°C 35 825°C (bGd) 100 cI2 Im 3 m A2 W
800 37 790°C
0.95 11
77.5 (aGd) 100 hP2 P6 3/mmc A3 Mg
700
600 (Ag) (aGd) 138-140 (1985)
500
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Gadolinium Gd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
8
Ag Weight Percent Germanium
Ag-Ge
0 10 20 30 40 50 60 70 80 90 100
1000
961.93°C
938.3°C
L
Ag-Ge
800
Struktur-
651°C
Phase at.% Ge symbol group designation Prototype
(Ag) 9.6 24.5 (Ag) 0 to 9.6 cF4 Fm 3 m A1 Cu
600
(Ge) 100 cF8 Fd 3 m A4 C (diamond)
R.W. Olesinski and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 9(1), 58-64
400 (1988)
(Ge)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Germanium Ge
1300 1200 1100 1000 900

Temperature, °C
800 700 600 500
Ag-H
-4.0
L+G
-4.5
L
Ag-H
Struktur-
-5.0 Composition, Pearson Space bericht
Phase at.% H symbol group designation Prototype
(Ag) 0 to ? cF4 Fm 3 m A1 Cu
(Ag) + G
-5.5
P.R. Subramanian, J. Phase Equilibria, 12(6), 649-651 (1991)
-6.0
(Ag)
-6.5
-7.0
6 7 8 9 10 11 12 13 14
10000 / T(K)
0 10 20 30 40
Weight Percent Hafnium
50 60 70 80 90 100
Ag-Hf
950
Ag-Hf
Struktur-
Phase at.% Hf symbol group designation Prototype
877°C (Ag) 0 to ? cF4 Fm 3 m A1 Cu
AgHf 50 tP4 P4/nmm B11 gCuTi
AgHf2 66.7 tI6 I4/mmm C11b MoSi2
850 (Ag) (aHf) (bHf) 100 cI2 Im 3 m A2 W
(aHf) 100 hP2 P63/mmc A3 Mg

800
750
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Hafnium Hf

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ag
0 10 20 30 40
Weight Percent Mercury
50 60 70 80 90 100
Ag-Hg
961.93°C
900
Ag-Hg
L Struktur-
700
Phase at.% Hg symbol group designation Prototype
(Ag) 0 to 37.3 cF4 Fm 3 m A1 Cu
z 42.5 to 46.0 hP2 P63/mmc A3 Mg
500
g 55.1 to 56.8 cI* I23 … …
(aHg) 100 hR1 R 3m A10 aHg
356.623°C (bHg) 100 tI2 I4/mmm … bHg
B.P.
300 (Ag) 276°C
37.3 44.8 96 M.R. Baren, J. Phase Equilibria, 17(2), 122-128 (1996)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
127°C
100 46 56.8 99.3
z
g -39°C
-38.8290°C
(aHg)
-100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Mercury Hg
0 10 20 30 40
Weight Percent Holmium
50 60 70 80 90 100
Ag-Ho
1600
1474°C
1400
Ag-Ho
L Struktur-
Phase at.% Ho symbol group designation Prototype
1200 1165°C (Ag) 0 to 1.6 cF4 Fm 3 m A1 Cu
Ag51Ho14 21 to 24.5 hP65 P6/m … Ag51 Gd14
Ag2Ho 33.3 tI6 I4/mmm C11b MoSi2
990°C Pm 3 m
1000 970°C AgHo 50 cP2 B2 CsCl
961.93°C 36.5
920°C (Ho) 100 hP2 P63/mmc A3 Mg
890°C 880°C
26.5 81.0
800 795°C K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(2),
1.6 11.5
140-141 (1985)
(Ho)
600 (Ag)
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Holmium Ho
0 10 20 30
Weight Percent Indium
40 50 60 70 80 90 100
Ag-In
1000
961.93°C
900 Ag-In
Struktur-
b L Phase at.% In symbol group designation Prototype
700 21
695°C 29.5 660°C (Ag) 0 to 21 cF4 Fm 3 m A1 Cu
25
20.9
25 29
32.5
b 25 to 29 cI2 Im 3 m A2 W
670°C
600 Ag3In 25 cP4 Pm 3 m L12 AuCu3
z 25 to 45.9 hP* … … …
500 z’ ? hP8 P63 /mmc D019 Ni3Sn
z
(Ag) Ag2In 31.1 to 33.6 cP52 P 4 3m D83 Cu9Al4
400
AgIn2 66.7 tI12 I4/mcm C16 CuAl2
312°C (In) 100 tI2 I4/mmm A6 In
300
205°C M.R. Baren, Phase Diagrams of Indium Alloys and Their Engineering
200 187°C 200°
20
z'
33.5 45.9 166°C 92.2
156.634°C
Applications, C.E.T. White and H. Okamoto, ed., ASM International, Materials
33.5
144°C 96.8 Park, OH, 15-19 (1992)
100
(In)
See also
0
0 10 20 30 40 50 60 70 80 90 100
H. Okamoto, J. Phase Equilibria Diffusion, 27(5), 536 (2006)
Ag Atomic Percent Indium In
10
Ag Weight Percent Iridium
Ag-Ir
0 10 20 30 40 50 60 70 80 90 100
2500
L2 2447°C
2386°C
96.5
G
2177°C
2163°C 8.9 Ag-Ir
L1
2000 Struktur-
Phase at.% Ir symbol group designation Prototype
(Ir) 100 cF4 Fm 3 m A1 Cu
1500 L1 + (Ir)
(1986)
1000 961°C
961.93°C
(Ag) (Ir)
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Iridium Ir
0 10 20 30
Weight Percent Lanthanum
40 50 60 70 80 90 100
Ag-La
1000°C 1005°C
1000
961.93°C
Ag-La
L (gLa) 918°C Struktur-
880°C 875°C
860°C
865°C Composition, Pearson Space bericht
825°C 854°C
800 792°C 40.5 807°C Phase at.% La symbol group designation Prototype
800°C 43
786°C 8.1 793°C (Ag) 0 to 0.05 cF4 Fm 3 m A1 Cu
bAg5La 16.7 … … … …
aAg5La 16.7 hP* … … …
600
Ag51 La14 ~21.5 hP65 P6/m … Ag51 Gd14
535°C 76.5
529°C 76
Ag2La 33.3 oI12 Imma … CeCu2
AgLa 50 cP2 Pm 3 m B2 CsCl
400 (Ag) (bLa) (gLa) 97 to 100 cI2 Im 3 m A2 W
(bLa) 100 cF4 Fm 3 m A1 Cu
310°C
(aLa) 100 hP4 P63/mmc A3’ aLa
200
(aLa) H. Okamoto, J. Phase Equilibria, 22(6), 688 (2001)
1983Gsc
2000Li
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Lanthanum La
0
Weight Percent Lithium
5 10 20 30 40 60 80 100
Ag-Li
1000
961.63°C
900
Ag-Li
800
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Phase at.% Li symbol group designation Prototype

700
L (Ag) 0 to 61 cF4 Fm 3 m A1 Cu
600 b 50 to 77 cP2 Pm 3 m B2 CsCl
g3 63.5 to 76 cP52? P 4 3m? D83 ? …
500 g2 76 to 86 cI52? I 4 3m? D82 ? …
g1 87 to 94 c** … … …
400
(bLi) 91 to 100 cI2 Im 3 m A2 W
330°C
(Ag) 317 67.6 (aLi) 100 hP2 P63 /mmc A3 Mg
300 60.8
b 201°C A.D. Pelton, Bull. Alloy Phase Diagrams, 7(3), 223-228 (1986)
200
65.5 164°C 180.6°C
154°C
86 145.5°C (bLi)
100 g3 g2
g1
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Lithium Li
Ag
0 2 4
Weight Percent Lutetium
6 8 10 12
Ag-Lu
1100
L
1000
Ag-Lu
961.93°C
Struktur-
Phase at.% Lu symbol group designation Prototype
814°C
(Ag) 0 to 5.78 cF4 Fm 3 m A1 Cu
800 5.78
Ag4 Lu 20 tI10 I4/m D1a MoNi4
(Ag) Ag2 Lu 33.3 tI6 I4/mmm C11b MoSi2
700 AgLu 50 cP2 Pm 3 m B2 CsCl
(Lu) 100 hP2 P63/mmc A3 Mg
600
(Ag) + Ag4 Lu
374-375 (1983)
500
400
300
0 1 2 3 4 5 6 7 8
Ag Atomic Percent Lutetium
0
Weight Percent Magnesium
10 20 30 40 50 60 70 80 90 100
Ag-Mg
1000
961.93°C
900 Ag-Mg
Struktur-
820°C
L Composition, Pearson Space bericht
800 50
33.4 Phase at.% Mg symbol group designation Prototype
29.3 759.3 35.5 Fm 3 m
(Ag) 0 to 29.3 cF4 A1 Cu
700 Ag3Mg 19 to 27 cP4 Pm 3 m L12 AuCu3
650° C AgMg 35.5 to 65.43 cP2 Pm 3 m B2 CsCl
600 AgMg e’ 75.8 to 78.2 tI* … … …
(Ag) e 75.8 to 78.2 cF* … … …
494°C 77.43
472°C AgMg4 80 hP* … … …
500 65.43
484°C 82.43 96.17 (Mg) 96.17 to 100 hP2 P63/mmc A3 Mg
447°C 465°C
e'
400 392°C A.A. Nayeb-Hashemi and J.B. Clark, Bull. Alloy Phase Diagrams, 5(4),
e (Mg) 348-358 (1984)
300 See also
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Magnesium Mg
0 10 20
Weight Percent Manganese
30 40 50 60 70 80 90 100
Ag-Mn
1300
L2
1246°C
1207°C
52.4 94.8 98.8
L1 1128°C
(dMn) 1138°C Ag-Mn
1100 46.3 (gMn) 1100°C
1069°C Struktur-
42.6 Composition, Pearson Space bericht
38 989°C
43.6 99.6
Phase at.% Mn symbol group designation Prototype
961.93°C
(Ag) 0 to 43.6 cF4 Fm 3 m A1 Cu
900
(bMn) (dMn) 98.8 to 100 cI2 Im 3 m A2 W
(gMn) 99.3 to 100 cF4 Fm 3 m A1 Cu
(Ag) (bMn) 99.6 to 100 cP20 P4132 A13 bMn
724°C
700 30.9
727°C
(aMn) 100 cI58 I 4 3m A12 aMn
(1990)
500 (aMn)
300
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Manganese Mn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
12
Ag
0 10 20
30 40 50 60 70 80 90 100
Ag-Mo
2900
2700
2623°C
L Ag-Mo
2500
Struktur-
2300
2100
(Mo) 100 cI2 Im 3 m A2 W
1900
M.R. Baren, Bull. Alloy Phase Diagrams, 11(6), 548-549 (1990)
1700 (Mo)
1500
1300
1100
(Ag)
961.93°C 958.5°C
900
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Molybdenum Mo
0
Weight Percent Sodium
10 20 30 40 50 60 70 80 100
Ag-Na
1050
961.93°C
L Ag-Na
850 Struktur-
Phase at.% Na symbol group designation Prototype
(Ag) 0 cF4 Fm 3m A1 Cu
650
Ag2Na 33.3 cF24 Fd 3 m C15 Cu2 Mg
(bNa) 100 cI2 Im 3m A2 W
450
A.D. Pelton, Bull. Alloy Phase Diagrams, 7(2), 133-136 (1986)
322°C
250
(Ag)
97.7°C
97.8°C
(bNa)
50
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Sodium Na
0 10 20 30
Weight Percent Neodymium
40 50 60 70 80 90 100
Ag-Nd
1100
1025°C
1021°C
1000 L Ag-Nd
961.93°C 952°C (bNd) Struktur-
Phase at.% Nd symbol group designation Prototype
900
863°C
Ag51Nd 14 21.5 to 25.5 hP65 P6/m … Ag51Gd 14
825°C
806°C 810°C bAg 2Nd 33.3 hP* … … …
800 0.2 40.8
10.5
aAg 2Nd 33.3 oI12 Imma … CeCu2
?
741°C AgNd 50 cP2 Pm 3 m B2 CsCl
(bNd) 96.5 to 100 cI2 Im 3 m A2 W
700
(aNd) 98.7 to 100 hP4 P6 3/mmc A3’ aLa
(Ag) 635°C 640°C
80
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600
21-23 (1985)
(aNd)
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Neodymium Nd
Ag
0 10 20
Weight Percent Nickel
30 40 50 60 70 80 90 100
Ag-Ni
1700
L1 L1 + L2 L2
1500 Ag-Ni
1435°C 97 1455°C
3.89 99 Struktur-
1300 Phase at.% Ni symbol group designation Prototype
(Ni) 99 to 100 cF4 Fm 3 m A1 Cu
1100
M. Singleton and P. Nash, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed.,
0.321 960°C ASM International, Materials Park, OH, 1-3 (1991)
961.93
0.2
900
(Ag) (Ni)
700
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Nickel Ni
0 0.1
Weight Percent Oxygen
0.2 0.3
Ag-O
1300
Ag-O
1200
Struktur-
Phase at.% O symbol group designation Prototype
(Ag) 0 to ? cF4 Fm 3 m A1 Cu
L+G
Ag2O 33.3 cP6 Pm 3 m C3 Ag 2O
L
1100 (aO) 100 mC4 C2/m … aO
1000
961.93°C
939°C
(Ag) (Ag) + G
900
0 0.5 1 1.5 2 2.5
Ag Atomic Percent Oxygen
0 10 20 30 40
Weight Percent Osmium
50 60 70 80 90 100
Ag-Os
3200
L2
3028°C 3033°C
99.5
Ag-Os
2800
Struktur-
G G + (Os)
Phase at.% Os symbol group designation Prototype
2400 (Ag) 0 cF4 Fm 3 m A1 Cu
(Os) 100 hP2 P6 3/mmc A3 Mg
2175°C
2163°C 7.1
L1
2000 I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 7(4), 360-362
(1986)
1600
L1 +(Os) (Os)
1200
961°C
961.93°C
(Ag)
800
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Osmium Os
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
14
Ag
0 10
Weight Percent Phosphorus
20 30 40 50 60 70 80 90 100
Ag-P
1400
1200 Ag-P
L1 L1 + G
Struktur-
1000
961.93°C Phase at.% P symbol group designation Prototype
880°C (Ag) 0 cF4 Fm 3 m A1 Cu
800
AgP 2 66.7 m** … … …
(Ag) + G Ag3P11 78.4 m** … … …
P (black) 100 oC8 Cmca A17 P (black)
600 P (white) 100 c** … … …
554°C
P (red) 100 c*66 … … …
458°C
400 G I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9(3), 232-236
280°C
(1988)
(Ag) 277°C B.P.
200 L2
P (white)
44.1°C 44.14°C
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Phosphorus P
0 10 20 30 40 50
Weight Percent Lead
60 70 80 90 100
Ag-Pb
1000
961.93°C
900
Ag-Pb
800 Struktur-
700 Phase at.% Pb symbol group designation Prototype
600 (Ag) (Pb) 99.81 to 100 cF4 Fm 3 m A1 Cu
500 I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 8(4), 326-334
(1987)
400
304°C 327.502°C
300 0.8 95.5
99.81
200
(Pb)
100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Lead Pb
0 10 20 30
Weight Percent Palladium
40 50 60 70 80 90 100
Ag-Pd
1600
1555°C
1500 Ag-Pd
Struktur-
1400 L Phase at.% Pd symbol group designation Prototype
(Ag,Pd) 0 to 100 cF4 Fm 3 m A1 Cu
1300
(1988)
1200
1100 (Ag,Pd)
1000
961.93°C
900
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Palladium Pd

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ag Weight Percent Promethium
Ag-Pm
0 10 20 30 40 50 60 70 80 90 100
1200
L 1042°C
1000 990°C (bPm) Ag-Pm
960°C
961.93°C Struktur-
810°C Phase at.% Pm symbol group designation Prototype
800 770°C
755°C
736°C (Ag) 0 cF4 Fm 3 m A1 Cu
Ag51Pm14 21.5 to 25 hP65 P6/m … Ag51Gd14
650°C 645°C
bAg2Pm 33.3 … … … …
600
aAg2Pm 33.3 oI12 Imma … CeCu2
AgPm 50 cP2 Pm 3 m B2 CsCl
(bPm) ? to 100 cI2 Im 3 m A2 W
400
(aPm) (aPm) ? to 100 hP4 P63 /mmc A3’ aLa
(Ag)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Promethium Pm
0 10 20 30
Weight Percent Praseodymium
40 50 60 70 80 90 100
Ag-Pr
1200
1028°C
1000 L Ag-Pr
961.93°C 932°C Struktur-
931°C
9.4 831°C 837°C 35.7 Phase at.% Pr symbol group designation Prototype
819°C
798°C
800 38.3 795°C
7.7 (Ag) 0 to 0.05 cF4 Fm 3 m A1 Cu
(bPr)
Ag5Pr 16.7 … … … …
617°C
646°C Ag51Pr14 21.5 hP65 P6/m … Ag51Gd14
79 94.1 98.7
600 578°C bAg2Pr 33.3 hP* … … …
76.5
aAg2Pr 33.3 oI12 Imma … CeCu2
AgPr 50 cP2 Pm 3 m B2 CsCl
400 (bPr) 94.1 to 100 cI2 Im 3 m A2 W
(aPr) (aPr) 98.7 to 100 hP4 P63 /mmc A3’ aLa
(Ag)
200 H. Okamoto, J. Phase Equilibria, 23(3), 279 (2002)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Praseodymium Pr
0 10 20 30 40
50 60 70 80 90 100
Ag-Pt
1800
1769.0°C
1600
L Ag-Pt
Struktur-
1400
Phase at.% Pt symbol group designation Prototype
1200 31.0 1188°C (Ag) 0 to 40 cF4 Fm 3 m A1 Cu
40.0 87.0 (Pt) Ag15Pt1 7 53 **32 … … …
(Pt) 87 to 100 cF4 Fm 3 m A1 Cu
1000
961.93°C
803°C
800
30.0 53.0 93.9
(Ag)
600
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Platinum Pt

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
16
Ag
0 10 20 30 40 50
Weight Percent Plutonium
60 70 80 90 100
Ag-Pu
1100
1000 977°C Ag-Pu

961.93°C L Struktur-
900 L1 + L2 Composition, Pearson Space bericht
817°C Phase at.% Pu symbol group designation Prototype
801°C 795°C
800 9.2 41 (Ag) 0 cF4 Fm 3 m A1 Cu
Ag51Pu14 21.5 hP65 P6/m … Ag51 Gd14
700
659°C Ag2Pu 33.3 … … … …
640°C
600 (ePu)
(ePu) 95.5 to 100 cI2 Im 3 m A2 W
(d’Pu) 100 tI2 I4/mmm A6 In
500
483°C (dPu) 100 cF4 Fm 3 m A1 Cu
463°C
(d'Pu) (gPu) 100 oF8 Fddd … gPu
400
(dPu) (bPu) 100 mC34 C2/m … bPu
320°C
300 (Ag) (aPu) 100 mP16 P21 /m … aPu
(gPu)
215°C
200
(bPu) D.H. Wood, E.M. Cramer, and P.L. Wallace, Nucl. Metall., 17, 707-719 (1970)
125°C
100
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Plutonium Pu

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 1
Weight Percent Rhenium
2 3
Ag-Re
2500
G + (Re)
2163°C
2163°C 0.25 Ag-Re
2000
L Struktur-
Phase at.% Re symbol group designation Prototype
(Re) 100 hP2 P6 3/mmc A3 Mg
L + (Re)
1500
(1988)
1000 961°C
961.93°C
(Ag) (Ag) + (Re)
500
0 0.5 1 1.5 2
Ag Atomic Percent Rhenium
0 10 20 30
Weight Percent Rhodium
40 50 60 70 80 90 100
Ag-Rh
2200
L1 + L2 L2
2000 L1
1900°C 1963°C
80
1800 Ag-Rh
Struktur-
1600
L1 + (Rh) Phase at.% Rh symbol group designation Prototype
1400
1200 (Rh) ? to 100 cF4 Fm 3 m A1 Cu
1000
961.93°C (Rh) I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 7(4), 362-365
(1986)
800
600
400
(Ag)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Rhodium Rh
Ag
0 1
Weight Percent Ruthenium
2 3 4
Ag-Ru
980
L1 + L2
961.93°C
960 L1 Ag-Ru
Struktur-
L1 + ? Phase at.% Ru symbol group designation Prototype
940 (Ag) 0 cF4 Fm 3 m A1 Cu
(Ru) 100 hP2 P6 3/mmc A3 Mg
920°C I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 7(4), 365-368
920
3.1 (1986)
900
(Ag) (Ag) + ?
880
0 0.5 1 1.5 2 2.5 3 3.5 4 4. 5 5
Ag Atomic Percent Ruthenium
0 10
Weight Percent Sulfur
20 30 40 50 60 70 80 90 100
Ag-S
1200
L1
L1 + L2
1000 L2 Ag-S
961.93°C L2 + L3
906°C Struktur-
5.8 31
800
806°C Phase at.% S symbol group designation Prototype
32
742°C (Ag) 0 to 0.14 cF4 Fm 3 m A1 Cu
36
gAg 2S 33.27 to 33.57 cF12 … … …
600 571°C
622°C
bAg 2S 33.27 to 33.51 cI6 … … …
aAg2S 33.3 mP24 P21c … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(bS) 100 mP48 P21a … …
400 L3
(aS) 100 oF128 Fddd A16 aS
(Ag)
R.C. Sharma and Y.A. Chang, Bull. Alloy Phase Diagrams, 7(3), 263-269
200 178°C
(1986)
176°C
115°C (bS)
115.22°C
95.5°C
(aS)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Sulfur S
0 10 20 30
Weight Percent Antimony
40 50 60 70 80 90 100
Ag-Sb
1000
961.93°C
900
Ag-Sb
Struktur-
800
Phase at.% Sb symbol group designation Prototype
702. 5
700 7.2 8.5 (Ag) 0 to 7.2 cF4 Fm 3 m A1 Cu
(Ag) z 8.5 to 16.4 hP2 P63 /mmc A3 Mg
630.755°C
600 e 20 to 25 tP4 P4/mmm L60 Cu3Ti
562°C
16.4 21.1
25
(Sb) 100 hR2 R 3m A7 aAs
500 484°C
25 38
z
400
e
(Sb)
300
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Antimony Sb
18
Ag Weight Percent Scandium
Ag-Sc
0 10 20 30 40 50 60 70 80 90 100
1600
1541°C
(bSc)
1400
L 1337°C Ag-Sc
1230°C Struktur-
1200 1155°C Composition, Pearson Space bericht
1130°C
40 Phase at.% Sc symbol group designation Prototype
(Ag) 0 to 10.4 cF4 Fm 3 m A1 Cu
1000
961.93 936°C 920°C
Ag4Sc 20 tI10 I4/m D1a MoNi4
10.4 12 926°C 80 Ag2Sc 33.3 tI6 I4/mmm C11 b MoSi2
(Ag) AgSc 50 cP2 Pm 3 m B2 CsCl
800
(bSc) 100 cI2 Im 3 m A2 W
(aSc) 100 hP2 P6 3/mmc A3 Mg
600
(aSc) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 4(4),
375-377 (1983)
400
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Scandium Sc
0 10 20
Weight Percent Selenium
30 40 50 60 70 80 90 100
Ag-Se
1000
961.93°C L1 L1 + L2 L2
890°C
840°C
G Ag-Se
800
Struktur-
L2 + L3 94.8
L3
685°C B.P. Phase at.% Se symbol group designation Prototype
616°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600 44.5 95.5
bAg 2Se 33.3 cI* … … …
aAg 2Se 33.3 o** … … …
(Ag) gSe
(Se) 100 hP3 P3121 A8
400
(1990)
217°C
221°C
200
130°C 132°C
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Selenium Se
0 10
Weight Percent Silicon
20 30 40 50 60 70 80 90 100
Ag-Si
1500
1414°C
1400
Ag-Si
L
1300 Struktur-
Phase at.% Si symbol group designation Prototype
1200
(Si) 100 cF8 Fd 3 m A4 C (diamond)
1100
R.W. Olesinski and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 10(6), 635-
1000
640 (1989)
961.93°C
900
835°C
11
800
(Ag) (Si)
700
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Silicon Si
Ag
0 10 20 30
Weight Percent Samarium
40 50 60 70 80 90 100
Ag-Sm
1200
1100 Ag-Sm
L 1074°C
Struktur-
(gSm)
1000
961.93°C
960°C Phase at.% Sm symbol group designation Prototype
935°C
922°C (Ag) 0 to 1 cF4 Fm 3 m A1 Cu
900 Ag51 Sm14 21.5 to 25.5 hP65 P6/m … Ag51 Gd14
bAg2Sm 33.3 hP* P63? … …
800 790°C
775°C (bSm)
aAg2Sm 33.3 … … … …
760°C
1 10
37 AgSm 50 cP2 Pm 3 m B2 CsCl
734°C
700 694°C (gSm) 100 … … … …
675°C
82 (bSm) 100 hP2 P63/mmc A3 Mg
(aSm) 100 hR3 R 3m C19 aSm
600 (Ag)
(aSm) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(2),
500 142-143 (1985)
400
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Samarium Sm
0 10 20 30
Weight Percent Tin
40 50 60 70 80 90 100
Ag-Sn
1000
961.93°C
Ag-Sn
800
Struktur-
11.5
724°C L Composition, Pearson Space bericht
13 19.5
Phase at.% Sn symbol group designation Prototype
(Ag) 0 to 11.5 cF4 Fm 3 m A1 Cu
600
z 11.8 to 22.85 hP2 P63/mmc A3 Mg
(Ag) 480°C
e 23.2 to 25 oP8 Pmmn D0a bCu3Ti
22.85
25 49.6 (bSn) 99.91 to 100 tI4 I41/amd A5 bSn
400 z (aSn) 100 cF8 Fd 3 m A4 C (diamond)
e
221°C 231.9681°C (1987)
200 96.2
(bSn)
(aSn)
13°C
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Tin Sn
0 10 20
Weight Percent Strontium
30 40 50 60 70 80 90 100
Ag-Sr
1000
961.93°C
900 Ag-Sr
L Struktur-
800 784°C Phase at.% Sr symbol group designation Prototype
760°C 769°C
748°C (Ag) 0 cF4 Fm 3 m A1 Cu
11.3
713°C
700
702 Ag5Sr 16.7 hP6 P6/mmm D2d CaCu5
26.2 680°C 665°C Ag4Sr 20 … … … …
638°C 643 Ag2Sr 33.3 oI12 Imma … CeCu2
44.9 55.1
600 (bSr) AgSr 50 oP8 Pnma B27 FeB
Ag2Sr3 60 hR45 R3 … Er3Ni2
(Ag) 547°C
(bSr) 100 cI2 Im 3 m A2 W
500 (aSr) 100 cF4 Fm 3 m A1 Cu
436°C
76.2 H. Okamoto, J. Phase Equilibria Diffusion, 28(6), 594 (2007)
400
(aSr)
300
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Strontium Sr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
20
Ag
0 10 20 30 40
Weight Percent Terbium
50 60 70 80 90 100
Ag-Tb
1400
1356°C
(bTb)
1289°C Ag-Tb
L Struktur-
1145°C Phase at.% Tb symbol group designation Prototype
Ag51Tb14 21.5 to 26 hP65 P6/m … Ag51 Gd14
Ag2Tb 33.3 tI6 I4/mmm C11b MoSi2
1000 985°C AgTb 50 cP2 Pm 3 m B2 CsCl
961.93 (bTb) 100 cI2 Im 3 m A2 W
915°C
885
900°C (aTb) 100 hP2 P63/mmc A3 Mg
35
31.5 860°C
75
801°C K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 6(1),
800
1.1 11 144-145 (1985)
(aTb)
(Ag)
600
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Terbium Tb
0 10 20 30
Weight Percent Tellurium
40 50 60 70 80 90 100
Ag-Te
1200
1100 G Ag-Te
L2
Struktur-
1000
L1 Composition, Pearson Space bericht
961.93°C
L1 + L2 960°C 988°C
Phase at.% Te symbol group designation Prototype
900 11.9 881°C 30.3 Fm 3 m
(Ag) 0 cF4 A1 Cu
11.5 869°C
802°C gAg2Te 33.3 to 33.8 … … … …
800
bAg2Te 33.3 to 33.7 cF12 … … …
700 689°C 40.3 aAg2Te 33.3 mP12 P21/c … Ag2Te
33.8
bAg1.9Te 34.35 to 34.7 … … … …
600 aAg1.9Te 34.35 to 34.7 hP55 P6/mmm … …
500 (Ag) bAg5Te3 37.65 to 38 … … … …
33.6 460°C
449.57°C aAg5Te3 37.4 to 38.03 … … … …
420°C 51.7
400 55.6 (Te) 100 hP3 P3121 A8 gSe
38 353°C
66.7
295°C
300
265 I. Karakaya and W.T. Thompson, J. Phase Equilibria, 12(1), 56-63 (1991)
200 178 (Te)
145°C
120
100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Tellurium Te
0 10 20 30 40 50
Weight Percent Thorium
60 70 80 90 100
Ag-Th
1800
1755°C
1700
Ag-Th
1600
Struktur-
1500
L Phase at.% Th symbol group designation Prototype
(bTh) Fm 3 m
1400 (Ag) 0 cF4 A1 Cu
1360°C Ag51Th14 21.5 hP65 P6/m … Ag51Gd 14
1300 Ag2Th 33.3 hP3 P6/mmm C32 AlB2
AgTh2 66.7 tI2 I4/mcm C16 Al2Cu
1200 (bTh) 100 cI2 Im 3 m A2 W
1110°C (aTh) Fm 3 m
100 cF4 A1 Cu
1100
1020°C 1035°C
1000 31
975°C 960°C
961.93°C
72
890°C 905°C
900 53
7.7
(aTh)
800 (Ag)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`
700
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Thorium Th
Ag
0 10
Weight Percent Titanium
20 30 40 50 60 70 80 90 100
Ag-Ti
1700
1670°C
1600
1500 L Ag-Ti
Struktur-
Phase at.% Ti symbol group designation Prototype
1300 (Ag) 0 to 5 cF4 Fm 3 m A1 Cu
(bTi)
AgTi 50 to 52 tP4 P4/nmm B11 gCuTi
1200
AgTi2 66.7 tI6 I4/mmm C11b MoSi2
(bTi) 82 to 100 cI2 Im 3 m A2 W
1100
(aTi) 95.3 to 100 hP2 P63 /mmc A3 Mg
1020°C
1000 84.5
960°C
961.93°C
5 50
940°C J.L. Murray and K.J. Bansali, Phase Diagrams of Binary Titanium Alloys, J.L.
52 88
900
882° C
Murray, ed., ASM International, Metals Park, OH, 178-183 (1987)
855°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
92.4 95.3
800
(Ag)
(aTi)
700
600
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Titanium Ti
0 10 20 30 40
Weight Percent Thallium
50 60 70 80 90 100
Ag-Tl
1000
961.93°C
900
800 L
Ag-Tl
700 Struktur-
Phase at.% Tl symbol group designation Prototype
600
(Ag) 7.8 (Ag) 0 to 7.8 cF4 Fm 3 m A1 Cu
(bTl) 100 cI2 Im 3 m A2 W
500
(aTl) 100 hP2 P6 3/mmc A3 Mg
400
M.R. Baren, Bull. Alloy Phase Diagrams, 10(6), 641-643 (1989)
300 291°C 304°C

5.1 97.4
230°C (bTl)
230°C
200
(aTl)
100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Thallium Tl
0 10 20 30 40
Weight Percent Thulium
50 60 70 80 90 100
Ag-Tm
1600
1545°C
Ag-Tm
1400
Struktur-
Phase at.% Tm symbol group designation Prototype
1200
(Ag) 0 to 4.57 cF4 Fm 3 m A1 Cu
Ag51Tm 14 21.5 hP65 P6/m … Ag5 1Gd 14
1000 Ag3Tm 25 cP4 Pm 3 m L12 AuCu3
961.93°C Ag3Tm* 25 oP8 Pmmn D0a TiCu 3
Ag2Tm 33.3 tI6 I4/mmm C11 b MoSi2
800 787°C AgTm 50 cP2 Pm 3 m B2 CsCl
4.57
(Tm) 100 hP2 P6 3/mmc A3 Mg
(Ag) * Low-temperature phase?
600
(Tm)
Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
400
107, 109 (1990)
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Thulium Tm
22
Ag Weight Percent Uranium
Ag-U
0 10 20 30 40 50 60 70 80 90 100
1200
L2
1132°C 1135°C
2.6 99.5
1100
L1
Ag-U
1000 Struktur-
961.93°C 2.3 950°C Composition, Pearson Space bericht
0.4 Phase at.% U symbol group designation Prototype
900
(gU)
(gU) 100 cI2 Im 3 m A2 W
800
(bU) 100 tP30 P42 /mnm Ab bU
776°C
776°C (aU) 100 oC4 Cmcm A20 aU
(bU)
700 M.R. Baren, Bull. Alloy Phase Diagrams, 10(6), 644-645 (1989)
668°C
668°C
600
(Ag) (aU)
500
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Uranium U
0 10
Weight Percent Vanadium
20 30 40 50 60 70 80 90 100
Ag-V
3000
2854°C
L1 L2
2500
L1 + L2
Ag-V
2163°C B.P. Struktur-
1851.5°C 92.38 1910°C
Phase at.% V symbol group designation Prototype
7.62 96.82
1500 (V) 96.82 to 100 cI2 Im 3 m A2 W
J.F. Smith, Bull. Alloy Phase Diagrams, 2(3), 343-344 (1981)

1000 961°C
961.93°C 99.61
500 (Ag) (V)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Vanadium V
0 10 20 30 40
Weight Percent Tungsten
50 60 70 80 90 100
Ag-W
5555°C B.P.
G
5000
Ag-W
G + L2 L2 Struktur-
Phase at.% W symbol group designation Prototype
3422°C
3422°C (Ag) 0 cF4 Fm 3m A1 Cu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(W) 100 cI2 Im 3 m A2 W

3000
G + (W)
S.V. Nagender Naidu and P. Rama Rao, Phase Diagrams of Binary Tungsten
2163°C 2200°C
B.P. Alloys, S.V. Nagender Naidu and P. Rama Rao, ed., Indian Institute of Metals,
2000 Calcutta, India, 5-6 (1991)
L1 L1 + (W)
1000 962°C
961.93°C
(Ag) (W)
0
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Tungsten W
Ag
0 10 20
Weight Percent Yttrium
30 40 50 60 70 80 90 100
Ag-Y
1600
1522°C
1478°C
1400 (bY) Ag-Y

L Struktur-
1200 1160°C Phase at.% Y symbol group designation Prototype
(Ag) 0 to 1.31 cF4 Fm 3 m A1 Cu
Ag51Y14 21.5 to 25.5 hP65 P6/m … Ag51Gd1 4
1000 960°C
961.93°C 940°C 945°C Ag2Y 33.3 tI6 I4/mmm C11b MoSi 2
35 885°C
29 72.5
AgY 50 cP2 Pm 3 m B2 CsCl
800
799°C 900°C (bY) 100 cI2 Im 3 m A2 W
1.31 11.5
(aY) 100 hP2 P6 3/mmc A3 Mg
600
(Ag)
(aY) 377-379 (1983)
400
200
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Yttrium Y
0 10 20 30 40
Weight Percent Ytterbium
50 60 70 80 90 100
Ag-Yb
1000
961.93°C
Ag-Yb
L Struktur-
(gYb)
800
729°C 795°C Phase at.% Yb symbol group designation Prototype
749°C
724°C (Ag) 0 to 1.92 cF4 Fm 3 m A1 Cu
685°C Ag9Yb2 18.2 … … … …
1.92 13 661°C Ag7Yb2 22.2 hP18 … … …
646°C
632°C
Ag2Yb 33.3 oI2 Imma … CeCu2
600 589°C
39.5 bAgYb 50 cP2 Pm 3 m B2 CsCl
552°C
aAgYb 50 oP8 Pnma B27 FeB
(Ag) Ag2Yb3 60 tP10 P4/mbm D5a Si2U 3
456°C Ag3Yb5 62.5 tI32 I4/mcm D8 l Cr5B 3
446°C
79
(gYb) 100 cI2 Im 3 m A2 W
400
(bYb) 100 cF4 Fm 3 m A1 Cu
(bYb) (aYb) 100 hP2 P6 3/mmc A3 Mg
200 147-149 (1985)
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Ytterbium Yb
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Weight Percent Zinc
0 10 20 30 40 50 60 70 80 90 100
Ag-Zn
1000
961.93°C
Massalski2
900 1998Gom
L
Ag-Zn
800
Struktur-
700 Phase at.% Zn symbol group designation Prototype
(Ag) 0 to 40.2 cF4 Fm 3 m A1 Cu
600 z 37 to 51.2 hP* … … …
b b 36.7 to 58.6 cI2 Im 3 m A2 W
500 g 58 to 64.7 cI52 I 4 3m D82 Cu5Zn8
(Ag)
419.58°C
e 66.2 to 90.5 hP2 P63/mmc A3 Mg
400 g (Zn) 96 to 100 hP2 P63/mmc A3 Mg
e
(Zn)
200
z
100
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Zinc Zn
24
Ag
0 10 20
Weight Percent Zirconium
30 40 50 60 70 80 90 100
Ag-Zr
1900
1855°C
Ag-Zr
1700
Struktur-
Phase at.% Zr symbol group designation Prototype
L
1500 (Ag) 0 to 0.1 cF4 Fm 3 m A1 Cu
AgZr 48.5 to 51.5 tP4 P4/nmm B11 gCuTi
AgZr2 66 to 67 tI6 I4/mmm C11b MoSi2
1300 (bZr) 80.2 to 100 cI2 Im 3 m A2 W
(aZr) 97.8 to 100 hP2 P63/mmc A3 Mg
63.5 1190°C
80.2 (bZr)
46.5 1136°C 66.7
1100
50 66 I. Karakaya and W.T. Thompson, J. Phase Equilibria, 13(2), 143-146 (1992)
See also
961.93°C 940°C
2.5 48.5
900
863°C
820°C 96.1
(Ag) 67 97.8
(aZr)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
700
0 10 20 30 40 50 60 70 80 90 100
Ag Atomic Percent Zirconium Zr
0 10 20 30 40 50
Weight Percent Arsenic
60 70 80 90 100
Al-As
2000
1800
L
Al-As
1600 Struktur-
Phase at.% As symbol group designation Prototype
1400
(Al) 0 cF4 Fm 3 m A1 Cu
AlAs 50 cF8 F 4 3m B3 ZnS (sphalerite)
1200
(As) 100 hR2 R3 m A7 aAs
1000
815°C 825°C T.P.
800
658°C
660.452°C
(As) 614 °C S.P.
600
(Al)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Arsenic As
Weight Percent Gold

0 20 40 50 60 70 80 90 95 100 Al-Au
1200
1991Oka1
2004Liu
1060°C
Al-Au
1064.43°C Struktur-
1000
Phase at.% Au symbol group designation Prototype
L (Al) 0 to 0.06 cF4 Fm 3 m A1 Cu
Al2Au 33 to 34 cF12 Fm 3 m C1 CaF2
AlAu 50 mP8 P21 /m … …
800 gAlAu2 65 to 66.8 tI6 I4/mmm C11b MoSi2
bAlAu2 65.1 to 66.1 oP32 Pnmn … …
aAlAu2 66.3 to 66.7 oP12 Pnma … …
660.452°C 650°C Al3Au8 72.7 hR132 R 3c … …
1.1 625°C 624°C gAlAu2
56 b 80 to 81.2 cI2 Im 3 m A2 W
600 575
569 °C AlAu4 80 cP20 P21 3 … …
545°C 545°C
525 87 (Au) 87 to 100 cF4 Fm 3 m A1 Cu
b (Au)
(Al) bAlAu2 510
aAlAu2 H. Okamoto, J. Phase Equilibria diffusion, 26(4), 391-393 (2005)

400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Gold Au
Al
0 10
20 30 40 50 60 70 80 90 100
Al-B
2400
2200
2075°C
2000 2047°C
L Al-B
1800 Struktur-
1600 Phase at.% B symbol group designation Prototype
1400
AlB2 66.7 hP3 P6/mmm C32 AlB2
1200 AlB12 92.3 tP216 P41 21 2 … …
(bB) 97 to 100 hR108 R3m … …
1000 972°C
800 H. Okamoto, J. Phase Equilibria Diffusion, 27(2), 195-196 (2006)

660.452°C 659.84°C
600
400
213°C
200
(Al)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Boron B
0 10 20 30 40 50 60 70
80 90 100
Al-Ba
1200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1104°C
Al-Ba
1000
Struktur-
914°C 37
L Phase at.% Ba symbol group designation Prototype
Al4Ba 20 tI10 I4/mmm D1 3 Al 4Ba
800 Al13Ba7 35 hP20 P 3 m1 … …
750°C 51 Al5Ba3 37.5 hP16 P6 3/mmc … …
730°C 52.3 727°C Al5Ba4 44.4 hP18 P6 3/mmc … …
659°C (Ba) 100 cI2 Im 3 m A2 W
660.452°C
0.2
600 V.P. Itkin and C.B. Alcock, J. Phase Equilibria, 14(4), 518-524 (1993)
538°C
71.5
(Al)
(Ba)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Barium Ba
0 10
20 30 40 50 60 70 80 90 100
Al-Be
1300 1987Mur
(bBe) 1287°C
2004Pan 1254°C
Al-Be
1200 L Struktur-
Phase at.% Be symbol group designation Prototype
1100 (Al) 0 cF4 Fm 3 m A1 Cu
(bBe) 100 cI2 Im 3 m A2 W
1000 (aBe) 100 hP2 P6 3/mmc A3 Mg
H. Okamoto, J. Phase Equilibria Diffusion, 27(4), 424-425 (2006)

900
800 (aBe)
700
660.452°C
2.7 644°C
(Al)
600
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Beryllium Be
26
Al
0 20 40 50 60 70
80 90 95 100
Al-Bi
1037°C
19.7
1000 L1
Al-Bi
L2
Struktur-
(Bi) 100 hR2 R3 m A7 aAs
660.452 657°C
0.45 84
600
400
270°C 271.442°C
(Al) (Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Bismuth Bi
89.78 89.80
Weight Percent Bromine
89.82 89.84 89.86 89.88
Al-Br
250
Al-Br
200 Struktur-
Phase at.% Br symbol group designation Prototype
L (Al) 0 cF4 Fm 3 m A1 Cu
AlBr 3 75 mP16 P21/a … …
150
J. Thonstad, Can. J. Chem., 42, 2739-2743 (1964)
100 97.91°C 98.01°C
50
74.75 74.80 74.85 74.90 74.95 75
Atomic Percent Bromine
0
10 20 30
Al-C
2500
L + (C)
L Al-C
2173°C
18.6 Struktur-
2000 Phase at.% C symbol group designation Prototype
Al4C 3 42.9 hR7 R 3m D7 1 Al 4C 3
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(C) 100 cF8 Fd 3 m A4 C (diamond)
Al4C3 + (C)
1500
1000
0 10 20 30 40 50
Al Atomic Percent Carbon
Al
0 10 20 30 40
50 60 70 80 90 100
Al-Ca
1200
1100 1081°C
Al-Ca
1000 Struktur-
L
900 Phase at.% Ca symbol group designation Prototype
842°C (Al) 0 cF4 Fm 3 m A1 Cu
800 Al4Ca 20 tI10 I4/mmm D13 Al4Ba
701°C
Al2Ca 33.3 cF24 Fd 3 m C15 Cu2Mg
700
9.9 Al14Ca13 48.1 m** … … …
660.452 632°C
613°C
61.6
Al3Ca8 72.7 aP22 P1 … Ca8In3
600 5.5 575°C
557°C 549°C (bCa) 100 cI2 Im 3 m A2 W
66.4 80.5 (aCa) Fm 3 m
100 cF4 A1 Cu
500 (bCa)
(Al) 443°C
400
300 (aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Calcium Ca
0 10 20 30 40 50 60
70 80 90 100
Al-Cd
1200
L
Al-Cd
1000
Struktur-
L1 + L2 Phase at.% Cd symbol group designation Prototype
800
(Cd) 100 hP2 P6 3/mmc A3 Mg
660.452 650°C
1.76 94.9
600
400
320.4°C
321.108°C
200
(Al)
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Cadmium Cd
0 10 20 30 40 50 60 70
80 90 100
Al-Ce
1600
1480°C Al-Ce
1400 Struktur-
1235°C Phase at.% Ce symbol group designation Prototype
1200 L Fm 3 m
1135°C (Al) 0 cF4 A1 Cu
bAl11Ce3 21.4 tI10 I4/mmm D13 Al4Ba
1020°C
1000 aAl11Ce3 21.4 oI28 Immm … aAl11La3
Al3 Ce 25 hP8 P63/mmc D019 Ni3Sn
845°C
(dCe) Al2 Ce 33.3 cF24 Fd 3 m C15 Cu2 Mg
800 798°C
726°C
AlCe 50 oC16 Cmc2 or Cmcm … …
685°C
660.452°C 640°C 97.5 bAlCe3 75 cP4 Pm 3 m L12 AuCu3
72.5 600°C
4
600
86 aAlCe3 75 hP8 P63/mmc D019 Ni3Sn
(dCe) 97.5 to 100 cI2 Im 3 m A2 W
400
(gCe) (gCe) 99.5 to 100 cF4 Fm 3 m A1 Cu
(bCe) 100 hP4 P63/mmc A3’ aLa
250°C
200 (aCe) 100 cF4 Fm 3 m A1 Cu
(Al)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Cerium Ce

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
28
Al Weight Percent Cobalt
Al-Co
0 10 20 30 40 50 60 70 80 90 100
1640°C
1600 50
1495°C
L Al-Co
80.5
1180°C AlCo Phase at.% Co symbol group designation Prototype
1200 23.8 (aCo)
20.8 1135 46.3 (Al) 0 cF4 Fm 3 m A1 Cu
1093 1121°C
16.5 Al9Co2 18.1 mP22 P21 /a … …
Tc
1000 970°C Al13Co4 23.5 mC93 Cm … …
10.5 Al3Co 25.6 … … … …
Al5Co2 27.5 to 28.6 hP28 P63/mmc D811 Al5Co2
800
AlCo 46.3 to 79.5 cP2 Pm 3 m B2 CsCl
657°C (aCo) 83 to 100 cF4 Fm 3 m A1 Cu
660.452°C
600
0.5 (eCo) 100 hP2 P63/mmc A3 Mg

400 (Al) 422° C
56 98
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Cobalt Co
0 10 20 30 40
50 60 70 80 90 100
Al-Cr
2000
1863°C
Al-Cr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1800
Struktur-
1600
1400
1320°C Al7Cr 12.5 to 14 mC104 C2/m … Al45V7
Al11Cr2 15.2 to 17 mP48 P2 … …
(Cr)
1200
1140°C Al4Cr 18.5 to 20 mP180 P2/m … …
1060°C Al11Cr4 25 aP30 P1 … …
1000 1040°C
910°C
aAl9Cr4 30 to 34 cI52 I 4 3m … …
895°C
bAl8Cr5 30 to 42 … … … …
799°C Al11Cr2 882°C 62
800
785
AlCr aAl8Cr5 30 to 42 hR26 R 3m D810 Al8Cr5
660.452°C 656°C 700 AlCr 60.5 to 63 cP2 Pm 3 m B2 CsCl
600 AlCr2 65.5 to 71.4 tI6 I4/mmm C11b MoSi2
(Al) X ~75 … … … …
400 350°C (Cr) 54.5 to 100 cI2 Im 3 m A2 W
Tc
X H. Okamoto, J. Phase Equil. Diffusion, 29(1), 112-113 (2008)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Chromium Cr
0 10 20 30 40 50 60 70
Weight Percent Cesium
80 90 100
Al-Cs
800
L
L1 + L2
700 675°C, 50at.%
660.452°C
660°C Al-Cs
600 Struktur-
Phase at.% Cs symbol group designation Prototype
500
(Cs) 100 cI2 Im 3 m A2 W
400
J. Sangster and A.D. Pelton, J. Phase Equilibria, 14(3), 365 (1993)
300 (Al) (Al) + L2
200
100
(Cs)
28.6°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Cesium Cs
Al Weight Percent Copper
Al-Cu
0 10 20 30 40 50 60 70 80 90 100
1100
1084.87°C Al-Cu
1049°C 1032
75
Struktur-
82 84.4
1000
e1 g0 b (Al) 0 to 2.48 cF4 Fm 3 m A1 Cu
900 L q 31.9 to 33.0 tI12 I4/mcm C16 Al2Cu
848°C
52.2 h1 49.8 to 52.4 oP16 or oC16 Pban or Cmmm … …
800 h2 49.8 to 52.3 mC20 Cm/2 … …
z1 55.2 to 56.8 hP42 P6/mmm … …
g1 z2
700 55.2 to 56.3 m** … … …
660.452
(Cu)
e1 59.4 to 62.1 c** … … …
624°C e2 e2
600 32.2 36.3 591°C 55.0 to 61.1 hP4 P63 /mmc B8 1 NiAs
h1 567°C d 59.3 to 61.9 hR* R 3m … …
548.2°C
33
563°C
49.8
d 76.1
80.3
2.48 17.1 31.9
530
g0 63 to 68.5 cI52 I 4 3m D82 Cu5Zn8
500 z1
g1 62.5 to 68.5 cP52 P 4 3m D83 Al4Cu9
(Al) b 69.5 to 82 cI2 Im 3 m A2 W
q h2 a2
400 76.5 to 78 … … … …
363°C 80.3
z2 (Cu) 80.3 to 100 cF4 Fm 3 m A1 Cu
a2
300
0 10 20 30 40 50 60 70 80 90 100 J.L. Murray, Phase Diagrams of Binary Copper Alloys, P.R. Subramanian, D.J.
Al Atomic Percent Copper Cu Chakrabarti, and D.E. Laughlin, ed., ASM International, Materials Park, OH,
18-42 (1994)
X.L. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, J. Alloys Compds, 264, 201-
208 (1998)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 20 40 50 60 70
80 90 100
Al-Dy
1800
1600
1500°C
Al-Dy
(bDy) Struktur-
L 1412°C
1381°C
1300°C
Phase at.% Dy symbol group designation Prototype
1200 (Al) 0 cF4 Fm 3 m A1 Cu
1110°C
1090°C bAl3Dy ~26 hR20 R 3m … Al3 Ho
1005°C 1025°C
1000
990°C 940°C
aAl3Dy 25 to 26 hP16 P63/mmc D0 24 Ni3 Ti
78 Al2Dy 33.3 cF24 Fd 3 m C15 Cu2 Mg
800 AlDy 50 oP16 Pmma … AlEr
Al2Dy3 60 tP20 P42/mnm … Al2 Zr3
660.452 636°C
600 2.5 AlDy2 66.7 oP12 Pnma C23 Co2 Si
(bDy) ~100 cI2 Im 3 m A2 W
400
(aDy) (aDy) ~100 hP2 P63/mmc A3 Mg
(Al)
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Dysprosium Dy
0 20 40 50 60 70
80 90 100
Al-Er
1600
1529°C
1455°C
Al-Er
1400 Struktur-
Phase at.% Er symbol group designation Prototype
1200 (Al) 0 cF4 Fm 3 m A1 Cu
Al3Er 25 cP4 Pm 3 m L1 2 AuCu3
Al2Er 32 to 36 cF24 Fd 3 m C15 Cu2Mg
1005°C AlEr 50 oP16 Pmma … AlEr
1000
Al2Er3 60 tP20 P4 2/mnm … Al2Zr3
AlEr2 66.7 oP12 Pnma C23 Co2Si
(Er)
(Er) 100 hP2 P63/mmc A3 Mg
800

660.452°C 655 °C
1
600
(Al)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Erbium Er
30
Al Weight Percent Europium
Al-Eu
0 20 40 50 60 70 80 90 100
1400
1300°C
1200
Al-Eu
L Struktur-
1000
? Phase at.% Eu symbol group designation Prototype
? 822°C
800 Al4Eu 20 tI10 I4/mmm D13 Al4 Ba
Al2Eu 33.3 cF24 Fd 3 m C15 Cu2 Mg
660.452 628°C
650°C AlEu 50 oP18 Pnnm … …
2.25 75
600 (Eu) 100 cI2 Im 3 m A2 W
400
(Al) (Eu)
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Europium Eu
0 10
20 30 40 50 60 70 80 90 100
Al-Fe
1600
1538°C
Fe-Al
Struktur-
1400 L
1310°C
Phase at.% Al symbol group designation Prototype
1232 1165°C (aFe) 0 to 45 cI2 Im 3 m A2 W
1200 (aFe) 1169°C 1160°C
e (gFe) 0 to 1.3 cF4 Fm 3 m A1 Cu
Fe3Al 23 to 34 cF16 Fm 3 m D03 BiF3
1102°C
(gFe) FeAl 23.3 to 55 cP8 Pm 3 m B2 CsCl
1000
e 58 to 65 cI16? … … …
912°C FeAl2 66 to 66.9 aP18 P1 … Al2Fe
Fe2Al5 70 to 73 oC* Cmcm … …
800 FeAl FeAl3 74.5 to 76.6 mC102 C2/m … …
771°C Tc
655°C 660.452°C
99.1
600 U.R. Kattner and B.P. Burton, Phase Diagrams of Binary Iron Alloys, H.
Okamoto, ed., ASM International, Materials Park, OH, 12-28 (1993)
Fe 3Al (Al)
Tc
400
0 10 20 30 40 50 60 70 80 90 100
Fe Atomic Percent Aluminum Al
0 10 20 30 40 50
Weight Percent Galium
60 70 80 90 100
Al-Ga
700
660.452°C
600
Al-Ga
Struktur-
500 L
400 Fm 3m
(Al) 0 to 9 cF4 A1 Cu
(Ga) 100 oC8 Cmca A11 Ga
300
J.L. Murray, Bull. Alloy Phase Diagrams, 4(2), 183-190 (1983)
200
100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Al) 26.6°C 29.7741°C

9 97.9
0
(Ga)
-100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Galium Ga
Al Weight Percent Gadolinium
Al-Gd
0 1020 30 40 50 60 70 80 90 100
1600
1520°C
1988Gsc
2000Sac Al-Gd
1400
Struktur-
L (bGd) 1313°C Composition, Pearson Space bericht
1200°C
1235°C Phase at.% Gd symbol group designation Prototype
1200
1125°C (Al) 0 cF4 Fm 3 m A1 Cu
1070°C Al3Gd 25 hP8 P63 /mmc D019 Ni3Sn
1000 970°C Al2Gd 33.3 cF24 Fd 3 m C15 Cu2Mg
AlGd 50 oP16 Pmma … AlEr
940°C 865°C
Al2Gd3 60 tP20 P42 /mnm … Al2Zr3
77
800 AlGd2 66.7 oP12 Pnma C23 Co2Si
(bGd) 100 cI2 Im 3 m A2 W
660.452°C
5
650°C (aGd) 100 hP2 P63 /mmc A3 Mg
600
(aGd) H. Okamoto, J. Phase Equilibria, 23(4), 380 (2002)

400 (Al)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Gadolinium Gd
0 10 20 30 40 50
Weight Percent Germanium
60 70 80 90 100
Al-Ge
1000
938.3
900
Al-Ge
800
Struktur-
L
700 Phase at.% Ge symbol group designation Prototype
660.452
(Al) 0 to 2.6 cF4 Fm 3 m A1 Cu
600 (Ge) 98.9 to 100 cF8 Fd 3 m A4 C (diamond)

420°C
2.6 28.4 98.9
See also
400
300 (Al)
(Ge)
200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Germanium Ge
0
Weight Percent Hydrogen
0.0001 0.0002 0.0003
Al-H
1200
Al-H
1000 L Struktur-
(Al) 0 to 0.00012 cF4 Fm 3m A1 Cu
800
L+G
A. San-Martin and F.E. Manchester, J. Phase Equilibria, 13(1), 17-21 (1992)
660.452
600
(Al) (Al) + G
400
200
0 0.002 0.004 0.006 0.008
Al Atomic Percent Hydrogen
32
Al
0 20 40 50 60 70
80 90 100
Al-Hf
2231°C
2200
2000
L Al-Hf
Struktur-
(bHf)
1800 1761°C
1743°C
1613°C 1656°C Phase at.% Hf symbol group designation Prototype
1569°C 1566°C 1567°C
1600 1606 1638°C 69 (Al) 0 cF4 Fm 3 m A1 Cu
1528°C
1400 1454°C 72.8 bAl3Hf 25 tI16 I4/mmm D023 Al3Zr
1400°C
1200°C (aHf) aAl3Hf 25 tI8 I4/mmm D022 Al3Ti
1200
Al2Hf 33.3 hP12 P63/mmc C14 MgZn2
1000
Al3Hf2 40 oF40 Fdd2 … …
AlHf 50 oC8 Cmcm Bf CrB
800 Al3Hf4 57.1 hP7 P6 … …
661.6°C
660.452°C
650°C Al2Hf3 60 tP20 P42/mnm … Al2Zr3
600 AlHf2 66.7 tI12 I4/mcm C16 Al2Cu
(bHf) 69 to 100 cI2 Im 3 m A2 W
400
(Al) (aHf) 72.8 to 100 hP2 P63/mmc A3 Mg
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Hafnium Hf
0 20 40 50 60 70
80 90 100
Al-Hg
700
660.452°C
600 L
Al-Hg
Struktur-
500
400 (Al) 0 cF4 Fm 3 m A1 Cu
(Hg) 100 hR1 R 3m A10 aHg
300
(Al)
200
100
0
-38.8°C
-38.8290°C
(Hg)
-100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Mercury Hg
0 1020 30 40 50 60 70
80 90 100
Al-Ho
1700
1530°C
Al-Ho
1500
1474°C
Struktur-
1300 (Al) 0 cF4 Fm 3 m A1 Cu
Al3Ho 25 hR20 R 3m … …
Al2Ho 33.3 cF24 Fd 3 m C15 Cu2Mg
1115°C
1100 1087°C AlHo 50 oP16 Pmma … AlEr
Al2Ho3 60 tP20 P4 2/mnm … Al2Zr3
1018°C
994°C 976°C AlHo2 66.7 oP12 Pnma C23 Co2Si
984°C 65 76 (Ho) 100 hP2 P6 3/mmc A3 Mg
900
(Ho) 684-686 (1988)
700
660.452°C 650°C
1.8
(Al)
500
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Holmium Ho
Desk Handbook: Phase Diagrams for Binary Alloys 33

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Al
93.36
Weight Percent Iodine
93.37 93.38
Al-I
320
Al-I
300 Struktur-
Phase at.% I symbol group designation Prototype
280
AlI3 75 hP* or t** … … …
260
L
J. Thonstad, Can. J. Chem., 42, 2739-2743 (1964)
(Al) + L
240
220
200
188.17°C 188.32°C
(Al) + AlI3 AlI3
180
74.91 74.92 74.93 74.94 74.95 74.96 74.97 74.98 74.99 75
Atomic Percent Iodine
0 10 20 30 40 50 60
70 80 90 100
Al-In
1000
900
875°C
L2
L1 Al-In
800
L1 + L2 Struktur-
700 Phase at.% In symbol group designation Prototype
660.452
4.7
639°C (Al) 0 cF4 Fm 3 m A1 Cu
88.5
600 (In) 100 tI2 I4/mmm A6 In
500 J.L. Murray, Phase Diagrams of Indium Alloys and Their Engineering
400 Park, OH, 19-25 (1992)
(Al)
300
200
156°C
156.634°C
(In)
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Indium In
0 20 40 50 60 70
Weight Percent Iridium
80 90 100
Al-Ir
2447°C
2400
2200
Al-Ir
2000
L Struktur-
1800 Phase at.% Ir symbol group designation Prototype
(Ir) (Al) 0 cF4 Fm 3 m A1 Cu
1600 Al9 Ir2 18.2 mP22 P21/c D8 d Co2 Al9
Al45 Ir13 22.4 oP232 Pnma … …
1400
Al28 Ir9 24.3 tP* P31c … …
1200
Al3 Ir 25 hP8 P63/mmc D0 18 Na3As
Al2.7 Ir 26.7 to 27.5 cP32 P23 … …
1000 AlIr 47.5 to 52.5 cP2 Pm 3 m B2 CsCl
(Ir) 86 to 100 cF4 Fm 3 m A1 Cu
800
660.452°C H. Okamoto, J. Phase Equilibria Diffusion, 30(2), 206-207 (2009)

600
400 (Al)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Iridium Ir
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
34
Al
0 10 20 30 40
Weight Percent Potassium
50 60 70 80 90 100
Al-K
1100
L1 L2
1000
900
L1 + L2 Al-K
Struktur-
800
700
Phase at.% K symbol group designation Prototype
657°C Fm 3 m
660.452 (Al) 0 cF4 A1 Cu
600 (K) 100 cI2 Im 3 m A2 W
500 M. Ono, Nippon Kinzoku Gakkai-shi, 8(6), 269-276 (1944)

400 See also
(Al) J. Sangster and A.D. Pelton, J. Phase Equilibria, 14(3), 366 (1993)
300
200
100 62.5°C
63.71°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Potassium K

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70
80 90 100
Al-La
1600
1400
1405°C Al-La
Struktur-
1240°C 1240°C Composition, Pearon Space bericht
1200 1233°C L
Phase at.% La symbol group designation Prototype
1169
1091°C (Al) 0 cF4 Fm 3 m A1 Cu
1000 bAl11La3 21.4 tI10 I4/mmm D13 Al4Ba
(gLa)
915°C 873°C 54.4 918°C aAl11 La3 21.4 oI28 Immm … aAl11 La3
832°C 865°C
800
Al3La 25 hP8 P63 /mmc D019 Ni3Sn
AlxLa 29.3 hP3 P6/mmm C32 AlB2
660.452°C 628°C Al2La 33.3 cF24 Fd 3 m C15 Cu2Mg
600 3.5
522°C
AlLa 50 oC16 Cmcm … AlCe
521°C
77.2 AlLa3 75 hP8 P63 /mmc D019 Ni3Sn
400
(gLa) 100 cI2 Im 3 m A2 W
277°C
(aLa)* 100 hP4 P63 /mmc A3’ aLa
200 (bLa)
(Al) * Not shown.
0 H. Okamoto, J. Phase Equilibria Diffusion, 28(6), 581 (2007)

0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Lanthanum La
0 10
20 30 40 50 60 70 80 90100
Al-Li
800
Al-Li
700 700°C
50 L Struktur-
660.452°C
600 596°C Phase at.% Li symbol group designation Prototype
15 26 45 Fm 3 m
(Al) 0 to 15 cF4 A1 Cu
(Al) AlLi
520°C AlLi 45 to 55 cF16 Fd 3 m B32 NaTl
55 77
500 Al2 Li3 60 hR15 R 3m … …
bAl4 Li9 69.2 … … … …
aAl4Li9 69.2 mC26 C2/m … …
400
bAl4Li9 (bLi) 100 cI2 Im 3 m A2 W
330°C
90
300
275°C
95
200
177°C 180.6°C
98
(b Li)
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Lithium Li
Al
01020 30 40 50 60 70
80 90 100
Al-Lu
1800
1663°C
1600
1500°C
Al-Lu
Struktur-
1200 (Al) 0 cF4 Fm 3 m A1 Cu
Al3 Lu 25 cP4 Pm 3 m L1 2 AuCu3
1000°C
1000
80 Al2 Lu 33.3 cF24 Fd 3 m C15 Cu2Mg
AlLu 50 oP16 Pbcn … …
800 Al2 Lu3 60 tP20 P4 2/mmm … …
AlLu2 66.7 oP12 Pnma … PbCl2
660.452 650°C
600 2 (Lu) 100 hP2 P6 3/mmc A3 Mg
(Lu) H. Okamoto, J. Phase Equilibria, 14(3), 394-395 (1993)

400
(Al)
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Lutetium Lu

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Al-Mg
700
660.452°C
650°C
600 L Al-Mg
Struktur-
Phase at.% Mg symbol group designation Prototype
500
(Al) 0 to 18.6 cF4 Fm 3 m A1 Cu
452°C 458°C
450°C
(Al) 437°C Al3Mg2 37.5 to 40 cF1832 Fd 3 m … …
18.6 l (Mg)
410°C 62.3 69 88.5
l 42.5 … … … …
400
g e 43.5 to 44.8 hR53 R3 … …
g 43.2 to 62.3 cI58 I 4 3m A12 aMn
e
(Mg) 88.5 to 100 hP2 P63/mmc A3 Mg
300

200
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Magnesium Mg
Al-Mn
Al-Mn
Struktur-
Weight Percent Manganese Composition, Pearson Space bericht
0 10 20 30 40 50 60 70 80 90 100 Phase at.% Mn symbol group designation Prototype
1400
(Al) 0 to 0.62 cF4 Fm 3 m A1 Cu
87Mca Al6Mn 14.2 oC28 Cmcm D2h Al6Mn
96Liu
1300
96Mul l ? oP60 Pnnn ... ...
1246°C m(Al4Mn) 19 to 20.8 hP574 P63 /mmc ... ...
1200
L Al11Mn4(HT) 25 to 28.7 oP160 Pnma ... ...
(d Mn)
1138°C Al11Mn4(LT) 27 aP30 P1 ... ...
1100 e 1100°C g1 30 to 38.2 ... ... ... ...
1048°C g g2(Al8Mn5) 31.4 to 49 hR26 R 3m D810 Al8Cr5
1000 g1 g 34.5 to 51.3 cI2 Im 3 m A2 W
( g Mn)
923°C e 53.2 to 60 hP2 P63 /mmc A3 Mg
900 (dMn) 61.5 to 100 cI2 Im 3 m A2 W
(gMn) 90.9 to 100 cF4 Fm 3 m A1 Cu
800 m (bMn) 59.5 to 100 cP20 P41 32 A13 bMn
g2
(bMn)
(aMn) 98 to 100 cI58 I 4 3m A12 aMn
705°C 727°C
700
658°C
660.452°C H. Okamoto, J. Phase Equilibria, 18(4), 398-399 (1997)
600 (a Mn) 87Mca: A.J. McAlister and J.L. Murray, Bull. Alloy Phase Diagrams, 8(5),
(Al) l 438-447 (1987)
96Liu: X.J. Liu, R. Kainuma, H. Ohtani, and K. Ishida, J. Alloys Compounds,
500
0 10 20 30 40 50 60 70 80 90 100 235, 256-261 (1996)
Al Atomic Percent Manganese Mn 96 Mul: C. Muller, H.H. Stadelmaier, B. Reinsh, and G. Petzow, Z. Metallkd.,
87(7), 594-597 (1996)
36
Al
0 10 20 30 40 50 60
70 80 90 100
Al-Mo
2800
Al-Mo
2600
Struktur-
2400
2200 (Al) 0 cF4 Fm 3 m A1 Cu
(Mo) Al12Mo 7.5 to 8.1 cI26 Im 3 … Al12W
2000
bAl5Mo 16.7 to 17.1 hP12 P63 … Al5W
1800 aAl5Mo 16.7 to 17.1 hR36 R 3c … …
Al22Mo5 18.2 to 18.5 oF216 Fdd2 … …
1600 1546°C 1570°C AlMo Al17Mo4 19 to 19.3 mC84 C2 … …
1535 1490°C 1470°C Al4Mo 20 to 20.4 mC30 Cm … Al4W
1400
Al3Mo 24.8 to 25.3 mC32 Cm … …
1222°C Al8Mo3 26.8 to 27.8 mC22 C2/m … …
1200 Al63Mo37
1152°C Al63Mo37 37 … … … …
1000
Al4Mo Al 3Mo AlMo 48.1 to 54.1 cI2 Im 3 m A2 W
942
846°C Al8Mo3
AlMo3 74.2 to 76.6 cP8 Pm 3 n A15 Cr3Si
800
712°C (Mo) 80 to 100 cI2 Im 3 m A2 W
660.452°C Al 17Mo4
600 660
Al22Mo5 H. Okamoto, J. Phase Equil. Diffusion, 31(5), 492-493 (2010)
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Molybdenum Mo
0
Weight Percent Nitrogen
10 20 30
Al-N
3000
L1 + L2 L2
2800°C
Al-N
2500
Struktur-
Phase at.% N symbol group designation Prototype
2000 (Al) 0 cF4 Fm 3 m A1 Cu
AlN 50 hP4 P63mc B4 ZnS (wurtzite)
L1 L1 + AlN
H.A. Wriedt, Bull. Alloy Phase Diagrams, 7(4), 329-333 (1986)
AlN
1500
See also
M. Hillert and S. Jonsson, Mater. Trans. A., 23, 3141-3149 (1992)
1000
660.452°C 660°C
(Al) (Al) + AlN
500
0 10 20 30 40 50
Al Atomic Percent Nitrogen
0 10 20
30 40 50 60 70 80 90 100
Al-Na
800
L1 L1 + L2
700
659.25°C
660.452°C
Al-Na
600 Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

500
L2 (bNa) 100 cI2 Im 3 m A2 W
400
(Al) J.L. Murray, Bull. Alloy Phase Diagrams, 4(4), 407-410 (1983)
300
200
97.8°C
100 97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Sodium Na
Al
0 10 20 30 40 50 60
Weight Percent Niobium
70 80 90 100
Al-Nb
2600
2469°C
2400
Al-Nb
2200 Struktur-
L
2060
72
2000 77.5 78.5 Phase at.% Nb symbol group designation Prototype
1940°C
64 68 75 (Al) 0 cF4 Fm 3 m A1 Cu
(Nb)
1800 Al3Nb 24.5 to 25.5 tI8 I4/mmm D022 Al3Ti
1680°C AlNb2 58 to 70 tP30 P42/mnm D8b sCrFe
1600 1590°C AlNb3 75 to 81.4 cP8 Pm 3 n A15 Cr3Si
45 58 AlNb2
(Nb) 78.5 to 100 cI2 Im 3 m A2 W
1400
U.R. Kattner, Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H.
1200 Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM International,
Materials Park, OH, 179-181 (1990)
1000
800 (Al)
661.4°C
660.452°C
600
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Niobium Nb
0 10 20 30 40 50 60 70
80 90 100
Al-Nd
1600
1460°C
Al-Nd
1400
Struktur-
1235°C
1200 1205°C Phase at.% Nd symbol group designation Prototype
1021°C bAl11Nd3 21.4 tI10 I4/mmm D13 Al4 Ba
1000
950°C (bNd)
940°C
aAl11 Nd3 21.4 oI28 Immm … …
863°C Al3Nd 25 hP8 P6 3/mmc D019 Ni3 Sn
800 795°C
780°C Al2Nd 33.3 cF24 Fd 3 m C15 Cu2 Mg
690°C
81 650°C AlNd 50 oP16 Pmma … AlEr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
660.452°C 632°C
600 2.5 90 AlNd2 66.7 oP12 Pnma C23 Co2 Si
AlNd3 75 ... ... ... ...
(bNd) 88 to 100 cI2 Im 3m A2 W
400
(aNd) (aNd) 98 to 100 hP4 P6 3/mmc A3’ aLa
200 (Al) H. Okamoto, J. Phase Equilibria, 21(2), 206 (2000)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Neodymium Nd
0 10 20 30 40 50
60 70 80 90 100
Al-Ni
1800
1638°C
1600 Al-Ni
L Struktur-
1360°C 80 1362°C
69 (Al) 0 cF4 Fm 3 m A1 Cu
Al3Ni 25 oP16 Pnma D011 Fe3C
1200
Al3Ni2 37 to 42 hP5 P 3 m1 D513 Al3Ni2
1133°C (Ni)
42 AlNi AlNi 42 to 69 cP2 Pm 3 m B2 CsCl
Al3Ni5 64 to 68 oC16 Cmmm … Ga3 Pt5
1000
AlNi3 72 to 77 cP4 Pm 3 m L12 AuCu3
854°C (Ni) 80 to 100 cI2 Im 3 m A2 W
800
700°C H. Okamoto, J. Phase Equilibria, 14(2), 257-259 (1993)
660.452°C 639.9°C see also
(Al)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Nickel Ni
38
Al
0 10
20 30 40
Al-O
2300
L1 + L2 L2
2100 2046.5°C 2054°C
0.1 59.5
1900 Al-O
Struktur-
1700
1500
aAl 2O3 60 hR10 R 3m D5 1 aAl 2O3
1300 L1 L1 + aAl2O3 aAl2O3

1100
900
700 660°C
660.452°C
(Al) (Al) + aAl2O3
500
0 10 20 30 40 50 60
Al Atomic Percent Oxygen
0 10 20 30
40 50 60 70 80 90 100
Al-P
2600
2400 L
2200 Al-P
2000 Struktur-
1800
Phase at.% P symbol group designation Prototype
1600 (Al) 0 cF4 Fm 3 m A1 Cu
1400 AlP 50 cF8 F 4 3m B3 ZnS (sphalerite)
(aP) 100 c** … … aP
1200
1000
800
660.452°C 660°C
600
400
200 (Al)
44°C 44.14°C
0
(aP)
-200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Phosphorus P
0 20 40 50 60 70 80
Weight Percent Lead
90 100
Al-Pb
1800
1600 1566°C
44.8
Al-Pb
1400 L1
L2 Struktur-
L1 + L2 (Al) 0 cF4 Fm 3 m A1 Cu
1000
(Pb) 100 cF4 Fm 3 m A1 Cu

800
659°C
660.452°C
0.19 98
600
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Al)
400
327°C
327.502°C
99.9
(Pb)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Lead Pb
Al
0 10 20 30 40 50 60
70 80 90 100
Al-Pd
1800
1645°C
1600 Al-Pd
1555°C
Struktur-
1418°C
1400 Phase at.% Pd symbol group designation Prototype
1316°C
1318 (Al) 0 cF4 Fm 3 m A1 Cu
Al4Pd 20 hP* P6322 … …
1200 Al3Pd 25 o** … … …
Al21Pd8 27.6 tI116 I41/a … Al21Pt8
1056°C 81.1 Al3Pd2 39 to 41 hP5 P 3 m1 D513 Al3Ni2
1000 980
952°C AlPd 44 to 56 cP2 Pm 3 m B2 CsCl
28.4 44
858°C
b’(a) 48.5 to 52.8 hR78 R3 … …
(Pd)
800 791°C m(a) 48 to 49 cF8 P213 B20 FeSi
782°C AlPd Al3Pd5 62.5 oP16 Pbam … Ge3 Rh5
660.452°C
AlPd2 65 to 72.5 oP12 Pnma C23 Co2Si
6.9 618°C
600
615°C Al2Pd5 70.5 to 71.5 oP28 Pbmn … Ga2 Pd5
604°C
579°C (Pd) 81.1 to 100 cF4 Fm 3 m A1 Cu
(Al) (a) Not shown.
400
0 10 20 30 40 50 60 70 80 90 100 H. Okamoto, J. Phase Equilibria Diffusion, 29(2), 199 (2008)
Al Atomic Percent Palladium Pd
0 10 20 30 40 50 60 70
Weight Percent Promethium
80 90 100
Al-Pm
1800
Al-Pm
1600 Struktur-
Phase at.% Pm symbol group designation Prototype
1400 L
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1235°C
1200
bAl11Pm3 21.4 … … … …
aAl11 Pm3 21.4 … … … …
1042°C Al3Pm 25 … … … …
1000
940°C (bPm) Al2Pm 33.3 … … … …
950°C
890°C
800°C
AlPm 50 … … … …
800 AlPm2 66.7 … … … …
660.452 640°C
675°C
640°C AlPm3 75 … … … …
600 8 85 (bPm) 100 cI2 Im 3 m A2 W
(aPm) 100 hP4 P6 3/mmc A3’ aLa
400
(Al) (aPm) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
200
192-193 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Promethium Pm
0 10 20 30 40 50 60 70
80 90 100
Al-Pr
1600
1480°C 2000Oka Al-Pr

1400
2001Yin Struktur-
19.9 1245°C Phase at.% Pr symbol group designation Prototype
1200 (Al) 0 to 0.1 cF4 Fm 3 m A1 Cu
1074°C bAl11Pr3 21.4 tI10 I4/mmm D13 Al3Ba
1000 aAl11 Pr3 21.4 oI28 Immm … …
965°C 895°C
64.4 (bPr) 931°C Al3Pr 25 hP8 P63 /mmc D019 Ni3Sn
Al2Pr 33.3 cF24 Fd 3 m C15 Cu2Mg
800 795°C
700°C
739°C 70.4
76 81.4
bAlPr 50 oC16 Cmcm … AlCe
684
660.452 639°C 651°C aAlPr 50 oP16 Pmma … AlEr
600 2.1
619°C 91.4 97.5 AlPr2 66.7 oP12 Pnma C23 Co2Si
(aPr)
bAlPr3 75 cP4 Pm 3 m L12 AuCu3
400 aAlPr3 75 hP8 P63 /mmc D019 Ni3Sn
330°C
(bPr) 90 to 100 cI2 Im 3 m A2 W
200
(Al) (aPr) 97 to 100 hP4 P63 /mmc A3’ aLa

0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Praseodymium Pr
40
Al
0 2030 40 50 60 70
80 90 100
Al-Pt
2000
Al-Pt
Struktur-
1800
1600 1554°C 1556°C (Al) 0 cF4 Fm 3 m A1 Cu
1527°C
1468
1397°C 1507
85.7
Al21Pt5 19.2 c** … … …
79.5
31.8 1406 44.7 1455°C Al21Pt8 27.6 tI116 I4 1a … …
1400 b 57.9 bAlPt3
Al2Pt 32.5 to 33.5 cF12 Fm 3 m C1 CaF2
1290°C 1280°C
1260°C
87 (Pt) Al3Pt2 40 hP5 P3m1 … …
54.2
1200 AlPt 50 cF8 P2 13 B20 FeSi
1127°C
18.8 b 52 to 56 cP2 Pm 3 m B2 CsCl
1060
Al3Pt5 61.5 to 63.0 oP16 Pbam … Ge3Rh5
1000
bAlPt2 66 to 67 oP12 Pnma C23 Co2Si
806°C
aAlPt2 66 to 67 oP24 Pmma … …
800 3.1 bAlPt3 67.3 to 77.7 cP4 Pm 3 m L12 AuCu3
660.452°C
657°C aAlPt3 73.5 to 78 tP16 P4/mbm … …
0.4
600 (Pt) 85.7 to 100 cF4 Fm 3 m A1 Cu
(Al)
400
A.J. McAlister and D.J. Kahan, Bull. Alloy Phase Diagrams, 7(1), 47-51 (1986)
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Platinum Pt
0 20 40 50 60 70 80
90 100
Al-Pu
1600
1490°C Al-Pu
Struktur-
1400
1271°C L Phase at.% Pu symbol group designation Prototype
1200 1177°C (Al) 0 cF4 Fm 3 m A1 Cu
Al4Pu 20 oI20 Imma D1b Al4U
1027°C
1000 dAl3Pu 25 cP4 Pm 3 m L12 AuCu3
928°C
923°C
gAl3Pu 25 hP* P63 /mmc … …
796°C bAl3Pu 25 hR* R3m … …
800
782°C aAl3Pu 25 hR* R3m … …
650°C
660.452 621°C
e 640°C Al2Pu 33.3 cF24 Fd 3 m C15 Cu2Mg
600 AlPu 50 cI58 … … …
571°C
d' 483°C AlPu3 75 tP4 P4/mmm … Pb3Sr
463°C
400 (dPu) (ePu) 85.5 to 100 cI2 Im 3 m A2 W
320°C (d’Pu) 99.75 to 100 tI2 I4/mmm A6 In
g
200
201°C 215°C (dPu) 84.5 to 100 cF4 Fm 3 m A1 Cu
(Al) b
95°C 125°C (gPu) 100 oF8 Fddd … gPu
a (bPu) 100 mC34 C2/m … bPu
0
0 10 20 30 40 50 60 70 80 90 100 (aPu) 100 mP16 P21 /m … aPu
Al Atomic Percent Plutonium Pu
0 20 30 40 50 60 70
80 90 100
Al-Re
3186°C
3000
Al-Re
Struktur-
2500 L Composition, Pearson Space bericht
2000 °C Im 3
2000 Al12Re 7.7 cI26 … Al12W
Al6Re 14.3 oC28 Cmcm D2h Al6Mn
1665°C 1655°C
aAl4Re 20.5 to 21 aP40 P1 … …
1500 1410°C bAl4Re 22.5 to 23.5 … … … …
Al3 Re Al3Re 25 to 25.5 mP* … … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1060°C (Re)
Al11Re4 26 to 26.7 aP30 P1 … Al11Mn4
1000 AlRe 50 tP4 P4/nmm B11 gCuTi
813°C
833 AlRe2 66.7 tI6 I4/mmm C11b MoSi2
660.452°C
658°C
746°C (Re) 96 to 100 hP2 P63 /mmc A3 Mg
500
(Al)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Rhenium Re
Al
0 10 20 30 40 50 60
70 80 90 100
Al-Rh
2000
1963°C
Massalski2
1800 2001Yur
L Al-Rh
Struktur-
1600
75 Phase at.% Rh symbol group designation Prototype
1400
1325°C Al9Rh2 18.2 mP22 P21 /c D8d Co2 Al9
bAl 5Rh2 Al3Rh-1 24 o** … … …
1220°C
1230°C
1200 Al3Rh-2 25 o** … … …
1110°C Al7Rh3
bAl5Rh2 26.5 to 29.5 cP* Pm 3 … …
1015°C
1000
930°C aAl5Rh2 28.6 hP28 P63 /mmc D811 Al5 Co2
(Rh)
875°C Al7Rh3 30 m** … … …
875
800 AlRh 45 to 52 cP2 Pm 3 m B2 CsCl
657°C AlRh2 66.7 … … … …
660.452°C
600 (Rh) 100 cF4 Fm 3 m A1 Cu
530°C
400 (Al) H. Okamoto, J. Phase Equilibria Diffusion, 28(5), 485 (2007)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Rhodium Rh
0 10 20 30 40
50 60 70 80
Al-Ru
2000 AlRu + L
2003Pri Al-Ru
2003Mi
1805°C
Struktur-
Phase at.% Ru(a) symbol group designation Prototype
L 1675°C
1600 (Al) 0 cF4 Fm 3 m A1 Cu
1492°C Al6Ru 14.3 oC28 Cmcm … …
Al13Ru4 23.5 mC102 C2/m … …
1400 1420°C Al5Ru2 28.6 oC16 Cmcm
1340°C
Al2Ru 33.3 tI6 I4/mmm C11a CaC2
1200
m** … … …
oF24 Fddd C54 TiSi2
Al3Ru2 40 hP5 P 3 m1 D513 Al3Ni2
1000 AlRu + (Ru)
tI10 I4/mmm … …
AlRu 50 cP2 Pm 3 m B2 CsCl
800
734°C
(Ru) 100 hP2 P63 /mmc A3 Mg
(a) For stoichiometric composition
657°C
600
0 10 20 30 40 50 60
Al Atomic Percent Ruthenium
0 10 20 30
40 50 60 70 80 90 100
Al-S
L2
1200 L1 L1 + L2 gAl2S3
AlS L3 Al-S
1100°C L2 + L3
1060°C Struktur-
1010°C 1040°C
1000°C
Phase at.% S symbol group designation Prototype
800 AlS 50 … … … …
gAl2S3 ~60 hR10 R 3m D51 aAl2 O3
660.452 660°C aAl2S3 60 hP30 … … …
600 (bS) 100 mP48 P21 /a … …
400 R.C. Sharma and Y.A. Chang, Bull. Alloy Phase Diagrams, 8(2), 128-131
(1987)
(Al)
200 (bS)
115°C
115.22°C
95.5°C
(aS)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Sulfur S
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
42
Al Weight Percent Antimony
Al-Sb
0 10 20 30 40 50 60 70 80 90 100
1063.2°C
1050 L
Al-Sb
Struktur-
850 AlSb 50 cF8 F 4 3m B3 ZnS (sphalerite)
(Sb) 100 hR2 R3 m A7 aAs

750
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
660.452°C 657.2°C
650 0.476
625.1°C 630.755°C
98.33
(Al) (Sb)
550
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Antimony Sb
0 10 20 30 40
Weight Percent Scandium
50 60 70 80 90 100
Al-Sc
1600
1541°C
L
1400 Al-Sc
1337°C Struktur-
1200 1185°C Phase at.% Sc symbol group designation Prototype
(bSc)
Al3Sc 25 cP4 Pm 3 m L1 2 AuCu3
1000 970°C
(aSc) Al2Sc 33.3 cF24 Fd 3 m C15 Cu2Mg
AlSc 50 cP2 Pm 3 m B2 CsCl
800
AlSc2 66.7 hP6 P6 3/mmc B8 2 Ni2In
(bSc) 81 to 100 cI2 Im 3 m A2 W
660.452°C 655°C (aSc) 91 to 100 hP2 P6 3/mmc A3 Mg
600
400 (Al)
200
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Scandium Sc
0 10 20 30 40 50
60 70 80 90 100
Al-Se
1000
L
800 Al-Se
Struktur-
660°C
660.452°C
Phase at.% Se symbol group designation Prototype
600 (Al) 0 cF4 Fm 3 m A1 Cu
Al2Se3 60 mC20 Cc … …
(Se) 100 hP3 P3121 A8 gSe
400
J.W. Howe, Bull. Alloy Phase Diagrams, 10(6), 650-652 (1989)
(Al)
221°C
221°C
200
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Selenium Se
Al Weight Percent Silicon
Al-Si
0 10 20 30 40 50 60 70 80 90 100
1500
1414°C
1300
Al-Si
L Struktur-
1100
(Al) 0 to 1.5 cF4 Fm 3m A1 Cu
(Si) 99.984 to100 cF8 Fd 3 m A4 C (diamond)
900
J.L. Murray and A.J. McAlister, Bull. Alloy Phase Diagrams, 5(1), 74-84
(1984)
700
660.452°C
577°C
1.5 12.2
500
(Al) (Si)
300
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Silicon Si
0 1020 30 40 50 60 70
80 90 100
Al-Sm
1600
1480°C
1400 1380°C Al-Sm

1340°C
Struktur-
L
1200
1074°C (Al) 0 cF4 Fm 3 m A1 Cu
1000 980°C Al11Sm3 21.4 tI10 I4/mmm D13 Al4Ba
860°C
922°C Al3Sm 25 hP8 P63 /mmc D019 Ni3Sn
(bSm) Al2Sm 33.3 cF24 Fd 3 m C15 Cu2Mg
800 780°C
700°C 734°C AlSm 50 oP16 Pmma … AlEr
660.452 635°C ? AlSm2 66.7 oP12 Pnma C23 Co2Si
600 (aSm) (gSm) 88 to 100 cI2 Im 3 m A2 W
(bSm) 96 to 100 hP2 P63 /mmc A3 Mg
400 (aSm) ? to 100 hR3 R 3m C19 aSm
(Al)
H. Okamoto, J. Phase Equilibria Diffusion, 29(2), 200, (2008)
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Samarium Sm
0 10 20 30 40 50 60 70
Weight Percent Tin
80 90 100
Al-Sn
700
660.452°C
600 Al-Sn
L
Struktur-
500 Phase at.% Sn symbol group designation Prototype
(bSn) 99 to 100 tI4 I41/amd A5 bSn
400 (aSn) 100 cF8 Fd 3 m A4 C (diamond)
A.J. McAlister and D.J. Kahan, Bull. Alloy Phase Diagrams, 4(4), 410-414
300 (1983)
228°C 231.9681°C
97.6
200
(bSn)
(Al)
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Tin Sn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
44
Al
0 10 20 30 40 50 60
70 80 90 100
Al-Sr
1100
1034°C
1994Cha
1000 2003Wan
928°C
Al-Sr
900 L Struktur-
800 Phase at.% Sr symbol group designation Prototype
769°C (Al) 0 cF4 Fm 3 m A1 Cu
Al4Sr 20 tI10 I4/mmm D1 3 Al4Ba
700
664°C Al2Sr 33.3 oI12 Imma … CeCu2
660.452 654°C
(bSr)
Al7Sr8 53.3 cP60 P213 … …
600 579°C
547°C
(aSr) 100 hP2 P63/mmc A3 Mg
500
(Al) (aSr)
400
300
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Strontium Sr
0 20 40 50 60 70
Weight Percent Tantalum
80 90 95 100
Al-Ta
3000 3020°C
Al-Ta
L Struktur-
Phase at.% Ta symbol group designation Prototype
(Al) 0 to 0.038 cF4 Fm 3 m A1 Cu
67.8 2074°C (Ta)
75.9 93 Al3Ta 24 to 25 tI8 I4/mmm D022 Al3Ti
2000
Al69Ta39 35.5 to 37.6 cF432 F 4 3m … …
j 52.2 to 57.3 mP86 P21 /c … …
23.7
32.7 1612°C 1581°C s 65 to 81 tP30 P42/mnm D8b sFeCr
51
1500 1541°C 1464°C
37.6 52.2 (Ta) 93 to 100 cI2 Im 3 m A2 W
s
j
Al69Ta 39 V.T. Witusiewicz, A.A. Bondar, U. Hecht, J. Zollinger, V.M. Petyukh, O.S.
1098°C
1000
25 36.8 52.4 Fomichov, V.M. Voblikov, and S. Rex, Intermetallics, 18(1), 92-106 (2010)
660.5°C
660.452°C
(Al) 24.7
500
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Al Atomic Percent Tantalum Ta
0 1020 30 40 50 60 70
80 90 100
Al-Tb
1600
1514°C
1400 (bTb)
Al-Tb
L 1356°C
1289°C
Struktur-
1200
1079°C
986°C
1000 Al3Tb 25 hR12 R 3m … BaPb3
960°C 903°C
77 Al2Tb 33.3 cF24 Fd 3 m C15 Cu2 Mg
800 AlTb 50 oP16 Pmma … AlEr
Al2Tb3 60 tP20 P42/mnm … Al2 Zr3
660.452 642°C AlTb2 66.7 oP12 Pnma C23 Co2 Si
600 3.5
(bTb) 100 cI2 Im 3 m A2 W
(aTb) 100 hP2 P63/mmc A3 Mg
(aTb)
400
(Al) R. Ferro, S. Delfino, G. Borzone, A. Saccone, and G. Cacciamani, J. Phase

200 Equilibria, 14(3), 273-279 (1993)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Terbium Tb
Al Weight Percent Tellurium
Al-Te
0 10 20 30 40 50 60 70 80 90 100
1100
1000 L1 L1 + L2 Al-Te
903°C Struktur-
900 L2
800
720°C
700
AlTe? 50? … … … …
660.452 649°C Al7Te10* 58.8 hR34 R32 … …
600 bAl 2Te3 60 … … … …
aAl 2Te3 60 mP240 P21 … …
500
465°C
Al2Te5 71.4 … … … …
415°C
435°C 449.57°C (Te) 100 hP3 P3121 A8 gSe
400 * Not shown.
300 (Al) H. Okamoto, J. Phase Equilibria, 21(1), 106-107 (2000)

(Te)
200
100
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Tellurium Te
0 20 40 50 60 70 80
90 100
Al-Th
1800
1755°C
Al-Th
1600 L
1520°C (bTh) Struktur-
1400 1394°C 1382°C Phase at.% Th symbol group designation Prototype
1318°C 1301°C 1307°C
1360°C (Al) 0 cF4 Fm 3 m A1 Cu
1290°C 1296°C 1243°C Al7Th2 22.2 oP18 Pban … …
1200
80 Al3Th 25 hP8 P63/mmc D0 19 Ni3Sn
1120°C
1100°C Al2Th 33.3 hP3 P6/mmm C32 AlB 2
1075°C
AlxTh 38 t** … … …
1000 AlTh 50 oC8 Cmcm Bf CrB
Al2Th3 60 tP10 P4/mbm D5 a Si2U 3
876°C
(aTh) AlTh2 66.7 tI12 I4/mcm C16 Al2Cu
800 (bTh) ? to 100 cI2 Im 3 m A2 W
(aTh) 99.15 to 100 cF4 Fm 3m A1 Cu
660.452°C 630°C
600 2.9
M.E. Kassner and D.E. Peterson, Phase Diagrams of Binary Actinide Alloys,
(Al) M.E. Kassner and D.E. Peterson, ed., ASM International, Materials Park, OH,
12-16 (1995)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Thorium Th
0 10 20
30 40 50 60 70 80 90 100
Al-Ti
1800
1670°C
Ti-Al
1600 L Struktur-
1503°C
1476°C Phase at.% Al symbol group designation Prototype
(bTi) 1408°C (bTi) 0 to 44.8 cI2 Im 3 m A2 W
1400 1387°C
(aTi) 0 to 52.3 hP2 P63/mmc A3 Mg
b 29 to 41 cP2 Pm 3 m B2 CsCl
b TiAl
1206°C Ti3Al ? to 40 hP8 P63/mmc D019 Ni3 Sn
1200
TiAl 47.4 to 66.7 tP4 P4/mmm L10 AuCu
1124°C
TiAl2 66.7 tI24 I41 /amd … …
Ti2Al5 71.4 … … … …
1000 TiAl3 75 tI8 I4/mmm D022 Al3 Ti
991°C
Ti 3Al (Al) 99.3 to 100 cF4 Fm 3 m A1 Cu
882°C
(aTi) I. Ohnuma, Y. Fujita, H. Mitsui, K. Ishikawa, R. Kainuma, and K. Ishida, Acta
800
Material., 48(12), 3113-3124 (2000)
665°C
660.452°C
(Al)
600
0 10 20 30 40 50 60 70 80 90 100
Ti Atomic Percent Aluminum Al
46 Desk Handbook: Phase Diagrams for Binary Alloys

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Al Weight Percent Thallium
Al-Tl
0 2030 40 50 60 70 80 90 100
2520°C
2500
G
Al-Tl
2000 Struktur-
1500 1473°C (bTl) 100 cI2 Im 3 m A2 W
1477°C, 52.2
(aTl) 100 hP2 P63 /mmc A3 Mg
L1 L2
1000 L1 + L2
660.452°C
500
(Al) + L2
(bTl)
304°C
230°C
(Al) (aTl)
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Thallium Tl
0 1020 30 40 50 60 70
80 90 100
Al-Tm
2000
1800 Al-Tm
L Struktur-
1600
1500°C 1545°C
1400
? Al3Tm 25 cP4 Pm 3 m L1 2 AuCu 3
1200 ? ?
? Al2Tm 33.3 cF24 Fd 3 m C15 Cu2Mg
?
1000°C AlTm 50 oP16 Pmma … AlEr
1000
80 Al2Tm3 60 tP20 P4 2/mnm … Al2Zr3
AlTm2 66.7 … … … …
800
(Tm) 100 hP2 P6 3/mmc A3 Mg
660.452°C 645°C
600 1.74
400 (Tm) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
(Al)
229-230 (1990)
200
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Thulium Tm
0 20 40 50 60 70 80
Weight Percent Uranium
90 100
Al-U
1700
1620°C
1600
Al-U
1500 L Struktur-
1400
1350°C Phase at.% U symbol group designation Prototype
13
1300 (Al) 0 cF4 Fm 3 m A1 Cu
bAl4 U0.9 17.5 to 20 oI20 Imma D1b Al4 U
1200 aAl4U0.9 17.5 to 20 oI20 Imma D1b Al4 U
1135°C
1100
1105°C Al3U 25 cP4 Pm 3 m L12 AuCu3
Al2U 33.3 cF24 Fd 3 m C15 Cu2 Mg
1000 (gU) Im 3 m
? to 100 cI2 A2 W
(gU)
900 (bU) ? to 100 tP30 P42 /mnm Ab bU
(aU) 100 oC4 Cmcm A20 aU
800
758°C 776°C
731°C
bAl4U0.9 (bU) M.E. Kassner, M.G. Adamson, P.H. Adler, and D.E. Peterson, Bull. Alloy Phase
700 668°C
660.452°C 646°C 668°C Diagrams, 11(1), 82-89 (1990)
1.7 641°C
600 aAl4U0.9 (aU)
(Al)
500
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,
Al Atomic Percent Uranium U
Al Weight Percent Vanadium
Al-V
0 10 20 30 40 50 60 70 80 90 100
2000
1910°C
1800 Al-V
L Struktur-
(1670°C)
28 46 Composition, Pearson Space bericht
1600 1989Mur Phase at.% V symbol group designation Prototype
2000Ric
1408°C
1400 (1360°C) Al21 V2 8.7 cF176 Fd 3 m … …
14 Al45 V7 13.7 mC104 C2/m … …
1270°C
(V)
Al23 V4 14.8 hP54 P63 /mmc … …
1200
Al3V 25 tI8 I4/mmm D022 Al3 Ti
Al8V5 38.5 cI52 I 4 3m D82 Cu5Zn8
1000 AlV3 ? cP8 Pm 3 m A15 Cr3 Si
(V) 46 to 100 cI2 Im 3 m A2 W
800 For [1989Mur].
736°C
730°C
660.452°C 665°C
600
(Al) AlV3
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Vanadium V
0 20 30 40 50 60 70
80 90 100
Al-W
3500
3422°C
Al-W
Struktur-
3000
L Phase at.% W symbol group designation Prototype
2500
Al12W 7.7 cI26 Im 3 … …
Al5W 16.7 to 18.0 hP12 P6 3 … …
Al4W 19.0 to 21.5 mC30 Cm … …
2000 Al3W 23 to 25 … … … …
Al7W3 29 to 30 … … … …
1650°C Al2W 32.5 to 37.0 … … … …
1326°C 37 91.3
1500
23.7
(W) 84.5 to 100 cI2 Im 3 m A2 W
1420°C Al2W
1344°C 1335°C
1300°C 85.5 S.V. Nagender Naidu and P. Rama Rao, Phase Diagrams of Binary Tungsten
Al7W3 Alloys, S.V. Nagender Naidu and P. Rama Rao, ed., Indian Institute of Metals,
Al 5W Al3W 1317°C
1000
870°C
(W) Calcutta, India, 7-13 (1991)
697°C
660.452°C
(Al) Al12W
500
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Tungsten W

Al-Y
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1600
(bY) 1522°C
1490°C
97.9 1478°C
Al-Y
1400 Struktur-
Phase at.% Y symbol group designation Prototype
1200 (Al) 0 cF4 Fm 3 m A1 Cu
1137°C 51.1 bAl3Y 25 hR12 R 3m … BaPb3
1104°C
1083 aAl3Y 25 hP8 P6 3/mmc D019 Ni3 Sn
56.2
1000 980°C 978°C 70.8 Al2Y 33.3 cF24 Fd 3 m C15 Cu2 Mg
954°C
12.6 AlY 50 oC8 Cmcm Bf CrB
73.7
Al2Y3 60 tP20 P4 2/mnm … Al2 Zr3
AlY2 66.7 oP12 Pnma C23 Co2 Si
800
(bY) 100 cI2 Im 3 m A2 W
644°C
660.452°C (aY)
3 637°C
(Al)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Yttrium Y
48
Al Weight Percent Ytterbium
Al-Yb
0 20 30 40 50 60 70 80 90 100
1600
1400 Al-Yb
1360°C
Struktur-
1200
Phase at.% Yb symbol group designation Prototype
Al3Yb 25 cP4 Pm 3 m L12 AuCu3
Al2Yb 33.3 cF24 Fd 3 m C15 Cu2 Mg
1000 980°C
(gYb) 97.5 to 100 cI2 Im 3 m A2 W
(bYb) ? to 100 cF4 Fm 3 m A1 Cu
(gYb)
819°C
800 770°C 795°C
97.5
675°C
47-49 (1989)
660.452°C 625°C 77.5
600 4
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(bYb)
(Al)
400
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Ytterbium Yb
0 10 20 30 40 50
Weight Percent Zinc
60 70 80 90 100
Al-Zn
800
700 Al-Zn
660.452°C
L Struktur-
600
Phase at.% Zn symbol group designation Prototype
(Al) 0 to 67 cF4 Fm 3 m A1 Cu
500
(Zn) 97.2 to 100 hP2 P6 3/mmc A3 Mg
419.58°C
400 (Al) H. Okamoto, J. Phase Equilibria, 16(3), 281-282 (1995)
381°C
351.5°C 67 88.7 97.2
300 277°C
16.5 59 98.4
200
(Zn)
100
0
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Zinc Zn
0 10 20 30 40 50 60
70 80 90 100
Al-Zr
2000
1993Oka Al-Zr
1855°C
1800
2001Wan Struktur-
1660°C Phase at.% Zr symbol group designation Prototype
1600 1580°C 1590 (Al) 0 cF4 Fm 3 m A1 Cu
1550°C
1500
Al3Zr 25 tI16 I4/mmm D023 Al3Zr
1485°C 1480
28 Al2Zr 33.3 hP12 P6 3/mmc C14 MgZn2
1400 Al3Zr2 40 oF40 Fdd2 … …
1350
(bZr) AlZr 50 oC8 Cmcm Bf CrB
1275°C
Al4Zr5 55.6 hP18 P6 3/mcm … Ga4Ti5
1215°C
1200 Al3Zr4 57.1 hP7 P6 … Al3Ir4
Al2Zr3 60 tP20 P4 2/mnm … Al2Zr3
1019°C Al3Zr5 62.5 tI32 I4/mcm D8 m W5Si3
1000 AlZr2 66.7 hP6 P6 3/mmc B8 2 Ni2In
910°C AlZr3 75 cP4 Pm 3 m L1 2 AuCu3
863°C (bZr) Im 3m
74 to 100 cI2 A2 W
800
(aZr) (aZr) 91.7 to 100 hP2 P6 3/mmc A3 Mg
660.8°C
660.452°C
(Al) H. Okamoto, J. Phase Equilibria, 23(5), 455-456 (2002)
600
0 10 20 30 40 50 60 70 80 90 100
Al Atomic Percent Zirconium Zr
Am Weight Percent Boron
Am-B
0 10 20 30 50 100
3000
Am-B
Struktur-
2500
L (gAm) Im 3 m
0 cI2 A2 W
(bAm) 0 cF4 Fm 3 m A1 Cu
2092°C
2000 (aAm) 0 hP4 P63/mmc A3’ aLa
? AmB4 80 … … … …
AmB6 85.7 cP7 Pm 3 m D21 CaB6
AmB66 98.5 … … … …
1500 (bB) 100 hR105 R 3m … bB
(gAm)
1176°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
1077°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1000
244-245 (1990)
(bAm)
769°C
(bB)
(aAm)
500
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Boron B
0
10 20 30 40 50 60 70 80 90 100
Am-Cr
2000
1900
1863°C Am-Cr
1800
Struktur-
1600 Phase at.% Cr symbol group designation Prototype
L
(gAm) 0 cI2 Im 3 m A2 W
1500
1400
(aAm) 0 hP4 P63 /mmc A3’ aLa
1300
(Cr) 100 cI2 Im 3 m A2 W
1200
1176°C
(gAm)
1077°C
1000
6(5), 415-416 (1985)
(bAm)
900
828°C
800 39 769°C
769°C
700
600
(aAm) (Cr)
500
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Chromium Cr
0 10
20 30 40 50 60 70 80 90 100
Am-Mo
5000
4639°C
G
Am-Mo
4000 Struktur-
L2
G + L2 Phase at.% Mo symbol group designation Prototype
(gAm) 0 cI2 Im 3 m A2 W
3000 (bAm) 0 cF4 Fm 3m A1 Cu
2607°C 2623°C (aAm) 0 hP4 P63 /mmc A3’ aLa
(Mo) 100 cI2 Im 3 m A2 W
G + (Mo)
2000
L1 L1 + (Mo)
(Mo) L. Brewer and R.H. Ramoreaux, Molybdenum: Physico-Chemical Properties of
Its Compounds and Alloys, Special Issue No. 7, International Atomic Energy
(gAm) Agency, Vienna, 208-209 (1980)
1176°C
1077°C
1000
(bAm)
769°C
(aAm)
0
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Molybdenum Mo
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
50
Am Weight Percent Neptunium
Am-Np
0 10 20 30 40 50 60 70 80 90 100
1200
1176°C
L1 + L2 L
1100 (gAm) Am-Np
1077°C
1039°C Struktur-
1000
Phase at.% Np symbol group designation Prototype
(gAm) 0 to 21 cI2 Im 3m A2 W
900
(bAm) 0 to 20 cF4 Fm 3 m A1 Cu
(aAm) 0 to ? hP4 P63/mmc A3’ aLa
(bAm) (gNp) 97 to 100 cI2 Im 3 m A2 W
800 (bNp) ? to 100 tP4 P2412 Ad bNp
769°C
(aNp) 100 oP8 Pnma Ac aNp
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
700
652°C
(aAm) 639°C
(gNp)
600
576°C
(bNp)
500
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Neptunium Np
9.0 9.5
10.0 10.5 11.0 11.5
Am-O
2500
L Am-O
Struktur-
(gAm)* 0 cI2 Im 3 m A2 W
(bAm)* 0 cF4 Fm 3m A1 Cu
1500 (aAm)* 0 hP4 P6 3/mmc A3’ aLa
AmO 2 AmO* 50 cF8 Fm 3m B1 NaCl
bAm2O3 60 hP5 P 3 m1 D52 La2O3
1000
aAm2O3 60 to 61.3 cI* … … …
aAm2O3 ’ 61.8 to 62.6 cI80 Ia 3 D53 Mn2O3
AmO2 61.5 to >66.7 cF12 Fm 3m C1 CaF2
* Not shown.
500
H. Okamoto, J. Phase Equil. Diffusion, 27(2), 197 (2006)
aAm2O 3
0
60 61 62 63 64 65 66 67
Atomic Percent Oxygen
60
70 80 90 100
Am-Pd
1600
1555°C
1500°C
1400 L
Am-Pd
1200
Struktur-
87.5 88
Phase at.% Pd symbol group designation Prototype
1000 (gAm) 0 cI2 Im 3 m A2 W
800 (aAm) 0 hP4 P63/mmc A3’ aLa
AmPd3 73 to 78.5 cP4 Pm 3 m L12 AuCu3
600
(Pd) 88 to 100 cF4 Fm 3 m A1 Cu
(Pd)
400 AmPd3
200
0
70 80 90 100
Atomic Percent Palladium Pd
Am Am-Pt
0 10 20 30 40 50 60 70 80 90 100
2000
Am-Pt
Struktur-
1800 L 1769.0°C Composition, Pearson Space bericht
1600 (gAm) 0 to 1 cI2 Im 3 m A2 W
(bAm) 0 to 1 cF4 Fm 3 m A1 Cu
(aAm) 0 hP4 P6 3/mmc A3’ aLa
1400
Am7Pt3 30 … … … …
Am3Pt2 40 … … … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1200 (gAm)
AmPt 50 … … … …
1176°C (Pt) Am3Pt4 57.1 … … … …
1077°C AmPt2 66.7 to 74 cF24 Fd 3 m C15 Cu2Mg
1000 AmPt5 83.3 hP6 P6/mmm D2 d CaCu5
(bAm) (Pt) 99 to 100 cF4 Fm 3 m A1 Cu
800
769°C
D.E. Peterson, Bull. Alloy Phase Diagrams, 10(2), 115-116 (1989)
(aAm)
600
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Platinum Pt
0 10 20 30
40 50 60 70 80 90 100
Am-Pu
1200
1176°C
L Am-Pu
1977°C Struktur-
Phase at.% Pu symbol group designation Prototype
(gAm,ePu)
(gAm, ePu) 0 to 100 cI2 Im 3 m A2 W
800
769°C
(bAm,dPu) 0 to 100 cF4 Fm 3 m A1 Cu
(aAm) 0 to 5 hP4 P63/mmc A3’ aLa
640°C (d’Pu) ? to 100 tI2 I4/mmm A6 In
600
(gPu) 100 oF8 Fddd … gPu
483°C (bPu) 100 mC34 C2/m … bPu
463°C
(d'Pu) (aPu) 100 mP16 P2 1/m … aPu
400 (bAm,dPu)
320°C
(gPu)
200 (aAm) 215°C
(bPu)
125°C
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Plutonium Pu
0
10 20 30 40 50 60 80 100
Am-Si
1600
1414°C
1400 L Am-Si
Struktur-
1200 (gAm)
1176°C Phase at.% Si symbol group designation Prototype
1077°C (gAm) 0 cI2 Im 3 m A2 W
1000 (bAm) Fm 3 m
0 cF4 A1 Cu
(bAm) (aAm) 0 hP4 P63/mmc A3’ aLa
800 Am5Si3 37.5 tI32 I4/mcm D8 m W5Si3
769°C
AmSi 50 oP8 Pnma B27 FeB
b 60 to 62.5 hP3 P6/mmm C32 AlB 2
600 (Si) AmSi2 66.7 tI12 I41/amd Cc ThSi2
(Si) 100 cF8 Fd 3m A4 C (diamond)
400 (aAm) b
200 Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
257-258 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Silicon Si
52
Am Weight Percent Uranium
Am-U
0 10 20 30 40 50 60 70 80 90 100
1300
L1 L2
1200
1176°C L1 + L2 Am-U
1135°C Struktur-
1108°C
1077°C (gAm) 23 1084°C 90 Phase at.% U symbol group designation Prototype
(gU)
(gAm) 0 to 23 cI2 Im 3 m A2 W
1000
964°C (bAm) 0 to 10 cF4 Fm 3 m A1 Cu
(bAm) 10
(aAm) 0 to ? hP4 P6 3/mmc A3’ aLa
900 (gU) 90 to 100 cI2 Im 3m A2 W
(bU) 98 to 100 tP30 P4 2/mnm Ab bU
800 (aU) ? to 100 oC4 Cmcm A20 aU
769°C 760°C 97 776°C
(bU) H. Okamoto, J. Phase Equilibria, 20(4), 452 (1999)

700
668°C
(aAm)
600 (aU)
500
0 10 20 30 40 50 60 70 80 90 100
Am Atomic Percent Uranium U
0 10
Weight Percent Argon
20 30 40 50 60 70 80 90 100
Ar-Mo
5000
4639°C
G Mo-Ar
4500
Struktur-
4000
Phase at.% Ar symbol group designation Prototype
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Mo) 0 cI2 Im 3 m A2 W
L. Brewer and R.H. Lamoreaux, Molybdenum: Physico-Chemical Properties of

3500 L L+G Its Compounds and Alloys, Special Issue No. 7, International Atomic Energy
Agency, Vienna, 209-210, (1980)
3000
2623°C
2500
(Mo) (Mo) + G
2000
0 10 20 30 40 50 60 70 80 90 100
Mo Atomic Percent Argon Ar
0 10
20 30 40 50 60 70 80 90 100
Ar-N
-180
-189.35°C
T.P.
-190
L -195.8°C
Ar-N
B.P.
-200 Struktur-
-210
-210.0042°C Phase at.% N symbol group designation Prototype
T.P.
(bAr,bN) 0 to 100 hP24 P6 3/mmc … N
-220 (aAr) 0 cF4 Fm 3 m A1 Cu
(aN) 100 cP8 P2 13 … …
(bAr,bN)
-230
H. You and S.C. Fain, Jr., Physical Review B: Cond. Matter, 34, 2840-2851
-237.54°C
-240 (1986)
(aAr)
-250
(aN)
-260
-270
0 10 20 30 40 50 60 70 80 90 100
Ar Atomic Percent Nitrogen N
As Weight Percent Gold As-Au
0 10 20 30 40 50 60 70 80 90 100
1100
1064.43°C
1000
As-Au
L Struktur-
Phase at.% Au symbol group designation Prototype
817°C
800 (Au) 100 cF4 Fm 3 m A1 Cu
H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 5(1), 56-59
700 (1984)
636°C
43.5
600
(As) (Au)
500
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Gold Au
0
10 20 30 40 50 60 70 80 100
As-B
1600
2092°CM.P.
1400
As-B
1200
Struktur-
1070°C
1000 (As) 0 hR2 R 3m A7 aAs
AsB 50 cF8 F 4 3m B3 ZnS (sphalerite)
817°C
800 AsB 6 85.7 hR14 R 3m … …
(bB) 100 hR108 R 3m … …
600
(bB) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
400 (As) 261-262 (1990)
200
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Boron B
0 10 20 30 40 50
60 70 80 90 100
As-Bi
900
817°C
800
L As-Bi
700 Struktur-
600
Phase at.% Bi symbol group designation Prototype
(Bi) 100 hR2 R 3m A7 aAs
500
G.A. Geach and R.A. Jettery, J. Met., 5, 1084 (1953)

400
300
270.3°C
271.442°C
99.5
200
(As) (Bi)
100
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Bismuth Bi

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

As Weight Percent Bromine
As-Br
80 85 90 95 100
40
30 30°C
As-Br
20
Struktur-
10 Phase at.% Br symbol group designation Prototype
AsBr3 75 oP16 P2 12 12 1 … …
(Br) 100 oC8 Cmca A14 I
0
-7.25°C W. Biltz and K. Jeep, Z. Anorg. Allg. Chem., 162, 32-48 (1927)
T.P.
-10
AsBr3
-20
(Br)
-30
-34°C
-40
75 80 85 90 95 100
Atomic Percent Bromine Br
0 10 20 30 40
50 60 70 80 90 100
As-Cd
817°C
800 L
As-Cd
715°C
Struktur-
620°C 621°C 44 610°C
600 32.3 595°C Phase at.% Cd symbol group designation Prototype
As2Cd 31 to 34 tI12 I41 22 … …
465°C bAs2Cd 3 60 cF12 Fm 3 m C1 CaF2
a”As2Cd3 60 tP40 P42/nmc D59 P2Zn3
400
a’As2Cd 3 60 tP160 P42 /nbc … …
320°C
99.5
321.108°C aAs2Cd 3 60 tI160 I41 cd … …
(Cd) 100 hP2 P63/mmc A3 Mg
225°C
200
(As) H. Okamoto, J. Phase Equilibria, 13(2), 147-154 (1992)
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Cadmium Cd
0 10 20
30 40 50 60 70 80 90 100
As-Co
1600
1495°C As-Co
1400
Struktur-
Phase at.% Co symbol group designation Prototype
1200 1180°C (As) 0 hR2 R 3m A7 aAs
1115°C As3Co 25 cI32 Im 3 D0 2 CoAs3
1063°C
bAs 2Co 33.3 oP6 Pnnm C18 FeS 2 (marcasite)
997°C
1000 975°C
aAs 2Co 33.3 mP12 P2 1/c … CoSb2
940°C
876°C bAsCo 50 … P63/mmc B8 1 NiAs
817°C
800
aAsCo 50 oP8 Pna21 … …
(aCo) As2Co3 60 … … … …
624°C
bAsCo 2 66.7 hP9 P 62 m C22 Fe2P
600
597°C
aAsCo 2 66.7 … … … …
As2Co5 71.4 hP42 P6 3cm … Pd5Sb2
(As) 452°C
422°C (aCo) 97.5 to 100 cF4 Fm 3 m A1 Cu
400
(eCo) 98 to 100 hP2 P63/mmc A3 Mg
(eCo)
K. Ishida and T. Nishizawa, Bull. Alloy Phase Diagrams, 11(6), 550-554 (1990)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Cobalt Co
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
As
0 10 20
30 40 50 60 70 80 90 100
As-Cr
2000
1863°C
As-Cr
Struktur-
1500 (As) 0 hR2 R 3m A7 aAs
As2Cr 33.3 mC12 C2/m … Ge2 Os
1250°C (Cr) As3Cr2 40 … … … …
bAsCr 50 to 54 hP4 P63/mmc B81 NiAs
aAsCr 50 to 54 mP28 P21 /m B31 MnP
1000 1000°C
bAs3Cr4 57 to 60 … … … …
907°C
aAs3Cr4 57 to 60 mC28 Cm … …
800°C
As3Cr5 62.5 oP32 Pnma … Yb5Sb3
614°C S.P.
bAsCr 2 66.7 hP9 P 62 m C22 Fe2P
500
aAsCr 2 66.7 tP6 P4/nmm C38 Cu2Sb
AsCr3 79 cP8 Pm 3 n A15 Cr3Si
(As) (Cr) 94 to 100 cI2 Im 3 m A2 W
0 (1990)
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Chromium Cr
0 10 20
30 40 50 60 70 80 90 100
As-Cu
1200
1084.87°C
As-Cu
1000 L Struktur-
827°C
800 (As) 0 hR2 R 3m A7 aAs
d 70.4 to 71.4 cF16 Fm 3 m D03 BiF3
709°C
614°C.
66
74.9 81.8
685°C
93.17
d’ 70.4 to 71.4 oI28 Ibam … Cu5As2
g
S.P.
600
600°C g 72.2 to 74.9 hP8 P63 /mmc D018 Na3As
54
(Cu) g’ 72.2 to 74.5 hP24 P 3 c1 … Cu3As
d 450-475°C b 85.7 to 88.9 hP2 P63 /mmc A3 Mg
400 380°C (Cu) 93.17 to 100 cF4 Fm 3 m A1 Cu
d' 325°C
300°C
71
74.2 93.5 P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper
Alloys, P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed., ASM
200 g'
b
International, Materials Park, OH, 43-52 (1994)
(As) See also
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Copper Cu
0 10 20 30 40 50
60 70 80 90 100
As-Dy
3000
>2500°C
2500 L As-Dy
Struktur-
2000 Phase at.% Dy symbol group designation Prototype
AsDy 50 cF8 Fm 3 m B1 NaCl
1500 (bDy) 98 to 100 cI2 Im 3 m A2 W
1412°C
1381°C (aDy) 99 to 100 hP2 P63/mmc A3 Mg
(bDy)
1000
817°C
275-276 (1990)
(aDy)
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Dysprosium Dy
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
56
As
0 10 20 30 40 50
60 70 80 90 100
As-Er
3500
3000
L As-Er
>2500°C
Struktur-
2000 Fm 3 m
AsEr 50 cF8 B1 NaCl
(Er) 99 to 100 hP2 P63 /mmc A3 Mg
1500 1529°C
275, 277 (1990)
1000
817°C
(Er)
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Erbium Er
As-Eu
Weight Percent Europium As-Eu
0 10 20 30 40 50 60 70 80 90 100
1200 Struktur-
Phase at.% Eu symbol group designation Prototype
1100
L
bAs3Eu 25 mC16 C2/m … …
1000 990°C aAs3Eu 25 aP8 … … …
950°C As2Eu 33.3 oP12 … … …
930°C
912°C As3+xEu2 <40 … … … …
900
As3Eu2 41 mP40 … … …
842°C
As4Eu3 42.9 oF56 Fdd2 … …
802°C 822°C
800°C P 62 m
800 AsEu 50 hP12 … NaO
790°C
As10Eu11 52.4 oI84 … … …
As4Eu5 55.6 oC36 Cmca … …
700
697°C bAs3Eu4 57.1 cI28 I 4 3d D73 Th3P4
614°C S.P.
aAs3Eu4 57.1 hR28 R3 … …
600 (Eu)
(As) As2Eu3 60 cI20 I 4 3d … Ba3P2
As2Eu3+y >60 … … … …
500
As2Eu3+x >60 tI40 I41 /acd … …
bAs3Eu5 62.5 hP48 P63 /mc … Ca5Pb3
aAs3Eu5 62.5 hP16 P63 /mcm D88 Mn5Si3
400
0 10 20 30 40 50 60 70 80 90 100 (Eu) 100 cI2 Im 3 m A2 W
As Atomic Percent Europium Eu
279-282 (1986)
0 10 20
Weight Percent Iron
30 40 50 60 70 80 90 100
As-Fe
1600
1538°C
1400 As-Fe
L 1394°C
Struktur-
1200 Phase at.% Fe symbol group designation Prototype
(gFe)
1020°C 1030°C
1000°C As 2Fe3 As2Fe 33.3 oP6 Pnnm C18 FeS2(marcasite)
1000 42
930°C
AsFe 50 oP8 Pnma B31 MnP
1008°C 912°C As2Fe3 56 to 63 … … … …
840°C
817°C 800°C
824°C 91 AsFe2 66.7 tP6 P4/nmm C38 Cu2Sb
800
6.5
730°C 770°C (aFe) 91 to 100 cI2 Im 3 m A2 W
(gFe) 98 to 100 cF4 Fm 3 m A1 Cu
(aFe)
614°C S.P.
600
400 (As)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Iron Fe
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
As
0 10 20 30
40 50 60 70 80 90 100
As-Ga
1400
1238°C
1200 L As-Ga
Struktur-
1000
817°C
800
810°C AsGa 50 cF8 F 4 3m B3 ZnS (sphalerite)
282-283 (1990)
400
(As)
200
(Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Gallium Ga
0 10 20 30 40 50
60 70 80 90 100
As-Gd
3000
2500 L
As-Gd
Struktur-
Phase at.% Gd symbol group designation Prototype
1500 (bGd) AsGd 50 cF8 Fm 3 m B1 NaCl
(bGd) ? to 100 cI2 Im 3 m A2 W
1313°C
1235°C (aGd) ? to 100 hP2 P6 3/mmc A3 Mg
1000
W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
817°C Publishing Co., Schenectady, NY
(aGd)
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Gadolinium Gd
0 10 20 30
40 50 60 70 80 90 100
As-Ge
1000
950
938.3°C
900 As-Ge
L
Struktur-
850
817°C (As) 0 to 12 hR2 R 3m A7 aAs
800 As2Ge 33.3 oP24 Pbam … …
AsGe 50 mC24 C2/m … …
762°C
745°C
756°C 754°C (Ge) 99.82 to 100 cF8 Fd 3 m A4 C (diamond)
750 60
25 40 750°C
12
(As)
700
(Ge)
650
600
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Germanium Ge
58
As Weight Percent Mercury
As-Hg
0 10 20 30 40 50 60 70 80 90 100
1000
900
L1 + G
817°C
800
As-Hg
Struktur-
700
600
(As) + G (As) 0 hR2 R 3m A7 aAs
500 (Hg) 100 hR1 R 3m A10 Hg
400 C. Guminski, Polish J. Chem., 78, 1733-1751 (2004)
356.623°C
300
200
(As) + L2
100
0
-38.8290°C
(As) + (Hg)
-100
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Mercury Hg
0 10 20 30 40 50
60 70 80 90 100
As-Ho
3500
3000
L >2500°C
As-Ho
2500 Struktur-
2000
AsHo 50 cF8 Fm 3 m B1 NaCl
1500
(Ho) 99 to 100 hP2 P63 /mmc A3 Mg
1474°C
817°C
286-287 (1990)
(Ho)
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Holmium Ho

0 10 20 30 40 50 60 70
As-I
250
L1
200
As-I
Struktur-
L1 + L2 Phase at.% I symbol group designation Prototype
L2
150 (As) 0 hR2 R 3m A7 aAs
135°C AsI3 75 hR24 R3 … …
120°C
(I) 100 oC8 Cmca A14 I
100
A.P. Chernov, S.A. Dembovskii, and A.F. Borisenkova, Russ. J. Inorg. Chem.,
18(10), 1530-1531 (1973)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(As)
50
0
0 10 20 30 40 50 60 70 80
As Atomic Percent Iodine
As
0 10 20 30 40
50 60 70 80 90 100
As-In
1100
1000
938°C L
900
As-In
817°C
800
Struktur-
700
14.4 Phase at.% In symbol group designation Prototype
600 AsIn 50 cF8 F 4 3m B3 ZnS (sphalerite)
(In) 100 tI2 I4/mmm A6 In
500
H. Okamoto, Phase Diagrams of Indium Alloys and Their Engineering

400
(As)
300
Park, OH, 26-28 (1992)
200
156.6°C
156.634°C
100
(In)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Indium In
0 10
20 30 40 50 60 70 80 90 100
As-K
900
800
L As-K
700 Struktur-
625°C
600 584 588°C
54.5 (As) 0 hR2 R 3m A7 aAs
531°C
41 63 bAs11K3 21.4 … … … …
500
aAs11K3 21.4 oP56 Pnab … aNa3 P11
bAs2K 33.3 … … … …
400 386°C
371°C
aAs2K 33.3 … … … …
AsK 50 oP16 P21 2121 … NaP
300
As4K5 55.6 … … … …
AsK3 75 hP8 P63 /mmc D018 Na3 As
200 (As) hP24 P63 cm D021 Cu3 P
(K) 100 cI2 Im 3 m A2 W
100
63.7°C
63.71°C J. Sangster and A.D. Pelton, J. Phase Equilibria, 14(2), 234-237 (1993)
(K)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Potassium K
0 10 20 30 40 50
60 70 80 90 100
As-Lu
3000
>2500°C
2500 L
As-Lu
Struktur-
2000 Phase at.% Lu symbol group designation Prototype
1663°C AsLu 50 cF8 Fm 3 m B1 NaCl
1500 (Lu) 99 to 100 hP2 P63 /mmc A3 Mg
1000
291-293 (1990)
817°C
(Lu)
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Lutetium Lu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
60
As
0 10
20 30 40 50 60 70 80 90 100
As-Mg
1200
L bAs2Mg3
As-Mg
1000
Struktur-
817°C Phase at.% Mg symbol group designation Prototype
800
As4Mg 20 tP20 P4 1212 … …
650°C bAs 2Mg3 60 to 62 cI80 Ia 3 D5 3 Mn 2O 3
600
aAs 2Mg3 60 to 61.5 hP5 P 3 m1 D5 2 La2O 3
(Mg) 100 hP2 P63/mmc A3 Mg
400
(As) A.A. Nayeb-Hashemi and J.B. Clark, Bull. Alloy Phase Diagrams, 6(5), 432-
(Mg) 434 (1985)
200
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Magnesium Mg
0 10 20
30 40 50 60 70 80 90 100
As-Mn
1400
As-Mn
(d Mn) 1246°C Struktur-
1200 L (gMn) Composition, Pearson Space bericht
1138°C
1100°C Phase at.% Mn symbol group designation Prototype
1029°C
1000
935°C 930°C gAsMn 50 hP4 P6 3/mmc B8 1 NiAs
95
bAs2Mn3 bAsMn 50 mP28 P21/m B31 MnP
(bMn)
800
750°C
775°C aAsMn 50 hP4 P6 3/mmc B8 1 NiAs
727°C As3Mn4 57.1 tI* … … …
614°C
S.P.
650°C bAs2 Mn3 ~60 … … … …
600
aAs2 Mn3 ~60 … … … …
AsMn2 66.7 to ? tP6 P4/nmm C38 Cu2Sb
AsMn3 75 oP16 Pmmn D0d AsMn3
400
(aMn) (dMn) 99 to 100 cI2 Im 3m A2 W
(gMn) 100 cF4 Fm 3 m A1 Cu
200 (bMn) 95 to 100 cP20 P4132 A13 bMn
125°C (aMn) 100 cI58 I 4 3m A12 aMn
40°C
0 H. Okamoto, Bull. Alloy Phase Diagrams, 10(5), 549-554 (1989)
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Manganese Mn
0 10 20 30
40 50 60 70 80 90 100
As-Mo
2200
2000 G + (Mo)
As-Mo
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1830°C Struktur-
1600 (As) 0 hR2 R 3m A7 aAs
As5Mo 16.7 oP6 Pnnm C18 FeS2 (marcasite)
1400 As2Mo 33.3 … … … …
As3Mo2 40 mC20 C2/m … W2As3
1250°C
1200
As4Mo5 55.6 tI18 I4/m … Ti5Te4
(Mo) 100 cI2 Im 3 m A2 W
1065°C (Mo)
1000
L. Brewer and R.H. Lamoreaux, Bull. Alloy Phase Diagrams, 1(2), 76-78
(1980)
800 G
614°C S.P.
600
(As)
400
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Molybdenum Mo
As
0 10 20 30 40
50 60 70 80 90 100
As-Nd
2400
2220°C
2200
L As-Nd
2000
Struktur-
1800
1690°C Phase at.% Nd symbol group designation Prototype
1600
As2Nd 33.3 mP12 P2 1/c … …
1400 AsNd 50 cF8 Fm 3 m B1 NaCl
AsNd3 75 … … … …
1200 (bNd) 99 to 100 cI2 Im 3m A2 W
(aNd) 99.5 to 100 hP4 P63/mmc A3’ aLa
970°C 1021°C
1000
865°C 850°C
(bNd) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 7(4),
863°C
800 345-347 (1986)
(aNd)
614°C S.P.
600
(As)
400
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
As Atomic Percent Neodymium Nd
30 40
50 60 70 80 90 100
As-Ni
1500
1455°C
As-Ni
1300 Struktur-
Phase at.% Ni symbol group designation Prototype
bAs 2Ni 33.3 oP6 Pnnm C18 FeS 2 (marcasite)
1100 aAs 2Ni 33.3 oP24 Pbca … …
AsNi 48.7 to 50 hP4 P63/mmc B8 1 NiAs
970°C As8Ni11 57.9 tP76 P4 1212 … …
As2Ni5 71.26 to 71.91 hP42 Pb3cm … …
897°C (Ni)
900
853°C 76.6 (Ni) 95 to 100 cF4 Fm 3m A1 Cu
42 830°C
804°C
62.8 M. Singleton and P. Nash, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed,
12-15 (1991)
700
600°C
aAs2Ni
500
30 40 50 60 70 80 90 100
Atomic Percent Nickel Ni
0 10 20 30 40 50
60 70 80 90 100
As-Os
2000
3033°C M.P.
As-Os
1500 Struktur-
As2Os 33.3 oP6 Pnnm C18 FeS2 (marcasite)
1000 (Os) 100 hP2 P63/mmc A3 Mg
614°C S.P. (Os) 303-304 (1990)
500
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Osmium Os
62
As Weight Percent Phosphorus
As-P
0 10 20 30 40 50 60 70 80 90 100
900
817°C As-P
800 L Struktur-
(As) 0 to 19.1 hR2 R 3m A7 aAs
AsP 37 to 46 … … … …
700
683°C
(P) (red) 64.6 to 100 c*66 … … …
19.1 39.9 52.4
(As)
618°C
44.9 64.6 76.2
600
576°C
AsP
(P)
500
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Phosphorus P
0 10 20 30 40 50
Weight Percent Lead
60 70 80 90 100
As-Pb
900
817°C
As-Pb
L Struktur-
700
Phase at.% Pb symbol group designation Prototype
500
N.A. Gokcen, Bull. Alloy Phase Diagrams, 11(2), 120-124 (1990)
327. 502°C
300 291°C
93.15
(As)
(Pb)
100
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Lead Pb

0 10 20 30 40 50 60 70 80 90 100
As-Pd
1600
1555°C
1400
As-Pd
Struktur-
1200 L Phase at.% Pd symbol group designation Prototype
As2Pd 33.3 cP12 Pa 3 C2 FeS2 (pyrite)
1000
bAsPd2 66.7 hP9 P 62 m C22 Fe2P
860°C aAsPd2 66.7 mP54 P2/m … …
820°C
800 777°C
802°C
770°C
As2Pd5 71.4 hP84 P 3 m1 … …
737°C 715 As3Pd8 72.7 hP33 P3 … …
728 80
AsPd3 75 tI32 I4 D0e Ni 3P
614°C S.P. 610°C
600 59.2 AsPd5 83.3 mC24 C2 … …
485°C bAsPd2 (Pd) 100 cF4 Fm 3 m A1 Cu
(Pd)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Palladium Pd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
As Weight Percent Platinum
As-Pt
0 10 20 30 40 50 60 70 80 90 100
1800
1769.0°C
1600 L+G 1 atm. As-Pt

1475°C Struktur-
L (As) 0 hR2 R 3m A7 aAs
1200
As2Pt 33.3 cP12 Pa 3 C2 FeS2 (pyrite)
1000
817°C
800
614 °C S.P. 600°C

600
400 (As) (Pt)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Platinum Pt
0 10 20 30
Weight Percent Rubidium
40 50 60 70 80 90 100
As-Rb
900
817°C
800
As-Rb
L Struktur-
Phase at.% Rb symbol group designation Prototype
600 (As) 0 hR2 R 3m A7 aAs
bAs 11Rb 3 21.4 … … … …
500 aAs 11Rb 3 21.4 oP56 Pnab … …
bAs11Rb3
416°C
bAs 7Rb 3 30 cF40 Fm 3 m … …
400 aAs 7Rb 3 30 … … … …
335°C As3Rb2 40 oF40 Fmmm … Rh2P 3
AsRb 50 oP16 P212 12 1 … NaP
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
300
As4Rb5 55.6 … … … …
AsRb3 75 hP8 P63/mmc D0 18 Na3As
200
(As) (Rb) 100 cI2 Im 3 m A2 W
100
J. Sangster and A.D. Pelton, J. Phase Equilibria, 14(2), 243-245 (1993)
39.48°C
39.48°C
(Rb)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Rubidium Rb

0 10 20 30 40 50 60 70 80 90 100
As-S
900
L1
817°C
L1 + L2
800
As-S
Struktur-
600 (As) 0 hR2 R 3m A7 aAs
L2 gAs 4S3 42.9 … … … …
500 bAs 4S3 42.9 t** … … …
(As) aAs 4S3 42.9 oP28 pnma … …
400 bAsS 50 mP32 P2 1/n … …
318°C 310°C
aAsS 50 mP32 P2 1/c Bl AsS
300
266°C
As2S3 60 mP20 P2 1/c D5 f As2S3
(S) 100 oF128 Fddd A16 aS
200°C
200
131°C 115.22°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
100
(S)
314-315 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Sulfur S
64
As Weight Percent Antimony
As-Sb
0 10 20 30 40 50 60 70 80 90 100
850
817°C
750
As-Sb
L
Struktur-
650 (As,Sb) 0 to 100 hR2 R 3m A7 aAs
630.755°C
612°C
(As,Sb) 314, 316 (1990)
550
450
350
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Antimony Sb

As-Se
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
900
817°C
800
As-Se
700 Struktur-
600
bAs4Se3 42.9 mC112 C2/c … …
500
aAs4Se3 42.9 oP28 pnma … …
(As) AsSe 50 mP32 P21/c Bl AsS
400
370°C As2Se3 60 mP20 P21/c D5f As2S3
300°C 297°C
(Se) 100 hP3 P31 21 A8 gSe
300
249°C
S.A. Degterov, A.D. Pelton, and J.D. L’Ecuyer, J. Phase Equilibria, 18(4), 357-
221°C
200 368 (1997)
147°C
127°C
100
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Selenium Se
0 10
20 30 40 50 60 70 80 90 100
As-Si
1500
1414°C
1400
As-Si
1300 L
Struktur-
1200
1100
1113°C 1097°C (As) 0 hR2 R 3m A7 aAs
96.5 As2Si 33.3 oP* Pbam … …
AsSi 50 o** … … …
1000 977°C
(Si) 96.5 to 100 cF8 Fd 3 m A4 C (diamond)
900
(Si) R.W. Olesinski and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 6(3), 254-
817°C
800
797°C 258 (1985)
700
(As)
600
500
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Silicon Si
As Weight Percent Samarium
As-Sm
0 10 20 30 40 50 60 70 80 90 100
2500
As-Sm
2000 Struktur-
L
Phase at.% Sm symbol group designation Prototype
1500 AsSm 50 cF8 Fm 3 m B1 NaCl
(gSm) 100 cI2 Im 3 m A2 W
(gSm) (bSm) 100 hP2 P63/mmc A3 Mg
1074°C (aSm) 100 hR3 R 3m C19 aSm
1000 992°C
(bSm) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
734°C
614°C S.P.
320-321 (1990)
500
(As) (aSm)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Samarium Sm
0 10 20 30 40
Weight Percent Tin
50 60 70 80 90 100
As-Sn
900
817°C
800
As-Sn
L Struktur-
(As) 0 to 21.9 hR2 R 3m A7 aAs
595°C
600
579°C 57.5 AsSn 50 cF8 Fm 3 m B1 NaCl
21.9 587.8°C
(As) As3Sn4 57.14 to 59 hR7 R 3m D8i Mo2B5
(bSn) 100 tI4 I41 /amd A5 bSn
500
(aSn) 100 cF8 Fd 3 m A4 C (diamond)
400 N.A. Gokcen, Bull. Alloy Phase Diagrams, 11(3), 271-278 (1990)
300
231.3°C 99.8
231.9681°C
(Sn)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Tin Sn
0 10 20 30 40 50
60 70 80 90 100
As-Ta
1400
1200 As-Ta
G + AsTa Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
As2Ta 33.3 mC12 C2 … …
800
AsTa 50 tI8 I41md … …
(Ta)
G As4Ta5 55.6 tI18 I4/m … Ti5 Te4
AsTa2 66.7 oP36 Pnnm … …
614°C AsTa3 75 mC64 C2/c … …
600
(Ta) 100 cI2 Im 3 m A2 W
Q. Han and R. Schmid-Fetzer, Mater. Sci. Eng., B22, 141-148 (1994)

400 (As)
200
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Tantalum Ta
66
As Weight Percent Terbium
As-Tb
0 10 20 30 40 50 60 70 80 90 100
3000
>2500°C
2500 L As-Tb
Struktur-
Phase at.% Tb symbol group designation Prototype
2000
AsTb 50 cF8 Fm 3 m B1 NaCl
(bTb) 98 to 100 cI2 Im 3m A2 W
1500
1356°C
(aTb) 99 to 100 hP2 P63/mmc A3 Mg
1289°C
(bTb) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
817°C 324-325 (1990)
(aTb)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
500
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Terbium Tb
0 10 20 30 40
50 60 70 80 90 100
As-Te
900
817°C
800
700 As-Te
L Struktur-
600
500
As2Te3 60 mC20 C2/2 … …
449.57°C
(Te) 100 hP3 P31 21 A8 gTe
400 380°C
364°C
73 H. Okamoto, J. Phase Equil. Diffusion, 31(2), 207 (2010)
300
200
(As) (Te)
100
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Tellurium Te
60 70
80 90 100
As-Th
3200
3000
As-Th
2600 L Phase at.% Th symbol group designation Prototype
bAs2Th 33.3 tP6 P4/nmm C38 Cu2Sb
2400
aAs2Th 33.3 oP12 Pnma C23 Co2Si
2200 As4Th3 42.9 cI28 I 4 3d D73 Th3P4
AsTh 50 to 51 cF8 Fm 3 m B1 NaCl
2000 (bTh) Im 3 m
100 cI2 A2 W
(aTh) 100 cF4 Fm 3 m A1 Cu
1800
1755°C
1600 1545°C
93.5 Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1400 (bTh) 326, 328 (1990)
1360°C
1200 (aTh)
1000
30 40 50 60 70 80 90 100
Atomic Percent Thorium Th
As Weight Percent Titanium
As-Ti
70 80 90 100
1800
1700
1670°C
1600
L
As-Ti
Struktur-
1500
1400
As2 Ti 33.3 oP24 Pnnm … …
bAsTi 50 hP4 P63 /mmc B81 NiAs
1300
(bTi) aAsTi 50 hP8 P63 /mmc Bi TiAs
1200
AsTi4 80 … … … …
(bTi) ? to 100 cI2 Im 3 m A2 W
1100 (aTi) 100 hP2 P63 /mmc A3 Mg
1000 J.L. Murray, Phase Diagrams of Binary Titanium Alloys, J.L. Murray, ed., ASM
International, Metals Park, OH, 25-26 (1987)
900
882°C
(aTi)
800
75 80 85 90 95 100
Atomic Percent Titanium Ti
0 10 20 30 40 50
60 70 80 90 100
As-Tl
900
817°C
800
As-Tl
Struktur-
700
600 (As) 0 hR2 R 3m A7 aAs
500 (aTl) 100 hP2 P63/mmc A3 Mg
R.C. Sharma and Y.A. Chang, J. Phase Equilibria, 17(5), 422-424 (1996)
400
L1
L1 + L2 L2
300 (bTl) 304°C
37 240°C 71
230°C
200 220°C 80.8
(As) (aTl)
100
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Thallium Tl
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50
60 70 80 90 100
As-Tm
3000
>2500°C
2500 L As-Tm
Struktur-
2000
AsTm 50 cF8 Fm 3 m B1 NaCl
1545°C (Tm) 99 to 100 hP2 P63 /mmc A3 Mg
1500
1000 330, 332 (1990)
817°C
500 (Tm)
(As)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Thulium Tm
68
As Weight Percent Uranium
As-U
0 10 20 30 40 50 60 70 80 90 100
3000
2705°C
L As-U
2500
Struktur-
Phase at.% U symbol group designation Prototype
2000 (As) 0 hR2 R 3m A7 aAs
As2U 33.3 tP6 P4/nmm C38 Cu2Sb
As4U3 42.9 cI28 I 4 3d D7 3 Th3P 4
1500 AsU 50 cF8 Fm 3 m B1 NaCl
(gU) 100 cI2 Im 3 m A2 W
1125°C
1135°C (bU) 100 tP30 P42/mnm Ab bU
1000 (aU) 100 oC4 Cmcm A20 aU
(gU)
817° C 776°C
(bU) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
500
(As) 330, 333-334 (1990)
(aU)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Uranium U
70
80 90 100
As-Yb
2800
2600
2400
As-Yb
2200 Struktur-
2000
1800
AsYb 50 cF8 Fm 3 m B1 NaCl
1600 bAs 3Yb 4 57.1 cI28 I 4 3d D7 3 Th3P 4
1400 aAs 3Yb 4 57.1 hR28 R3 … …
As3Yb5 62.5 hP16 P63/mcm D8 8 Mn5Si3
1200
1000 (bYb) 100 cF4 Fm 3 m A1 Cu
(gYb)
819°C
800 795°C
400 335-336 (1990)
(b Yb)
200
0
40 50 60 70 80 90 100
Atomic Percent Ytterbium Yb
0 10 20 30
Weight Percent Zinc
40 50 60 70 80 90 100
As-Zn
1015°C
1000
L As-Zn
Struktur-
800 770°C Phase at.% Zn symbol group designation Prototype
19
38
651°C As2Zn 33 to 34 mP24 P21/c … …
600 bAs2Zn3 60 cF12 Fm 3 m C1 CaF2
a’As2Zn3 60 tP160 P42/nbc … …
aAs2Zn3 60 tI160 I41cd … …
419°C 419.58°C (Zn) 100 hP2 P63/mmc A3 Mg
400
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

(As)
200 190°C
(Zn)
0
0 10 20 30 40 50 60 70 80 90 100
As Atomic Percent Zinc Zn
At Weight Percent Molybdenum
At-Mo
0 10 20 30 40 50 60 70 80 90 100
1400
2623°C M.P.
1200 G + (Mo)
At-Mo
? Struktur-
1000
G
(At) 0 … … … …
800 At2Mo 33.3 oC36 Cmca … …
(Mo) 100 cI2 Im 3 m A2 W
?
L 340-341 (1990)
400
(Mo)
302°C
200
(At)
0
0 10 20 30 40 50 60 70 80 90 100
At Atomic Percent Molybdenum Mo
0
5 10 20 30 40 60 100
Au-B
2400
2200
L1 L2
L1 + L2
Au-B
2092°C
Struktur-
2000
1800 (Au) 0 cF4 Fm 3 m A1 Cu
AuB2 66.7 … … … …
1600
(bB) 100 hR108 R 3m … …
H. Okamoto and T.B. Massalski, Phase Diagrams of Binary Gold Alloys, H.

1400 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 25-27
(1987)
1200
1064.43°C
1000
(Au) AuB2 (bB)
800
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Boron B
0
10 20 30 40 60 100
Au-Be
1300
1289°C
(bBe) 1270°C
Au-Be
1200
Struktur-
1100
1064.43°C
L (Au) 0 to 0.2 cF4 Fm 3 m A1 Cu
1000
Au3Be 25 o** … … …
Au2Be 33.3 tI6 I4/mmm C11b MoSi2
900
? ? Au4Be3 42.9 … … … …
? bAuBe 49 to 51 … … … …
800
aAuBe 49 to 51 cF8 P213 B20 FeSi
730°C
bAuBe Fd 3 m
700 AuBe3 73 to 77 cF16 B32 NaTl
645°C
40.3 610°C
? AuBe5 82 to 86 cF24 F 4 3m C15 b AuBe5
596 595 602 595°C (bBe) Im 3 m
600 580°C
25.9 39.4 585°C 100 cI2 A2 W
21.5
555°C (aBe) (aBe) 99.75 to 100 cF4 Fm 3 m A1 Cu
500
(Au)
400 390°C Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 28-31
(1987)
300
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Beryllium Be

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
70
Au
0 10 20 30
40 50 60 70 80 90 100
Au-Bi
1200
1064.43°C
1000
Au-Bi
L Struktur-
(Au) 0 cF4 Fm 3 m A1 Cu
600 Au2Bi 33.3 cF24 Fd 3 m C15 Cu 2Mg
400 371°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
241.1°C 271.442°C 343, 345-346 (1990)
200 86.8
116°C
(Au) (Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Bismuth Bi
0 10
20 30
Au-C
1200
L L + (C)
1100
1064.43°C
Au-C
0.082 4.7 Struktur-beri
1000
Composition, Pearson Space cht
(Au) 0 to 0.082 cF4 Fm 3 m A1 Cu
(C) 100 hP4 P6 3/mmc A9 C (graphite)
900
(Au) (1984)
800 (Au) + (C)
700
600
0 1 2 3 4 5 6
Au Atomic Percent Carbon
0
10 20 30 40 50 60 70 80 100
Au-Ca
1100
1064.43°C
Au-Ca
1015°C Struktur-
L Phase at.% Ca symbol group designation Prototype
bAu9Ca10 (Au) 0 cF4 Fm 3 m A1 Cu
900 880°C
864°C
Au5Ca 16.7 cF24 F 4 3m C15b AuBe5
860°C
853
844°C
842°C
Au4Ca 20 … … … …
804°C 807°C 798°C Au3Ca 25 … … … …
800
bAu2Ca 33.3 … … … …
764°C aAu2 Ca 33.3 … … … …
700
700°C AuCa* 50 oC8 Cmcm Bf CrB
658°C bAu9Ca10 50 to 55 … … … …
(Au) 95.5 aAu9 Ca10 49 to 55.5 … … … …
600 Au3Ca4 57.1 … … … …
AuCa2 66.7 … … … …
(bCa) 95.5 to 100 cI2 Im 3 m A2 W
500
*Not shown.
H. Okamoto, T.B. Massalski, C.B. Alcock, and V.P. Itkin, Phase Diagrams of
400
0 10 20 30 40 50 60 70 80 90 100 Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed., ASM International,
Metals Park, OH, 39-42 (1987)
Au Atomic Percent Calcium Ca
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Au
0 10 20
30 40 50 60 70 80 90 100
Au-Cd
1200
1064.43°C
1000
L Au-Cd
800 Struktur-
627 629°C
Phase at.% Cd symbol group designation Prototype
600 (Au) (Au) 0 to 32.5 cF4 Fm 3 m A1 Cu
540°C 505°C a1 ~25 cP4 Pm 3m L12 AuCu3
a2
516 d
412°C d' a2 25.5 to 35.5 hP* … … …
400
b 370 375 e
305 309°C
Long-period superstructures
340°C 321.108°C
270 Au3Cd 24 tI16 I4/mmm D023 Al3Zr
e' 4H(1d) 25 hP4 P63/mmc A3’ aLa
200 d" h'
(Cd) 9a0-4H(2d) 24 to 27 hP* … … …
a1 6H 25 to 27 hR3 R 3m C19 aSm
h
0 9R 26 to 30 hR* … … …
7a0-2H 29 to 34 hP* P63/mmc … …
9a0-2H 29 to 34 hP* P63/mmc … …
-200
0 10 20 30 40 50 60 70 80 90 100 b 43 to 57 cP2 Pm 3 m B2 CsCl
Au Cd d 61.2 to 67.6 cI52 I 4 3m D82 Cu5Zn8
Atomic Percent Cadmium
d’ 61.2 to 65.5 cI52 I 4 3m D82 Cu5Zn8
d” 62.6 to 64.5 … … … …
Au3Cd5 61.6 to 62.1 tI32 I4/mcm D8m W5 Si3
e 69.9 to 76.5 tI* … … …
e’ 72 to 76 tI* … … …
h’ 82 … … … …
40 50 60
600 h 82 … … … …
(Cd) 96.5 to 100 hP2 P63/mmc A3 Mg
L
540°C 61.6 H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 7(1), 52-67 (1986)
56 61.2
516°C 61.5
56.5 61.2 505°C
70
500 d 67.6 496°C 70.8
72.5
450°C
65.5 66 69.9
b d'
400
e
370°C 375°C
57 70.1
340°C d"
56
305°C
300 63.6 71.1
270°C
e'
200
50 55 60 65 70 75
Atomic Percent Cadmium

Au-Ce
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1500
1372°C
Au-Ce
1300 Struktur-
L Phase at.% Ce symbol group designation Prototype
1150°C
1130°C
1100 (Au) 0 cF4 Fm 3 m A1 Cu
1064.43 1025°C Au6 Ce 14.3 mC28 C/2c … Au6 Pr
995°C
31
38.7
Au51 Ce1 4 21.5 hP65 P6/m … Ag51 Gd1 4
?
Au2 Ce 33.3 oI12 Imma … Cu2 Ce
900
bAuCe 50 oC8 Cmcm Bf CrB
808°C (dCe) aAuCe
9.5 798°C 50 oP8 Pnma B27 FeB
726°C
AuCe2 66.7 oP12 Pnma C23 Co2 Si
700 (dCe) Im 3 m
665°C 100 cI2 A2 W
76
(gCe) 100 cF4 Fm 3 m A1 Cu
520°C (bCe) 100 hP4 P63/mmc A3’ aLa
500 480°C 84 (aCe) Fm 3 m
100 cF4 A1 Cu
(Au)
(gCe)
K.A. Gschneidner, Jr., F.W. Calderwood, H. Okamoto, and T.B. Massalski,
300 Phase Diagrams of Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed.,
0 10 20 30 40 50 60 70 80 90 100
ASM International, Metals Park, OH, 57-60 (1987)
Au Atomic Percent Cerium Ce
72
Au
0
Weight Percent Chlorine
10 20 30 40
Au-Cl
400
350 342°C L
60 Au-Cl
304°C Struktur-
Phase at.% Cl symbol group designation Prototype
260°C
250 68
AuCl 50 tI16 I41 /amd … …
AuCl3 75 mP16 P21/c … …
(Cl) 100 oC8 Cmca A14 I
200
(Au)
150 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 60-62
(1987)
100 90°C
50
0 10 20 30 40 50 60 70 80
Au Atomic Percent Chlorine

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10
20 30 40 50 60 70 80 90 100
Au-Co
1600
1495°C
1400
L
Au-Co
1200 (aCo)
Struktur-
1064.43°C
996.5°C
1000 23 24.8 98.1 (Au) 0 to 23 cF4 Fm 3 m A1 Cu
(Au)
(aCo) 97.5 to 100 cF4 Fm 3 m A1 Cu
800 (eCo) 100 hP2 P6 3/mmc A3 Mg
600 H. Okamoto, T.B. Massalski, M. Hasebe, and T. Nishizawa, Bull. Alloy Phase
Diagrams, 6(5), 449-454 (1985)
422°C
422°C
400
200 (eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Cobalt Co
0 10
20 30 40 50 60 70 80 90 100
Au-Cr
1900
1863°C
1700
Au-Cr
L
1500 Struktur-
1300
(Au) 0 to 47 cF4 Fm 3 m A1 Cu
23.9 1160°C
1100
47 ? a’ 12 to 23 tI10 I4/m D1a MoNi4
1064.43
(Cr) ? to 100 cI2 Im 3 m A2 W
900
(Au) (Cr) (1985)
700
500
?
300
a'
100
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Chromium Cr
Au Weight Percent Cesium
Au-Cs
0 10 20 30 40 50 60 70 80 90 100
1200
?
1064.43°C
1000
Au-Cs
L Struktur-
800 Phase at.% Cs symbol group designation Prototype
Au 5Cs 16.7 hP6 P6/mmm D2 d CaCu 5
600 585°C AuCs 50 cP2 Pm 3 m B2 CsCl
(Cs) 100 cI2 Im 3 m A2 W
400
(Au)
200
(Cs)
27°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Cesium Cs
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10
20 30 40 50 60 70 80 90 100
Au-Cu
1100
1084.87°C
1064.43°C
1000 L
910°C Au-Cu
900 44
Struktur-
700 (Au,Cu) 0 to 100 cF4 Fm 3 m A1 Cu
(Au,Cu) Au 3Cu ? to 39 cP4 Pm 3 m L1 2 AuCu3
600
AuCuII 40 to 63 oI40 Imma … …
AuCuI <42 to >57 tP4 P4/mmm L1 0 AuCu
500
AuCu3II 66 to ? tP28 P 4 mm … Cu3Pd
AuCuII 410°C AuCu3II
400 390°C AuCu3I 67 to >81 cP4 Pm 3 m L1 2 AuCu3
385
64
300 285 AuCu3I H. Okamoto, D.J. Chakrabarti, D.E. Laughlin, and T.B. Massalski, Phase
240 AuCuI
38.5 Diagrams of Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed., ASM
200
Au 3Cu
100
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Copper Cu
0 10 20
30 40 50 60 70 80 90 100
Au-Dy
1800
1660°C
1600 Au-Dy
L
Struktur-
(bDy) Composition, Pearson Space bericht
1412°C
1400 1360°C 1381°C Phase at.% Dy symbol group designation Prototype
1320°C
(Au) 0 to 2.3 cF4 Fm 3 m A1 Cu
1230°C 1235°C Au 6Dy 14.3 tP56 P4 2/ncm … Au 6Ho
1200 1185 38
27 Au 51Dy 14 21.5 hP65 P6/m … Ag 51Gd 14
1095°C
1065°C Au 3Dy 25 oP8 Pmmn D0 a bTiCu3
1064.43
1000
Au 2Dy 33.3 tI6 I4/mmm C11 b MoSi2
935°C bAuDy 50 cP2 Pm 3 m B2 CsCl
79
845°C aAuDy 50 oC8 Cmcm Bf CrB
808°C
800 2.3 9.5
AuDy2 66.7 oP12 Pnma C23 Co 2Si
(aDy) (aDy) 100 hP2 P63/mmc A3 Mg
600
(Au) K.A. Gschneidner, Jr., F.W. Calderwood, H. Okamoto, and T.B. Massalski,
400
Phase Diagrams of Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed.,
0 10 20 30 40 50 60 70 80 90 100 ASM International, Metals Park, OH, 96-98 (1987)
Au Atomic Percent Dysprosium Dy
74
Au Weight Percent Erbium
Au-Er
0 10 20 30 40 50 60 70 80 90 100
1800
1710°C
bAuEr
1600
1529°C Au-Er
L
Struktur-
1400 1385°C
1285°C
1255 37.5
1200
27 (Au) 0 to 5.5 cF4 Fm 3 m A1 Cu
1120°C 70 Au4Er 20 tI10 I4/m D1a MoNi4
1064.43
17.5 1000
1030°C Au3Er 25 oP8 Pmmn D0a bTiCu3
1000 76 >99
Au2Er 33.3 tI6 I4/mmm C11b MoSi2
Au10Er7 41.1 tI136 I41 /acd … Au10Gd7
805°C
800 5.5 11
bAuEr 50 cP2 Pm 3 m B2 CsCl
aAuEr 50 oC8 Cmcm Bf CrB
600
AuEr2 66.7 oP12 Pnma C23 Co2Si
(Au) (Er) (Er) >99 to 100 hP2 P63 /mmc A3 Mg
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Erbium Er
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Au-Eu
1200
1085°C
1064.43°C
1020°C Au-Eu
1000 975°C
Struktur-
905 900°C L Composition, Pearson Space bericht
850°C 855°C
810°C
822°C
800 Fm 3 m
755°C (Au) 0 cF4 A1 Cu
Au5Eu 16.7 hP6 P6/mmm D2d CaCu 5
Au4Eu 20 … … … …
600
565°C
Au2Eu 33.3 oI12 Imma … CeCu 2
bAuEu 50 … … … …
500
465°C aAuEu 50 oP8 Pnma B27 FeB
400 Au2Eu3 60 hR45 R3 … …
(Au) Au3Eu7 70 hP20 P6 3/mc D102 Fe3Th7
AuEu3 75 oP16 Pnma D011 Fe3C
(Eu) 100 cI2 Im 3 m A2 W
200 (Eu)
0
0 10 20 30 40 50 60 70 80 90 100
364, 366-367 (1990)
Au Atomic Percent Europium Eu
0 10
Weight Percent Iron
20 30 40 50 60 70 80 90 100
Au-Fe
1600
1538°C
89 97.6 (dFe)
1400 97.3 Au-Fe
1394°C
L Struktur-
1433°C
1200 56.8 1173°C Phase at.% Fe symbol group designation Prototype
74.1 91.9
(gFe)
(Au) 0 to 74.1 cF4 Fm 3 m A1 Cu
1064.43°C
1036°C (dFe) 97.6 to 100 cI2 Im 3 m A2 W
1000 18.5
(gFe) 91.9 to 100 cF4 Fm 3 m A1 Cu
912°C
868°C 97.8 (aFe) 98.6 to 100 cI2 Im 3 m A2 W
53.1 98.6
800 769°C 770°C
(Au) Tc H. Okamoto, T.B. Massalski, L.J. Swartzendruber, and P.A. Beck, Phase
(aFe) Diagrams of Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed., ASM
600
400
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Iron Fe
Au Weight Percent Gallium
Au-Ga
0 10 20 30 40 50 60 70 80 90 100
1200
1064.43°C
1000
Au-Ga
Struktur-
800
(Au) 0 to 12.4 cF4 Fm 3 m A1 Cu
600 a’ 12.75 to 14.2 hP16 P63/mmc D024 Ni3Ti
a' 491.3°C b 20.4 to 22.1 hP* … … …
461.3°C
(Au) b’
12.4
415.4°C 409.8°C 56 448.6°C 21.3 to 24.8 o** … … …
400 375
348° C 348.9 339.4°C g 29.8 to 31 o** … … …
346.7 g 33.6
282°C 286°C
g’ 29.8 to 31 o** … … …
274°C
200 b AuGa 50 oP8 Pnma B31 MnP
AuGa2 66.7 cF12 Fm 3 m C1 CaF2
g' (Ga) 100 oC8 Cmca A11 Ga
30°C
29.7741°C
0 b'
(Ga) T.B. Massalski and H. Okamoto, Phase Diagrams of Binary Gold Alloys, H.
Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 111-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
-200
0 10 20 30 40 50 60 70 80 90 100 118 (1987)
Au Atomic Percent Gallium Ga
0 10 20
30 40 50 60 70 80 90 100
Au-Gd
1600 1585°C Au-Gd
Struktur-
bAuGd
1400 L
1340°C (Au) 0 to 0.7 cF4 Fm 3 m A1 Cu
(bGd) 1313°C
Au6Gd 14.3 tP56 P42/ncm … Au6Ho
1200°C
1220°C 1235°C Au51Gd14 21.5 hP65 P6/m … Ag51Gd14
1200 1180°C 1160 97
1165°C
Au3Gd 25 oP8 Pmmn D0a bTiCu3
1140°C
1135°C 1100°C Au2Gd 33.3 tI6 I4/mmm C11b MoSi2
1064.43
Au10Gd7 41.2 tI136 I41/acd … …
1000
935°C Au4Gd3 42.9 hR42 R3 … Pu3 Pd4
855°C
bAuGd 50 cP2 Pm 3 m B2 CsCl
845°C
800°C 79 aAuGd 50 oC8 Cmcm Bf CrB
800
11 AuGd2 66.7 oP12 Pnma C23 Co2Si
(bGd) 97 to 100 cI2 Im 3 m A2 W
600 (aGd) (aGd) ? to 100 hP2 P63 /mmc A3 Mg
(Au)
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Gadolinium Gd
0 10
20 30 40 50 60 70 80 90 100
Au-Ge
1200
1064.43°C
Au-Ge
1000 Struktur-
L Phase at.% Ge symbol group designation Prototype
800
(1984)
600
400
361°C
3 28
(Au) (Ge)
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Germanium Ge
76
Au Weight Percent Hafnium
Au-Hf
0 10 20 30 40 50 60 70 80 90 100
2231°C
2200
2000Lom
2003Du Au-Hf
2000 L Struktur-
(bHf) Composition, Pearson Space bericht
1800 1747°C Phase at.% Hf (a) symbol group designation Prototype
1743°C
1655°C (Au) 0 to 9 cF4 Fm 3 m A1 Cu
1600 Au5Hf 14.5 to 17 tI10 I4/m D1a MoNi4
1520°C
1543
1513°C
1492°C Au4Hf 20 oP20 Pnma … Au4 Zr
1400 Au3Hf 25 oP8 Pmmn D0a bTiCu3
1298°C 1286°C Au2Hf 29 to 33.3 tI6 I4/mmm C11b MoSi2
1200 Au10Hf7 41.2 tI34 … … …
1145°C
1114°C gAuHf 47 to 50 oP4? … … …
1064.43 1100 1031 1046°C
1000 bAuHf 48 to 50 tP4 P4/nmm B11 gCuTi
AuHf2 66.7 tI6 I4/mmm C11b MoSi2
(Au) (bHf) 87 to 100 cI2 Im 3 m A2 W
800
(aHf) (aHf) 97 to 100 hP2 P63/mmc A3 Mg
600 (a) For [2003Du].

0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Hafnium Hf
0 10 20 30
40 50 60 70 80 90 100
Au-Hg
1100
1064.43°C
900
Au-Hg
Struktur-
(Au) 0 to 19.8 cF4 Fm 3 m A1 Cu
500 a1 16 to 23 hP36 P63/mmc … …
419°C
19.8 z 20 to 26 hP2 P63/mmc A3 Mg
388°C
(Au) Au2Hg 33.3 hP22 P63/mmc … …
300
122°C
100 H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 10(1), 132-139
z (1989)
-39.0°C
-38.8290°C
-100
a1 (Hg)
-300
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Mercury Hg
0 10 20
30 40 50 60 70 80 90 100
Au-Ho
1800
1700°C
bAuHo
1600 1610°C
L Au-Ho
1474°C
Struktur-
1400
1350°C 40.5 1360°C Composition, Pearson Space bericht
1250°C 1285°C Phase at.% Ho symbol group designation Prototype
28 38.5
1200 1230°C (Au) 0 to 4 cF4 Fm 3 m A1 Cu
1095°C Au6Ho 14.3 tP56 P42/ncm … Au6Ho
17.5 1060°C 70
1064.43 Au4Ho 20 tI10 I4/m D1a MoNi4
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000 985°C
15 950°C 78 >99 Au51Ho14 21.5 hP65 P6/m … Ag51Gd14
13 840°C Au3Ho 25 oP8 Pmmn D0a bTiCu3
805°C
800 4 11
Au2Ho 33.3 tI6 I4/mmm C11b MoSi2
Au10Ho7 41.1 tI136 I41/acd … Au10 Gd7
bAuHo 50 cP2 Pm 3 m B2 CsCl
600
(Ho) aAuHo 50 oC8 Cmcm Bf CrB
AuHo2 66.7 oP12 Pnma C23 Co2Si
400 (Au) (Ho) >99 to 100 hP2 P63 /mmc A3 Mg

200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Holmium Ho
Au
0 10 20
30 40 50 60 70 80 90 100
Au-In
1200
Au-In
Struktur-
L a1 8.5 to 14.5 hP16 P63 /mmc D024 Ni3Ti
800 hP4 P63 /mmc A3’ aLa
z 11 to 21 hP2 P63 /mmc A3 Mg
649°C b 21.5 hP* … … …
(Au)
600
641°C o** … … …
506°C
539°C b1 22 hP26 P3 … Cu10Sb3
487°C
461°C 496°C e 25 oP8 Pmmn D0a bTiCu3
a1 479
450°C y 456 °C
400 z 380 g g 29 to 30 cP52 P 4 3m D83 Al4Cu9
337
361°C g’ 29.8 hP* … … …
b
y 36 to 39 hP5 P 3 m1 D513 Al3Ni2
275 224°C
200 AuIn 50 to 50.1 aP* … … …
e 156°C
b1 g' 156.634°C AuIn2 66.7 cF12 Fm 3 m C1 CaF2
(In)
0
0 10 20 30 40 50 60 70 80 90 100 H. Okamoto, J. Phase Equilibria, 25(2), 197-198 (2004)
Au Atomic Percent Indium In
0
10 20 30 40 50 60 70 80 100
Au-K
1064.43°C
1000 975°C
Au-K
Struktur-
L Phase at.% K symbol group designation Prototype
650°C
Au5K 16 to 20 hP6 P6/mmm D2d CaCu 5
600
Au2K 33.3 … … … …
532°C
AuK 50 … … … …
AuK2 66.7 … … … …
400 (K) 100 cI2 Im 3 m A2 W
(Au)
270°C A.D. Pelton, Bull. Alloy Phase Diagrams, 7(1), 23-25 (1986)
200
57°C 98
63.71°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Potassium K
0 10 20
30 40 50 60 70 80 90 100
Au-La
1400
1325°C
Au-La
1204°C 1214°C Struktur-
1200
37.3 L Phase at.% La symbol group designation Prototype
1054°C
1064.43°C
31 (Au) 0 cF4 Fm 3 m A1 Cu
1000 Au6 La 14.3 mC28 C2/c … Au6Pr
? (gLa) Au51 La14 21.5 hP65 P6/m … Ag51 Gd14
918°C
865°C Au2 La 33.3 oI12 Imma … CeCu2
800
808°C
9
bAuLa 50 oC8 Cmcm Bf CrB
aAuLa 50 oP8 Pnma B27 FeB
660°C 665°C AuLa2 66.7 oP12 Pnma C23 Co2Si
600 (gLa) 100 cI2 Im 3 m A2 W
(Au) 561°C
84 (bLa) 100 cF4 Fm 3 m A1 Cu
(bLa)
400
310°C
(aLa)
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Lanthanum La

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Au Weight Percent Lithium
Au-Li
0 2 5 10 20 30 50 100
1200
Au-Li
1000
L (Au) 0 to 40 cF4 Fm 3 m A1 Cu
a1 17 to 38 cP4 Pm 3 m L12 AuCu3
800
a2 38 to 40 … … … …
Au5 Li4 44.4 hP* … … …
645°C
40
631 b’2 47 to 53 oP2 … … …
600 (Au) 45.5
b’1 53 to 55 tP2 … … …
508 511°C
b'1 b' 55.8 61 b’ 55 to 56 cP2 Pm 3 m B2 CsCl
450°C
a1
440°C
d2
436
71
d2 63 to 65 hP9 … … …
400
?
d1 62.5 to 65.5 … … … …
300°C Fm 3 m
278°C AuLi3 75 cF16 D03 BiF3
297°C 245°C
Au4 Li15 79 cI76 I 4 3d D86 Cu15Si4
200
b'2 155°C 94.7 180.6°C (bLi) 99.3 to 100 cI2 Im 3 m A2 W
a2 99.3
d1 (bLi) (aLi) 100 hP2 P63/mmc A3 Mg
0
0 10 20 30 40 50 60 70 80 90 100 A.D. Pelton, Bull. Alloy Phase Diagrams, 7(3), 228-231 (1986)
Au Atomic Percent Lithium Li
0 10 20
30 40 50 60 70 80 90 100
Au-Lu
1800 1780°C
1663°C
1600 L Au-Lu
Struktur-
1331°C 67.7
1200 1176°C (Au) 0 cF4 Fm 3 m A1 Cu
1130°C
1082°C
31.5 78.7 Au4Lu 20 tI10 I4/m D1a MoNi4
1064.43 1030°C 1047°C Au3Lu 25 oP8 Pmmn D0a bTiCu3
1000 21.3 27.9
Au2Lu 33.3 tI6 I4/mmm C11b MoSi 2
1024°C
AuLu 50 cP2 Pm 3 m B2 CsCl
800
742°C AuLu2 66.7 oP12 Pnma C23 Co2Si
11.4 (Lu) 100 hP2 P6 3/mmc A3 Mg
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600 (Lu)

400 (Au)
226°C
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Lutetium Lu
0
10 20 30 40 50 60 80 100
Au-Mg
1200 Au-Mg
1150°C Struktur-
1064.43°C
1000 L Au4Mg 20 … … … …
Au15 Mg4 * 21 mP38 P2/m … …
Au78 Mg22 22 tI16 I4/mmm D023 Al3Zr
Au77 Mg23 23 hP108 P63 /mcm … …
818°C Au76 Mg24 24 oC64 Cmcm … …
(Au)
800 780 788°C Au74 Mg26 26 oC160 Cm2m … …
AuMg 33 to 58 cP2 Pm 3 m B2 CsCl
721
AuMg2 66.7 oP108 Pnma … …
Au2Mg5 71.4 … … … …
AuMg 650°C
AuMg3 75 hP8 P63 /mmc D018 Na3As
600
575°C hP24 P 3 c1 … …
93.04 99.9 (Mg) 99.9 to 100 hP2 P63 /mmc A3 Mg
* Not shown
(Mg)
A.A. Nayeb-Hashemi and J.B. Clark, Phase Diagrams of Binary Gold Alloys, H.
400 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH,
0 10 20 30 40 50 60 70 80 90 100
165-168 (1987)
Au Atomic Percent Magnesium Mg
Au
0 10
20 30 40 50 60 70 80 90 100
Au-Mn
1400
1300 1260°C (dMn)

1246°C
1200 L
1138°C
1100 1095°C 69.2 75 1100°C
1064.43°C
1000 960°C (gMn) Au-Mn
31 33.4 Struktur-
900 b
(bMn) Composition, Pearson Space bericht
800 760°C Phase at.% Mn symbol group designation Prototype
(Au) 727°C
700 680°C 660°C (Au) 0 to 31 cF4 Fm 3 m A1 Cu
600
Au4Mn 17 to 20 tI10 I4/m D1a MoNi4
a” 21.2 to 22 oP* Pnnm … …
500
Lozenge structures
400 Au31 Mn9 22.50 tP40 P4/m … …
300 Au72 Mn21 22.58 m** … … …
(aMn) Au41 Mn12 22.64 m** … … …
200
b 1' Au167Mn4 9 22.69 o** … … …
100 Au95 Mn28 22.76 m** … … …
0
Au27 Mn8 22.86 o** … … …
b1 b2 h(Au13Mn4 ) 23.53 o** … … …
-100
0 10 20 30 40 50 60 70 80 90 100 Au3Mn 25
Au Atomic Percent Manganese Mn
5H hP* … … …
3R hR* … … …
M=1 tI8 I4/mmm D022 Al3Ti
6H1 hP* … … …
6H2 hP* … … …
Au11 Mn4 26.67 mC810 Cm … …
Weight Percent Manganese Au5Mn2 28.57 mC14 C2/m … …
5 10 15 Au2Mn 33.33 tI6 I4/mmm C11b MoSi2
900 b 33.4 to 69.2 cP2 Pm 3m B2 CsCl
b1’ 41 to 59 t** … … …
800
b1 45 to 50 t** … … …
740°C
b b2 50 to 55 t** … … …
700
650°C AuMn2 66.67 tI6 I4/mmm C11b MoSi2
(Au) 625°C 620°C
(dMn) Im 3 m
600
? to 100 cI2 A2 W
(gMn) 75 to 100 cF4 Fm 3m A1 Cu
525°C
500
500°C (bMn) 100 cP20 P4 132 A13 bMn
450°C
(aMn) ? to 100 cI58 I 4 3m A12 aMn
400
T.B. Massalski and H. Okamoto, Bull. Alloy Phase Diagrams, 6(5), 454-467
300 (1985)
h
200
100
-100
10 15 20 25 30 35 40
Atomic Percent Manganese
0 10
20 30 40 50 60 70 80 90 100
Au-Mo
2800
2623°C
2400
L --`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
2000 Au-Mo
Struktur-
1600
(Au) 0 to 1.25 cF4 Fm 3 m A1 Cu
1200 (Mo) 99.6 to 100 cI2 Im 3 m A2 W
2.1 1054°C
1064.43
1.25 99.975
T.B. Massalski, H. Okamoto, and L. Brewer, Bull. Alloy Phase Diagrams, 7(5),
800 449-452 (1986)
(Au) (Mo)
400
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Molybdenum Mo
80
Au Weight Percent Sodium
Au-Na
0 10 20 30 40 50 60 80 100
1100
1064.43°C
1002°C
1000
900 877°C Au-Na

800 Struktur-
700 Au5Na Phase at.% Na symbol group designation Prototype
Au2Na
600 Au5Na 15 to 22 … … … …
Au2Na 32 to 40 cF24 Fd 3 m C15 Cu 2Mg
500
AuNa 50 … … … …
AuNa2 66.7 tI12 I4/mcm C16 Al 2Cu
400 372°C
(Na) 100 cI2 Im 3 m A2 W
300 (Au)
200
163°C
82.5
100 81°C 97.8°C
96
(Na)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Sodium Na
0 10
20 30 40 50 60 70 80 90 100
Au-Nb
2500
2469°C
2000 Au-Nb
L
Struktur-
(Nb) Phase at.% Nb symbol group designation Prototype
52 1570°C
64
1560°C (Au) 0 to 57 cF4 Fm 3 m A1 Cu
57
1500
1415°C
Au2Nb 33.3 hP3 P6/mmm C32 AlB 2
Au2Nb3 60 tI10 I4/mmm … …
1220°C AuNb3 73 to 83 cP8 Pm 3n A15 Cr 3Si
(Nb) 64 to 100 cI2 Im 3 m A2 W
1064.43°C 1035°C
1000
(Au)
920°C H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 6(2), 134-136
(1985)
500
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Niobium Nb
0 10 20
30 40 50 60 70 80 90 100
Au-Nd
1600
1470°C
gAuNd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1400
Au-Nd
1360°C Struktur-
41.5 1250°C L Composition, Pearson Space bericht
1210°C
28
37 (Au) 0 to 0.3 cF4 Fm 3 m A1 Cu
1064.43°C 1080
1000 1050
(bNd)
1021°C Au6Nd 14.3 mC28 C2/c … Au6Pr
Au51Nd14 20.3 to 21.5 hP65 P6/m … Ag51Gd14
13 875°C
810°C 70 90 99 862°C Au36Nd17 32.1 tP106 … … Au36 Nd17
795°C
800
0.3 9
825°C Au4Nd3 42.9 hR14 R3 … Pu3 Pd4
655°C gAuNd 50 cP2 Pm 3 m B2 CsCl
600 81 bAuNd 50 oC8 Cmcm Bf CrB
aAuNd 50 oP8 Pnma B27 FeB
430°C
AuNd2 66.7 oP12 Pnma C23 Co2Si
400
(bNd) 99 to 100 cI2 Im 3 m A2 W
(aNd) (aNd) 100 hP4 P63 /mmc A3’ aLa
200 (Au)

0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Neodymium Nd
Au Weight Percent Nickel
Au-Ni
0 10 20 30 40 50 60 70 80 90 100
1500
1455°C
1300
L
Au-Ni
1100
Struktur-
955°C Phase at.% Ni symbol group designation Prototype
42.5
900 (Au,Ni) 0 to 100 cF4 Fm 3 m A1 Cu
(Au,Ni) 810.3
70.6
700
Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 193-
208 (1987)
500
300
100
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Nickel Ni
0
10 20 30 40 50 60 70 80 100
Au-P
1800
1600
1400
Au-P
Struktur-
1200
1064.43 (Au) 0 cF4 Fm 3 m A1 Cu
1000
935°C (aP) 100 c** … … …
13.5
800
(1984)
600 G
(Au)
400
277°C B.P.
200 L2
(aP)
44.14°C
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Phosphorus P
Weight Percent Lead

0 10 20 30 40 50 60 70 80 90 100
Au-Pb
1100
1064.43°C
900
Au-Pb
L Struktur-
700 0.11 Composition, Pearson Space bericht
(Au) 0 to 0.11 cF4 Fm 3 m A1 Cu
500 Au2Pb 33.3 cF24 Fd 3 m C15 Cu 2Mg
434°C AuPb 2 66.7 tI12 I4/mcm C16 Al2 Cu
43
AuPb 3 75 tI32 I 4 2m … aV3S
300
327.502°C (Pb) 99.8 to 100 cF4 Fm 3 m A1 Cu
253°C 73.5
82.1 212.5°C
221.5°C
99.8
84.1 H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 5(3), 276-284
(Au)
100
(1984)
52°C See also
(Pb)
-100
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Lead Pb

--`,`,``,`,```,,``,``
82
Au Weight Percent Palladium
Au-Pd
0 10 20 30 40 50 60 70 80 90 100
1600
1555°C
1400
L
Au-Pd
1200
Struktur-
1064.43°C
1000 (Au,Pd) Phase at.% Pd symbol group designation Prototype
870°C (Au,Pd) 0 to 100 cF4 Fm 3 m A1 Cu
850°C
Au3Pd 12 to 32 cP4 Pm 3 m L12 AuCu3
800
AuPd3 AuPd ~50 … … … …
Au3Pd AuPd3 68 to 90 cP4 Pm 3 m L12 AuCu3
600
400 (1985)
200
100°C
AuPd
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Palladium Pd
0 10 20
30 40 50 60 70 80 90 100
Au-Pm
1600
1459°C
1400
Au-Pm
1196°C 1189°C
L Struktur-
1200
36.9
1064.43°C
1069 Phase at.% Pm symbol group designation Prototype
27.6 (bPm) 1042°C
1000 (Au) 0 cF4 Fm 3 m A1 Cu
907°C
12.9
890° C Au6 Pm 14.3 … … … …
831°C 849°C 92.6
72.1 Au51 Pm14 21.5 … … … …
800 8.6
Au2 Pm 33.3 … … … …
671°C AuPm 50 … … … …
82.3
600 AuPm2 66.7 … … … …
(bPm) 100 cI2 Im 3 m A2 W
(aPm) 100 hP4 P63/mmc A3’ aLa
400
(aPm) H. Okamoto and T.B. Massalski, Phase Diagrams of Binary Gold Alloys, H.
(Au)
200 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 227-
126°C
228 (1987)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Promethium Pm
0 10 20
30 40 50 60 70 80 90 100
Au-Pr
1500
1420°C gAuPr
Au-Pr
1320°C Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1300
41.3
1250°C
1210°C
L Phase at.% Pr symbol group designation Prototype
1180°C
1100°C Au6Pr 14.3 mC28 C2/c … Au6Pr
1100
1064.43 1050
1090°C Au51Pr14 21.5 hP65 P6/m … Ag51Gd14
1000°C Au36Pr17 32.1 tP106 I4/nmm … Au36Nd17
(bPr) 931°C Au2Pr 33.3 oI12 Imma … CeCu2
900 13 900°C
Au4Pr3 42.9 … … … …
1.6 7.6
795°C gAuPr 50 cP2 Pm 3 m B2 CsCl
750°C 760°C
790°C
70.1 90 98.5 bAuPr 50 oC8 Cmcm Bf CrB
700
aAuPr 50 oP8 Pnma B27 FeB
(Au) 610°C AuPr2 66.7 oP12 Pnma C23 Co2Si
84.3
(aPr) (bPr) 98.5 to 100 cI2 Im 3 m A2 W
500
440°C
(aPr) 99.5 to 100 hP4 P63 /mmc A3’ aLa
aAuPr H. Okamoto, J. Phase Equilibria Diffusion, 18(5), 489 (2007)

300
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Praseodymium Pr
Au Weight Percent Platinum
Au-Pt
0 10 20 30 40 50 60 70 80 90 100
1800
1769.0°C
1600 L
1400 Au-Pt
Struktur-
1260°C
1200 Phase at.% Pt symbol group designation Prototype
(Au,Pt) 0 to 100 cF4 Fm 3 m A1 Cu
1064.43 (Au,Pt)
1000
(1985)
800
(Au) + (Pt)
600
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Platinum Pt
0 10 20 30
40 50 60 70 80 90 100
Au-Pu
1250°C
1200
Au-Pu
L Struktur-
1064.43°C 1103°C 1100°C Composition, Pearson Space bericht
1064
1000 1075°C
860°C Au5Pu 16.7 … … … …
820°C
800 780°C Au4Pu 20 … … … …
Au3Pu 25 hP* … … …
652°C c 30 … … … …
640°C
Au2Pu 33.3 … … … …
600 (ePu)
q 42 … … … …
(d'Pu)
483°C AuPu 50 … … … …
463°C
c (dPu) h 65 … … … …
400 q
320°C
(ePu) 99 to 100 cI2 Im 3 m A2 W
(gPu) (d’Pu) 100 tI2 I4/mmm A6 In
(Au) 215°C
200 170°C (dPu) 100 cF4 Fm 3 m A1 Cu
125°C (gPu) 100 oF8 Fddd … gPu
h (bPu)
(aPu) (bPu) 100 mC34 C2/m … bPu
0
0 10 20 30 40 50 60 70 80 90 100
(aPu) 100 mP16 P21/m … aPu
Au Atomic Percent Plutonium Pu
H. Okamoto, T.B. Massalski, and D.E. Peterson, Bull. Alloy Phase Diagrams,
7(6), 525-528 (1986)
0 10
20 30 40 50 60 70 80 90 100
Au-Rb
1100
1064.43°C
1000
Au-Rb
900
Struktur-
800
L Phase at.% Rb symbol group designation Prototype
730°C
700 (Au) 0 cF4 Fm 3 m A1 Cu
Au5Rb 16.7 hP6 P6/mmm D2 d CaCu 5
600 580°C Au2Rb 33.3 … … … …
AuRb 50 cP2 Pm 3 m B2 CsCl
500 498°C
(Rb) 100 cI2 Im 3 m A2 W
400 (Au)
300
200
(Rb)
100
34°C 34.98°C
98.6
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Rubidium Rb

--`,`,``,`,```,,``,``,`,```,
84
Au Weight Percent Rhodium
Au-Rh
0 10 20 30 40 50 60 70 80 90 100
3200
2800
Au-Rh
L
2509°C Struktur-
2400
Phase at.% Rh symbol group designation Prototype
L1 + L2
2000
1885°C 1963°C (Rh) 98.1 to 100 cF4 Fm 3 m A1 Cu
17.8 90 98.1
1600 (1984)
1200
1068°C
1064.43°C
1.6 99.7
800
(Au) (Rh)
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Rhodium Rh
0 10
20 30 40 50 60 70 80 90 100
Au-Ru
2400
2334°C
L L1 + L2
2012°C
2000 27 73 Au-Ru
Struktur-
Phase at.% Ru symbol group designation Prototype
1600
1066°C (1984)
1064.43°C 2
800
(Au)
(Ru)
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Ruthenium Ru
0
10 20 30 40 50 60 70 80 100
Au-S
1800
1600
1400 L1 + G
Au-S
Struktur-
L1
1064.43 1048°C Phase at.% S symbol group designation Prototype
1000 (Au) 0 cF4 Fm 3 m A1 Cu
(bS) 100 … … … …
800
(Au) (Au) + G G
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600 (1984)
444.6 B.P.
400
(Au) + L2 L2
200
115.22°C
(bS)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Sulfur S
Au Weight Percent Antimony
Au-Sb
0 10 20 30 40 50 60 70 80 90 100
1200
1064.43°C
1000
Au-Sb
Struktur-
800
AuSb2 66.7 cP12 Pa 3 C2 FeS 2 (pyrite)
630.755°C
600

460°C
400
(Sb)
(Au)
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Antimony Sb
0
10 20 30 40 50 60 70 80 90 100
Au-Sc
1800
1700°C
1615°C
1600 L Au-Sc
? 1510°C Composition, Pearson Space bericht
1400 Phase at.% Sc symbol group designation Prototype
(bSc) Fm 3 m
1305°C 1337°C (Au) 0 to 8.8 cF4 A1 Cu
1275°C Au4Sc 20 tI10 I4/m D1a MoNi4
1225
1200
Au3Sc 25 oP8 Pmmn D0a bTiCu3
(aSc)
1135°C Au2Sc 33.3 tI6 I4/mmm C11 b MoSi2
1115°C
AuSc 50 cP2 Pm 3 m B2 CsCl
1064.43 1040°C
AuSc 2 66.7 oP12 Pnma … PbCl2
1000
(Au) Au2Sc7 77.8 oI142 Immm … …
(bSc) ? to 100 cI2 Im 3 m A2 W
(aSc) ? to 100 hP2 P6 3/mmc A3 Mg
800
600
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Scandium Sc
Weight Percent Selenium Au-Se

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1200
L1
1064.43°C
L1 + L2 L3
1000
963°C L2 Au-Se
15 33
Struktur-
800 760°C Phase at.% Se symbol group designation Prototype
52 99 Fm 3 m
(Au) 0 cF4 A1 Cu
aAuSe 50 mC24 C2/m … …
600
(Se) 100 hP3 P3 121 A8 gSe
425°C H. Okamoto and T.B. Massalski, Phase Diagrams of Binary Gold Alloys, H.
400 99.5 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 263-
266 (1987)
218°C
221°C
200 (Au) 99.9
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Selenium Se
86
Au Weight Percent Silicon
Au-Si
0 10 20 30 40 50 60 70 80 100
1500
1414°C
1300
Au-Si
L Struktur-
1100
900 (Au) 0 cF4 Fm 3 m A1 Cu
(1983)
500
363°C
18.6
300
(Au) (Si)
100
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Silicon Si
0 10 20
30 40 50 60 70 80 90 100
Au-Sm
1525°C Au-Sm
1500 1480 Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

1300
Au6Sm 14.3 tP56 P42 /ncm … Au6 Ho
1210°C
1180°C
Au51 Sm14 21.5 hP65 P6/m … Ag51Gd14
1170°C
1135 bAu3Sm 25 … … … …
1105°C
1100 1085 aAu3 Sm 25 oP8 Pmmn D0a bTiCu3
1064.43 28 36.5
1080 (gSm) 1074°C
1035°C
Au2Sm 33.3 tP108 P4/nmm … Au2 Nd
Au10 Sm7 41.2 tI136 I41 /acd … …
922°C Au7Sm6 46.2 hR13 R 3m … …
900 878°C
865°C
99.7 bAuSm 50 cP2 Pm 3 m B2 CsCl
770°C
800°C
(bSm) aAuSm 50 oC8 Cmcm Bf CrB
0.3 11.5
734°C
AuSm2 66.7 oP12 Pnma C23 Co2Si
705°C
700 81 (gSm) 99.7 to 100 cI2 Im 3 m A2 W
(bSm) 100 hP2 P63 /mmc A3 Mg
(aSm)
(Au) (aSm) 100 hR3 R 3m … aSm
500
0 10 20 30 40 50 60 70 80 90 100 K.A. Gschneidner, Jr., F.W. Calderwood, H. Okamoto, and T.B. Massalski,
Au Atomic Percent Samarium Sm Phase Diagrams of Binary Gold Alloys, H. Okamoto and T.B. Massalski, ed.,
0 10 20
Weight Percent Tin
30 40 50 60 70 80 90 100
Au-Sn
1200
1064.43°C
1000 Au-Sn
Struktur-
b 6 to 9 hP16 P63 /mmc D0 24 Ni3 Ti
600
7.3 9
20.6 532°C z 8 to 16 hP2 P63 /mmc A3 Mg
11.1 21 522°C
(Au) z’ 16.7 hR6 R3 … …
419°C
400 d 50 to 50.5 hP4 P63 /mmc B81 NiAs
b
311°C 72.3 e 66.7 oP24 Pbca … …
z 278°C
252°C 88.7
16 29
190°C
215°C 231.9681°C h 80 oC20 Aba2 D1 c PdSn4
200 13.9
h
95.4 (bSn) 99.8 to 100 tI4 I41/amd A5 bSn
(bSn)
z' 50°C (aSn) 99.994 to 100 cF8 Fd 3 m A4 C (diamond)
27
0 d e 13°C
-5°C -67°C H. Okamoto, J. Phase Equilibria Diffusion, 28(5), 490 (2007)
(aSn)
-200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Tin Sn
Au Weight Percent Strontium
Au-Sr
0 10 20 30 40 50 60 70 80 90 100
1200
1100 1085°C Au-Sr

1064.43°C 1040°C Struktur-
1000
970°C
L Phase at.% Sr symbol group designation Prototype
900 890°C Au5Sr 15.7 to 16.7 hP6 P6/mmm D2d CaCu5
7 875°C
22.5 850°C Au2Sr 33.3 oI12 Imma … CeCu2
44
800
a 50 to 54 … … … …
770°C
769°C b 59 to 60 … … … …
a b 750°C
725°C 63.5 g 58 to 71.5 … … … …

700
AuSr3 75 … … … …
(Au) 640°C (bSr) AuSr9 90 … … … …
600 590°C (bSr) 100 cI2 Im 3 m A2 W
g (aSr) 100 hP2 P63/mmc A3 Mg
547°C
520°C
500 81.5
(aSr) C.B. Alcock, V.P. Itkin, H. Okamoto, and T.B. Massalski, Bull. Alloy Phase
Diagrams, 7(5), 452-454 (1986)
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Strontium Sr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30
40 50 60 70 80 90 100
Au-Ta
3200
3020°C
2800 Au-Ta
Struktur-
2400
2000 ? ? 33 … … … …
Au2Ta3 60 oI* I4/mmm … Au2Nb3
(Ta)
? ? s 65 to 78 tP30 P42/mnm D8b sCrFe
?
1600 s AuTa5 82 to 84 cP8 Pm 3 n A15 Cr3Si
(Ta) 81 to 100 cI2 Im 3 m A2 W
?
1064.43°C ? (1985)
800
(Au) ?
?
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Tantalum Ta
0 10 20
30 40 50 60 70 80 90 100
Au-Tb
1800
Au-Tb
1590°C Struktur-
1600 bAuTb Composition, Pearson Space bericht
L
1450°C
1400 (Au) 0 cF4 Fm 3 m A1 Cu
41 1340°C
(bTb)
1356°C Au6Tb 14.3 tP56 P42/ncm … Au6Ho
1265°C 1289°C Au51Tb14 21.5 hP65 P6/m … Ag51Gd14
1215°C
1200 1175°C 1210°C 91.5
1210°C Au3Tb 25 oP8 Pmmn D0a bTiCu3
1195°C
1160°C Au2Tb 33.3 tI6 I4/mmm C11b MoSi2
1064.43 Au10Tb7 41.2 tI136 I41/acd … Au10 Gd7
1000°C
1000
71
Au4Tb3 42.9 hR42 R3 … Pu 3Pd4
880°C bAuTb 50 cP2 Pm 3 m B2 CsCl
12 855°C
805°C
80 aAuTb 50 oC8 Cmcm Bf CrB
800 11 AuTb2 66.7 oP12 Pnma C23 Co2Si
(bTb) ? to 100 cI2 Im 3 m A2 W
(aTb) (aTb) ? to 100 hP2 P63 /mmc A3 Mg
600
(Au)
400
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Terbium Tb
88
Au Weight Percent Tellurium
Au-Te
0 10 20 30 40 50 60 70 80 90 100
1064.43°C
1000
Au-Te
Struktur-
L
800 Phase at.% Te symbol group designation Prototype
AuTe2 66.7 mC6 C2/m C34 AuTe2 (calaverite)
(Te) 100 hP3 P31 21 A8 gSe
600
(1984)
464°C
447°C 449.57°C
53 416°C
400 88
(Au)
(Te)
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Tellurium Te
0 10 20 30
40 50 60 70 80 90 100
Au-Th
1800
1755°C
(bTh)
1600 Au-Th
L
1440°C Struktur-
1405°C 1420°C
1400
1360°C
1325 1330°C
28.5 38
86.1 Phase at.% Th symbol group designation Prototype
1280°C
1200 1180°C (Au) 0 cF4 Fm 3 m A1 Cu
1110 Au51Th1 4 21.5 hP65 P6/m … Ag51Gd 14
1064.43 1050°C
1000 76 Au2Th 33.3 hP3 P6/mmm C32 AlB 2
Au4Th3 42.9 hR42 R3 … Pu3Pd4
AuTh 50 oC8 Cmcm Bf CrB
800 <0.04 10 Au2Th3 60 c** … … …
AuTh2 66.7 tI12 I4/mcm C16 Al2Cu
600 (bTh) 100 cI2 Im 3 m A2 W
(aTh) (aTh) 100 cF4 Fm 3 m A1 Cu
400 (Au)
H. Okamoto, T.B. Massalski, and D.E Peterson, Phase Diagrams of Binary
200 Gold Alloys, H. Okamoto and T.B. Massalski, ed., ASM International, Metals
Park, OH, 303-305 (1987)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Thorium Th
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10
20 30 40 50 60 70 80 100
Au-Ti
1800
1700
L 1670°C Au-Ti
1600 Struktur-
1500
1455°C Phase at.% Ti symbol group designation Prototype
1395°C Fm 3 m
1400 1385 1367 (Au) 0 to 12 cF4 A1 Cu
40 48 (bTi)
1310°C 85 Au4Ti 18 to 21 tI10 I4/m D1a MoNi4
1300 62 67
gAuTi Au2Ti 33.3 tI6 I4/mmm C11b MoSi2
1200 1172°C gAuTi 48 to 62 cP2 Pm 3 m B2 CsCl
11 1123
12 18
bAuTi 49 to 51 oP4 Pmma B19 AuCd
1100
1064.43 aAuTi 49 tP4 P4/nmm B11 gCuTi
1000 (Au)
AuTi3 75 cP8 Pm 3 n A15 Cr3Si
900 (bTi) 85 to 100 cI2 Im 3 m A2 W
882°C
(aTi) 98 to 100 hP2 P63/mmc A3 Mg
800 95.8
700 J.L. Murray, Bull. Alloy Phase Diagrams, 4(3), 278-283 (1983)
(aTi)
?
600 ?
?
bAuTi
aAuTi
500
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Titanium Ti
Au Weight Percent Thallium
Au-Tl
0 10 20 30 40 50 60 70 80 90 100
1200
1064.43°C
1000 Au-Tl
Struktur-
800 Phase at.% Tl symbol group designation Prototype
L
600 (aTl) 100 hP2 P6 3/mmc A3 Mg

400 Okamoto and T.B. Massalski, ed., ASM International, Metals Park, OH, 311-
316 (1987)
(bTl) 304°C
217° C 230°C
200
147°C
75.3
(Au) (aTl)
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Thallium Tl

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Au-Tm
1800
1720°C
bAuTm
1600 Au-Tm
L 1545°C
Struktur-
1400 40
1300°C
1345°C Phase at.% Tm symbol group designation Prototype
1320°C
27 38 (Au) 0 to 6.5 cF4 Fm 3 m A1 Cu
1270°C
1200 1160°C Au4Tm 20 tI10 I4/m D1a MoNi4
69
Au3Tm 25 oP8 Pmmn D0a bTiCu3
1064.43 1035°C 1035°C
1000 17 76 Au2Tm 33.3 tI6 I4/mmm C11b MoSi2
>99
Au10Tm7 41.1 tI136 I41 /acd … Au10Gd7
6.5
840°C bAuTm 50 cP2 Pm 3 m B2 CsCl
11
800 aAuTm 50 oC8 Cmcm Bf CrB
AuTm2 66.7 oP12 Pnma C23 Co2Si
(Tm)
600 (Tm) >99 to 100 hP2 P63 /mmc A3 Mg

400
(Au)
200
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Thulium Tm
0 10 20 30
40 50 60 70 80 90 100
Au-U
1600
1400 1390°C
1340°C L1 L1 + L2 L2
Au-U
1275°C
1185°C
Struktur-
1200
1135°C
1064.43°C
1000 (Au) 0 cF4 Fm 3 m A1 Cu
(gU)
Au51 U14 21.5 hP65 P6/m … Ag51 Gd14
840°C
Au2 U 33.3 hP3 P6/mmm … CeCd2
800 776°C
745°C (gU) ? to 100 cI2 Im 3 m A2 W
(bU)
660°C
668°C (bU) 100 tP30 P42/mnm Ab bU
600 (aU) 100 oC4 Cmcm A20 aU
(Au) (aU) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
449-451 (1990)
200
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Uranium U
90
Au Weight Percent Vanadium
Au-V
0 10 20 30 40 50 60 70 80 90 100
2000
1910°C
1800
L Au-V
1600
Struktur-
1385°C (V) Composition, Pearson Space bericht
1400 55
61 67 Phase at.% V symbol group designation Prototype
1244°C 1280°C
58 69 76 78
1200
Au4V 15 to 26 tI10 I4/m D1a MoNi4
1064.43 Au2V 32 to 35 oC12 … … …
1000
(Au) AuV3 76 to 81 cP8 Pm 3 n A15 Cr3Si
800
(V) 67 to 100 cI2 Im 3 m A2 W
735°C
600 565°C
460°C 29
400
200 Au4V
0
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Vanadium V
0 10 20 30
40 50 60 70 80 90 100
Au-W
3600
3422°C
L
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
3200
Au-W
2800
Struktur-
2400
(W) 100 cI2 Im 3 m A2 W
2000
(1985)
1600
1200
1064.43°C 1063°C
(Au) (W)
800
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Tungsten W
0 10 20
30 40 50 60 70 80 90 100
Au-Yb
1400
Au-Yb
1200
1150°C
1131
28 (Au) 0 to 6.9 cF4 Fm 3 m A1 Cu
1100 L
1064.43°C 1061°C Au4Yb 20 tI10 I4/m D1a MoNi4
41.5
1000 989°C Au3Yb 25 oP8 Pmmn D0a bTiCu3
926°C Au2Yb 33.3 tI6 I4/mmm C11b MoSi2
900 bAuYb 46 to 50 cP2 Pm 3 m B2 CsCl
861°C (gYb)
817°C 819°C aAuYb 50 oP8 Pnma B27 FeB
800 (Au) 6.9 11 795°C Au4Yb5 55.6 oP36 Pnma … Sm5Ge4
712°C Au3Yb5 62.5 tI32 I4/mcm D8l Cr5B3
700
661°C AuYb2 66.7 oP12 Pnma C23 Co2Si
Au3Yb7 70 hP20 P6 3/mc D102 Fe3Th7
600
548°C (gYb) 100 cI2 Im 3 m A2 W
81.5
500 470°C
(bYb)
400 K.A. Gschneidner, Jr., F.W. Calderwood, H. Okamoto, and T.B. Massalski,
300 ASM International, Metals Park, OH, 328-331 (1987)
0 10 20 30 40 50 60 70 80 90 100
Au Atomic Percent Ytterbium Yb
Au
0 10
Weight Percent Zinc
20 30 40 50 60 70 80 90 100
Au-Zn
1100
1064.43°C Au-Zn
1000 Struktur-
900
800
735°C
(Au) 0 to 34.5 cF4 Fm 3 m A1 Cu
700 48.5 681°C a3 10 to 19 oP* Pn2n or Pnmn … …
34.5 684 57.2 673°C a1 22 to 33 t** … … …
600 582 82.1
a2’(a) 23 to 24 tI64 I41/acd … …
(Au) 521
500 b' g 490 91.7 a2 26 oC32 Cmca … …
g3 95.8
408 °C 397°C 38.3 445 419.58°C Au5Zn3 37.5 oP16 Pmc2 1 … …
400 (Zn)
a1 b’ 38.3 to 57.2 cP2 Pm 3 m B2 CsCl
305°C
300 16 299
267°C b1(a) 49 to 51 … … … …
e d ~56 … … … …
200 54.5 182°C 185
g 64 to 74 cI52 I 4 3m D82 Cu5Zn8
100
g2 75 cP32 Pm 3 m … H3U
g2
0 d g3 79 to 83 hP* P6/mmm … …
e'
a3 e’ 84.5 o** … … …
-100
a2 e 86 to 90 hP2 P63 /mmc A3 Mg
-200 (Zn) 94.5 to 100 hP2 P63 /mmc A3 Mg
0 10 20 30 40 50 60 70 80 90 100
(a) Not shown, but reported in [Massalski2].
Au Atomic Percent Zinc Zn
0 10
20 30 40 50 60 70 80 90 100
Au-Zr
2000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1999Oka
2000Su
1855°C Au-Zr
1800
Struktur-
1600 1572°C 30 1587°C 1575°C Phase at.% Zr symbol group designation Prototype
1535°C 1490°C (Au) 0 to 8 cF4 Fm 3 m A1 Cu
1476 47 Au4Zr 20 oP20 Pnma … Au4Zr
1400
Au3Zr 25 oP8 Pmmn D0a bTiCu3
1254°C Au2Zr 33.3 tI6 I4/mmm C11b MoSi2
13 (bZr)
1200
1146°C 70 1143°C
Au10Zr7 41.2 tI34 … … …
1077°C 1097°C
1120°C 1105°C bAuZr 47 to 55 … … … …
1064.43
1000 (Au) aAuZr 48 to 52 … … … …
927
Au2Zr3 60 … … … …
863°C AuZr2 66.7 tI6 I4/mmm C11b MoSi2
800 776°C
AuZr3 75 cP8 Pm 3 n A15 Cr3Si
(bZr) 84 to 100 cI2 Im 3 m A2 W
600 569°C (aZr) (aZr) 98 to 100 hP2 P63 /mmc A3 Mg
For [1999Oka].
400
0 10 20 30 40 50 60 70 80 90 100 H. Okamoto, J. Phase Equilibria, 23(1), 111 (2002)
Au Atomic Percent Zirconium Zr
0 30 50 60 70 80
90 100
B-Ba
4000
3907°C G
L1
3000 2972°C B-Ba
7.2 98.4
Struktur-
Phase at.% Ba symbol group designation Prototype
2075°C
(bB) 0 hR108 R 3m … …
2092°C
1965°C
2000 B 6Ba 14.3 cP7 Pm 3 m D2 1 CaB 6
L2 (Ba) 100 cI2 Im 3 m A2 W
1000
727°C
(bB) 727°C
(Ba)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Barium Ba
92
B Weight Percent Beryllium
B-Be
0 10 20 30 40 50 60 70 80 90 100
2400
B-Be
? Struktur-
2200
2092°C ? Composition, Pearson Space bericht

2000 ? L Phase at.% Be symbol group designation Prototype
(bB) 0 hR108 R 3m … …
(bB)
B12Be 7.7 t** or hP* … … …
1800
?
?
B6Be 14.3 tP196 P432 12 … …
B4Be 20 tP20 P4/mbm D1e B4Th
1600 B2Be? 25 hP117 P6/mmm … …
?
B3Be2 40 t** … … …
1400 ?
(bBe) BBe2 66.7 cF12 Fm 3 m C1 CaF2
1289°C BBe4 80 tP10 P4/nmm … …
1270°C
1200 1235 (bBe) ? to 100 cI2 Im 3 m A2 W
1140°C 1120°C
88.5 (aBe) 100 hP2 P63/mmc A3 Mg
1000 975°C
? H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
(aBe) Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 21-26
800
(1987)
600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Beryllium Be
0 40 60 70 80 90
95 98 100
B-Bi
3000
2500 L1 G
L1 + G B-Bi
Struktur-
(bB) + G
(bB) 0 hR108 R 3m … …
1564°C
1500 L2
1000 (bB) + L2
(bB)
500
271.442°C
(bB) + (Bi) (Bi)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Bismuth Bi
0 10
20 30 40
B-C
2800
2600 L
2450°C
2400 18.5 2375°C B-C
19.2 29
Struktur-
2200
2092°C 2075°C
(bB) 0 hR108 R 3m … …
2000
B4C 9 to 19.2 hR15 R 3m D1g B4C
(C) 100 hP4 P63/mmc A9 C (graphite)
1800

1600
(bB) B 4C B4C + (C)

1400
1200
18.8
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,
1000
0 5 10 15 20 25 30 35 40
B Atomic Percent Carbon
B
0 10 20 30 40 50 60
70 80 90 100
B-Ca
4000
3907°C
G
L1
3162°C
0.95 95.4 B-Ca
3000
Struktur-
(bB) 0 hR108 R 3m … …
2075°C
2092°C B6 Ca 14.3 cP7 Pm 3 m D21 CaB6
2000
1503°C
(aCa) 100 cF4 Fm 3 m A1 Cu
98.4 1494°C
L2
1000
842°C
842°C
(bB) (bCa)
443°C
443°C
(aCa)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Calcium Ca
0 20 40 50 60 70 80
90 100
B-Cd
3000
L1
L1 + L2 B-Cd
L2 Struktur-
2092°C
?
2000
(bB) 0 hR108 R 3m … …
P.K. Liao and K.E. Spear, J. Phase Equilibria, 17(3), 229 (1996)
1000 (bB)
321.108°C
?
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Cadmium Cd
0 20 4050 60 70 80
90 100
B-Ce
2500
2330°C
2165°C
26
2092°C
1990°C
L
2000
1
B-Ce
10.4
Struktur-
Phase at.% Ce symbol group designation Prototype
1500 (bB) 0 hR108 R 3m … …
B6Ce 10. 4 to 14.3 cP7 Pm 3 m D21 CaB6
B4Ce 20 tP20 P4/mbm D1e B4Th
(dCe) 100 cI2 Im 3 m A2 W
1000
798°C (bCe) 100 hP4 P63/mmc A3’ aLa
726°C
(dCe)
500 P.K. Liao, K.E. Spear, and M.E. Schlesinger, J. Phase Equilibria, 18(3), 280-
(bB)
283 (1997)
(gCe)
139°C
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Cerium Ce

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

B Weight Percent Chlorine
B-Cl
91 92 93 94 95 96 97 98 99 100
-100
-103°C
-108.8°C B-Cl
-110
Struktur-
L Phase at.% Cl symbol group designation Prototype
BCl3 75 to ? hP8 P6 3/m … …
(Cl) ? to 100 oC8 Cmca A14 I
-120
L. Hackspill, Helv. Chim. Acta, 16, 1099-1118 (1933)
-130
-136°C
BCl3 + (Cl)
-140
75 80 85 90 95 100
Atomic Percent Chlorine Cl
0 10 20 30 40 50 60 70
80 90 100
B-Co
2200
(2092°C)
2075°C 1988Lia
2000
2002Du
B-Co
1800 Struktur-
1600 1462°C Phase at.% Co symbol group designation Prototype
(1460°C) 1495°C (bB) 0 hR108 R 3m … …
1400 1353°C (1350 °C) 1276°C BCo 50 oP8 Pnma B27 FeB
1271°C (1280°C)
BCo2 66.7 tI12 I4/mcm C16 Al2 Cu
1200 (1250°C) 1158°C 1133°C BCo3 75 oP16 Pnma D011 Fe3C
(1125°C) (1110°C) (aCo) 100 cI2 Im 3 m A2 W
1000
(eCo) 100 hP2 P63 /mmc A3 Mg
845°C
800
(bB) H. Okamoto, J. Phase Equilibria Diffusion, 24(4), 376 (2003)
(aCo)
600
422°C
400
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Cobalt Co
0 10 20 30 40 50 60
70 80 90 100
B-Cr
2300
(2200°C) 1986Lia
2200 2002Cam
2157°C
(2100°C)
2100 2083°C 2087°C B-Cr
(2092°C)
(2070°C) Struktur-
(2050°C) L Composition, Pearson Space bericht
2000
1914°C
1900 1878 (bB) 0 hR108 R 3m … …
(1900°C) (1870)
1839°C (1863°C) B4Cr 20 o** … … …
1800 (1830°C) B2Cr 33.3 hP3 P6/mmm C32 AlB2
B4Cr3 42.9 oI14 Immm D7 b Ta3B4
1700 BCr 50 oC8 Cmcm Bf CrB
(bB) (1630°C) B3Cr5 62.5 tI32 I4/mcm D8 l Cr5B3
1600
1605°C
BCr2 66.7 oF40 Fddd D1 f Mn4B
(Cr) 99 to 100 cI2 Im 3 m A2 W
1506°C
1500
(1500°C)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Cr)
1400
1300
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Chromium Cr
B Weight Percent Copper
B-Cu
0 1020 30 40 50 60 70 80 90 100
2200
2092°C
2000
1800 B-Cu
L Struktur-
1400 (bB) 0 to 4 hR108 R 3m … …
(Cu) 99.71 to 100 cF4 Fm 3 m A1 Cu
1200
1084.87°C D.J. Chakrabarti and D.E. Laughlin, Bull. Alloy Phase Diagrams, 3(1), 45-48
1013°C
1000 3 86.7 99.71 (1982)
800
(bB) (Cu)
600
400
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Copper Cu
0 30 50 60 70 80
90 100
B-Dy
3000
G
B-Dy
2500 B.P.
2200°C L (bB) R 3m
0 hR108 … …
2100 2100°C
2092°C
2025
B66Dy 2 cF1880 Fm 3 c … B66Th
2000 2020
B12Dy 7.7 cF52 Fm 3 m D2f UB12
B6Dy 14 to 15 cP7 Pm 3 m D21 CaB6
(bB) B4Dy 20 tP20 P4/mbm D1e B4Th
1500
B2Dy 33.3 hP3 P6/mmm C32 AlB2
1400°C (bDy) Im 3 m
1412°C
1384°C 100 cI2 A2 W
(bDy) (aDy) 100 hP2 P63/mmc A3 Mg
1000 P.K. Liao and K.E. Spear, Binary Alloy Phase Diagrams, 2nd ed., T.B.
(aDy) Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
See also
M.E. Schlesinger, J. Phase Equilibria, 19(1), 49-55 (1998)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Dysprosium Dy
0 30 50 60 70 80
90 100
B-Er
2500
2360°C
2185°C
2092°C 2070
2083°C 35 L B-Er
(bB) (bB) 0 hR108 R 3m … …
1500°C 1529°C
1500
B65Er 1.4 to 1.8 cF1880 Fm 3 c … B66Th
B12Er 7.7 cF52 Fm 3 m D2 f UB12
B4Er 20 tP20 P4/mbm D1e B4Th
B2Er 33.3 hP3 P6/mmm C32 AlB 2
1000
(Er) (Er) 100 hP2 P6 3/mmc A3 Mg
P.K. Liao, Spear, and M.E. Schlesinger, J. Phase Equilibria, 17(4), 326-329
500
(1996)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Erbium Er

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
96
B Weight Percent Europium
B-Eu
0 30 50 60 70 80 90 100
3000
2660°C
L1 G
2500 2580°C
B-Eu
Struktur-
2092°C
11.6 Phase at.% Eu symbol group designation Prototype
(bB) 0 hR108 R 3m … …
1500 L2 1529°C B.P. B6Eu 11.6 to 14.3 cP7 Pm 3 m D2 1 CaB 6
(Eu) 100 cI2 Im 3 m A2 W
(bB)
820°C 822°C
381 (1997)
500
(Eu)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Europium Eu
0
10 20 30 40 50 60 70 80 90100
B-Fe
2300
1993Lia
2100 2002Van 2092°C
2075°C
Fe-B
1900 L Struktur-
1700 1650°C (dFe) 0 cI2 Im 3 m A2 W
(gFe) 0 to 0.019 cF4 Fm 3 m A1 Cu
1538°C (dFe) 1603°C
1500
63.2 64.0
1500°C (aFe) 0 to 0.0045 cI2 Im 3 m A2 W
97.5
1394°C
8.4 31.8 1395°C Fe2B 33.3 tI2 I4/mcm C16 Al2 Cu
7.2
32.5 1389°C FeB 50 oP8 Pbmn B27 FeB
1300
16.4 (bB) (bB) 97.5 to 100 hR108 R 3m … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1195°C
1173°C 17
(gFe)
912°C
900
(aFe)
700
0 10 20 30 40 50 60 70 80 90 100
Fe Atomic Percent Boron B
0 20 30 40 50 60 70
80 90 100
B-Ga
3000
L1 + G G
2500 L1
L1 + L2 2237°C B-Ga
L2 B.P.
2092°C
2000 Struktur-
(bB) 0 hR108 R 3m … …
1500
(bB) + L2
1000
(bB)
500
(Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Gallium Ga
B Weight Percent Gadolinium B-Gd
0 30 50 60 70 80 90 100
3000
2650°C
2510°C
2500 11 14.3
L B-Gd
2190
2100°C Struktur-
2092°C 2050°C
2000
4 10.4 1950°C
(bB) 0 hR108 R 3m … …
(bGd) B66Gd 1.5 cF1880 Fm 3 c … B66Th
1500
1280°C B6Gd 10. 4 to 14.3 cP7 Pm 3 m D21 CaB6

1313°C
1180°C
1235°C B4Gd 20 tP20 P4/mbm D1e B4Th
88 B5Gd2 28.6 … … … …
1000
B2Gd 33.3 hP3 P6/mmm C32 AlB2
(bGd) 100 cI2 Im 3 m A2 W
(aGd) 100 hP2 P63/mmc A3 Mg
500 (bB) (aGd)
P.K. Liao, K.E. Spear, and M.E. Schlesinger, J. Phase Equilibria, 17(4), 330-
334 (1996)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Gadolinium Gd
0 20 30 40 50 60 70
80 90 100
B-Ge
2400
L1
2200
L1 + L2 L2
2092°C
2000 B-Ge
Struktur-
(bB) 0 to 4 hR108 R 3m … …
1600
1400
(bB)
478 (1984)
1200
1000
938.3°C
800
(Ge)
600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Germanium Ge
0 30 50 60 70 80
90 100
B-Hf
3500
3380°C
3000
B-Hf
L Struktur-
(bB) 0 hR108 R 3m … …
2500 B2Hf 33 to 35 tI12 I4/mcm C16 Al2Cu
BHf 49 to 51 oP8 Pnma B27 FeB
(bHf) 98 to 100 cI2 Im 3 m A2 W
2231°C (aHf)
(bHf) 98 to 100 hP2 P6 3/mmc A3 Mg
2100°C
2092°C 2065°C
76
1880°C
87 98
1800°C
(bB) 1743°C
488-489 (1990)
(aHf)
1500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Hafnium Hf

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
98
B Weight Percent Mercury B-Hg
0 30 50 60 70 80 90 100
3000
2800
2600 L1
2400
L2
L 1 + L2 B-Hg
2200
2092°C Struktur-
1800 Phase at.% Hg symbol group designation Prototype
1600 (bB) 0 hR108 R 3m … …
1400 (Hg) 100 hR1 R 3m A10 aHg
1200
1000
800 (bB) 488, 490-491 (1990)
600
400
200
0 -38.8290°C
(Hg)
-200
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Mercury Hg
0 30 50 60 70 80
90 100
B-Ho
3000
G
2695°C
2500°C
2500 B-Ho
L Struktur-
2180°C 2200°C Composition, Pearson Space bericht
2092°C 2100 Phase at.% Ho symbol group designation Prototype
2000 2025
(bB) 0 hR108 R 3m … …
B66Ho 2 cF1880 Fm 3 c … B 66Th
(bB) B12Ho 7.7 cF52 Fm 3 m D2f UB12
1500 1450°C 1474°C
B6Ho 13.5 to 15 cP7 Pm 3 m D21 CaB 6
B4Ho 20 tP20 P4/mbm D1e B 4Th
B2Ho 33.3 hP3 P6/mmm C32 AlB2
1000
(Ho) 100 hP2 P6 3/mmc A3 Mg
(Ho) P.K. Liao and K.E. Spear, Binary Alloy Phase Diagrams, 2nd ed., T.B.
500 Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
See also
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Holmium Ho
0 20 40 50 60 70 80
90 100
B-In
2500
L1 G
L1 + G
2092°C 2073°C
2000 L2 B-In
L1 + L2 Struktur-
Phase at.% In symbol group designation Prototype
1500
(bB) 0 hR108 R 3m … …
(bB) + L2
1000
(bB) Applications, C.E.T. White and H. Okamoto, ed., ASM International, Materials
Park, OH, 41 (1992)
500
156.634°C
(bB) + (In) (In)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Indium In

--`,`,``,`,```,,``,``,`,```,,-`-
B Weight Percent Lanthanum
3000
0 30 50 60 70 80 90 100 B-La
2715°C
2500 B-La
Struktur-
2092°C 2052°C
2000 Phase at.% La symbol group designation Prototype
2007°C
1800°C (bB) 0 hR108 R 3m … …
33.3 B9La 10 … … … …
B6La 13 to 14.3 cP7 Pm 3 m D21 CaB6
1500 1527°C
B4La 20 tP20 P4/mbm D1e B4Th
(gLa) 100 cI2 Im 3m A2 W
(bB) (bLa) 100 cF4 Fm 3 m A1 Cu
1000
918°C (aLa) 100 hP4 P63/mmc A3’ aLa
865°C
(gLa)
M.E. Schlesinger, P.K. Liao, and K.E. Spear, J. Phase Equilibria, 20(1), 73-78
500 (bLa) (1999)
310°C
(aLa)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Lanthanum La
0 10 20 30 40
50 60 70 80 90 100
B-Li
2400
2200
2092°C M.P. Li-B
2000
Struktur-
1800
1600 (bLi) 0 cI2 Im 3 m A2 W
(aLi) 0 hP2 P63 /mmc A3 Mg
1400
B.P. 1342°C, 0.1 MPa Li5B4 44 to 50 hR10 R3m ... ...
1200 LiB3 75 ... ... ... ...
L Li3B14 82.4 tI160 I 4 2d ... ...
1000 LiB6 85.7 ... ... ... ...
LiB12 ~92 tP216 P4 12 12 ... AlB12
800
(bB) 100 hR108 R 3m ... ...
600 From [Pearson3].
400 H.B. Borgstedt and C. Guminski, J. Phase Equilibria, 24(6), 572-574 (2003)
180.6°C
200
(bLi)
0
0 10 20 30 40 50 60 70 80 90 100
Li Atomic Percent Boron B
0 30 50 60 70 80
90 100
B-Lu
3000
2600°C
B-Lu
2500
L Struktur-
2176°C Phase at.% Lu symbol group designation Prototype
2092°C 2100°C (bB) 0 hR108 R 3m … …
2000
B66 Lu 2 cF1880 Fm 3 c … B66Th
B12 Lu 7.7 cF52 Fm 3 m D2f UB12
1663°C B4Lu 20 tP20 P4/mbm D1e B4Th
1500
1500°C B2Lu 33.3 hP3 P6/mmm C32 AlB2
(Lu) 100 hP2 P63/mmc A3 Mg
(bB)
P.K. Liao and K.E. Spear, Binary Alloy Phase Diagrams, 2nd ed., T.B.
1000 (Lu) Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
See also
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Lutetium Lu

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
100
B
0 10
20 30 40 50 60 70 80 90 100
B-Mg
4000
G
3500
Mg-B
3000 G + L2 L2 Struktur-
2500
(Mg) 0 hP2 P63 /mmc A3 Mg
2191°C MgB2 66.7 hP3 P6/mmm C32 AlB2
2092°C
2000
2142°C MgB4 80 oP20 Pnma … …
2009°C
1707°C
MgB7 87.5 oI64 Imam … …
MgB20 95.2 hR* R 3m … …
1500
(bB) 100 hR108 R 3m … …
1090°C
L1
650°C
500
(Mg)
0
0 10 20 30 40 50 60 70 80 90 100
Mg Atomic Percent Boron B
0 10 20 30 40 50 60 70
80 90 100
B-Mn
2200
2092°C
B-Mn
1890°C
L Phase at.% Mn symbol group designation Prototype
1800°C
1800
4.5 20 1750°C (bB) 0 to 4.5 hR108 R 3m … …
B4Mn 20 mC10 C2/m … …
1600 1630°C 1580°C B2Mn 33.3 hP3 P6/mmm C32 AlB2
1510°C B4Mn3 42.9 oI14 Immm D7b Ta3B4
63 bBMn 50 oP8 Pnma B27 FeB
1400 aBMn 50 oC8 Cmcm Bf CrB
1285°C (dMn) bBMn2 66 tI12 I4/mcm C16 Al2Cu
1211°C 1246°C
1200
1142°C 85.7 aBMn2 68 oF40 Fddd D1f Mn4B
1138°C
1075°C 1095°C 1100°C (dMn) 99 to 100 cI2 Im 3 m A2 W
(bB) 1050°C
(gMn) (gMn) 99 to 100 cF4 Fm 3 m A1 Cu
1000
(bMn) (bMn) 99 to 100 cP20 P41 32 A13 bMn
(aMn) ? to 100 cI58 I 4 3m A12 aMn
800
705°C 727°C
(aMn) H. Okamoto, J. Phase Equilibria, 14(1), 121-122 (1993)
600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Manganese Mn
0 20 40 50 60 70 80
90 100
B-Mo
2800
2600°C 2623°C B-Mo

2600
L Struktur-
2400 2375°C Phase at.% Mo symbol group designation Prototype
30
2280°C (bB) 0 to 2 hR108 R 3m … …
70 B4 Mo 19 to 21 hP20 P63 /mmc … B4W
2200 2180°C 2175°C
2140°C 67 77 99.2 B5 Mo2 30 to 34 hR7 R 3m D8i Mo2 B5
2092°C
21
? B2 Mo 34 to 39 hP3 P6/mmm C32 AlB2
2000
bBMo 48.5 to 50.5 oC8 Cmcm Bf CrB
1920°C ? aBMo 50 to 51.5 tI16 I41/amd Bg MoB
2 6 B2 Mo3 60 … … … …
1807°C
1800
1
1800°C
(Mo) BMo2 65 to 67 tI12 I4/mcm C16 Al2 Cu
39
(Mo) 99.2 to 100 cI2 Im 3 m A2 W
(bB)
1600 K.E. Spear and P.K. Liao, Bull. Alloy Phase Diagrams, 9(4), 457-466 (1988)
1517°C
1400
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Molybdenum Mo

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
B
0 10 20 30
40 50 60 70 80 90 100
B-N
4500
4002°C G
4000
B-N
Struktur-
3500
3000 L (bB) 0 hR108 R 3m ... bB
BN 50 hP4 P63mc B4 ZnS (wurtzite)
2500 2397°C
H. Wen and H.L. Lukas, COST 507, Thermochemical Database for Light Metal
Alloys, I. Ansara, A.T. Dinsdale, and M.H. Rand, ed., European Communities,
2092°C
2000 vol. 2, 123-125 (1998)
1500
(bB)
1000
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Nitrogen N
0 20 40 50 60 70 80
90 100
B-Nb
3030°C 2913°C
3000
2903°C
39
L B-Nb
Struktur-
2500
2180°C
Phase at.% Nb symbol group designation Prototype
51.2 98
84.9 (bB) 0 to 0.5 hR108 R 3m … …
4.6 2012°C
2000
0.5 29.7
2077°C B2Nb 29.7 to 39 hP3 P6/mmm C32 AlB2
B3Nb2 40 oC20 Cmcm … B3 V2
B4Nb3 42.9 oI14 Immm D7b Ta3 B4
B6Nb5 45.5 oC* Cmmm … …
1500
BNb 50 to 51.2 oC8 Cmcm Bf CrB
(bB)
B2Nb3 60 tP10 P4/mbm D5a Si2 U3
(Nb) (Nb) 98 to 100 cI2 Im 3 m A2 W
1000
H. Okamoto, J. Phase Equil. Diffusion, 31(2), 208-209 (2010)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Niobium Nb
0 20 4050 60 70 80
90 100
B-Nd
3000
2610°C
B-Nd
2500
2400°C
27
Struktur-
2150
6 Phase at.% Nd symbol group designation Prototype
2092°C 2050 L
2000
(bB) 0 hR108 R 3m … …
B66Nd 1.5 cF1880 Fm 3 c … B66Th
B6Nd 6 to 14.3 cP7 Pm 3 m D21 CaB6
1500
1350°C B4Nd 20 tP20 P4/mbm D1e B4Th
(bB)
35 B5Nd2 28.6 … … … …
(bNd) 100 cI2 Im 3 m A2 W
1010°C 1021°C
1000 99.2 (aNd) 100 hP4 P63/mmc A3’ aLa
863°C
(bNd)
500 339 (1996)
(aNd)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Neodymium Nd

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
102
B Weight Percent Nickel
B-Ni
0 10 20 30 40 50 60 70 80 90 100
2100
2092°C
B-Ni
1900 Struktur-
L Phase at.% Ni symbol group designation Prototype
1700
(bB) 0 hR108 R 3m … …
BNi 50 oC8 Cmcm Bf CrB
1500
m-B3Ni4 56.4 mC* C2/c … …
1455°C o-B3 Ni4 58.6 oP* Pnma … …
BNi2 66.7 tI12 I4/mcm C16 Al2Cu
1300 BNi3 75 oP16 Pnma D011 Fe3C
(Ni) 100 cF4 Fm 3 m A1 Cu
1156°C
1125°C
1100 1093°C
70
1035°C 1031°C 1018 83 K.E. Spear and P.K. Liao, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed.,
1018°C 54.7 60.5 1111°C ASM International, Materials Park, OH, 31-36 (1991)
900 (Ni)
(bB)
700
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Nickel Ni
0 30 50 70 80 90
Weight Percent Neptunium
100
B-Np
3000
B-Np
2500
L Struktur-
2092°C Phase at.% Np symbol group designation Prototype
2000 (bB) 0 hR108 R 3m … …
B66Np 1.5 cF2064 Fm 3 c … B66Y
B12Np 7.7 cF52 Fm 3m D2f UB12
1500 Pm 3m
B6Np 14.3 cP7 D21 CaB6
B4Np 20 tP20 P4/mbm D1e B4 Th
B2Np 33.3 hP3 P6/mmm C32 AlB2
1000 (gNp) 100 cI2 Im 3 m A2 W
(bNp) 100 tP4 P2412 Ad bNp
(bB)
639°C (aNp) 100 oP8 Pnma Ac aNp
576°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
500 (gNp)
(bNp) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
280°C
(aNp)
0 510-511 (1990)
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Neptunium Np
0 30 5060 70 80
90 100
B-Os
3500
B-Os
3000
3033°C Struktur-
(bB) 0 to ? hR108 R 3m … …
2500 B2Os 31 to 32.5 oP6 Pmmn … B2Ru
bB3Os2 38 to 40 hP* … … …
aB3Os2 40 hP* … … …
2092°C
B11Os10 45.5 to 50 hP* … … …
2000 (Os) 100 hP2 P63 /mmc A3 Mg
1870°C
1780°C 1820°C
1710°C H. Okamoto, J. Phase Equilibria Diffusion, 27(3), 302 (2006)
1500 (bB)
(Os)
1000
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Osmium Os
B Weight Percent Protoactinium
B-Pa
0 30 50 70 80 90 100
2800
2600
B-Pa
L
2400 Struktur-
2200 Phase at.% Pa symbol group designation Prototype
2092°C
(bB) 0 hR108 R 3m … …
2000
B66Pa 1.5 … … … …
1800
B6Pa 14.3 … … … …
B4Pa 20 … … … …
1600 (bB) B2Pa 33.3 … … … …
1572°C
(bPa) 100 cI2 Im 3 m A2 W
1400 (aPa) 100 tI12 I4/mmm Aa aPa
(bPa)
1200 1170°C
(aPa) 515-516 (1990)
800
600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Protoactinium Pa
0 30 50 70 80
Weight Percent Lead
90 100
B-Pb
2500
L1 L1 + L2 L2
2092°C
2000
B-Pb
1750°C Struktur-
B.P. Composition, Pearson Space bericht
1500
(bB) 0 hR108 R 3m … …
(bB)
515 (1990)
500
327.502°C
(Pb)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Lead Pb
0 20 40 50 60 70 80
90 100
B-Pd
2500
B-Pd
2092°C
2000
Struktur-
L Phase at.% Pd symbol group designation Prototype
(bB) 0 hR108 R 3m … …
1500
1555°C BPd 2 66.7 oP6 Pnnm C18 FeS2 (marcasite)
B2Pd5 71.4 mC28 C2/c … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
BPd 3 75 oP16 Pnma D011 Fe3C

1115°C B3Pd16 83.5 to 85 … … … …
1000 964°C 65 1065°C 81.4 (Pd) 81.4 to 100 cF4 Fm 3 m A1 Cu
57.4 890°C
(Pd)
346 (1996)
500
(bB) 397°C 410°C
320°C 93.9
82.3 312°C
B3Pd16
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Palladium Pd
104
B Weight Percent Promethium
B-Pm
0 20 4050 60 70 80 90 100
3000
2600°C
B-Pm
2500
2350°C L Struktur-
2092°C (bB)
2000
2050°C 2000°C 0 hR108 R 3m … …
B66Pm 2 cF1880 Fm 3 c … B66Th
B6Pm 13.5 to 15 cP7 Pm 3 m D21 CaB 6
B4Pm 20 tP20 P4/mbm D1e B4Th
1500 B5Pm2 29 … P21/c … B5Sm2
1000°C 1042°C
1000 P.K. Liao and K.E. Spear, Binary Alloy Phase Diagrams, 2nd ed., T.B.
890°C Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
(bPm)
(bB) International, Materials Park, OH, 517, 519-520 (1990)
(aPm)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Promethium Pm
0 20 4050 60 70 80
90 100
B-Pr
3000
2610°C B-Pr
2500 Struktur-
2350°C
Phase at.% Pr symbol group designation Prototype
(bB) 0 hR108 R 3m … …
2092°C 2025°C
2000
2000°C B6Pr 13.5 to 15 cP7 Pm 3 m D2 1 CaB 6
B4Pr 20 tP20 P4/mbm D1e B 4Th
BxPr 28 … … … …
(bPr) 100 cI2 Im 3 m A2 W
1500 (aPr) 100 hP4 P6 3/mmc A3’ aLa
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM

1000 International, Materials Park, OH, 519, 521-522 (1990)
(b B) 931°C
See also
(bPr)
795°C M.E. Schlesinger, J. Phase Equilibria, 19(1), 49-55 (1998)
(aPr)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Praseodymium Pr
0 30 50 60 70 80
90 100
B-Pt
2200
2092°C
2000
B-Pt
1800 1769.0°C
Struktur-
1600 Phase at.% Pt symbol group designation Prototype
(bB) 0 hR108 R 3m … …
1400
B2Pt3 60 … … … …
BPt2 65 to 66.7 hP6 P63 /mmc C7 MoS2
BPt3 73 to 75 t** … … …
1200
(Pt) 99 to 100 cF4 Fm 3m A1 Cu
1000
920°C 940°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
890°C 825°C
800 522-523 (1990)
790°C
600 (Pt)
(bB)
400
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Platinum Pt
B Weight Percent Plutonium
B-Pu
0 30 5060 70 80 90 100
2500
2430°C B-Pu
Struktur-
2092°C
2000 L Phase at.% Pu symbol group designation Prototype
(bB) 0 hR108 R 3m … …
B66Pu 1 cP2064 Pm 3 n … …
B12Pu 7.7 cF52 Fm 3 m D2f UB12
1500 Pm 3 m
B6Pu 14.3 cP7 D21 CaB 6
B4Pu 20 tP20 P4/mbm D1e B 4Th
B2Pu 33.3 hP3 P6/mmm C32 AlB2
(ePu) 100 cI2 Im 3 m A2 W
1000
(dPu) 100 cF4 Fm 3 m A1 Cu
(bB) (ePu)
(d'Pu) (bPu) 100 mC34 C2/m … bPu
500 483°C
463°C
(dPu) (aPu) 100 mP16 P21/m … aPu
320°C
(gPu)
215°C
(bPu)
(aPu)
125°C P. Rogl and P.E. Potter, Phase Diagrams of Binary Actinide Alloys, M.E.
0
0 10 20 30 40 50 60 70 80 90 100
Kassner and D.E. Peterson, ed., ASM International, Materials Park, OH, 292-
296 (1995)
B Atomic Percent Plutonium Pu
0 30 50 60 70 80
90 100
B-Re
3200 3186°C
3000
B-Re
Struktur-
2800 L Phase at.% Re symbol group designation Prototype
(bB) 0 to 1 hR108 R 3m … …
2600 B2Re 22 to 35 hP6 P6 3/mmc … …
B3Re7 70 to 71 hP20 P6 3/mc D102 Fe3Th7
2400
2400°C BRe 3 74 to 75 oC16 Cmcm E1a Re3B
(Re) 99 to 100 hP2 P6 3/mmc A3 Mg
2200 2150°C
2092°C
8 2000°C
2000 B2Re 525-526 (1990)
(Re)
1830°C
1800 (bB) 58
1600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Rhenium Re
0 20 40 50 60 70 80
90 100
B-Rh
2400
2092°C B-Rh
2000
L 1963°C Struktur-
1600 (bB) 0 hR108 R 3m … …
B1.1 Rh 48 hP4 P63/mmc D81 NiAs
B3Rh7 70 hP20 P6 3/mc D102 Fe3Th7
1260°C
1200 1140°C (Rh) 100 cF4 Fm 3 m A1 Cu
? 1131°C
?
527-528 (1990)
(bB) (Rh)
400
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Rhodium Rh

--`,`,``,`,```,,``,``,`,```,,
106
B Weight Percent Ruthenium
B-Ru
0 20 40 50 60 70 80 90 100
2400
2334°C
2200
2092°C B-Ru
2000
L Struktur-
1800 Phase at.% Ru symbol group designation Prototype
1660°C
(bB) 0 hR108 R 3m … …
1600
1600°C B2Ru 33.3 oP6 Pmmn … …
1550°C
1500°C B3Ru2 40 hP12 P63 /mmc … …
44 1420 BRu 47 to 51 hP2 P 6 m2 Bh WC
1400 56 B3 Ru7
B3Ru7 62 to 70 hP20 P63/mc D102 Fe3 Th7
1480°C
(Ru) 98 to 100 hP2 P63 /mmc A3 Mg
1200
(bB) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(Ru)
527, 529 (1990)
800
600
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Ruthenium Ru
0 10 20 30 40 50
60 70 80 90 100
B-S
600
L
500 B-S
Struktur-
417°C
400
(bB) 0 hR108 R 3m … …
B12S 7.7 hR* … … …
(bB)
B4S 20 … … … …
300 BS 50 … … … …
B2S3 60 mC70 C2/m … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
BS2 66.7 mP48 P2 1/c … …
200 (bS) 100 … … … …
115.22°C
100 (bS) H. Okamoto, J. Phase Equilibria Diffusion, 29(6), 540, (2008)
95.5°C
(aS)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Sulfur S
0 20 40 50 60 70 80
90 100
B-Sb
3000
G
2500 L1 L1 + G
B-Sb
Struktur-
2092°C
(bB) + G
(bB) 0 hR108 R 3m … …
1500 L2
1587°C
B.P. (Sb) 100 hR2 R 3m A7 aAs
(bB) + L2 H. Okamoto, J. Phase Equilibria, 12(3), 391-393 (1991)

1000
630.755°C
500
(bB) (Sb)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Antimony Sb
B Weight Percent Scandium
B-Sc
0 10 20 30 40 50 60 70 80 90 100
2400
2250°C
2200
B-Sc
4
1877°C Phase at.% Sc symbol group designation Prototype
17 (bB) 0 to 2 hR108 R 3m … …
1800
B12Sc 7.7 tI26 I4/mmm D2b Mn12 Th
B2 Sc 33.3 hP3 P6/mmm C32 AlB2
1600 (bSc) 100 cI2 Im 3 m A2 W
(bSc) 1541°C
(aSc) 100 hP2 P63/mmc A3 Mg
1400
1277°C
1337°C K.E. Spear and P.K. Liao, Bull. Alloy Phase Diagrams, 11(4), 321-324 (1990)
83
1200
(bB)
(aSc)
1000
800
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Scandium Sc
90
95 100
B-Se
600
500
480°C L
B-Se
Struktur-
400
B2Se3 60 … … … …
(Se) 100 hP3 P3 121 A8 gSe
300
V.A. Boryakova, Ya.Kh. Grinberg, E.G. Zhukov, V.A. Koryazhkin, and Z.S.
220°C
221°C Medvedeva, Inorg. Mater., 5(3), 397-399 (1969)
200
100 (Se)
0
50 60 70 80 90 100
Atomic Percent Selenium Se
0 10 20 30 40 50
60 70 80 90 100
B-Si
2200
2092°C (bB) 1984Ore

2001Zai
2000
L B-Si
1850°C Struktur-
1800
(bB) 0 to 3 hR108 R 3m … …
1600 BnSi 2 to 6.7 hR12 R 3m … B
B6Si 14.3 oP280 Pnnm … …
B3Si 21.5 to 25.7 hR15 R 3m D1g B4C
1400 1414°C
(Si) 97 to 100 cF8 Fd 3 m A4 C (diamond)
1362°C 86 96.5
For [1984Ore].
1200
(Si)
1000
800
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Silicon Si

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

B Weight Percent Samarium
B-Sm
0 20 4050 60 70 80 90 100
3000
2580°C B-Sm
2500
2400°C Struktur-
27
2150°C
2092°C 9.1 Phase at.% Sm symbol group designation Prototype
2000 (bB) 0 hR108 R 3m … …
B66Sm 1.5 cF1880 Fm 3 c … B66Th
B6Sm 9.1 to 14.3 cP7 Pm 3 m D21 CaB 6
1500 (bB) B4Sm 20 tP20 P4/mbm D1e B4Th
1350°C
35 B5Sm2 28.6 *P* P21/c … …
(gSm) (gSm) 100 cI2 Im 3 m A2 W
1010°C 1074°C
1000 90
(bSm) 100 hP2 P6 3/mmc A3 Mg
922°C
(bSm) (aSm) 100 hR3 R 3m C19 aSm
734°C
(aSm) 350 (1996)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Samarium Sm
0 20 40 50 60 70 80
Weight Percent Tin
90 100
B-Sn
3200
L1 + G G
2700
2603°C
B-Sn
L1 L1 + L2 Struktur-
2092°C Phase at.% Sn symbol group designation Prototype
(bB) 0 hR108 R 3m … …
1700
(bSn) 100 tI4 I4 1/amd A5 bSn
V.P. Itkin, J. Phase Equilibria, 17(2), 129-130 (1996)

1200
(bB) + L2
(bB) L2
700
(bSn)
231.968°C 231.9681°C
200
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Tin Sn
0 20 40 50 60 70
80 90 100
B-Sr
4000
3907°C
G
L1
2955°C
B-Sr
3000
1.2 98.5 Struktur-
Phase at.% Sr symbol group designation Prototype
(bB) 0 hR108 R 3m … …
2075°C
2092°C
2000
B6Sr 14.3 cP7 Pm 3 m D21 CaB6
(aSr) 100 cF4 Fm 3 m A1 Cu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1371°C
H. Okamoto, J. Phase Equilibria Diffusion, 29(3) 288 (2008)
L2
1000
777°C
(bB) 769°C
547°C (bSr)
547°C
(aSr)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Strontium Sr
B Weight Percent Tantalum
B-Ta
0 30 50 60 70 80 90 100
3200
2990°C 3090°C
3037°C
3000 34 3030 3020°C B-Ta
39
Struktur-
2800 Phase at.% Ta symbol group designation Prototype
(bB) 0 to 1 hR108 R 3m … …
B2Ta 26 to 39 hP3 P6/mmm C32 AlB2
2600 B4Ta3 41 to 44 oI14 Immm D7b Ta3 B4
BTa 48 to 51 oC8 Cmcm Bf CrB
B2Ta3 60 to 61 tP10 P4/mbm D5a Si2 U3
2380°C
2400 2360°C BTa2 69 to 72 tI12 I4/mcm C16 Al2 Cu
51 77 98
(Ta) 98 to 100 cI2 Im 3 m A2 W
B2Ta
2200 2180°C
50.5 H. Okamoto, J. Phase Equilibria, 14(3), 393-394 (1993)
2092°C 2070°C
2 2040°C
26
2000 61 70
(bB) (Ta)
1800
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Tantalum Ta

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 30 50 60 70 80
90 100
B-Tb
2800
2600 2600°C
B-Tb
2400
2340 Struktur-
2200 2200 Phase at.% Tb symbol group designation Prototype
2092°C
2100 2100°C (bB) 0 hR108 R 3m … …
2000
2030 2000°C B66Tb 2 cF1880 Fm 3c … B66Th
B12Tb 7.7 cF52 Fm 3 m D2 f UB12
1800 B6Tb 14.5 to 16 cP7 Pm 3 m D21 CaB 6
B4Tb 20 tP20 P4/mbm D1e B4Th
1600
B2Tb 33.3 hP3 P6/mmm C32 AlB 2
1400 (bTb) (aTb) 100 hP2 P6 3/mmc A3 Mg
1356°C
1289°C
1200
1200°C P.K. Liao and K.E. Spear, Bull. Alloy Phase Diagrams, 11(4), 325-328 (1990)
(bB)
(aTb)
1000
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Terbium Tb
0 20 40 50 60 70 80
Weight Percent Technetium
90 100
B-Tc
3000
2500
L B-Tc
Struktur-
2092°C
2000 Phase at.% Tc symbol group designation Prototype
(bB) 0 hR108 R 3m … …
B2Tc 33.3 hP6 P63/mmc … …
B3Tc7 70 hP20 P6 3/mc D102 Fe3Th7
1500
BTc3 75 oC16 Cmcm E1a Re3B
(Tc) 100 hP2 P63/mmc A3 Mg
1000 (bB) (Tc) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
544-545 (1990)
500
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Technetium Tc
110
B Weight Percent Tellurium
B-Te
98.6 98.8 99.0 99.2 99.4 99.6 99.8 100
1100
1000
L
900
B-Te
800
Struktur-
700 (B) + L
(Te) 100 hP3 P3 121 A8 gSe
600
I.N. Odin, V.V. Grnibko, E.V. Safronov, and V.F. Kozlovskij, Zh. Neorg.
Khim., 46(7), 1210-1214 (2001)
500
449.57°C
400
(B) + (Te)
300 (Te)
200
86 88 90 92 94 96 98 100
Atomic Percent Tellurium Te
0 30 5060 70 80 90
100
B-Th
2500 2450°C 2475°C
2400°C
2300
L B-Th
2092°C
1900
Phase at.% Th symbol group designation Prototype
1755°C (bB) 0 hR108 R 3m … …
1700
(bTh) B66Th 1.5 cF1880 Fm 3 c … B66Th
1500 1450°C
B6Th 14.3 cP7 Pm 3 m D21 CaB6
B4Th 20 tP20 P4/mbm D1e B4 Th
1360°C
1300 (bTh) 100 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1100
900 (aTh)
(bB) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
700
544, 546 (1990)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Thorium Th
0 10 20 30 40 50 60
70 80 90 100
B-Ti
3225°C
1987Mur
2004Ma
3000 B-Ti
Struktur-
L Phase at.% Ti symbol group designation Prototype
2500
(bB) 0 hR108 R 3m … …
2204°C B2Ti 33.3 to 34.4 hP3 P6/mmm C32 AlB2
2092°C 2080°C B4Ti3 42.9 oI14 Immm D7 b Ta3B4
2000 2057°C BTi 50 to 51 oP8 Pnma B27 FeB
(bTi) 100 cI2 Im 3 m A2 W
1670°C (aTi) 100 hP2 P6 3/mmc A3 Mg
1540°C
1500 1532°C
For [1987Mur]
(bB) (bTi) H. Okamoto, J. Phase Equilibria Diffusion, 27(3), 303 (2006)
1000
883°C
882°C
(aTi)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Titanium Ti
B Weight Percent Thallium
B-Tl
0 10 20 30 40 50 60 70 80 90 100
3000
L1
B-Tl
2500
G Struktur-
2092°C Phase at.% Tl symbol group designation Prototype
2000
(bB) 0 hR108 R 3m … …
(bB) + G
(aTl) 100 hP2 P63/mmc A3 Mg
1500 1473°C
L2
1000
(bB)
500
(bTl)
303°C
230°C
(aTl)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Thallium Tl
0 30 50 60 70 80
90 100
B-Tm
3000
G
B-Tm
2550°C L+G
2500 L Struktur-
2180°C
2250°C Phase at.% Tm symbol group designation Prototype
(bB) 0 hR108 R 3m … …
2092°C 2100°C
2000 B66Tm 2 cF1880 Fm 3 c … B66Th
1947°C
B12Tm 7.7 cF52 Fm 3 m D2f UB12
B4Tm 20 tP20 P4/mbm D1e B4Th
B2Tm 33.3 hP3 P6/mmm C32 AlB2
1500°C 1545°C
1500 (Tm) 100 hP2 P63/mmc A3 Mg
1000 International, Materials Park, OH, 549-551 (1990)
(Tm)
See also
(bB) M.E. Schlesinger, J. Phase Equilibria, 19(1), 49-55 (1998)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Thulium Tm
0 30 5060 70 80 90
100
B-U
2500
28.6
2382°C
2179°C
9.1
2092°C 1.9 B-U
2000 2044°C L
Struktur-
(bB) 0 hR108 R 3m … …
1500
B12U 7.7 cF52 Fm 3 m D2f UB12
B4U 20 tP20 P4/mbm D1e B4Th
1108°C
B2U 33.3 hP3 P6/mmm C32 AlB2
1135°C
(gU) 100 cI2 Im 3 m A2 W
1000 (g U)
(bU) 100 tP30 P42/mnm Ab bU
776°C
669°C 668°C
(bU)
500 P.Y. Chevalier and E. Fischer, J. Nucl. Mater., 288, 100-129 (2001)
(b B) (aU)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Uranium U

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
112
B Weight Percent Vanadium
B-V
0 10 20 30 40 50 60 70 80 90 100
3100
2900
B-V
2750°C
2700 2653
Struktur-
2640°C 51
2500 2551°C Phase at.% V symbol group designation Prototype
(bB) 0 hR108 R 3m … …
2300 B2V 33.3 hP3 P6/mmm C32 AlB2
B3V2 40 oC* Cmcm … …
2100 2068°C B4V3 42.9 oI14 Immm D7b Ta3B4
2092°C 3 B6V5 45.5 oC* Ammm … …
1925°C
1900 1910°C BV 50 oC8 Cmcm Bf CrB
75
B2V3 60 tP10 P4/mbm D5a Si2 U3
1727°C 1735°C
1700 85
(V) 100 cI2 Im 3 m A2 W
1500 (bB) P.K. Liao, K.E. Spear, and J.F. Smith, Bull. Alloy Phase Diagrams, 8(5), 447-
(V) 454 (1987)
1300
1100
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Vanadium V
0 30 50 60 70 80
90 100
B-W
3600
3422°C B-W
3400
Struktur-
3200
L (bB) 0 hR108 R 3m … …
3000
B4W 17 to 18 hP20 P63/mmc … MoB4
B5W2 29.5 to 32.5 hP14 P63/mmc D8h W2B5
2800 bBW 48 to 54 oC8 Cmcm Bf CrB
2665°C 2670°C aBW 48 to 51 tI16 I41/amd Bg MoB
2600°C
2600 2580°C
68 73 99.8
BW2 66 to 68 tI12 I4/mcm C16 Al2Cu
54 57 66
(W) 99.8 to 100 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
2400 2365°C
2337°C
37 48 S.V. Nagender Naidu and P. Rama Rao, Phase Diagrams of Binary Tungsten
2200 2170°C
Alloys, S.V. Nagender Naidu and P. Rama Rao, ed., Indian Institute of Metals,
2110°C (W) Calcutta, India, 21-28 (1991)
2092°C 51
9 2020°C
2000 1970°C 18 29.5
4 17
(bB)
1800
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Tungsten W
0 20 40 50 60 70
80 90 100
B-Y
3000
2800°C B-Y
Struktur-
2500 Phase at.% Y symbol group designation Prototype
(bB) 0 hR108 R 3m … …
2100 L B66Y 2 cF1880 Fm 3c … B66Th
2200°C
B12Y 7.7 cF52 Fm 3 m D2 f UB12
2100°C
2092°C
2000°C
B6 Y ~14.3 cP7 Pm 3 m D21 CaB6
2000 2050
B4 Y 20 tP20 P4/mbm D1e B4Th
2030
B2 Y 33.3 hP3 P6/mmm C32 AlB2
(bY) 100 cI2 Im 3 m A2 W
(aY) 100 hP2 P63 /mmc A3 Mg
(bY)
1522°C
1500 1479°C P.K. Liao and K.E. Spear, J. Phase Equilibria, 16(6), 521-524 (1995)
1290°C
(bB) (aY)
1000
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Yttrium Y
B Weight Percent Ytterbium
B-Yb
0 30 50 60 70 80 90 100
3000
G
B-Yb
Struktur-
2500
2300°C
2200 (bB)
2092°C 2150 0 hR108 R 3m … …
2000
1850°C B66Yb 2 cF1880 Fm 3 c … B66Th
B12Yb 7.7 cF52 Fm 3 m D2f UB12
B6Yb ~14.3 cP7 Pm 3 m D21 CaB6
1500°C
1500
B4Yb 20 tP20 P4/mbm D1e B4Th
1350°C
B2Yb 33.3 hP3 P6/mmm C32 AlB2
L2
1194°C (gYb) 100 cI2 Im 3 m A2 W
1000 (bYb) 100 cF4 Fm 3 m A1 Cu
800°C 819°C
795°C
760°C P.K. Liao and K.E. Spear, Binary Alloy Phase Diagrams, 2nd ed., T.B.
(gYb) Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
500
(bB) (bYb) See also
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Ytterbium Yb
0 1020 30 40 50 60 70
Weight Percent Zinc
80 90 100
B-Zn
2500
L1 G
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
2092°C
B-Zn
2000
Struktur-
1500 (bB) 0 hR108 R 3m … …
(bB) + G
(Zn) 100 hP2 P63/mmc A3 Mg

1000
907°C
(bB) + L2 L2
500
419.58°C
(bB) (Zn)
0
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Zinc Zn
0 20 40 50 60 70 80
90 100
B-Zr
3500
3244°C
3000
B-Zr
L Struktur-
2500 Phase at.% Zr symbol group designation Prototype
(bB) 0 to 1 hR108 R 3m … …
2092°C 2082°C B12Zr 7.6 cF52 Fm 3 m D2f UB12
2000 2053 B2Zr 32 to 33.3 hP3 P6/mmm C32 AlB2
1855°C BZr 50 cF8 Fm 3 m B1 NaCl
1696°C 1662°C
32 86.3
(bZr) 98.5 to 100 cI2 Im 3 m A2 W
1500 (bZr) (aZr) 100 hP2 P63/mmc A3 Mg
1250°C
(bB)
1000
800°C 863°C
(aZr)
500
0 10 20 30 40 50 60 70 80 90 100
B Atomic Percent Zirconium Zr
114
Ba Weight Percent Beryllium
Ba-Be
0 10 20 30 40 50 70 100
2000
1807°C
Ba-Be
Struktur-
1500
(Ba) 0 cI2 Im 3 m A2 W
BaBe13 92.9 cF112 Fm 3 c D23 NaZn13
1289°C (bBe) 100 cI2 Im 3 m A2 W
1270°C
(aBe) 100 hP2 P6 3/mmc A3 Mg
(bBe)
H. Okamoto, L.E. Tanner, V.P. Itkin, and C.B. Alcock, Phase Diagrams of
1000
Binary Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International,
Metals Park, OH, 26-28 (1987)
727°C
(aBe)
(Ba)
500
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Beryllium Be
40 50 60
70 80 90 100
Ba-Bi
700
600
L Ba-Bi
Struktur-
500
447°C Phase at.% Bi symbol group designation Prototype
Ba3 Bi2 40 … … … …
400
BaBi3 75 tP4 P4/mmm L10 AuCu
300
262°C 271.442°C
98.6 G. Grube and A. Dietrich, Z. Elektrochem., 44, 755-758 (1938)
200
(Bi)
100
0
30 40 50 60 70 80 90 100
Atomic Percent Bismuth Bi

0 10 20 30 40 50 60 70 80 90 100
Ba-Br
1100
960°C
41.2 Ba-Br
900 L2 Struktur-
L1 L1 + L2 Composition, Pearson Space bericht
855°C
800°C
62.7 (Ba) 0 cI2 Im 3 m A2 W
BaBr2 66.7 oP12 Pnma … PbCl 2
727°C
701°C
700
562, 565 (1990)
500 (Ba)
300
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Bromine Br
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ba Weight Percent Calcium
Ba-Ca
0 10 20 30 40 50 60 70 80 90 100
900
842°C
800
Ba-Ca
L
727°C
Struktur-
(Ba,bCa) 0 to 100 cI2 Im 3 m A2 W
605°C
600 54.5 (aCa) 70 to 100 cF4 Fm 3 m A1 Cu
500
C.B. Alcock and V.P. Itkin, Bull. Alloy Phase Diagrams, 7(4), 338-340 (1986)
443°C
(Ba,bCa)
400
300
(aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Calcium Ca
0 10 20
30 40 50 60 70 80 90 100
Ba-Cd
800
727°C
700 Ba-Cd
672°C
L Struktur-
642°C
620°C
610 Phase at.% Cd symbol group designation Prototype
600 588°C 85.7
560°C
554°C
53.8 75 Ba2Cd 33.3 tI6 I4/mmm C11b MoSi2
BaCd 50 cP2 Pm 3 m B2 CsCl
500
BaCd2 66.7 oI12 Imma … …
Ba7Cd31 81.6 hP41 P6/mmm … …
409°C BaCd11 91.7 tI48 I41 /amd … …
400
380°C
26 (Cd) 100 hP2 P63 /mmc A3 Mg
21
321°C
321.108°C
(Ba)
566, 568-569 (1990)
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Cadmium Cd

0 10 20 30 40 50 60 70 80 90 100
Ba-Cl
1300
Ba-Cl
1100
Struktur-
47.4
L1
962°C
bBaCl2
L1 L1 + L2
920°C (Ba) 0 cI2 Im 3 m A2 W
900 890°C
bBaCl2 66.7 cF12 Fm 3 m C1 CaF2
aBaCl2 66.7 oP12 Pnma … PbCl2
727°C 712°C
700
569-570 (1990)
500 (Ba)
300
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Chlorine Cl

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Ba
0 10 20 30
40 50 60 70 80 90 100
Ba-Cs
900
L1
L1 + L2
800 L2
727°C
725°C Ba-Cs
700
Struktur-
600 Phase at.% Cs symbol group designation Prototype
500 (Cs) 100 cI2 Im 3 m A2 W
400 W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
(Ba) (Ba) + L2 Publishing Co., Schenectady, NY
300
200
100
(Cs)
28.6°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Cesium Cs
0 10
20 30 40 50 60 70 80 90 100
Ba-Cu
1200
1084.87°C
Ba-Cu
1000 Struktur-
L Phase at.% Cu symbol group designation Prototype
800 BaCu 50 hP8 P63 /mmc … …
758°C
727°C 70.4 BaCu13 92.9 cF112 Fm 3 c D23 NaZn13
(Cu) 100 cF4 Fm 3m A1 Cu
600
49.4
460°C (Cu)
23.9
400
(Ba)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Copper Cu
0 10 20 30
40 50 60 70 80 90 100
Ba-Eu
900
Ba-Eu
L 822°C Struktur-
800
(Ba,Eu) 0 to 100 cI2 Im 3 m A2 W

727°C
700
(Ba,Eu)
600
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Europium Eu
Ba
0
Weight Percent Fluorine
10 20 30
Ba-F
1500
1400
Ba-F
1300
Struktur-
L
1200 Phase at.% F symbol group designation Prototype
1100 BaF2 ? to 66.7 cF12 Fm 3 m C1 CaF2
900
574, 576 (1990)
800
727°C
700
(Ba)
600
0 10 20 30 40 50 60 70 80
Ba Atomic Percent Fluorine
0 10
Weight Percent Iron
20 30 40 50 60 70 80 90 100
Ba-Fe
2000
L1+ L2 L2
L1
Ba-Fe
1538°C
1538°C Struktur-
1500
(dFe) Composition, Pearson Space bericht
1394°C
1394°C
(gFe) (dFe) 100 cI2 Im 3 m A2 W
1000 (gFe) 100 cF4 Fm 3 m A1 Cu
912°C
912°C (aFe) 100 cI2 Im 3 m A2 W
729°C
727°C H. Okamoto, Phase Diagrams of Binary Iron Alloys, H. Okamoto, ed., ASM
International, Materials Park, OH, 48 (1993)
500
(aFe)
(Ba)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Iron Fe
0 10
20 30 40 50 60 70 80 90 100
Ba-Ga
1200
1016°C
1000 Ba-Ga
Struktur-
L
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
800
727°C
Ba10Ga 9.1 cF176 Fd 3 m … Al10 V
Ba8Ga7 46.7 cP60 P21 3 … Al7Sr8
600 584°C
BaGa2 66.7 hP3 P6/mmm C32 AlB2
BaGa4 80 tI10 I4/mmm D13 Al4Ba
456°C (Ga) 100 oC8 Cmca A11 Ga
414°C
400 24.6
V.P. Itkin and C.B. Alcock, J. Phase Equilibria, 12(5), 575-577 (1991)
200
(Ba) (Ga)
29.5°C 29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Gallium Ga
118
Ba
0 10 20
30 40 50 60 70 80 90 100
Ba-Ge
1200
1105°C
1100
L Ba-Ge
Struktur-
1000°C
940°C 915°C 938.3°C Phase at.% Ge symbol group designation Prototype
895°C 905
900
42.5 56 (Ba) 0 cI2 Im 3 m A2 W
815°C 810°C
Ba2Ge 33.3 oP12 Pnma C23 Co2Si
800 808°C 770°C Ba5Ge3 37.5 tP32 P4/ncc … …
727°C BaGe 50 oC8 Cmcm Bf CrB
700 bBa3 Ge4 57.1 tP28 P42 /nmn … …
640°C
608°C
aBa3 Ge4 57.1 oC56 Cmmm … …
7.5
600 BaGe2 66.7 oP24 Pmna … BaSi2
Ba6Ge25 80.6 cP124 P41 32 … …
500 Ba8Ge43 84.3 cI408 Ia 3 d … …
450°C
(Ba) BaGe5 ~83.3 … … … …
400 ? ~84 … … … …
340°C
? (Ge)
300

200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Germanium Ge
0
0.5 1.0 1.5
Ba-H
1300
1200
1100
L Ba-H
1000
950° C
Struktur-
900 Phase at.% H symbol group designation Prototype
(Ba) 0 to 57 cI2 Im 3 m A2 W
800
bBa2H ? to 66.7 cI* … … …
727°C aBa2H ? to 66.7 oP12 Pnma C23 Co 2Si
700
600
(Ba) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
581-582 (1990)
500
400
300
0 10 20 30 40 50 60 70
Ba Atomic Percent Hydrogen
0 10 20 30 40
50 60 70 80 90 100
Ba-Hg
900
822°C
800
Ba-Hg
Struktur-
726°C
700
660°C Phase at.% Hg symbol group designation Prototype
600 (Ba) 0 cI2 Im 3 m A2 W
Ba2Hg 33.3 tI6 I4/mmm C11b MoSi2
517°C
500 490°C 505°C BaHg 50 cP2 Pm 3 m B2 CsCl
434°C BaHg2 66.7 oI12 Imma … CeCu2
410
400 379°C Ba14Hg51 78.5 hP65 … … …
Ba7Hg31 81.6 hP38 P6/mmm … Ba7Cd31
300 BaHg6 85.7 … … … …
255°C
BaHg11 91.7 cP36 Pm 3 m D2e BaHg11
200 BaHg13 93 … … … …
160°C (Hg) 100 hR1 R 3m A10 aHg
100 (Ba)
C. Guminski, J. Phase Equilibria, 21(2), 173-178 (2000)
0
-38.8290°C
(Hg)
-100
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Mercury Hg
--`,`,``,`,```,,
Ba
0 10 20 30
40 50 60 70 80 90 100
Ba-I
1100
914°C
900 33.3
Ba-I
Struktur-
L1 L2 Composition, Pearson Space bericht
L1 + L2 Phase at.% I symbol group designation Prototype
727°C 712°C
700 684°C BaI2 66.7 oP12 Pnma C23 Co2 Si
3.8 660°C (I) 100 oC8 Cmca A14 I
62.4
500
584-585 (1990)
(Ba)
300
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Iodine I
0 10 20
30 40 50 60 70 80 90 100
Ba-In
1000
965°C
835°C 842°C
800 L Ba-In
Struktur-
727°C
640°C Phase at.% In symbol group designation Prototype
600 ? (Ba) 0 cI2 Im 3 m A2 W
542°C 532°C bBa 2In Ba13 In 7.1 … … … …
505°C Ba3 In 25 … … … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
478°C
bBa 2In 33.3 … … … …
400 aBa 2In 33.3 … … … …
BaIn 50 … … … …
(Ba) BaIn 2 66.7 oI12 Imma … CeCu2
BaIn 4 80 tI10 I4/mmm D13 Al4Ba
200 (In) 100 tI2 I4/mmm A6 In
156°C
156.634°C
(In)
0 Park, OH, 42-43 (1992)
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Indium In
0 10
20 30 40 50 60 70 80 90 100
Ba-K
900
L1 L2
L1 + L2
800
725°C
727°C
700
Ba-K
Struktur-
600
500
(K) 100 cI2 Im 3 m A2 W
400
(Ba) (Ba) + L2 W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
300 Publishing Co., Schenectady, NY
200
100
63.4°C
63.71°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Potassium K
120
Ba
0 10 20 30
40 50 60 70 80 90 100
Ba-La
1200
L1
L2
1000 L1 + L2
(gLa)
918°C Ba-La
865°C
820°C Struktur-
800 0.5 90 99 Composition, Pearson Space bericht
727°C 0.4 710°C Phase at.% La symbol group designation Prototype
0.2
(Ba) 0 to 0.2 cI2 Im 3 m A2 W
600 (gLa) 100 cI2 Im 3 m A2 W
(bLa) 99 to 100 cF4 Fm 3 m A1 Cu
(bLa)
(aLa) 100 hP4 P6 3/mmc A3’ aLa
400
310°C
200 587-588 (1990)
(Ba) (aLa)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Lanthanum La
0
10 20 30 4050 70 100
Ba-Li
800
727°C
700
Ba-Li
Struktur-
600
L Im 3 m
500 (Ba) 0 cI2 A2 W
Ba19Li44 69.8 tI252 I 4 2d … …
400
BaLi4 80 hP30 P63 /mmc … …
(bLi) 100 cI2 Im 3 m A2 W
300 H. Okamoto, J. Phase Equil. Diffusion, 31(5), 489 (2010)
200
180.6°C
156°C 81.6
89.5 143°C
126°C
100
(Ba)
(bLi)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Lithium Li
0
10 20 30 40 50 60 70 80 100
Ba-Mg
800
727°C
707°C
700 Ba-Mg
L Struktur-
650°C
97.5
600
607°C
73 598°C Phase at.% Mg symbol group designation Prototype
589°C (Ba) 0 cI2 Im 3 m A2 W
BaMg2 66.7 hP12 P6 3/mmc C14 MgZn2
Ba6Mg23 79.3 cF116 Fm 3 m D8a Mn 23Th 6
500
Ba2Mg17 89.5 hR19 R 3m … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Mg) 100 hP2 P6 3/mmc A3 Mg

(Mg)
400 A.A. Nayeb-Hashemi and J.B. Clark, Bull. Alloy Phase Diagrams, 7(2), 144-
358°C 149 (1986)
35
300
(Ba)
200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Magnesium Mg
Ba Weight Percent Manganese
Ba-Mn
0 10 20 30 40 50 60 70 80 90 100
1400
L1 + L2 L2
1300 L1
6.5 99.75
1246°C Ba-Mn
1200 (dMn) Struktur-
1143°C
(gMn) Phase at.% Mn symbol group designation Prototype
1100
1079°C (Ba) 0 cI2 Im 3 m A2 W
(dMn) 100 cI2 Im 3 m A2 W
1000
(bMn) 100 cP20 P4132 A13 bMn
900 (bMn) (aMn) 100 cI58 I 4 3m A12 aMn
800 I. Obinata, Y. Takeuchi, K. Kurihara, and M. Watanabe, Nippon Kinzoku

Gakkai-shi, 28, 562-568 (1964)
727°C 710°C
700
1.2 695°C
(Ba) (aMn)
600
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Manganese Mn
0 10 20
30 40 50 60 70 80 90 100
Ba-Mo
5000
4680°C
G
Ba-Mo
4000 Struktur-
G + L2 L2
3000
(Mo) 100 cI2 Im 3 m A2 W
2623°C
G + (Mo)
2000
1898°C 592, 594 (1990)
L1 L1 + (Mo) (Mo)
1000
727°C
(Ba) (Ba) + (Mo)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Molybdenum Mo
0
10 20 30 40 50 60 70 80 100
Ba-Na
800
727°C
700
600 Ba-Na
L Struktur-
500
(Ba) 0 to 5 cI2 Im 3 m A2 W
400 BaNa 50 to 73 t** … … …
BaNa4 80 o** … … …
300 (bNa) 98.8 to 100 cI2 Im 3 m A2 W

200 197°C
5 72
100
(Ba) 95.5 97.8°C
83°C
BaNa
70°C 98.8
BaNa4 (bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Sodium Na

--`,`,``,`,```,,``,``,`,```,,-`-`,
122
Ba Weight Percent Neodymium
0 10 20 30 40 50 60 70 80 90 100
Ba-Nd
1600
1500
L2
1400 L1 Ba-Nd
Struktur-
1200 Im 3 m
(Ba) 0 cI2 A2 W
1100
(aNd) 100 hP4 P6 3/mmc A3’ aLa
1013°C 1021°C
1000
L1 + (bNd)
V.A. Lysenko, Zh. Fiz. Khim., 77(9), 1556-1560 (2003)
(bNd)
900
858°C 863°C
800 L1 + (aNd)
(aNd)
727°C
727°C
700
(Ba) (Ba) + (aNd)
600
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Neodymium Nd
0 10
20 30 40 50 60 70 80 90 100
Ba-Ni
1800
L2
1600 L1 + L2
Ba-Ni
1455°C
1400
L1 Struktur-
1000 (Ni) 100 cF4 Fm 3 m A1 Cu
800 H. Okamoto, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed., ASM
727°C International, Materials Park, OH, 36-37 (1991)
600°C
600
6
400
(Ba) (Ni)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Nickel Ni
0
5 10 15 20
Ba-O
2200
2013°C
2000
Ba-O
1800
Struktur-
1600
L Phase at.% O symbol group designation Prototype
1400
BaO 50 to 53.8 cF8 Fm 3 m B1 NaCl
1200 BaO2 59.5 to 66.7 tI6 I4/mmm C11 a CaC 2
53.8 1077°C 66.7
59.5
800
727°C
600 581°C
9.8
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
400 (Ba)
200
0 10 20 30 40 50 60 70
Ba Atomic Percent Oxygen
Ba Weight Percent Phosphorus
Ba-P
0 10 20 30 40 50 60 70 80 90100
1400
1340°C
1300
1230°C Ba-P
1200 Struktur-
1150°C
L Phase at.% P symbol group designation Prototype
1100
1000 Ba2 P 33.3 … … … …
Ba3 P2 40 cI28 I 4 3d D73 Th3P4
900
Ba4 P3 42.9 oF56 Fdd2 … As4Eu3
880°C Ba1.1 P 47.6 … … … …
Ba4 P5 52 to 58 … … … …
800
BaP1.82 64.5 … … … …
740°C
727°C
BaP2 66.7 … … … …
700 BaP3 75 mC16 C2/m … …
(Ba)
500 598, 601-602 (1990)
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Phosphorus P
0 10 20 30 40
Weight Percent Lead
50 60 70 80 90 100
Ba-Pb
1100
1000 970°C
915°C L
900 Ba-Pb
835°C
Struktur-
bBa3Pb5
727°C
725°C Phase at.% Pb symbol group designation Prototype
700 705°C (Ba) 0 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
654°C
13.5 610°C Ba2Pb 33.3 oP12 Pnma C23 Co2 Si
600
Ba5Pb3 37.5 tI32 I4/mcm D8 l Cr5 B3
500
BaPb 50 oC8 Cmcm Bf CrB
bBa3Pb5 62.5 … … … …
400 aBa3Pb5 62.5 oC32 Cmcm … Pu3 Pd5
327.502°C BaPb3 75 hR12 R 3m … …
(Ba)
300
93 (Pb) 100 cF4 Fm 3 m A1 Cu
200
M. Idbenali, C. Servant, N. Selhaoui, and L. Bouirden, Calphad, 31, 479-489 (2007)
(Pb)
100
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Lead Pb
0 10 20
30 40 50 60 70 80 90 100
Ba-Pd
1800
1600
L 1555°C
Ba-Pd
Struktur-
1400
1360°C
1260°C
1230°C (Ba) 0 cI2 Im 3 m A2 W
75
1200 BaPd 50 oC8 Cmcm Bf CrB
BaPd2 66.7 cF24 Fd 3 m C15 Cu2Mg
BaPd5 83.3 hP6 P6/mmm D2d CaCu5
1000
(Pd) 100 cF4 Fm 3 m A1 Cu
800
727°C
(Pd)
600
(Ba)
400
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Palladium Pd
124
Ba
0 10 20 30
40 50 60 70 80 90 100
Ba-Pm
1500
L1 Ba-Pm
L1 + L2 L2
Struktur-
1038°C
1042°C
1000 Phase at.% Pm symbol group designation Prototype
L1 + (bPm) (bPm) Im 3 m
(Ba) 0 cI2 A2 W
890°C
L1 + (aPm)
727°C
500
605 (1990)
(Ba) (aPm)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Promethium Pm
91 92 93
94 95 96 97 98 99 100
Ba-Pr
1000
L1 + L2 L2
Ba-Pr
950
Struktur-
927°C 931° C
900
L1 + (bPr) (bPr) (aPr) 100 hP4 P6 3/mmc A3’ aLa
850
221-223 (1988)
800
795°C
L1 + (aPr) (aPr)
750
729°C
(Ba) + (aPr)
700
90 91 92 93 94 95 96 97 98 99 100
Atomic Percent Praseodymium Pr
0 10 20 30
40 50 60 70 80 90 100
Ba-Pt
2000
1850°C
L
1820°C
1800
1770°C 1730°C 1769.0°C Ba-Pt
77
95 Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1600
1400 BaPt2 66.7 cF24 Fd 3 m C15 Cu2 Mg
BaPt5 83.3 hP6 P6/mmm D2d CaCu5
1200 (Pt)
1000
800
727°C
(Ba)
600
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Platinum Pt
Ba Weight Percent Rubidium
Ba-Rb
0 10 20 30 40 50 60 70 80 90 100
900
L1
L2
L1 + L2
800
725°C
727°C Ba-Rb
700
Struktur-
600
500 (Rb) 100 cI2 Im 3 m A2 W
(Ba) (Ba) + L2 Publishing Co., Schenectady, NY
300
200
100
(Rb)
38.6°C
39.48°C
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Rubidium Rb
20 25
30 35 40 45
Ba-S
1100
1000 Ba-S
Struktur-
925°C L
900
800 BaS 50 cF8 Fm 3 m B1 NaCl
bBaS2
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
66.7 … … … …
aBaS2 66.7 mC12 C2/c … …
700 BaS3 75 oP16 P421 m D017 BaS3
664°C
600
BaS
500 610-611 (1990)
400
50 55 60 65 70 75 80
Atomic Percent Sulfur
0 10
20 30 40 50 60 70 80 90 100
Ba-Sc
2000
1800 L1 L2
L1 + L2
Ba-Sc
1600
1541°C Struktur-
1460°C 96.7 Composition, Pearson Space bericht
98.3
1400 (bSc) Phase at.% Sc symbol group designation Prototype
1337°C
1.2 (Ba) 0 cI2 Im 3 m A2 W
1200
(bSc) 98.3 to 100 cI2 Im 3 m A2 W
(aSc) 98 to 100 hP2 P6 3/mmc A3 Mg
1000 (aSc)
800 610, 612 (1990)
726°C
727°C
98.8
600
(Ba)
400
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Scandium Sc
126
Ba Weight Percent Selenium
Ba-Se
0 10 20 30 40 50 60 70 80 90 100
2000
1800 1780°C
L
1600
Ba-Se
Struktur-
1200 (Ba) 0 cI2 Im 3 m A2 W
BaSe 50 cF8 Fm 3 m B1 NaCl
1000
930°C
Ba2Se3 60 … … … …
840°C
BaSe 2 66.7 mC12 C2/c Cg C 2Th
800 760°C BaSe 3 75 tP8 P 4 21m … …
717°C
727°C
(Se) 100 hP3 P3121 A8 gSe
600

400
(Ba)
219°C 221°C
200
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Selenium Se
0
10 20 30 40 50 60 70 80 90 100
Ba-Si
1500
1414°C
1400
1300 Ba-Si
L 1180°C
Struktur-
1200
1100
1060°C
1030°C (Ba) 0 cI2 Im 3 m A2 W
1015 83
1000 60 Ba2Si 33.3 oP12 Pnma C23 Co2 Si
935°C
920
Ba5Si3 37.5 tP32 P4/ncc … …
900 880°C 52.5 BaSi 50 oC8 Cmcm Bf CrB
855 825°C Ba3Si4 57.1 tP28 P42 /mnm … …
800 40 BaSi2 66.7 oP24 Pmna … BaSi2
727°C (Si) (Si) 100 cF8 Fd 3 m A4 C (diamond)
700
630°C
600 11
M. Pani and A. Palenzona, J. Alloys Compds., 454, L1-L2 (2008)
500 (Ba)
400
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Silicon Si

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

0 10 20 30 40 50 60 70 80 90 100
Ba-Sm
1300 L1 L2
L1 + L2 Ba-Sm
Struktur-
1100 Phase at.% Sm symbol group designation Prototype
1070°C 1074°C
(gSm)
900
922°C (aSm) 100 hR3 R 3m C19 aSm
(bSm)
223-224 (1988)
727°C 734°C
700
(Ba) (aSm)
500
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Samarium Sm
Ba Weight Percent Tin
Ba-Sn
20 30 40 50 60 70 80 90 100
800
Ba-Sn
700
? L Struktur-
Ba2Sn 33.3 oP12 Pnma C23 Co2Si
Ba5Sn3 * 37.5 tI32 I4/mcm D8l Cr5B3
500
BaSn* 50 oC8 Cmcm Bf CrB
422°C BaSn3 75 … … … …
400 89.9 BaSn5 83.3 … … … …
300
*Not shown
232°C
231.9681°C
(bSn) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
100
616, 618 (1990)
(aSn)
13°C
0
20 30 40 50 60 70 80 90 100
Atomic Percent Tin Sn
0 10 20
30 40 50 60 70 80 90 100
Ba-Sr
800
L 769°C
727°C
700
Ba-Sr
Struktur-
547°C (Ba,bSr) 0 to 100 cI2 Im 3 m A2 W
500 (aSr) 78 to 100 cF4 Fm 3 m A1 Cu
(Ba,bSr) C.B. Alcock and V.P. Itkin, Bull. Alloy Phase Diagrams, 8(6), 534-536 (1987)
400
300
(aSr)
200
100
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Strontium Sr
0 10 20 30
40 50 60 70 80 90 100
Ba-Te
1600
1470°C
1400 L Ba-Te
Struktur-
1000 (Ba) 0 cI2 Im 3 m A2 W
BaTe 50 cF8 Fm 3 m B1 NaCl
860°C
Ba2Te3 60 … … … …
800 790°C
714°C
BaTe2 66.7 … … … …
727°C
(Te) 100 hP3 P3121 A8 gSe
600
440°C 449.57°C
400 99.51 Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
620-621 (1990)
(Ba)
200 (Te)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Tellurium Te

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
128
Ba Weight Percent Titanium
0 10 20 30 40 50 60 70 80 90 100
Ba-Ti
3500
G
3000
Ba-Ti
2500
L2 Struktur-
2000
1670°C (bTi) 100 cI2 Im 3 m A2 W
1500 L1 (aTi) 100 hP2 P6 3/mmc A3 Mg
(bTi)
S. Shang, Z.J. Liu, and Z.K. Liu, J. Alloys Compds, 430, 188-193 (2007)
1000
882°C
727° C
500
(Ba) (aTi)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Titanium Ti
0 10 20 30 40
50 60 70 80 90 100
Ba-Tl
900
805°C
800
L Ba-Tl
727°C 706°C
700 Struktur-
625°C
600
601°C 55.8 602°C Phase at.% Tl symbol group designation Prototype
540°C (Ba) 0 cI2 Im 3 m A2 W
502°C 38 Ba13 Tl 7 … … … …
500
Ba2 Tl 33.3 … … … …
442°C
19.9 415°C BaTl 50 … … … …
400 BaTl2 66.7 hP6 P63/mmc … CaIn 2
bBaTl3 75 … … … …
305°C
300 304°C aBaTl3 75 … … … …
253°C
(Ba) 92.5 230°C
BaTl4 80 … … … …
200
170°C (bTl) (bTl) 97 to 100 cI2 Im 3 m A2 W
(aTl) 98 to 100 hP2 P63/mmc A3 Mg
100 (aTl)
B. Bruzzone, Ann. Chim. (Rome), 56, 1306-1319 (1966)

0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Thallium Tl

0 10 20 30 40 50 60 70 80 90 100
Ba-V
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
3000
2500
G + L2 L2
Ba-V
2000
Struktur-
G + (V) 1910°C Composition, Pearson Space bericht
1805°C Phase at.% V symbol group designation Prototype
1500
(V) 100 cI2 Im 3 m A2 W
L1 + (V)
L1
J.F. Smith, Phase Diagrams of Binary Vanadium Alloys, J.F. Smith, ed., ASM
1000
729°C
727°C
500
(Ba) (Ba) + (V) (V)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Vanadium V
Ba Weight Percent Yttrium
Ba-Y
0 10 20 30 40 50 60 70 80 90 100
1800
1600
(bY)
1522°C
1478°C
1400 L1 L2 Ba-Y
L1 + L2
Struktur-
1200 1153°C
(aY) Phase at.% Y symbol group designation Prototype
16.6 82.5 92.1
1000 (Ba) 0 to 0.24 cI2 Im 3 m A2 W

(bY) 98 to 100 cI2 Im 3 m A2 W
800
(aY) 92.1 to 100 hP2 P63 /mmc A3 Mg
727°C 0.94 709°C
0.24 98.46
600
625, 627-628 (1990)
400
(Ba)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Yttrium Y
0 10 20 30
40 50 60 70 80 90 100
Ba-Yb
900
819°C
800 795°C
Ba-Yb
L
727°C Struktur-
(Ba,gYb) 0 to 100 cI2 Im 3 m A2 W
600
560°C (bYb) <90 to 100 cF4 Fm 3 m A1 Cu
40 (aYb) 100 hP2 P63 /mmc A3 Mg
500
400
(Ba,gYb) (bYb)
300
200
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Ytterbium Yb
Weight Percent Zinc

0 10 20 30 40 50 60 70 80 90 100
Ba-Zn
1000
885°C
800 Ba-Zn
727°C L Struktur-
635°C
600
Ba2 Zn 33.3 tI6 I4/mmm C11 b MoSi2
BaZn 50 cP2 Pm 3 m B2 CsCl
419.5 419.58°C BaZn2 66.7 oI12 Imma … CeCu2
400 380°C
350°C 360°C BaZn5 83.3 oC24 Cmcm … …
349°C
325°C Fm 3 c
25
330°C 46 53.5 (Zn) BaZn13 92.9 cF112 D23 NaZn13
(Zn) 100 hP2 P6 3/mmc A3 Mg
200
(Ba) H. Okamoto, J. Phase Equilibria, 12(4), 469-471 (1991)
0
0 10 20 30 40 50 60 70 80 90 100
Ba Atomic Percent Zinc Zn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
130
Be Weight Percent Bismuth
Be-Bi
0 3050 70 80 90 100
1400 L1 L1 + L2 L2
1289°C
1270°C 98.9
1200 (bBe) Be-Bi
Struktur-
800 (aBe) 0 hP2 P6 3/mmc A3 Mg
(aBe) (Bi) 100 hR2 R 3m A7 aAs
600
H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 28-30
400
(1987)
271.442°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Bismuth Bi

0 10 20 30 40 50 60 70 80 90 100
Be-Ca
2600
2472°C
2400 G
Be-Ca
2200
Struktur-
L1 Phase at.% Ca symbol group designation Prototype
1800 (bBe) 0 cI2 Im 3 m A2 W
(aBe) 0 hP2 P63/mmc A3 Mg
1600 1583°C
0.4 Be13 Ca 7.1 cF112 Fm 3 c D23 NaZn13
1462°C 99.8
1400 (bBe) 87.4 1440°C (bCa) 97.6 to 100 cI2 Im 3 m A2 W
1289°C
L2 (aCa) 100 cF4 Fm 3 m A2 Cu
1270°C
1200
V.P. Itkin, C.B. Alcock, H. Okamoto, and L.E. Tanner, Phase Diagrams of
1000 Binary Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International,
833°C 97.2 842°C Metals Park, OH, 33-37 (1987)
800 97.6
(aBe) (bCa)
600
(aCa)
443°C
400
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Calcium Ca
0 0.1
0.2 0.3
Be-Ce
800
700
Be-Ce
600
Struktur-
(aBe) Composition, Pearson Space bericht
500 Phase at.% Ce symbol group designation Prototype
(aBe) 0 to ? hP2 P63 /mmc A3 Mg
400 Be13 Ce 7.1 cF112 Fm 3 c D23 NaZn13
K.A. Gschneidner, Jr. and F.W. Calderwood, Phase Diagrams of Binary

300 (aBe) + Be 13Ce
Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International, Metals
Park, OH, 38-40 (1987)
200
100
0
0 0.005 0.01 0.015 0.02 0.025
Be Atomic Percent Cerium
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Be Weight Percent Cobalt
Be-Co
0 20 30 40 50 60 70 80 90 100
1600
Be-Co
1500 1495°C
Struktur-
L
1400°C
1400 47 Phase at.% Co symbol group designation Prototype
(bBe)
(bBe) 0 to 6 cI2 Im 3 m A2 W
1310°C (aBe)
1300
1289°C 1260 1262°C
0 to 2.75 hP2 P63 /mmc A3 Mg
1270°C
20 1230°C 88 g 8 to ? cI52 Im 3 m … …
g/ g' 1245°C 53.5
1200 1215°C g’ ? to 20 cF416 Fm 3 m … …
b b1 (aCo) e 12.5 hP19 P6m2 … …
1100 1118 1090°C 1092°C 25.5 hP48 P63 /mcm … …
1032°C z 23 to 30 hP96 P63 /mcm … …
1000 993°C 52.5 77.3 88.8
b 25.5 to 53.5 cP2 Pm 3 m B2 CsCl
b1 71 to 84 cI2 Im 3 m A2 W
900 (aCo) 88 to 100 cF4 Fm 3 m A1 Cu
e z
800 H. Okamoto, L.E. Tanner, and T. Nishizawa, Phase Diagrams of Binary
(aBe) Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International, Metals
700 Park, OH, 45-55 (1987)
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Cobalt Co
0 1020 30 40 50 60 70
80 90 100
Be-Cr
1900
1840°C 1863°C
1800
L
Be-Cr
1700 Struktur-
1600
(bBe) 0 to 0.2 cI2 Im 3 m A2 W
1514°C (aBe) 0 to 0.08 hP2 P6 3/mmc A3 Mg
1500 67 90.8
(Cr) Be12Cr 7.7 tI26 I4/mmm D2 b Mn 12Th
Be2Cr 33.3 hP12 P6 3/mmc C14 MgZn2
1400 (Cr) 90.8 to 100 cI2 Im 3 m A2 W
(b Be)
1338°C
1300
1289°C (1986)
1270°C 1247°C
12
1200 1222°C
(aBe)
1100
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Chromium Cr
0
10 20 30 40 50 60 70 80 100
Be-Cu
1300 (bBe)
1199°C 1289°C
1270°C
1219°C
1200 78
L 78.8 80 82.7 1275°C
Cu-Be
1109 Struktur-
1100 81.5 90.5
86.3
(aBe) Phase at.% Be symbol group designation Prototype
1000
(Cu) 0 to 13.7 cF4 Fm 3 m A1 Cu
45.5 933°C
b 22.5 to 43.3 cI2 Im 3 m A2 W
39.3 900 50 64.3
900
863°C
24.1
858°C
45.8
d g 44.7 to 50 cP2 Pm 3 m B2 CsCl
13.7 22.5 28.3 d 64.3 to 81.5 cF24 Fd 3 m C15 Cu 2Mg
800
b (bBe) 82.7 to 100 cI2 Im 3 m A2 W
(Cu)
g (aBe) 90.5 to 100 hP2 P6 3/mmc A3 Mg
700
618°C
D.J. Chakrabarti, D.E. Laughlin, and L.E. Tanner, Phase Diagrams of Binary
600 10.1 31.4 44.7 Copper Alloys, P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed.,
ASM International, Materials Park, OH, 81-96 (1994)
500
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Beryllium Be

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
132
Be Weight Percent Iron
Be-Fe
0 20 40 50 60 70 80 90 95 100
1600
1538°C
1463°C Be-Fe
28 L Struktur-
1400 16.5 18 1394°C
(bBe) 21 1375°C Composition, Pearson Space bericht
1289°C 4.5 Phase at.% Fe symbol group designation Prototype
1270°C
1215°C (gFe)
(bBe) 0 to 2 cI2 Im 3 m A2 W
1200
0.9 1205°C 1165°C (aBe) 0 to 0.9 hP2 P63/mmc A3 Mg
d 37 64 70
e 9 to 11 hP19 P6m2 … …
1050°C
z (aFe)
1020°C hP48 P63/mcm … …
1000
d 7 to 18 cF24 Fd 3 m C15 Cu2Mg
912°C z 21 to 37 hP12 P63/mmc C14 MgZn2
800
770°C (aFe) 70 to 100 cI2 Im 3 m A2 W
(aBe) 663°C
600 Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 81-96
e (1987)
400
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Iron Fe
0 20 40 50 60 70
80 90 100
Be-Ga
2000
1842°C
1800 31.2
L Be-Ga
1600
(bBe) Struktur-
L1 + L2
1400
1289°C 1260°C
1270°C (bBe) 0 cI2 Im 3 m A2 W
1200 2.3 85
1000

800
(1987)
600
(aBe)
400
200
(Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Gallium Ga
0 20 40 50 60 70
80 90 100
Be-Ge
1500
L1
Be-Ge
(bBe) L1 + L2
1300
1289°C
Struktur-
1270°C
1210°C L2 Composition, Pearson Space bericht
1100 (aBe) 0 hP2 P6 3/mmc A3 Mg
938.3°C
900 875°C
86 Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 98-99
(1987)
700
(aBe) (Ge)
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Germanium Ge
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Be Weight Percent Hydrogen
Be-H
0 0.0005 0.0010 0.0015 0.0020 0.0025
1300
5 MPa
1290
1289°C
L
1280
Be-H
(bBe) L+G Struktur-
1270
1260
(bBe) + G (bBe) 0 to 0.0125 cI2 Im 3 m A2 W
1250 (aBe) 0 to 0.0092 hP2 P63 /mmc A3 Mg
1240 H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
(aBe)
1230 (1987)
(aBe) + G
1220
1210
1200
0 0.005 0.010 0.015 0.020 0.025
Be Atomic Percent Hydrogen
0 30 5060 70 80 90
100
Be-Hf
2400
2231°C
2200
Be-Hf
2000
Struktur-
1800 1760°C
(b Hf) (bBe) 0 cI2 Im 3 m A2 W
1743°C
1620
1600 1590°C Be13 Hf 7.1 cF112 Fm 3 c D23 NaZn13
aBe17Hf2 10.5– hP38 P63/mmc … Ni17 Th2
1390°C bBe17Hf2 10.5+ hR19 R 3m … Be17 Nb2
1400
Be5 Hf 16.7 hP6 P6/mmm D2d CaCu5
1289°C Be2 Hf 33.3 hP3 P6/mmm C32 AlB2
1270°C
1200 (bBe) (bHf) 98 to 100 cI2 Im 3 m A2 W
1125°C
58 (aHf) 99.5 to 100 hP2 P63/mmc A3 Mg
1000
(aBe) (aHf) H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
800
0 10 20 30 40 50 60 70 80 90 100
(1987)
Be Atomic Percent Hafnium Hf
0 30 50 70 80 90
95 100
Be-Hg
1400
L1
1289°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1270°C
1200
(bBe)
Be-Hg
1000
Struktur-
800 G Phase at.% Hg symbol group designation Prototype
(bBe) 0 cI2 Im 3m A2 W
600
(aBe) BeHg 2 66.7 ? ? ? ?
(aHg) 100 hR1 R 3m A10 Hg
400
356.623°C
C. Guminski, Polish J. Chem., 78, 1733-1751 (2004)
200 ? L2
0
-38.8290°C
(Hg)
-200
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Mercury Hg
134
Be
0 20 4050 60 70 80
90 100
Be-In
1400 L1 L1 + L2
1289°C 1285.5°C 99.79

1270°C 99.80
1200
(bBe)
Be-In
Struktur-
800
(aBe) 0 hP2 P63 /mmc A3 Mg
L2
600 (aBe)
400
(1987)
200
156.634°C
(In)
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Indium In
0 10 20
30 40 50 60 70 80 90 100
Be-Li
1800
1600
L2
Be-Li
L1 L1 + L2
1400 Struktur-
1270°C
1200 (bBe)
1000
800
(aBe) (aBe) +L2
600
400
200 180.6°C
(aBe) + (bLi) (bLi)
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Lithium Li
Be-Mg
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

0 10 20 30 40 50 60 70 80 90 100
1400
L (bBe)
1289°C
1270°C
1200
Be-Mg
(aBe) Struktur-
1000
800 L (bBe) 0 cI2 Im 3 m A2 W
650°C Be13Mg 7.1 cF112 Fm 3 c D2 3 NaZn 13
600 (Mg) 100 hP2 P6 3/mmc A3 Mg
A.A. Nayeb-Hashemi and. J.B. Clark, Bull. Alloy Phase Diagrams, 8(1), 57-58
400
(1987)
(Mg)
200
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Magnesium Mg
Be
0 20 40 50 60 70 80
90 100
Be-Mo
2623°C
2500
L
Be-Mo
Struktur-
2027°C
1827°C Phase at.% Mo symbol group designation Prototype
57 (bBe) Im 3 m
1690°C 0 cI2 A2 W
1500
Be22 Mo 4.3 cF184 Fd 3 m … Zn22 Zr
1300
1289°C
1270°C
Be12 Mo 7.7 tI26 I4/mmm D2b Mn12 Th
Be2Mo 33.3 hP12 P63/mmc C14 MgZn2
(bBe)
1000
900°C
BeMo3 75 cP8 Pm 3 n A15 Cr3Si
(Mo) 99 to 100 cI2 Im 3 m A2 W

500
(Mo) Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 119-123
(aBe) (1987)
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Molybdenum Mo
0 10 20 30 40 50
60 70 80 90 100
Be-Na
1400 L1 L1 + L2 L2
1289°C
1270°C
1200 (bBe)
Be-Na
Struktur-
800
(bNa) 100 cI2 Im 3 m A2 W
(aBe) (aBe) + L2
600

400
200
97.6°C 97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Sodium Na
0 20 40 50 60 70 80
90 100
Be-Nb
2500
2469°C
L Be-Nb
2000 Struktur-
1800°C Phase at.% Nb symbol group designation Prototype
1672°C (bBe) 0 cI2 Im 3 m A2 W
1620°C 1590°C (aBe) 0 hP2 P6 3/mmc A3 Mg
1520°C 84
1500 1440°C (Nb) Be12Nb 7.7 tI26 I4/mmm D2 b Mn 12Th
Be17Nb2 10.5 hR19 R 3m … …
1289°C Be3Nb 25 hR12 R 3m … …
1270°C
Be2Nb 33.3 cF24 Fd 3 m C15 Cu 2Mg
(bBe)
Be2Nb3 60 tP10 P4/mbm D5a Si 2U 3
1000
(Nb) 84 to 100 cI2 Im 3 m A2 W
(aBe)
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Niobium Nb
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
136
Be
01020 30 40 50 60 70
80 90 100
Be-Ni
1605°C
1600
L
1455°C
1390°C 1395°C Be-Ni
1400
1236°C
8 16
10 11.5 Struktur-
1289°C (bBe) Composition, Pearson Space bericht
1270°C 2 1240
19
1200 25 29.5
1150°C
g (bBe) Im 3 m
51.6 76.2 85
(Ni)
0 to 10 cI2 A2 W
4.5 12 b
8.5 (aBe) 0 to 4.5 hP2 P63 /mmc A3 Mg
1000
1062°C
g 11.5 to ? cI52 I 4 3m D82 Cu5 Zn8
g' g’ 14 to 20 cF416 F23 … …
850°C
800 b 25 to 51.6 cP2 Pm 3m B2 CsCl
(Ni) 85 to 100 cF4 Fm 3 m A1 Cu
600
(aBe) H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
400 (1987)
200
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Nickel Ni
0 10 20
30 40 50 60
Be-O
2700
2550°C
2500
L Be-O
2300
Struktur-
2105°C
2100 Phase at.% O symbol group designation Prototype
1900
bBeO 50 tP6 P42/mnm C4 TiO 2 (rutile)
aBeO 50 hP4 P63mc B4 ZnS (wurtzite)
1700

1500
(bBe)
1300
1289°C
1270°C
(aBe)
1100
0 10 20 30 40 50
Be Atomic Percent Oxygen
0 20 40 50 60 70 80
90 100
Be-Pd
1600
1555°C
1500
1455°C Be-Pd
Struktur-
1400
1300 (bBe)
1289°C (bBe) 0 cI2 Im 3 m A2 W
1270°C
1200°C
(aBe) 0 to 5 hP2 P63/mmc A3 Mg
1200
1170 Be12 Pd 7.7 tI26 I4/mmm D2b Mn12 Th
(a Be) Be5Pd 16.7 cF24 F 4 3m C15b AuBe5
1100 1090°C (Pd) BePd 50 cP2 Pm 3 m B2 CsCl
1055°C
Be3Pd4 57.1 … … … …
1000 Be2Pd3 60 … … … …
960°C
930°C BePd2 66.7 … … … …
900 BePd3 75 o** … … …
(Pd) 99.3 to 100 cF4 Fm 3 m A1 Cu
800
700
0 10 20 30 40 50 60 70 80 90 100 (1987)
Be Atomic Percent Palladium Pd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Be
0 30 5060 70 80 90
100
Be-Pt
1800
1769.0°C
1700
Be-Pt
Struktur-
1500 (bBe) 0 to ? cI2 Im 3 m A2 W
>1400°C (aBe) 0 to ? hP2 P6 3/mmc A3 Mg
1400 Be12Pt 7.7 tI26 I4/mmm D2b Mn1 2Th
Be5Pt 16.7 cF24 F 4 3m C15 b AuBe5
(bBe) (Pt)
Be21Pt5 19.2 c** … … …
1300
1289°C
1270°C BePt 50 cP2 Pm 3 m B2 CsCl
(aBe) BePt 15 93.8 hP* … … …
1200
>1100°C
>1100°C (Pt) 99 to 100 cF4 Fm 3 m A1 Cu
1100
1000 (1987)
950°C
900
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Platinum Pt
0 40 60 70 80 90
100
Be-Pu
2000 1950°C
1800
L Be-Pu
1600
Struktur-
1400
1289°C
1270°C
1200
1000
(bBe) Be13Pu 7.1 cF112 Fm 3c D2 3 NaZn13
(ePu) 98 to 100 cI2 Im 3 m A2 W
800 (d’Pu) 100 tI2 I4/mmm A6 In
630°C 640°C (dPu) 100 cF4 Fm 3 m A1 Cu
600 (ePu)
(d'Pu) 483°C
400 (dPu)
463°C (bPu) 100 mC34 C2/m … bPu
(aBe) 320°C (aPu) 100 mP16 P21/m … aPu
(gPu)
200 215°C
(bPu)
125°C H. Okamoto, L.E. Tanner, and D.E. Peterson, Phase Diagrams of Binary
(aPu)
0 Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International, Metals
0 10 20 30 40 50 60 70 80 90 100
Park, OH, 165-168 (1987)
Be Atomic Percent Plutonium Pu
0 30 5060 70 80 90
100
Be-Re
3186°C
3000
L
Be-Re
2500
Struktur-
2000
Be22 Re 4.3 cF184 Fd 3 m … Zn22 Zr
? Be16 Re0 .92 5.4 cF24 F 4 3m C15b AuBe5
1500
(bBe) Be6 Re 14.3 … … … …
1289°C Be2 Re 30 to 40 hP12 P63/mmc C14 MgZn2
1270°C
(Re) 90 to 100 hP2 P63/mmc A3 Mg
1000
(aBe) Be2Re (Re) Okamoto and L.E. Tanner, ed., ASM International, Metals Park, OH, 170-175
(1987)
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Rhenium Re
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
138
Be
0 20 40 50 60 70 80
90 100
Be-Ru
2400
2334°C
2200
Be-Ru
Struktur-
1800 (aBe) 0 hP2 P6 3/mmc A3 Mg
1670°C
Be12Ru 7.7 mP* P21 or P21/m … …
1620°C BexRu 13 hP* P 6 m2 … …
1600
Be17Ru3 15 cI160 Im 3 … …
26 35 Be10Ru3 23 to 26 cI* … … …
1420°C
1400 (bBe) Be2Ru 33.3 hP12 P6 3/mmc C14 MgZn2
55 99
Be3Ru2 40 cI80 Ia 3 D53 Mn2O3
1289°C
1270°C 18 (Ru) 99 to 100 hP2 P6 3/mmc A3 Mg
1200
3 (Ru)
(aBe) H. Okamoto and L.E. Tanner, Phase Diagrams of Binary Beryllium Alloys, H.
1000
0 10 20 30 40 50 60 70 80 90 100 (1987)
Be Atomic Percent Ruthenium Ru
0 20 4050 60 70 80
90 100
Be-Sb
1400
L
1289°C
1270°C (bBe)
1200 Be-Sb
(aBe)
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
800 (aBe) 0 hP2 P63/mmc A3 Mg
Be13 Sb 7.1 cF112 Fm 3 c D23 NaZn13
Be3 Sb2 40 … … … …
630.755°C
600 Be2 Sb3 60 c** … … …
BeSb2 66.7 … … … …
425°C (Sb) 100 hR2 R 3m A7 aAs
400
(Sb)
200
(1987)
>RT
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Antimony Sb
0 10 20 30 40 50 60 70
80 90 100
Be-Sc
1900
1800
Be-Sc
1700 Struktur-
1600 L Phase at.% Sc symbol group designation Prototype
1541°C (bBe) 0 cI2 Im 3 m A2 W
1500
(aBe) 0 hP2 P63 /mmc A3 Mg
(bSc)
1400 Be13 Sc 7.2 cF112 Fm 3 c D23 NaZn13
(bBe) 1337°C Be17 Sc2 10.5 hP38 P63 /mmc ... Ni17Th2
1300
1289°C hR19 R 3m ... Th2Zn17
1270°C
1200 Be5Sc 16.7 hP6 P6/mmm D2d CaCu5
1100 (aSc) 100 hP2 P63 /mmc A3 Mg
1000 (aSc)
(aBe) H. Okamoto, J. Phase Equilibria Diffusion, 29(5), 465 (2008)
900
800
700
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Scandium Sc
Be Weight Percent Silicon
0 10 20 30 40 50 60 70 80 90 100
Be-Si
1500
1414°C
1400
Be-Si
Struktur-
(bBe)
L
1300
1289°C
1200
1100 1085°C
Z. Pan, Y. Du, and B. Huang, Z. Metallkd., 96(11), 1301-1307 (2005)
Z. Pan, Y. Du, B. Huang, H. Xu, Y. Liu, H. Chan, and W. Xiong, 41, 2525-2528
1000 (2006)
(aBe) (Si)
900
800
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Silicon Si
0 20 4050 60 70 80
Weight Percent Tin
90 100
Be-Sn
1400 L1 L1 + L2 L2
1289°C 1278°C
1270°C
96.5 Be-Sn
1200 (bBe)
Struktur-
800
(bSn) ? to 100 tI4 I4 1/amd A5 bSn
(aBe) (aBe) + L2 (aSn) 100 cF8 Fd 3 m A4 C (diamond)
600
400 (1987)
?
231.9681°C
200
(bSn)
(aSn)
13°C
0
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Tin Sn
0 20 40 50 60 70 80
90 100
Be-Sr
2000
G
L1
1670°C Be-Sr
0.9 99.5 Struktur-
1500 1460°C 99.95 Phase at.% Sr symbol group designation Prototype
73
1289°C (aBe) 0 hP2 P63 /mmc A3 Mg
1270°C
Be13 Sr 7.1 cF112 Fm 3 c D23 NaZn13
(bBe)
L2 (bSr) 100 cI2 Im 3 m A2 W
1000
H. Okamoto, L.E. Tanner, V.P. Itkin, and C.B. Alcock, Phase Diagrams of
Binary Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International,
769°C
Metals Park, OH, 191-192 (1987)
(aBe) (b Sr)
(aSr)
547°C
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Strontium Sr

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
140
Be Weight Percent Tantalum
Be-Ta
0 40 60 70 80 90 100
3020°C
2900
Be-Ta
L
Struktur-
1980°C
1850°C
Be12 Ta 7.7 tI26 I4/mmm D2b Mn12 Th
1900
? Be17 Ta2 10.5 hR19 R 3m … Be17 Nb2
<1800°C
Be3 Ta 25 hR12 R 3m … Be3Nb
(Ta)
>1300°C Be2 Ta 33.3 cF24 Fd 3 m C15 Cu2 Mg
?
1400 Be2 Ta3 60 tP10 P4/mbm D5a Si2U3
1289°C
1270°C BeTa2 66.7 tI12 I4/mcm C16 Al2Cu
(bBe) (Ta) 100 cI2 Im 3 m A2 W
900
(aBe) (1987)
400
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Tantalum Ta
0 40 60 70 80 90
100
Be-Th
1930°C
1900
1755°C Be-Th
1700 L Struktur-
1500 Phase at.% Th symbol group designation Prototype
(bTh) (bBe) Im 3 m
0 cI2 A2 W
1330 78.8
1360°C (aBe) 0 hP2 P63/mmc A3 Mg
1300
1289°C 1230°C Be13 Th 7.1 cF112 Fm 3 c D23 NaZn13
1270°C
65
(bBe) (bTh) 100 cI2 Im 3 m A2 W
1100 (aTh) 100 cF4 Fm 3 m A2 Cu
900
H. Okamoto, L.E. Tanner, and D.E. Peterson, Phase Diagrams of Binary
(aTh) Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International, Metals
(aBe) Park, OH, 198-200 (1987)
700
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Thorium Th
0 10 20 30 40 50 60 70
80 90 100
Be-Ti
1800
Be-Ti
1700 Struktur-
1670°C
1600
1500 (bBe) 0 cI2 Im 3 m A2 W
L (aBe) 0 hP2 P63 /mmc A3 Mg
1400
Be12Ti 7.7 tI26 I4/mmm D2b Mn12Th
1300 Be10Ti 9.1 … … … …
1289°C
1270°C bBe17Ti2 10.5 hR19 R 3m … Be17Nb2
1200 (bBe) aBe17 Ti2 10.5 hP38 P63 /mmc … Ni17Th2
1100
Be13Ti2 13.3 … … … …
Be3Ti 25 hR12 R 3m … Be3Nb
1000 980°C (bTi) Be2Ti 33.3 cF24 Fd 3 m C15 Cu2Mg
Be5Ti4 44.4 … … … …
900
(aBe)
882°C (bTi) 91 to 100 cI2 Im 3 m A2 W
800 (aTi) 100 hP2 P63 /mmc A3 Mg
700 (aTi) T. Tokunaga, H. Ohtani, and M. Hasebe, J. Phase Equilibria Diffusion, 27(1),
600
83-91 (2006)
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Titanium Ti

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Be Weight Percent Uranium
Be-U
0 40 60 70 80 90 100
2000
1800 L
L1 + L2 Be-U
1600 Struktur-
1550°C
1400
1289°C
1270°C (aBe)
1200
0 hP2 P6 3/mmc A3 Mg
(bBe) 1090°C 97 1135°C Be13U 7.1 cF112 Fm 3c D23 NaZn13
1000
98 (gU) 98 to 100 cI2 Im 3 m A2 W
(gU) (bU) 100 tP30 P4 2/mnm Ab bU
800
776°C
(bU)
668°C
600
H. Okamoto, L.E. Tanner, and D.E. Peterson, Phase Diagrams of Binary
(aBe) (aU)
Park, OH, 205-210 (1987)
400
200
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Uranium U
0 10 20 30 40 50 60 70
80 90 100
Be-V
2000
1910°C
L
1800
Be-V
Struktur-
1630°C
(V)
1600 50
1400
Be12 V 7.5 to 8.5 tI26 I4/mmm D2 b Mn12Th
1289°C
1270°C Be17 V2 10.5
1200 Be2V 31.5 to 35.5 hP12 P6 3/mmc C14 MgZn2
(V) 85 to 100 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
800
600
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Vanadium V
0 30 5060 70 80 90
100
Be-W
3500
3422°C
3000
L Be-W
Struktur-
2500
<2250°C (bBe) 0 cI2 Im 3 m A2 W
2100°C
(W) (aBe) 0 hP2 P6 3/mmc A3 Mg
2000 60
Be22W 4.3 cF184 Fd 3 m … Zn22 Zr
<1750°C Be12W 7.7 tI26 I4/mmm D2b Mn1 2Th
Be2W Be2W 28 to 36 hP12 P6 3/mmc C14 MgZn2
1500 (W) 95 to 100 cI2 Im 3 m A2 W
1289°C
1270°C (bBe)
H. Okamoto and L.E. Tanner, Bull. Alloy Phase Diagrams, 7(4), 356-358 (1986)
1000 (aBe)
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Tungsten W
142
Be Weight Percent Yttrium
Be-Y
0 20 40 50 60 70 80 90 100
2000
1920°C
1800 Be-Y
L Struktur-
(bY) (bBe) 0 cI2 Im 3 m A2 W
1522°C
1478°C (aBe) 0 hP2 P63/mmc A3 Mg
1400 Be13 Y 7.1 cF112 Fm 3 c D23 NaZn13
(bY) 100 cI2 Im 3 m A2 W
1289°C
1270°C
(aY) 100 hP2 P63/mmc A3 Mg
1200 (bBe)
K.A. Gschneidner, Jr. and F.W. Calderwood, Phase Diagrams of Binary
1070°C Beryllium Alloys, H. Okamoto and L.E. Tanner, ed., ASM International, Metals
61.4
1000
Park, OH, 216-218 (1987)
(aY)
(aBe)
800
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Yttrium Y
0 10 20 30 40
50 60 70
Be-Yb
1800
1700 L
Be-Yb
1600 Struktur-
1500 (bBe) Im 3 m
0 cI2 A2 W
1400 Be13 Yb 7.1 cF112 Fm 3 c D23 NaZn13
1300
1289°C
1270°C
(gBe) K.A. Gschneidner, Jr. and F.W. Calderwood, Phase Diagrams of Binary
1200
Park, OH, 218-219 (1987)
(bBe)
1100
1000
0 2 4 6 8 10 12 14
Be Atomic Percent Ytterbium
0 2030 40 50 60 70 80
Weight Percent Zinc
90 100
Be-Zn
1600
1400 L1 L2
(bBe)
L1 + L2 Be-Zn
1289°C
1270°C Struktur-
0.08
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
(aBe) 0 to 0.08 hP2 P63/mmc A3 Mg
(Zn) 100 hP2 P63/mmc A3 Mg
800
(aBe)
600
(1987)
400 419.58°C
99.96
(Zn)
200
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Zinc Zn
Be Weight Percent Zirconium
0 20 40 50 60 70 80 90 100
Be-Zr
2000
1900 1987Oka
2006Tok 1855°C
1800°C
1800
Be-Zr
1700 Struktur-
1600
1590°C Phase at.% Zr symbol group designation Prototype
1500
1475°C (bBe) 0 cI2 Im 3 m A2 W
1400 (aBe) 0 hP2 P63 /mmc A3 Mg
1300
1289°C
Be13 Zr 7.1 cF112 Fm 3 c D23 NaZn13
1270°C R 3m
1200 1235°C Be17 Zr2 10.5 hR19 … Be17Nb2
(bBe) (bZr) Be5 Zr 16.7 hP6 P6/mmm D2d CaCu5
1100
Be2 Zr 33.3 hP3 P6/mmm C32 AlB2
1000 965°C (bZr) 96 to 100 cI2 Im 3 m A2 W
65 96
900 (aZr) 100 hP2 P63 /mmc A3 Mg
863°C
800
800°C 98
700
(aZr)
600 (aBe)
500
0 10 20 30 40 50 60 70 80 90 100
Be Atomic Percent Zirconium Zr
0 10
20 30 40 50 60 70 80 90 100
Bi-Br
600
538°C
53
500 L1 Bi-Br
Struktur-
L1 + L2 (Bi) 0 hR2 R 3m A7 aAs
L2 BiBr 50 … … … …
300 294°C bBiBr3 75 … … … …
271.442
6
263°C
56 aBiBr3 75 oP* P213 … …
3.75 (Br) 100 oC8 Cmca A14 I
218.5°C
200
165°C
70.3 bBiBr3 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(Bi) 718-719 (1990)
100
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Bromine Br
Bi-Ca
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

0 10 20 30 40 50 60 70 80 90 100
1600
1400 1350°C
Bi-Ca
Struktur-
1075°C
1000 (Bi) 0 hR2 R 3m A7 aAs
Bi3Ca 25 … … … …
800
820°C 842°C Bi10Ca11 52.4 tI84 I4/mmm … …
98
Bi3Ca5 62.5 oP32 Pnma … …
BiCa2 66.7 tI12 I4/mmm … …
600 (bCa) (bCa) 100 cI2 Im 3 m A2 W
505°C
443°C
400
271.442°C
200 (aCa)
720-721 (1990)
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Calcium Ca
144
Bi Weight Percent Cadmium
Bi-Cd
0 10 20 30 40 50 60 70 80 90 100
400
350
Bi-Cd
271.442°C
250 (Bi) 0 hR2 R 3m A7 aAs
200
Z. Moser, J. Dutkiewicz, L. Zabdyr, and J. Salawa, Bull. Alloy Phase Diagrams,
9(4), 445-448 (1988)
150 146°C
55
100
(Bi) (Cd)
50
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Cadmium Cd
0 10 20
30 40 50 60 70 80 90 100
Bi-Ce
2000
1800 1740°C
Bi-Ce
1630°C
Struktur-
?
1400 (Bi) 0 hR2 R 3m A7 aAs
? Bi2Ce 33.3 aP27 P1 or P 1 … …
1200
BiCe 50 cF8 Fm 3 m B1 NaCl
Bi3Ce4 57.1 cI28 I 4 3d … Th3P4
1000
910°C Bi3Ce5 62.5 hP16 P63/mcm D88 Mn5Si3
21
BiCe2 66.7 tI12 I4/mmm … La2Sb
800 ? ? 798°C
726°C (dCe) ? to 100 cI2 Im 3 m A2 W
(dCe) (gCe) 100 cF4 Fm 3 m A1 Cu
600
400
(gCe)
271.4°C K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams,
271.442°C
200 10(4a), 427-430 (1989)
(Bi) (bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Cerium Ce
0
10 20 30 40 50 60 70 80 100
Bi-Cl
1000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Bi-Cl
L1
600 Bi6Cl7 53.8 oP104 Pnnm … …
560°C Bi7Cl10 58.8 tI1088 I41 /acd … …
68
L1 + L2 BiCl3 75 oP16 Pn21a … …
400
L2 H. Okamoto, J. Phase Equil. Diffusion, 31(1), 82 (2010)
320°C
271°C
271.442°C
234°C
202°C 68
200
190°C
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Chlorine Cl
Bi Weight Percent Cobalt
Bi-Co
0 10 20 30 40 50 60 70 80 90 100
1600
L1
L1 + L2 L2 1495°C
1400
1345°C Bi-Co
2.9 93
Struktur-
Tc
1121°C Phase at.% Co symbol group designation Prototype
1000 (aCo) 100 cF4 Fm 3 m A1 Cu
(eCo) 100 hP2 P63/mmc A3 Mg
800 Li + (aCo) (aCo)
K. Ishida and T. Nishizawa, J. Phase Equilibria, 12(3), 346-348 (1991)
600
422°C
400
L1 + (eCo) (eCo)
271.442°C
(Bi) (Bi) + (e Co)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Cobalt Co

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10
20 30 40 50 60 70 80 90 100
Bi-Cr
2500
2134°C
L1 L2
Bi-Cr
2000
L1 + L2
Struktur-
1863°C
1553°C
1500
(Cr) 100 cI2 Im 3 m A2 W
1000
(1988)
(Cr)
500
271.442°C
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Chromium Cr
0 10 20
30 40 50 60 70 80 90 100
Bi-Cs
700
650°C
600 595°C
L Bi-Cs
Struktur-
500
418 (Bi) 0 hR2 R 3m A7 aAs
400 390°C Bi2Cs 33.3 cF24 Fd 3 m C15 Cu2Mg
Bi4Cs5 55.6 … … … …
Bi2Cs3 60 … … … …
300
267°C BiCs3 75 cF16 Fd 3 m B32 NaTl
271.442
2 cF16 Fm 3 m D03 BiF3
200
(Cs) 100 cI2 Im 3 m A2 W
(Bi) J. Sangster and A.D. Pelton, J. Phase Equilibria, 12(4), 443-446 (1991)
100
28.39°C
(Cs)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Cesium Cs
146
Bi Weight Percent Copper
Bi-Cu
0 10 20 30 40 50 60 70 80 90 100
1200
1084.87°C
Bi-Cu
1000
L Struktur-
800
(Cu) 100 cF4 Fm 3 m A1 Cu
D.J. Chakrabarti and D.E. Laughlin, Bull. Alloy Phase Diagrams, 5(2), 148-155
600 (Cu) (1984)
400
0.5 270.6°C
271.442°C
(Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Copper Cu
0 10 20
30 40 50 60 70 80 90 100
Bi-Dy
1900
1700
1500 L 1447°C (bDy) Bi-Dy

1412°C
1381°C
1300
Struktur-
1147°C Phase at.% Dy symbol group designation Prototype
1100 81
BiDy 50 cF8 Fm 3 m B1 NaCl
900
Bi3Dy5 62.5 oP32 Pnma … …
700 (aDy) 100 hP2 P6 3/mmc A3 Mg
500
(aDy) H. Okamoto, J. Phase Equilibria, 15(4), 450-451 (1994)
300 269°C
271.442°C
(Bi)
100
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Dysprosium Dy
0 10 20
30 40 50 60 70 80 90 100
Bi-Er
2000
1807°C
1800
1600 L
1529°C
1427°C Bi-Er
1400
Struktur-
1200
>99 Phase at.% Er symbol group designation Prototype
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000 (Bi) 0 hR2 R 3m A7 aAs

BiEr 50 cF8 Fm 3 m B1 NaCl
800 Bi3Er5 62.5 oP32 Pnma … Bi3 Y5
(Er) > 99 to 100 hP2 P63 /mmc A3 Mg
600

400 (Er)
269°C
271. 442°C
200
0 (Bi)
-200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Erbium Er
Bi Weight Percent Fluorine
Bi-F
0 5 10 15 20
800
727°C
L
700
600
Bi-F
Struktur-
500
Phase at.% F symbol group designation Prototype
400 (Bi) 0 hR2 R 3m A7 aAs
BiF3 75 oP16 Pnma … YF3
(F) 100 oC8 Cmca A14 I
300
270°C
271.442°C
200
(Bi)
100
0
0 10 20 30 40 50 60 70
Bi Atomic Percent Fluorine
0 10
Weight Percent Iron
20 30 40 50 60 70 80 90 100
Bi-Fe
1800
L1 L1 + L2
L2
1600
1538°C
1538°C Bi-Fe
3.6
(dFe) Struktur-
1400 1394°C
1394°C
1200 L1 + (gFe)
(gFe) (Bi) 0 hR2 R 3m A7 aAs
1000
912°C
(gFe) 100 cF4 Fm 3 m A1 Cu
912°C
0.2 (aFe) 100 cI2 Im 3 m A2 W
800
H. Okamoto, Phase Diagrams of Binary Iron Alloys, H. Okamoto, ed., ASM
600 L1 + (aFe) International, Materials Park, OH, 62-63 (1993)
(aFe)
400
271.442°C
271.442°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Iron Fe

0 10 20 30 40 50 60 70 80 90 100
Bi-Ga
350
300 L
271.442°C
Bi-Ga
250
L1 + L2 Struktur-
222°C
38.5 91.5
200
150
(Bi) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
100 738-739 (1990)
50
29.48°C 99.78
29.7741°C
(Ga)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Gallium Ga

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
148
Bi Weight Percent Gadolinium
Bi-Gd
0 10 20 30 40 50 60 70 80 90 100
2000
1800 1770°C
1580°C
1600 L
1480°C
1400 (b Gd) Bi-Gd
1313°C Struktur-
1235°C
1080°C
1000
910°C (Bi) 0 hR2 R 3m A7 aAs
Bi2Gd 33.3 … … … …
800
BiGd 50 cF8 Fm 3 m B1 NaCl
600 Bi3Gd4 57.1 cI28 I 4 3d … Th3P4
Bi3Gd5 62.5 hP16 P63/mcm D88 Mn5 Si3
400 (aGd) (bGd) ? to 100 cI2 Im 3 m A2 W
271.442°C 269°C
(aGd) ? to 100 hP2 P63/mmc A3 Mg
200
0 (Bi) H. Okamoto, J. Phase Equilibria, 15(6), 650-651 (1994)
-200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Gadolinium Gd
0 10
20 30 40 50 60 70 80 90 100
Bi-Ge
1000
938.3°C
900 L
800 Bi-Ge
Struktur-
600 (Bi) 0 hR2 R 3m A7 aAs
500
400
540 (1986)
300 271.35°C
271.442°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
200
(Bi) (Ge)
100
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Germanium Ge

0 0.5 1.0 1.5 2.0
Bi-Hf
800
700
L Bi-Hf
600
Struktur-
500 (Bi) 0 hR2 R 3m A7 aAs
L + Bi2Hf?
Bi2Hf 33.3 o** … … …
400
300
271.442°C
742-743 (1990)
200
(Bi) (Bi) + Bi2Hf?

100
0
0 0.5 1 1.5 2 2.5
Bi Atomic Percent Hafnium
Bi Weight Percent Mercury
Bi-Hg
0 10 20 30 40 50 60 70 80 90 100
700
600
L+G G Bi-Hg
500 Struktur-
400
356.623°C
300
271.442 L
L. Zabdyr and C. Guminski, J. Phase Equilibria, 17(3), 230-236 (1996)
200
100
(Bi)
0
-39.2°C
-38.8290°C
(Hg)
-100
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Mercury Hg
0 10 20
30 40 50 60 70 80 90 100
Bi-Ho
2000
1800 1775°C
1600 L Bi-Ho
1400
1200 1155°C
1000 BiHo 50 cF8 Fm 3 m B1 NaCl
Bi3Ho5 62.5 oP32 Pnma … Bi3Y5
800 (Ho) ? to 100 hP2 P63/mmc A3 Mg
600 (Ho) H. Okamoto, J. Phase Equilibria, 15(6), 651-652 (1994)

400
271°C
271.442°C
200
0 (Bi)
-200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Holmium Ho

0 10 20 30 40 50 60 70 80 90 100
Bi-I
500
458°C
40 L Bi-I --`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
408°C
Struktur-
350°C
60
330°C
bBiI Bi4.4I 18.5 … … … …
300°C
300 295°C Bi3.3I 23.2 … … … …
295°C
271.442 269°C bBiI 50 … … … …
aBiI 50 … … … …
BiI3 75 hR* R3 … FeCl3
200 (I) 100 oC8 Cmca A14 I
113°C
113.6° C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
100
744, 747-748 (1990)
(Bi)
(I)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Iodine I
150
Bi Weight Percent Indium
Bi-In
0 10 20 30 40 50 60 70 80 90 100
300
271.442°C
250
Bi-In
L Struktur-
156.634°C BiIn 50 tP4 P4/nmm B10 PbO
150
Bi3In 5 62.5 tI32 I4/mcm D8l Cr5 B3
BiIn2 66.8 to 67.7 hP6 P63/mmc B82 Ni2 In
109.7°C 110.0°C e 88 to 92 tI2 … … …
46.8
100
88.9°C 89.5°C 83.2 93.5°C (In) 92.5 to 100 tI2 I4/mmm A6 In
72.7°C (In)
88
e H. Okamoto, Phase Diagrams of Indium Alloys and Their Engineering
88.7°C 78.5
50 (Bi) 49°C 92.5 Applications, C.E.T. White and H. Okamoto, ed., ASM International, Materials
89.5
Park, OH, 46-54 (1992)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Indium In
0 10 20 30
40 50 60 70 80 90 100
Bi-Ir
1500
1420°C 1440°C
L
52.3 1410°C
1300 Bi-Ir
Struktur-
Bi3Ir 25 oP16 Pnma … …
900 Bi2Ir 33.3 m*12 … … …
800°C BiIr 50 … … … …
BiIr2 66.7 … … … …
700
550°C
751-752 (1990)
300
271.442°C
(Bi)
100
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Iridium Ir

0 10 20 30 40 50 60 70 80 100
Bi-K
800
715°C
L Bi-K
600 Struktur-
445°C 442°C Fd 3 m
60.5
Bi2K 33.3 cF24 C15 Cu2Mg
400 53.5
Bi4K5 55.6 … … … …
381°C
355°C Bi2K3 60 … … … …
50
bBiK3 75 cF16 Fm 3 m D03 BiF3
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
271.442°C 265°C
280°C
aBiK3 75 hP8 P63/mmc D018 Na3As
2.5 (K) 100 cI2 Im 3 m A2 W
200
A. Petric and A.D. Pelton, J. Phase Equilibria, 12(1), 29-33 (1991)

(Bi)
63.71°C 63.71°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Potassium K

Provided by IHS under license with AMS International
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Desk Handbook: Phase Diagrams for Binary Alloys
Licensee=AECOM Sites 243 - 246/5906698018, User=Weber, Sam
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151
Bi Weight Percent Lanthanum
Bi-La
0 10 20 30 40 50 60 70 80 90 100
1800
1670°C
1600
Bi-La
1615°C
Struktur-
1400 L 1350°C Phase at.% La symbol group designation Prototype
1252°C (Bi) 0 hR2 R 3m A7 aAs
1200
Bi2 La 33.3 o*12 … … …
aP27 P1 or P 1 … …
1000
932°C
(gLa) BiLa 50 cF8 Fm 3 m B1 NaCl
918°C
820°C 865°C Bi3 La4 57.1 cI28 I 4 3d … Th3P4
800 77.5 750°C Bi3 La5 62.5 hP16 P63/mcm D88 Mn5 Si3
BiLa2 66.7 tI12 I4/mmm … La2Sb
600 (gLa) ? to 100 cI2 Im 3 m A2 W
(bLa)
(bLa) ? to 100 cF4 Fm 3 m A1 Cu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
400 (aLa) 100 hP4 P63/mmc A3’ aLa
310°C
271.442°C
200 K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams,
(Bi) (aLa) 10(4a), 440-443 (1989)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Lanthanum La
0
10 20 30 50 100
Bi-Li
1200
1145°C
1000
Bi-Li
Struktur-
800
bBiLi 50 … … … …
600
aBiLi 50 tP4 P4/mmm L10 AuCu
BiLi3 73.8 to 75.2 cF16 Fm 3 m D03 BiF3
415°C (bLi) 100 cI2 Im 3 m A2 W
400
400°C
bBiLi
271.442°C 243°C
14
200 175°C 180.6°C
99
(Bi)
(bLi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Lithium Li

0 10 20 30 40 50 60 70 80 90 100
Bi-Lu
2000
1820°C
1800
1663°C Bi-Lu
1600
L Struktur-
1400
1200 1165°C
Bi2Lu 33.3 … … … …
1000 BiLu 50 cF8 Fm 3 m B1 NaCl
Bi3Lu5 62.5 … … … …
800
(Lu) ? to 100 hP2 P63 /mmc A3 Mg

(Lu)
400
269°C
271.442°C 0.3
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Lutetium Lu
152
Bi Weight Percent Magnesium
Bi-Mg
0 10 20 30 40 50 60 80 100
900
825°C
800
bBi2Mg3
L Bi-Mg
701°C Struktur-
700
650°C Phase at.% Mg symbol group designation Prototype
600
(Bi) 0 to 0.01 hR2 R 3m A7 aAs
554°C bBi2Mg3 60 to 61.2 … … … …
aBi2Mg3 60 to 64.3 hP5 P 3 m1 D52 La2O3
500 (Mg) 99 to 100 hP2 P63/mmc A3 Mg
M. Paliwal and I.H. Jung, Calphad, 33, 744-754 (2009)

400
(Mg)
300
261°C
271.442°C
(Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Magnesium Mg
0 10
20 30 40 50 60 70 80 90 100
Bi-Mn
1400
L1 + L2 L2
1235°C
1246°C
1200 (dMn)
1138°C
Bi-Mn
1100°C
(gMn) Struktur-
L1
(bMn) (Bi) 0 hR2 R 3m A7 aAs
800 aBiMn 50 hP4 P6 3/mmc B81 NiAs
727°C bBiMn 51.9 o*32 … … …
600
446°C (bMn) 100 cP20 P4132 A13 bMn
400
355°C bBiMn (aMn) 100 cI58 I 4 3m A12 aMn
340°C
271.442°C 262°C
2.2 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
200
(aMn) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
(Bi) 759, 761-762 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Manganese Mn

0 10 20 30 40 50 60 70 80 90 100
Bi-Mo
5000
4680°C
G B.P.
Bi-Mo
4000
Struktur-
G + L2 Phase at.% Mo symbol group designation Prototype
3000
(Mo) 100 cI2 Im 3 m A2 W
2623°C
2000 G + (Mo) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
762-763 (1990)
1564°C
B.P.
1000
L1 L1 + (Mo)
271.442°C
(Bi) (Mo)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Molybdenum Mo

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Bi
0
10 20 30 40 50 60 80 100
Bi-Na
900
845°C
800
Bi-Na
700
Struktur-
L Phase at.% Na symbol group designation Prototype
600
BiNa 50 tP4 P4/mmm L1 0 AuCu
500 BiNa3 73.5 to 77.5 hP8 P6 3/mmc D0 18 Na 3As
444°C
48
400 (aNa) 100 hP2 P6 3/mmc A3 Mg
300 J. Sangster and A.D. Pelton, J. Phase Equilibria, 12(4), 451-456 (1991)
271.442°C
216°C
200 22
(Bi) 97.75°C
100 97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Sodium Na
0 0.001
0.002 0.003 0.004 0.005
Bi-Nb
700
600 Bi-Nb
L
Struktur-
500 Phase at.% Nb symbol group designation Prototype
(Nb) 100 cI2 Im 3 m A2 W
400
L + (Nb)
300
765-766 (1990)
271°C
271.442°C
200
(Bi)
100
0 0.002 0.004 0.006 0.008 0.010 0.012
Bi Atomic Percent Niobium
0 10 20
30 40 50 60 70 80 90 100
Bi-Nd
2000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1800 1775°C
Bi-Nd
L
1260°C (Bi) 0 hR2 R 3m A7 aAs
1200
Bi2Nd 33.3 aP27 P1 or P 1 … …
(bNd)
1021°C BiNd 50 cF8 Fm 3 m B1 NaCl
1000 950°C
Bi3Nd4 57.1 cI28 I 4 3d … Th3P4
835°C 863°C
800
Bi3Nd5 62.5 hP16 P63 /mcm D88 Mn5 Si3
660°C BiNd2 66.7 tI12 I4/mmm … La2Sb
600
(bNd) ? to 100 cI2 Im 3 m A2 W
(aNd) 100 hP4 P63 /mmc A3’ aLa
400 (aNd)
265°C H. Okamoto, J. Phase Equilibria, 23(2), 191 (2002)
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Neodymium Nd
154
Bi
0 10
20 30 40 50 60 70 80 90 100
Bi-Ni
1455°C
1400
Bi-Ni
1200 Struktur-
L
1000 (Bi) 0 hR2 R 3m A7 aAs
Bi3Ni 25 oP16 Pnma … …
BiNi 49 to 50.5 hP4 P63/mmc B81 NiAs
800
(Ni) ? to 100 cF4 Fm 3 m A1 Cu
646°C
600 G.P. Vassilev, X.J. Liu, and K. Ishida, J. Phase Equilibria Diffusion, 26(2),
161-168 (2005)
465°C
400
(Ni)
271.442°C 270°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Nickel Ni
0
10 20 30 40 50 70 100
Bi-O
1800
G
1600 Bi-O
1564°C
Struktur-
1400
1200
bBi2O3 60 cF12 Fm 3 m C1 CaF2
L1 + L2 aBi2O3 60 mP20 P2 1/c … …
1000
825°C
800 788°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
729°C bBi2O3
770 (1990)
600
D. Risold, B. Hallstedt, L.J. Gauckler, H.L. Lukas, and S.G. Fries, J. Phase
Equilibria, 16(3), 223-234 (1995)
400
271°C
271.442°C
200 (Bi)
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Oxygen O
0 10 20 30
40 50 60 70 80 90 100
Bi-Os
G + L2 L2
3000 3033°C
Bi-Os
Struktur-
G
G + (Os) (Bi) 0 hR2 R 3m A7 aAs
2000 (Os) 100 hP2 P6 3/mmc A3 Mg
1000
L1 L1 + (Os)
271.442°C
(Bi) (Os)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Osmium Os
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Bi
0
10 20 30 40 50 60 70 80 100
Bi-P
900
800
Bi-P
L1 + L2 L2 Struktur-
700
600 (P) (red) 100 … … … …
589.6°C
W. Klemm, Angew. Chem., 62(6), 133-142 (1950)

500
400 L1 L1 + (P) (P)
300
271.442°C
(Bi) (Bi) + (P)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Phosphorus P
Weight Percent Lead Bi-Pb

0 10 20 30 40 50 60 70 80 90 100
350
327.502°C
300
271.442°C
L Bi-Pb
250
Struktur-
150
(Pb) e 56.9 to 73.8 hP2 P6 3/mmc A3 Mg
127.6°C
e (Pb) 75 to 100 cF4 Fm 3 m A1 Cu
100

50
(Bi)
-45.15°C
-50 0.01 73.8 87.7
-100
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Lead Pb
0 10
20 30 40 50 60 70 80 90 100
Bi-Pd
1600
1555°C
Bi-Pd
1400 Struktur-
1200 (Pd) Phase at.% Pd symbol group designation Prototype
L R 3m aAs
(Bi) 0 hR2 A7
1000 bBi2Pd 33.3 to 34.8 tI6 I4/mmm C11b MoSi 2
935°C
aBi 2Pd 33.3 to 34.8 mC12 C2/m … …
bBiPd3
800
800°C bBiPd 50 oC32 Cmc2 1 … …
683°C aBiPd 50 mP32 P21 … …
618°C
600
605°C Bi12Pd31 g 62.4 to 67.8 hP16 … … …
bBi2Pd 584°C g 550
485°C <550°C Bi2Pd5 71.4 mC28 C2/m … …
400 380°C >380°C <400°C
Bi12Pd31 72.1 hR44 R3 … …
16.4 bBiPd3 75 … … … …
271.442°C 256°C
5.8 210°C aBiPd3 75 oP16 Pmma … …
200
0 (Bi) H. Okamoto, J. Phase Equilibria, 15(2), 191-194 (1994)
-200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Palladium Pd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
156
Bi Weight Percent Praseodymium
0 10 20 30 40 50 60 70 80 90 100
Bi-Pr
2000
1817°C
1800
1637°C Bi-Pr
1600 Struktur-
1400 1387°C Phase at.% Pr symbol group designation Prototype
1200 1137°C Bi2Pr 33.3 oC24 Cmca … SbSm2
BiPr 50 cF8 Fm 3 m B1 NaCl
1000 (bPr)
931°C Bi3Pr4 57.1 cI28 I 4 3d … Th3P4
807°C 837°C Bi3Pr5 62.5 hP16 P63 /mcm D88 Mn5Si3
800 777°C 88 795°C
BiPr2 66.7 tI12 I4/mmm … La2Sb
(bPr) ? to 100 cI2 Im 3 m A2 W
600
(aPr) 100 hP4 P63 /mmc A3’ aLa
400 (aPr)
267°C
271.442°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Praseodymium Pr
Weight Percent Platinum Bi-Pt

0 10 20 30 40 50 60 70 80 90 100
1800
1769.0°C
1600
Bi-Pt
1400
Struktur-
L
1200
dBi2Pt 33.3 oP6 Pnnm C18 FeS 2 (marcasite)
1000
gBi2Pt 33.3 hP9 P3 … …
Bi3Pt2 bBi 2Pt 33.3 cP12 Pa 3 C2 FeS 2 (pyrite)
800 765°C
730°C aBi 2Pt 33.3 oP24 Pbca … …
685°C 57
640°C
660°C Bi3Pt2 40 o** … … …
570°C
600
dBi2Pt BiPt 50 hP4 P6 3/mmc B81 NiAs
420°C (Pt) 100 cF4 Fm 3 m A1 Cu
400
bBi2Pt (Pt)
>272°C
271.442°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Platinum Pt

Bi-Pu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1400
Bi-Pu
Struktur-
L Phase at.% Pu symbol group designation Prototype
1000 Bi2Pu 33.3 … … … …
BiPu 50 cF8 Fm 3 m B1 NaCl
830°C BiPu2? 60 to 67 … … … …
800
640°C (dPu) Fm 3 m
600 100 cF4 A1 Cu
(ePu)
483°C
463°C (bPu) 100 mC34 C2/m … bPu
(d'Pu)
400
(dPu) (aPu) 100 mP16 P21 /m … aPu
320°C
271.442°C (gPu)
215°C
P. Chiotti, V.V. Akhachinskij, and I. Ansara, The Chemical Thermodynamics of
200
(bPu) Actinide Elements and Compounds, Part 5: The Actinide Binary Alloys, V.
(Bi) 125°C Medvedev, M.H. Rand, E.F. Westrum, Jr., and F.L. Oetting, ed., International
(aPu)
Atomic Energy Agency, Vienna (1981)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Plutonium Pu
Bi Weight Percent Rubidium
Bi-Rb
0 10 20 30 40 50 60 70 80 90 100
700
642°C
610°C
600
L Bi-Rb
Struktur-
500
465°C
455°C
62 (Bi) 0 hR2 R 3m A7 aAs
400
53.8 403 Bi2Rb 33.3 cF24 Fd 3 m C15 Cu2 Mg
376°C 370 BiRb 50 … … … …
51
Bi4Rb5 55.6 … … … …
300 Bi2Rb3 60 … … … …
271.442 268°C bBiRb3 75 cF16 Fm 3 m D03 BiF3
1.6
230°C
aBiRb3 75 hP8 P63 /mmc D018 Na3 As
200 (Rb) 100 cI2 Im 3 m A2 W
100 (Bi) A.D. Pelton and A. Petric, J. Phase Equilibria, 14(3), 368-372 (1993)
39.48°C
(Rb)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Rubidium Rb
Weight Percent Rhenium Bi-Re

0 10 20 30 40 50 60 70 80 90 100
3500
G + L2 L2
3186°C
3000
Bi-Re
2500 Struktur-
G G + (Re) Composition, Pearson Space bericht
2000
(Re) 100 hP2 P6 3/mmc A3 Mg
1564°C
1500
1000 782-783 (1990)
L1 L1 + (Re)
500
271.442°C
(Bi) (Re)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Rhenium Re

0 10 20 30 40 50
Bi-Rh
1100
997°C
Bi-Rh
900 Struktur-
776°C Phase at.% Rh symbol group designation Prototype
700 Bi4Rh 20 cI20 Ia 3 d … …
Bi3Rh 25 oP16 Pnma … …
bBi2Rh 33.3 aP* P1 … …
aBi2Rh 33.3 mP12 P21/c … CoSb2
500 466°C BiRh 45 to <48 hP4 P63 /mmc B81 NiAs
433°C
370°C H. Okamoto, J. Phase Equil. Diffusion, 31(2), 204 (2010)

336°C
300
271.442°C 266°C
(Bi)
100
0 10 20 30 40 50 60 70
Bi Atomic Percent Rhodium
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
158
Bi Weight Percent Ruthenium
Bi-Ru
0 0.01 0.02
800
700 Bi-Ru
Struktur-
500
L + (Ru)
300
783, 785 (1990)
271°C
271.442°C
200
(Bi) (Bi) + (Ru)

100
0
0 0.01 0.02 0.03 0.04 0.05
Bi Atomic Percent Ruthenium

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Weight Percent Sulfur Bi-S

0 10 20 30 40 50 60 70 80 100
900
L1 + L2
800 775°C
Bi-S
L 727°C
67 99.3 Struktur-
700
600
Bi2S 3 60 oP20 Pnma D5 8 Sb 2S 3
500 (bS) 100 mP48 P21/a … …
400
J.C. Lin, R.C. Sharma, and Y.A. Chang, J. Phase Equilibria, 17(2), 132-139
300
270°C
271.442°C (1996)
200
(bS)
(Bi) 115°C 115.22°C
100 95.5°C
95°C
(aS)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Sulfur S
0 10 20
30 40 50 60 70 80 90 100
Bi-Sb
650
630.755°C
600
550
Bi-Sb
L
Struktur-
500
(Bi,Sb) 0 to 100 hR2 R 3m A7 aAs
450
400
787-789 (1990)
350
(Bi,Sb)
300
271.442°C
250
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Antimony Sb
Bi Weight Percent Selenium
Bi-Se
0 10 20 30 40 50 60 70 80 90 100
800 Bi-Se
L2 Struktur-
705°C
L1 + L2
700
L1 Phase at.% Se symbol group designation Prototype
(Bi) 0 to ? hR2 R 3m A7 aAs
607°C 614°C Bi3Se 25 … … … …
600
Bi7Se3 30 hR20 R 3m … …
Bi2Se 33.3 hP9 Pm 3 1 … …
500 Bi5Se3 37.5 hP48 Pm 3 1 … …
470°C
Bi8Se5 38.5 … … … …
Bi3Se2 40 hP30 Pm 3 1 … …
400 Bi4Se3 42.9 hR7 R 3m … …
Bi6Se5 45.5 hP33 Pm 3 1 … …
Bi8Se7 46.7 … … … …
300
271.442°C
271°C BiSe 50 hP12 Pm 3 1 … …
Bi8Se9 52.9 hP17 Pm 3 1 … …
221°C
200 Bi6Se7 53.8 hP39 Pm 3 1 … …
(Bi) (Se)
Bi5Se6 54.5 … … … …
Bi4Se5 55.6 hP27 Pm 3 1 … …
100
0 10 20 30 40 50 60 70 80 90 100
Bi3Se4 57.1 hP42 Pm 3 1 … …
Bi2Se3 60 hR5 R 3m C33 Bi2Te3
Bi Atomic Percent Selenium Se
(Se) 100 hP3 P31 21 A8 gSe

0 10 20 30 40 50 60 7080 100
Bi-Si
1800
L1 L2
1600 L1 + L2
1400°C
Bi-Si
1400 1414°C
Struktur-
1200 Phase at.% Si symbol group designation Prototype
1000 (Si) 100 cF8 Fd 3 m A4 C (diamond)
800 R.W. Olesinski and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 6(4), 359-
L1 + (Si)
361 (1985)
600
400
217.442°C
200
(Bi) (Si)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Silicon Si

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Bi-Sm
2000
1817°C
1800
1697°C
Bi-Sm
1600
L 1605°C
Struktur-
1400
1297°C
1200
Bi2Sm 33.3 oP12 Pmmm … …
1025°C 1074°C BiSm 50 cF8 Fm 3 m B1 NaCl
1000
897°C
(gSm) Bi3Sm4 57.1 cI28 I 4 3d … Th3P4
922°C
800 (bSm) Bi3Sm5 62.5 hP16 P6 3/mcm D88 Mn5Si3

734°C BiSm2 66.7 tP6 P4/nmm C38 Cu2Sb
600
(gSm) 96 to 100 cI2 Im 3 m A2 W
(bSm) 99 to 100 hP2 P6 3/mmc A3 Mg
400
(aSm)
(aSm) 99 to 100 hR3 R 3m C19 aSm
271.442°C 252°C
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
794-795 (1990)
Bi Atomic Percent Samarium Sm
160
Bi Weight Percent Tin
0 10 20 30 40 50 60 70 80 90 100
Bi-Sn
300
271.442°C
250
Bi-Sn
L 231.9681°C Struktur-
(Bi) 0 to 3 hR2 R3m A7 aAs
(bSn) 93.5 to 100 tI4 I4 1/amd A5 bSn
150 (aSn) ? to 100 cF8 Fd 3 m A4 C (diamond)
138°C
61
100 (Bi) (bSn)
50
13°C
(aSn)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Tin Sn
Weight Percent Strontium Bi-Sr

0 10 20 30 40 50 60 70 80 90 100
1000
945°C
900
858°C Bi-Sr
L 813
800 Struktur-
(bSr) 769°C Composition, Pearson Space bericht
720°C
700 40 Phase at.% Sr symbol group designation Prototype
658°C
? 88 (Bi) 0 hR2 R 3m A7 aAs
600 582°C Bi3Sr 25 cP4 Pm 3 m L12 AuCu3
547°C BiSr 50 … … … …
500 Bi2Sr3 60 … … … …
BiSr2 66.7 tI12 I4/mmm … La2Sb
400 (bSr) 100 cI2 Im 3 m A2 W
300
265°C
271.442°C
(aSr) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
200
(Bi) 794, 797 (1990)
100
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Strontium Sr
0 10 20
30 40 50 60 70 80 90 100
Bi-Ta
3500
G + L2 L2
3020°C
3000 Bi-Ta
Struktur-
2500
G G + (Ta) (Bi) 0 hR2 R 3m A7 aAs
2000 (Ta) 100 cI2 Im 3 m A2 W
1564°C S.P. Garg, N. Krishnamurthy, and M. Venkatraman, J. Phase Equilibria, 13(3),

1500 269-270 (1992)
1000
L1 L1 + (Ta) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
798 (1990)
500
271.442°C
(Bi) (Ta)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Tantalum Ta

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Bi Weight Percent Terbium
Bi-Tb
0 10 20 30 40 50 60 70 80 90 100
2000
1800 1727°C
1600
L 1600°C
1490°C
1410°C (bTb) Bi-Tb
1400 1265°C 1356°C Struktur-
1289°C
1200
83
1000 (Bi) 0 hR2 R 3m A7 aAs
BiTb 50 cF8 Fm 3 m B1 NaCl
800
Bi3Tb4 57.1 cI28 I 4 3d … Th3P4
600
bBi3Tb5 62.5 hP16 P6 3/mcm D88 Mn5Si3
aBi 3Tb 5 62.5 … … … …
(aTb)
400 (bTb) 99 to 100 cI2 Im 3 m A2 W
269°C
271.442°C 0.2 (aTb) 99 to 100 hP2 P6 3/mmc A3 Mg
200
0
(Bi)
-200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Terbium Tb
Weight Percent Tellurium Bi-Te

0 10 20 30 40 50 60 70 80 90 100
650
600 586°C
562°C
550 L 540°C Bi-Te
500
Struktur-
450 449.57°C Phase at.% Te symbol group designation Prototype
420°C 413°C
400 90
375°C Bi7Te3 30 hR20 R 3m … …
350
Bi2Te 33.3 hP9 Pm 3 1 … …
312°C
300 Bi4Te3 42.9 hR7 R 3m … Bi4Se3
271.442
2.4
266°C BiTe 50 hP12 Pm 3 1 … BiSe
250
Bi6Te7 53.8 hP39 Pm 3 1 … …
200 Bi4Te5 55.6 hP27 Pm 3 1 … …
150
(Te) Bi2Te3 59.7 to 60.2 hR5 R 3m C33 Bi2Te3
(Bi) (Te) 100 hP3 P3121 A8 gSe
100
0
0 10 20 30 40 50 60 70 80 90 100
800-801 (1990)
Bi Atomic Percent Tellurium Te
0 10 20 30
40 50 60 70 80 90 100
Bi-Th
2500
L 2000°C Bi-Th
2000
Struktur-
1500
(bTh) (Bi) 0 hR2 R 3m A7 aAs
1350°C
1360°C Bi2Th 33.3 tP6 P4/nmm C38 Cu2Sb
1230°C 80
Bi4Th3 42.9 cI28 I 4 3d D73 Th3P 4
BiTh 50 cP2 Pm 3 m B2 CsCl
1000 Bi3Th5 62.5 hP16 P6 3/mcm D88 Mn5Si3
BiTh 2 66.7 … … … …
(aTh) (bTh) 100 cI2 Im 3 m A2 W
500
271.442°C 271°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(Bi) 802-803 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Thorium Th
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
162
Bi Weight Percent Titanium
Bi-Ti
0 10 20 30 40 50 60 70 80 90 100
1800
1670°C
1600
L Bi-Ti
1400
1340°C
Struktur-
1287°C Phase at.% Ti symbol group designation Prototype
1200
(bTi) R 3m aAs
(Bi) 0 hR2 A7
997°C Bi2Ti 33.3 … … … …
1000
Bi3Ti2 40 … … … …
817°C
882°C Bi9Ti8 47.1 tP34 P4/nmm … …
800
725°C BiTi2 66.7 tP12 P42/mmc … …
687°C
BiTi3 75 t** … … …
600 (bTi) 90 to 100 cI2 Im 3 m A2 W
(aTi) 98.5 to 100 hP2 P63/mmc A3 Mg
400 (aTi)
271.442°C
217°C H. Okamoto, J. Phase Equil. Diffusion, 31(3), 314-315 (2010)
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Bi Atomic Percent Titanium Ti
Weight Percent Thallium Bi-Tl

0 10 20 30 40 50 60 70 80 90 100
350
306°C 304.5°C 304°C Bi-Tl

300 89 99
L Struktur-
300°C
250 (bTl)
230°C (Bi) 0 hR2 R 3m A7 aAs
213°C d 31 to 46 hP3 P6/mmm C32 AlB2
37.5
200 198°C
31 188°C a a 60 to 95 cF4 Fm 3 m A1 Cu
24
46 53 60 BiTl3 70 to 77 hP2 P63/mmc A3 Mg
d hP8 P63/mmc D019 Ni3Sn
150 (bTl) ? to 100 cI2 Im 3 m A2 W
123°C (aTl) ? to 100 hP2 P63/mmc A3 Mg
100 100°C
(Bi) 80°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
50 (aTl) 805-806 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Thallium Tl
0 10 20
30 40 50 60 70 80 90 100
Bi-Tm
2000
1996Abd
(1780°C)
1800 2003Abu
1737°C
1600
(1510°C) 1545°C
Bi-Tm
1400
L Struktur-
1417°C
1200 (1140°C) Phase at.% Tm symbol group designation Prototype
1137°C (Bi) 0 hR2 R 3m A7 aAs
1000 BiTm 50 cF8 Fm 3 m B1 NaCl
Bi3Tm5 62.5 oP32 Pnma … Bi3 Y5
800 (Tm) 100 hP2 P63/mmc A3 Mg
400 (Tm)
272°C
271.442°C
(266°C)
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Thulium Tm
Bi Weight Percent Uranium
Bi-U
0 10 20 30 40 50 60 70 80 90 100
1600
L1 + L2 L2
1400
L1 48 98 Bi-U
Struktur-
1200
1130°C 1135°C
26 99
1010°C
1000 17.6
Bi2U 33.3 tP6 P4/nmm C38 Cu2Sb
(gU) Bi4U 3 42.9 cI28 I 4 3d D73 Th3P4
BiU 50 cF8 Fm 3 m B1 NaCl
800
776°C (gU) 100 cI2 Im 3 m A2 W
(bU) (bU) bU
668°C
100 tP30 P4 2/mnm Ab
600
400 (aU) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
808-809 (1990)
270°C
271.442°C
(Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Uranium U
Weight Percent Vanadium Bi-V

0 10 20 30 40 50 60 70 80 90 100
3500
3409°C
G
3000
Bi-V
G + L2
2500
L2 Struktur-
2000
1877°C 1910°C (Bi) 0 hR2 R 3m A7 aAs
0.0022 G + (V) 97.69
(V) 99.68 to 100 cI2 Im 3 m A2 W
1576°C
1564°C
1500 4.04 99.68
J.F. Smith, Phase Diagrams of Binary Vanadium Alloys, J.F. Smith, ed., ASM
L1 International, Metals Park, OH, 30-32 (1989)
1000
L1 + (V)
(V)
500
271.4°C
271.442°C
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Vanadium V
0 10 20
30 40 50 60 70 80 90 100
Bi-W
900
800
Bi-W
700 Struktur-
600 Phase at.% W symbol group designation Prototype
L L + (W) (W) (Bi) 0 hR2 R 3m A7 aAs
Im 3 m
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
500 (W) 100 cI2 A2 W
400
Publishing Co., Schenectady, NY
300
271.442°C
200
(Bi) (Bi) + (W)

100
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Tungsten W
164
Bi Weight Percent Yttrium
Bi-Y
0 10 20 30 40 50 60 70 80 90 100
2400
2200
2020°C
2000
L Bi-Y
1800
Struktur-
1600 1530°C (bY) Phase at.% Y symbol group designation Prototype
1522°C
1478°C (Bi) 0 hR2 R 3m A7 aAs
1400
BiY 50 cF8 Fm 3 m B1 NaCl
1200 1145°C
Bi3Y 5 62.5 oP32 Pnma … …
81.5 (bY) 100 cI2 Im 3 m A2 W
1000
(aY) ? to 100 hP4 P6 3/mmc A3 Mg
800
K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams,
600 10(4a), 455-457 (1989)
(aY)
400
269°C
271.442°C
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Yttrium Y
0 10 20
30 40 50 60 70 80 90 100
Bi-Yb
1600
1480°C
1400°C Bi-Yb
1400
72 Struktur-
1200 Phase at.% Yb symbol group designation Prototype
L 1100°C
84
1000
Bi2Yb 33.3 oC12 Cmcm C49 ZrSi2
900°C (gYb)
Bi10 Yb11 52.4 tI84 I4/mmm … …
40 Bi3Yb4 57.1 cI28 I 4 3d D73 Th3P4
780°C 819°C
800
95
795°C Bi3Yb5 62.5 oP32 Pnma … …
650°C
BiYb2 66.7 tI12 I4/mmm … La2Sb
600 28 (gYb) 100 cI2 Im 3 m A2 W
(aYb) 100 hP2 P63/mmc A3 Mg
400
(bYb)
271.442°C 250°C H. Okamoto, J. Phase Equilibria, 20(4), 453 (1999)
5
200
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Ytterbium Yb
Weight Percent Zinc Bi-Zn

0 10 20 30 40 50 60 70 80 90 100
600
579.8°C
87 L2
Bi-Zn
L1
500 Struktur-
L1 + L2
(Bi) 0 to 1.6 hR2 R 3m A7 aAs
416.5°C 99.2 419.58°C (Zn) 99.93 to 100 hP2 P6 3/mmc A3 Mg
37.1 99.93
400
D.V. Malakhov, Calphad, 24(1), 1-14 (2000)
(Zn)
300
271.442°C
254.5°C
1.6 8.1 99.99
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(Bi)
200
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Zinc Zn
Bi Weight Percent Zirconium
Bi-Zr
0 10 20 30 40 50 60 70 80 90 100
2000
1855°C
Bi-Zr
L Struktur-
1497°C
1342°C
43
1302°C 1292°C
(bZr) (Bi) 0 hR2 R 3m A7 aAs
75 85
Bi2 Zr 33.3 oP24 Pnnm … …
BiZr 50 … … … …
1000 Bi2 Zr3 60 … … … …
901°C 97
96 863°C
BiZr2 66.7 … … … …
?
714°C
BiZr3 75 tI32 I4 D0e Ni3P
4 (bZr) 85 to 100 cI2 Im 3 m A2 W
(aZr) 96 to 100 hP2 P63/mmc A3 Mg
500 (aZr)
271.3°C
H. Okamoto, Bull. Alloy Phase Diagrams, 11(3), 295-297 (1990)
271.442°C
(Bi)
0
0 10 20 30 40 50 60 70 80 90 100
Bi Atomic Percent Zirconium Zr
0 10
20 30 40 50 60 70 80 90 100
Bk-Mo
5000
4680°C
G
4000 Bk-Mo
Struktur-
G + L2
3000 (bBk) 0 cF4 Fm 3 m A1 Cu
2617°C
(aBk) 0 hP4 P63 /mmc A3’ aLa
G + (Mo) (Mo) 100 cI2 Im 3 m A2 W
2157°C
2000
L1
L1 + (Mo) (Mo) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
816, 818 (1990)
1050°C (bBk)
1000
977°C
(aBk) (aBk) + (Mo)
0
0 10 20 30 40 50 60 70 80 90 100
Bk Atomic Percent Molybdenum Mo
9
10 11
Bk-O
900
800
Bk-O
700
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

600 aBk2O3( s) BkO2(a) (Bk) 0 hP4 P63/mmc A3’ aLa
gBk2 O3 60 hP* … … …
bBk 2O3 60 m** … … …
500
aBk 2O3 (s) <59 to 62 cI80 Ia 3 D53 Mn2O3
BkO2 (a) 63 to >67 c** … … …
400
300 a1 + a2
200
59 60 61 62 63 64 65 66 67
166
Br Weight Percent Bromine
Br-Ca
0 10 20 30 40 50 60 70 80 90 100
1400
1300
L
Ca-Br
1200
Struktur-
L1 + L2 (bCa) 0 cI2 Im 3 m A2 W
1000
CaBr2 66.7 oP6 Pnnm C35 CaCl2
900
842°C
H. Okamoto, J. Phase Equilibria, 15(3), 363 (1994); 18(1), 110 (1997)
800
700
(b Ca)
600
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Bromine Br
45
50 55 60
Br-Cd
1000
900
Cd-Br
800 L2 Struktur-
700
CdBr 2 66.7 … … … …
L1 + L2
L.E. Topol and A.L. Landis, J. Am. Chem. Soc., 82, 6291 (1960)
600
568°C
536°C
500
L1 + CdBr2
400
50 55 60 65 70
0 10 20
30 40 50 60 70 80 90 100
Br-Ce
900
850 L1 L1 + L2 Ce-Br
L2 Struktur-
800
798°C (dCe) 0 cI2 Im 3 m A2 W
(bCe) 0 hP4 P6 3/mmc A3’ aLa
(dCe)
750 (aCe) 0 cF4 Fm 3 m A1 Cu
732°C
CeBr 3 75 hP8 P63/m … UCl3
726° C (Br) 100 oC8 Cmca A14 I
(gCe) H. Okamoto, J. Phase Equilibria, 20(6), 632 (1999)

700
687°C
650
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Bromine Br
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Br Weight Percent Chlorine
Br-Cl
0 10 20 30 40 50 60 70 80 90 100
0
-7.25°C
L
Br-Cl
Struktur-
-50 Composition, Pearson Space bericht
(Br,Cl) 0 to 100 oC8 Cmca A14 I
-100 -100.97°C
(Br,Cl)
-150
0 10 20 30 40 50 60 70 80 90 100
Br Atomic Percent Chlorine Cl
0 5 10
15 20 25 30 35
Br-Cs
700
650
L Cs-Br
Struktur-
CsBr 50 … … … …
550
W. Grob and R.W. Schmutzler, Ber. Bunsenges. Phys. Chem., 93, 1078 (1989)
500
CsBr
450
400
0 10 20 30 40 50
Cs Atomic Percent Bromine

0 10 20 30 40 50 60 70
Br-Ga
180
164°C 164.5°C
Ga-Br
160
154°C Struktur-
152°C
140
bGaBr 50 ... ... ... ...
124°C aGaBr 50 ... ... ... ...
120
bGaBr2 66.7 ... ... ... ...
aGaBr2 66.7 ... ... ... ...
100 Ga3 Br7 70 ... ... ... ...
GaBr3 75 ... ... ... ...
88°C
80
81.2°C D. Mascherpa-Corral and A. Potier, Bull. Soc. Chim. Fr., (6), 1912-1918 (1973)
(Ga)
60
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,
0 10 20 30 40 50 60 70
Ga Atomic Percent Bromine
168
Br
0 10
20 30 40 50 60 70 80 90 100
Br-Hg
600
L1 + L2
500
Hg-Br
Struktur-
B.P. 400
356.58°C
300
(Hg) 0 cI2 Im 3 m A2 W
bHgBr 50 tI16 I4/mmm D31 HgCl
200 aHgBr 50 o** … … …
HgBr2 66.7 oC12 Cmc2 1 C24 HgBr2
100 (Br) 100 oC8 Cmca A14 I
B.P.
58.78°C
L C. Guminski, J. Phase Equilibria, 21(6), 539-543 (2000)
0 -7.25°C
-38.8290°C
-100
(Hg)
(Br)
aHgBr
-200
0 10 20 30 40 50 60 70 80 90 100
Hg Atomic Percent Bromine Br
0 10 20 30 40
50 60 70 80 90 100
Br-I
150
Br-I
113.6°C Struktur-
L Phase at.% I symbol group designation Prototype
(Br,BrI) 0 to 50 oC8 Cmca A14 I
BrI 50 oC8 Ccm21 … …
(BrI,I) 50 to 100 oC8 Cmca A14 I
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
50
(BrI,I)
0
(Br,BrI)
-50
0 10 20 30 40 50 60 70 80 90 100
Br Atomic Percent Iodine I
0 10 20
30 40 50 60 70 80 90 100
Br-In
450
L2 + G
419.7°C
400 In-Br
Struktur-
350
L1
L1 + L2
InBr 50 oC8 Cmcm B33 TlI
L2 In5Br7 58.3 tP192 P422 12 … …
300
285.2°C In4Br7 63.4 … … … …
InBr3 + G
InBr 2 66.7 … … … …
InBr 3 75 … … … …
250 (Br) 100 oC8 Cmca A14 I
234.3 234.6°C
197.1
H. Okamoto, Bull. Alloy Phase Diagams, 11(3), 297-300 (1990)
200 199.2°C 196°C
185.7°C
156.634°C 156°C
150 (In)
0 10 20 30 40 50 60 70 80 90 100
In Atomic Percent Bromine Br
Br-K
0 10 20 30 40 50 60 70 80 90 100
800
727°C L2 733.8°C
L1 35.9
23.3 708°C 45
K-Br
600
Struktur-
(K) 0 cI2 Im 3 m A2 W
KBr 50 cF8 Fm 3 m B1 NaCl
400 (Br) 100 oC8 Cmca A14 I
821-823 (1990)
200
63.7°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
K Atomic Percent Bromine Br
0 10 20
30 40 50 60 70 80 90 100
Br-La
900
(gLa)
865°C La-Br
L Struktur-
850
800 (aLa) 0 hP4 P63 /mmc A3’ aLa
(bLa)
786°C LaBr3 75 hP8 P63 /m … UCl3

750
728°C
700
0 10 20 30 40 50 60 70 80 90 100
La Atomic Percent Bromine Br
50 60
70 80 90 100
Br-Mo
2500
Mo-Br
2000 Struktur-
(Mo) + G Phase at.% Br symbol group designation Prototype
1500 MoBr2 66.7 oC72 Cmca … …
MoBr3 75 hP* P63222 … …
oP16 Pnmm … …
1080°C G MoBr4 80 … … … …
1000 (Br) 100 oC8 Cmca A14 I
690°C
500 (Mo) + MoBr 2 824-825 (1990)
140°C L
MoBr4 59.1°C
0
50 60 70 80 90 100

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Br-Na
0 10 20 30 40 50 60 70 80 90 100
1200
1090°C
L 33.3
Na-Br
1000
Struktur-
800
747°C (bNa) 0 cI2 Im 3 m A2 W
740°C
3.3 49 NaBr 50 cF8 Fm 3 m B1 NaCl
600
400 824, 826 (1990)
200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Na Atomic Percent Bromine Br
90 92
94 96 98 100
Br-P
120
100
L P-Br
80
Struktur-
PBr3 75 oP16 Pnma … SbCl3
40
PBr5 83.3 oP24 Pbcm … …
PBr7 87.5 oP32 Pnma … …
PBr9 90 … … … …
20
12
PBr17 94.4 … … … …
0
-7.25°C W. Biltz and K. Jeep, Z. Anorg. Allgem. Chem., 162, 32-48 (1927)
-20
(Br)
-40
PBr3
75 80 85 90 95 100
0 10 20
30 40 50 60 70 80 90 100
Br-Pr
750
L
Pr-Br
Struktur-
(aPr) 0 hP4 P63/mmc A3’ aLa
650 (aPr) Pr5Br12 70.6 … … … …
PrBr3 75 hP8 P63/m … UCl3
601°C
579°C
550
0 10 20 30 40 50 60 70 80 90 100
Pr Atomic Percent Bromine Br
Br-Rb
0 10 20 30 40 50 60 70 80 90 100
800
L 693°C
Rb-Br
Struktur-
600
(Rb) 0 cI2 Im 3 m A2 W
RbBr 50 cF8 Fm 3 m B1 NaCl
400
827-828 (1990)
200
39.48°C
(Rb)
0
0 10 20 30 40 50 60 70 80 90 100
Rb Atomic Percent Bromine Br
0 10 20 30 40 50
60 70 80 90 100
Br-S
120
115.22°C
(bS)
100
95.5°C
80 S-Br
Struktur-
L Phase at.% Br symbol group designation Prototype
40 (bS) 0 mP48 P21 /a … …
20 SBr 50 … … … …
0
-7.25°C
L.F. Denisova, Zh. Neorg. Chim., 1(4), 758-771 (1956)
-20
-40°C
-40 -46°C
46 -55°C
-60 59.5
(aS)
(Br)
-80
0 10 20 30 40 50 60 70 80 90 100
S Atomic Percent Bromine Br
70 75
80 85 90 95 100
Br-Sb
100
94
80
Sb-Br
60
Struktur-
SbBr3 75 oP16 Pnma … SbCl 3
40
75 oP16 P2 12 12 1 … AsBr3
SbBr3
20
W. Biltz and K. Jeep, Z. Anorg. Allgem. Chem., 162, 32-48 (1927)
0
-7.25°C
-20
(Br)
75 80 85 90 95 100

--`,`,``,`,```,,``

Br
0 10 20 30 40
50 60 70 80 90 100
Br-Sc
1100
1541°C M.P.
L Sc-Br
1000 Struktur-
(aSc) 0 hP2 P63 /mmc A3 Mg
900 Sc2Br3 60 … … … …
880°C
ScBr 3 75 hR24 R3 … …
850°C (Br) 100 oC8 Cmca A14 I
817°C
70.67 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
800
(aSc)
827, 829 (1990)
700
0 10 20 30 40 50 60 70 80 90 100
Sc Atomic Percent Bromine Br
Weight Percent Bromine Br-Se

0 10 20 30 40 50 60 70 80 90 100
250
221°C
Se-Br
200
Struktur-
L
150 (Se) 0 hP3 P3121 A8 gSe
123°C SeBr 50 … … … …
SeBr4 80 … … … …
100 (Br) 100 oC8 Cmca A14 I
(Se) P. Born, R. Kniep, and D. Mootz, Z. Anorg. Allg. Chem., 352, 12-24 (1979)
50
5°C
0°C -4°C
0 -9°C -7°C
(Br)
-50
0 10 20 30 40 50 60 70 80 90 100
Se Atomic Percent Bromine Br
92 93 94
95 96 97 98 99 100
Br-Si
20
10
5°C Si-Br
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L
-7.25°C
SiBr4 80 … … … …
-10

-20
-30
-33°C
-40
SiBr4 (Br)
-50
80 82 84 86 88 90 92 94 96 98 100
Br-Sn
0 10 20 30 40 50 60 70 80 90 100
900
800
L1
700
Sn-Br
600 Struktur-
L1 + L2
400
SnBr2 66.7 … … … …
300
SnBr4 80 mP20 P21/c … …
231.9681°C (Br) 100 oC8 Cmca A14 I
200 221°C
F. Thevert, C. Dagron, and J. Flahaut, Compt. Rend. Acad. Sc. Paris, C, 278,
100 (bSn)
1223-1225 (1974) in French
28°C
13°C
0 -16°C -7.25°C
(aSn) (Br)
-100
0 10 20 30 40 50 60 70 80 90 100
Sn Atomic Percent Bromine Br
0 10 20 30
40 50 60 70 80 90 100
Br-Sr
1200
1100 Sr-Br
L 1064°C
43.2 Struktur-
1000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
900
L1 + L2 (aSr) 0 cF4 Fm 3 m A1 Cu
bSrBr2 66.7 … … … …
800 aSrBr2 66.7 tP* P4/n … …
769°C
745°C (Br) 100 oC8 Cmca A14 I
2.9
700
640°C
600 (bSr) 830-831 (1990)
547°C
500
(aSr)
400
0 10 20 30 40 50 60 70 80 90 100
Sr Atomic Percent Bromine Br
40
50 60 70
Br-Ta
700
676°C
Ta-Br
Struktur-
(Ta) 0 cI2 Im 3 m A2 W
Ta3Br7 70 … … … …
500
Ta2Br5 71.4 cI112 Ia3d … …
(Ta) + Ta3Br7 Ta6Br17 73.9 … … … …
450°C
TaBr 4 80 oC40 Cmcm … …
400 392°C
TaBr 5 83.3 oP48 Pbam … …

300
272°C
267°C
200
60 65 70 75 80 85
174
Br-Te
0 10 20 30 40 50 60 70 80 90 100
500
449.57°C
400 388°C Te-Br

Struktur-
300
(Te) 0 hP3 P3121 A8 gSe
Te2Br 33.3 tP24 Pnam … …
225°C TeBr4 80 mC80 C2/c … …
200°C (Br) 100 oC8 Cmca A14 I
200
50
830, 832 (1990)
100 (Te)
0
0 10 20 30 40 50 60 70 80 90 100
Te Atomic Percent Bromine Br
0 88 90
92 94 96 98 100
Br-Ti
50
40
38°C
30 Ti-Br
Struktur-
10 bTiBr4 80 cP40 Pa 3 … SnI4
aTiBr4 80 mP20 P121 /c1 … …
0
bTiBr4 W. Biltz and K. Jeep, Z. Anorg. Allgem. Chem., 162, 32-48 (1927)
-7.25°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
-10
-16°C
-20
-26°C
-30
aTiBr4 (Br)
-40
80 82 84 86 88 90 92 94 96 98 100
75 80
85 90 95 100
Br-Tl
500
L1
456
400 Br-Tl
BrTl
L2 Struktur-
303
300 304°C BrTl 50 cP2 Pm 3 m B2 CsCl
(bTl)
(bTl) 100 cI2 Im 3m A2 W
232
230°C
200 Yu.P. Afinogenov and T.N. Larionova, Zh. Neorg. Khim., 37, 2606-2608 (1992)
in Russian, TR: Russ. J. Inorg. Chem., 37, 1344-1345 (1992)
(aTl)
100
0
50 60 70 80 90 100
Atomic Percent Thallium Tl
C Weight Percent Carbon
C-Ca
0 10 20 30 40 50 60 70 80 90 100
2800
2600
2400
L
2200 Ca-C
2000 Struktur-
1800
1600 (aCa) 0 cF4 Fm 3 m A1 Cu
1400
gCaC2 66.7 cF8 Fm 3 m B1 NaCl
1200
(C) bCaC2 66.7 tI6 I4/mmm C11 a CaC2
1000 aCaC2 66.7 aP24 P1 ... ...
842°C
800 (C) 100 hP4 P63 /mmc A9 C (graphite)
600 (bCa)
E. Schürmann and H. Jacke, Steel Res., 58(9), 399-405 (1987)
443°C
400
200 (aCa)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Carbon C
0 20 40 50 60 70 80
90 100
C-Ce
2600
2400
2250°C
2220°C
2200 C-Ce
Struktur-
1900°C
1800
(C) 0 hP4 P63 /mmc A9 C (graphite)
1600 bC2Ce 33.3 cF12 Fm 3 m C1 CaF2
aC2Ce 33.3 tI6 I4/mmm C11a CaC2
1400
C3Ce2 40 cI40 I 4 3d D5c Pu2 C3
1200 (dCe) 97 to 100 cI2 Im 3 m A2 W
1050°C (gCe) 95 to 100 cF4 Fm 3 m A1 Cu
1000
(dCe)
800 798°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
600 (C) 833-835 (1990)
(gCe)
400
200
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Cerium Ce
93 94
95 96 97 98 99 100
C-Cl
-20 -22.8°C
C-Cl
bCCl4 Struktur-
-40
-47.5°C
L bCCl4 80 o** … … …
-60 aCCl4 80 mC160 C12/c1 … CBr 4
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
-80 M. Abassalti and M. Michaud, Rev. Chim. Min., 12(2), 134-138 (1975): in
French
-100 -100.97°C
-114.4°C
-120
(Cl)
80 82 84 86 88 90 92 94 96 98 100
176
C
0 1
2 3 4
C-Co
1800
1600
L
1495°C
1400
Co-C
1320°C Struktur-
4.1 11.6
(aCo) Composition, Pearson Space bericht
1121°C Tc (aCo) 0 to 4.1 cF4 Fm 3 m A1 Cu
1000 (eCo) 0 hP2 P6 3/mmc A3 Mg

800
(aCo) + (C)
600
422°C
400
(eCo) (eCo) + (C)

200
0 2 4 6 8 10 12 14 16 18 20
Co Atomic Percent Carbon
0 2 4
6 8 10 12 14 16 18
C-Cr
2000
1863°C
Cr-C
L 1811°C Struktur-
1800
1766°C
1727°C
31.5 32.6 (Cr) 0 to 0.3 cI2 Im 3 m A2 W
Cr23C6 20 to 21 cF116 Fm 3 m D84 Cr23C6
Cr7C3 28.5 to 31.5 oP40 Pnma D101 Cr7C3
1600 1576°C Cr3C2 39.5 to 40 oP20 Pnma D510 Cr2C3
17 21
1534°C
0.3 14 20 M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 11(2), 152-
159 (1990)
1400
(Cr)
1200
0 10 20 30 40 50
Cr Atomic Percent Carbon
0 0.01
0.02 0.03 0.04
C-Cu
2400
2200
L
2000 Cu-C
Struktur-
1600 L + (C) (Cu) 0 to 0.04 cF4 Fm 3 m A1 Cu
P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper

1400
1200
1100°C
1084.87°C 0.04
1000 (Cu)
(Cu) + (C)
800
600
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0.22
Cu Atomic Percent Carbon

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
C Weight Percent Erbium
C-Er
0 30 50 60 70 80 90 100
2500
2260°C
L
C-Er
Struktur-
2000
(C) 0 to ? hP4 P6 3/mmc A9 C (graphite)
g C2Er 33.3 tI6 I4/mmm C11 a CaC 2
1529°C g ? … … … …
1500
C19Er15 44.1 tP68 P 4 2 1c … Sc15C19
1310°C CEr 2 66.7 … … … …
CEr 3 75 cF5 Fm 3 m L’1 Fe4N
(Er) 100 hP2 P6 3/mmc A3 Mg
1000
(C) (Er) Publishing Co., Schenectady, NY
500
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Erbium Er
0 1
2 3 4 5 6
C-Fe
1600
1538°C
2.43
(dFe) 1493°C
L
0.74
1400
1394°C L + C(graphite) Fe-C
1252°C Struktur-
1200 17.1
1153°C
9.06
9.23
1147°C 17.3
(gFe) (dFe) 0 to 0.4 cI2 Im 3 m A2 W
1000 (gFe) 0 to 9.06 cF4 Fm 3 m A1 Cu
(aFe) 0 to 0.096 cI2 Im 3 m A2 W
912°C
Fe3C* 25 oP16 Pnma D011 Fe3C
800
0.096 2.97 740°C * Metastable
0.104 3.46 727°C

(aFe)
400
0 5 10 15 20 25
Fe Atomic Percent Carbon
0 1020 30 40 50 60 70
80 90 100
C-Ge
4500
G
G
3826°C
C-Ge
3500 Struktur-
2834°C (C) 0 hP4 P6 3/mmc A9 C (graphite)
2500
(C) 486 (1984)
1500
938.3°C
(Ge)
500
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Germanium Ge

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
178
C-Hf
0 10 20 30 40 50 70 100
4000 3942°C
48.4
L
Hf-C
3500 Struktur-
3173°C
49.9 68 Phase at.% C symbol group designation Prototype
3000
(bHf) 0 to 0.5 cI2 Im 3 m A2 W
(aHf) 0 to 14 hP2 P63 /mmc A3 Mg
2500
HfC 35.5 to 49.9 cF8 Fm 3 m B1 NaCl
6 2376°C HfC
14 33.5
2231°C 1.4
2207°C .5 2.9
2000 (bHf) H. Okamoto, J. Phase Equilibria, 22(4), 510 (2001)
(C)
1743°C
(aHf)
1500
1000
0 10 20 30 40 50 60 70 80 90 100
Hf Atomic Percent Carbon C
0 30 50 60 70 80
90 95 98 100
C-Hg
4000
3826°C ?
G
3000
C-Hg
Struktur-
G (C) 0 hP4 P63 /mmc A9 C (graphite)
2000
(Hg) 100 hR2 R 3m A7 aAs
(C)
C. Guminski, Polish J. Chem., 78, 1733-1751 (2004)
1000
356.623°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L
0 -38.8290°C
(Hg)
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Mercury Hg

0 30 50 60 70 80 90 100
C-Ir
3000
2900
C-Ir
2800
Struktur-
2700
2600
(Ir) 96.88 to 100 cFI4 Fm 3 m A1 Cu
2500 L
2447°C
2400
853-854 (1990)
2300 2296°C
79.2 96.88
2200
(Ir)
(C)
2100
2000
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Iridium Ir
C
0
5 10 15 20 25
C-La
2500
2250°C
2000
La-C
Struktur-
1500 (gLa) 0 to 2 cI2 Im 3 m A2 W
1415°C
(bLa) 0 to 3.4 cF4 Fm 3 m A1 Cu
1060°C La2C3 54 to 60 cI40 I 4 3d D5c Pu2C 3
1000 (gLa) bLaC2 63 to 67.5 tI6 I4/mmm C11 a CaC 2
918°C 875°C
865°C 806°C aLaC2 66.7 cF12 Fm 3 m C1 CaF 2
20.6
(bLa) (C) 100 hP4 P6 3/mmc A9 C (graphite)
500
310°C 446-449 (1986)
(aLa)
0
0 10 20 30 40 50 60 70 80
La Atomic Percent Carbon
0 10 20
30 40 50 60 70 80 90 100
C-Li
1100
C-Li
(C)
? L Struktur-
? Phase at.% Li symbol group designation Prototype
700 C72Li 1.4 hP* … … …
C40Li* 2.4 hP* … … …
C36Li 2.7 hP* … … …
500 C18Li 5.3 hP* … … …
C16Li* 5.9 hP* … … …
C12Li 7.7 hP* … … …
300 C6 Li 14.3 hP7 P/mmm … …
175°C
bCLi 50 oI8 Immm … CsO
180.6°C
aCLi 50 mP28 Pm/2 … …
100
(bLi) (aLi) 100 hP2 P63 /mmc A3 Mg
-100 *Not shown.
-193°C
(aLi) H. Okamoto, Bull. Alloy Phase Diagrams, 10(1), 69-72 (1989)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
-300
0 10 20 30 40 50 60 70 80 90 100 See also
J. Sangster, J. Phase Equilibria Diffusion, 28(6), 561-570 (2007)
C Atomic Percent Lithium Li
0 10 20
30 40 50 60 70 80 90 100
C-Mg
3100
2900
2700 L 2625°C
2500 Mg-C
2300 Struktur-
2100
1900 (Mg) 0 hP2 P6 3/mmc A3 Mg
1700
MgC 50 … … … …
1500
(C)
1300
I.Y. Ignateva, O.M. Barabash, and T.N. Legkaya, Superhard Mater., 12, 1-5
(1990)
1100
900
780°C?
700
650°C M.P.
500 (Mg)
300
0 10 20 30 40 50 60 70 80 90 100
Mg Atomic Percent Carbon C
180
C
0
5 10
C-Mn
1800
1600 Mn-C
L Struktur-
1400
1333°C Phase at.% C symbol group designation Prototype
(dMn)
1246°C
1308°C (dMn) 0 to 0.1 cI2 Im 3 m A2 W
1200 1231°C 1243 1171°C
1138°C e (gMn) 0 to 13 cF4 Fm 3 m A1 Cu
1100°C 1052°C (bMn) 0 to 0.5 cP20 P4132 A13 bMn
1000 (gMn) 990°C 1034°C 971°C (aMn) 0 to 6.5 cI58 I 4 3m A12 aMn
(bMn)
e 13.5 to 24. 5 … … … …
818°C
800 770°C Mn23C6 20.7 cF116 Fm 3 m D84 Cr23C6
727°C Mn3C 25 oP16 Pnma D011 Fe3C
Mn5C2 28.6 mC28 C2/c … …
600
Mn7C3 30 oP40 Pnma D10 1 Cr7C 3
(aMn) (C) 100 hP4 P6 3/mmc A9 C (graphite)
428°C
400
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
200
0 10 20 30 40 859-861 (1990)
Mn Atomic Percent Carbon
0
10 20 30 40 50 60 80 100
C-Mo
3000
2623°C L 2605°C 2589°C

42 43 45
2500 34 d Mo-C
Struktur-
2205°C b
1.1 17 27 Composition, Pearson Space bericht
2000 1956°C Phase at.% C symbol group designation Prototype
40.4
(Mo) 0 to 1.1 cI2 Im 3 m A2 W
h
1647°C b 27 to 36 hP3 P63/mmc L’3 Fe2N
39
1500 b’ 32 to 34 oP12 Pbcn … …
1278°C b” 33 to 33.5 … … … …
1220°C
h 37 to 40 hP8 P63/mmc Bi TiAs
b' d 37 to 43 cF8 Fm 3 m B1 NaCl
1000
MoC 50 hP2 P 6 m2 Bh WC
(Mo) b"
500
(C)
861-862 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Mo Atomic Percent Carbon C
0 5
10 20 30 40 60 80 100
C-Nb
4700
4200
L Nb-C
3200
3007°C (Nb) 0 to 5 cI2 Im 3 m A2 W
Nb2C 29 to 33.5 hP4 P63 /mmc B81 NiAs
2700 NbC NbC 37.7 to 50 cF8 Fm 3 m B1 NaCl
2469°C 2340°C
2200
(C) H. Okamoto, J. Phase Equilibria, 19(1), 87 (1998)
(Nb)
Nb2C
1700
1200
700
0 10 20 30 40 50 60 70 80 90 100
Nb Atomic Percent Carbon C
C
0
10 20 30 40 50 60 70 80 100
C-Ni
4000
3500
Ni-C
L Struktur-
(Ni) 0 to 2.7 cF4 Fm 3 m A1 Cu
2500 (C) 100 hP4 P6 3/mmc A9 C (graphite)
M.F. Singleton and P. Nash, Phase Diagrams of Binary Nickel Alloys, P. Nash,
2000 ed., ASM International, Materials Park, OH, 50-55 (1991)
1500
1455°C 1326.5°C
2.7
1000
(Ni) (C)
500
0 10 20 30 40 50 60 70 80 90 100
Ni Atomic Percent Carbon C
0
1 2 3 4
C-Os
3600
3400
L Os-C
3200 Struktur-
L + (C) Composition, Pearson Space bericht
3033°C
(Os) 0 to ? hP2 P63 /mmc A3 Mg
2800
2732°C
(Os)
2600
866, 868 (1990)
2400
2200 (Os) + (C)
2000
1800
0 5 10 15 20 25 30 35 40
Os Atomic Percent Carbon
0 10 20 30 40 50
60 70 80 90 100
C-P
5000
4000
L
C-P
Struktur-
3000
(red P) 100 … … … …
(C) FactSage, Collection of Phase Diagrams (2004)

2000
1000
(red P)
0
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Phosphorus P

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
182
C
0 30 50 60 70 80 90
Weight Percent Lead
95 98 100
C-Pb
5000
L
4000
C-Pb
Struktur-
3000
2000 FactSage, Collection of Phase Diagrams (2004)

(C)
1000
327.502°C
(Pb)
0
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Lead Pb

C-Pd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 2 4 6 8 10
1800
L L + (C)
1600
1555°C
1504°C Pd-C
Struktur-
(Pd)
(Pd) 0 to 8 cF4 Fm 3 m A1 Cu
1000
(Pd) + (C) 869-870 (1990)
800
600
0 5 10 15 20 25 30 35 40 45 50
Pd Atomic Percent Carbon

0 10 20 30 40 50 70 100
C-Pr
2400
2320°C
2254°C
2200 71.5
2000
Pr-C
Struktur-
1600 1545°C
(bPr) 0 to ? cI2 Im 3 m A2 W
1400
(aPr) 0 to ? hP4 P6 3/mmc A3’ aLa
Pr2C 3 54 to 60 cI40 I 4 3d D5c Pu2C 3
1200 1145
bPrC2 64.5 to 68 c** … … …
1134°C
aPrC2 66 to 66.7 tI6 I4/mmm C11 a CaC 2
1000 (bPr) (C) 100 hP4 P6 3/mmc A9 C (graphite)
931°C
800°C
800
15 (C)
795°C
600 (aPr) 871-872 (1990)
400
0 10 20 30 40 50 60 70 80 90 100
Pr Atomic Percent Carbon C
C-Pt
0 1 2 3 4 5
2500
2300
2100 L Pt-C
L + (C)
Struktur-
1769.0°C
1705°C
1700
16.8 (Pt) 0 to ? cF4 Fm 3 m A1 Cu
1500
1300
(Pt)
871, 873 (1990)
1100
(Pt) + (C)
900
700
500
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 5 10 15 20 25 30 35 40 45 50
Pt Atomic Percent Carbon
0
10 20 30 40 60 100
C-Pu
2500
Pu-C
Struktur-
2050°C
2000
1654°C 1660°C
1500 (dPu) 0 cF4 Fm 3 m A1 Cu
(bPu) 0 mC34 C2/m … bPu
(aPu) 0 mP16 P21/m … aPu
1000
Pu3C 2 40 … … … …
PuC 44 to 48 cF8 Fm 3 m B1 NaCl
(ePu) Pu2C 3 59 to 60 cI40 I 4 3d D5c Pu2C 3
640°C 575°C
500 (d'Pu) bPuC2 66.7 c** … … …
483°C
463°C (dPu) aPuC2 66.7 tI6 I4/mmm C11 a CaC 2
320°C
(gPu) (C) 100 hP4 P6 3/mmc A9 C (graphite)
215°C
(bPu)
125°C
(aPu) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
0
0 10 20 30 40 50 60 70 80 90 100 Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
Pu Atomic Percent Carbon C 874-875 (1990)
0 1
2 3 4 5 6
C-Re
3200
3186°C
3000 Re-C
Struktur-
L
2800 (Re) 0 to 11 hP2 P63 /mmc A3 Mg
874, 876-877 (1990)
2505°C
(Re) 11 23
2400
(Re) + (C)
2200
0 10 20 30 40 50
Re Atomic Percent Carbon
184
C
0 2
4 6 8 10
C-Rh
2500
2300
L Rh-C
2100
Struktur-
L + (C)
1900
1700
1694°C (Rh) 0 to ? cF4 Fm 3 m A1 Cu
1500
(Rh) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
1300
877-878 (1990)
1100
(Rh) + (C)
900
700
500
0 10 20 30 40 50
Rh Atomic Percent Carbon
0 20
30 40 50 10
C-Ru
2400
2334°C
2200 L Ru-C
L + (Ru) Struktur-
1940°C
(Ru) (Ru) 0 to 3 hP2 P63 /mmc A3 Mg
3 18
1800
877, 879 (1990)
1600
(Ru) + (C)
1400
1200
0 10 20 30 40 50
Ru Atomic Percent Carbon
0
10 20 30 40 50
C-Sc
2600
2400 L Sc-C
2270°C
31.6
Struktur-
2200
2000 (bSc) 0 to 2.5 cI2 Im 3 m A2 W
1864°C (aSc) 0 to 4.5 hP2 P63 /mmc A3 Mg
Sc2C 1794°C
1800
1722°C Sc2C 21 to 38 hR3 R 3m C19 CdCl2
(bSc) 62.0 bSc4C3 42.8 to 48 … … … …
1600 1579°C aSc4C3 42.8 cI28 I 4 3d D73 Th3P4
1541°C 1504°C
1543°C
Sc15C19 54 to 56 tP68 P 4 21c … …
1400 (C) 100 hP4 P63 /mmc A9 C (graphite)
1337°C
(aSc) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
880-881 (1990)
1000 950°C
800
0 10 20 30 40 50 60 70 80
Sc Atomic Percent Carbon

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
C-Si
0 10 20 30 40 50 60 70 80 90 100
4500
4000
G
3826°C Si-C
Struktur-
3200°C
3000
SiC 50 cF8 F 4 3m B3 ZnS (sphalerite)
L (C) 100 hP4 P6 3/mmc A9 C (graphite)
2545°C
2500 27
489 (1984)
2000
(C)
1500 1404°C
1414°C
(Si)
1000
0 10 20 30 40 50 60 70 80 90 100
Si Atomic Percent Carbon C
0
5 10 20 30 40 60 80 100
C-Ta
4700
4200
L 3969°C Ta-C
46.7 Struktur-
3700
3476°C
3346°C 49 70 Phase at.% C symbol group designation Prototype
22 38
3200 (Ta) 0 to 8 cI2 Im 3 m A2 W
3020°C Ta2C 28 to 33 hP3 P63/mmc L’3 Fe2N
TaC
2774°C hP3 P 3 m1 C6 CdI2
2700 (Ta) 8 28
TaC 38 to 49 cF8 Fm 3 m B1 NaCl
2200
(C)
1700
1200
700
0 10 20 30 40 50 60 70 80 90 100
Ta Atomic Percent Carbon C
0 2
4 6 8 10
C-Tc
2200
2155°C
L
2000
(Tc) Tc-C
1835°C Struktur-
d (Tc) 0 to 5 hP2 P6 3/mmc A3 Mg
1600 d 13 to 20 cF8 Fm 3m B1 NaCl
1400 H. Okamoto, Binary Alloy Phase Diagrams Updating Service (1991)
1200
1000
0 10 20 30 40 50
Tc Atomic Percent Carbon
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
186
C-Th
0 2 4 6 8 10 12
3000
2610°C
L 2500°C
2500 70.4
66.2 2445°C Th-C
Struktur-
2000 1707°C
1755°C
55
gThC2 (bTh) 0 to 9.5 cI2 Im 3m A2 W
(bTh) 11.5
(aTh) 0 to ? cF4 Fm 3 m A1 Cu
1470°C 1495°C
1500
1440°C ThC ? cF8 Fm 3 m B1 NaCl
1360°C
1255°C gThC2 ? to 66.2 cP12 Pa 3 C2 FeS2 (pyrite)
1140°C
23 bThC2 bThC2 63 to 66 tP6 P42/mmc … …
1000 (aTh)
aThC2 66 mC12 C2/c Cg C2Th
500 ThC R. Benz and P.L. Stone, High Temp. Sci., 1, 114-127 (1969)
0
0 10 20 30 40 50 60 70
Th Atomic Percent Carbon
0 10 20 30 40 50 60
70 80 90 100
C-Ti
3500
3000 L
C-Ti
Struktur-
2500
CTi 50 to 68 cF8 Fm 3 m B1 NaCl
2000 (bTi) 98.2 to 100 cI2 Im 3 m A2 W
CTi
(C) (aTi) 98.3 to 100 hP2 P6 3/mmc A3 Mg
1670°C For [2003Fri]
1500
(bTi)
1000
1996Sei 882°C
2003Fri (aTi)
500
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Titanium Ti
0 30 5060 70 80 90
95 98 100
C-U
3000
L C-U
2500 2426°C 33 Struktur-
d Phase at.% U symbol group designation Prototype
1763°C 34.4
38.7 1833°C d 34.4 to 52 cF8 Fm 3 m B1 NaCl
47.4
34.4 1756 e 34.1 to 35.2 tI6 I4/mmm C11 a CaC 2
e z
1500 1477°C 40 cI40 I 4 3d D5 c Pu 2C3
34.1
(gU) 100 cI2 Im 3 m A2 W
1117°C
1135°C (bU) 100 tP30 P4 2/mnm Ab bU
50.1 99
1000
(gU)
776°C
(C) z 776 °C
669°C
668°C P.Y. Chevalier and E. Fischer, J. Nucl. Mater., 288, 100-129 (2001)
500 (bU)
(aU)
0
0 10 20 30 40 50 60 70 80 90 100
C Atomic Percent Uranium U
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
C-V
0 10 20 30 40 50 60 70 80 90 100
4500
4000 V-C
L Struktur-
3500
(V) 0 to 3.8 cI2 Im 3 m A2 W
3000
V2C 29.3 to 33.3 oP12 Pbcn … …
2658°C 2606°C hP3 P63 /mmc L’3 Fe2N
2500 49.5
hP9 P 31m … …
2193°C
25.8 V4C3-x 38 hR20 R 3m … …
2000
VC
1910°C
1876 VC 37.1 to 47 cF8 Fm 3 m B1 NaCl
(C)
(V)
1649°C V6C5 42 to 44 mB44 B2 … …
3.8 13.3 29.3
1500 V8C7 46.7 cP60 P41 32 … …
1262
cP60 P43 32 … …
1000 1056°C (C) 100 hP4 P63 /mmc A9 C (graphite)
500
V6 C5
0
0 10 20 30 40 50 60 70 80 90 100
V Atomic Percent Carbon C
0
2 4 6 8 10 12
C-W
3500
L
W-C
L + (C)
3000 Struktur-
2785°C 2785°C
2715°C
bWC Phase at.% C symbol group designation Prototype
gW2C 2720°C
Im 3 m
2516°C
(W) 0 to 1 cI2 A2 W
2500
2400°C 2384°C
gW2C 25.5 to 34 hP3 P63 /mmc L’3 Fe2 N
bW2C 29.5 to 33 oP12 Pbcn … …
aW2C 29.5 to 32.5 hP3 P 3m1 C6 CdI2
2097°C
bWC 37.1 to 50 cF8 Fm 3 m B1 NaCl
2000
aWC 49 to 50 hP2 P 6 m2 Bh WC
(W) aW2C aWC + (C) (C)* 100 hP4 P63 /mmc A9 C (graphite)
* Not shown.
1500
1250°C
1000
0 10 20 30 40 50 60 70
W Atomic Percent Carbon
0
5 10 20 30
C-Y
2600
2400
Y-C
2364°C
L 2306°C Struktur-
2200
2018°C
2000 (bY) 0 to 6 cI2 Im 3 m A2 W
(aY) 0 to 6 hP2 P63/mmc A3 Mg
1800 1807°C Y2C* 33.3 hR3 R 3m C19 CdCl2
(bY) 1654°C g 17 to 66.7 cF5 Fm 3 m L’1 Fe4N
1600 1559°C
1527°C bY15 C19 55.9 … … … …
1522°C
1478°C 1529°C g aY15C19 55.9 tP68 P 4 21c … Sc15C19
1400
1304°C 1324°C bY2C3 56 to 60 … … … …
(aY)
1200 1186°C aY2C3 57 to 60 … … … …
aYC 2 66.7 tI6 I4/mmm C11a CaC2
1000 *Not shown.
800
600
0 10 20 30 40 50 60 70 80
Y Atomic Percent Carbon
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
188
C-Yb
0 10 20 30 40 50 70 100
1500
Yb-C
Struktur-
G Composition, Pearson Space bericht
1300
1194°C (gYb) 0 cI2 Im 3 m A2 W
1100 (bYb) 0 cF4 Fm 3 m A1 Cu
bYb2C ~30 to ~33 cF5 Fm 3 m L’1 Fe4 N
L
aYb2C ~33 hR3 R 3m C19 CdCl2
900 Yb4C5 ~55.6 m*26 … … …
819°C P 4 21c
795°C (C) Yb15 C19 ~56 tP68 … …
700
(gYb) Yb2C3 ~60 cI40 I 4 3d D5c Pu2C3
aYbC2 66.7 tI6 I4/mmm C11 a CaC2
a’YbC2 66.7 o** … … C2Lu
500 YbC6 85.7 hP14 P63 /mmc … C6Eu
(bYb)
300 Phase diagram:

J.M. Haschke and H.A. Eick, J. Am. Chem. Soc., 92, 1526-1530 (1970)
100 Table:
0 10 20 30 40 50 60 70 80 90 100
K.A. Gschneidner, Jr., and F.W. Calderwood, Bull. Alloy Phase Diagrams, 7(6),
Yb Atomic Percent Carbon C 568-570 (1986)
0
10 20 30 40 50 60 80 100
C-Zr
4800
4492°C
4300
L Zr-C
Struktur-
3800
3300 (bZr) 0 cI2 Im 3 m A2 W
2927°C
(aZr) 0 hP2 P6 3/mmc A3 Mg
2800 ZrC 36 to 50 cF8 Fm 3 m B1 NaCl

ZrC
(C)
1855°C 1854°C
1800
(bZr)
1300
(aZr) 886°C
863°C
800
0 10 20 30 40 50 60 70 80 90 100
Zr Atomic Percent Carbon C
0 10 20 30 40 50
60 70 80 90 100
Ca-Cd
1000
Ca-Cd
842°C Struktur-
800
701°C bCaCd2 (bCa) Im 3 m
685°C 0 cI2 A2 W
650°C
624°C 614°C 622°C (aCa) 0 cF4 Fm 3 m A1 Cu
600 (bCa) 55.5 75.5 87
Ca3 Cd2 40 tP20 P42nm … …
595°C 90.5
565 Pm 3 m
31
527°C CaCd 50 cP2 B2 CsCl
bCaCd2 66.7 oI12 Imma … …
443°C
408°C aCaCd2 66.7 hP12 P63/mmc C14 MgZn2
400 22
Ca14 Cd51 78.5 hP65 P6/m … Ag51 Gd1 4
316°C
321.108°C Ca3 Cd17 85 … … … …
97.5
CaCd6 85.7 cI184 Im 3 … …
(Cd) (Cd) 100 hP2 P63/mmc A3 Mg
200
(aCa)
0 899, 901(1990)
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Cadmium Cd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ca Weight Percent Cerium
Ca-Ce
0 10 20 30 40 50 60 70 80 90 100
880
860 L1 L1 + L2 L2
Ca-Ce
Struktur-
842°C
840 (bCa) 0 cI2 Im 3 m A2 W
835°C
820 511-512 (1987)
(bCa)
800
795°C 798°C
99.7
(dCe)
780
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Cerium Ce
Weight Percent Chlorine Ca-Cl

0 10 20 30 40 50 60 70 80 90 100
1400
L
1300
1200 Ca-Cl
Struktur-
1100
L1 + L2 (bCa) 0 cI2 Im 3 m A2 W
1000 (aCa) 0 cF4 Fm 3 m A1 Cu
CaCl2 66.7 oP6 Pnnm C35 CaCl 2
900
842°C H. Okamoto, J. Phase Equilibria, 15(1), 127 (1994); 18(1), 110 (1997)
800
700
(bCa)
600
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Chlorine Cl
92
94 96 98 100
Ca-Co
700
(bCa) + (aCo)
626°C 92.1
92 Ca-Co
(aCo)
600
Struktur-
(bCa) + (eCo)
(aCo) ? to 100 cF4 Fm 3 m A1 Cu
500
(eCo) 92 to 100 hP2 P63 /mmc A3 Mg
422°C
400
902, 905 (1990)
(eCo)
(aCa) + (eCo)
300
200
86 88 90 92 94 96 98 100
Atomic Percent Cobalt Co
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
190
Ca
0 10 20 30 40 50 60
70 80 90 100
Ca-Cs
1000
L1
900
L1 + L2 L2
839°C
842°C Ca-Cs
800
Struktur-
700
(bCa) (bCa) + L2 (aCa) 0 cF4 Fm 3 m A1 Cu
600
500 (Cs) 100 cI2 Im 3 m A2 W
443°C
400
300
(aCa) (aCa) + L2
200
100
(Cs)
28.6°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Cesium Cs
0 10 20 30 40
50 60 70 80 90 100
Ca-Cu
1100
1084.87°C
1000
Ca-Cu
951°C
Struktur-
909°C
900 90.2 Composition, Pearson Space bericht
L Phase at.% Cu symbol group designation Prototype
842°C
800
Ca2Cu 33.3 oP12 Pnma … …
700 bCaCu 50 oP40 Pnma … …
aCaCu 50 mP20 P21/m … …
600
(bCa) CaCu5 83.3 hP6 P6/mmm D2d CaCu 5
567°C
51.9 (Cu) (Cu) 100 cF4 Fm 3 m A1 Cu
500 481°C 30.2 489°C
26.2
D. Risold, B. Hallstedt, L.J. Gauckler, H.L. Lukas, and S.G. Fries, Calphad,
453°C
443°C 20(2), 151-160 (1996)
400
(aCa)
300
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Copper Cu
Weight Percent Europium Ca-Eu

0 10 20 30 40 50 60 70 80 90 100
1000
L
842°C
822°C
800 Ca-Eu
735°C
38 Struktur-
600
(bCa, Eu) 0 to 100 cI2 Im 3 m A2 W
(aCa) 0 to ? cF4 Fm 3 m A1 Cu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
443°C
(bCa,Eu) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 8(6),
400
513-514 (1987)
200
(aCa)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Europium Eu
Ca Weight Percent Fluorine
Ca-F
0 10 20 30 40 50 60 70 80 90 100
1500
1400
Ca-F
1320°C
1300
L Struktur-
1304°C
1200
1100
CaF2 66.7 cF12 Fm 3 m C1 CaF2
1000
900
842°C
800 824°C
(bCa)
700
600
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Fluorine F
0 10 20 30 40
Weight Percent Iron
50 60 70 80 90 100
Ca-Fe
2400
2200
2000 L2
1800 Ca-Fe
Struktur-
1600
(dFe) Phase at.% Fe symbol group designation Prototype
1400 1394°C
1200 L1 (gFe) (aCa) Fm 3 m
0 cF4 A1 Cu
1000 (dFe) 99.97 to 100 cI2 Im 3 m A2 W
912°C
842°C (gFe) ~100 cF4 Fm 3 m A1 Cu
800
(aFe) ~100 cI2 Im 3 m A2 W
600 (bCa) (aFe)
443°C H. Okamoto, J. Phase Equil. Diffusion, 31(1), 88-90 (2010)
400
(aCa)
200
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Iron Fe
Weight Percent Gallium Ca-Ga

0 10 20 30 40 50 60 70 80 90 100
1100
1000 990°C Ca-Ga

980°C
930°C Struktur-
842°C
L Phase at.% Ga symbol group designation Prototype
800 795°C
750°C
700
640°C Ca28Ga11 28.2 oI78 Imm2 … …
600
610°C Ca5Ga3 37.5 tI32 I4/mcm D8l Cr5B 3
(bCa)
545°C Ca11Ga7 38.9 cF144 Fm 3 m … …
512°C
500 CaGa 50 oC8 Cmcm Bf CrB
443°C Ca3Ga5 62.5 oC32 Cmcm … …
400 CaGa2 66.7 hP6 P6 3/mmc … …
CaGa2+x 67.7 to 70.6 hP3 P6/mmm C32 AlB 2
300 Ca3Ga8 72.7 oI22 Immm … …
CaGa4 80 mC10 C2/m … …
200 (aCa) (Ga) 100 oC8 Cmca A11 Ga
100
(Ga) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
30°C
0
29.77°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
0 10 20 30 40 50 60 70 80 90 100 913-914 (1990)
Ca Atomic Percent Gallium Ga
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
192
Ca Weight Percent Germanium
Ca-Ge
0 10 20 30 40 50 60 70 80 90 100
1400
1310°C
1240 1210°C
1200 1170
Ca-Ge
1155 L Struktur-
1000
938.3°C
840°C 845°C
842°C Ca2Ge 33.3 oP12 Pnma C23 Co2Si
780°C
800
745°C
Ca5Ge3 37.5 tI32 I4/mcm D8l Cr5B3
775°C Ca7Ge6 46.2 oP52 Pnma … Ca7Sn6
CaGe 50 oC8 Cmcm Bf CrB
(bCa)
600 CaGe2 66.7 hR6 R 3m C12 CaSi2
(Ge)
443°C
400
( aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Germanium Ge
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
1 2 3 4 5
Ca-H
1000
L
900 890°C
32
842°C
800 780°C Ca-H
29 Struktur-
(bCa)
700
(bCa) 0 to 32 cI2 Im 3 m A2 W
600°C
600
16 (aCa) 0 cF4 Fm 3 m A1 Cu
g 1 to 16 hP2 P63/mmc A3 Mg
500 bCaH2 66 to ? … … … …
aCaH2 65.5 to ? oP12 Pnma C23 Co2Si
443°C g
400
2.5
300
(aCa)
200
0 10 20 30 40 50 60 70
Ca Atomic Percent Hydrogen
Weight Percent Mercury Ca-Hg

0 10 20 30 40 50 60 70 80 90 100
1100 Ca-Hg
1000
Struktur-
961°C
900
L Phase at.% Hg symbol group designation Prototype
842°C (bCa) 0 cI2 Im 3 m A2 W
800
746°C (aCa) 0 cF4 Fm 3 m A1 Cu
712°C
700 660°C
Ca3Hg 25 oP16 Pnma D011 Fe3 C
Ca2Hg 33.3 oP12 Pnma C23 Co2Si
(bCa) 587°C
600 570°C Ca5Hg3 37.5 tI32 I4/mcm D8l Cr5B3
523°C 530°C Ca3Hg2 40 tP10 P4/mbm D5a Si2U3
500 486°C 513°C
443°C
CaHg 50 cP2 Pm 3 m B2 CsCl
400 CaHg2 66.7 hP3 P 3 m1 … CeCd2
Ca4Hg9 69.2 cP52 P 4 3m D83 Al4Cu9
300 264°C CaHg3 75 hP8 P63 /mmc D019 Ni3Sn
? Ca14Hg51 78.5 hP65 P6/m … Ag51Gd14
200
CaHg5 83.3 … … … …
(aCa)
100 84°C CaHg8-11 88.9 to 90.7 cP36 Pm 3 m D2e BaHg11
0
-38.836°C
(Hg)
-100 C. Guminski, J. Phase Equilibria, 14(1), 90-96 (1993)
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Mercury Hg
Ca Weight Percent Iodine
Ca-I
0 10 20 30 40 50 60 70 80 90 100
1400
L1
1300 L2
Ca-I
1200 Struktur-
1100
L1 + L2 (aCa) Fm 3 m
0 cF4 A1 Cu
1000 CaI2 66.7 oP6 Pnnm C35 CaCl 2
900
H. Okamoto, J. Phase Equilibria, 15(3), 364 (1994); 18(3), 317 (1997)
842°C
800
700
( bCa)
600
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Iodine I
0 10 20 30 40 50
60 70 80 90 100
Ca-In
1000
895°C
Ca-In
842°C (bCa)
835°C L
765°C
660°C
632°C 35.5
600 12.5 (aCa) 0 cF4 Fm 3 m A1 Cu
Ca3 In 25 cF16 Fm 3 m D03 BiF3
CaIn 50 cP2 Pm 3 m B2 CsCl
443°C CaIn 2 66.7 hP6 P63/mmc … YbGa2
400 (In) 100 tI2 I4/mmm A6 In

200 (aCa) Park, OH, 57-60 (1992)
156°C 156.634°C
(In)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Indium In
0 10 20 30
40 50 60 70 80 90 100
Ca-K
1000
L1
900
L1 + L2 L2
839°C
842°C
Ca-K
800
Struktur-
700
600
500 (K) 100 cI2 Im 3 m A2 W
443°C
300
(aCa) (aCa) + L2
200
100
63.4°C
63.71°C
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Potassium K

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Ca Weight Percent Lanthanum
Ca-La
0 10 20 30 40 50 60 70 80 90 100
1000
(gLa)
L 918° C
855° C Ca-La
842°C L1 + L2
800
798°C Struktur-
70
(bLa) Phase at.% La symbol group designation Prototype
697°C
3 (bCa) 0 to 1.5 cI2 Im 3 m A2 W
600 (gLa) ? to 100 cI2 Im 3 m A2 W
(bCa) (bCa) + (bLa)
(bLa) ? to 100 cF4 Fm 3 m A1 Cu
443°C
400 515-516 (1987)
(aCa) (aCa) + (bLa)
310°C
(aCa) + (aLa) (aLa)

200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Lanthanum La

0 10 20 30 40 50 60 70 80 100 Ca-Li
900
842°C
800
Ca-Li
700 Struktur-
L Phase at.% Li symbol group designation Prototype
600
(bCa) 0 to 9.5 cI2 Im 3 m A2 W
(aCa) 0 to 10.5 cF4 Fm 3 m A1 Cu
500 CaLi2 66.7 hP12 P6 3/mmc C14 MgZn 2
(bCa) (bLi) 99 to 100 cI2 Im 3 m A2 W
443°C
400
370°C
C.W. Bale and A.D. Pelton, Bull. Alloy Phase Diagrams, 8(2), 125-127 (1987)
300
230°C
(aCa)
200
180.6°C
141°C
(bLi)
100
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Lithium Li
0 10 20 30 40 50 60
70 80 90 100
Ca-Lu
2000
L1 + L2
L2
1663°C Ca-Lu
1600°C
1.08 92.8 93.6 Struktur-
1500 (Lu) Composition, Pearson Space bericht
(bCa) 0 to 0.31 cI2 Im 3 m A2 W
(Lu) 93.6 to 100 hP2 P63/mmc A3 Mg
L1 L1 + (Lu)
1000 925-926 (1990)
842°C
0.46 792°C
0.31 98.13
(bCa)
500
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Lutetium Lu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ca Weight Percent Magnesium Ca-Mg
0 10 20 30 40 50 60 70 80 90 100
900
842°C
800
Ca-Mg
L
Struktur-
711°C
650°C
600
(bCa) (aCa) 0 cF4 Fm 3 m A1 Cu
CaMg2 66.7 hP12 P63/mmc C14 MgZn2
517°C (Mg) 99.56 to 100 hP2 P63/mmc A3 Mg
500 99.56

443°C
400
(Mg)
(aCa)
300
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Magnesium Mg
0 10 20 30
40 50 60 70 80 90 100
Ca-Mn
1500
1400
L1 + L2 Ca-Mn
L2
1300 Struktur-
1240°C
1246°C
99.28 Phase at.% Mn symbol group designation Prototype
1200 (dMn)
1143°C
1100 (gMn) (dMn) ? to 100 cI2 Im 3 m A2 W
1079°C
(gMn) ? to 100 cF4 Fm 3 m A1 Cu
1000 (bMn) ? to 100 cP20 P4132 A13 bMn
L1 (bMn) (aMn) 100 cI58 I 4 3m A12 aMn
900
830°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
800
928-929 (1990)
700 710°C
600 (bCa) (aMn)
500
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Manganese Mn
0 10 20 30 40 50
60 70 80 90 100
Ca-Mo
5000 G
4680°C
Ca-Mo
Struktur-
L2 Phase at.% Mo symbol group designation Prototype
G + L2
3000
(Mo) 100 cI2 Im 3 m A2 W
2683°C
2000
G + (Mo) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
928, 930 (1990)
1484°C
L1 L1 + (Mo) (Mo)
1000
842°C
(bCa)
443°C
(aCa)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Molybdenum Mo
196
Ca Weight Percent Nitrogen Ca-N
0 5 10 15 20 25
1600
1450°C Ca-N
1400 Struktur-
1200 (bCa) 0 cI2 Im 3 m A2 W
Ca3N2 40 cI80 Ia 3 D5 3 Mn 2O 3
1000
842°C 814°C
V.P. Itkin and C.B. Alcock, Bull. Alloy Phase Diagrams, 11(5), 497-503 (1990)
800 2.35
600
(bCa)
443°C
400
(aCa)
200
0 5 10 15 20 25 30 35 40 45 50
Ca Atomic Percent Nitrogen

0 10 20 30 40 50 60 70 80 90 100
Ca-Na
1200
L2
L1 Ca-Na
1000
Struktur-
L1 + L2
842°C Phase at.% Na symbol group designation Prototype
800
(bCa) 710°C
600
443°C
400
200 (aCa)
97.55°C
97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Sodium Na
0 10 20 30 40 50 60
70 80 90 100
Ca-Nd
1100
1021°C
1000 L1 + L2 L2 Ca-Nd
L1 Struktur-
76.6 86.6
(bNd) 863°C Phase at.% Nd symbol group designation Prototype
842°C 0.5 831°C
0.1 87.1 (bCa) 0 to 0.1 cI2 Im 3 m A2 W
800
(bNd) 86.6 to 100 cI2 Im 3 m A2 W
700
(aNd) 96 to 100 hP4 P6 3/mmc A3’ aLa
(bCa)
517-518 (1987)
500
444°C
443°C
429°C 93 96
400
(aCa)
(aNd)
300
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Neodymium Nd

--`,`,``,`,```,,``,``
Ca Weight Percent Nickel
Ca-Ni
0 10 20 30 40 50 60 70 80 90 100
1600
1455°C
1400 Ca-Ni
Struktur-
1206°C 1187°C
1127°C 87.7
71.5 (bCa) 0 cI2 Im 3 m A2 W
1007°C (aCa) 0 cF4 Fm 3 m A1 Cu
1000 56.1
CaNi2 66.7 cF24 Fd 3 m C15 Cu 2Mg
872°C CaNi3 75 hR12 R 3m … Ni 3Pu
842°C 37.8
800 Ca2Ni7 77.8 hR18 R 3m … Co 7Gd 2
CaNi5 83.3 hP6 P6/mmm D2 d CaCu 5
627°C (Ni) 100 cF4 Fm 3 m A1 Cu
600 17
(Ni)
(bCa) H. Okamoto, J. Phase Equilibria Diffusion, 28(3), 299 (2007)
443°C
400
(aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Nickel Ni
0
10 20
Ca-O
2750
1985Wri (two possibilities) 2613°C

2500 2000Zai
Ca-O
2250 L Struktur-
1750 (aCa) 0 cF4 Fm 3 m A1 Cu
CaO 50 cF8 Fm 3 m B1 NaCl
1500
CaO2 * 66.7 tI6 I4/mmm C11a CaC2
* Not shown.
1250

1000
839°C
842°C
750
(bCa)
500
443°C
(aCa)
250
0 10 20 30 40 50
Ca Atomic Percent Oxygen

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70
Weight Percent Lead
80 90 100
Ca-Pb
1400
1992Itk
1203°C 2004Car
1200
1130°C Ca-Pb
Struktur-
1000
965°C
842°C
800 (aCa) 0 cF4 Fm 3 m A1 Cu
750°C
9.7 Ca2Pb 33.3 oP12 Pnma C23 Co2Si
666°C Ca5Pb3 37.5 hP48 P63 /mc … …
638°C 63.5
651
600 624°C 68.5 CaPb 50 tP4 P4/mmm L10 AuCu
(bCa)
CaPb3 75 cP4 Pm 3 m L12 AuCu3
443°C (Pb) 100 cF4 Fm 3 m A1 Cu
400
329.4°C
327.502°C H. Okamoto, J. Phase Equilibria Diffusion, 26(6), 643-644 (2005)
326.2°C
200 (aCa)
(Pb)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Lead Pb
198
Ca Weight Percent Palladium Ca-Pd
0 10 20 30 40 50 60 70 80 90 100
1600
1555°C
Ca-Pd
1400 Struktur-
1200 L (bCa) 0 cI2 Im 3 m A2 W
1000
Ca9 Pd 10 … … … …
Ca3 Pd 25 oP16 Pnma D011 Fe3C
Ca5 Pd2 28.6 mC28 C2/c … …
842° C
800 Ca3 Pd2 40 hR45 R3 … …
CaPd 50 cP2 Pm 3 m B2 CsCl
CaPd2 66.7 cF24 Fd 3 m C15 Cu2 Mg
600 CaPd5 83.8 to 87 hP6 P6/mmm D2d CeCu5
(bCa)
443° C (Pd)
400
(aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Palladium Pd

0 10 20 30 40 50 60 70 80 90 100
Ca-Pm
1200
L2
L1 L1 + L2 1042°C
1000 Ca-Pm
Struktur-
(bPm) 890°C Composition, Pearson Space bericht
800
(bCa) (bPm) ? to 100 cI2 Im 3 m A2 W
600
(aPm) ? to 100 hP4 P6 3/mmc A3’ aLa
942, 944 (1990)
(aPm)
200 (aCa)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Promethium Pm
0 10 20 30 40 50 60
70 80 90 100
Ca-Pt
1400
Ca-Pt
1200 Struktur-
1000 975°C (bCa) 0 cI2 Im 3 m A2 W
950°C (aCa) 0 cF4 Fm 3 m A1 Cu
850°C Ca5Pt2 28.6 mC28 C2/c … Mn5C 2
842°C
800 Ca5Pt3 37.5 tI32 I4/mcm D8m W5Si3
Ca3Pt2 40 hR45 R3 … Er3Ni2
CaPt2 66.7 cF24 Fd 3 m C15 Cu2Mg
600 585°C Ca2Pt7 77.8 hP36 P63/mmc … Ce2Ni7
15
CaPt5 83.3 hP6 P6/mmm D2d CaCu 5
(bCa) (Pt)
443°C
400
(aCa)
200
945-946 (1990)
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Platinum Pt
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ca Weight Percent Plutonium Ca-Pu
0 20 30 40 50 60 70 80 90 100
1000
L1 L1 + L2
900
Ca-Pu
842°C
800
Struktur-
(bCa) + L2
L2
700
640°C
600 (aCa) 0 cF4 Fm 3 m A1 Cu
(bCa) (ePu) (ePu) 100 cI2 Im 3 m A2 W
500 (d’Pu) 100 tI2 I4/mmm A6 In
(d'Pu) 483°C
463°C
443°C (dPu) 100 cF4 Fm 3 m A1 Cu
400 (dPu) (gPu) 100 cF8 Fddd … gPu
320°C (bPu) 100 mC34 C2/m … bPu
300
(gPu)
(aPu) 100 mP16 P21/m … aPu
(aCa)
200 215°C
(bPu) K.M. Axler and D.E. Peterson, Bull. Alloy Phase Diagrams, 10(4a), 472-473
125°C (1989)
100
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Plutonium Pu

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50
60 70 80 90 100
Ca-Rb
1000
L1
900
L1 + L2 L2
839°C
842°C Ca-Rb
800
Struktur-
700
600
500 (Rb) 100 cI2 Im 3 m A2 W
443°C
300
(aCa) (aCa) + L2
200
100
38.6°C
(Rb)
39.48°C
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Rubidium Rb
0 10 20 30 40 50
60 70 80 90 100
Ca-Sb
1200
1123°C
1100
Ca-Sb
L 996°C
1000 Struktur-
900 Phase at.% Sb symbol group designation Prototype
842°C 827°C
800 (aCa) 0 cF4 Fm 3 m A1 Cu
Ca2Sb 33.3 tI12 I4/mmm … La2Sb
700
Ca5Sb3 37.5 oP32 Pnma … Yb5Sb3
hP16 P6 3/mcm D8 8 Mn 5Si3
606°C 630.755°C Ca11Sb1 0 47.6 tI84 I4/mmm … Ge1 0Ho 11
600 597°C 587°C CaSb2 66.7 mP6 P21/m … …
( bCa) (Sb) 100 hR2 R 3m A7 aAs
500
443°C
(Sb) H. Okamoto, J. Phase Equilibria, 14(4), 531-532 (1993)
400
(aCa)
300
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Antimony Sb
200
Ca Weight Percent Scandium
Ca-Sc
0 10 20 30 40 50 60 70 80 90 100
1800
L1
L1 + L2 L2
1600
1462°C 95.4
1541°C Ca-Sc
2.18 97.4 Struktur-
1400
(bSc) 1337°C Composition, Pearson Space bericht
Phase at.% Sc symbol group designation Prototype
1200 (bCa) 0 to 0.03 cI2 Im 3 m A2 W
(aSc) (aCa) 0 cF4 Fm 3 m A1 Cu
1000 (bSc) 97.4 to 100 cI2 Im 3 m A2 W
(aSc) ? to 100 hP2 P6 3/mmc A3 Mg
0.08 841°C
842°C
800 0.03 98.6
600 (bCa) 951-952 (1990)
443°C
400
(aCa)
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Scandium Sc
Weight Percent Silicon Ca-Si

0 10 20 30 40 50 60 70 80 90 100
1500
1414°C
1400
Ca-Si
1300 1280°C
L Struktur-
1257°C
1235°C
1200 1236°C Phase at.% Si symbol group designation Prototype
1100 1083°C
1028°C 1024°C
1000 Ca2Si 33.3 oP12 Pnma C23 Co2Si
937°C Ca5Si3 37.5 tI32 I4/mcm D8l Cr5B3
900 CaSi 50 oC8 Cmcm Bf CrB
842°C 880°C Ca3Si4 57.1 hP42 P63 /m … …
798°C
800 Ca14Si19 57.6 … … … …
(Si) CaSi2 66.7 hR6 R 3m C12 CaSi2
700
(bCa) (Si) 100 cF8 Fd 3 m A4 C (diamond)
600
500 (aCa)
443°C
443°C
400
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Silicon Si
0 10 20 30 40 50 60
Weight Percent Tin
70 80 90 100
Ca-Sn
1200
1135°C
1000
1000°C Ca-Sn
L Struktur-
842°C
800 780°C (bCa) 0 cI2 Im 3 m A2 W
Ca2 Sn 33.3 oP12 Pnma C23 Co2Si
615°C 630°C Ca31 Sn20 39.2 tI204 I4/mcm … Pu31Rh20
600 (bCa) 68 CaSn 50 oC8 Cmcm Bf CrB
CaSn3 75 cP4 Pm 3 m L12 AuCu3
(bSn) 100 tI4 I41/amd A5 bSn
443°C
(aCa)
(bSn) 954-955 (1990)
230°C 231. 9681°C
99.6
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Tin Sn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ca Weight Percent Strontium
Ca-Sr
0 10 20 30 40 50 60 70 80 90 100
900
842°C
L
800 Ca-Sr
769°C
738°C Struktur-
700 Phase at.% Sr symbol group designation Prototype
(bCa,bSr) 0 to 100 cI2 Im 3 m A2 W
(bCa,bSr) (aCa,aSr) 0 to 100 cF4 Fm 3 m A1 Cu
600
547°C H. Okamoto, J. Phase Equil. Diffusion, 31(5), 491 (2010)

500
443°C
400
(aCa,aSr)
300
200
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Strontium Sr
Weight Percent Terbium Ca-Tb

0 10 20 30 40 50 60 70 80 90 100
1500
L1 + L2 L2
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L1 1358°C
1290°C 89.5
Ca-Tb
(bTb) 1289°C
91.05 Struktur-
(aTb) Composition, Pearson Space bericht
(bTb) ? to 100 cI2 Im 3 m A2 W
1000 (aTb) ? to 100 hP2 P63 /mmc A3 Mg
842°C 1.04 837°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
0.5 96.7 956, 958 (1990)
(bCa)
500
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Terbium Tb
0 10 20 30
40 50 60 70 80 90 100
Ca-Ti
1300
Ca-Ti
1200
Struktur-
1100
L L + (bTi) (bTi) (bTi) 100 cI2 Im 3 m A2 W
(aTi) 100 hP2 P63/mmc A3 Mg
1000 J.L.Murray, Phase Diagrams of Binary Titanium Alloys, J.L. Murray, ed., ASM
900
882°C
L + (aTi) (aTi)
842°C
(bCa) (bCa) + (aTi)
800
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Titanium Ti
202
Ca Weight Percent Thallium
Ca-Tl
0 10 20 30 40 50 60 70 80 90 100
1200
Ca-Tl
L Phase at.% Tl symbol group designation Prototype
842°C
800 (bCa) 0 cI2 Im 3 m A2 W
742°C (aCa) Fm 3 m
700°C
0 cF4 A1 Cu
34 Ca3 Tl 25 cF16 Fm 3 m D03 BiF3
625°C
600 (bCa) Ca5 Tl2 28.6 … … … …
564°C
525°C CaTl 47 to 50 cP2 Pm 3 m B2 CsCl
16
Ca3 Tl4 57.1 … … … …
443°C Pm 3 m
(bTl)
CaTl3 75 cP4 L12 AuCu3
400
(bTl) 97.5 to 100 cI2 Im 3 m A2 W
313°C
265°C 97.5 304°C (aTl) 98 to 100 hP2 P63/mmc A3 Mg
98 230°C
200
(aCa) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(aTl)
959, 961 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Thallium Tl
Weight Percent Thulium Ca-Tm

0 10 20 30 40 50 60 70 80 90 100
1600
L1 + L2 L2
L1 1545°C
1500 1495°C
92.85 93.65
(Tm) Ca-Tm
1400 Struktur-
1300 Phase at.% Tm symbol group designation Prototype
(bCa) 0 to 0.42 cI2 Im 3 m A2 W
1200 (Tm) 93.65 to 100 hP2 P6 3/mmc A3 Mg
1100
959, 962-963 (1990)
1000
900
842°C 0.67 835°C

0.42 97.88
800
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(bCa)
700
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Thulium Tm
0 10 20 30
40 50 60 70 80 90 100
Ca-V
3000
G
2500
G+L L
Ca-V
2000 Struktur-
(V) Phase at.% V symbol group designation Prototype
G + (V)
1500
1495°C (aCa) Fm 3 m
0 cF4 A1 Cu
(V) 100 cI2 Im 3 m A2 W
L L + (V)
1000
J.F. Smith and K.J. Lee, Phase Diagrams of Binary Vanadium Alloys, J.F. Smith,
842°C
ed., ASM International, Metals Park, OH, 43-44 (1989)
(bCa) (bCa) + (V)
500
443°C
(aCa) (aCa) + (V)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Vanadium V
Ca Weight Percent Yttrium
Ca-Y
0 10 20 30 40 50 60 70 80 90 100
1600
1522°C
(bY) 1478°C
1400 L1 + L2 L2
L1
Ca-Y
1200°C Struktur-
1200
10 77 99.8 Composition, Pearson Space bericht
1000 (bCa) 0 cI2 Im 3 m A2 W
842°C
815°C (bY)
800
100 cI2 Im 3 m A2 W
99.45
(aY) 99.45 to 100 hP2 P6 3/mmc A3 Mg
600 (bCa)
519-520 (1987)
443°C
400
200 (aCa) (aY)
0
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Yttrium Y
Weight Percent Ytterbium Ca-Yb

0 10 20 30 40 50 60 70 80 90 100
900
842°C
L
Ca-Yb
810°C 819°C
800 75 Struktur-
795°C
(bCa,gYb) 0 to 100 cI2 Im 3 m A2 W
(bCa,gYb)
700 (aCa,bYb) 0 to 100 cF4 Fm 3 m A1 Cu
521-522 (1987)
600
(aCa,bYb)
500
443°C
400
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Ytterbium Yb
0 10 20 30 40
Weight Percent Zinc
50 60 70 80 90 100
Ca-Zn
900
842°C Ca-Zn
800 Struktur-
L 724°C Phase at.% Zn symbol group designation Prototype
700
704°C 695°C 690 (bCa) 0 cI2 Im 3 m A2 W
86.4 669 (aCa) 0 cF4 Fm 3 m A1 Cu
642°C
Ca3Zn 25 oC16 Cmcm E1a Re3B
76.4
Ca5Zn3 37.5 tI32 I4/mcm D8 l Cr5B 3
600
CaZn 50 oC8 Cmcm Bf CrB
(bCa) CaZn2 66.7 oI12 Imma … CeCu2
CaZn3 74 to 75 hP32 P6 3/mmc … …
500 CaZn5 83.3 to 83.9 hP6 P6/mmm D2d CaCu5
CaZn11 91.7 tI48 I4 1/amd … BaCd11
42.5 439°C
443°C
414°C
CaZn13 92.9 cF112 Fm 3 c … NaZn13
35 419.58°C
400 394°C 391°C (Zn) 100 hP2 P6 3/mmc A3 Mg
27.4
(aCa) V.P. Itkin and C.B. Alcock, Bull. Alloy Phase Diagrams, 11(4), 328-333 (1990)
300
0 10 20 30 40 50 60 70 80 90 100
Ca Atomic Percent Zinc Zn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
204
Cd
0 10 20 30
40 50 60 70 80 90 100
Cd-Ce
1000
945°C
930°C
900 875°C
845°C 835°C L Cd-Ce
800 825°C 798°C
Struktur-
700
700°C 726°C Phase at.% Ce symbol group designation Prototype
650°C (Cd) 0 hP2 P6 3/mmc A3 Mg
595°C Cd11Ce 8.3 cP36 Pm 3 m D2e BaHg 11
600 (dCe)
580 Cd17Ce2 10.5 hP38 P6 3/mmc … Ni17Th2
500 525°C Cd6Ce 14.3 cI168 Im 3 … YCd 6
Cd58Ce13 18.3 hP142 P6 3/mmc … Pu13Zn58
400 375°C Cd3Ce 25 cF16 Fm 3 m D03 BiF3
315°C
Cd2Ce 33.3 hP3 P 3 m1 C6 CdI2
321.108°C
300 CdCe 50 cP2 Pm 3 m B2 CsCl
(gCe) (dCe) ? to 100 cI2 Im 3 m A2 W
200
(gCe) ? to 100 cF4 Fm 3 m A1 Cu
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Cerium Ce
0
10 20 30 40
Cd-Cl
600
563°C
550°C L2
550
L1 Cd-Cl
520°C
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
CdCl2 65 to 66.7 hR9 R 3m … …
450
CdCl2
400
350
326°C
321.108°C
(Cd)
300
0 10 20 30 40 50 60 70
Cd Atomic Percent Chlorine
0 0.5
1.0 1.5 2.0 2.5 3.0
Cd-Co
500
(aCo) 482°C heating

0.263
Co-Cd
450
Struktur-
cooling
(aCo) 0 to ? cF4 Fm 3 m A1 Cu
400
(eCo) 0 to 0.263 hP2 P6 3/mmc A3 Mg
(eCo)
(eCo) + (Cd) U. Haschimoto, Nippon Kinzoku Gakkai-shi, 2(2), 67-77 (1938)
350
300
0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
Co Atomic Percent Cadmium
Cd Weight Percent Chromium
Cd-Cr
0 10 20 30 40 50 60 70 80 90 100
2000
L1 + L2 L2
1863°C
1800
1600 Cd-Cr
Struktur-
1200 L1 (Cr) (Cd) 0 hP2 P6 3/mmc A3 Mg
(Cr) 100 cI2 Im 3 m A2 W
1000 L1 + (Cr)
800
600
400
321.108°C
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Chromium Cr

Cd-Cs
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
600
500
L1 L1 + L2
Cd-Cs
400°C
Struktur-
321.108
300 Cd13 Cs 7.1 cF112 Fm 3 c D23 NaZn13
(Cs) 100 cI2 Im 3 m A2 W
200
L2 A.D. Pelton, Bull. Alloy Phase Diagrams, 8(6), 541-542 (1987)
(Cd)
100
28.39°C
(Cs)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Cesium Cs

0 10 20 30 40 50 60 70 80 90 100
Cd-Cu
1200
1084.87°C
1000
Cd-Cu
L
Struktur-
(Cd) 0 to 0.2 hP2 P63/mmc A3 Mg
600
e 23.1 to 24.4 hP28 P63/mmc D811 Al5Co2
563°C
47.8
52.7 549°C d 34 to 47.8 cI52 I 4 3m D82 Cu5Zn8
544°C 547°C 97.93
g 55.9 to 58.2 cF1124 F 4 3m … …
400
397°C d b 66.7 hP24 P63/mmc C36 MgNi2
7.3 23.6 34
314°C (Cu) 97.93 to 100 cF4 Fm 3 m A1 Cu
321.108°C
2.1
(Cu)
P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 11(2), 160-
200 e g b
169 (1990)
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Copper Cu
206
Cd Weight Percent Europium
Cd-Eu
0 10 20 30 40 50 60 70 80 90 100
900
822°C
800 Cd-Eu
760°C L
Struktur-
720°C
695°C
700
671°C 673 670°C Phase at.% Eu symbol group designation Prototype
652 41.5
651°C
600
Cd11Eu 8.3 tI48 I4/amd … BaCd11
Cd6Eu 14.3 cI168 Im 3 … YCd 6
Cd58Eu13 18.3 hP142 P6 3/mmc … Pu13Zn58
503°C Cd51Eu14 21.5 hP65 P6/m … Gd14Ag51
500
445°C
Cd8Eu3 27.3 … … … …
75 Cd2Eu 33.3 oI12 Imma … …
400 Cd5Eu6 54.5 cP2 Pm 3 m B2 CsCl
(Eu) 100 cI2 Im 3 m A2 W
321.108°C (Eu)
(Cd) 26-28 (1988)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Europium Eu
0 10 20
Weight Percent Iron
30 40 50 60 70 80 90 100
Cd-Fe
1800
L2
1600
1538°C
1538°C Cd-Fe
(dFe) Struktur-
1400 1394°C
1394°C
G Phase at.% Fe symbol group designation Prototype
1200 (Cd) 0 hP2 P63 /mmc A3 Mg
(gFe)
1000 (gFe) 100 cF4 Fm 3 m A1 Cu
912°C
912°C
(aFe) 100 cI2 Im 3 m A2 W
800 767°C
767°C
H. Okamoto, Phase Diagrams of Binary Iron Alloys, H. Okamoto, ed., ASM
600
L1 (aFe) International, Materials Park, OH, 87-88 (1993)
400
321°C
312.108°C
200
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Iron Fe

0 10 20 30 40 50 60 70 80 90 100
Cd-Ga
350
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
321.108°C L1 + L2
300
L1 L2
291°C
22.7 282°C 74.95
250 Cd-Ga
Struktur-
200 Phase at.% Ga symbol group designation Prototype
150
Z. Moser, J. Dutkiewics, W. Gasior, and J. Salawa, Bull. Alloy Phase Diagrams,
9(1), 691-694 (1988)
100
50
29.38°C
29.7741°C
(Cd) (Ga)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Gallium Ga
Cd Weight Percent Gadolinium
Cd-Gd
0 10 20 30 40 50 60 70 80 90 100
1400
1313°C
1235°C
1200 1170°C Cd-Gd
L Struktur-
1010°C
995°C 937°C
(bGd) (Cd) 0 hP2 P63/mmc A3 Mg
73
Cd6 Gd 14.3 cI168 Im 3 … YCd6
815°C
800 803°C Cd58 Gd1 3 18.3 hP142 P63/mmc … Pu13 Zn58
806
716°C 725°C Cd45 Gd11 19.6 cF448 F 4 3m … Sm11 Cd45
84 Cd3 Gd 25 hP8 P63/mmc D019 Ni3Sn
(aGd) bCd 2Gd 33.3 … … … …
600
aCd 2Gd 33.3 hP3 P 3 m1 C6 CdI2
CdGd 50 cP2 Pm 3 m B2 CsCl
(bGd) ? to 100 cI2 Im 3 m A2 W
400
(aGd) ? to 100 hP2 P63/mmc A3 Mg
316°C
321.108°C
2.5
(Cd) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 9(1),
200 29-31 (1988)
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Gadolinium Gd
0 10 20
30 40 50 60 70 80 90 100
Cd-Ge
1000
938. 3°C
900
L Cd-Ge
800
Struktur-
700
600
500
400
179 (1986)
321.108°C 320.02°C
300 0.23
200
(Cd) (Ge)
100
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Germanium Ge

0 10 20 30 40 50 60 70 80 90 100
Cd-Hg
800
768°C B.P.
700
G Cd-Hg
Struktur-
600
L+G Composition, Pearson Space bericht
500
(Cd) 0 to 25 hP2 P63/mmc A3 Mg
w 29 to 96 tI2 I4/mmm A6 In
400
357°C B.P. w’ 33 to 42 tI6 I4/mmm C11b MoSi2
321.108
300 w” 58 to 71 tI6 I4/mmm C11b MoSi2
L
(Hg) 97 to 100 hR1 R 3m A10 aHg
200 188
C. Guminsky and L.A. Zabdyr, J. Phase Equilibria, 13(4), 401-410 (1992)
100
(Cd) see also
w
0 -18°C -12°C H. Okamoto, J. Phase Equilibria, 22(6), 689 (2001)
-34°C
-38.8290°C
-100
w' w" (Hg)
-200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Mercury Hg
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
208
Cd
55
60 65 70
Cd-I
1100
1000
900 Cd-I
L2 Struktur-
800 Phase at.% I symbol group designation Prototype
CdI2 66.7 … … … …
700
L1 + L2 L.E. Topol and A.L. Landis, J. Am. Chem. Soc., 82, 6291 (1960)
600
500
400 383°C 388°C
L1 + CdI2
300
50 55 60 65 70
0 10 20 30
40 50 60 70 80 90 100
Cd-In
400
350
321.108°C Cd-In
300
L Struktur-
(Cd) 0 to 1.4 hP2 P6 3/mmc A3 Mg
Cd3 In 21.8 to 25.8 cP4 Pm 3 m L12 AuCu3
200 196°C
21.8 45 aK 80.8 to 96 cF4 Fm 3 m A1 Cu
Cd3In (In), aT 94 to 100 tI2 I4/mmm A6 In
148°C 156.634°C
150
127.7°C 74.3
1.4 126°C 80.8 J. Dutkiewicz, L. Zabdyr, W. Zakulski, Z. Moser, J. Salawa, P.J. Horrocks, F.H.
25.8
Hayes, and M.H. Rand, Phase Diagrams of Indium Alloys and Their
100 aK aT
Engineering Applications, C.E.T. White and H. Okamoto, ed., ASM
(Cd) International, Materials Park, OH, 61-68 (1992)
50
(In)
94
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Indium In
0 10
20 30 40 50 60 70 80 90 100
Cd-K
600
L1 L1 + L2 L2
500 487°C Cd-K --`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
468°C
15
Struktur-
94
400
(Cd) 0 hP2 P63 /mmc A3 Mg
Cd13K 7.1 cF112 Fm 3 c D23 NaZn13
321.108 321°C
(K) 100 cI2 Im 3 m A2 W
300
200
(Cd)
100
63.7°C 63.71
(K)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Potassium K
Cd
0 10 20 30
40 50 60 70 80 90 100
Cd-La
1100
1000
953°C Cd-La
946°C
L Struktur-
918°C
900 874°C
42 865°C
24.2
800 (Cd) 0 hP2 P6 3/mmc A3 Mg
Cd11 La 8.3 cP36 Pm 3 m D2e BaHg11
700 688°C Cd17La2 11.8 hP38 P6 3/mmc … Ni17Th2
625°C
642°C
(gLa)
Cd58La1 3 18.3 hP142 P6 3/mmc … Pu13Zn58
77
600 4.1 Cd2 La 33.3 hP3 P 3 m1 C6 CdI 2
CdLa 50 cP2 Pm 3 m B2 CsCl
(bLa)
500 (gLa) 79 to100 cI2 Im 3 m A2 W
451°C 86.5 97.5 (bLa) 97.5 to 100 cF4 Fm 3 m A1 Cu
400 (aLa) 97 to 100 hP4 P6 3/mmc A3’ aLa
321.108°C
300 (aLa) 310°C K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 9(1),
32-34 (1988)
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Lanthanum La
0
10 20 30 40 50 70 100
Cd-Li
600
550 549°C
50
Cd-Li
500 507°C
L Struktur-
450
400 (Cd) 0 to 30 hP2 P63 /mmc A3 Mg
370°C
357°C
Cd3 Li 20 to 29 hP2 P63 /mmc A3 Mg
25
350 CdLi 38 to 78 cF16 Fd 3 m B32 NaTl
321.108 (Cd) Fm 3 m
CdLi CdLi3 65 to 78 cF4 A1 Cu
300
272°C (bLi) 82 to 100 cI2 Im 3 m A2 W
265
Cd3Li 75
250 255
200
CdLi3 180.6°C
?
150 (bLi)
100
50
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Lithium Li
0
10 20 30 40 50 60 70 80 90 100
Cd-Mg
700
650°C
600
Cd-Mg
L Struktur-
500
(Cd,Mg) 0 to 100 hP2 P63 /mmc A3 Mg
400 Cd3 Mg 25 to 32 hP8 P63 /mmc D019 Ni3Sn
CdMg 38 to 60 oP4 Pmma B19 AuCd
CdMg3 63 to 82 hP8 P63 /mmc D019 Ni3Sn
321.108 (Cd,Mg)
300
253°C Z. Moser, W. Gasior, J. Wypartowicz, and L. Zabdyr, Bull. Alloy Phase
Diagrams, 5(1), 23-30 (1984)
200
100
CdMg CdMg3
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Magnesium Mg
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
210
Cd
0 0.1
0.2 0.3 0.4
Cd-Mn
700
600
L Cd-Mn
Struktur-
500
(Cd) 0 to 0.049 hP2 P6 3/mmc A3 Mg
L + (aMn) (aMn) ? to 100 cI58 I 4 3m A12 aMn
J. Dutkiewicz, J. Phase Equilibria, 14(1), 84-85 (1993)

400
0.06 320.1°C
321.108°C
0.049
300
(Cd) (Cd) + (aMn)
200
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Cd Atomic Percent Manganese
0 10 20
30 40 50 60 70 80 90 100
Cd-Mo
4680°C
4500
G
4000
Cd-Mo
3500 G + L2 L2
Struktur-
3000
2623°C
2623°C
2500 (Mo) 100 cI2 Im 3 m A2 W
G + (Mo) (Mo)
1500 997-998 (1990)
1000
767°C
500 L1 L1 + (Mo)
321.108°C
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Molybdenum Mo
0
10 20 30 40 50 60 70 80 90 100
Cd-Na
450
400
384°C L Cd-Na
364°C
348°C Struktur-
350
321.108°C Phase at.% Na symbol group designation Prototype
300 288°C (Cd) 0 hP2 P6 3/mmc A3 Mg
5 Cd11Na2 15.4 cP39 Pm 3 D8c Mg2Zn11
Cd2Na 33.3 cF1192 … … …
250
200 A.D. Pelton, Bull. Alloy Phase Diagrams, 9(1), 41-46 (1988)
(Cd)
150
100 94.5°C
97.8°C
99.4
(bNa)
50
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Sodium Na

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cd
0 10 20
30 40 50 60
Cd-Nd
L
530°C
2.6
500 Cd-Nd
Struktur-
400 (Cd) 0 hP2 P6 3/mmc A3 Mg
Cd11Nd 8.3 cP36 Pm 3 m D2e BaHg 11
Cd6Nd 14.3 cI168 Im 3 … YCd 6
321.108 Cd58Nd13 18.3 hP142 P6 3/mmc … Pu13Zn58
300 Cd45Nd11 19.6 cF448 F 4 3m … Cd45Sm11
Cd3Nd 25 cF16 Fm 3 m D03 BiF3
(Cd)
Cd2Nd 33.3 hP3 P 3 m1 C6 CdI2
CdNd 50 cP2 Pm 3 m B2 CsCl
200
128-130 (1988)
100
0 10 20 30 40 50 60
Cd Atomic Percent Neodymium
0 10
20 30 40 50 60 70 80 90 100
Cd-Ni
1600
1455 °C
1400
Cd-Ni
Struktur-
1200
(Ni) Cd5Ni 12 to 19.5 cP52 P 4 3m D83 Al4 Cu9
1000
CdNi 47.3 to 50 cF112 Fd 3 m E93 Fe3 W3 C
800
690 °C F.A. Shunk and P. Nash, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed.,
ASM International, Materials Park, OH, 59-61 (1991)
600
495 °C
400
318 °C
321.108 °C
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Nickel Ni
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 5 10
Weight Percent Neptunium
15 20 25
Cd-Np
650
600
L Cd-Np
Struktur-
500
485°C Cd11Np 8.3 cP36 Pm 3 m D2e BaHg11
Cd6Np 14.3 … … … …
450
P. Chiotti, V.V. Akhachinskij, I. Ansara, and M.H. Rand, Bull. Alloy Phase
Diagrams, 2(4), 485-488 (1981)
400
350
321.108°C
(Cd)
300
0 2 4 6 8 10 12 14 16
Cd Atomic Percent Neptunium
212
Cd
0
5 10 15 20 25
Cd-O
700
600 Cd-O
Struktur-
500 L Phase at.% O symbol group designation Prototype
400
CdO 49.8 to 50 cF8 Fm 3 m B1 NaCl
CdO2 66.7 cP12 Pa 3 C2 FeS2 (pyrite)
321°C
321.108
300 49.9 H.A. Wriedt, Bull. Alloy Phase Diagrams, 8(2), 140-147 (1987)
200
(Cd)
100
0
0 10 20 30 40 50 60 70
Cd Atomic Percent Oxygen
0 10
20 30 40 50 60 70 80 90 100
Cd-P
800 L1 L1 + L2 782°C
L2
748°C
Cd-P
740°C
728°C 51.5 734
Struktur-
600 (Cd) 0 hP2 P6 3/mmc A3 Mg
Cd3P2 40 tP40 P4 2/nmc D59 P2Zn 3
Cd6P7 53.8 c*52 … … …
Cd7P10 58.8 oF136 Fdd2 … …
420°C
bCdP2 66.7 tP24 P432 12 … …
400
aCdP2 66.7 oP12 Pna21 … …
318°C
321.108 CdP 4 80 mP10 P21/c … …
(aP) 100 c** … … …
200
(Cd) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1008-1009 (1990)
(aP) 44.14°C
0
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cd Atomic Percent Phosphorus P
0 10 20 30 40
Weight Percent Lead
50 60 70 80 90 100
Cd-Pb
350
327.502°C
321.108°C
L Cd-Pb
300 Struktur-
248°C
250 (Pb) (Pb) 94.1 to 100 cF4 Fm 3 m A1 Cu
71.9 94.1
J. Dutkiewicz, Z. Moser, and W. Zakulski, Bull. Alloy Phase Diagrams, 9(6),

(Cd) 694-701 (1988)
200
See also
W. Zakulski and Z. Moser, J. Phase Equilibria, 16(3), 239-242 (1995)

150
100
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Lead Pb
Cd
0 10 20 30
40 50 60 70 80 90 100
Cd-Pd
800
Cd-Pd
Struktur-
700 L
600
b g 17 to 19 cP52 P 4 3m D83 Al4Cu9
g1 20 to 23 c** … … …
500 g’ 26 c**
b 37 to 45 cP2 Pm 3 m B2 CsCl
b1 45 to 67 tP4 P4/mmm L10 AuCu
400 b1 (Pd)
(Pd) 74 to 100 cF4 Fm 3 m A1 Cu
320.4°C 325°C
321.108°C
300 0.3 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
1011-1012 (1990)
200 g g1 g'
(Cd)
100
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Palladium Pd
0 10 20 30
40 50 60 70 80 90 100
Cd-Pm
1200
Cd-Pm
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1050°C
L 1042°C Struktur-
1000
900°C
890°C
800 Cd11 Pm 8.3 … … … …
(bPm)
Cd6 Pm 14.3 … … … …
Cd58 Pm13 18.3 … … … …
600
Cd45 Pm11 19.6 … … … …
Cd3 Pm 25 … … … …
Cd2 Pm 33.3 … … … …
CdPm 50 … … … …
400 (aPm) (bPm) ? to 100 cI2 Im 3 m A2 W
321.108°C (aPm) ? to 100 hP4 P63/mmc A3’ aLa
1011, 1013 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Promethium Pm
0 10 20
30 40 50 60
Cd-Pr
700
L Cd-Pr
Struktur-
600
570°C
3.5 Phase at.% Pr symbol group designation Prototype
Cd11Pr 8.3 cP36 Pm 3 m D2e BaHg11
500
Cd6Pr 14.3 cI168 Im 3 … YCd 6
Cd58Pr13 18.3 hP142 P6 3/mmc … Pu13Zn58
Cd45Pr11 19.6 cF448 F 4 3m … Cd45Sm 11
400 Cd3Pr 25 cF16 Fm 3 m D03 BiF 3
Cd2Pr 33.3 hP3 P 3 m1 C6 CdI 2
CdPr 50 cP2 Pm 3 m B2 CsCl
321.108°C
130-132 (1988)
(Cd)
200
0 10 20 30 40 50 60
Cd Atomic Percent Preseodymium
214
Cd
0 10 20 30 40
50 60 70 80 90 100
Cd-Pt
900
800 L
770°C Cd-Pt
730°C Struktur-
710°C
670°C (Pt)
600
g 14.5 to 17 cI392 I 4 3m … …
g1 23.5 to 24.5 … … … …
500 a' g2 26 to 28 … … … …
Cd2Pt 31 to 38 … … … …
a1 ' a1’ 49 to 59 tP4 P4/mmm L10 AuCu
400 g g1 g2
a’ ~75 cP4 Pm 3 m L12 AuCu3
314°C Fm 3 m
321.108°C
300
(Pt) 74 to 100 cF4 A1 Cu
H. Nowotny, E.Bauer, A. Stampfl, and H. Bittener, Monatsh. Chem., 83, 221-

200 236 (1952)
(Cd)
100
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Platinum Pt
0 10 20 30 40 50
60 70 80 90 100
Cd-Pu
1200 Cd-Pu
L1 L2 Struktur-
L1 + L2
1000
945°C Phase at.% Pu symbol group designation Prototype
910°C (Cd) 0 hP2 P63/mmc A3 Mg
40
800°C
Cd11 Pu 8.3 cP36 Pm 3 m D2e BaHg11
800
730°C
Cd6 Pu 14.3 cI168 Im 3 … YCd6
Cd4 Pu 20 … … … …
640°C Cd2 Pu 33.3 … … … …
600 (ePu) 100 cI2 Im 3 m A2 W
(ePu)
483°C
463°C (dPu) Fm 3 m
410°C (d'Pu) 100 cF4 A1 Cu
400
320°C
(dPu) (gPu) 100 oF8 Fddd … gPu
321.108°C 320°C
(gPu)
200
215°C (aPu) 100 mP16 P21/m … aPu
(bPu)
(Cd) 125°C
(aPu)
Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH, ,
0
0 10 20 30 40 50 60 70 80 90 100 1017-1018 (1990)
Cd Atomic Percent Plutonium Pu
0 10 20
30 40 50 60 70 80 90 100
Cd-Rb
700
L2
600 L1 Cd-Rb
L 1 + L2
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
500°C
500
Cd13 Rb 7.1 cF112 Fm 3 c D23 NaZn13
400
(Rb) 100 cI2 Im 3 m A2 W
321.108
300 A.D. Pelton, Bull. Alloy Phase Diagrams, 8(6), 546-547 (1987)
200
(Cd)
100
39.48°C
(Rb)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Rubidium Rb
Cd
0 10
20 30 40 50 60 70 80 90 100
Cd-S
1600
1400
L1 1405°C
L1 + L2
Cd-S
1200 Struktur-
1000
59.5 99.9
CdS 50 hP4 P63mc B4 ZnS (wurtzite)
800 (bS) 100 mP48 P21 /a … …
600 L2
R.C. Sharma and Y.A. Chang, J. Phase Equilibria, 17(2), 140-145 (1996)
400
321°C
321.108°C
200
(Cd) (bS)
115.22°C
95.5°C
(aS)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Sulfur S
0 10 20 30
40 50 60 70 80 90 100
Cd-Sb
650
630.755°C
600
Cd-Sb
Struktur-
550
L
500 (Cd) 0 hP2 P63 /mmc A3 Mg
456°C
CdSb 50 to 51 oP16 Pbca Be CdSb
450 445°C (Sb) 100 hR2 R 3m A7 aAs
57
1020, 1022-1023 (1990)
350
321.108°C
300
(Sb)
290°C
7
250
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Antimony Sb
0 10
20 30 40 50 60 70 80 90 100
Cd-Sc
1600
1541°C
1400
L (bSc) 1337°C Cd-Sc
1255°C
Struktur-
1200 1150°C
CdSc
(aSc)
1000 (Cd) 0 hP2 P6 3/mmc A3 Mg
Cd7Sc 12.5 oC32 Cmcm … …
Cd3Sc 25 hP8 P6 3/mmc D019 Ni 3Sn
800 760°C
CdSc 50 to ? cP2 Pm 3 m B2 CsCl
600 (aSc) ? to 100 hP2 P6 3/mmc A3 Mg
415°C
321.108°C 315°C
200
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Scandium Sc
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
216
Cd
0 10 20
30 40 50 60 70 80 90 100
Cd-Se
1400
1300 1264°C
L1
1200 L1 + L2
Cd-Se
1100 Struktur-
67.5 Phase at.% Se symbol group designation Prototype
900 (Cd) 0 hP2 P6 3/mmc A3 Mg
CdSe 50 hP4 P6 3mc B4 ZnS (wurtzite)
800
(Se) 100 hP3 P3121 A8 gSe
700
L2 R.C. Sharma and Y.A. Chang, J. Phase Equilibria, 17(5), 425-431 (1996)
600
500
400
321.108°C 321°C
300
(Cd) 221°C
200
(Se)
100
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Selenium Se

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10
20 30 40 50 60 70 80 90100
Cd-Si
1400 1414°C
Cd-Si
L
1200 Struktur-
1000
800
536 (1985)
600
400
320°C
321.108°C
200
(Cd) (Si)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Silicon Si
0 10 20 30
40 50 60 70 80 90 100
Cd-Sm
1200
1100
1074°C
(gSm)
1023°C Cd-Sm
1000 L
Struktur-
910°C 922° C Composition, Pearson Space bericht
900
38
796°C (bSm) (Cd) 0 hP2 P6 3/mmc A3 Mg
800 780°C
742 25 Cd11Sm 8.3 cP36 Pm 3 m D2e BaHg11
728°C 734°C
700
Cd6Sm 14.3 cI168 Im 3 … YCd 6
Cd58Sm 13 18.3 hP142 P6 3/mmc … Pu13Zn58
600 Cd45Sm 11 19.6 cF448 F 4 3m … Sm11Cd 45
Cd2Sm 33.3 hP3 P 3 m1 C6 CdI2
500 CdSm 50 cP2 Pm 3 m B2 CsCl
430°C
(aSm)
400 (bSm) 100 hP2 P6 3/mmc A3 Mg
321.108°C (aSm) 100 hR3 R 3m … aSm
300
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
133-135 (1988)
Cd Atomic Percent Samarium Sm
Cd
0 10 20 30
Weight Percent Tin
40 50 60 70 80 90 100
Cd-Sn
350
321.108°C
300
L Cd-Sn
Struktur-
250
231. 9681°C
223°C Phase at.% Sn symbol group designation Prototype
96
200
(Cd) 0 to 0.24 hP2 P63 /mmc A3 Mg
176°C
b 94.1 to 99 hP2 P63 /mmc A3 Mg
0.24 66.55 94.1 b (bSn) 98.8 to 100 tI4 I41 /amd A5 bSn
150 (aSn) ? to 100 cF8 Fd 3 m A4 C (diamond)
133°C 94.7
98.8
J. Dutkiewicz, L. Zabdyr, Z. Moser, and J. Salawa, Bull. Alloy Phase Diagrams,
100 10(3), 223-229 (1989)
(Cd) (bSn)
50
13°C
(aSn)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Tin Sn
0 10 20
30 40 50 60 70 80 90 100
Cd-Sr
800
769°C
730°C
Cd-Sr
629°C
L
Struktur-
600 600°C 597°C
23.5
580°C
(bSr) Composition, Pearson Space bericht
531°C 547°C Phase at.% Sr symbol group designation Prototype
Cd11Sr 8.3 tI48 I4 1/amd … …
430°C
Cd6Sr 14.3 … … … …
400 384°C Cd9Sr2 18.2 … … … …
80
321°C
Cd2Sr 33.3 oI12 Imma … …
321.108 CdSr 50 cP2 Pm 3 m B2 CsCl
Cd3Sr5 62.5 tI32 I4/mcm D8 l Cr5B 3
200
(aSr)
1030-1031 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Strontium Sr
0 10 20 30
40 50 60 70 80 90 100
Cd-Te
1200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1098°C
1100 Cd-Te
Struktur-
L
900 (Cd) 0 hP2 P6 3/mmc A3 Mg
CdTe 50 hP4 P6 3mc B4 ZnS (wurtzite)
800 (Te) 100 hP3 P3121 A8 gSe
700 R.C. Sharma and Y.A. Chang, Bull. Alloy Phase Diagrams, 10(4), 334-339
(1989)
600
500
446.2°C 449.57°C
98.61
400
321°C
321.108°C
300 (Te)
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Tellurium Te
218
Cd
0 10 20 30 40
50 60 70 80 90 100
Cd-Th
1800
1755°C
1600
(bTh)
Cd-Th
1400 L 1360°C Struktur-
1200 Phase at.% Th symbol group designation Prototype
995°C
1000
930°C
Cd11 Th 8.3 cP36 Pm 3 m D2e BaHg11
895°C 910°C
53.6 Cd5 Th 16.7 hP36 P63 /mmc … EuMg5
800
740°C
780°C Cd23 Th6 20.7 cF116 Fm 3 m D84 Cr2 3C6
Cd3 Th 25 hP8 P63 /mmc D019 Ni3 Sn
600 565°C
Cd2 Th 33.3 hP3 P6/mmm C32 AlB2
CdTh 50 oP24 Pma2 C46 AuTe2 (krennerite)
(aTh) (bTh) 100 cI2 Im 3 m A2 W
400
321.108°C
320°C (aTh) 100 cF4 Fm 3 m A1 Cu
200
J. Dutkiewicz, J. Phase Equilibria, 14(1), 86-89 (1993)
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Thorium Th
0 10
20 30 40 50 60 70 80 90 100
Cd-Ti
1800
1670°C
L
1600 Cd-Ti
Struktur-
1200
CdTi 50 tP4 P4/nmm B11 gCuTi
(bTi)
CdTi2 66.7 tI6 I4/mmm C11b MoSi2
1000 (bTi) 70 to 100 cI2 Im 3 m A2 W
(aTi) 93.5 to 100 hP2 P63 /mmc A3 Mg
850°C 882°C
800 785°C
J.L. Murray, Bull. Alloy Phase Diagrams, 4(4), 399-401 (1983)
(aTi)
620°C
600
L
400
321.108°C
(Cd)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Titanium Ti
0 10 20 30 40
50 60 70 80 90 100
Cd-Tl
350
321.108°C
304°C
Cd-Tl
300
L Struktur-
250
(bTl) 95.5 to 100 cI2 Im 3 m A2 W
230°C (aTl) 97.5 to 100 hP2 P63/mmc A3 Mg
(bTl)
203.5°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
200 73 95.5
1037-1038 (1990)
165°C
97
150
(aTl)
(Cd)
100
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Thallium Tl

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cd
0 10 20 30 40 50
60 70 80 90 100
Cd-U
1200
L
1135°C
1000
Cd-U
(gU) Struktur-
800
776°C (Cd) 0 hP2 P63/mmc A3 Mg
(bU)
Cd11U 8.3 cP36 Pm 3 m D2 e BaHg11
668° C
(gU) 100 cI2 Im 3 m A2 W
600
L (aU) (bU) 100 tP30 P42/mnm Ab bU
1.196
400
320.6°C
P. Chiotti, Bull. Alloy Phase Diagrams, 1(2), 97-99 (1980)
321.108°C
200
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Uranium U
0 10
20 30 40 50 60 70 80 90 100
Cd-V
3600
3409°C
3200 G
Cd-V
2800
L2
Struktur-
G + L2
2400
2000
1910°C
(V) 100 cI2 Im 3m A2 W
1600 J.F. Smith, Phase Diagrams of Binary Vanadium Alloys, J.F. Smith, ed., ASM
G + (V) (V)
1200
800
767°C
L1 L1 + (V)
400
321.108°C
(Cd) (Cd) + (V)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Vanadium V
0 10 20
30 40 50 60 70 80 90 100
Cd-Y
1600
1522°C
1478°C
1400
Cd-Y
(bY) Struktur-
L (aY) Composition, Pearson Space bericht
1015°C
1000 31
Cd6Y 14.3 cI168 Im 3 … YCd6
Cd58Y13 18.3 hP142 P63/mmc … Pu13Zn58
20.5 810°C Cd45Y11 19.6 cF448 F 4 3m … Sm11Cd45
800 760°C Cd3Y 25 oC16 Cmcm … Cd3Er
710°C
12 Cd2Y 33.3 hP3 P 3 m1 C6 CdI2
600 CdY 50 cP2 Pm 3 m B2 CsCl
(bY) ? to 100 cI2 Im 3 m A2 W
400 (aY) ? to 100 hP2 P63/mmc A3 Mg
321.108°C 321°C
200 139-141 (1988)
(Cd)
0
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Yttrium Y

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Cd
0 10 20 30 40
50 60 70 80 90 100
Cd-Yb
900
(gYb) 819°C Cd-Yb

800 796°C
795° C Struktur-
755°C
bCd2Yb Composition, Pearson Space bericht
L Phase at.% Yb symbol group designation Prototype
703°C
700 695°C 680°C (Cd) 0 hP2 P63/mmc A3 Mg
655°C 654°C 38.8
636°C 648°C Cd6 Yb 14.3 cI168 Im 3 … YCd6
614°C
600
627°C Cd5.7Yb 14.9 … … … …
Cd51 Yb1 4 21.5 hP65 P6/m … Ag51 Gd1 4
(bYb) Cd8 Yb3 27.3 … … … …
500 bCd 2Yb 33.3 … … … …
aCd 2Yb 33.3 hP12 P63/mmc C14 MgZn2
77.7
CdYb 50 cP2 Pm 3 m B2 CsCl
400 (gYb) Im 3 m
96.7 to 100 cI2 A2 W
(bYb) 98.6 to 100 cF4 Fm 3 m A1 Cu
321.108°C 317°C
300
(Cd) 141-143 (1988)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Ytterbium Yb
0 10 20
Weight Percent Zinc
30 40 50 60 70 80 90 100
Cd-Zn
450
419. 58°C
400 Cd-Zn
Struktur-
350 (Cd) 0 to 4.35 hP2 P6 3/mmc A3 Mg
(Zn) 98.54 to 100 hP2 P6 3/mmc A3 Mg
321.108
J. Dutkiewicz and W. Zakluski, Bull. Alloy Phase Diagrams, 5(1), 30-36 (1984)
300
See also
266°C
4.35 26.6 98.75
250
(Cd) (Zn)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Zinc Zn

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Cd-Zr
1200
(bZr)
1000 Cd-Zr
905°C 85
Struktur-
863°C
800 (aZr) (Cd) 0 hP2 P6 3/mmc A3 Mg
Cd3Zr 25 tP4 P4/mmm L10 AuCu
Cd2Zr 33.3 … … … …
CdZr 50 tP4 P4/nmm B11 gCuTi
600
L CdZr 2 66.7 tI6 I4/mmm C11 b MoSi2
L+? (bZr) ? to 100 cI2 Im 3 m A2 W
452°C (aZr) 82.5 to 100 hP2 P6 3/mmc A3 Mg
400 L + Cd3Zr Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
1047-1048 (1990)
200
0 10 20 30 40 50 60 70 80 90 100
Cd Atomic Percent Zirconium Zr
Ce
0 10
20 30 40 50 60 70 80 90 100
Ce-Cl
1200
Ce-Cl
1000
L1 + L2 L2 Struktur-
812°C
800
798°C
777°C (dCe) 0 to ? cI2 Im 3 m A2 W
(dCe) 725°C 73
726°C (gCe) 0 to ? cF4 Fm 3 m A1 Cu
600 CeCl3 75 hP8 P63/m … …
(gCe)
1047, 1049 (1990)
200
61°C
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Chlorine Cl
0 10
20 30 40 50 60 70 80 90 100
Ce-Co
1600
1495°C
1400
Ce-Co
Struktur-
1220°C
1200
1204°C Phase at.% Co symbol group designation Prototype
L 1130°C (dCe) Im 3 m
1103°C
1134 0 cI2 A2 W
1050°C (gCe) Fm 3 m
1036°C 0 cF4 A1 Cu
1000 Ce24 Co11 31.4 hP70 P63/mc … …
CeCo2 66.7 cF24 Fd 3 m C15 Cu2 Mg
CeCo3 75 hR12 R 3m … …
800
798°C (dCe) (aCo) Ce2Co7 77.8 hP36 P63/mmc … …
726°C
Ce5Co19 79.2 hR24 R 3m … …
600 CeCo5 83.3 hP6 P6/mmm D2d CaCu5
600°C
bCe2Co 17 89.5 hP38 P63/mmc … Ni17 Th2
424°C
446°C 443°C aCe2Co 17 89.5 hR19 R 3m … Th2 Zn17
34 422°C
400 24 (aCo) 100 cF4 Fm 3 m A1 Cu
(gCe) (eCo) (eCo) 100 hP2 P63/mmc A3 Mg
200
0 10 20 30 40 50 60 70 80 90 100 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
Ce Atomic Percent Cobalt Co Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1047, 1050 (1990)
0 10
20 30 40 50 60 70 80 90 100
Ce-Cr
2400
2200 L2
L1 + L2
2000
L1 1863°C Ce-Cr
1790°C
1800
Struktur-
1400 (dCe) 0 to ? cI2 Im 3 m A2 W
(gCe) 0 to ? cF4 Fm 3 m A1 Cu
1200
(Cr) (bCe) 0 hP4 P6 3/mmc A3’ aLa
1000 (Cr) ? to 100 cI2 Im 3 m A2 W
800 785°C
798°C
726°C
A. Palenzona and S. Cirafici, Bull. Alloy Phase Diagrams, 11(5), 488-491
(dCe) 715°C
(1990)
600
400 (gCe)
200
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Chromium Cr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
222
Ce
0 10
20 30 40 50 60 70 80 90 100
Ce-Cu
1200
1100
1084.87 °C Ce-Cu
Struktur-
L 938 °C Phase at.% Cu symbol group designation Prototype
900 892°C (dCe) 0 cI2 Im 3 m A2 W
91.2
817 °C 74.3
(dCe) 799°C CeCu 50 oP8 Pnma B27 FeB
800 784
798 °C 73.2 CeCu2 66.7 oI12 Imma … …
726 °C 73.7 790°C
700 4.2 CeCu4 80 oP20 Pnnm … …
CeCu5 83.3 hP6 P6/mmm D2d CaCu5
CeCu6 85.7 oP28 Pnma … …
600 (Cu)
515 °C
500 39.4 W. Zhuang, Z.Y. Giao, S. Wei, and J. Shen, J. Phase Equilibria, 17(6), 508-521
427 °C (1996)
400 27.0
(gCe)
300
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Copper Cu
0 10 20 30
40 50 60 70 80 90 100
Ce-Dy
1412°C
1400 1381°C
L Ce-Dy
1200
Struktur-
1000
(dCe, bDy) 0 to 100 cI2 Im 3 m A2 W
? (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(dCe,bDy)
800
798°C (bCe) 0 to ? hP4 P6 3/mmc A3’ aLa
726°C
(aCe) 0 to ? cF4 Fm 3 m A1 Cu
600 d 50 to 62.5 hR3 R 3m … aSm
(aDy) ? to 100 hP2 P6 3/mmc A3 Mg
(gCe)
400
(aDy) W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
(bCe) d
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Dysprosium Dy
0 10 20 30
40 50 60 70 80 90 100
Ce-Er
1600
1529°C
1400
L Ce-Er
1200
Struktur-
1000 (dCe) 0 to ? cI2 Im 3 m A2 W
800
? (bCe) 0 to ? hP4 P63/mmc A3’ aLa
798°C (dCe)
726°C d 40 to 50 hR3 R 3m … aSm
(Er) ? to 100 hP2 P63/mmc A3 Mg
600
(gCe)
d 1055-1056 (1990)
(bCe) (Er)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Erbium Er

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ce Weight Percent Europium
Ce-Eu
0 10 20 30 40 50 60 70 80 90 100
1200
L2
1000 Ce-Eu
L1 L1 + L2
Struktur-
822°C Phase at.% Eu symbol group designation Prototype
800
798°C
(dCe) (dCe) 0 to ? cI2 Im 3 m A2 W
726°C
600 (bCe) 0 to ? hP4 P6 3/mmc A3’ aLa
(Eu) 100 cI2 Im 3 m A2 W
400 (gCe) K.A. Gschneidner, Jr. and F.W. Calderwood, Bull. Alloy Phase Diagrams, 3(2),
183-185 (1982)
(Eu)
200
61°C
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Europium Eu
0 10
Weight Percent Iron
20 30 40 50 60 70 80 90 100
Ce-Fe
1600
(dFe) 1538°C
1399°C
1400 1394°C Ce-Fe
90.6
Struktur-
1200 (gFe) Phase at.% Fe symbol group designation Prototype
1063°C (dCe) 0 cI2 Im 3 m A2 W
59
1000
925°C
919°C
46.4
912°C
(bCe) 0 hP4 P63 /mmc A3¢ aLa
(dCe)
800
798°C
CeFe2 66.7 cF24 Fd 3 m C15 Cu2Mg
726°C
726°C
4.2 bCe2 Fe17 89.5 hR19 R 3m … Th2Zn17
600
592°C aCe2 Fe17 89.5 hP38 P63 /mmc … Ni17Th2
16.4
400 (aFe) (gFe) 100 cF4 Fm 3 m A1 Cu
(gCe) (aFe) 100 cI2 Im 3 m A2 W
200
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Iron Fe
0 10
20 30 40 50 60 70 80 90 100
Ce-Ga
1600
1460°C
Ce-Ga
1400
Struktur-
L
1000 960°C
(bCe) 0 hP4 P63/mmc A3¢ aLa
850°C
(dCe) Ce3 Ga 25 cP4 Pm 3 m L12 AuCu3
800
798°C Ce3 Ga2 40 tP20 P42/mnm … …
726°C
637°C CeGa 50 oC8 Cmcm Bf CrB
CeGa2
600 557°C CeGa2 66.7 to ? hP3 P6/mmm C32 AlB2
477°C bCeGa6 85.7 … … … …
18
aCeGa6 85.7 tP14 P4/nbm … …
400
(gCe)
(bCe) (Ga) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
61°C 29°C
29.7741°C 1060-1061 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Gallium Ga
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
224
Ce Weight Percent Gadolinium
Ce-Gd
0 10 20 30 40 50 60 70 80 90 100
1400
1313°C
1235°C
1200 L Ce-Gd
Struktur-
1000
(dCe,bGd) (dCe,bGd) 0 to 100 cI2 Im 3 m A2 W
? (gCe) 0 to ? cF4 Fm 3 m A1 Cu
800
798°C
726°C
720°C (bCe) 0 to ? hP4 P63/mmc A3’ aLa
8 700°C d 65 to 73 hR3 R 3m … aSm
600 (aGd) ? to 100 hP2 P63/mmc A3 Mg
(gCe)
400
185-187 (1982)
(bCe) d (aGd)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Gadolinium Gd
0 10
20 30 40 50 60 70 80 90 100
Ce-Ge
1800
Ce-Ge
1600 Struktur-
1500°C 1513°C
L 1433°C
1400
1345°C 1340°C
1293°C 51 (dCe) 0 cI2 Im 3 m A2 W
1200 (gCe) 0 cF4 Fm 3 m A1 Cu
(bCe) 0 hP4 P63/mmc A3¢ aLa
1000 Ce3Ge 25 … … … …
938.3°C
Ce5Ge3 37.5 hP16 P63/mcm D88 Mn5 Si3
(dCe) 810°C
800 790°C
84
Ce4Ge3 42.9 cI28 I 4 3d D73 Th3P4
798°C 15
726°C 670°C Ce5Ge4 44.4 oP* Pnma … …
600
11 CeGe 50 to 50.5 oP8 Pnma B27 FeB
560°C
490°C bCeGe2-x 61.1 to 62.12 tI12 I4 1/amd Cc ThSi2
aCeGe2-x 61.1 to 62.12 oI* Imma … …
400 (gCe)
(Ge) ? to 100 cF8 Fd 3 m A4 C (diamond)
(Ge)
200
139°C A.B. Gokhale and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 10(2),
(bCe) 142-146 (1989)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Germanium Ge
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
1 2
Ce-H
1200
1100 L+e
L 1025°C
1000
?
970°C Ce-H
900 (dCe) + e Struktur-
800°C e Composition, Pearson Space bericht
800
798°C (dCe) Phase at.% H symbol group designation Prototype
726°C ?
700 (dCe) 0 to ? cI2 Im 3 m A2 W
600
(gCe) (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(bCe) 0 to ? hP4 P6 3/mmc A3¢ aLa
500
e <60 to >75 cF* Fm 3 m … …
400 h1 ~70 tI28 … … …
(gCe) + e h2 ~73 … … … …
300
200
F.D. Manchester and J.M. Pitre, J. Phase Equilibria, 18(1), 63-77 (1997)
100
61°C
h2
0
(bCe)
h1
-100
0 10 20 30 40 50 60 70
Ce Atomic Percent Hydrogen
Ce Weight Percent Hafnium
Ce-Hf
0 10 20 30 40 50 60 70 80 90 100
2400
2200 L1 + L2 L2 2231°C
L1 2020°C Ce-Hf
2000 21 76 (bHf)
Struktur-
1800
1743°C Phase at.% Hf symbol group designation Prototype
1600
(bHf) ? to 100 cI2 Im 3 m A2 W
1400
(aHf) ? to 100 hP2 P6 3/mmc A3 Mg
1260°C
1200
1000 (aHf) 1065, 1067 (1990)
800 795°C
798°C
726°C
(dCe) 700°C
(gCe)
600
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Hafnium Hf
0 10 20 30
40 50 60 70 80 90 100
Ce-Hg
1000
900 L1 L1 + G
800 Ce-Hg
798°C (dCe) (dCe) + G
726°C Struktur-
700
(gCe) + G
600
555°C (dCe) 0 cI2 Im 3 m A2 W
500 485°C (gCe) 0 cF4 Fm 3 m A1 Cu
455°C
400 G Pm 3 m
CeHg 50 cP2 B2 CsCl
357°C
L2 CeHg2 66.7 hP3 P 3 m1 C6 CdI2
300 (gCe)
CeHg3 75 hP8 P6 3/mmc D019 Ni3Sn
200 Ce11Hg45 80.3 cF448 F 4 3m … Cd45Sm11
CeHg6.5 86 o** … … Hg6.5La
100 (Hg) 100 hR1 R 3m A10 aHg
61°C
0
(bCe) -38°C C. Guminski, J. Phase Equilibria, 14(3), 382-387 (1993)
-38.8290°C
(Hg)
-100
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Mercury Hg

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30
40 50 60 70 80 90 100
Ce-Ho
1800
1600
1474°C Ce-Ho
L
1400 Struktur-
1200 Phase at.% Ho symbol group designation Prototype
(dCe) 0 to ? cI2 Im 3 m A2 W
1000 (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(bCe) 0 to ? hP4 P63/mmc A3’ aLa
? d R 3m aSm
800 (dCe) 40 to 55 hR3 …
798°C
726°C (Ho) ? to 100 hP2 P63/mmc A3 Mg
600
(gCe) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
400
(Ho) 1069-1071 (1990)
d
200 (bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Holmium Ho
226
Ce
0 10 20
30 40 50 60 70
Ce-I
900
L1 L1 + L2
850
Ce-I
Struktur-
L2
800
801°C
798°C
(dCe)
750 CeI 50 … … … …
738°C CeI2 66.7 … … … …
726°C
CeI2.2 68.8 … … … …
719°C
CeI3 75 oC16 Ccmm … …
700
R.J.M. Konings and A. Kok-Scheele, Thermochim. Acta, 331(1), 45-48 (1999)

(gCe)
650
600
0 10 20 30 40 50 60 70
Ce Atomic Percent Iodine
0 10 20
30 40 50 60 70 80 90 100
Ce-In
1400
Ce-In
1200
1130°C
1180°C
Struktur-
1170°C
1090 1120°C
1070°C
1000 (dCe) 0 to ? cI2 Im 3 m A2 W
960°C
890°C
910°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(dCe)
800
798°C Ce3In 24 to 25 cP4 Pm 3 m L12 AuCu3
730°C
726°C 13 Ce2In 32 to 33.3 hP6 P63 /mmc B82 Ni2In
650°C
8
Ce5In4 43 to 47 … … … …
600 Ce9In11 55 … … … …
(gCe) Ce3In5 60 to 63 oC32 Cmcm … Pd5Pu3
CeIn2 66.7 oI12 Imma … CeCu2
400
CeIn3 75 cP4 Pm 3 m L12 AuCu3
200
156.634°C H. Okamoto, Phase Diagrams of Indium Alloys and Their Engineering
(In)
61°C
0
(bCe) Park, OH, 69-72 (1992)
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Indium In
0 10 20 30
40 50 60 70 80 90 100
Ce-Ir
2500
2447°C
Ce-Ir
1900 L
82 85 (gCe) 0 cF4 Fm 3 m A1 Cu
1700 Ce4Ir 20 … … … …
Ce3Ir 25 … … … …
1500 Ce7Ir 3 30 hP20 P6 3/mc D102 Fe3Th7
Ce5Ir 3 37.5 tP32 P4/ncc … Pu5Rh3
1300 Ce5Ir 4 44.4 oP36 Pnma … …
1180°C
1100 CeIr 2 63 to 70 cF24 Fd 3 m C15 Cu2Mg
1100
CeIr 3 75 hR12 R 3m … PuNi 3
950°C
900 (Ir) Ce2Ir 7 77.8 hR18 R 3m … Ce2Ni7
(dCe)
798°C
726°C 710
CeIr 5 83.3 cF24 F 4 3m C15 b AuBe 5
700
8 650°C
500
(gCe) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
300
0 10 20 30 40 50 60 70 80 90 100 1073-1075 (1990)
Ce Atomic Percent Iridium Ir
Ce Weight Percent Lanthanum Ce-La
0 10 20 30 40 50 60 70 80 90 100
L 918°C
900
865°C
(dCe,gLa) Ce-La
798°C
Struktur-
726°C
700
(dCe,gLa) 0 to 100 cI2 Im 3 m A2 W
(gCe,bLa) 0 to 100 cF4 Fm 3 m A1 Cu
500
(gCe,bLa) (bCe,aLa) 0 to 100 hP4 P63/mmc A3’ aLa
300
310°C 445-447 (1981)
100
61°C
(bCe,aLa)
-100
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Lanthanum La
0
5 10 20 30 40 60 100
Ce-Li
1000
900
(dCe)
800 L1 L1 + L2 Ce-Li
798°C
726°C Struktur-
19
600 L2 (dCe) Im 3 m
0 cI2 A2 W
500
400
(gCe)
300
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
200
180.6°C
110°C
100 89.9
61°C
(bCe) (bLi)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Lithium Li
0 10 20 30
40 50 60 70 80 90 100
Ce-Lu
2000
Ce-Lu
1663°C Struktur-
1500 Phase at.% Lu symbol group designation Prototype
1000
d 27 to 33 hR3 R 3m … aSm
(Lu) ? to 100 hP2 P63/mmc A3 Mg
798°C (dCe)
?
(gCe)
1077-1078 (1990)
500
(Lu)
(bCe) d
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Lutetium Lu
228
Ce Weight Percent Magnesium
Ce-Mg
0 10 20 30 40 50 60 70 80 100
900
800 L 796°C
798°C Ce-Mg
750°C
726°C 711°C
Struktur-
35 Phase at.% Mg symbol group designation Prototype
(dCe) 635°C 650°C
615°C (dCe) 0 to 8.2 cI2 Im 3 m A2 W
611°C
600
95.7
CeMg 50 cP2 Pm 3 m B2 CsCl
500 (gCe)
505°C CeMg2 66.6 cF24 Fd 3 m C15 Cu2Mg
8.2
CeMg3 75 to ? cF16 Fm 3 m D03 BiF3
Ce5 Mg41 89.1 tI92 I4/m … …
400 CeMg10.3 91.2 hP38 P63/mmc … Ni17Th2
CeMg12 92.3 to ? tI26 I4/mmm D2b Mn12 Th
(Mg) (Mg) 100 hP2 P63/mmc A3 Mg
300
A.A. Nayeb-Hashemi and J.B. Clark, Phase Diagrams of Binary Magnesium
Alloys, ASM International, Materials Park, OH, 78-88 (1988)
200
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Magnesium Mg
0 10
20 30 40 50 60 70 80 90 100
Ce-Mn
1400
(dMn)
1246°C Ce-Mn
1200
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
84.6 1088°C 1100°C
L (gMn) Phase at.% Mn symbol group designation Prototype
998° C
1000 (dCe) 0 to 5.3 cI2 Im 3 m A2 W
71.7
(gCe) 0 to 1.5 cF4 Fm 3 m A1 Cu
(dMn) 97.2 to 100 cI2 Im 3 m A2 W
800
(bMn) (gMn) 97 to 100 cF4 Fm 3 m A1 Cu
798°C (dCe)
726°C 727°C (bMn) 97.2 to 100 cP20 P4 132 A13 bMn
638°C 14.3
625°C
(aMn) 100 cI58 I 4 3m A12 aMn
600 16.4 622°C
(aMn) C. Tang, Y. Du, L. Zhang, H. Xu, and Z. Zhu, J. Alloys Compounds, 437, 102-
106 (2007)
400 (gCe)
200
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Manganese Mn
0 10 20
30 40 50 60 70 80 90 100
Ce-Mo
3500
3000 L2
L1 L1 + L2 Ce-Mo
2500 32 93.3 99.7 Composition, Pearson Space bericht
2000
1500 (Mo) 99.7 to 100 cI2 Im 3 m A2 W
A. Palenzona and S. Cirafici, J. Phase Equilibria, 17(1), 57-59 (1996)

1000
798°C
726°C
(dCe)
500
(gCe) (Mo)
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Molybdenum Mo
Ce Weight Percent Nitrogen Ce-N
0 5 10
2500 2480°C
Ce-N
L
Struktur-
2000
1500 (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(bCe) 0 to ? hP4 P6 3/mmc A3’ aLa
CeN ~50 cF8 Fm 3 m B1 NaCl
(dCe) 805°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
798°C
726°C 750°C 1082, 1084 (1990)
500
(gCe)
(bCe)
61°C
0
0 10 20 30 40 50 60
Ce Atomic Percent Nitrogen
0 10 20
30 40 50 60 70 80 90 100
Ce-Nb
3000
L1 + L2 L2
2500 L1 2420°C 2469°C

99 Ce-Nb
Struktur-
1500
(Nb) 99 to 100 cI2 Im 3 m A2 W
1000
805°C
798°C
726°C 705°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
(dCe)
1085-1086 (1990)
500
(gCe) (Nb)
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Niobium Nb
0 10 20 30
40 50 60 70 80 90 100
Ce-Nd
1200
L 1021°C
1000 Ce-Nd
Struktur-
(dCe,bNd) Phase at.% Nd symbol group designation Prototype
800
798°C
(dCe,bNd) 0 to 100 cI2 Im 3 m A2 W
726°C
600 (bCe,aNd) 0 to 100 hP4 P6 3/mmc A3’ aLa
(gCe) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
400
(b Ce,a Nd) 1085, 1087 (1990)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Neodymium Nd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
230
Ce Weight Percent Nickel
Ce-Ni
0 10 20 30 40 50 60 70 80 90 100
1600
1455°C
1400
Ce-Ni
Struktur-
1211°C
L 1076°C (dCe) 0 cI2 Im 3 m A2 W
1000 957°C
800
811°C Ce7Ni3 30 hP20 P63 /mc D102 Fe3Th7
798°C
726°C
(dCe) CeNi 50 oC8 Cmcm Bf CrB
658°C
CeNi2 66.7 cF24 Fd 3 m C15 Cu2Mg
600 CeNi3 75 hP* P63/mmc … …
483°C 487°C Ce2Ni7 77.8 hP36 P63/mmc … …
CeNi5 82.5 to 85.7 hP6 P6/mmm D2d CaCu5
400 Tc
354.2°C (Ni) 100 cF4 Fm 3 m A1 Cu
(gCe)
200
(Ni) H. Okamoto, J. Phase Equil. Diffusion, 30(4), 406 (2009)
61°C
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Nickel Ni
0 2
5 10 20 30 40 50 60 80 100
Ce-O
4000
3838°C, 60.8 Ce-O
Struktur-
3500
(dCe) 0 to 0.6 cI2 Im 3 m A2 W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
3000
3033°C, 45.6 (gCe) 0 to 0.5 cF4 Fm 3 m A1 Cu
gCe2O3 57.3 to 59.3 … … ... …
2500 L bCe2O3 56.9 to 58.6 hP5 P 3 m1 D52 La2O3
gCe2 O3
2227°C
2293°C
aCe2O3 56.9 to 60 cI80 Ia 3 D53 Mn2O3
Ce7O12 63.2 hR19 R3 … …
2000
bCe2O3 1: Ce3O5 Ce3O5 62.2 to 62.8 … … ... …
2: Ce7O12 CeO2 62.2 to 66.7 cF12 Fm 3 m C1 CaF2
aCe2O3 3: Ce9O16
1500
4: Ce19O34
Ce9O16 64.0 hR* … … …
5: Ce5O9 Ce19O34 64.2 … … ... …
6: Ce31O56 Ce5O9 64.3 … … ... …
1000 (dCe) 1 7: Ce11O20 Ce31O56 64.4 … … ... …
807°C
798°C
726°C Ce11O20 64.5 aP31 P1 ... …
732°C
612°C
500
(gCe) H. Okamoto, J. Phase Equilibria Diffusion, 29(6), 545-547 (2008)
2 3,4,5,6,7
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Oxygen O
0 10 20 30 40
Weight Percent Lead
50 60 70 80 90 100
Ce-Pb
1400 1380°C
Ce-Pb
L
Struktur-
1000 Ce2Pb 33.3 … … … …
CePb3 75 cP4 Pm 3 m L12 AuCu 3
800
798°C
(dCe) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
600 1092-1093 (1990)
400
327.502°C
(Pb)
200
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Lead Pb
Ce Weight Percent Palladium Ce-Pd
0 10 20 30 40 50 60 70 80 90 100
1800
Ce-Pd
1600
L 1555°C Struktur-
1400 Phase at.% Pd symbol group designation Prototype
Ce7Pd3 30 hP20 P63 /mc D102 Fe3Th7
1200 Ce3Pd2 40 … … … …
1137°C 1180°C
bCePd 50 … … … …
87 1075°C aCePd
1000 992°C 50 oC8 Cmcm Bf CrB
1037°C 64
(Pd) Ce3Pd4 57.1 hR14 R3 … …
800
801°C Ce3Pd5 62.5 hP8 P62 … …
709°C 87.7 CePd3 74.8 to 76.2 cP4 Pm 3 m L12 AuCu3
600 bCePd5 83.3 hR* … … …
aCePd5 83.3 cF* … … …
400 CePd7 ~87.5 cF* Fm 3 m … …
(Pd) 87 to 100 cF4 Fm 3 m A1 Cu
200
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Palladium Pd
0 10 20 30
40 50 60 70 80 90 100
Ce-Pm
1200
L 1042°C Ce-Pm
1000
Struktur-
890° C
(dCe,bPm) Phase at.% Pm symbol group designation Prototype
800
798°C
(dCe,bPm) 0 to 100 cI2 Im 3 m A2 W
726°C (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(bCe,aPm) 0 to 100 hP4 P63 /mmc A3’ aLa
600
(gCe)
400
1095-1096 (1990)
(bCe,aPm)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Promethium Pm
0 10 20 30
40 50 60 70 80 90 100
Ce-Pr
1000
931°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L
Ce-Pr
(dCe,bPr) Struktur-
800 795°C
798°C
726°C 750°C
(dCe,bPr) 0 to 100 cI2 Im 3 m A2 W
600 (gCe) 0 to ? cF4 Fm 3 m A1 Cu
(gCe) (bCe,aPr) 0 to 100 hP4 P63/mmc A3’ aLa
400 187-188 (1982)
(bCe,a Pr)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Praseodymium Pr
232
Ce Weight Percent Platinum
Ce-Pt
0 10 20 30 40 50 60 70 80 90 100
2000
1800 1770°C
Ce-Pt
1750°C 1724°C 1769.0°C Struktur-
1600 L
1517°C 1529°C Phase at.% Pt symbol group designation Prototype
92 (dCe) 0 cI2 A2 W
Im 3 m
1400
1311
1359°C
59 Ce7Pt3 30 hP20 P63 /mc D102 Fe3Th7
1200 Ce5Pt3 37.3 to 38.4 tP32 P4/ncc … Pu5Rh3
1075°C Ce3Pt2 40 hR15 R3 … …
1012°C
1000
936°C
Ce5Pt4 44.4 oP36 Pnma … Ge4Sm5
861°C
CePt 49 oC8 Cmcm Bf CrB
800 (dCe) Ce3Pt4 57.1 hR14 R3 … …
798°C 714°C
726°C CePt2 66 to 75 cF24 Fd 3 m C15 Cu2Mg
649°C
600 1 11.5 CePtx 81.5 ... ... ... ...
(Pt) CePt5 83.3 hP6 P6/mmm D2d CaCu5
(gCe) (Pt) 100 cF4 Fm 3 m A1 Cu
400
A. Janghorban, M. Lomello-Tafin, J.M. Moreau, and Ph. Galez, Intermetallics,

200
0 10 20 30 40 50 60 70 80 90 100 18(11), 2208-2218 (2010)
Ce Atomic Percent Platinum Pt
0 10 20 30 40
50 60 70 80 90 100
Ce-Pu
800
798°C
(dCe)
726°C 720°C L
700
625°C 83.5 640°C Ce-Pu

600 (gCe) 34 610°C 76 (ePu)
Struktur-
500
(d'Pu) 483°C (dCe) 0 to 18 cI2 Im 3 m A2 W
463°C
400
(dPu)
(ePu) ? to 100 cI2 Im 3m A2 W
320°C
300 (d’Pu) 100 tI2 I4/mmm A6 In
(gPu)
(dPu) 76 to 100 cF4 Fm 3m A1 Cu
200
(bPu) (bPu) 100 mC34 C2/m … bPu
125°C (aPu) 100 mP16 P21/m … aPu
100
61°C (aPu)
(bCe) J.E. Selle and D.E. Ether, Trans. Metall. Soc. AIME, 230, 1000-1005 (1964)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Plutonium Pu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Ce-Rh
2000
1963°C
1800
Ce-Rh
1600 Struktur-
1400
1200 Ce7Rh3 30 hP20 P6 3/mc D102 Fe3Th7
1055°C bCe5Rh 3 37.5 c** … … …
1000 aCe5Rh 3 37.5 tP32 P4/ncc … …
953°C
920°C Ce3Rh2 40 hR15 R3 … …
(dCe)
815°C (Rh) Ce5Rh4 44.4 oP36 Pnma … …
800 753°C
798°C 735 CeRh 50 oC8 Cmcm Bf CrB
726°C
715°C 703°C CeRh2 66.7 cF24 Fd 3 m C15 Cu2Mg
620°C
600 CeRh3 75 cP4 Pm 3 m L12 AuCu3
(gCe) (Rh) 100 cF4 Fm 3 m A1 Cu
400
Ce Atomic Percent Rhodium Rh
Ce Weight Percent Ruthenium Ce-Ru
0 10 20 30 40 50 60 70 80 90 100
2400
2334°C
2200
Ce-Ru
2000 Struktur-
1800
L Phase at.% Ru symbol group designation Prototype
1600 1570°C
98 (gCe) 0 cF4 Fm 3 m A1 Cu
1400 Ce3Ru 25 oP16 Pnma D011 Fe3 C
Ce7Ru3 30 hP20 P63/mc D102 Fe3 Th7
1200 Ce16Ru9 36 hR150 R3m … …
Ce4Ru3 42.9 mC28 C2/m … …
1000 CeRu2 66.7 cF24 Fd 3 m C15 Cu2 Mg
(Ru) (Ru) 98 to 100 hP2 P63 /mmc A3 Mg
(dCe)
800 41 750°C
798°C 34
726°C 28 720°C H. Okamoto, J. Phase Equilibria, 13(4), 437-438 (1992)
19 595°C 685°C
600 545°C
15
400 (gCe)
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Ruthenium Ru
10
15 20 25 30 35
Ce-S
2600
2450°C
2400
2200 Ce-S
L 2000
2050°C Struktur-
2000
53.4 1890 Composition, Pearson Space bericht
1800
1700°C
CeS 50 cF8 Fm 3 m B1 NaCl
1600 Ce3S4 57.1 … … … …
1450 Ce5S7 58.3 tI192 I41/acd … …
1400
L + CeS bCe2S3 60 cI28 I 4 3d D73 Th3P4
1200 aCe2S3 60 oP20 Pnma … …
1100°C
CeS2 66.7 tP24 P4/nmm … …
1000
800
600 1103, 1105 (1990)
400
200
20 25 30 35 40 45 50 55 60 65 70
Atomic Percent Sulfur

0 10 20 30 40 50 60 70 80 90 100
Ce-Sb
2000
1820°C
1800
Ce-Sb
L Struktur-
1600
1400
1330°C (dCe) 0 cI2 Im 3 m A2 W
1200
1130°C
1000 Ce2Sb 33.3 tI12 I4/mmm … …
900°C
Ce4Sb3 42.9 cI28 I 4 3d D7 3 Th3 P4
800
798°C
770°C CeSb 50 cF8 Fm 3 m B1 NaCl
700°C
726°C
625°C bCeSb2 66.7 … … … …
(dCe) 630.755°C
600
aCeSb2 66.7 oC24 Cmca … Sb2 Sm
400
(gCe) (Sb)
V.D. Abulkhaev, Zh. Neorg. Khim., 42(2), 341-345 (1997) in Russian; TR: Russ. J.
200
(bCe) Inorg. Chem., 42(2), 283-286 (1997)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Antimony Sb
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
234
Ce Weight Percent Scandium Ce-Sc
0 10 20 30 40 50 60 70 80 90 100
1600
1541°C
1400
L 1337°C Ce-Sc
Struktur-
1200
1000 (dCe,bSc) 0 to 100 cI2 Im 3 m A2 W
800 (dCe,bSc) (bCe) 0 hP4 P6 3/mmc A3’ aLa
798°C
726°C 680°C
(aSc) 85 to 100 hP2 P6 3/mmc A3 Mg
19 55 85 (aSc)
600
189-190 (1982)
400
(gCe)
200
61°C
(bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Scandium Sc
0 10 20
30 40 50 60 70 80 90 100
Ce-Se
2000
1820°C 1800°C
1800
L Ce-Se
1600
Struktur-
1400
1200
1000 (bCe) 0 hP4 P6 3/mmc A3’ aLa
CeSe 50 cF8 Fm 3 m B1 NaCl
800
798°C 750°C Ce3Se4 57.1 to 60 cI28 I 4 3d D73 Th3P4
726°C Ce4Se7 63.6 mP22 P21/a … …
(dCe) CeSe2 66.7 mP12 P21/c … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600
(Se) 100 hP3 P3121 A8 gSe
400 (gCe)
200 221°C Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
(bCe) (Se) 1107, 1109-1110 (1990)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Selenium Se

0 10 20 30 40 50 60 70 80 100
Ce-Si
1800
1725°C
1630°C
1600 1575°C Ce-Si
1500°C
1532°C
Struktur-
1400
1260°C
1198°C (dCe) 0 cI2 Im 3 m A2 W
1200
82 (gCe) 0 cF4 Fm 3 m A1 Cu
1000
Ce5Si3 37.5 tI32 I4/mcm D8m W5Si3
(dCe) Ce3Si2 40 tP10 P4/mbm D5a Si2U3
800
798°C
Ce5Si4 44.4 tP36 P41 2 12 … Si4Zr5
726 °C
635°C
CeSi 50 oP8 Pnma B27 FeB
600 10.5 Ce3Si5 61.5 to 62.5 oI12 Imma … GdSi2
(Si)
CeSi2 63 to 67 tI12 I41 /amd Cc ThSi2
400
(gCe)
200
( bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Silicon Si
Ce Weight Percent Samarium Ce-Sm
0 10 20 30 40 50 60 70 80 90 100
1200
1074°C
L
1000 Ce-Sm
922°C Struktur-
(dCe,gSm) Composition, Pearson Space bericht
800 (bSm) Phase at.% Sm symbol group designation Prototype
798°C
734° C
(dCe,gSm) 0 to 100 cI2 Im 3 m A2 W
726°C
700°C
600 (bCe) 0 to ? hP4 P63/mmc A3’ aLa
(bSm) ? to 100 hP2 P63/mmc A3 Mg
(aSm) 80 to 100 hR3 R 3m … aSm
(gCe)
400
190-192 (1982)
200
(aSm)
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Samarium Sm
0 10 20
Weight Percent Tin
30 40 50 60 70 80 90 100
Ce-Sn
2000 Ce-Sn
Struktur-
L Phase at.% Sn symbol group designation Prototype
1505°C 1510°C (dCe) 0 to ? cI2 Im 3 m A2 W
1500
(bCe) 0 hP4 P6 3/mmc A3¢ aLa
1162°C Ce3Sn 25 cP4 Pm 3 m L12 AuCu 3
bCe 5Sn 3 37.5 hP16 P6 3/mcm D88 Mn5Si3
1000 940°C aCe 5Sn 3 37.5 tI32 I4/mcm D8m W5Si3
(dCe) Ce5Sn4 44.4 oP36 Pnma … …
798°C
725°C Ce11Sn1 0 47.6 tI84 I4/mmm … …
726°C
690°C
Ce3Sn5 62.5 oC32 Cmcm … …
Ce3Sn7 70 o** … … …
500 Ce2Sn5 71.4 o** … … …
CeSn3 75 cP4 Pm 3 m L12 AuCu 3
(gCe)
230°C 231.9681°C
(bSn) 100 tI4 I4 1/amd A5 bSn
(bCe) (bSn) (aSn) 100 cF8 Fd 3 m A4 C (diamond)
61°C (aSn)
0 13°C
0 10 20 30 40 50 60 70 80 90 100 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
Ce Atomic Percent Tin Sn
1112, 1114-1115 (1990)
0 10 20 30
40 50 60 70 80 90 100
Ce-Ta
L1 + L2 L2 3020°C
3000
2500 Ce-Ta
Struktur-
L1 (dCe) 0 cI2 Im 3 m A2 W
(Ta) (gCe) 0 cF4 Fm 3 m A1 Cu
1500 (bCe) 0 hP4 P6 3/mmc A3¢ aLa
(Ta) 100 cI2 Im 3 m A2 W
1000
(dCe) S.P. Garg, M. Venkatraman, N. Krishnamurthy, and S.J. Vijaykar, J. Phase
798°C Equilibria, 19(4), 385-394 (1998)
726°C
500
(gCe)
139°C
61°C (bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Tantalum Ta
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
236
Ce Weight Percent Terbium Ce-Tb
0 10 20 30 40 50 60 70 80 90 100
1500
1356°C Ce-Tb
1289°C
Struktur-
L
(dCe,bTb) 0 to 100 cI2 Im 3 m A2 W
1000
(dCe,bTb) ? (bCe) 0 to ? hP4 P63/mmc A3’ aLa
798°C
d 60 to 70 hR3 R3m C19 aSm
726°C
(aTb) ? to 100 hP2 P63/mmc A3 Mg
(gCe)
500
1115, 1117 (1990)
d (aTb)
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Terbium Tb
0 10 20 30
40 50 60 70 80 90 100
Ce-Te
2000
1820°C
Ce-Te
1800
Struktur-
1600 1585°C Phase at.% Te symbol group designation Prototype
55
1400 (gCe) 0 cF4 Fm 3 m A1 Cu
1340°C
1250°C
1200 CeTe 50 cF8 Fm 3 m B1 NaCl
Ce3Te4 57.1 to 60 cI28 I 4 3d D73 Th3P4
1000 Ce4Te7 63.6 tP* … … …
(dCe) CeTe2 66 to 67 tP6 P4/nmm C38 Cu2Sb
870°C
800 829°C
Ce2Te5 71.4 oC28 Cmcm … …
760°C
798°C
726°C
CeTe3 75 oC16 Cmcm … …
(Te) 100 hP3 P3121 A8 gSe
600 607°C
(gCe) 435°C 449.57°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(Te) 1118, 1120 (1990)
200
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Tellurium Te
0 10 20 30 40
50 60 70 80 90 100
Ce-Th
2000
1755°C
Ce-Th
L Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1500
(bTh) Composition, Pearson Space bericht
1300°C 70 1360°C Phase at.% Th symbol group designation Prototype
(gCe,aTh) 0 to 100 cF4 Fm 3 m A1 Cu
1000 (bCe) 0 to ? hP4 P6 3/mmc A3¢ aLa
(bTh) 70 to 100 cI2 Im 3 m A2 W
798°C
(dCe)
500 (gCe,aTh) 1118-1119, 1121 (1990)
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Thorium Th
Ce Weight Percent Titanium Ce-Ti
0 10 20 30 40 50 60 70 80 90 100
1800
1670°C
1600 L1 L2 Ce-Ti
L1 + L2
Struktur-
98.3
1400 Phase at.% Ti symbol group designation Prototype
(dCe) 0 to 0.2 cI2 Im 3 m A2 W
1200 (bTi) 98.3 to 100 cI2 Im 3 m A2 W
(bTi)
(aTi) 98.8 to 100 hP2 P6 3/mmc A3 Mg
1000
J.L. Murray, Phase Diagrams of Binary Titanium Alloys, J.L. Murray, ed., ASM
910°C
98.8 882°C
800 790°C
798°C
(dCe) 710°C
726°C
(gCe) (aTi)
600
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Titanium Ti
0 10 20 30 40
50 60 70 80 90 100
Ce-Tl
1400
Ce-Tl
1200
1210°C Struktur-
1090°C 1100°C Phase at.% Tl symbol group designation Prototype
1040°C 51 60 69 1060°C
1000 44 1040°C (dCe) 0 to 9 cI2 Im 3 m A2 W
950°C
800 (dCe) 780°C
798°C Ce3Tl 24.5 to 25.5 cP4 Pm 3 m L12 AuCu 3
726°C 12 685°C Ce2Tl 32.5 to 33.5 … … … …
9
620°C Ce5Tl3 37 to 38 tI32 I4/mcm D8m W5Si3
600 3 6
CeTl 44 to 51 cP2 Pm 3 m B2 CsCl
cI2 Im 3 m A2 W
400 Ce3Tl5 62 to 63 oC32 Cmcm … Pd5Pu3
(gCe) Pm 3 m
303°C CeTl 3 75 cP4 L12 AuCu 3
304°C
(bTl) (bTl) 100 cI2 Im 3 m A2 W
230°C
200 (aTl) 100 hP2 P6 3/mmc A3 Mg
(aTl)
61°C
(bCe) S. Delfino, A. Saconne, A. Palenzona, and R. Ferro, Binary Alloy Phase
0
0 10 20 30 40 50 60 70 80 90 100
Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R. Subramanian, and L.
Kacprzak, ed., ASM International, Materials Park, OH, 1123-1124 (1990)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ce Atomic Percent Thallium Tl
0 10 20 30
40 50 60 70 80 90 100
Ce-Tm
1600
1545°C
1400 Ce-Tm
L Struktur-
1200
1000
?
800
798°C (dCe) d 33 to 38 hR3 R 3m … aSm
726°C (Tm) ? to 100 hP2 P63/mmc A3 Mg
600
(gCe) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
(Tm)
400 1123, 1125 (1990)
(bCe) d
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Thulium Tm
238
Ce
Weight Percent Uranium Ce-U
0 10 20 30 40 50 60 70 80 90 100
1400
L1 L2
1300 Ce-U
L1 + L2
Struktur-
1106°C 98.3 1135°C Phase at.% U symbol group designation Prototype
1100 (dCe) Im 3 m
1.4 99.69 0 cI2 A2 W
1000
(gU) 99.69 to 100 cI2 Im 3 m A2 W
(gU)
(bU) 99.83 to 100 tP30 P42 /mnm Ab bU
900
800
798°C (dCe) 754°C 776°C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
726°C 752°C
700 (bU)
636°C 668°C 1126-1127 (1990)
600
500 (gCe) (aU)
400
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Uranium U
0 10
20 30 40 50 60 70 80 90 100
Ce-V
2100
L1 L1 + L2 L2
99.0 1910°C
1900 1.69 99.4
Ce-V
Struktur-
1500
(dCe) 0 to 0.0011 cI2 Im 3 m A2 W
L1 + (V)
(V) 99.4 to 100 cI2 Im 3 m A2 W
1300
J.F. Smith and K.J. Lee, Bull. Alloy Phase Diagrams, 8(6), 523-525 (1987)
1100
900
801°C
798°C 0.0004
0.0011 99.99
726°C
700 (dCe)
(gCe) (V)
500
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Vanadium V

0 10 20 30 40 50 60 70 80 90 100
Ce-W
3500
3340°C L2 3422°C
2.87 97.13
3000
L1 + L2
Ce-W
2500 Struktur-
L1 Phase at.% W symbol group designation Prototype
2000 L1 + (W) (W)
1500
(bCe) 0 hP4 P63 /mmc A3’ aLa
(W) 100 cI2 Im 3 m A2 W
1000 (dCe) N. Krishnamurthy, T. Kundu, A. Awasthi, and S.P. Garg, Z. Metallkd., 91(3),
798°C 234-240 (2000) (Revised by the authors)
726°C
500 (gCe) + (W)

(gCe)
139°C
61°C (bCe)
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Tungsten W

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Ce Weight Percent Yttrium
Ce-Y
0 10 20 30 40 50 60 70 80 90 100
1600
1522°C
1478°C
1400
Ce-Y
L Struktur-
(dCe,bY) 0 to 100 cI2 Im 3 m A2 W
1000 (gCe) 0 to 12.7 cF4 Fm 3 m A1 Cu
(bCe) 0 to 47 hP4 P63 /mmc A3’ aLa
31 782°C (aY) 70.1 to 100 hP2 P63 /mmc A3 Mg
800
798°C
(dCe,bY)
40.4 70.1
726°C 694°C (aY)
12.7 16.1 28.3 F.G. Meng, L.B. Liu, H.S. Liu, and Z.P. Jin, Calphad, 30(3), 323-325 (2006)
600 (gCe)
400
(bCe)
200
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Yttrium Y
0 10
Weight Percent Zinc
20 30 40 50 60 70 80 90 100
Ce-Zn
1100
Ce-Zn
960°C
900
L 885 Phase at.% Zn symbol group designation Prototype
875°C 870°C
825°C
840°C (dCe) 0 cI2 Im 3 m A2 W
810
795°C 795°C
800 73.2 820 (gCe) 0 cF4 Fm 3 m A1 Cu
798°C 55.7
(dCe) CeZn 50 cP2 Pm 3 m B2 CsCl
726°C
700 CeZn2 66.7 oI12 Imma … …
CeZn3 75 oC16 Cmcm … …
600
Ce3 Zn11 78.6 oI28 Immm … …
Ce13 Zn5 8 81.7 hP142 P63mc … …
495°C
CeZn5 83.3 hP6 P6/mmm D2d CaCu5
500
Ce3 Zn22 88 tI100 I41/amd … …
419.58°C
Ce2 Zn17 89.5 hR19 R 3m … …
400 CeZn11 91.7 tI48 I41/amd … …
(gCe) (Zn) 100 hP2 P63/mmc A3 Mg
(Zn)
300
200
0 10 20 30 40 50 60 70 80 90 100 1132-1133 (1990)
Ce Atomic Percent Zinc Zn
0 10 20
30 40 50 60 70 80 90 100
Ce-Zr
2000
L2 1855°C
1800
L1 L1 + L2
1600 Ce-Zr
1490°C
96 Struktur-
(bZr) Phase at.% Zr symbol group designation Prototype
1200
1000
863°C (bZr)
800
96 to 100 cI2 Im 3 m A2 W
798°C
726°C (aZr) ? to 100 hP2 P63/mmc A3 Mg
(dCe)
600
(aZr)
(gCe) 1132, 1134 (1990)
200
(bCe)
61°C
0
0 10 20 30 40 50 60 70 80 90 100
Ce Atomic Percent Zirconium Zr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
240
Cf Weight Percent Molybdenum Cf-Mo
0 10 20 30 40 50 60 70 80 90 100
5000
4639°C
G
Cf-Mo
4000
Struktur-
G+L L Phase at.% Mo symbol group designation Prototype
(Cf) 0 hP4 P63 /mmc A3’ aLa
3000
(Mo) 100 cI2 Im 3 m A2 W
2623°C
L. Brewer and R.H. Lamoreaux, Binary Alloy Phase Diagrams, 2nd ed., T.B.
2000
G + (Mo)
1077°C
1000
(Cf) (Mo)
0
0 10 20 30 40 50 60 70 80 90 100
Cf Atomic Percent Molybdenum Mo
56.0 56.5
57.0 57.5
Cl-Cr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
880
870
Cr-Cl
Struktur-
860
850 L (Cr) 0 cI2 Im 3 m A2 W
CrCl2 66.667 oP6 Pnnm ... ...
840
S. Seetharaman and L.I. Staffansson, Acta Chem. Scand., A, 30, 303-305 (1976)
(Cr) + L
830
822°C
820
810
806°C
(Cr) + CrCl2
800
65.0 65.2 65.4 65.6 65.8 66.0 66.2 66.4 66.6 66.8
Atomic Percent Chlorine
0
10 20
Cl-Cs
800
L 640°C Cs-Cl
600
Struktur-
469°C (Cs) 0 cI2 Im 3 m A2 W
bCsCl 50 cF8 Fm 3 m B1 NaCl
400 aCsCl 50 cP2 Pm 3 m B2 CsCl
1137-1138 (1990)
200
28.4°C
28.39°C
(Cs)
0
0 10 20 30 40 50 60
Cs Atomic Percent Chlorine
Cl
40
45 50
Cl-Cu
650
628°C
600 Cu-Cl
Struktur-
550
bCuCl 50 hP4 P63mc B4 ZnS (wurtzite)
500
aCuCl 50 cF8 F 4 3m B3 ZnS (sphalerite)
488°C bCuCl2 66.7 … … … …
aCuCl2 66.7 mC6 C2/m ... ...
(Cl) 100 oC8 Cmca ... Cl
450
423°C bCuCl T. Kekesi, K. Miura, and M. Isshiki, Mater. Trans., JIM, 36(5), 649-658 (1995)
407°C
400
378°C
aCuCl
350
50 52 54 56 58 60 62 64 66
0
10 20 30 40
Cl-Dy
800
L Dy-Cl
721°C
Struktur-
675°C Phase at.% Cl symbol group designation Prototype
652°C 651°C (aDy) 0 hP2 P6 3/mmc A3 Mg
bDyCl2 66.7 … … … …
aDyCl2 66.7 oP24 Pnca … …
600 Dy5Cl11 68.7 … … … …
DyCl3 75 mC16 C2/m … …
(aDy) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
507°C
500 71.8 1140-1141 (1990)
400
0 10 20 30 40 50 60 70 80
Dy Atomic Percent Chlorine
Weight Percent Chlorine Cl-Er

0 10 20 30 40 50 60 70 80 100
1600
1529°C
1400 Er-Cl
Struktur-
1200
(Er) 0 hP2 P6 3/mmc A3 Mg
ErCl3 75 mC16 C2/m … …
1000
L (Cl) 100 oC8 Cmca A14 I
800 777°C
74
1140, 1142 (1990)
600
(Er)
400
200
0 10 20 30 40 50 60 70 80 90 100
Er Atomic Percent Chlorine Cl
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
242
Cl Weight Percent Chlorine
Cl-Eu
32 34 36 38 40
900
854°C
800 Eu-Cl
Struktur-
700 bEuCl2 66.7 … … … …
aEuCl2 66.7 oP12 Pnma C23 Co2Si
624°C
Eu5Cl11 68.8 … … … …
600 593°C
Eu4Cl9 69.2 … … … …
Eu3Cl7 70 … … … …
555°C
EuCl3 75 hP8 P63 /m … UCl3
523°C
500 D.M. Laptev, N.M. Kulagin, I.S. Astakhova, and N.V. Tolstoguzov, Russ. J. Inorg.
Chem., 26(4), 553-556 (1981)
Eu5C11
400 386°C
67 68 69 70 71 72 73 74 75
62 64
Weight Percent Fluorine
66 68 70 72
Cl-F
-70
Cl-F
-80
L Struktur-
gClF3 75 … … … …
-90 bClF3 75 mP32 P121 /c1 … …
aClF3 75 oP16 Pnma … …
Cl5F19 79.2 … … … …
L1 + L2 bClF5 83.3 … … … …
-100 aClF5 83.3 … … … …
-110
-120
75 76 77 78 79 80 81 82 83
Atomic Percent Fluorine

Cl-Ga
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
200
L1 + L2
180
170°C 171°C
160 Ga-Cl
Struktur-
140 L2 Composition, Pearson Space bericht
120 (Ga) 0 oC8 Cmca A11 Ga
bGaCl2 66.7 tP24 Pnma … …
100 aGaCl2 66.7 … … … …
87°C Ga4Cl9 69.2 … … … …
L1 78°C
80 GaCl 3 75 aP8 P1 … …
66°C (Cl) 100 oC8 Cmca A14 I
60 58°C
29.7°C
29.7741°C 1143-1144 (1990)
20
(Ga)
0
0 10 20 30 40 50 60 70 80 90 100
Ga Atomic Percent Chlorine Cl
Cl-Gd
0 10 20 30 40 50 60 70 80 100
1000
L Gd-Cl
800 Struktur-
632°C 74.6 (bGd) 0 cI2 Im 3 m A2 W
605°C
600
601°C 74.8
Gd8 Cl5 38.5 mC28 C2/m … …
bGdCl3 75 hP8 P63/m … …
aGdCl3 75 oC16 Ccmm … …
400 (Cl) 100 oC8 Cmca A14 I
(aGd)
200 1143, 1145 (1990)
100°C
aGdCl3
0
0 10 20 30 40 50 60 70 80 90 100
Gd Atomic Percent Chlorine Cl
Weight Percent Chlorine Cl-Hg

0 10 20 30 40 50 60 70 80 100
800
700
L1 L1 + L2
600 L2 Hg-Cl
525°C 51 Struktur-
400 (Hg) 0 hR1 R 3m A10 aHg
bHgCl 50 tI16 I4/mmm D31 HgCl
300 273°C 279.5°C aHgCl 50 mP8 P21 /m … …
65.5
HgCl2 66.7 oP12 Pnma C23 Co2 Si
200 (Cl) 100 oC8 Cmca A14 I
100 C. Guminski, J. Phase Equilibria, 15(1), 101-107 (1994)
0
-39°C
-38.8290°C
-87.2°C -101°C
-100 -100.97°C
(Hg) (Cl)
-200
0 10 20 30 40 50 60 70 80 90 100
Hg Atomic Percent Chlorine Cl

Cl-Ho
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
800
L
Ho-Cl
721.5°C Struktur-
700 Phase at.% Cl symbol group designation Prototype
(Ho) 0 hP2 P63 /mmc A3 Mg
HoCl2.14 68.2 … … … …
(Ho)
HoCl3 75 mC16 C2/m … …
551°C
543°C
500
0 10 20 30 40 50 60 70 80 90 100
Ho Atomic Percent Chlorine Cl
244
Cl Weight Percent Iodine
Cl-I
0 10 20 30 40 50 60 70 80 90 100
150
113.6°C
100
L
Cl-I
50 Struktur-
0
Cl3I 25 aP1 P1 … …
ClI 50 mP8 P21/c … …
-50
(I)
-100
-100.97°C
(Cl)
-150
0 10 20 30 40 50 60 70 80 90 100
Cl Atomic Percent Iodine I
0 10
20 30 40 50 60 70 80 90 100
Cl-In
600
580°C
L+G In-Cl
Struktur-
500
400 bInCl 50 oC8 Cmcm B33 TlI
aInCl 50 cP64 P213 … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
bIn2Cl3 325°C In3Cl4 57.1 … … … …
300 302°C
284 bIn2 Cl3 ~60 … … … …
L1 + L2 265 258 aIn2 Cl3 60 … … … …
239°C
224 238°C bIn5 Cl9 64.3 … … … …
212°C 210°C
200 186°C aIn5 Cl9 64.3 … … … …
158°C bInCl2 66.7 oP24 Pnna … GaCl2
156.634°C
120°C aInCl2 66.7 m** … … …
100 InCl3 75 mC16 C2/m … AlCl3
(In)
H. Okamoto, Bull. Alloy Phase Diagrams, 11(3), 300-303 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
In Atomic Percent Chlorine Cl
0 10 20
30 40 50 60
Cl-K
1000
L K-Cl
800 790°C
37.9 769.5°C Struktur-
22.4 47.4 Composition, Pearson Space bericht
L1 + L2
(K) 0 cI2 Im 3 m A2 W
600
KCl 50 cF8 Fm 3 m B1 NaCl
400
1149-1150 (1990)
200
63.7°C
63.71°C
(K)
0
0 10 20 30 40 50 60 70
K Atomic Percent Chlorine
Cl-La
0 10 20 30 40 50 60 70 80 90 100
1000
L1 L1 + L2
L2
La-Cl
900
(gLa) Phase at.% Cl symbol group designation Prototype
(gLa) 0 to ? cI2 Im 3 m A2 W
865°C 860°C 859°C
LaCl3 75 hP8 P63 /m … …
826°C
1149, 1151 (1990)
(bLa)
700
0 10 20 30 40 50 60 70 80 90 100
La Atomic Percent Chlorine Cl
0 0.01 0.02
0.03 0.04 0.05 0.06
Cl-Li
600
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L Li-Cl
500
Struktur-
400 (bLi) 0 cI2 Im 3 m A2 W
LiCl 50 cF8 Fm 3 m B1 NaCl
L + LiCl
E.E. Konovalov, N.I. Seliverstov, and V.P. Emel’yanov, Russ. Metall., (3), 77-78
300 (1968)
200
180.6°C
(bLi) (bLi) + LiCl

100
0 0.002 0.004 0.006 0.008 0.010 0.012
Li Atomic Percent Chlorine
0 10 20
30 40 50 60 70 80 90 100
Cl-Mn
1500
1400
L1
L2
1300
(dMn)
1246°C Mn-Cl
1200
Struktur-
1100°C
(gMn) Phase at.% Cl symbol group designation Prototype
1000
900 (bMn) (bMn) 0 cP20 P41 32 A13 bMn
(aMn) 0 cI58 I 4 3m A12 aMn
800 MnCl2 66.7 hR9 R 3m … CdCl2
727°C
700
(aMn) H. Okamoto, J. Phase Equilibria Diffusion, 22(2), 180 (2001)
600
500
0 10 20 30 40 50 60 70 80 90 100
Mn Atomic Percent Chlorine Cl
246
Cl Weight Percent Chlorine Cl-Mo
30 40 50 60 70 80 90 100
1200
(Mo) + G
1000 Mo-Cl
950°C
Struktur-
800 G Phase at.% Cl symbol group designation Prototype
650°C MoCl2 66.7 oC72 Cmca … …
600 aMoCl3 75 mC16 C2/m … …
(Mo) + MoCl2
bMoCl3 76 mC32 C2/c … …
bMoCl4 80 hP* P 31 c … …
400 aMoCl4 80 m** … … NbCl4
MoCl5 83.3 mC72 C2/m … NbCl5
280°C L MoCl6 85.7 hR35 … … WCl6
277°C ?
197°C
200
aMoCl4 25°C 1152-1153 (1990)
0
50 60 70 80 90 100
0 10 20 30 40
50 60 70 80 90 100
Cl-Na
1400
1200 L
Na-Cl
1080°C
33.3 Struktur-
L 1 + L2 Phase at.% Cl symbol group designation Prototype
795.3°C 800°C (bNa) 0 cI2 Im 3 m A2 W
800
2.2 49.4 NaCl 50 cF8 Fm 3 m B1 NaCl
600
1152, 1154 (1990)
400
200
97.8°C
(bNa)
0
0 10 20 30 40 50 60 70 80 90 100
Na Atomic Percent Chlorine Cl
32
34 36 38 40 42
Cl-Nd
1200
1100 ? +L Nd-Cl
Struktur-
NdCl2 66.7 oP12 Pnma C23 Co 2Si
? +L L Nd4Cl9 69.2 … … … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
900
Nd7Cl16 69.6 … … … …
864°C
Nd3Cl7 70 … … … …
835°C
NdCl3 75 hP8 P6 3/m … UCl 3
818°C
800 808°C G.I. Novikov and O.G. Polyachenok, Russ. J. Inorg. Chem., 8(5), 545-550 (1963)
764°C 768°C
703°C
700
692°C 676°C
? + NdCl2
631°C
600
64 65 66 67 68 69 70 71 72 73 74 75
Atomic Percent Chroline
Cl-Ni
0 10 20 30 40 50 60 70 80 90 100
1800
L1
1600 L1 + L2
1455°C
L2 Ni-Cl
1400
Struktur-
1009.1°C
1000 977.5°C NiCl2 66.7 hR9 R 3m … CdCl2
800 H. Okamoto, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed., ASM
International, 68-69 (1991)
600
(Ni)
400
200
0
0 10 20 30 40 50 60 70 80 90 100
Ni Atomic Percent Chlorine Cl

Cl-O
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
-55
-59.6°C
-60
L
-65 Cl-O
Struktur-
-70 Composition, Pearson Space bericht
-75
ClO2 66.7 … … … …
-80
-85
J. Kepinski and K. Kalucki, Can. J. Chem., 48, 2320-2323, (1970)
-90
-95
-100 -101.6°C
-100.97°C
T.P. 1.6
-105
(Cl)
-110
0 10 20 30 40 50 60 70 80 90 100
Cl Atomic Percent Oxygen O
80
85 90 95 100
Cl-P
160
140
120 L
100
80
P-Cl
Struktur-
60
40 L Phase at.% Cl symbol group designation Prototype
PCl3 75 oP16 Pnma … PCl 3
20
PCl5 83.3 TP25 P4/n … PCl 5
0 (Cl) 100 oC8 Cmca A14 I
-20
-40
-60
-80
-94°C
-100 -100.97°C
PCl3 (Cl)
-120
75 80 85 90 95 100
248
Cl Weight Percent Chlorine Cl-Pb
0 5 10 15 20 25
550
L1 + L2 L2
500 497°C Pb-Cl

L1 486°C Struktur-
450 (Pb) 0 cF4 Fm 3 m A1 Cu
PbCl 2 66.7 oP12 Pnma C23 Co 2Si

400
350
327.502°C 327°C
(Pb)
300
0 10 20 30 40 50 60 70
Pb Atomic Percent Chlorine

Cl-Pd
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1200
(Pd) + G
1000 980°C 61 Pd-Cl

Struktur-
(Pd) + L L+G Phase at.% Cl symbol group designation Prototype
800
L 680°C gPdCl2
674°C 66.7 … … … …
bPdCl2 66.7 oP6 Pnmn … …
600
aPdCl2 66.7 … … … …
504°C
bPdCl2 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
401°C
400
1156-1157 (1990)
200 (Pd) G
0
0 10 20 30 40 50 60 70 80 90 100
Pd Atomic Percent Chlorine Cl
0 10
20 30 40 50 60 70 80 90100
Cl-Pr
850
L
(bPr)
800 Pr-Cl
795°C 785°C
Struktur-
(bPr) 0 to 1 cI2 Im 3 m A2 W
(aPr) (aPr) 0 hP2 P63/mmc A3 Mg
700
PrCl2.3 69.7 cF* … … …
659°C PrCl3 75 hP8 P63/m … …
650 645°C (Cl) 100 oC8 Cmca A14 I

600 594°C
550
500
0 10 20 30 40 50 60 70 80 90 100
Pr Atomic Percent Chlorine Cl
Cl
0
10 20 30 40 50 60 80 100
Cl-Pu
1200
1100
Pu-Cl
Struktur-
1000
L1 L1 + L2 L2 Phase at.% Cl symbol group designation Prototype
900 (d’Pu) 0 tI2 I4/mmm A6 In
800
767°C (bPu) 0 mC34 C2/m … bPu
740°C
(aPu) 0 mP16 P2 1/m … aPu
700 PuCl3 75 hP8 P6 3/m … …
640°C
640°C (Cl) 100 oC8 Cmca A14 I
600
(ePu)
H. Okamoto, J. Phase Equilibria, 20(5) 534 (1999)
500 (d'Pu)
483°C
463°C
(dPu)
400
0 10 20 30 40 50 60 70 80 90 100
Pu Atomic Percent Chlorine Cl
0 10
20 30 40
Cl-Rb
800
747°C
706°C,38.7
700 696°C
L 30.1 45.1
Rb-Cl
600
L1 + L2 Struktur-
500 (Rb) 0 cI2 Im 3 m A2 W
RbCl 50 cF8 Fm 3 m B1 NaCl
400
300 1156, 1158 (1990)
200
100
39.48°C
(Rb)
0
0 10 20 30 40 50 60 70
Rb Atomic Percent Chlorine
37 38 39
40 41 42 43 44 45 46 47 48
Cl-Re
700
L Re-Cl
600
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

(Re)* 0 hP2 P63 /mmc A3 Mg
500 ReCl3 ReCl3 75 hR72 R 3m ... ...
ReCl4 80 mP20 P12/c1 ... ...
ReCl5 83.3 mP48 P121 /c1 ... ...
(Cl)* 100 oC8 Cmca A14 I
400
* Not shown
350°C
D.V. Drobot, V.A. Aleksandrova, and B.G. Korshunov, Russ. J. Inorg. Chem.,
15(5), 584-585 (1970)
300
278°C
260°C
ReCl5
200
75 76 77 78 79 80 81 82 83
250
Cl-S
0 10 20 30 40 50 60 70 80 90 100
300
S-Cl
200
Struktur-
L+G
115.22°C
SCl 50 oF64 Fdd2 … SCl
100
SCl2 66.7 oF24 P2 12 12 1 … SCl2
SCl4 80 cP160 P 4 3n … SeCl4
0 L
L.A. Nisel’son, T.D. Sokolova, and S.I. Solov’ev, Russ. J. Inorg. Chem., 25(2),
-34.05°C
B.P. 284-288 (1980)
-70°C ?
-86°C -81°C?
-100 -100.75°C
-101°C T.P.
-132°C
-129°C?
-168°C?
-200
0 10 20 30 40 50 60 70 80 90 100
S Atomic Percent Chlorine Cl
50
60 70 80 90 100
Cl-Sb
80
72°C
60
40
Sb-Cl
20
Struktur-
0
SbCl3 75 oP16 Pnma … SbCl 3
SbCl5* 83.3 hP12 P6 3/mmc … SbCl 5
-20 (Cl) 100 oC8 Cmca A14 I
* Not shown.
-40
SbCl 3
-60
-80 -82°C
-100 -103°C -100.97°C

(Cl)
75 80 85 90 95 100
Weight Percent Chlorine Cl-Sc

0 10 20 30 40 50 60 70 80 90 100
1200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1100 L
Sc-Cl
Struktur-
(aSc) 0 hP2 P63/mmc A3 Mg
900 877°C Sc2Cl3 60 … … … …
ScCl3 75 hR24 R 3m … …
803°C
800
1159-1160 (1990)
700
(aSc)
600
500
0 10 20 30 40 50 60 70 80 90 100
Sc Atomic Percent Chlorine Cl
Cl
0 10
20 30 40 50 60 70 80 90 100
Cl-Se
350
300
250
L Se-Cl
221°C Struktur-
200
150
(Se) 0 hP3 P3121 A8 gSe
SeCl4 80 … … … …
100
H. Oppermann, U. Hanke, and G. Krabbes, Z. Anorg. Allg. Chem., 542, 89-101
50 (1986) in German
(Se)
0
-50
-100
0 10 20 30 40 50 60 70 80 90 100
Se Atomic Percent Chlorine Cl
32 34
36 38 40
Cl-Sm
900
858°C
Sm-Cl
800
Struktur-
770°C
bSmCl2 66.7 … … … …
700
681°C aSmCl2 66.7 oP12 Pnma C23 Co2Si
Sm5Cl11 68.8 … … … …
633°C Sm13Cl30 69.8 … … … …
626°C Sm3Cl7 70 … … … …
600 SmCl3 75 hP8 P6 3/m … UCl3
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
575°C
529°C D.M. Laptev, V.F. Goryushkin, I.S. Astakhova, and G.G. Polyakova, Russ. J.
511°C Inorg. Chem., 24(5), 730-733 (1979)
500 487°C
400
67 68 69 70 71 72 73 74 75
0 10
20 30 40 50 60 70 80 90 100
Cl-Sn
400
Sn-Cl
Struktur-
L1
L1 + L2 L2
245°C (aSn) 0 cF8 Fd 3 m A4 C (diamond)
231.9681 SnCl2 66.7 oP12 Pnam … …
232°C
SnCl4 80 mP20 P21/c … …
200
(bSn) 1159, 1161 (1990)
100
(aSn)
13°C
0
0 10 20 30 40 50 60 70 80 90 100
Sn Atomic Percent Chlorine Cl
252
Cl-Sr
0 10 20 30 40 50 60 70 80 90 100
1200
1106°C
L
49
Sr-Cl
1000 Struktur-
L1 + L2
873°C
838°C
65.4 (aSr) 0 cF4 Fm 3 m A1 Cu
800
769°C 754°C
SrCl2 66 to 66.7 cF12 Fm 3 m C1 CaF 2
2
(bSr)
1159, 1162 (1990)
600
547°C
(aSr)
400
0 10 20 30 40 50 60 70 80 90 100
Sr Atomic Percent Chlorine Cl

0 10 20 30 40 50 60 70 80 90 100
Cl-Te
500
449.57°C
Te-Cl
400
Struktur-
(Te) 0 hP3 P31 21 A8 gSe
300
Te3Cl2 40 mP20 P21 /c … …
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
TeCl4 80 mC80 C2/c … …
239°C
223°C
200
1163-1164 (1990)
(Te)
100
0
0 10 20 30 40 50 60 70 80 90 100
Te Atomic Percent Chlorine Cl
0
10 20 30 40 50 60 70 80 100
Cl-Th
1200
L
1000 Th-Cl
(aTh) + L
Struktur-
800 771°C
(bTh) 0 cI2 Im 3 m A2 W
700°C
675°C (reaction unknown)
600
bThCl4 80 tI20 I41/amd … …
aThCl4 80 … … … …
400
1163, 1165 (1990)
200
(aTh)
0
0 10 20 30 40 50 60 70 80 90 100
Th Atomic Percent Chlorine Cl
Cl-Tl
0 10 20 30 40 50 60 70 80 100
500
L
430°C
Tl-Cl
400 388°C bTl2Cl 3
Struktur-
366°C
56.4
304°C (bTl) 0 cI2 Im 3 m A2 W
300
(bTl) TlCl 50 cP2 Pm 3 m B2 CsCl
232°C
230°C bTl2Cl3 60 … … … …
200 aTl2Cl3 60 hP160 P 31 c … …
TlCl 2 66.7 … … … …
152°C
TlCl 3 75 mC16 C2/m
132°C
70
(aTl)
1163, 1166 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Tl Atomic Percent Chlorine Cl

25 30 35 40 45
Cl-Tm
900
828°C
Tm-Cl
800
L Struktur-
728°C (Tm) 0 hP2 P6 3/mmc A3 Mg
718°C
TmCl2 66.7 oP24 Pbca … …
700 <9 compounds>
TmCl3 75 mC16 C2/m … …
662°C 658°C
652°C
647°C
640°C
631°C
600 609°C 1167-1168 (1990)
585°C
578°C
500
60 65 70 75 80
44 45 46
47 48 49 50 51 52 53 W-Cl
Cl-W
300
Struktur-
280°C
(a)
L 270°C (W) 0 cI2 Im 3 m A2 W
260 WCl2(a) 66.7 oC72 Cmca ... MoCl2
WCl3(a) 75 hR72 R3 ... ...
240°C
WCl4 80 mC20 C12/m1 ... ...
240
bWCl5 83.3 … … ... ...
aWCl5 83.3 mC72 C12/m1 ... ...
220
220°C
gWCl6 85.7 … … ... ...
bWCl6 85.7 hP21 P 3 m1 ... UCl6
198°C
aWCl6 85.7 hR21 R3 ... ...
200
190°C
(Cl)(a) 100 oC8 Cmca A14 I
(a) Not shown
180°C
180
176°C D.V. Drobot and A.V. Nikolaev, Zh. Neorg. Khim., 22(8), 2248-2250 (1977) in
Russian, TR: Russ. J. Inorg. Chem., 22(8), 1217-1218 (1977)
160
see also
D.V. Drobot, S.A. Ulanov, and A.V. Nikolaev, Zh. Neorg. Khim., 1977, 22(7),
140
1956-1960 (1977) in Russian, TR: Russ. J. Inorg. Chem., 1977, 22(8), 1062-
80 81 82 83 84 85 1064 (1977)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
254
Cl-Y
50 55 60
900
L Y-Cl
Struktur-
800 (aY) + L Composition, Pearson Space bericht
715°C
721°C YCl 3 75 mC16 C2/m … …
74.56
700
1167, 1169 (1990)
600
(aY) + YCl3
500
70 71 72 73 74 75 76 77 78 79 80

30 40
Cl-Yb
1000
900 875°C
L Yb-Cl
800 Struktur-
648
602.5°C
600 70.3 (bYb) 0 cF4 Fm 3 m A1 Cu
(aYb) 0 hP2 P63 /mmc A3 Mg
500
YbCl2 66.7 oP24 Pbca … …
<7 compounds>
400 YbCl3 75 mC16 C2/m … …
200 1170-1171 (1990)
100
0
60 65 70 75 80
Weight Percent Chromium Cm-Cr

0 10 20 30 40 50 60 70 80 100
2000
1900
1863°C
1800
Cm-Cr
1700 Struktur-
1500
(bCm) 0 cF4 Fm 3 m A1 Cu
1400
1345°C (aCm) 0 hP4 P63/mmc A3’ aLa
1300 (bCm)
1277°C (Cr) 100 cI2 Im 3 m A2 W
1200
1100
M. Venkataman, J.P. Neumann, and D.E. Peterson, Bull. Alloy Phase Diagrams,
6(5), 4176-417 (1985)
1000
900 860°C
41
800
700
(aCm) (Cr)
600
500
0 10 20 30 40 50 60 70 80 90 100
Cm Atomic Percent Chromium Cr

--`,`,``,`,```,,``,``,`
Cm Weight Percent Molybdenum
Cm-Mo
0 10 20 30 40 50 60 70 80 90 100
5000
4639°C
4500 G
Cm-Mo
4000 Struktur-
3500 L2
G + L2 (bCm) 0 cF4 Fm 3 m A1 Cu
(aCm) 0 hP4 P6 3/mmc A3’ aLa
3000 (Mo) Im 3 m
100 cI2 A2 W
2623°C
2500
G + (Mo) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1173-1174 (1990)
2000
L1 L1 + (Mo)
1500 (bCm)
1345°C
1277°C
(aCm) (Mo)
1000
0 10 20 30 40 50 60 70 80 90 100
Cm Atomic Percent Molybdenum Mo
8 9
10 11 12 13
Cm-O
2500
L
2265°C
PO2= 1/5 atm
Cm-O
2000
Struktur-
(bCm) 0 cF4 Fm 3 m A1 Cu
1500
L + aCm2 O3 (aCm) 0 hP4 P63/mmc A3’ aLa
bCm2O3 60 to 60.2 hP* … … …
aCm2O3 60 to 60.2 m** … … …
1000 “Cm2O3 ” 60.8 to 62.9 cI80 Ia 3 D53 Mn2O3
CmO1.71 63.7 to 63.9 hR* … … …
(aCm) "Cm2O3" CmO1.85 64.9 to 65 … … … …
+ CmO2 66.6 to 66.8 cF12 Fm 3 m C1 CaF2
500 aCm2O3
P.K. Smith and D.E. Peterson, J. Chem. Phys., 52(10), 4963-4972 (1970)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
56 58 60 62 64 66 68 70
60
70 80 90 100
Cm-Pd
1600 ~1550°C
1555°C
L Cm-Pd
1400
Struktur-
1200 1156°C Phase at.% Pd symbol group designation Prototype
86.5 90 (bCm) 0 cF4 Fm 3 m A1 Cu
1000 (aCm) 0 hP4 P63 /mmc A3’ aLa
CmPd3 ~75 cP4 Pm 3 m L12 AuCu3
800 (Pd) 90 to 100 cF4 Fm 3 m A1 Cu
(Pd)
V.M. Radchenko, A.G. Seleznev, L.S. Lebedeve, R.R. Droznik, M.A. Ryabinin,
600 CmPd3 and V.D. Shushakov, Radiokhimiya, 31(2), 1-7 (1989) in Russian, TR: Soviet
Radiochemistry, 31, 146-150 (1989)
400
200
0
70 75 80 85 90 95 100
Atomic Percent Palladium Pd
256
Cm Weight Percent Platinum
Cm-Pt
0 10 20 30 40 50 60 70 80 90 100
2200
Cm-Pt
2000 Struktur-
1800
1769.0°C (bCm) 0 cF4 Fm 3 m A1 Cu
(aCm) 0 hP4 P63/mmc A3’ aLa
1600
Cm3Pt 25 … … … …
Cm7Pt3 30 … … … …
Cm2Pt 33.3 … … … …
1400
Cm5Pt3 37.5 … … … …
1345°C CmPt 50 … … … …
(bCm)
1277°C (Pt) Cm3Pt4 57.1 … … … …
1200 CmPt2 66.7 to 75 cF24 Fd 3 m C15 Cu2Mg
CmPt5 83.3 o*72 … … Pt5Sm
(Pt) ? to 100 cF4 Fm 3 m A1 Cu
1000
(aCm) D.E. Peterson, Bull. Alloy Phase Diagrams, 10(2), 117-118 (1989)
800
0 10 20 30 40 50 60 70 80 90 100
Cm Atomic Percent Platinum Pt
0 10 20 30
40 50 60 70 80 90 100
Cm-Pu
1400
1350°C
1310°C (gCm) Cm-Pu
1200
L Struktur-
(bCm)
1040°C
1000 960°C (gCm) 0 to 50 cI2 Im 3 m A2 W
(bCm) 0 to 60 cF4 Fm 3 m A1 Cu
(aCm) 0 to ? hP4 P63/mmc A3’ aLa
800
(a’Cm) ? to 50 … … … …
647°C (ePu) ? to 100 cI2 Im 3 m A2 W
(a'Cm) 640°C
600 618°C (d’Pu) 100 tI2 I4/mmm A6 In
520°C (ePu)
(dPu) 93.5 to 100 cF4 Fm 3 m A1 Cu
483°C
(aCm) (gPu) gPu
463°C 100 oF8 Fddd …
400 (d'Pu) (dPu)
290°C 320°C
(gPu) (aPu) 100 mP16 P21 /m … aPu
215°C
200
(bPu)
125°C
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100
Cm Atomic Percent Plutonium Pu
0 10 20
30 40 50 60 70 80 90 100
Co-Cr
2000
1990Ish 1863°C
1800
2002Oik
Co-Cr
L Struktur-
1600
1495°C (aCo) 0 to 43 cF4 Fm 3 m A1 Cu
1400 (eCo) 0 to 38.3 hP2 P63 /mmc A3 Mg
(Cr) s 53.6 to 67 tP30 P42 /mnm D8b sCrFe
(Cr) 47 to 100 cI2 Im 3 m A2 W
1200
For [1990Ish].
1121°C (aCo)
1000
s
800
(eCo)
600
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Chromium Cr

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Co Weight Percent Copper
Co-Cu
0 10 20 30 40 50 60 70 80 90 100
1600
1495°C
L
1400
Co-Cu
Struktur-
1200
1112°C
1121°C Tc
1050°C 1084.87°C (aCo) 0 to 19.7 cF4 Fm 3 m A1 Cu
(Cu)
1000 (eCo) 0 hP2 P63 /mmc A3 Mg
(Cu) 92 to 100 cF4 Fm 3 m A1 Cu
800 T. Nishizawa and K. Ishida, Bull. Alloy Phase Diagrams, 5(2), 161-165 (1984)
600
422°C
400
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Copper Cu
0 10 20 30 40 50
60 70 80 90 100
Co-Dy
1600
1495°C
(bDy)
Co-Dy
1400 1390°C
1412°C Struktur-
1381°C
1360°C 1350
1325
1270°C L Phase at.% Dy symbol group designation Prototype
1200
(eCo) 0 hP2 P6 3/mmc A3 Mg
Co17Dy2 10.5 hR19 R 3m … Th2Zn17
Co5Dy 16.7 hP6 P6/mmm D2d CaCu 5
1000
Co7Dy2 22.2 hR18 R 3m … Co7Er2
Co3Dy 25 hR12 R 3m … Be3Nb
845°C
Co2Dy 33.3 cF24 Fd 3 m C15 Cu2Mg
800
735°C
Co7Dy12 63.2 mP38 P21/c … Co7Ho12
716°C 725°C
(aCo) 57.14 66.6 CoDy3 75 oP16 Pnma D011 Fe3C
600 (aDy) 100 hP2 P6 3/mmc A3 Mg
(aDy)
(bCo) H. Okamoto, J. Phase Equilibria, 17(1), 79-80 (1996)
422°C
400
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Dysprosium Dy
0 10 20 30 40 50
60 70 80 90 100
Co-Er
1600
1529°C
1500
1495°C 1442°C
Co-Er
1339
1363 1347°C
1300
7.7 1330 1340 Phase at.% Er symbol group designation Prototype
1240 (aCo) 0 cF4 Fm 3 m A1 Cu
1200 (eCo) 0 hP2 P63/mmc A3 Mg
Co17 Er2 10.5 hP38 P63/mmc … Ni17 Th2
1100
Co5 Er 16.7 hP6 P6/mmm D2d CaCu5
1000 Co7 Er2 22.2 hR18 R 3m … Co7 Er2
912°C
Co3 Er 25 hR12 R 3m … Be3Nb
900 Co2 Er 33.3 cF24 Fd 3 m C15 Cu2 Mg
795°C
825°C
805°C Co7 Er12 63.2 mP38 P21 /c … Co7 Ho12
800
56.25 67.5 CoEr3 75 oP16 Pnma D011 Fe3C
(aCo) (Er) 100 hP2 P63/mmc A3 Mg
700 (Er)
600
500
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Erbium Er
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
258
Co Weight Percent Iron
Co-Fe
0 10 20 30 40 50 60 70 80 90 100
1600
L 1538°C
1500
1495°C (dFe)
1400 1394°C
Co-Fe
1300 Struktur-
1200 (aCo, gFe) Composition, Pearson Space bericht
1121°C Phase at.% Fe symbol group designation Prototype
1100
Tc (aCo,gFe) 0 to 100 cF4 Fm 3 m A1 Cu
1000
912°C (dFe)
900 83 to 100 cI2 Im 3 m A2 W
800 Tc (aFe) 23 to 100 cI2 Im 3 m A2 W
770°C
(aFe) a’ 25 to 90 cP2 Pm 3 m B2 CsCl
700
600
H. Okamoto, J. Phase Equilibria Diffusion, , 29(4), 383-384 (2008)
500
422°C
400 a’
300
200
(eCo)
100
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Iron Fe
0 10 20 30
40 50 60 70 80 90 100
Co-Ga
1600
1495°C
Massalski2
1400 2004Su
L
Co-Ga
1200
1210°C
Struktur-
(aCo)
1000
(aCo) 0 to 19 cF4 Fm 3 m A1 Cu
855°C
800 b b Pm 3 m
29 to 64 cP2 B2 CsCl
CoGa3 75 tP16 P 4 n2 … …
600 (Ga) 100 oC8 Cmca A11 Ga
For [Massalski2].
422°C
400
200
(Ga)
30.5°C 29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Gallium Ga
0 10 20 30 40 50
60 70 80 90 100
Co-Gd
1600
Co-Gd
1495°C
Struktur-
1400 6. 7 1385°C
18.0 (bGd) Composition, Pearson Space bericht
1370°C Phase at.% Gd symbol group designation Prototype
1346 25.9 1313°C
1297
29.7 L 1262°C
1276 (aCo) 0 cF4 Fm 3 m A1 Cu
1200 97.5 1235°C
1115°C
44.5
Co17Gd2 10.5 hR19 R 3m … Th2Zn17
1000 hP38 P63/mmc … Ni17Th2
Co5Gd 16.7 hP6 P6/mmm D2d CaCu5
(aCo)
Co7Gd2 22.2 hR18 R 3m … Co7Er2
850°C 780°C
800 73.9 hP36 P63/mmc … Ni7Ce2
670°C 60.9 Co3Gd 25 hR12 R 3m … Be3Nb
645°C
63.2 Co2Gd 33.3 cF24 Fd 3 m C15 Cu2Mg
600
Co3Gd4 57.1 hP2 P63 /m … Co3Ho4
CoGd3 75 oP16 Pnma D011 Fe3C
422°C (aGd)
400 (bGd) 100 cI2 Im 3 m A2 W
( e Co)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`-

0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Gadolinium Gd
Co Weight Percent Germanium
Co-Ge
0 10 20 30 40 50 60 70 80 90 100
1600
1495°C Co-Ge
1400 Struktur-
1210°C
1200 37.5 (aCo) 0 to 17.5 cF4 Fm 3 m A1 Cu
1123°C
1108 (eCo)
1121°C 17.5
25.5
32.5 0 to 18 hP2 P6 3/mmc A3 Mg
(aCo) 985°C 52.5
Co3Ge 21.5 to 22 cP8 Pm 3 n A15 Cr3Si
1000 43
938.3°C Co5Ge2 28.6 hP* … … …
Tc bCo 5Ge3 32.5 to 43 hP6 P6 3/mmc B82 Ni2In
832°C 817°C
800 770°C 806°C 73
aCo 5Ge3 36.5 to 40 oP* Pbnm … …
Co3Ge
34.5 CoGe 48.5 to 52.5 mC16 C2/m … …
cF8 P213 B20 FeSi
600 636°C Co5Ge7 58.3 tI24 I4mm … …
CoGe2 66.7 oC24 Aba2 … …
(Ge) (Ge) 100 cF8 Fd 3 m A4 C (diamond)
422°C
400 (eCo) 382° C
36.5
aCo5Ge3
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Germanium Ge
0 0.01
0.02 0.03
Co-H
1600
PH = 50 MPa L
2 L+G
1400 Co-H
Struktur-
(aCo) (aCo) Fm 3 m
0 to 0.5 cF4 A1 Cu
(eCo) 0 to 0.2 hP2 P63 /mmc A3 Mg
1000
(aCo) + G Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1192-1194 (1990)
800
600
(eCo) (eCo) + G
400
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
Co Atomic Percent Hydrogen
0 10 20 30 40 50
60 70 80 90 100
Co-Hf
2400
2231°C
2200
L Co-Hf
2000
(bHf) Struktur-
1800 Phase at.% Hf symbol group designation Prototype
1670°C 1743°C
43.5
1640°C (aCo) 0 to 2 cF4 Fm 3 m A1 Cu
1600
1495°C 1550°C (eCo) 0 to 0.5 hP2 P6 3/mmc A3 Mg
1400 1350°C Co7Hf 12.5 tP32 … … …
27 1315°C
1230°C
1270°C Co23Hf6 20.7 cF116 Fm 3 m D8a Mn2 3Th 6
74 86
1200 11 Co7Hf2 22.2 mC36 C2/m … Ni7Zr2
1050°C Co2Hf 27 to 36 cF24 Fd 3 m C15 Cu2Mg
1000 950°C
CoHf 49 to 51 cP2 Pm 3 m B2 CsCl
800 CoHf2 67 to 74 cF112 Fd 3 m E93 Fe3W3C
(bHf) 95 to 100 cI2 Im 3 m A2 W
(aCo) (aHf)
600 (aHf) 98 to 100 hP2 P6 3/mmc A3 Mg
422°C 400°C
400
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Hafnium Hf

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
260
Co Weight Percent Mercury
Co-Hg
0 10 20 30 40 50 60 70 80 90 100
1600
L1 L1 + G
1495°C
1400
Co-Hg
1200
Struktur-
(aCo) (aCo) + G
G (aCo) 0 cF4 Fm 3 m A1 Cu
800 (eCo) 0 hP2 P6 3/mmc A3 Mg
600
C. Guminski, J. Phase Equilibria, 14(5), 643-647 (1993)
422°C
400 (eCo) + G
356.623°C
200
(eCo) (eCo) + L2 L2
0
-38.8290°C
(eCo) + (Hg) (Hg)
-200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Mercury Hg
0 10 20 30 40 50
60 70 80 90 100
Co-Ho
1600
Co-Ho
1495°C
1474°C Struktur-
1400 1390°C
1345
1370°C
1365
L (aCo)
7 1340 1330°C 0 cF4 Fm 3 m A1 Cu
1200 Co17Ho2 ~10.5 hR19 R 3m … Th2Zn17
hP38 P6 3/mmc … Ni17Th2
1150°C
hP52 P6 3/mmc … …
Co5Ho ~16.7 hP6 P6/mmm D2d CaCu 5
1000 Co7Ho2 22.2 hR18 R 3m … Co7Er2
Co3Ho 25 hR12 R 3m … Be3Nb
895°C
(aCo) Co2Ho 33.3 cF24 Fd 3 m C15 Cu2Mg
Co3Ho4 57.1 hP22 P63/m … …
795°C
800 775°C 60 770°C Co7Ho12 63.2 mP38 P21/c … …
755°C
67
(Ho) CoHo3 75 oP16 Pnma D011 Fe3C
(Ho) 100 hP2 P6 3/mmc A3 Mg
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Holmium Ho 1196-1197 (1990)
0 10 20 30 40
50 60 70 80 90 100
Co-In
1600
1502°C
1495°C L 60
1400 L1 + L2 Co-In
1286°C
Struktur-
1000
(aCo)
CoIn 2 66.7 oF48 Fddd Cb CuMg 2
800
CoIn 3 75 tP16 P 4 n2 … CoGa3
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600 550°C
422°C
400
200 (eCo) 156°C

156.634°C
(In)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Indium In
Co Weight Percent Iridium
Co-Ir
0 10 20 30 40 50 60 70 80 90 100
2500
2447°C
2000 L Co-Ir
Struktur-
1500
1495°C (aCo,Ir) 0 to 100 cF4 Fm 3 m A1 Cu
(eCo) 0 to ? hP2 P63/mmc A3 Mg
(aCo,Ir)
1000
Heating W. Koster and E. Horn, Z. Metallkd., 43, 444-449 (1952)
Cooling
500
422°C Tc
(eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Iridium Ir
0 0. 2 0.4
0.6 0.8 1.0 1.2 1.4
Co-K
500
(aCo) + L
(aCo)
477°C
0.35
Co-K
Struktur-
450
(aCo) ~0 cF4 Fm 3 m A1 Cu
(eCo) ~0 hP2 P63/mmc A3 Mg
(K) ~100 cI2 Im 3 m A2 W
400
(eCo) (eCo) + L U. Haschimoto, Nippon Kinzoku Gakkai-shi, 2(2), 67-77 (1938) (Phase diagram)
K. Ishida and T. Nishizawa, Binary Alloy Phase Diagrams, 2nd ed., T.B.
350
International, Materials Park, OH, 1201 (1990) (Table)
300
0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2
Co Atomic Percent Potassium

0 10 20 30 40 50 60 70 80 90 100
Co-La
1600
1495°C
Co-La
Struktur-
1400
1185°C
1200 L (aCo) 0 cF4 Fm 3 m A1 Cu
(aCo) 1090°C (eCo) 0 hP2 P63/mmc A3 Mg
1000 Co13La 7.1 cF112 Fm 3 c D23 NaZn13
918°C Co5La 16.7 hP6 P6/mmm D2d CaCu5
868°C (gLa)
800°C
865°C Co19La5 20.8 … … … …
800
Co7La2 22.2 hR18 R 3m … …
695°C
hP36 P63/mmc … Ni7Ce2
600 570°C Co3La2 40 oC20 CmCa … La2Ni3
543°C
521°C Co1.7La2 54.1 … … … …
523°C
422°C
CoLa3 75 oP16 Pnma D011 Fe3C
400 (bLa)
(eCo) 310°C
200 (aLa) 100 hP4 P63/mmc A3’ aLa
(aLa)
C.P. Wang, J. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, J. Alloys
0
0 10 20 30 40 50 60 70 80 90 100 Compd., , 453, 174-179 (2008)
Co Atomic Percent Lanthanum La

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---

Co Weight Percent Lithium Co-Li
0 1 2 3 4 5 6 7
700
(aCo) + L
28.6 650°C
29.5
Co-Li
600 (aCo) Struktur-
505°C (aCo) 0 to ? cF4 Fm 3 m A1 Cu
500
(eCo) 0 to 29.5 hP2 P63 /mmc A3 Mg
467°C
426°C
400
1201, 1203-1204 (1990)
(eCo) + L
300
Heating
(eCo)
Cooling
200
0 10 20 30 40
Co Atomic Percent Lithium
0 10 20 30 40 50
60 70 80 90 100
Co-Lu
1663°C
1600
1495°C Co-Lu
1400 Struktur-
1200
(aCo) (aCo) 0 cF4 Fm 3 m A1 Cu
1000
Co17 Lu2 8 to 12 hP38 P63/mmc … Ni17Th2
Co7 Lu2 22.2 hR18 R 3m … Co7Er2
800 R 3m
Co3 Lu 25 hR12 … Be3Nb
Co2 Lu 33.3 cF24 Fd 3 m C15 Cu2Mg
600 Co3 Lu4 57.1 hP22 P63/m … …
CoLu3 75 oP16 Pnma D011 Fe3C
422°C
400 (Lu) (Lu) 100 hP2 P63/mmc A3 Mg
(eCo)
1204-1205 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Lutetium Lu
0 10
20 30 40 50 60 70 80 90 100
Co-Mg
1600
1495°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1400 Co-Mg
Struktur-
1200 Phase at.% Mg symbol group designation Prototype
Tc
1121°C (aCo) 0 cF4 Fm 3 m A1 Cu
1000 970°C
Co2Mg 33.3 hP12 P63/mmc C14 MgZn2
(Mg) 100 hP2 P63/mmc A3 Mg
800
A.A. Nayeb-Hashemi and J.B. Clark, Bull. Alloy Phase Diagrams, 8(4), 352-
(aCo) 635°C
354 (1987)
650°C
600
422°C
400 (Mg)
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Magnesium Mg
Co Weight Percent Manganese Co-Mn
0 10 20 30 40 50 60 70 80 90 100
1800
1600 Co-Mn
L Struktur-
1400 Phase at.% Mn symbol group designation Prototype
(dMn)
1246°C (eCo) 0 to ? hP2 P63 /mmc A3 Mg
1200 1161°C
59 1138°C s 49.5 to 50.5 tP30 P42 /mnm D8b sCrFe
1121°C 62 (gMn) 1100°C
(dMn) 91 to 100 cI2 Im 3 m A2 W
1000 (gMn) 95 to 100 cF4 Fm 3 m A1 Cu
Tc
(aCo) (bMn) 52 to 100 cP20 P4132 A13 bMn
800 (bMn) (aMn) 96 to 100 cI58 I 4 3m A12 aMn
727°C
600
545°C
See also
422°C
400 (eCo) s (aMn)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Manganese Mn
0 10 20 30 40
50 60 70 80 90 100
Co-Mo
2800
2600 2623°C
2400
Co-Mo
2200 L Struktur-
2000 Phase at.% Mo symbol group designation Prototype
1800 (Mo)
1619°C
1600
1514°C a’ 16.5 to 19.5 hP2 P63 /mmc A3 Mg
1495°C
1400
e 25 hP8 P63 /mmc D019 Ni3Sn
1337°C
s m 41.5 to 49 hR13 R 3m D85 Fe7W6
1201°C
1200 (aCo) s 62 to 64.5 tP30 P42 /mnm D8b sCrFe
1121°C a' 1047°C
998°C (Mo) 93 to 100 cI2 Im 3 m A2 W
1000 1018°C
870°C m
e
600 532°C
422°C (eCo)
400
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Molybdenum Mo
0 2 4
6 8 10 12 14 16 18
Co-N
1700
L Co-N
1500
1495°C Struktur-
1300 ep Phase at.% N symbol group designation Prototype
(aCo) ~0 cF4 Fm 3 m A1 Cu
1115°C
1100 (eCo) ~0 hP2 P63/mmc A3 Mg
Co4 N 20 c** ... ... ...
Co3 N 25 hP* ... ... ...
900 Co2 N 33.3 oP6 Pnnm ... ...
CoN 50 cF8 Fm 3 m B1 NaCl
700 cF8 F 4 3m B3 ZnS (sphalerite)
500
422°C
International, Materials Park, OH, 1210 (1990) (Table)
300 (eCo)
A. Fernandez Guillermet and F. Jonsson, Z. Metallkd., 83(1), 21-31 (1992)
(Phase diagram)
100
0 10 20 30 40 50
Co Atomic Percent Nitrogen
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
264
Co
0 0.5
1.0 1.5 2.0 2.5 3.0
Co-Na
550
Co-Na
(aCo) + L
(aCo) Struktur-
480°C Phase at.% Na symbol group designation Prototype
0.5 (aCo) 0 cF4 Fm 3 m A1 Cu
450
(aNa) 100 hP2 P63 /mmc A3 Mg
U. Haschimoto, Nippon Kinzoku Gakkai-shi, 2(2), 67-77 (1938) (Phase diagram)
(eCo) (eCo) + L K. Ishida and T. Nishizawa, Binary Alloy Phase Diagrams, 2nd ed., T.B.
400
International, Materials Park, OH, 1210-1211 (1990) (Table)
350
0 1 2 3 4 5 6 7 8
Co Atomic Percent Sodium
0 10 20 30 40
50 60 70 80 90 100
Co-Nb
2500
2469°C
L Co-Nb
2000
Struktur-
1484°C (aCo) 0 to 5.5 cF4 Fm 3 m A1 Cu
1500 (aCo) 1424°C 1424°C
1495°C
1364°C (eCo) 0 hP2 P63/mmc A3 Mg
1379°C
1264°C 94.7 Co7Nb2 22.2 to 22.5 … … … …
1250°C
5.5 1239°C
1086°C
aCo2Nb 24 to 25 hP24 P63/mmc C36 MgNi2
1000
gCo2Nb 25 to 35.5 cF24 Fd 3 m C15 Cu2 Mg
1029°C
bCo2Nb 36 to 37.5 hP12 P63/mmc C14 MgZn2
Co6Nb7 47 to 57 hR13 R 3m D85 Fe7 W6
(Nb) 94.7 to 100 cI2 Im 3 m A2 W
(Nb)
500
422°C
(eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Niobium Nb
0 10 20 30 40 50
60 70 80 90 100
Co-Nd
1600 Co-Nd
Struktur-
1495°C
1306°C 1266°C
L (eCo) 0 hP2 P63/mmc A3 Mg
1200
1152°C
1143°C Co17 Nd2 10.5 hR19 R 3m … Th2Zn17
1100°C
1050°C
Co5Nd 16.7 hP6 P6/mmm D2d CaCu 5
1000
1021°C Co19 Nd5 20.8 hR24 R 3m … Co19Ce5
(bNd)
Co7Nd2 22.2 hR18 R 3m … …
863°C hP36 P63/mmc … Ni7Ce2
800 Co3Nd 25 hR12 R 3m … Be3Nb
Co2Nd 33.3 cF24 Fd 3 m C15 Cu2Mg
(aCo) 650°C 646°C
599°C 596
625°C bCo 3Nd2 40 … … … …
600 80
583°C 566°C 64
aCo 3Nd2 40 o** … … …
Co1.7Nd 2 54.1 h** … … …
422°C
400 (aNd) Co3Nd7 70 hP20 P6 3/mc D102 Fe3Th7
CoNd3 75 oP16 Pnma D011 Fe3C
(eCo) (bNd) Im 3 m
100 cI2 A2 W
200 (aNd) 100 hP4 P63/mmc A3’ aLa
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Neodymium Nd H. Okamoto, J. Phase Equilibria, 14(1), 122-124 (1993)

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Co Weight Percent Nickel
Co-Ni
0 10 20 30 40 50 60 70 80 90 100
1600
L
1495°C
1455°C
1400
Co-Ni
Struktur-
1200
1121°C
1000 (aCo,Ni) 0 to 100 cF4 Fm 3 m A1 Cu
Tc
800
T. Nishizawa and K. Ishida, Bull. Alloy Phase Diagrams, 4(4), 390-395 (1983)
600
(aCo,Ni)
422°C
400
361° C
200 (e Co)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Nickel Ni
0 5
10 15 20 25
Co-O
2300
2200
L
2100
Co-O
L1 + L2 Struktur-
2000
1900
1790°C
1813°C CoO 50 cF8 Fm 3 m B1 NaCl
1800
Co3 O4 57.1 cF56 Fd 3 m … …
1700
L.A. Zabdyr and O.B. Fabrichnaya, Calphad, 28, 293-298 (2004)
1600
1493°C
1500
1495°C
1400 (aCo)
1300
0 10 20 30 40 50 60
Co Atomic Percent Oxygen
0 10 20 30 40 50 60
70 80 90 100
Co-Os
2400
2000 L Co-Os
Struktur-
1600 Phase at.% Os symbol group designation Prototype
1495°C (aCo) 0 to 20 cF4 Fm 3 m A1 Cu
(eCo,Os) 0 to 100 hP2 P63/mmc A3 Mg
(aCo)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1200
1121°C W. Koster and E. Horn, Z. Metallkd., 43, 444-449 (1952)
(eCo,Os)
800
422°C
400 Tc
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Osmium Os
266
Co Weight Percent Phosphorus
Co-P
0 10 20 30 40
1600
1500
1495°C
Co-P
1400 1386°C
L Struktur-
1300 Phase at.% P symbol group designation Prototype
1200 Co2P 33 to 34 oP12 Pnma C23 Co2Si
CoP 50 oP8 Pnma B31 MnP
1100
K. Ishida and T. Nishizawa, Bull. Alloy Phase Diagrams, 11(6), 555-560 (1990)
1023°C
1000 19.9
900
(aCo)
800
700
0 10 20 30 40 50 60
Co Atomic Percent Phosphorus
0 10 20 30 40 50 60
Weight Percent Lead
70 80 90 100
Co-Pb
1600
L1 L1 + L2 L2
1495°C
1492°C 99.16
1400
Co-Pb
Struktur-
1200
1000 (eCo) 0 hP2 P6 3/mmc A3 Mg
(aCo) (aCo) + L2
800
Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH, ,
1220-1221 (1990)
600
422°C
400
(eCo) + L2
327.502°C
326°C
(eCo) (Pb)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Lead Pb
0 10 20 30 40
50 60 70 80 90 100
Co-Pd
1600
1555°C
1495°C
1400 L
Co-Pd
1217°C
1200 Struktur-
1000
Tc
(aCo,Pd) (aCo,Pd) 0 to 100 cF4 Fm 3 m A1 Cu
800

600
422°C
400
200
(eCo)
0
-200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Palladium Pd

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Co Weight Percent Praseodymium
Co-Pr
0 10 20 30 40 50 60 70 80 90 100
1495°C
Co-Pr
1400
Struktur-
1268°C 10.6 Composition, Pearson Space bericht
16.8
1200
1232°C Phase at.% Pr symbol group designation Prototype
28.8
1127°C
29.8 L (aCo) 0 cF4 Fm 3 m A1 Cu
1118°C 34.9
1065°C (eCo) 0 hP2 P63 /mmc A3 Mg
1000
937°C Co17Pr2 10.5 hR19 R 3m … Th2Zn17
931°C
854°C
43.6 Co5 Pr 16.7 hP6 P6/mmm D2d CaCu5
(bPr)
800 795°C Co19Pr5 20.8 hR24 R 3m … Co19 Ce5
Co7 Pr2 22.2 hR18 R 3m … …
22.2 hP36 P63 /mmc … Ni7 Ce2
600 588°C 59.5 579°C 569°C R 3m
67.8 Co3 Pr 25 hR12 … Be3 Nb
78.9
533°C 66.1 Co2 Pr 33.3 cF24 Fd 3 m C15 Cu2 Mg
422°C 544°C Co3 Pr4 57.1 hP14 … … Co3 Nd4
400
Co2 Pr5 71.4 mC28 C2/c … Pd5B2
(aPr) CoPr3 75 oP16 Pnma D011 Fe3C
200 (bPr) 100 cI2 Im 3 m A2 W
0
Co Atomic Percent Praseodymium Pr
0 10 20 30 40 50 60
70 80 90 100
Co-Pt
1800
1769.0°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1600
1495°C
Co-Pt
1400
Struktur-
1200 (aCo,Pt) Phase at.% Pt symbol group designation Prototype
1121°C
(aCo,Pt) 0 to 100 cF4 Fm 3 m A1 Cu
1000 Tc (eCo) 0 to ? hP2 P63/mmc A3 Mg
825°C CoPt 41 to 74 tP4 P4/mmm L1 0 AuCu
800 750°C CoPt3 ~75 cP4 Pm 3 m L1 2 AuCu3
600 CoPt3 H. Okamoto, J. Phase Equilibria, 22(5), 591 (2001)
422°C
400
(eCo) CoPt
200
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Platinum Pt
0 10 20 30 40 50 60
70 80 90 100
Co-Pu
1600
Co-Pu
1495°C Struktur-
1210°C 1230°C L (aCo) 0 cF4 Fm 3 m A1 Cu
1200
Tc 1170°C (eCo) 0 hP2 P63 /mmc A3 Mg
1121°C
Co17Pu2 10.5 hP38 P63 /mmc … Ni17Th2
1000
Co3Pu 25 hR12 R 3m … Be3Nb
Co2Pu 33.3 cF24 Fd 3 m C15 Cu2Mg
800 CoPu2 65.5 to 68 hP9 P 62 m C22 Fe2P
CoPu3 75 to 76 oC16 Cmcm E1a Re3B
600
605°C (d'Pu)
640° C CoPu6 85.7 tI28 I4/mcm D2c MnU6
(ePu) (ePu) 98 to 100 cI2 Im 3 m A2 W
483°C
422°C
442°C
415°C 463°C (d’Pu) 100 tI2 I4/mmm A6 In
405°C
400
395°C (dPu) (dPu) 100 cF4 Fm 3 m A1 Cu
320°C
(gPu) (gPu) 100 oF8 Fddd … gPu
215°C
200 (bPu) (bPu) 100 mC34 C2/m … bPu
125°C (aPu) 100 mP16 P2 1/m … aPu
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100 D.M. Poole, M.G. Bale, P.G. Mardon, J.A.C. Marples, and J.L. Nichols,
Co Atomic Percent Plutonium Pu Plutonium 1960, Cleaver-Hume Press, London, 267-280 (1961)
268
Co Weight Percent Rhenium
Co-Re
0 10 20 30 40 50 60 70 80 90 100
3500
3186°C
3000
Co-Re
L Struktur-
2000
(eCo,Re) 0 to 100 hP2 P63 /mmc A3 Mg
1500
15
25 1550°C
O.M. Barabash and Yu.N. Koval, ed., Crystal Structures of Metals and Alloys,
19
1495°C Naukova Dumka, Kiev, 241-242 (1986)
(aCo)
1000 (eCo,Re)
500
422°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Rhenium Re
0 10 20 30 40
50 60 70 80 90 100
Co-Rh
2000
1963°C
1800
L Co-Rh
1600 Struktur-
(aCo,Rh) 0 to 100 cF4 Fm 3 m A1 Cu
1200
(eCo) 0 to 49 hP2 P63/mmc A3 Mg
1121°C
1000 Tc
W. Koster and E. Horn, Z. Metallkd., 43, 444-449 (1952)
800 (aCo,Rh)
600
422°C
400
200 (eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Rhodium Rh
0 10 20 30 40
50 60 70 80 90 100
Co-Ru
2400
2334°C
Co-Ru
2000 L
Struktur-
1600
1495°C
(eCo,Ru) 0 to 100 hP2 P63/mmc A3 Mg
(aCo)
1200 W. Koster and E. Horn, Z. Metallkd., 43, 444-449 (1952)
1121°C
(eCo,Ru)
800
422°C Tc
400
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Ruthenium Ru
Co Weight Percent Sulfur
Co-S
0 10 20 30 40 50
1500
1495°C
L Co-S
Struktur-
1300
1121°C
Tc (aCo) 0 cF4 Fm 3 m A1 Cu
1100
Co4S3 42.7 to 44 … … … Maucherite
932°C
Co9S8 47.1 cF68 Fm 3 m D89 Co 9S8
900 877°C
40 833°C CoS 50 to 55 hP4 P63/mmc B81 NiAs
788°C Co3S4 57.1 cF56 Fd 3m D72 Co 3S4
Co4S3 CoS 2 65.5 to 66.7 cP12 Pa 3 C2 FeS2 (pyrite)
700 680°C
(aCo) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
500
1232-1233 (1990)
422°C
(eCo)
300
0 10 20 30 40 50 60 70
Co Atomic Percent Sulfur
0 10 20 30 40
50 60 70 80 90 100
Co-Sb
1600
1495°C 1991Oka
2004Li Co-Sb
1400
L
Struktur-
1217°C
1118°C (aCo) Fm 3 m
0 to 2.5 cF4 A1 Cu
1000 (aCo)
936°C b 43.5 to 52.5 hP4 P63/mmc B81 NiAs
874°C g 65 oP6 Pnnm C18 FeS2 (marcasite)
800 g’ 65 mP12 P21 /c … …
d 75 cI32 Im 3 D02 CoAs3
g 630.6°C
630.755°C
600 For [2001Oka].
422°C H. Okamoto, J. Phase Equilibria Diffusion, 26(2), 198 (2005)

400 377°C (Sb)
(eCo) g'
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Antimony Sb
0 10 20
30 40 50 60 70 80 90 100
Co-Sc
1800
1600
1520°C (bSc) 1541°C Co-Sc
1495°C
L Struktur-
1400
1337°C
1200 1140°C (aCo) 0 to 1.3 cF4 Fm 3 m A1 Cu
1.3 14.2 1050°C 54.2 (eCo) 0 hP2 P63 /mmc A3 Mg
1000 Co2Sc 31 to 36 cF24 Fd 3m C15 Cu2 Mg
76.8 Pm 3 m
819°C 840°C
870°C CoSc 48 cP2 B2 CsCl
99.9
800 63.9 CoSc2 66.7 tI12 I4/mcm C16 Al2Cu
(aCo) 773°C
CoSc3 77.3 oP32 Pnma … …
600 (bSc) 100 cI2 Im 3m A2 W
(aSc) 99.9 to 100 hP2 P63 /mmc A3 Mg
422°C 421°C
400 (aSc)
200 (eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Scandium Sc
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
270
Co Weight Percent Selenium
Co-Se
0 10 20 30 40 50 60 70 80 90 100
1600
L1 L1 + L2
1495°C 1448°C
1400 Co-Se
Struktur-
L2
1200 Phase at.% Se symbol group designation Prototype
1078°C
L2 + L3
L3 (aCo) 0 cF4 Fm 3 m A1 Cu
54
1000 952°C
70
910°C
50.7 938°C Co9Se8 47.1 cF68 Fm 3 m D89 Co9S8
44.5
Co1-xSe 50.7 to 59 hP4 P63 /mmc B81 NiAs
800
m** … … …
(aCo) CoSe2 66.7 cP12 Pa 3 C2 FeS2 (pyrite)
600 540°C (Se) 99.7 to 100 hP3 P3121 A8 gSe
420°C
422°C
400
417°C
217°C
1235, 1237 (1990)
221°C
200 (eCo)
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Selenium Se
0 10 20
30 40 50 60 70 80 90 100
Co-Si
1600
1495°C 1457°C L
Co-Si
1414°C Struktur-
1400
1327°C 1314°C 1320°C Composition, Pearson Space bericht
1304°C
1237°C 1238°C
13.1 77.9 (aCo) 0 to 13.1 cF4 Fm 3 m A1 Cu
1200
1194°C (eCo) 0 to 19 hP2 P63 /mmc A3 Mg
Co3 Si 25 t** … … …
(aCo) aCo2Si 32 to 33.3 oP12 Pnma C23 Co2 Si
1000 bCo2Si 33 to 34.5 … … … …
CoSi 49 to 51.5 cF8 P2 13 B20 FeSi
CoSi2 66.7 cF12 Fm 3 m C1 CaF2
(Si) (Si) 100 cF8 Fd 3 m A4 C (diamond)
800
600 (eCo)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Silicon Si
0 10 20 30 40 50
60 70 80 90 100
Co-Sm
1600
Co-Sm
Struktur-
1500
1400
1327°C
1347°C (aCo) 0 to 0.04 cF4 Fm 3 m A1 Cu
1322°C
1300 0.04 9.2 1270 L (eCo) 0 hP2 P63/mmc A3 Mg
1241
1200°C
Co17Sm2 10.5 to 12.5 hR19 R 3m … Th2Zn17
1200
Co5Sm 15 to 17.5 hP6 P6/mmm D2d CaCu5
Co19Sm5 20.8 hR24 R 3m … Co19Ce5
1100 1070°C
1072°C Co7Sm2 22.2 hR18 R 3m … …
(gSm)
1000 Co3Sm 25 hR12 R 3m … Be3Nb
922°C Co2Sm 33.3 cF24 Fd 3 m C15 Cu2Mg
900 Co4Sm9 69.2 o** … … …
CoSm3 75 oP16 Pnma D011 Fe3C
800 810°C (bSm)
(aCo)
734°C
700 (bSm) 100 hP2 P63/mmc A3 Mg
670°C
613°C 82.6 (aSm) 100 hR3 R 3m … aSm
600 590°C
63 (aSm)
Co4Sm9 H. Okamoto, J. Phase Equilibria, 16(4), 367-368 (1995)
500
0 10 20 30 40 50 60 70 80 90 100
See also
Co Atomic Percent Samarium Sm H. Okamoto, J. Phase Equilibria, 20(5), 535-536 (1999)
M.F. de Campos --`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
and F.J.G. Landgraf, J. Phase Equilibria, 21(5), 443-446 (2000)
Co Weight Percent Tin
Co-Sn
0 10 20 30 40 50 60 70 80 90 100
1600
1495°C Co-Sn
1400
Struktur-
1200 1181°C (aCo) 0 to 3 cF4 Fm 3 m A1 Cu
1121°C 1103°C (eCo) 0 hP2 P63 /mmc A3 Mg
bCo3Sn2 37 to 42 hP4 P63 /mmc B81 NiAs
Tc
1000 965°C aCo3Sn2 40 to 41 oP20 Pnma … Ni3Sn2
CoSn 50 hP6 P6/mmm B35 CoSn
(aCo) CoSn2 66.7 tI12 I4/mcm C16 Al2Cu
800
bCoSn3 75 tI16 I41/acd … …
aCoSn3 75 oC32 Cmca … PdSn3
600 570 °C
422°C
422°C
400
345°C
(eCo) 275°C (bSn)
232°C 231.9681°C
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Tin Sn
0 10 20 30 40 50
60 70 80 90 100
Co-Ta
3200
3000 3020°C Co-Ta

2800 Struktur-
2600
2400
L
2200 (eCo) 0 to ? hP2 P63 /mmc A3 Mg
2000 Co7 Ta2 22.2 … … … …
(Ta)
1800 1700°C 1800°C l3 27.5 to 29 hP24 P63 /mmc C36 MgNi2
1620°C
43 52 58
1670°C l2 29.9 to 36 cF24 Fd 3 m C15 Cu2Mg
1600
1570°C
1495°C 1450°C 1540 l1 37 hP12 P63 /mmc C14 MgZn2
1400
1280°C
l1 Co6 Ta7 44 to 56 hR13 R 3m D85 Fe7W6
1200 8
CoTa2 66.7 tI12 I4/mcm C16 Al2Cu
1130°C
950°C Im 3 m
1000 (Ta) 80 to 100 cI2 A2 W
800 (aCo) Co6Ta7
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
600
H. Okamoto, Binary Alloy Phase Diagrams Updating Service, H. Okamoto, ed,.
422°C ? l3 l2 ASM International, Materials Park, OH (1991)
400
200
(eCo) See also
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Tantalum Ta
0 10 20 30 40 50
60 70 80 90 100
Co-Tb
1600
Co-Tb
1495°C
Struktur-
1356°C
1355°C 1355
1325
1315°C (bTb) Phase at.% Tb symbol group designation Prototype
L 1289°C
(aCo) Fm 3 m
0 cF4 A1 Cu
1200 1185°C
(aCo)
Co17Tb2 ~10.5 hP38 P63/mmc … Ni17Th2
1000 hR19 R 3m … Th2Zn17
Co5Tb ~16.7 hP6 P6/mmm D2d CaCu5
840°C Co7Tb2 22.2 hR18 R 3m … Co7Er2
800 Co3Tb 25 hR12 R 3m … Be3Nb
695°C 700°C Fd 3 m
62.5 Co2Tb 33.3 cF24 C15 Cu2Mg
690°C
Co3Tb4 57.1 … … … …
600
Co7Tb12 63.2 mP38 P21 /c … …
(aTb) CoTb3 75 oP16 Pnma D011 Fe3C
422°C
400
(aTb) 100 hP2 P63/mmc A3 Mg
(eCo)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Terbium Tb 1244, 1246 (1990)
272
Co Weight Percent Tellurium
Co-Te
0 10 20 30 40 50 60 70 80 90 100
1600
L1 L1 + L2
1495°C 1460°C
1400 Co-Te
L2 Struktur-
1200 Phase at.% Te symbol group designation Prototype
Tc
1121°C (aCo) 0 cF4 Fm 3 m A1 Cu
1015°C (eCo) 0 hP2 P63/mmc A3 Mg
1000 980°C
b 55 to 65 hP4 P63/mmc B81 NiAs
g 66.5 to 69.7 oP6 Pnn2 … FeSb2
800 764°C (Te) 100 hP3 P31 21 A8 gSe
b
(aCo) K. Ishida and T. Nishizawa, Binary Alloy Phase Diagrams, 2nd ed., T.B.
448.5°C
422°C
400
g 449. 57°C
(eCo) (Te)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Tellurium Te
0 10 20 30 40 50 60
70 80 90 100
Co-Th
1800
1755°C
1600
Co-Th
Struktur-
1495°C 1460°C L (bTh) Composition, Pearson Space bericht
1425°C
1400 1410°C 1360°C
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
(aCo) 1300°C (aCo) 0 cF4 Fm 3 m A1 Cu
Tc 1125°C 1125°C 1130°C
1121°C 1100°C Co17Th2 10.5 hR19 R 3m … Th2Zn17
1100°C 1025°C Co5Th ~16.7 hP6 P6/mmm D2d CaCu5
1000 960°C
bCo7Th2 22.2 hR18 R 3m … Co7Er2
aCo7Th2 22.2 hP36 P63/mmc … Ce2Ni7
800 CoTh 50 oC8 Cmcm Bf CrB
Co3Th7 70 hP20 P63 /mc D102 Fe3Th7
600 (aTh) (bTh) 100 cI2 Im 3 m A2 W
422°C
400
K. Ishida, T. Nishizawa, and H. Okamoto, Binary Alloy Phase Diagrams, 2nd
(eCo) ed., T.B. Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed.,
200 ASM International, Materials Park, OH, 1247-1250 (1990)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Thorium Th
0 10 20
30 40 50 60 70 80 90 100
Co-Ti
1800
Co-Ti
1670°C
Struktur-
1495°C
(aCo) 0 to 14.4 cF4 Fm 3 m A1 Cu
1400 Pm 3 m
Co3Ti 19.3 to 24.5 cP4 L12 AuCu3
1325°C
Co2Ti(h) 28 to 31.25 hP24 P63/mmc C36 MgNi2
1235°C Co2Ti(c) 33 to 33.5 cF24 Fd 3 m C15 Cu2Mg
1190
1200
14.4 CoTi 45 to 51 cP2 Pm 3 m B2 CsCl
1170
1121°C CoTi2 66.7 to 67.1 cF96 Fd 3 m E93 Fe3W3 C
(aCo) 1058°C
51 72.9 1020°C
(bTi) 85.5 to 100 cI2 Im 3 m A2 W
1000 67.1 76.8 85.5 (bTi) (aTi) 99.2 to 100 hP2 P63/mmc A3 Mg
Tc
882° C J.L. Murray, Bull. Alloy Phase Diagrams, 3(1), 74-85 (1982)
800
See also
93 99.2
(aTi)
600
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Titanium Ti
Co Weight Percent Uranium
Co-U
0 10 20 30 40 50 60 70 80 90 100
1600
1495°C
Co-U
Struktur-
1400
L (aCo)
1200 1185°C 0 cF4 Fm 3 m A1 Cu
1120°C 1135°C (eCo) 0 hP2 P63/mmc A3 Mg
1090 Co11 U2 15.4 hR* R 3m … …
1000 Co4U 20 … … … …
(gU) Co3U 25 hR12 R 3m … Ni3Pu
830°C
805°C 826°C Co2U 27 to 33.3 cF24 Fd 3 m C15 Cu2Mg
800
(aCo) 734°C
756°C 776°C CoU 50 cI16 I213 Ba CoU
(bU) CoU6 85.7 tI28 I4/mcm D2c MnU6
668°C
(gU) 98.4 to 100 cI2 Im 3 m A2 W
600
(bU) 100 tP30 P42 /mnm Ab bU
422°C
400 (aU)
(eCo)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Uranium U
0 10 20
30 40 50 60 70 80 90 100
Co-V
2000
1910°C
1800
L Co-V
1600 Struktur-
1400
1422°C Phase at.% V symbol group designation Prototype
(V) (aCo) 0 to 33 cF4 Fm 3 m A1 Cu
1248°C (eCo) 0 to 2 hP2 P63 /mmc A3 Mg
1200
(aCo) 1070°C Co3V 18 to 26 hP24 P 6 m2 … …
1121°C
Tc 1026°C 1025°C s 46 to 69 tP30 P42 /mnm D8b sCrFe
1000 s
CoV3 75 cP8 Pm 3 n A15 Cr3Si
800
(V) 81 to 100 cI2 Im 3 m A2 W

600
See also
422°C
(eCo)
200
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Vanadium V

0 10 20 30 40 50 60 70 80 90 100
Co-W
3500
1989Gui
2006Ost
3000
Co-W
Struktur-
Co3W 25 hP8 P63/mmc D019 Ni3Sn
Co7W6 42 to 46 hR13 R 3m D85 Fe7W6
1500
1495°C (W) 98 to 100 cI2 Im 3 m A2 W
(aCo) For [1989Gui].
1121°C
1000 898°C H. Okamoto, J. Phase Equilibria Diffusion, 29(1), 119 (2008)
(W)
500
422°C
(eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Tungusten W
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
274
Co Weight Percent Yttrium
Co-Y
0 10 20 30 40 50 60 70 80 90 100
1600
1522°C
Co-Y
1495°C (bY) Struktur-
1478°C
1345°C
1308°C Phase at.% Y symbol group designation Prototype
1340°C 1320
L (aCo) 0 to 0.095 cF4 Fm 3 m A1 Cu
1200 1154°C (eCo) 0 hP2 P63/mmc A3 Mg
Co17Y2 10.3 to 11 hP38 P63/mmc … Ni17Th2
hR19 R 3m … Th2Zn17
1000
Co5Y 13.8 to 16.4 hP6 P6/mmm D2d CaCu5
866°C 889°C Co7Y2 22.2 hR18 R 3m … Co7Er2
800
798°C Co3Y 25 hR12 R 3m … Be3Nb
819°C
775 749°C 738°C hP24 P63/mmc … CeNi3
732 Fd 3 m
Co2Y 33.3 cF24 C15 Cu2Mg
(aY)
600 Co3Y2 40 cP* … … …
Co7Y6 45.4 … … … …
422°C
CoY 50 oC8 Cmcm Bf CrB
400 Co3Y4 57.1 hP22 P63 /m … …
1992Oka Co5Y8 61.5 mP52 P21 /c … …
2004Du
CoY3 75 oP16 Pnma D011 Fe3C
200 (bY) 100 cI2 Im 3 m A2 W
0 10 20 30 40 50 60 70 80 90 100
(aY) 100 hP2 P63/mmc A3 Mg
Co Atomic Percent Yttrium Y
0 10 20 30 40 50
60 70 80 90 100
Co-Yb
1800
L1 L2
1600 L1 + L2
1495°C Co-Yb
1400 Struktur-
1310°C
1200 Phase at.% Yb symbol group designation Prototype
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
Co17Yb2 10.5 hP38 P6 3/mmc … …
800 819°C Co3Yb 25 hR12 R 3m … …
795°C
Co2Yb 33.3 cF24 Fd 3 m C15 Cu2Mg
(gYb)
600
422°C
400
(bYb) Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
200 1261-1262 (1990)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Ytterbium Yb
Weight Percent Zinc

0 10 20 30 40 50 60 70 80 90 100
Co-Zn
1600
1495°C
1400 Co-Zn
L Struktur-
1200 Phase at.% Zn symbol group designation Prototype
1121°C (aCo) 0 to 36.8 cF4 Fm 3 m A1 Cu
Tc (aCo)
1000 966°C 66.4 (eCo) 0 to 2.8 hP2 P63 /mmc A3 Mg
35.8
36.8
925°C 924°C
b 50 to 53 cI2 Im 3 m A2 W
b 904°C 69.1
800
b1 46.7 to 57 cP20 P4132 A13 bMn
92.1
742°C
79.8
746°C
d
g 69.1 to 82 cP52 P 4 3m D83 Al4 Cu9
20 23.4 46.7 b1 675°C
688°C g1 87.5 … … … …
600 567°C
99.1
d 88 … … … …
g 419.5. 419.58°C
g2 92.5 mC28 C2/m … …
422°C 385°C
400 3.7 (Zn) 100 hP2 P63 /mmc A3 Mg
2.8 52.5
g1 g2
Tc H. Okamoto, J. Phase Equilibria Diffusion, 28(3), 315 (2007)
200
(Zn)
(eCo)
0
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Zinc Zn
Co Weight Percent Zirconium
Co-Zr
0 10 20 30 40 50 60 70 80 90 100
2000
1855°C
1800
Co-Zr
L
1600
Struktur-
1495°C 1452°C
1400
1312°C (aCo) 0 to 1 cF4 Fm 3 m A1 Cu
1272
1232°C 46.6 (eCo) 0 hP2 P6 3/mmc A3 Mg
1200 9.5
1121°C
Tc g 15.5 … … … …
1061°C
65 (bZr) d 20.7 cF116 Fm 3 m D8a Mn2 3Th 6
1000 961°C
(aCo) e 27 to 35 cF24 Fd 3 m C15 Cu2Mg
78.5
834°C 863° C z 50 cP2 Pm 3 m B2 CsCl
800
g d e z h h 66.7 tI12 I4/mcm C16 Al2Cu
(bZr) 95 to 100 cI2 Im 3 m A2 W
600
(aZr) 97.5 to 100 hP2 P6 3/mmc A3 Mg
(aZr)
422°C
(eCo) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
200 1264-1265 (1990)
0 10 20 30 40 50 60 70 80 90 100
Co Atomic Percent Zirconium Zr
0 10 20 30 40 50
60 70 80 90 100
Cr-Cs
1200
1000
(Cr) + G Cr-Cs
G
Struktur-
671°C (Cr) 0 cI2 Im 3 m A2 W
600 Im 3 m
(Cs) 100 cI2 A2 W
M. Venkatraman and J.P. Neuman, Bull. Alloy Phase Diagrams, 5(4), 397
400
L (1984)
(Cr) (Cr) + L
200
28.38°C
0
(Cr) + (Cs) (Cs)
-200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Cesium Cs

0 10 20 30 40 50 60 70 80 90 100
Cr-Cu
2000
1984Cha 1907°C
1985Zen 1863°C
2000Jac
1800
L Cu-Cr
Struktur-
1600 Phase at.% Cr symbol group designation Prototype
(Cu) ~0 cF4 Fm 3 m A1 Cu
(Cr) ~100 cI2 Im 3 m A2 W
1400
1200
1084.87°C 1075°C
1000
(Cu) (Cr)
800
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Chromium Cr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
276
Cr Weight Percent Dysprosium
Cr-Dy
0 10 20 30 40 50 60 70 80 90 100
2100
2015°C
2000 50
1900 L1 L2
1863°C L1 + L2 Cr-Dy
1800 Struktur-
1700 20.0 80.0 Phase at.% Dy symbol group designation Prototype
1600 (Cr) 0 cI2 Im 3 m A2 W
1500 (bDy) (aDy) 100 hP2 P63 /mmc A3 Mg
1400 1412°C
1381°C
1344.5°C S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
95.6
1300
1200
1100 (Cr) (aDy)
1000
900
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Dysprosium Dy
0 10 20 30 40 50 60
70 80 90 100
Cr-Er
2100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
2000
1900
1863°C L
Cr-Er
1800
Struktur-
1600
(Cr) 0 cI2 Im 3 m A2 W
1500
1529°C (Er) 100 hP2 P6 3/mmc A3 Mg
1414.6°C
1400 89.0 S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1300
1200
1100 (Cr) (Er)
1000
900
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Erbium Er
0 10 20 30 40 50
60 70 80 90 100
Cr-Eu
3000
2500
L1 L1 + L2
Cr-Eu
Struktur-
2000
1863°C
1862.8°C Phase at.% Eu symbol group designation Prototype
(Eu) 100 cI2 Im 3 m A2 W
1500
(Cr) + L2 L2 S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1000
822°C
500
(Cr) (Cr) + (Eu) (Eu)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Europium Eu
Cr Weight Percent Fluorine
Cr-F
42 44 46 48 50 52
1450
1404°C
1350
Cr-F
1250
L Struktur-
1150
CrF2 ? to 66.8 mP6 P21/n … …
1050 Cr2F5 70.6 to 71.1 t*42 … … …
997°C
CrF3 74.3 to ? hR24 R3c … …
CrF3
950 B.J. Sturm, Inorg. Chem., 1(3), 665-672 (1960)
894°C
850 831°C
750
66 67 68 69 70 71 72 73 74 75
Atomic Percent Fluorine
Weight Percent Iron

0 10 20 30 40 50 60 70 80 90 100
Cr-Fe
1900
1863°C
1700 L
1513°C 1538°C
Cr-Fe
1500 79 Struktur-
1300 Phase at.% Fe symbol group designation Prototype
(Cr,aFe) 0 to 100 cI2 Im 3 m A2 W
(Cr,aFe)
s 50 to 55.5 tP30 P42/mnm D8b sCrFe
1100 (gFe)
85.7 (gFe) 88.1 to 100 cF4 Fm 3 m A1 Cu
88.1
912°C
900 846°C
830°C O. Kubaschewski, Iron – Binary Alloy Phase Diagrams, Springer-Verlag, Berlin
93
53
770° C (1982)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
700 Tc
s See also
V.P. Itkin, Phase Diagrams of Binary Iron Alloy, H. Okamoto, ed., ASM
51
300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Iron Fe

0 10 20 30 40 50 60 70 80 90 100
Cr-Ga
2000
1863°C 1972Bor
1800
2005Bel
Cr-Ga
1629°C
1600 15.7 32.4 Struktur-
(Cr) 0 to 15.7 cI2 Im 3 m A2 W
1200 (Cr) bCr3Ga 23 … … … …
1101°C
14.5 65.6 aCr3Ga 23 cP8 Pm 3 n A15 Cr3Si
1000
883°C CrGa 50 hR26 R 3m D810 Cr5Al8
80.7 Cr5Ga6 56.6 … … … …
800 775°C
700°C 92.3 CrGa4 77 cI10 I 4 32 … PtHg4
736°C
97.4 (Ga) 100 oC8 Cmca A11 Ga
600

400
200
(Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Gallium Ga
278
Cr
0 10 20 30 40 50
60 70 80 90 100
Cr-Gd
2700
2500 2452°C
50
Cr-Gd
2300 L1 L2 Struktur-
2100 L1 + L2 Phase at.% Gd symbol group designation Prototype
1900 (bGd) 100 cI2 Im 3 m A2 W
1863°C
1760.5°C
(aGd) 100 hP2 P63 /mmc A3 Mg
11 89
1700
S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1500
1300 1278.1°C 98.2 1313°C

1235°C
(bGd)
1100
(Cr)
(aGd)
900
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Gadolinium Gd
0 10 20 30
40 50 60 70 80 90 100
Cr-Ge
2000
1800 Cr-Ge
Struktur-
1600 1564°C 25.2 L Phase at.% Ge symbol group designation Prototype
(Cr) 11.8 21.4
(Cr) 0 to 11.8 cI2 Im 3 m A2 W
1400
Cr3Ge 20.3 to 25.3 cP8 Pm 3 n A15 Cr3 Si
bCr5Ge3 37.2 to 38.4 … … … …
1262°C 44.6 aCr5Ge3 37.2 to 38 tI32 I4/mcm D8m W5Si3
25.3
1200 1170°C Cr11 Ge8 42.1 oP76 Pnam … …
38.4 50.4 CrGe 50 cF8 P2 13 B20 FeSi
Cr11 Ge19 63.3 tP120 P 4 n2 … Mn11 Si19
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1002°C 998°C 66.5
1000
927°C 79.3
938.3°C
895°C 86.7
800
(Ge)
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Gremanium Ge
0 0.02
0.04 0.06 0.08
Cr-H
2000
Cr-H
Struktur-
1900
(Cr) 0 to 4 cI2 Im 3 m A2 W
CrH 47 to 50 hP4 P6 3/mmc B81 NiAs
1863°C Fm 3 m
CrH 2 55 to 67 cF12 C1 CaF2
CrH 3 75 … … … …
M. Venkatraman and J.P. Neumann, J. Phase Equilibria, 12(6), 672-677 (1991)

1800
(Cr)
1700
0 1 2 3 4
Cr Atomic Percent Hydrogen
Cr Weight Percent Hafnium Cr-Hf
0 10 20 30 40 50 60 70 80 90 100
2500
Cr-Hf
2231°C Struktur-
2000 (Cr) 0 cI2 Im 3 m A2 W
bCr2 Hf 33 to 35 hP12 P63 /mmc C14 MgZn2
1863°C 1825°C aCr 2Hf 33 to 35 cF24 Fd 3 m C15 Cu2 Mg
(bHf) (bHf) Im 3 m
1743°C 84 to 100 cI2 A2 W
1665°C (aHf) 99 to 100 hP2 P63 /mmc A3 Mg
13
1500
1500°C M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 7(6), 570-573
70 84
(1986)
1370°C
1335°C
(Cr) (aHf)
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Hafnium Hf
0 10 20 30 40 50 60
70 80 90 100
Cr-Hg
1000
800
Cr-Hg
Struktur-
(Cr) + G G Composition, Pearson Space bericht
400
357°C M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 10(2), 570-
573 (1989)
200
(Cr) + L L
0
-38.8290°C
(Cr) (Cr) + (Hg) (Hg)

-200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Mercury Hg
0 10 20 30 40 50 60
70 80 90 100
Cr-Ho
2400
2200 2185°C
50
Cr-Ho
L1 L2 Struktur-
2000
L1 + L2
1863°C
1800
1731°C (Ho) 100 hP2 P6 3/mmc A3 Mg
15.6 84.4
1600 S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1474°C
1415.7°C
1400 95.5
1200 (Cr) (Ho)
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Holmium Ho
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
280
Cr
80
85 90
Cr-I
900
890
L
880
Cr-I
Struktur-
860 857°C
CrI2 66.7 mC6 C2/m … …
850
CrI3 75 hP24 P31,212 … …
840
831°C L. Guen, M. Allaume, R. Enolie, and J. Flahaut, Compt. Rend. Acad. Sc. Paris,
830
C, 275, 111-114 (1972)
820
810
800
58 60 62 64 66 68 70 72 74 76 78 80 82

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50
60 70 80 90 100
Cr-In
2600
2400
2200 L1 L1 + L2
L2 Cr-In
2000
Struktur-
1863°C
1600
1400 CrIn2 66.7 t** … … …
<1500°C
1200 CrIn3 75 cF4 Fm 3 m A1 Cu
(In) ? to 100 tI2 I4/mmm A6 In
1000
800 H. Okamoto, Phase Diagrams of Indium Alloys and Their Engineering

600
Park, OH, 78-79 (1992)
400
(Cr)
200
156.634°C
(In)
0
-200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Indium In
0 10 20 30 40 50 60
70 80 90 100
Cr-Ir
2500
2447°C
L 2200°C Cr-Ir
73
70 Struktur-
(Cr) 0 to 12 cI2 Im 3 m A2 W
1863°C
Cr3 Ir 17 to 27 cP8 Pm 3 n A15 Cr3Si
24 1750
15 26 32 e 32 to 70 hP2 P6 3/mmc A3 Mg
12 1680 17 (Ir) 72 to 100 cF4 Fm 3 m A1 Cu
1500 M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 11(1), 5-8
(Cr) Cr3Ir e (Ir) (1990)
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Iridium Ir
Cr Weight Percent Potassium
Cr-K
0 10 20 30 40 50 60 70 80 90 100
1200
1000 Cr-K
(Cr) + G G
Struktur-
800 Phase at.% K symbol group designation Prototype
760°C
(K) 100 cI2 Im 3 m A2 W
600
M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 5(4), 398
(1984)
400 (Cr) + L L
200
63.71°C
0
(Cr) (Cr) + (K) (K)
-200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Potassium K
0 10 20 30 40 50
60 70 80 90 100
Cr-La
4000
3833°C
50
3500
L1 L2
Cr-La
3000
Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
2500 Phase at.% La symbol group designation Prototype
2000
1835.1°C
1863°C
2.4 97.6
1500
(Cr) + L2
1000 917.3°C 99.97 918° C
865° C
(gLa)
(Cr) (Cr) + (bLa) (bLa)
500
310°C
(Cr) + (aLa) (aLa)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Lanthanum La
0
10 20 30 40 50 60 80 100
Cr-Li
1500
(Cr) + G G
1344°C
1200 Cr-Li
Struktur-
900
(Cr) + L (Cr) 0 cI2 Im 3 m A2 W
(Cr) L (aLi) 100 hP2 P63 /mmc A3 Mg
600
(1984)
300
180.6°C
0 (Cr) + (bLi) (bLi)
-201°C
(Cr) + (aLi) (aLi)
-300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Lithium Li
282
Cr Weight Percent Lutetium
Cr-Lu
0 10 20 30 40 50 60 70 80 90 100
2100
2000
1900
Cr-Lu
1863°C L Struktur-
1700
1663°C (Cr) 0 cI2 Im 3 m A2 W
1600 (Lu) 100 hP2 P6 3/mmc A3 Mg
1402.8°C
1400 71.1
1300
1200
1100 (Cr) (Lu)
1000
900
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Lutetium Lu
0 10
20 30 40 50 60 70 80 90 100
Cr-Mg
2600
2400
L1 L2
L1 + L2 Cr-Mg
2200
Struktur-
1902°C
1800
1600 (Mg) 100 hP2 P6 3/mmc A3 Mg
1400
(Cr) (Cr) + L2
1200
1000
800
650°C
600
400 (Mg)
200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Magnesium Mg
0 10 20 30
40 50 60 70 80 90 100
Cr-Mn
2000
1863°C
Cr-Mn
Struktur-
L
1500 (Cr) 0 to 71.4 cI2 Im 3 m A2 W
a’ 60.2 to 65.3 … … … …
1312°C 81 a” 60.2 to 65.3 … … … …
89
71.4
77 1278°C 85 1246°C
s 73 to 78 tP30 P42/mnm D8b sCrFe
(dMn)
s’ 75 to 79 … … … …
s (gMn) 1138°C
(Cr) 1100°C s” 75 to 79 … … … …
69 999 78 1020°C (dMn) 85 to 100 cI2 Im 3 m A2 W
1000
926°C
900°C (gMn) 93 to 100 cF4 Fm 3 m A1 Cu
54 s' 94 (bMn)
91 (bMn) 94 to 100 cP20 P4132 A13 bMn
(aMn) 91 to 100 cI58 I 4 3m A12 aMn
a' 727°C
s" (aMn) M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 7(5), 457-462
a" (1986)
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Manganese Mn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cr Weight Percent Molybdenum
Cr-Mo
0 10 20 30 40 50 60 70 80 90 100
3000
2623°C
2500 L Cr-Mo
Struktur-
2000 (Cr,Mo) 0 to 100 cI2 Im 3 m A2 W
1863°C
(1987)
1500
(Cr,Mo)
1000
(Cr) + (Mo)
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Molybdenum Mo
Weight Percent Nitrogen Cr-N
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
2000
1863°C
L
1800°C
Cr-N
1640°C
Struktur-
4. 4 13.4 18 Cr2N Composition, Pearson Space bericht
1500
(Cr) 0 to 4.4 cI2 Im 3 m A2 W
Cr2 N 18 to 32.9 hP9 P 31 m … …
bCrN 49.5 to 50 cF8 Fm 3 m B1 NaCl
aCrN 49.5 to 50 oP4 Pnmm … …
logP N2 (bar) = 0
(Cr) M. Venkatraman and J.P. Neumann, Binary Alloy Phase Diagrams, 2nd ed., T.B.
-1
International, Materials Park, OH, 1293, 1295-1297 (1990)
-2
500
0 10 20 30 40 50 60
Cr Atomic Percent Nitrogen
0 10
20 30 40 50 60 70 80 90 100
Cr-Na
1200
(Cr) + G G
900 884°C Cr-Na
Struktur-
600 (Cr) 0 cI2 Im 3 m A2 W
(Cr) + L
(Cr) L (aNa) 100 hP2 P63 /mmc A3 Mg
300
(1984)
97.8°C
0
(Cr) + (bNa) (bNa)
-237°C
(Cr) + (aNa) (aNa)
-300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Sodium Na
284
Cr Weight Percent Niobium Cr-Nb
0 10 20 30 40 50 60 70 80 90 100
2500
2469°C
2300
Cr-Nb
L Struktur-
2100
1900
1863°C (Cr) 0 to 5.6 cI2 Im 3 m A2 W
bCr 2Nb 30.5 to 38.2 hP12 P6 3/mmc C14 MgZn 2
1730°C
1700 1668°C 33.5 38.2 49.5
1703°C aCr 2Nb 31.5 to 39.5 cF24 Fd 3 m C15 Cu 2Mg
(Cr) 5.6 18.5 30.8 1625°C 75.6
(Nb)
1585°C (Nb) 75.6 to 100 cI2 Im 3 m A2 W
1500 bCr2Nb
1300
1100
900
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Niobium Nb
0 10 20 30 40 50
60 70 80 90 100
Cr-Nd
3000
2890°C
50
2500 L1 L2 Cr-Nd
L1 + L2 Struktur-
1863°C 1795.2°C (Cr) 0 cI2 Im 3 m A2 W
6.6 93.4
1500 (aNd) 100 hP4 P63 /mmc A3’ aLa
(Cr) + L2
1015.9°C 1021°C
1000
(Cr) + (bNd) 99.75
863°C
(bNd)
500
(Cr) (Cr) + (aNd) (aNd)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Neodymium Nd
0 10 20 30
40 50 60 70 80 90 100
Cr-Ni
1900
1863°C
1700
Cr-Ni
L
Struktur-
1500
1455°C Phase at.% Ni symbol group designation Prototype
1345°C (Cr) 0 to 32 cI2 Im 3 m A2 W
1300 (Cr) 32 44 50 g’ 60 to 76 oP6 Immm … MoPt2
(Ni) 50 to 100 cF4 Fm 3 m A1 Cu
1100 P. Nash, Phase Diagrams of Binary Nickel Alloys, P. Nash, ed., ASM
(Ni)
900 See also
700
590°C
g'
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Nickel Ni
Cr Weight Percent Neptunium
Cr-Np
0 10 20 30 40 50 60 70 80 90 100
2000
1863°C
1800
Cr-Np
1600 Struktur-
1400 L (Cr) 0 cI2 Im 3 m A2 W
(gNp) 100 cI2 Im 3 m A2 W
1200 (bNp) 100 tP4 P241 2 Ad bNp
M. Venkatraman, J.P. Neumann, and D.E. Peterson, Bull. Alloy Phase Diagrams,
1000
6(5), 418-419 (1985)
(Cr)
800
(gNp)
639°C
600
576°C
503°C
83
(bNp)
400
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Neptunium Np
0 10
20 30 40 50 60 70 80 90 100
Cr-O
3200
3000 G
2800
Cr-O
2600 Struktur-
2400
L1 L2 Phase at.% O symbol group designation Prototype
2200 (Cr) 0 cI2 Im 3 m A2 W
L1 + L2
Cr3 O4 57.1 tI28 I41 /amd … Mn3O4
2000
Cr2 O3 60 hR10 R 3c D51 aAl2O3
1800
1600
See also
1400
E. Povoden, A.N. Grandy, and L.J. Gauckler, J. Phase Equilibria Diffusion,
1200 27(4), 353-362 (2006)
1000
(Cr)
800
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Oxygen O
0 10 20 30 40 50 60
70 80 90 100
Cr-Os
3200
3000 3033°C
2800
Cr-Os
2600 L Struktur-
2400
2200 (Cr) 0 to 30 cI2 Im 3 m A2 W
2000
Cr3Os 23 to 29 cP8 Pm 3n A15 Cr 3Si
1863°C
1900°C
15 1843°C s 30 to 35 tP30 P42/mnm D8 b sCrFe
30
1800 33 (Os) 35 to 100 hP2 P6 3/mmc A3 Mg
22 1673°C
1600 1540°C 45
20 s
(Os)
1400 (1990)
(Cr)
1200
1000 975°C
33 50
800
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Osmium Os
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
286
Cr Weight Percent Phosphorus
Cr-P
0 10 20 30 40 50 60 70 80 90 100
2000
1863°C
L 1723°C
90Ven
97Zai
Cr-P
1506°C Struktur-
1500
1371°C
15.4 Phase at.% P symbol group designation Prototype
Cr3P 25 tI32 I4 D0e Ni3P
1000 bCr2 P 33.3 hP9 P 62 m C22 Fe2P
aCr 2P 33.3 oP18 Pmmm … …
Cr12 P7 36.8 hP20 P63/m D8k S12Th7
CrP 50 oP8 Pnma B31 MnP
(Cr) Cr2P3 60 … … … …
500 CrP2 66.7 mC12 C2/m … Ge2Os
CrP4 80 mC20 C2/c … MoP4
(P) 100 … … … …
(P)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Phosphorus P
0 10 20 30 40 50 60
Weight Percent Lead
70 80 90 100
Cr-Pb
2500
2087°C
L1 L2 Cr-Pb
2000
Struktur-
L1 + L2
1500 1470°C
9 (Pb) 100 cF4 Fm 3 m A1 Cu
(1988)
1000
(Cr) (Cr) + L2
500
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
327°C
327. 502°C
(Cr) + (Pb) (Pb)

0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Lead Pb
0 10 20 30 40
50 60 70 80 90 100
Cr-Pd
1900
1863°C
1700
L Cr-Pd
1555°C Struktur-
1315°C
1300 (Cr) 0 to 1 cI2 Im 3 m A2 W
1 44 50
CrPd 50 to 52 tP4 P4/mmm L1 0 AuCu
Cr2Pd3 55 to 73 cP4 Pm 3 m L1 2 AuCu3
1100
(Pd) 50 to 100 cF4 Fm 3 m A1 Cu
(Pd)
900 (Cr) M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 11(1), 11-15
(1990)
700
570°C 63
505°C 66
500
52 60
Cr2Pd3
300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Palladium Pd
Cr Weight Percent Promethium
Cr-Pm
0 10 20 30 40 50 60 70 80 90 100
2400
2279°C
2200
L1
2000 L 1 + L2 L2
Cr-Pm
1863°C Struktur-
1800 1742.2°C Composition, Pearson Space bericht
13.8 86.2
1600 Im 3 m
(Cr) 0 cI2 A2 W
1400 (aPm) 100 hP4 P63 /mmc A3’ aLa
(Cr)
1028.8°C 1042°C
1000 99.28
(bPm)
890°C
800
(a Pm)
600
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Promethium Pm
0 10 20 30 40 50
60 70 80 90 100
Cr-Pr
3000
2895°C
50
L2
L1
2500
L1 + L2 Cr-Pr
Struktur-
1863°C 1795.5°C Phase at.% Pr symbol group designation Prototype
6.5 93.5
1500 (bPr) 100 cI2 Im 3 m A2 W
(Cr)
1000
928.3°C 99.86
931°C
(bPr)
795°C
500
(aPr)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Praseodymium Pr

0 10 20 30 40 50 60 70 80 90 100 Cr-Pt
2000
1863°C
L 1784°C Cr-Pt
1800
1769.0°C
76.7 Struktur-
1600 1571 28.1 Phase at.% Pt symbol group designation Prototype
(Cr) 6.8 13.8
21.8 31.3 1530°C (Cr) 0 to 6.8 cI2 Im 3 m A2 W
1400
Cr4Pt 17.3 to 25 cP8 Pm 3 n A15 Cr3Si
(Pt) Cr3Pt 34 to 41 cP4 Pm 3 m L12 AuCu3
CrPt 42 to 58 tP4 P4/mmm L10 AuCu
1200
1134°C CrPt3 60 to 80 cP4 Pm 3 m L12 AuCu3
73.3
(Pt) 31.3 to 100 cF4 Fm 3 m A1 Cu
1000
800
CrPt3
600
CrPt
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Platinum Pt
288
Cr Weight Percent Plutonium
Cr-Pu
0 10 20 30 40 50 60 70 80 90 100
2000
1863°C
1800
Cr-Pu
L
1600 Struktur-
1400 Phase at.% Pu symbol group designation Prototype
1200
(Cr) (ePu) 100 cI2 Im 3 m A2 W
1000
800
600
620°C 640°C (aPu) 100 mP16 P21/m … aPu
99.16
(ePu)
483°C
400 (d'Pu) 463°C M. Venkatraman, J.P. Neumann, and D.E. Peterson, Bull. Alloy Phase Diagrams,
(dPu) 6(5), 419-421 (1985)
320°C
(gPu)
200 215°C
(bPu)
125°C
(aPu)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Plutonium Pu
0 10 20 30 40
50 60 70 80 90 100
Cr-Rb
1200
1000
(Cr) + G Cr-Rb
G
Struktur-
688°C
600
(Rb) 100 cI2 Im 3 m A2 W
M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 5(4), 402
400 (Cr) + L
(1984)
(Cr) L
200
39°C
39.48°C
0
(Cr) + (Rb) (Rb)

-200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Rubidium Rb
0 10 20 30 40 50 60
70 80 90 100
Cr-Re
3200 3186°C
3000
1987Ven
2800 1998Hua
L
2600 Cr-Re
45.7 62.5 2362°C
Struktur-
2400
39.7 49.5 77.6 Composition, Pearson Space bericht
2200 2280°C 59.2 (Re) Phase at.% Re symbol group designation Prototype
2000 (Cr) 0 to 49.5 cI2 Im 3 m A2 W
1863°C
1800
s 56 to 68 tP30 P42/mnm D8b sCrFe
(Re) 77.6 to 100 hP2 P63/mmc A3 Mg
1600
For [1998Hua]
1400
(Cr) s H. Okamoto, J. Phase Equilibria, 20(5), 537 (1999)

1200
1000
800
600
400
265°C
200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Rhenium Re
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cr Weight Percent Rhodium Cr-Rh
0 10 20 30 40 50 60 70 80 90 100
2100
1963°C
1900
1863°C L Cr-Rh
Struktur-
1700
69
(Cr) 0 to 20 cI2 Im 3 m A2 W
1500 27
(Rh) Cr3Rh 22 to 23 cP8 Pm 3 n A15 Cr3Si
20 32
1475°C
e 32 to 82 hP2 P63 /mmc A3 Mg
(Cr) (Rh) 69 to 100 cF4 Fm 3 m A1 Cu
1300 1265°C
19 34
e (1987)
1100
900
700
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Rhodium Rh
0 10 20 30 40
50 60 70 80 90 100
Cr-Ru
2500
2334°C
L Cr-Ru
2000 Struktur-
1863°C
(Cr) 0 to 32 cI2 Im 3 m A2 W
37 1610°C
32 48 Cr3Ru 25 cP8 Pm 3n A15 Cr3Si
1580°C
1500 s 32 to 36 tP30 P42/mnm D8 b sCrFe
(Ru) 48 to 100 hP2 P6 3/mmc A3 Mg
(Cr)
(Ru)
s M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 8(2), 109-112
(1990)
1000 23 1000°C
800°C
750°C
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Ruthenium Ru
0 10 20
30 40 50 60 70 80 90 100
Cr-S
2000
L1
1863°C
1800 L 1 + L2 L2
Cr-S
1600 1565°C
Struktur-
1550°C L3
L2 + L3 Phase at.% S symbol group designation Prototype
1400 1350°C
1300°C (Cr) 0 cI2 Im 3 m A2 W
44 59 Cr1.0 3S 49.3 mC8 C2/c … …
1200 CrS 50 to 59 hP4 P6 3/mmc B81 NiAs
CrS
Cr7S 8 53.2 to 53.5 hP4 P 3 m1 … …
1000 Cr5S 6 54 hP22 P 31 c … …
Cr3S 4 56 to 58.2 mI14 I2/m … …
800 Cr2S 3(I) 58.5 to 59.5 hP20 P 31 c … …
Cr2S 3(II) 59.8 to 60.6 hR10 R3 … …
597°C Cr5S 8 61.5 mF52 F2/m … V5S8
600
Cr2S 5 71.4 … … … …
400 (Cr)
Cr7S8 M. Venkatraman and J.P. Neumann, Binary Alloy Phase Diagrams, 2nd ed., T.B.
Cr5S6 Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
200
0 10 20 30 40 50 60 70 80 90 100 International, Materials Park, OH, 1322, 1324-1326 (1990)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,
Cr Atomic Percent Sulfur S
290
Cr
0 10 20 30 40 50
60 70 80 90 100
Cr-Sb
2000
1863°C
1800
Cr-Sb
1600
L Struktur-
1200 CrSb 47 to 50 hP4 P63/mmc B81 NiAs
1113°C
(Cr) 1102°C CrSb2 66.7 oP6 Pnnm C18 FeS2 (marcasite)
5 42 47
1000 (Sb) 100 hR2 R 3m A7 aAs
800
718°C (1990)
89
620°C 630.755°C
600 95.5
400
(Sb)
200
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Antimony Sb
Weight Percent Scandium Cr-Sc

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
1900
1863°C
Cr-Sc
1700
L Struktur-
1500
(Cr) 0 to ? cI2 Im 3 m A2 W
1337°C
1300 (aSc) ? to 100 hP2 P63 /mmc A3 Mg
(bSc)
1090°C M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 6(5), 422-423
1100
65 (1985)
990°C
900
(Cr) (aSc)
700
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Scandium Sc
0 10 20 30 40
50 60 70 80 90 100
Cr-Se
2000
L1
1863°C
1800 L1 + L2 Cr-Se
L2 Struktur-
1400 (Cr) 0 cI2 Im 3 m A2 W
bCrSe 50 to 60 hP4 P63/mmc B81 NiAs
1200 bCrSe aCrSe 51 to 60.5 hP4 P 3 m1 … …
1100°C
Cr7 Se8 53.5 to 54 mF60 F2/m … …
aCrSe
1000
902°C Cr3 Se4 55.5 to 58.3 mI14 I2/m D7a dNi3 Sn4
Cr2 Se3(I) 59.4 hP20 P 31 c … ...
800
(Cr) P=1 bar (687°C) Cr2 Se3(II) 59.8 to 60.2 hR10 R3 … ...
600 Cr2Se3 (I) Cr5 Se8 61.5 mF52 F2/m … V5S8
(Se) 100 hP3 P3121 A8 gSe
400 362°C Cr2Se3 (II)
M. Venkatraman and J.P. Neumann, Binary Alloy Phase Diagrams, 2nd ed., T.B.
200
220°C
221°C Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM
(Se)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Selenium Se
Cr Weight Percent Silicon
Cr-Si
0 10 20 30 40 50 60 70 80 90 100
2000
1907°C
1900
Cr-Si
1700 Phase at.% Si symbol group designation Prototype
1701°C 1664°C 1666°C
(Cr) (Cr) 0 to 13 cI2 Im 3 m A2 W
1600 Cr3Si 22.4 to 25.3 cP8 Pm 3 n A15 Cr3Si
1519°C bCr5Si3 37.5 to 37.7 … … … …
1488°C
1500 aCr5Si3 37.5 tI32 I4/mcm D8m W5Si3
1439°C
1424°C
1414°C
CrSi 50 cF8 P21 3 B20 FeSi
1400 1408°C CrSi2 66.3 to 68 hP9 P6222 C40 CrSi2
1328°C
1300

1200
(Si)
1100
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Silicon Si
0 10 20 30 40 50
60 70 80 90 100
Cr-Sm
2600
2455°C
2400 50
Cr-Sm
L1 L2
2200 Struktur-
L1 + L2 Phase at.% Sm symbol group designation Prototype
2000
1863°C
1800 1760°C (gSm) 100 cI2 Im 3 m A2 W
11 89
1600 (aSm) 100 hR3 R 3m … aSm
1400 (Cr) S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
(Cr) + L2
1200
99.35 1074°C
1000 (gSm)
922°C
800
(bSm)
734°C
(aSm)
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Samarium Sm
0 10 20 30 40 50
Weight Percent Tin
60 70 80 90 100
Cr-Sn
2000
1863°C
Cr-Sn
L Struktur-
1500 1485°C
1374°C
2 22.8 55.5
1000
(Cr) (1988)
500
232°C
231.9681°C
1.5
(bSn)
(aSn)
13°C
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Tin Sn
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
292
Cr Weight Percent Tantalum
Cr-Ta
0 10 20 30 40 50 60 70 80 90 100
3300
3020°C
2800 Cr-Ta
L
Struktur-
(Cr) 0 to 4.3 cI2 Im 3 m A2 W
bCr2Ta 30.5 to 37.6 hP12 P63 /mmc C14 MgZn2
1863°C (Ta)
1800 bCr2Ta aCr2Ta 33 to 36.5 cF24 Fd 3 m C15 Cu2Mg
(Ta) 73 to 100 cI2 Im 3 m A2 W
(Cr)
1300
800
300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Tantalum Ta
Weight Percent Terbium Cr-Tb

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
2400
2200
L1 L2
2022°C Cr-Tb
2000 50
Struktur-
1863°C L1 + L2 Composition, Pearson Space bericht
1800
1708.8°C
19.8 80.2 (Cr) 0 cI2 Im 3 m A2 W
1600
(Cr) + L2
(aTb) 100 hP2 P63 /mmc A3 Mg
1400
1356°C
1292°C 96.4
1289°C S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1200
(bTb)
1000
(Cr) (aTb)
800
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Terbium Tb
0 10 20 30 40
Weight Percent Technetium
50 60 70 80 90 100
Cr-Tc
2400
L
2200 Cr-Tc
2155°C
Struktur-
2000 Phase at.% Tc symbol group designation Prototype
(Cr) 0 to ? cI2 Im 3 m A2 W
1863°C (Tc)
1800
s 60 to 75 tP30 P42 /mnm D8b sCrFe
(Tc) ? to 100 hP2 P63/mmc A3 Mg
1600 M. Venkatraman and J.P. Neumann, Bull. Alloy Phase Diagrams, 7(6), 573-574
(Cr) s (1986)
1400
1200
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Technetium Tc
Cr Weight Percent Tellurium
Cr-Te
0 10 20 30 40 50 60 70 80 90 100
1863°C
1800
L1 Cr-Te
Struktur-
1600 L1 + L2
1400
1204°C Im 3 m
1283°C Cr1-xTe (Cr) 0 cI2 A2 W
1215°C Cr1-xTe 52.4 to ? … … … …
1200
1181°C 1252°C Cr3Te4 -h 52.4 to 53.4 hP4 P63 /mmc B81 NiAs
hexagonal 53.5 to 59.2 mI14 I2/m … Cr3 S4
1000
Cr3Te4 -l 56.4 to 59.2 mI14 I2/m … Cr3 S4
monoclinic Cr2Te3 59.5 to 60.0 hP20 P 31 c … Cr2 S3
800 Cr5Te6 -m 60.5 to 61.5 mF52 F2/m … V5 Se8
Cr5Te6-tr
630°C Cr5Te6-m Cr5Te6 -tr 61.7 to 62.0 hP20 P 31 c … …
600 574°C
Cr2Te5 71.4 … … … …
480°C CrTe3 75 mp32 P2 1/c … …
455°C 449.57°C
461°C 445°C
400 (Te) 100 hP3 P3 121 A8 gSe
Cr3Te4-l
(Cr)
200 (Te) G. Chattopadhyay, J. Phase Equilibria, 15(4), 431-440 (1994)
Cr2Te 3
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Tellurium Te
0 10 20 30 40 50 60
70 80 90 100
Cr-Th
2000
1900
1863°C
Cr-Th
1800
1755°C Struktur-
1700
1600 (Cr) 0 cI2 Im 3 m A2 W
(bTh) 100 cI2 Im 3 m A2 W
1500 (aTh) 100 cF4 Fm 3 m A1 Cu
(bTh)
1360°C 6(5), 425-429 (1985)
1300
1236°C
75
1200
1100 (Cr) (aTh)
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Thorium Th

2000
0 10 20 30 40 50 60 70 80 90 100 Cr-Ti
1987Mur
1863°C 2000Zhu
1800 Cr-Ti
L Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1600 Phase at.% Ti symbol group designation Prototype

(Cr,bTi) 0 to 100 cI2 Im 3 m A2 W
1410°C gCr2Ti 34.5 to 36.3 hP24 P63/mmc C36 MgNi2
1400 1359°C 56 bCr2Ti 33.3 to 36.5 hP12 P63/mmc C14 MgZn2
gCr2Ti aCr2Ti Fd 3 m
1271°C 33.3 to 37 cF24 C15 Cu2Mg
1269°C 1223°C
1200 (aTi) 99.4 to 100 hP2 P63/mmc A3 Mg
For [2000Zhu]
(Cr, bTi)
bCr2Ti
882°C
804°C
800
2.6
aCr2Ti 667°C 99.4

89 (aTi)
600
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Titanium Ti
294
Cr Weight Percent Thulium
Cr-Tm
0 10 20 30 40 50 60 70 80 90 100
2000
1900
1863°C
1800 L Cr-Tm
Struktur-
1600
1545°C (Tm) 100 hP2 P6 3/mmc A3 Mg
1500
1409.3°C S. Ray and J.P. Neumann, J. Phase Equilibria, 17(3), 179-185 (1996)
1400 89
1300
1200 (Cr) (Tm)
1100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Thulium Tm
0 10 20 30 40 50 60
70 80 90 100
Cr-U
2000
1900
1863°C
1800 Cr-U
1700 Struktur-
1600
L Phase at.% U symbol group designation Prototype
1500
1400 (gU) 96 to 100 cI2 Im 3 m A2 W
1300 (bU) 99 to 100 tP30 P4 2/mnm Ab bU
1200
1135°C
1100 (Cr)
M. Venkatraman, J.P. Neumann, and D.E. Peterson, Bull. Alloy Phase Diagrams,
1000 6(5), 425-429 (1985)
900 860°C
96
81
800 (gU)
738°C 776°C
700 98.4
630°C (bU) 668°C
600 99.1
(aU)
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Uranium U
0 10 20 30
40 50 60 70 80 90 100
Cr-V
1950
Cr-V
1910°C
Struktur-
1900
L (Cr,V) 0 to 100 cI2 Im 3 m A2 W
1863°C
1850
1800
(Cr,V)
1750
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Vanadium V
Cr Weight Percent Tungsten
Cr-W
0 10 20 30 40 50 60 70 80 90 100
3500
3422°C
3000
L Cr-W
Struktur-
2500
(Cr,W) 0 to 100 cI2 Im 3 m A2 W
(Cr,W)
2000 S.V. Nagender Naidu, A.M. Sriramamurthy, and P. Rama Rao, Phase Diagrams
1863°C of Binary Tungsten Alloys, S.V. Nagender Naidu and P. Rama Rao, ed., Indian
1677°C Institute of Metals, Calcutta, India, 69-74 (1991)
50
1500
1000
(Cr) + (W)
500
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Tungsten W
0 10 20 30 40
50 60 70 80 90 100
Cr-Y
2400
2200
2104°C
Cr-Y
L1 32.6
2000
Struktur-
L1 + L2
1863°C
1800 (Cr) 0 cI2 Im 3 m A2 W
1740°C
10.9 61.1
(bY) 100 cI2 Im 3 m A2 W
(aY) 100 hP2 P63 /mmc A3 Mg
1600
(bY)
98.1
1478°C
1400
1300°C
85.9
1200
(Cr) (aY)
1000
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Yttrium Y
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60
70 80 90 100
Cr-Yb
2000
L1 L1 + G
1863°C
Cr-Yb
1500 (Cr) + G G Struktur-
1194°C
1000 (Cr) + L2 L2 (bYb) 100 cF4 Fm 3 m A1 Cu
819° C Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
795°C
(gYb) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1356-1357 (1990)
500
(Cr) (bYb)
0
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Ytterbium Yb
296
Cr
92 93 94
Weight Percent Zinc
95 96 97 98 99 100
Cr-Zn
530
510
(Cr) + L Cr-Zn
L Struktur-
490
481°C
470 CrZn 13 92.8 m** … … …
463°C CrZn 17 94.4 hP* … … …
(Zn) 100 hP2 P6 3/mmc A3 Mg
450
(Cr) + CrZn13 G. Reumont and P. Perrot, J. Phase Equilibria, 24(1), 50-54 (2003)
430
418°C 419.58°C
99.8
410
390 (Zn)
370
90 91 92 93 94 95 96 97 98 99 100
Atomic Percent Zinc Zn
0 10 20 30 40
50 60 70 80 90 100
Cr-Zr
2100
1900
1863°C L 1855°C
Cr-Zr
gCr2Zr 1677°C
1700
46
Struktur-
1625°C
1. 5 17.2
1500 1546°C bCr2Zr
31 1560°C 58 Phase at.% Zr symbol group designation Prototype
1332°C
(Cr) 0 to 1.5 cI2 Im 3 m A2 W
38 76.4 91.6 (bZr) gCr2Zr 32 to 34 hP12 P6 3/mmc C14 MgZn 2
1300
bCr 2Zr 31 to 36 hP24 P6 3/mmc C36 MgNi2
1100 aCr 2Zr 31 to 38 cF24 Fd 3 m C15 Cu 2Mg
(bZr) 91.6 to 100 cI2 Im 3 m A2 W
900 (aZr) 99.2 to 100 hP2 P6 3/mmc A3 Mg
831°C 863°C
98.2
(Cr)
700
(aZr)
500
300
0 10 20 30 40 50 60 70 80 90 100
Cr Atomic Percent Zirconium Zr
0 10
20 30 40 50 60 70 80 90 100
Cs-Cu
1600
1400
G + L2 L2
Cs-Cu
1200
Struktur-
1000 Phase at.% Cu symbol group designation Prototype
G + (Cu) (Cs) 0 cI2 Im 3 m A2 W
G (Cu)
800
671°C W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
400
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L1 L1 + (Cu)
200
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Copper Cu
Cs Weight Percent Fluorine
Cs-F
0 10 20
800
703°C
L
Cs-F
600
Struktur-
(Cs) 0 cI2 Im 3 m A2 W
CsF 50 cF8 Fm 3 m B2 NaCl
400
1361-1362 (1990)
200
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70
Cs Atomic Percent Fluorine
0 10 20
30 40 50 60 70 80 90 100
Cs-Ga
700
L1 L1 + L2
625°C L2
600°C
600
Cs-Ga
Struktur-
426°C (Cs) 0 cI2 Im 3 m A2 W
400 Cs5Ga8 61.5 o** … … …
CsGa3 75 tI24 I 4 m2 … Ga3Rb
CsGa7 87.5 hR16 R 3m … …
300
A.D. Pelton and S. Larose, Bull. Alloy Phase Diagrams, 11(4), 340-343 (1990)
200
100
28.38°C 29.77°C
28.39°C 29.7741°C
(Cs) (Ga)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Gallium Ga
0 10 20
30 40 50 60 70 80 90 100
Cs-Ge
1000
938.3°C
900
L
815°C
800
Cs-Ge
Struktur-
700
661°C Phase at.% Ge symbol group designation Prototype
600
CsGe 50 cP64 P 4 3n … GeK
500 tI64 I41/acd … NaPb
CsGe4 80 cP* Pm3n … …
400 (Ge) 100 cF8 Fd 3 m A4 C (diamond)
300 (Ge) J. Sangster and A.D. Pelton, J. Phase Equilibria, 18(3), 284-286 (1997)
200
100
(Cs) 28°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Germanium Ge
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
298
Cs Weight Percent Hydrogen
Cs-H
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
700
665°C
600 L L1 + L2
Cs-H
522°C Struktur-
400
CsH 50 cF8 Fm 3 m B2 CsCl
300
A.W. Szafranski, E. Keller, and E.U. Franck, Ber. Bunsenges. Phys. Chem.,
96(8), 955-962 (1992)
200 CsH
100
28.39°C
(Cs)
0
0 10 20 30 40 50
Cs Atomic Percent Hydrogen
0 10 20 30
40 50 60 70 80 90 100
Cs-Hf
2500
G + L2 L2
2231°C
2000 G + (bHf) (bHf) Cs-Hf

Struktur-
1743°C
1500
(bHf) 100 cI2 Im 3 m A2 W
G G + (aHf) (aHf) 100 hP2 P63 /mmc A3 Mg
1000
C.W. Bale, Bull. Alloy Phase Diagrams, 8(1), 43-44 (1987)
671°C
500
L1 L1 + (aHf)
(aHf)
(Cs)
28.39°C 28°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Hafnium Hf
0 10 20 30 40
50 60 70 80 90 100
Cs-Hg
250
208°C
200 bCsHg2 Cs-Hg
188°C
L Struktur-
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
171°C
164°C
150
? 140°C 152 Phase at.% Hg symbol group designation Prototype
75.8 Im 3 m
(Cs) 0 cI2 A2 W
CsHg 50 … … … …
100
Cs3Hg4 57.1 … … … …
bCsHg2 66.7 … … … …
50 aCsHg2 66.7 … … … …
CsHg4 80 … … … …
28.39°C 16°C 12°C CsHg6 84 to 85.7 … … … …
2
0 CsHg12 92 c** … … …
-46 -38.8290°C
-50 (Cs) 98 Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R.
(Hg) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
1368-1369 (1990)
-100
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Mercury Hg
Cs Weight Percent Iodine
Cs-I
0 10 20 30 40 50 60 70 80 90 100
800
700
L Cs-I
627°C Struktur-
500 (Cs) 0 cI2 Im 3 m A2 W
CsI 50 cP2 Pm 3 m B2 CsCl
CsI3 75 tP16 Pbnm … …
400
CsI4 80 mP20 P21/a … …
300
200 1368, 1370 (1990)
141°C
115°C
100
70°C
90
28°C
28.39°C
(Cs) (I)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Iodine I
0 10 20
30 40 50 60 70 80 90 100
Cs-In
800
700 L1
L1 + L2 Cs-In
L2
600
Struktur-
570°C 61 Composition, Pearson Space bericht
500 481°C (Cs) 0 cI2 Im 3 m A2 W
80
Cs2In3 60 … … … …
400
CsIn 3 75 tI24 I4m2 … Ga3Rb
300 A.D. Pelton and S. Larose, Bull. Alloy Phase Diagrams, 11(3), 229-232 (1990)
200
156.6°C
156.634°C
100
(Cs) (In)
28.3°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Indium In
0 10
20 30 40 50 60 70 80 90 100
Cs-K
150
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
100
Cs-K
L 63.71°C Struktur-
28.39°C
(Cs,K) 0 to 100 cI2 Im 3 m A2 W
0 CsK 2 66.7 hP2 … … …
-38.05°C C.W. Bale and A.D. Pelton, Bull. Alloy Phase Diagrams, 4(4), 379-382 (1983)
50.5
-50
(Cs,K)
-88°C
-100
-150
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Potassium K
300
Cs Weight Percent Lithium
Cs-Li
0 10 20 30 40 60 100
1400
1342°C
G
1200
Cs-Li
Struktur-
1000
G + L2
800 (bLi) 100 cI2 Im 3 m A2 W
(aLi) 100 hP2 P63 /mmc A3 Mg
671°C
600 C.W. Bale, Bull. Alloy Phase Diagrams, 10(3), 232-233 (1989)
400 L1 L1 + L2 L2
200
180.6°C
(Cs) L1 + (bLi) (bLi)

28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Lithium Li
0
10 20 30 40 50 60 70 80 100
Cs-Mg
900
800
L1 + L2 L2
700 Cs-Mg
650°C
1.6 Struktur-
500 Im 3 m
(Cs) 0 cI2 A2 W
(Mg) 100 hP2 P6 3/mmc A3 Mg
400

300 L1 L1 + (Mg) (Mg)
200
100
28.39°C
0
(Cs) (Cs) + (Mg)
-100
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Magnesium Mg
0 10 20
30 40 50 60 70 80 90 100
Cs-Mo
5000
4639°C
G
Cs-Mo
4000 Struktur-
G + L2 L2 Phase at.% Mo symbol group designation Prototype
3000 (Mo) 100 cI2 Im 3 m A2 W
2623°C
2000
G + (Mo) (Mo)
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1000
671°C
L1
(Cs) L1 + (Mo)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Molybdenum Mo
Cs Weight Percent Sodium
Cs-Na
0 10 20 30 40 50 60 70 80 100
120
100 97.8°C
80 L Cs-Na
Struktur-
60
40
CsNa2 66.7 … … … …
28.39°C (bNa) Im 3 m
100 cI2 A2 W
20

0
-7.9°C
-20
-31.83°C
(bNa)
-40
(Cs)
-60
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Sodium Na
0 10 20
30 40 50 60 70 80 90 100
Cs-Nb
5000
L1 L2
4500
Cs-Nb
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
4000
Struktur-
3500
3000 (Cs) 0 cI2 Im 3 m A2 W
(Nb) 100 cI2 Im 3 m A2 W
2500 2469°C
2000
1500
L1 + (Nb) (Nb)
1000
500
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Niobium Nb
0 2
5 10 15 20 25 30
Cs-O
600
590°C
Cs-O
Struktur-
495°C
450°C Phase at.% O symbol group designation Prototype
425°C
400
Cs7O 12.5 hP24 P 6 m2 … …
Cs4O 20 oP* Pna21 … …
300
Cs11O3 21.4 mP56 P2 1/c … …
L Cs3O 25 … … … …
Cs2O 33.3 hR3 R 3m … N2W
200 CsO 50 oI8 Immm … …
164°C
Cs2O3(a) 60 cI28 I 4 3d D73 Th3P4
bCsO2 66.7 cF8 Fm 3 m B1 NaCl
100
70°C aCsO2 66.7 tI6 I4/mmm C11a CaC2
53°C CsO3 75 … … … …
28.39°C
3°C (a) Not shown.
0 -2°C -10.5
-11°C
(Cs) H. Okamoto, J. Phase Equi. Diffusion, 31(1), 86-87 (2010)
-100
0 10 20 30 40 50 60 70 80
Cs Atomic Percent Oxygen
302
Cs Weight Percent Lead
Cs-Pb
0 10 20 30 40 50 60 70 80 90 100
800
700
647°C L Cs-Pb
L1 + L2 Struktur-
596°C
bCsPb
500 (Cs) 0 cI2 Im 3 m A2 W
bCsPb 50 … … … …
aCsPb 50 tI64 I41/acd … …
400
Cs2 Pb3 60 … … … …
327.502°C CsPb2 66.7 … … … …
300 CsPb3 75 … … … …
Cs4 Pb23 85.2 … … … …
200
(Pb) W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Lead Pb
0 10 20 30
40 50 60 70 80 90 100
Cs-Pr
1100
L1 + L2 L2
1000
L1
930°C 931°C
900
(b Pr) Cs-Pr
800
794°C
795°C Struktur-
700 Phase at.% Pr symbol group designation Prototype
600
500
(aPr) 100 hP4 P6 3/mmc A3’ aLa
(aPr) Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH,
300 1384-1385 (1990)
200
100
(Cs)
28°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Praseodymium Pr
0 10 20
30 40 50 60 70 80 90 100
Cs-Rb
50
40 39.48°C Cs-Rb
Struktur-
L Phase at.% Rb symbol group designation Prototype
30
28.39°C (Cs,Rb) 0 to 100 cI2 Im 3 m A2 W
C.W. Bale and A.D. Pelton, Bull. Alloy Phase Diagrams, 4(4), 382-384 (1983)
20
10 9.7°C
47.0
(Cs,Rb)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Rubidium Rb
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cs Weight Percent Sulfur Cs-S
0 10 20 30 40 50 60 70 80 90 100
600
500
460°C Cs-S
450°C
48 Struktur-
400
Cs2S 33.3 oP12 Pnma C23 Co2Si
300 L1
L2 CsS 50 oI8 Immm … …
Cs2S3 60 oC20 Cmc21 … …
L1 + L2 CsS 2 66.7 … … … …
206°C 213°C 211°C
200 58 182 Cs2S5 71.4 oP28 P212 121 … …
173°C
151 160 74
76 CsS 3 75 aP16 P1 … …
65
115°C
(bS) 100 mP64 P21/c … …
115.22°C
100
(bS)
28.39°C
(Cs)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Sulfur S
0 10 20
30 40 50 60 70 80 90 100
Cs-Sb
800
725°C
700
Cs-Sb
L Struktur-
600 586°C
575°C
560°C Phase at.% Sb symbol group designation Prototype
34.5
553 (Cs) 0 cI2 Im 3 m A2 W
493°C
500 487°C
473°C Cs3 Sb 24 to 25.3 cF16 Fd 3 m B32 NaTl
459
73
38.5
63 417
cF16 Fm 3 m D03 BiF3
404°C
400 59 bCs5Sb2 28.6 … … … …
352°C 339°C aCs5Sb2 28.6 … … … …
300 Cs2 Sb 33.3 … … … …
Cs5 Sb4 44.4 … … … …
CsSb 50 oP16 P2 12 12 1 … …
200
CsSb2 66.7 … … … …
(Sb) bCs3Sb7 70 … … … …
100 aCs3Sb7 70 … … … …
28.39°C (Sb) 100 hR2 R 3m A7 aAs
0 (Cs)
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Antimony Sb

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20
30 40 50 60 70 80 90 100
Cs-Se
800
770°C
700
600 Cs-Se
L Struktur-
500 484°C
432°C
400 Cs2Se 33.3 oP12 Pnma C23 Co2Si
365°C
320°C
338°C Cs3Se2 40 … … … …
300 57 Cs5Se4 44.4 … … … …
274°C
242°C
CsSe 50 … … … …
213°C 215°C 221°C Cs2Se3 60 oC20 Cmc2 1 … …
200 69 88 98 Cs2Se5 71.4 oP28 P2 121 21 … …
170°C
84 CsSe4 80 oP80 Pbcm … …
100
(Se) 100 hP3 P3121 A8 gSe
(Se)
(Cs)
28.39°C
27.5°C J. Sangster and A.D. Pelton, J. Phase Equilibria, 18(2), 173-176 (1997)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Selenium Se
304
Cs Weight Percent Tin
Cs-Sn
0 10 20 30 40 50 60 70 80 90 100
1000
930°C
900 L 875°C
76.5 Cs-Sn
800
760°C
Struktur-
700
L1 + L2 Phase at.% Sn symbol group designation Prototype
630°C (Cs) 0 cI2 Im 3 m A2 W
600°C 40.5
600 580°C CsSn 50 tI64 I41/acd … …
2.3 40
97.5
Cs2 Sn3 60 tP* P4/mcc or P4/cc … …
500 CsSn2 66.7 … … … …
Cs4 Sn23 85.2 cP54 Pm 3 n … …
400
300
231.9681°C J. Sangster and C.W. Bale, J. Phase Equilibria, 19(1), 64-66 (1998)
200
(bSn)
100
(Cs) (aSn)
28.39°C 13°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Tin Sn
0 10 20
30 40 50 60 70 80 90 100
Cs-Sr
900
L2
L1 L1 + L2
800 772°C
769°C
700
L1 + (bSr) (bSr) Cs-Sr

600 Struktur-
547°C
500
400
300
L1 + (aSr) W.G. Moffatt, ed., The Handbook of Binary Phase Diagrams, Genium
(aSr)
200
100
(Cs)
28.6°C
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Strontium Sr

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30
40 50 60 70 80 90 100
Cs-Ta
1400
1200
G Cs-Ta
1000 G + (Ta)
Struktur-
671°C
600 (Ta) 100 cI2 Im 3 m A2 W
S.P. Garg, M. Venkatraman, and N. Krishnamurthy, Phase Diagrams of Binary

400 Tantalum Alloys, S.P. Garg, M. Venkatraman, N. Krishnamurthy, and R.
L L + (Ta) Krishnan, ed., Indian Institute of Metals, Calcutta, India, 44-45 (1996)
200
28.39°C
0
(Cs) (Cs) + (Ta) (Ta)
-200
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Tantalum Ta
Cs Weight Percent Tellurium
Cs-Te
0 10 20 30 40 50 60 70 80 90 100
900
831°C
800 Cs-Te
Struktur-
661°C
622°C L Phase at.% Te symbol group designation Prototype
600 (Cs) 0 cI2 Im 3 m A2 W
bCs 2Te 33.3 … … … …
500 aCs2Te 33.3 oP12 Pnma C23 Co2Si
450°C
449.57°C bCs 5Te3 37.5 t** … … …
400
400°C 395°C aCs5Te3 37.5 m** … … …
345°C bCsTe 48.3 … … … …
300 aCsTe 48.3 oP* Pba2 or Pbam
263°C
235°C g? Cs2Te3 60 oC20 Cmc21 … …
200 215°C Cs2Te5 71.4 oC28 Cmcm … …
CsTe4 80 mP20 P21 /c … …
b?
a? (Te) 100 hP3 P31 21 A8 gSe
100
(Cs) (Te)
27°C
28.39°C H. Okamoto, J. Phase Equilibria, 17(6), 550-551 (1996)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Tellurium Te
0 10
20 30 40 50 60 70 80 90 100
Cs-Ti
2000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1800 G + L2 L2
1670°C
1600
Cs-Ti
Struktur-
1400
G + (bTi) (bTi) (Cs) 0 cI2 Im 3 m A2 W
1200
(bTi) 100 cI2 Im 3 m A2 W
1000 (aTi) 100 hP2 P6 3/mmc A3 Mg
882°C
800
G G + (aTi) C.W. Bale, Bull. Alloy Phase Diagrams, 10(2), 132-133 (1989)
671°C
600
400
L1 L1 + (aTi) (aTi)
200
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Titanium Ti
0 10 20 30 40
50 60 70 80 90 100
Cs-Tl
500
426°C
408°C
L
400
L1 + L2 Cs-Tl
355°C 350°C
Struktur-
310°C Phase at.% Tl symbol group designation Prototype
304°C
300 294°C (bTl) Im 3 m
(Cs) 0 cI2 A2 W
bCs 5Tl7 58.3 … … … …
90
235°C
230°C
aCs5Tl7 58.3 … … … …
Cs4Tl7 63.6 … … … …
200
CsTl3 75 … … … …
(aTl) 100 hP2 P63/mmc A3 Mg
(aTl)
100
V.D. Busmanov and S.P. Yatsenko, Russ. Metall., (5), 157-160 (1981)
28.39°C
(Cs)
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Thallium Tl
306
Cs Weight Percent Vanadium
Cs-V
0 10 20 30 40 50 60 70 80 90 100
4000
G
3500
3409°C
Cs-V
3000 Struktur-
G + L2 L2 Phase at.% V symbol group designation Prototype
2500
(V) 100 cI2 Im 3 m A2 W
2000
1910°C
1500
G + (V) (V)
1000
671°C
500 L1
L1 + (V)
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Vanadium V
0 10 20
30 40 50 60 70 80 90 100
Cs-Zr
2000
G + L2 L2
1855°C
Cs-Zr
Struktur-
1500
G + (bZr) (bZr)
(bZr) 100 cI2 Im 3 m A2 W
1000
(aZr) 100 hP2 P6 3/mmc A3 Mg
863°C
G G + (aZr)
671°C
500
L1 L1 + (aZr) (aZr)
(Cs)
28.39°C
0
0 10 20 30 40 50 60 70 80 90 100
Cs Atomic Percent Zirconium Zr
0 10 20 30 40 50
60 70 80 90 100
Cu-Dy
1500
1400 1412°C Cu-Dy

1381°C
Struktur-
L Phase at.% Dy symbol group designation Prototype
1200 (Cu) 0 cF4 Fm 3 m A1 Cu
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cu7Dy 12.5 … … … …
1100 bCu 5Dy 16.7 hP6 P6/mmm D2d CaCu5
1084.87
aCu 5Dy 16.7 cF24 F 4 3m C15 b AuBe5
1000 Cu9Dy2 18.2 … … … …
965° C 970°C 955°C
Cu7Dy2 22.2 … … … …
930 905°C (bDy)
900 890°C Cu2Dy 33.3 oI12 Imma … CeCu2
855°C 860°C 855
10 845°C 29
840°C CuDy 50 cP2 Pm 3 m B2 CsCl
39.5 790°C
800 775°C (bDy) 88 to 100 cI2 Im 3 m A2 W
70 ?
Cu7Dy
(aDy) 99 to 100 hP2 P6 3/mmc A3 Mg
700
(aDy) P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 9(3a), 331-
600 (Cu) 337 (1988)
500
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Dysprosium Dy
Cu Weight Percent Erbium
Cu-Er
0 10 20 30 40 50 60 70 80 90 100
1600
1529°C
1400
L Cu-Er
1200
Struktur-
1084.87°C
1010°C
1005°C
1000
940 935°C (Cu) 0 cF4 Fm 3 m A1 Cu
895°C 905°C
9.5
885°C
30 38.5
880°C Cu5Er 16.7 cF24 F 4 3m C15 b AuBe5
69.5
800 Cu9Er2 18.2 … … … …
Cu7Er2 22.2 … … … …
Cu2Er 33.3 oI12 Imma … CeCu2
600
CuEr 50 cP2 Pm 3 m B2 CsCl
(Cu) (Er) >99.5 to 100 hP2 P6 3/mmc A3 Mg
(Er)
400
P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 9(3a), 337-
200
342 (1988)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Erbium Er
0 10 20 30 40 50
60 70 80 90 100
Cu-Eu
1200
1084.87°C
1000 Cu-Eu
Struktur-
847°C
842° C
800
13 822°C Phase at.% Eu symbol group designation Prototype
Cu5 Eu 16.7 hP6 P6/mmm D2d CaCu5
597°C 41
Cu2 Eu 33.3 oI12 Imma … CeCu2
600
537°C 51
CuEu 50 oP8 Pnma B27 FeB
CuEu2 66.7 oP12 Pnma … Ca2Cu
73.3
442°C 437°C (Eu) 100 cI2 Im 3 m A2 W
400 (Cu) 74
347 (1988)
200 (Eu)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Europium Eu
0 10 20 30
Weight Percent Iron
40 50 60 70 80 90 100
Cu-Fe
1600
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1538°C
1500 L 1485°C
93.3 (dFe)
92.8
88.5
1400 1394°C
Cu-Fe
1300
(gFe) Struktur-
1200
(Cu) 0 to 4.6 cF4 Fm 3 m A1 Cu
1100
3.5 1096°C (dFe) 93.3 to 100 cI2 Im 3 m A2 W
1084.87 4.6
1000
(Cu)
(aFe) 98.1 to 100 cI2 Im 3 m A2 W
900 912°C
850°C
L.J. Swartzendruber, Phase Diagrams of Binary Iron Alloys, H. Okamoto, ed.,
1.3 ASM International, Materials Park, OH, 131-137 (1993)
800 (aFe)
760°C 770°C
Tc
700
600
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Iron Fe
308
Cu Weight Percent Gallium
Cu-Ga
0 10 20 30 40 50 60 70 80 90 100
1100
1084.87°C Cu-Ga
1000
Struktur-
21.2
900 16.3 836°C
27.45
30.9
L (Cu) 0 to 20.6 cF4 Fm 3 m A1 Cu
800
b b 19.3 to 27.45 cI2 Im 3 m A2 W
z 20.5 to 22.5 hP2 P63/mmc A3 Mg
700
g 645°C z’ 21.0 to 22.4 hP* … … …
620°C 616 34.7
600 20.6 23.7 g 29.5 to 34.7 cP52 P 4 3m D83 Al4Cu9
g1 29.8 to 37.6 cP52 P 4 3m … …
490°C 37.6 485°C 73.6
500
g2 33.9 to 37.7 cP* P 4 3m … …
(Cu) 38.1 76
z g1 468°C
g3 37.5 to 42.6 cP* P 4 3m … …
400
325°C q 64.6 to 66.7 tP3 P4/mmm … …
300 322°C (Ga) 100 oC8 Cmca A11 Ga
42.6 254°C
g3 96
200 P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper Alloys,
z'
P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed., ASM International,
100 OH, 174-184 (1994)
g2 q 29.6°C
(Ga)
29.7741°C
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Gallium Ga
0 10 20 30 40 50
60 70 80 90 100
Cu-Gd
1400
1313°C Cu-Gd
Struktur-
1235°C
1200
L Phase at.% Gd symbol group designation Prototype
1084.87°C
Cu7Gd 12.5 … … … …
1000 Cu6Gd 14.3 oP28 Pnma … …
930°C bCu 5Gd 16 to 17.3 hP6 P6/mmm D2d CaCu5
925°C bCu5Gd
870 870
aCu 5Gd 16 to 17.3 cF24 F 4 3m C15 b AuBe5
860°C 860°C
9.5 825 830°C Cu9Gd2 18.2 … … … …
800 820°C 29
770°C
Cu7Gd2 22.2 … … … …
44
(bGd) Cu2Gd 33.3 oI12 Imma … CeCu2
675°C CuGd 50 cP2 Pm 3 m B2 CsCl
aCu5Gd 630°C 70 85 (bGd) 85 to 100 cI2 Im 3 m A2 W
89.5 98
600 (aGd) 98 to 100 hP2 P6 3/mmc A3 Mg
(aGd)
(Cu) P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 9(3a), 347-
354 (1988)
400
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Gadolinium Gd
0 10 20 30
40 50 60 70 80 90 100
Cu-Ge
1100
1084.87°C
1000
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
L 938.3°C
Cu-Ge
900 Struktur-
824°C
800
12 Phase at.% Ge symbol group designation Prototype
747°C (Cu) 0 to 12 cF4 Fm 3 m A1 Cu
743.5 18.3
700
(Cu) 698°C z 11.5 to 18.3 hP2 P6 3/mmc A3 Mg
e2 e
e 644°C 23.1 to 23.8 hR* … … …
z
600
636°C 36.5
614°C
e1 23.1 to 25.1 oP8 Pmmn D0a bTiCu 3
549.5
e2 26.05 to 26.5 cI2 Im 3 m A2 W
500 (Ge) 100 cF8 Fd 3 m A4 C (diamond)
400 (Ge) R.W. Olesinski and G.J. Abbaschian, Bull. Alloy Phase Diagrams, 7(1), 28-35
e1 (1986)
300
200
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Germanium Ge
Cu Weight Percent Hydrogen
Cu-H
0 0.02 0.04 0.06 0.08
1100
PH2 = 50 MPa
1090
L
Cu-H
L + H2
Struktur-
1075°C (Cu) 0 to 0.2 cF4 Fm 3 m A1 Cu
0.2 0.6
1416-1417 (1990)
1060
(Cu)
(Cu) + H 2
1050
1040
0 1 2 3 4 5
Cu Atomic Percent Hydrogen
0 10 20 30 40 50
60 70 80 90 100
Cu-Hf
2231°C
2200
2000
Cu-Hf
1800
Struktur-
(bHf) 1743°C Composition, Pearson Space bericht
L
1600 1541°C 96 Phase at.% Hf symbol group designation Prototype
78.9 99.6 (Cu) 0 to 0.3 cF4 Fm 3 m A1 Cu
1400 Cu5Hf 16.7 … … … …
1311°C 1283°C
72.9 99.7 Cu51Hf14 21.5 hP65 P6/m … Ag51Gd 14
1200
13.8
1115°C Cu8Hf3 27.3 oP44 Pnma … …
1084.87
1000 963 1054 991°C 33.2 985°C 980°C Cu10Hf7 41.2 oC68 Aba2 … Ni10Zr7
0.3 7.5 961°C 35.7 43.6 (aHf) CuHf2 66.7 tI6 I4/mmm C11 b MoSi2
800
(Cu) (bHf) 96 to 100 cI2 Im 3 m A2 W
(aHf) 99.7 to 100 hP2 P63/mmc A3 Mg
600
400
200
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Hafnium Hf
0 10 20 30 40 50 60
70 80 90 100
Cu-Hg
1200
1100
1084.87°C
1000 L
900 Cu-Hg
800
Struktur-
L 1 + L2 Composition, Pearson Space bericht
700 660°C Phase at.% Hg symbol group designation Prototype
15 90 Fm 3 m
600 (Cu) 0 to 5 cF4 A1 Cu
Cu7Hg6 46 hR52 R 3m … …
500
400 (Cu)
300 D.J. Chakrabarti and D.E. Laughlin, Bull. Alloy Phase Diagrams, 6(6), 522-527
200 (1985)
128°C
100
Cu7Hg6
0 -38.8°C
-38.8290°C
-100
(Hg)
-200
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Mercury Hg
310
Cu
0 10 20 30 40 50
60 70 80 90 100
Cu-Ho
1600
1474°C
Cu-Ho
1400
Struktur-
L
1200 Phase at.% Ho symbol group designation Prototype
1084.87°C (Cu) 0 to 0.02 cF4 Fm 3 m A1 Cu
1000 985°C 990°C
1010°C
bCu5Ho 16.7 hP6 P6/mmm D2d CaCu5
970°C
875°C
920°C 915°C
875°C
aCu5Ho 16.7 cF24 F 4 3m C15b AuBe5
0.02 9.5 870°C 31.4 35.2 830°C Cu9Ho2 18.2 … … … …
800 70
Cu7Ho2 22.2 … … … …
Cu2Ho 33.3 oI12 Imma … CeCu2
600 CuHo 50 cP2 Pm 3 m B2 CsCl
(Ho) 100 hP2 P63/mmc A3 Mg
400
(Ho) P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 9(3a),
355-358 (1988)
200 (Cu)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Holmium Ho
70
80 90 100
Cu-I
140
Cu-I
135
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Struktur-
130
gCuI*1 50 cF8 F 4 3m B3 ZnS (sphalerite)
bCuI*2 50 hP4 P63mc B4 ZnS (wurtzite)
125 aCuI L aCuI*3 50 cF8 F 4 3m B3 ZnS (sphalerite)
*1 602 to 407°C. *2 407 to 356°C. *3 <356°C.
120
R. Kremann and V. Borjanovics, Monatsch. Chem., 36, 923-927 (1915)
H. Okamoto, Phase Diagrams of Binary Copper Alloys, P.R. Subramanian, D.J.

115
Chakrabarti, and D.E. Laughlin, ed., ASM International, OH, 216 (1994)
113.6°C
(I)
110
50 60 70 80 90 100
Atomic Percent Iodine I

0 10 20 30 40 50 60 70 80 90 100
Cu-In
1200
1084.87°C Cu-In
1000 Struktur-
L Phase at.% In symbol group designation Prototype
800 (Cu) 0 to 11 cF4 Fm 3 m A1 Cu
711°C
b 18.6 to 24.4 cI2 Im 3 m A2 W
684°C
g
670°C g 28.3 to 32.5 cP52 P 4 3m … InMn3
b 679
600 (Cu) 620 d 29.3 to 31.4 aP40 P1 … …
577°C h’ 33.4 to 36.5 hP4 P63 /mmc B81 NiAs
h' hP6 P63 /mmc B82 Ni2In
400 383
h 33.4 to 37 o** … … …
Cu11In9 45 mC20 C2/m … …
306°C
277°C
d h 155.5°C
156.634°C
(In)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Indium In
Cu Weight Percent Iridium
Cu-Ir
0 10 20 30 40 50 60 70 80 90 100
2500
2447°C
2300
L
Cu-Ir
2100 Struktur-
(Ir) (Cu) 0 to 8 cF4 Fm 3 m A1 Cu
1700 (Ir) 93.7 to 100 cF4 Fm 3 m A1 Cu
1500
(1987)
1300
4 1138°C
1100 8 97
1084.87°C
(Cu)
900
700
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Iridium Ir
0 10 20 30 40 50
60 70 80 90 100
Cu-La
1200
91Oka
1084.87°C
99Zhe Cu-La
1000 Struktur-
920°C L (gLa) Composition, Pearson Space bericht
918°C
873°C 864
865°C Phase at.% La symbol group designation Prototype
X 9 830°C
800
800°C (Cu) 0 cF4 Fm 3 m A1 Cu
743°C 735°C X 7.5 … … … …
25.5
bCu6La 14.3 oP28 Pnma … CeCu6
600
aCu6La 14.3 mP* … … …
(Cu) 525°C Cu5 La 16.7 hP6 P6/mmm D2d CaCu5
475°C Cu4 La 20 tI90 I 4 m2 … …
71 Cu2 La 33.3 hP3 P6/mmm C32 AlB2
400 (bLa) CuLa 50 oP8 Pnma B27 FeB
310°C (gLa) 100 cI2 Im 3 m A2 W
227°C (bLa) 100 cF4 Fm 3 m A1 Cu
200
(aLa) 100 hP4 P63 /mmc A3’ aLa
(aLa)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Lanthanum La

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0
10 20 30 40 50 70 100
Cu-Li
1200
1100
1084.87°C
1000 L Cu-Li
Struktur-
800 (Cu) 0 to 23.5 cF4 Fm 3 m A1 Cu
700
600
500
400
(Cu)
300
200 180.5°C
180.6°C
(bLi)
100
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Lithium Li
312
Cu Weight Percent Lutetium
Cu-Lu
0 10 20 30 40 50 60 70 80 90 100
1800
1663°C
1600
L Cu-Lu
1400 Struktur-
1200°C Phase at.% Lu symbol group designation Prototype
1200
1084.87 (Cu) 0 cF4 Fm 3 m A1 Cu

1040°C 1000°C 1025°C
995°C 1000°C
1000 985°C
67 Cu5 Lu 16.7 cF24 F 4 3m C15 b AuBe5
920°C 34.5
8
960°C
910°C 30.7
Cu9 Lu2 18.2 … … … …
800 Cu7 Lu2 22.2 … … … …
Cu2 Lu 33.3 oI12 Imma … CeCu2
CuLu 50 cP2 Pm 3 m B2 CsCl
600
(Lu) 100 hP2 P6 3/mmc A3 Mg
400
(Lu) P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 9(3a), 358-
(Cu)
361 (1988)
200
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Lutetium Lu
0 10
20 30 40 50 60 70 80 90 100
Cu-Mg
1100
1084.87°C
1000
Cu-Mg
Struktur-
L
800 797°C (Cu) 0 to 6.93 cF4 Fm 3 m A1 Cu
Cu2Mg 31 to 35.3 cF24 Fd 3 m C15 Cu2Mg
725°C
(Cu) 6.93 23.1 31
CuMg2 66.7 oF48 Fddd Cb CuMg2
700
(Mg) 99.987 to 100 hP2 P63/mmc A3 Mg
650°C
600 A.A. Nayeb-Hashemi and J.B. Clark, Bull. Alloy Phase Diagrams, 5(1), 36-43
568°C
552°C (1984)
35.3 58
500 485°C
85.5 99.987
400
(Mg)
300
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Magnesium Mg

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30
40 50 60 70 80 90 100
Cu-Mn
1300
(dMn)
1200
L
1100 Cu-Mn
1084.87°C
Struktur-
(bMn)
900
(Cu,gMn) 0 to 100 cF4 Fm 3 m A1 Cu
(dMn) ? to 100 cI2 Im 3 m A2 W
800
(Cu,g Mn) (bMn) ? to 100 cP20 P4132 A13 bMn
700 (aMn) ? to 100 cI58 I 4 3m A12 aMn
600
500
(aMn)
400
94Gok
300 93Lew
200
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Manganese Mn
Cu Weight Percent Molybdenum
Cu-Mo
0 10 20 30 40 50 60 70 80 90 100
3000
2800 G + L2
L2
2600 2585°C 2623°C Cu-Mo
13 2515°C 88.5
11.8 89.5 98.4
Struktur-
L1
2200 (Cu) 0 to 0.061 cF4 Fm 3 m A1 Cu
(Mo) 98.4 to 100 cI2 Im 3 m A2 W
2000
P.R. Subramanian and D.E. Laughlin, Bull. Alloy Phase Diagrams, 11(2), 169-
1800 L1 + (Mo)
(Mo) 172 (1990)
1600
1400
1200
1083.4°C
1084.87°C
99.937
1000
(Cu) (Cu) + (Mo)
800
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Molybdenum Mo
0 0.1
0.2 0.3
Cu-Na
1200
L1 + L2
1100 1084°C
L1
1000
Na-Cu
900
Struktur-
700 (bNa) 0 cI2 Im 3 m A2 W
600
500 L1 + (Cu) A.D. Pelton, Bull. Alloy Phase Diagrams, 7(1), 25-27 (1986)
400
300
200
100
97.8°C
(bNa) (bNa) + (Cu)
0
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.11
Na Atomic Percent Copper
0 10 20 30 40
50 60 70 80 90 100
Cu-Nb
2600
2469°C
2400
Cu-Nb
2200 L
Struktur-
2000
1800
(Nb) 98.8 to 100 cI2 Im 3 m A2 W
1600 D.J. Chakrabarti and D.E. Laughlin, Bull. Alloy Phase Diagrams, 2(4), 455-460
(Nb) (1982)
1400
See also
1200
1080°C
1084.87°C 0.2
0.1 98.8
1000
(Cu)
800
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,
Cu Atomic Percent Niobium Nb
314
Cu Weight Percent Neodymium
Cu-Nd
0 10 20 30 40 50 60 70 80 90 100
1200
1100
1084.87 °C
Cu-Nd
1000
(bNd) 1021 °C
Struktur-
950 °C L Composition, Pearson Space bericht
8.4 855°C 863 °C Fm 3 m
845°C 23.6 838 °C
90.5
(Cu) 0 cF4 A1 Cu
800 827°C 24.7 800 Cu6Nd 14.3 oP28 Pnma … CeCu 6
26.9
Cu5Nd 16.7 hP6 P6/mmm D2d CaCu 5
700
Cu4Nd 20 oP20 Pnnm … CeCu 4
Cu2Nd 33.3 oI12 Imma … CeCu 2
(Cu) 616 °C 51.1 CuNd 50 oP8 Pnma B27 FeB
600
(aNd) 100 hP4 P6 3/mmc A3’ aLa
500
459 °C
69.9 H. Okamoto, J. Phase Equilibria, 19(2), 181 (1998)
400
(aNd)
300
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Neodymium Nd
0 10 20 30
40 50 60 70 80 90 100
Cu-Ni
1600
1455°C
1400 L
Cu-Ni
1200 Struktur-
1084.87°C
1000
(Cu,Ni) 0 to 100 cF4 Fm 3 m A1 Cu
800
(Cu,Ni) D.J. Chakrabarti, D.E. Laughlin, S.W. Chen, and Y.A. Chang, Phase Diagrams
of Binary Nickel Alloys, P. Nash, ed., ASM International, Materials Park, OH,
85-95 (1991)
600
400
354.5°C Tc 354.4°C
67.3
200
a1 + a2
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Nickel Ni

--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 5
10 15 20 25
Cu-O
1400
1350 1345°C Cu-O

21.5 Struktur-
L1 L1 + L2 L2 (Cu) 0 to 0.03 cF4 Fm 3 m A1 Cu
1250 Cu2 O 33.3 cP6 Pn 3 m C3 Ag2 O
1230°C
1223°C Cu4 O3* 42.9 tI28 I4/mcm D2c MnU6
31 CuO 50 mC8 … … …
1200
* Not shown.
1150 J.P. Neumann, T. Zhong, and Y.A. Chang, Bull. Alloy Phase Diagrams, 5(2),
136-140 (1984)
1100 1091°C See also
1084.87°C 39
1066°C B. Hallstedt, D. Risold, and L.J. Gauckler, J. Phase Equilibria, 15(5), 483-499
1050
1.7 (1994)
L. Schramm, G. Behr, W. Löser, and K. Wetzig, J. Phase Equilibria Diffusion,
(Cu)
26(6), 605-612 (2005)
1000
0 10 20 30 40 50 60
Cu Atomic Percent Oxygen
Cu Weight Percent Osmium
Cu-Os
0 10 20 30 40 50 60 70 80 90 100
3500
3000 L
3033°C Cu-Os
Struktur-
2500
(Os) 100 hP2 P63 /mmc A3 Mg
2000
1500
1081°C
1084.87°C
1000
(Cu) (Os)
500
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Osmium Os
0 10
20 30 40 50 60 70 80 90 100
Cu-P
1200
1100
1084.87°C
Cu-P
1022°C L Struktur-
891°C (15 atm)
900 (Cu) 0 to 3.5 cF4 Fm 3 m A1 Cu
833°C bCu3P 25 to 31 hP8 P3m1 … …
31 49
800
aCu3P* 26.1 to 26.8 hP24 P63 cm D021 Cu3P
714°C CuP2 66.7 mP12 P21/c … …
700 3.5 15.7
Cu2P7 * 77.8 mC72 C2/m … …
* Not shown.
600
(Cu) P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper
500 Alloys, P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed., ASM
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
400
See also
200
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Phosphorus P
0 10 20 30 40 50 60
Weight Percent Lead
70 80 90 100
Cu-Pb
1200
1084.87°C L
1000 995°C Cu-Pb
955°C 35
15.5 65 Struktur-
L1 + L2
800 (Cu) 0 cF4 Fm 3 m A1 Cu
600 (1984)
(Cu)
See also
400
326°C
327.502°C
99.8
(Pb)
200
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Lead Pb
316
Cu Weight Percent Palladium
Cu-Pd
0 10 20 30 40 50 60 70 80 90 100
1600
1555°C
1400 L
Cu-Pd
1200 Struktur-
1084.87°C
1000
(Cu,Pd) 0 to 100 cF4 Fm 3 m A1 Cu
(Cu,Pd)
a’ 7.6 to 22 cP4 Pm 3 m L12 AuCu3
800 a” 17 to 28 tP28 P4mm … Cu3Pd
2D-LPS 19 to 31 … … … …
600 2D 598°C b 36 to 47 cP2 Pm 3 m B2 CsCl
508°C LPS
P.R. Subramanian and D.E. Laughlin, J. Phase Equilibria, 12(2), 231-243 (1991)
400 a" b
a'
200
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Palladium Pd
0 10 20 30 40 50
60 70 80 90 100
Cu-Pm
1200
1084.87°C
(bPm) 1042°C
1000
L Cu-Pm
930°C
890°C Struktur-
870°C 890°C
850 850°C 90.5
9
800°C
800
705°C 51.3 (Cu) 0 cF4 Fm 3 m A1 Cu
Cu6Pm 14.3 oP28 Pnma … CeCu 6
600
550°C
Cu5Pm 16.7 hP6 P6/mmm D2d CaCu 5
70 Cu4Pm 20 oP20 Pnnm … CeCu 4
Cu7Pm2 22.2 … … … …
(Cu)
400
Cu2Pm 33.3 oI12 Imma … CeCu 2
CuPm 50 oP8 Pnma B27 FeB
(aPm)
200
371 (1988)
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Promethium Pm
0 10 20 30 40 50
60 70 80 90 100
Cu-Pr
1200
1100
1084.87 °C
Cu-Pr
1000
Struktur-
945 °C
L 931 °C Composition, Pearson Space bericht
896° C (bPr)
900
8.6 Phase at.% Pr symbol group designation Prototype
831°C 24.3 831°C (Cu) 0 cF4 Fm 3 m A1 Cu
800 796 91.2 Cu6Pr 14.3 oP28 Pnma … CeCu 6
820 °C 795 °C
24.9 27.0
Cu5Pr 16.7 hP6 P6/mmm D2d CaCu 5
700 Cu4Pr 20 oP20 Pnnm … CeCu 4
Cu2Pr 33.3 oI12 Imma … CeCu 2
CuPr 50 oP8 Pnma B27 FeB
600 (Cu) 582 °C 53.0
(aPr) 100 hP4 P6 3/mmc A3’ aLa
500
442 °C
69.8 H. Okamoto, J. Phase Equilibria, 19(2), 182 (1998)
400
(aPr)
300
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Praseodymium Pr
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
Cu Weight Percent Platinum
Cu-Pt
0 10 20 30 40 50 60 70 80 90 100
1900
1769°C
1700
L Cu-Pt
Struktur-
1300 (Cu,Pt) 0 to 100 cF4 Fm 3 m A1 Cu
Cu3Pt 9 to 24 cP4 Pm 3 m L1 2 AuCu3
(Cu,Pt)
1D-LPS 23 to 28 tP28 P4mm … Cu3Pd
1100
1084.87 CuPt 37 to 53 hR32 R 3m L1 1 CuPt
CuPt3 68 to 75 o** … … …
900
816°C
735°C Alloys, P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, ed., ASM
700 CuPt
650°C ? International, Materials Park, OH, 326-337 (1994)
500
Cu3Pt CuPt3
418°C
1-D LPS
300
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Platinum Pt
0 10 20 30 40 50 60
70 80 90 100
Cu-Pu
1200
Cu-Pu
1084.87°C
Struktur-
954°C L
14
881°C 926
906 25 Phase at.% Pu symbol group designation Prototype
865°C
9 849°C (Cu) 0 cF4 Fm 3 m A1 Cu
29.5
800 Cu6Pu 14.3 oP28 Pnma … CeCu6
Cu17Pu4 19.1 … … … …
Cu4Pu 20 o*20 … … …
626°C 640°C
600 94 97 Cu2Pu 33.3 oI12 Imma … CeCu2
(Cu) (ePu) (ePu) 97 to 100 cI2 Im 3 m A2 W
450°C (d'Pu) 483°C (d’Pu) 100 tI2 I4/mmm A6 In
463°C
425°C
400
315°C
(dPu) (gPu) 100 oF8 Fddd … gPu
320°C
(gPu)
215°C (aPu) 100 mP16 P21/m … aPu
200
(bPu)
125°C P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper Alloys,
(aPu) P.R. Subramanian and D.E. Laughlin, ed., ASM International, Materials Park,
0
0 10 20 30 40 50 60 70 80 90 100
OH, 338-340 (1994)
Cu Atomic Percent Plutonium Pu
0 10 20 30 40 50
60 70 80 90 100
Cu-Re
4000
L1 L2
3500
L1 + L2
3186°C
3000 2900°C Cu-Re
6.7 87
Struktur-
2500
2000 (Re) 100 hP2 P6 3/mmc A3 Mg
P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper Alloys,
1500 P.R. Subramanian and D.E. Laughlin, ed., ASM International, Materials Park,
OH, 348-349 (1994)
1083°C
1084.87°C
1000 0.01
(Cu) (Re)
500
0 10 20 30 40 50 60 70 80 90 100
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,
Cu Atomic Percent Rhenium Re
318
Cu Weight Percent Rhodium
Cu-Rh
0 10 20 30 40 50 60 70 80 90 100
2100
1963°C
1900
Cu-Rh
L
1700
Struktur-
1500 (Cu,Rh) 0 to 100 cF4 Fm 3 m A1 Cu
1300
(Cu,Rh) (1982)
1150°C
1100
1084.87°C
900
(Cu) + (Rh)
700
500
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Rhodium Rh
0 10 20 30 40
50 60 70 80 90 100
Cu-Ru
2400
2334°C
2200
Cu-Ru
L Struktur-
1800
(Ru) 100 hP2 P63/mmc A3 Mg
1600 P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper
1400
See also
1084.87°C 1059°C
2.43
1000
(Cu) (Ru)
800
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Ruthenium Ru
0 10
20 30 40 50 60 70 80 90 100
Cu-S
1600
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
1400 L1
L1 + L2 Cu-S
L2
1200 L3 Struktur-
2 1105°C
1084.87°C Phase at.% S symbol group designation Prototype
1.48 1067°C
1000 L2 + L3
(Cu) 0 to 0.023 cF4 Fm 3 m A1 Cu
bCh 33.33 to 33.47 hP6 P6 3/mmc B82 Ni2In
40.1 813°C
800 36.4 99.83 aCh 33.33 to 33.44 mP144 P21/c … …
Dj 33.73 to 34.08 oP380 … … …
600
Dg 33.33 to 36.6 cF12 Fm 3 m C1 CaF2
Dg 507°C An 36.36 oP44 Pnma … …
435°C 36.6 99.98 Cv 50 hP12 P6 3/mmc B18 CuS
400 (S) 100 mP64 P21/c … bS
(Cu) bCh Cv
200
103.5°C 115.22°C
(1983)
75°C
aCh An (S)
0
0 10 20 30 Dj 40 50 60 70 80 90 100
Cu Atomic Percent Sulfur S
Cu Weight Percent Antimony
Cu-Sb
0 10 20 30 40 50 60 70 80 90 100
1200
Cu-Sb
L
g 15.5 to 16.0 hP2 P63 /mmc A3 Mg
800
d 18.5 to 20.0 hP* P63 /mmc … …
b 19.4 to 30.8 cF16 Fm 3 m D03 BiF3
683°C z 21.3 to 21.6 hP26 P3 … …
645°C e 22.8 to 25.3 oP8 Pmmn D0a bTiCu3
5.8 630.755°C
(Cu)
600
b
586°C h 32.0 to 33.3 tP6 P4/nmm C38 Cu2Sb
526°C (Sb) 100 hR2 R 3m A7 aAs
488°C 63
462°C
5.65
g P.R. Subramanian and D.E. Laughlin, Phase Diagrams of Binary Copper
400°C e 440°C h
400
4.6 360°C
(Sb) International, Materials Park, OH, 372-383 (1994)
d z
260°C
See also
--`,`,``,`,```,,``,``,`,```,,-`-`,,`,,`,`,,`---
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Antimony Sb
0 10 20
30 40 50 60 70 80 90 100
Cu-Sc
1600
1541°C
(bSc)
1400
1337°C Cu-Sc
L
Struktur-
1125°C
1084.87°C
1000 990°C (Cu) 0 to 0.5 cF4 Fm 3 m A1 Cu
925°C
890°C 875°C
Cu4Sc 20 … … … …
865°C
0.5 13 875°C 30 36.5 71 99 Cu2Sc 33.3 tI6 I4/mmm C11 b MoSi2
800
CuSc 50 cP2 Pm 3 m B2 CsCl
(aSc) (bSc) 100 cI2 Im 3 m A2 W
(Cu)
600 (aSc) 99 to 100 hP2 P6 3/mmc A3 Mg
P.R. Subramanian, D.E. Laughlin, and D.J. Chakrabarti, Bull. Alloy Phase
400
Diagrams, 9(3a), 378-382 (1988)
200
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Scandium Sc
0 10 20 30
40 50 60 70 80 90 100
Cu-Se
1600
1: Cu3Se 2
Cu-Se
1400
2: bCuSe Struktur-
L1 L1 + L2 Composition, Pearson Space bericht
3: aCuSe
1200 Phase at.% Se symbol group designation Prototype
1130°C
1084.87°C
1100°C (Cu) 0 cF4 Fm 3 m A1 Cu
1000
1.8 1063°C bCu 2-xSe 33.3 to 36.4 cF12 Fm 3 m C1 CaF 2
L2
aCu 2-xSe 33.3 to 33.8 m** … … …
L3 Cu3Se2 40 tP* P 42 m … …
800
gCuSe 50 hP* P63/mmc … …
L2 + L3
bCuSe 50 o** … … …
600
523°C
aCuSe 50 hP* P63/mmc … …
(Cu) 52.5 CuSe2 66.7 oP6 Pnnm C18 FeS 2 (marcasite)
400 377°C (Se) 100 hP3 P3121 A8 gSe
332°C
221°C
200 (1981)
123°C 120°C
112°C 2 (Se)
aCu2-xSe 51°C
1 3
0
0 10 20 30 40 50 60 70 80 90 100
Cu Atomic Percent Selenium Se
320
Cu Weight Percent Silicon
Cu-Si
0 10 20 30 40 50 60 70 80 90 100
1500
Cu-Si
1414°C
1400 Struktur-
1300
L
(Cu) 0 to 11.15 cF4 Fm 3 m A1 Cu
1200
k 11.05 to 14.5 hP2 P63/mmc A3 Mg
1100 b 14.2 to 17.2 cI2 Im 3 m A2 W
1084.87
g 17.15 to 17.6 cP20 P41 32 A13 bMn
1000

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Phase Diagrams for

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First printing, November 2010

Library of Congress Control Number: 201093980

Printed in the United States of America

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Binary Phase Diagrams

Iron ................................................................................................................................. 376

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Crystal Structure Tables for Systems Where

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William W. Scott, Jr., Ph.D., FASM

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Presently professor, Department of Information Management, Asahi University, Mizuho-shi, Gifu,

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1. Introduction [1990Mas]) and summarized the problems in

Fig. 1 A hypothetical phase diagram showing reactions in binary systems

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Fig. 4a When the solid solubility of the solid + (110%, 0 K)

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Ac Atomic Percent Boron B

Ac Atomic Percent Chromium Cr

Ac Atomic Percent Molybdenum Mo

Ac Atomic Percent Platinum Pt

700 b 32.1 (Ag) 0 to 20.4 cF4 Fm 3 m A1 Cu

Ag Atomic Percent Aluminum Al